CN104910847A - Stone seamless adhesive glue and preparation method thereof - Google Patents
Stone seamless adhesive glue and preparation method thereof Download PDFInfo
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Abstract
The invention discloses stone seamless adhesive glue and a preparation method thereof, relating to the technical field of stone adhesive glue. The stone seamless adhesive glue comprises the following components in parts by weight: 100 parts of unsaturated polyester resin, 3-10 parts of reinforcing agent, 5-15 parts of anti-settling agent, 0.5-1 part of ultraviolet adsorbent and 20-200 parts of filler. According to the invention, the adhesive strength of the stone seamless adhesive glue is remarkably improved, and the shedding phenomenon is avoided; firm seamless bonding of stone is realized; and the color durability of cured colloid under ultraviolet irradiation as well as the uniformity and stability of the colloid state are guaranteed.
Description
Technical field
The present invention relates to stone material bonded adhesives technical field, is specifically stone material seamless binding glue and preparation method thereof.
Background technology
In recent years, along with the development of architectural decoration, stone material is widely used in the wall ground facing of the large public buildings such as airport, subway station, shopping center, conference and exhibition center, Library, is also more and more applied to the parquets decoration etc. of star hotel and high-grade club.Seamless binding, decorative board one integrated mass develops into decoration main flow gradually.In addition, the requirement that artwork, ultra-thin type ceramic goods are seamless spliced is also more and more higher.
But the not special sizing agent carrying out seamless binding for stone material on the market now, general common cloud stone glue or the jointing glue for stone of adopting replaces, but common cloud stone glue and jointing glue for stone carry out seamless binding to stone material all there are some drawbacks.
The drawback being used for seamless binding with reference to patent CN1313556C " reinforced silicon dioxide transparent marble glue " common cloud stone glue is: 1.. the interface of stone material seamless binding is very little, be almost " linearly bonding ", thus very high (compression shear strength is not less than 20MPa) is required for the bonding strength after colloid solidification, and the intensity after common cloud stone glue solidification does not reach the requirement of strength of stone material seamless binding, and be lotion, it is bad that product infiltrates perviousness, causes bonding rear easy generation to come off.2.. common cloud stone glue weathering resistance, ultraviolet resistance are bad according to performance, and after solidification, As time goes on color can change, and makes cemented side seam and stone material produce aberration, affects attractive in appearance.3.. the sophistication of common cloud stone glue to colloid is less demanding, use its to stone material carry out bonding after, bonding vestige is comparatively obvious, does not reach seamless effect.
With reference to patent CN101851482B " jointing glue for stone ", patent CN101805581B " jointing glue for stone ", patent CN101851483B " a kind of jointing glue for stone ", jointing glue for stone is used as seamless binding and there is following drawback: 1.. and jointing glue for stone is mainly used in filling up or filling of gap between stone material and stone material, therefore it requires higher for the anti-contracility after colloid solidification and surperficial air-drying property, and less demanding for the bonding strength after colloid solidification, do not reach the requirement of strength of seamless binding.2.. when using jointing glue for stone to carry out seamless binding to stone material, lessly bonding vestige can be made more shallow if applied, but easily causing obscission; If coating more bonding vestige is comparatively obvious, the object of seamless binding between stone material and stone material fundamentally can not be reached.
Summary of the invention
For the defect existed in prior art, the object of the present invention is to provide stone material seamless binding glue and preparation method thereof, the present invention has increased substantially the bonding strength of stone material seamless binding glue, has stopped obscission; To achieve between stone material and stone material firmly seamless binding; Ensure that the fast in colour property of colloidal condensate under ultraviolet lighting; Ensure that the stable homogeneous of colloidal state.
For reaching above object, the technical scheme that the present invention takes is: stone material seamless binding glue, counts by weight, comprise pre-promotion unsaturated polyester resin 100 parts, toughener 3-10 part, antisettling agent 5-15 part, UV light absorber 0.5-1 part, filler 20-200 part, pigment 0-7 part.
On the basis of technique scheme, described toughener is made up of the lignocellulose of 25 ~ 75% and the modification lignocellulose of 25 ~ 75% by weight percentage.
On the basis of technique scheme, described modification lignocellulose is the one in Walocel MT 20.000PV, Natvosol, Vltra tears; Or described modification lignocellulose by Walocel MT 20.000PV, Natvosol, Vltra tears any two kinds form, often kind is 20 ~ 80% by the weight percent of modification lignocellulose gross weight; Or described modification lignocellulose is made up of Walocel MT 20.000PV, Natvosol, Vltra tears three kinds, often kind is 20 ~ 60% by the weight percent of modification lignocellulose gross weight.
On the basis of technique scheme, described lignocellulose and the wooden cellulosic order number of modification are 1000-1500 order.
On the basis of technique scheme, described antisettling agent by aluminum stearate, barium stearate, nickel stearate, lithium stearate any two kinds form, often kind of weight percent by antisettling agent gross weight is 10 ~ 90%; Or described antisettling agent by aluminum stearate, barium stearate, nickel stearate, lithium stearate any three kinds form, often kind of weight percent by antisettling agent gross weight is 10 ~ 80%; Or described antisettling agent is made up of aluminum stearate, barium stearate, nickel stearate, lithium stearate four kinds, often kind of weight percent by antisettling agent gross weight is 10 ~ 70%.
On the basis of technique scheme, the order number of described antisettling agent is 1000-3000 order.
On the basis of technique scheme, described UV light absorber by p-t-butylphenyl salicylate, ESCALOL 567,2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole, HMPA any two kinds form, often kind of weight percent by antisettling agent gross weight is 10 ~ 90%; Or described UV light absorber by p-t-butylphenyl salicylate, ESCALOL 567,2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole, HMPA any three kinds form, often kind of weight percent by antisettling agent gross weight is 10 ~ 80%; Or described UV light absorber is made up of p-t-butylphenyl salicylate, ESCALOL 567,2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole, HMPA four kinds, often kind of weight percent by antisettling agent gross weight is 10 ~ 70%.
On the basis of technique scheme, the weight percent meter of filler gross weight pressed by described filler, comprises silica 1 0%-70%, water-ground limestone 10%-70%, aluminium hydroxide 10%-70%, talcum powder 0%-10%, dry powder 10%-70%.
On the basis of technique scheme, described silicon-dioxide order number is 1000-5000 order, and water-ground limestone order number is 1000-5000 order, and aluminium hydroxide order number is 1000-5000 order, talcous order number is 1000-3000 order, and the order number of dry powder is 1000-5000 order.
On the basis of technique scheme, in described filler, the whiteness of silicon-dioxide, water-ground limestone, aluminium hydroxide, talcum powder, dry powder is all not less than 90 °.
On the basis of technique scheme, one or more in titanium dioxide, carbon black, medium chrome yellow medium yellow, iron oxide yellow, red iron oxide, chromoxide green, ultramarine, phthalocyanine blue, phthalocyanine green, fluorescent yellow, everbright fast red, Lithol Red elected as by described pigment.
The present invention also provides a kind of preparation method based on above-mentioned stone material seamless binding glue, comprises the following steps:
1) component is taken by above-mentioned raw materials parts by weight, for subsequent use;
2) by above-mentioned component vacuum tightness be 0.08-0.1Mpa, rotating speed be the negative pressure state being not less than 1500r/min under high-speed stirring even, churning time is 30-45 minute, namely obtains stone material seamless binding glue.
Beneficial effect of the present invention is:
1. the present invention adopts lignocellulose and the wooden cellulosic composition of modification as toughener, and in conjunction with 0.08-0.1MPa negative pressure state and the processing condition being not less than 1500r/min rotating speed, increase substantially the bonding strength of stone material seamless binding glue, stop the generation of obscission.
2. in the filler of stone material seamless binding glue of the present invention, the whiteness of silicon-dioxide, water-ground limestone, aluminium hydroxide, talcum powder, dry powder is all not less than 90 °, therefore the Color tunable after solidification is assigned to and stone material solid colour, and after adding UV light absorber, can shine by ultraviolet resistance, keep fast in colour stable, not passing in time and variable color, adds the aesthetic property of product.
3. the present invention adopts the filler of high order number, makes colloid fine and smooth, stone material rear gap bonding with stone material can be made very little, close to seamless state, reach the object of seamless binding between stone material and stone material.
4. stone material seamless binding glue of the present invention is fluid or semi-fluid condition, good penetrability, can make that bonding interface is less, cemented side seam is thinner, improve the effect of seamless binding between stone material and stone material.
5. the adding of antisettling agent of the present invention, make colloid not easily layering, can place for a long time, ensure that the stable homogeneous of colloidal state.
Accompanying drawing explanation
Accompanying drawing 1 is the graphic representation that the compression shear strength of stone material seamless binding adhesive curing thing and bending elastic modulus change with Mierocrystalline cellulose add-on;
Accompanying drawing 2 is the graphic representation that the tensile shear strength of stone material seamless binding adhesive curing thing and impelling strength change with Mierocrystalline cellulose add-on;
Accompanying drawing 3 is the graphic representation that the compression shear strength of stone material seamless binding adhesive curing thing changes with antisettling agent add-on.
Embodiment
Below in conjunction with drawings and Examples, the present invention is described in further detail.
Stone material seamless binding glue, counts by weight, comprises pre-promotion unsaturated polyester resin 100 parts, toughener 3-10 part, antisettling agent 5-15 part, UV light absorber 0.5-1 part, filler 20-200 part, pigment 0-7 part.It is mainly used in the seamless binding between stone material and stone material, as marble, quartzite, grouan, rostone etc.Seamless binding between the pottery that it also can be used for breaking, artwork gap.
Wherein, in advance promote that unsaturated polyester resin is the unsaturated polyester resin adding promotor, stopper and thinner.Unsaturated polyester resin is adjacent benzene-type unsaturated polyester resin, metaphenylene unsaturated polyester resin, terephthalic unsaturated polyester resin, Bisphenol a unsaturated polyester resin, dicyclopentadiene type unsaturated polyester resin, one or more in vinyl ester unsaturated polyester resin.Promotor is transition metal organic salt (manganese naphthenate, naphthenic acid vanadium, cobalt naphthenate, cobalt octoate etc.) and tertiary amine compounds (N, accelerine, N, N-Diethyl Aniline, N, N-dimethyl open-chain crown ether etc.), stopper is phenols or quinones (Resorcinol, pyrocatechol, p-ten.-butylcatechol, '-biphenyl diphenol, para benzoquinone, naphthoquinones, phenanthrenequione etc.).
Toughener is lignocellulose and modification lignocellulose composition, be made up of the lignocellulose of 25 ~ 75% and the modification lignocellulose of 25 ~ 75% by weight percentage, modification lignocellulose is the one in Walocel MT 20.000PV, Natvosol, Vltra tears; Or modification lignocellulose by Walocel MT 20.000PV, Natvosol, Vltra tears any two kinds form, often kind is 20 ~ 80% by the weight percent of modification lignocellulose gross weight; Or modification lignocellulose is made up of Walocel MT 20.000PV, Natvosol, Vltra tears three kinds, often kind is 20 ~ 60% by the weight percent of modification lignocellulose gross weight.Lignocellulose and the wooden cellulosic order number of modification are 1000-1500 order.
Antisettling agent by aluminum stearate, barium stearate, nickel stearate, lithium stearate any two kinds form, often kind of weight percent by antisettling agent gross weight is 10 ~ 90%; Or described antisettling agent by aluminum stearate, barium stearate, nickel stearate, lithium stearate any three kinds form, often kind of weight percent by antisettling agent gross weight is 10 ~ 80%; Or described antisettling agent is made up of aluminum stearate, barium stearate, nickel stearate, lithium stearate four kinds, often kind of weight percent by antisettling agent gross weight is 10 ~ 70%.The order number of antisettling agent is 1000-3000 order.
UV light absorber by p-t-butylphenyl salicylate, ESCALOL 567,2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole, HMPA any two kinds form, often kind of weight percent by antisettling agent gross weight is 10 ~ 90%; Or described UV light absorber by p-t-butylphenyl salicylate, ESCALOL 567,2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole, HMPA any three kinds form, often kind of weight percent by antisettling agent gross weight is 10 ~ 80%; Or described UV light absorber is made up of p-t-butylphenyl salicylate, ESCALOL 567,2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole, HMPA four kinds, often kind of weight percent by antisettling agent gross weight is 10 ~ 70%.
The weight percent meter of filler gross weight pressed by filler, comprises silica 1 0%-70%, water-ground limestone 10%-70%, aluminium hydroxide 10%-70%, talcum powder 0%-10%, dry powder 10%-70%.Silicon-dioxide order number is 1000-5000 order, and water-ground limestone order number is 1000-5000 order, and aluminium hydroxide order number is 1000-5000 order, and talcous order number is 1000-3000 order, and the order number of dry powder is 1000-5000 order.The whiteness of silicon-dioxide, water-ground limestone, aluminium hydroxide, talcum powder, dry powder is all not less than 90 °.
Pigment is one or more in titanium dioxide, carbon black, medium chrome yellow medium yellow, iron oxide yellow, red iron oxide, chromoxide green, ultramarine, phthalocyanine blue, phthalocyanine green, fluorescent yellow, everbright fast red, Lithol Red.
Based on a preparation method for above-mentioned stone material seamless binding glue, comprise the following steps:
1) component is taken by above-mentioned raw materials parts by weight, for subsequent use;
2) by above-mentioned component vacuum tightness be 0.08-0.1Mpa, rotating speed be the negative pressure state being not less than 1500r/min under high-speed stirring even, churning time is 30-45 minute, namely obtains stone material seamless binding glue.
Add cellulose substances in the present invention and obviously can increase gel strength, its enhanced mechanism is as follows: Mierocrystalline cellulose has very high mechanical moduli and intensity usually, when taking unsaturated polyester resin as matrix, when strengthening with Mierocrystalline cellulose, matrix can produce plasticity under stress, load is delivered on fiber, bears load by fiber.Matrix makes fibres bond fix, and protects fiber, makes it to be in steady state, material is thus formed the matrix material of a kind of high strength and high modulus.
The determination of each component of stone material seamless binding glue of the present invention:
Count by weight, get pre-promotion unsaturated polyester resin 100 parts, 3000 order silica flours 8 parts, 1250 4 parts, order aluminium hydroxides, 1000 object water-ground limestones 4 parts, 1500 object dry powders 4 parts, 2000 object aluminum stearates 2 parts, 1500 object nickel stearates 3 parts, ESCALOL 567 0.1 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.4 part, carbon black 0.15 part, what add Different Weight part again is 1000 object tougheners, and under 0.08Mpa negative pressure, 1500r/min high-speed stirring obtains colloid.Get this colloid of 100 weight parts, the solidifying agent being blended into 3 weight parts is cured.With reference to JC/T989-2006 method, Mechanics Performance Testing is carried out to stone material seamless binding adhesive curing thing, the results are shown in table 1,2,3,4, table 1, table 2, table 3, table 4 for after adding different components Mierocrystalline cellulose of the present invention respectively, the value of the compression shear strength of stone material seamless binding adhesive curing thing, tensile shear strength, bending elastic modulus, impelling strength.Accompanying drawing 1 and accompanying drawing 2 be respectively table 1,2,3, the change curve of 4 correspondences, wherein:
It is lignocellulose that A representative adds Mierocrystalline cellulose.
B representative adds Natvosol and lignocellulose, and weight ratio is 1:1.
C representative adds lignocellulose, Natvosol, Vltra tears, and weight ratio is 1:1:1.
D representative adds lignocellulose, Walocel MT 20.000PV, Natvosol, Vltra tears, and weight ratio is 1:1:1:1.
Table 1 adds the compression shear strength value (MPa) after different components Mierocrystalline cellulose
Table 2 adds the tensile shear strength value (MPa) after different components Mierocrystalline cellulose
Table 3 adds the bending elastic modulus (MPa) after different components Mierocrystalline cellulose
Table 4 adds the impelling strength (KJ/m after different components Mierocrystalline cellulose
2)
Shown in accompanying drawing 1 and accompanying drawing 2, add Mierocrystalline cellulose as after toughener, compression shear strength and the tensile shear strength of unsaturated polyester resin cured article significantly improve, and increase along with the increase of Mierocrystalline cellulose add-on, when cellulose amount is increased to after 9 parts, intensity level starts to decline.
Shown in accompanying drawing 1 and accompanying drawing 2, add Mierocrystalline cellulose as after toughener, bending elastic modulus and the impelling strength of stone material seamless binding adhesive curing thing significantly improve, and increase along with the increase of Mierocrystalline cellulose add-on, after add-on is more than 10 parts, be no longer significantly increased.
In the present embodiment, by above-mentioned formula, add different types of Mierocrystalline cellulose, wherein Mierocrystalline cellulose add-on is 9 parts, and order number is 1000 orders, obtained stone material seamless binding glue.Get this colloid of 100 weight parts, be blended into 3 weight part solidifying agent solidifications.The mechanical property of test stone material seamless binding adhesive curing thing is as shown in table 5, wherein:
A: Walocel MT 20.000PV.
B: Natvosol.
C: Vltra tears.
D: lignocellulose.
E: Natvosol and lignocellulose weight ratio are 1:1.
F: Walocel MT 20.000PV and lignocellulose weight ratio are 1:1.
G: Vltra tears and lignocellulose weight ratio are 1:1.
H: Walocel MT 20.000PV, Natvosol and lignocellulose weight ratio are 1:1:1.
I: Walocel MT 20.000PV, Vltra tears and lignocellulose weight ratio are 1:1:1.
J: Natvosol, Vltra tears and lignocellulose weight ratio are 1:1:1.
K: Walocel MT 20.000PV, Natvosol, Vltra tears and lignocellulose weight ratio are 1:1:1:1.
Table 5 adds the stone material seamless binding adhesive curing thing mechanical property after different components Mierocrystalline cellulose
Ginseng is shown in Table 5, Walocel MT 20.000PV, Natvosol, Vltra tears all has good reinforced effects, the reinforced effects of lignocellulose is relatively poor, and Walocel MT 20.000PV, Natvosol and Vltra tears are formed by lignocellulose modification, better than lignocellulose with the consistency of unsaturated polyester resin, but because the cost of lignocellulose is lower, therefore present invention employs lignocellulose and modification lignocellulose carries out interworking use.
In stone material seamless binding glue of the present invention, add UV light absorber can make colloid ultraviolet resistance photograph, color and luster keeps stable.Hydroxyl-OH and carbonyl C=O or diazo N=N is had in UV absorber molecules formula; Sauerstoffatom in carbonyl and the nitrogen-atoms in diazo all also exist lone-pair electron; it is the group that electronegativity is stronger; easily intramolecular hydrogen bond is formed with electropositive hydrogen atom aobvious in hydroxyl; form chelate ring; it is unstable after they absorb the energy of UV-light; generation molecular heat vibrates; hydrogen bond destroys; chelate ring is opened; will release energy, and change harmful UV-light into harmless heat energy, thus protect material.Therefore a small amount of UV light absorber can protect stone material seamless binding adhesive curing thing color stability of the present invention enduringly.
Count by weight, get pre-promotion unsaturated polyester resin 100 parts, 1500 object lignocelluloses 2 parts, 1250 object Natvosols 2 parts, 1500 object barium stearates 5 parts, 1000 object nickel stearates 6 parts, 2500 order silica flours 20 parts, 1000 30 parts, order aluminium hydroxides, 5000 object water-ground limestones 25 parts, 1250 object talcum powder 10 parts, 3000 object dry powders 20 parts, titanium dioxide 6 parts, phthalocyanine blue 0.01 part, add the UV light absorber of different ratios again, under 0.08Mpa negative pressure, 1500r/min high-speed stirring obtains colloid, detect according to GB/T14522-2008 method, by stone material seamless binding adhesive curing thing in ultraviolet light and aging proofing box (model: LRHS-UVN, producer: Shenyang ultraviolet ageing test box factory) in illumination after 70 hours under UVA340nm type fluorescent ultraviolet lamp, with color difference meter, (brand: 3nh tri-grace is speeded, model: NR110, producer: Tianyouli Standard Light-Source Co., Ltd., Shenzhen) survey its value of chromatism result as table 6, wherein
A:2-hydroxyl-4-methoxy benzophenone.
B:2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole.
C: HMPA.
D: p-t-butylphenyl salicylate.
E:2-hydroxyl-4-methoxy benzophenone and 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole weight ratio are 1:1.
F:2-hydroxyl-4-methoxy benzophenone and HMPA weight ratio are 1:2.
G: p-t-butylphenyl salicylate, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole and HMPA weight ratio are 1:2:1.
H: p-t-butylphenyl salicylate, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole, ESCALOL 567 and HMPA weight ratio are 1:1:2:1.
Table 6 color difference meter institute colour examining difference
Ginseng is shown in Table 6, and makes colloid ultra-violet resistance of the present invention can have remarkable improvement after UV light absorber adds.UV light absorber of the present invention is different classes of material, find in experiment, adopt the ultra-violet resistance after two or more interworking of above-mentioned ultraviolet can significantly better than one-component ultra-violet resistance energy, value of chromatism Δ E is all less than 2.0, and therefore the present invention adopts two or more ratio interworking to use.
Stone material seamless binding glue of the present invention is fluid or semi-fluid condition, adds stearates as antisettling agent, colloid can be made not stratified, can place for a long time, ensure that the quality stability of colloid.Antisettling agent has very strong swelling gelatinisation ability, high polymer long chain in system can be made swelling and be mutually wound around after adding, thus changes the rheological property of system, prevents filling settlement from occurring layering.
After adding a certain amount of stearates in stone material seamless binding glue of the present invention, can form oil reservoir interface when bonding stone material, affect adhesive effect, available compression shearing resistance characterizes.Count by weight, get pre-promotion unsaturated polyester resin 100 parts, 1500 object lignocelluloses 4.5 parts, 1000 object Vltra tearss 4.5 parts, p-t-butylphenyl salicylate 0.2 part, ESCALOL 567 0.5 part, 2000 order silica flours 15 parts, 3000 5 parts, order aluminium hydroxides, 1500 order water-ground limestones 20 parts, 3000 order dry powders 5 parts, the antisettling agent adding different amount (tests aluminum stearate and nickel stearate two component of to be weight ratio be 1:1 used, order number is 1250 orders), under 0.08Mpa negative pressure, 1500r/min high-speed stirring obtains colloid.Get this colloid of 100 weight parts, be blended into 3 weight part solidifying agent solidifications.Test the compression shear strength of stone material seamless binding adhesive curing thing with reference to JC/T989-2006 method, its changing value lists in table 7, and accompanying drawing 3 is its corresponding change curve.
Table 7 adds compression shear strength value after aluminum stearate and nickel stearate two component
Its compression shear strength variation tendency and above-mentioned close after other stearates of the present invention add.
Shown in accompanying drawing 3, after adding stearate in colloid, its compression shear strength can decline along with the increase of the add-on of stearate, when add-on is less than 15 weight part, compression shear strength fall is little, can obviously decline after more than 15 weight parts, therefore in stone material seamless binding glue of the present invention the add-on of antisettling agent no more than 15 weight parts.
Count by weight, get pre-promotion unsaturated polyester resin 100 parts, 1500 object lignocelluloses 4.5 parts, 1000 object Vltra tearss 4.5 parts, p-t-butylphenyl salicylate 0.2 part, ESCALOL 567 0.5 part, 2000 order silica flours 15 parts, 3,000 5 parts, order aluminium hydroxides, 1500 object water-ground limestones 20 parts, 3000 object dry powders 5 parts, then add the antisettling agent of different components, add-on is 6 parts.Obtained colloid is left standstill, observation colloid phase-splitting situation, record phase-splitting time.Table 8 leaves standstill the time occurring phase-splitting after adding different components stearate, adds stearate order number and all selects 1250 orders.Wherein
A: aluminum stearate.
B: barium stearate.
C: nickel stearate.
D: lithium stearate.
E: aluminum stearate and barium stearate weight ratio are 1:1.
F: aluminum stearate and nickel stearate weight ratio are 2:3.
G: aluminum stearate and lithium stearate weight ratio are 3:2.
H: barium stearate and nickel stearate weight ratio are 1:2.
I: barium stearate and lithium stearate weight ratio are 2:1.
J: nickel stearate and lithium stearate weight ratio are 1:1.
K: aluminum stearate, barium stearate and nickel stearate weight ratio are 1:1:1.
L: aluminum stearate, barium stearate and lithium stearate weight ratio are 1:2:1.
M: barium stearate, nickel stearate and lithium stearate weight ratio are 1:1:2.
N: aluminum stearate, barium stearate, nickel stearate and lithium stearate weight ratio are 1:1:1:1.
Other ratio also can produce effect same.
Table 8 adds the standing phase-splitting time after different components stearate
Note: the colloid of stone material seamless binding glue of the present invention leaves standstill the phase-splitting time and must ensure more than 12 months, otherwise does not reach requirement of dispatching from the factory.
Ginseng is shown in Table 8, and makes colloid resistance to settling of the present invention have remarkable improvement after antisettling agent adds.Draw in experiment and adopt the separation time of two or more component colloid of above-mentioned antisettling agent to be obviously longer than the separation time adding single component colloid, therefore antisettling agent of the present invention have employed two or more ratio interworking use.
Filler of the present invention is 1000-5000 object silicon-dioxide, account for the 10%-70% of filler gross weight, 1000-5000 object water-ground limestone, account for the 10%-70% of filler gross weight, 1000-5000 object aluminium hydroxide, account for the 10%-70% of filler gross weight, 1000-3000 object talcum powder, account for the 0%-10% of filler gross weight, 1000-5000 object dry powder, account for the 10%-70% of filler gross weight, the filler of high order number can make colloid very fine and smooth, and above-mentioned filler all can be good at merging with stone material; And the whiteness of silicon-dioxide, water-ground limestone, aluminium hydroxide, talcum powder, dry powder is all not less than 90 ° in filler of the present invention, colloid background color more shallow being conducive to can be made to mix colours.
The manufacturing condition of stone material seamless binding glue of the present invention is high-speed stirring under the negative pressure state of 0.08-0.1Mpa, and rotating speed is not less than 1500r/min.Stir under negative pressure state and can not make to produce bubble in colloid, if the bubble containing small wall thickness, colloid surface can be made coarse fineless and smooth, and after colloid solidification, inside there is cavity, produces internal stress and affects the mechanical properties.Meanwhile, adopt this technique that additive is fully homogenized, thus eliminate the interfacial stress between solid solid interface, solid-liquid interface, further increase mechanical property.
Count by weight, get pre-promotion unsaturated polyester resin 100 parts, 5000 object silica flours 20 parts, 1000 10 parts, object aluminium hydroxides, 4000 object water-ground limestones 30 parts, 3000 object talcum powder 5 parts, 4000 object dry powders 10 parts, 1500 object aluminum stearates 5 parts, 1250 object nickel stearates 5 parts, 1250 object Natvosols 3 parts, 1250 object lignocelluloses 3 parts, medium chrome yellow medium yellow 0.2 part, iron oxide yellow 0.1 part, Lithol Red 0.01 part, under negative pressure 0.08Mpa, under 1500r/min high-speed stirring and normal pressure, 400r/min stirs obtained colloid respectively.Get this colloid of 100 weight parts, be blended into 3 weight part solidifying agent solidifications.With reference to JC/T989-2006 method, stone material seamless binding adhesive curing thing impelling strength and bending elastic modulus are tested.
Table 9 stone material seamless binding adhesive curing thing impelling strength and bending elastic modulus
Ginseng is shown in Table 9, the mechanical property that the mechanical property that high-speed stirring obtains colloid under negative pressure state obtains colloid compared with atmospheric agitation promotes to some extent, therefore processing condition of the present invention are high-speed stirring under the negative pressure state of 0.08-0.1Mpa, and rotating speed is not less than 1500r/min.
Cloud stone glue technical requirements
(People's Republic of China (PRC) building material industry standard JC/T989-2006)
Below by 22 embodiments, the present invention is specifically described:
Embodiment 1 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting unsaturated polyester resin 100 parts in advance, 1250 object lignocelluloses 1 part, 1000 object Walocel MT 20.000PVs 3 parts, 1500 object aluminum stearates 0.5 part, 1000 object barium stearates 4.5 parts, ESCALOL 567 0.1 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.4 part, 2000 object silicon-dioxide 20 parts, 4000 object water-ground limestones 10 parts, 5000 10 parts, object aluminium hydroxides, 2500 order dry powders 15 parts, 0.02 part, ultramarine, titanium dioxide 5 parts composition.
Embodiment 2 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting unsaturated polyester resin 100 parts in advance, 1000 object lignocelluloses 1 part, 1500 object Natvosols 2 parts, 1000 object aluminum stearates 4 parts, 3000 object lithium stearates 2 parts, p-t-butylphenyl salicylate 0.3 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.5 part, 1250 object silicon-dioxide 20 parts, 1500 object water-ground limestones 30 parts, 1000 50 parts, object aluminium hydroxides, 1250 order talcum powder 5 parts, 5000 order dry powders 80 parts, chromoxide green 1 part composition.
Embodiment 3 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting unsaturated polyester resin 100 parts in advance, 1500 object lignocelluloses 4.5 parts, 1250 object Vltra tearss 1.5 parts, 1000 object aluminum stearates 4 parts, 1500 object barium stearates 2 parts, 3000 object lithium stearates 3 parts, 2000 order nickel stearates 5 parts, p-t-butylphenyl salicylate 0.3 part, ESCALOL 567 0.4 part, 3000 object silicon-dioxide 20 parts, 3500 object water-ground limestones 20 parts, 4,000 140 parts, object aluminium hydroxides, 2000 order dry powder 20 parts compositions.
Embodiment 4 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting unsaturated polyester resin 100 parts in advance, 1250 object lignocelluloses 4 parts, 1000 object Walocel MT 20.000PVs 3 parts, 1500 object Natvosols 2 parts, 3000 object barium stearates 5 parts, 1000 object lithium stearates 7 parts, p-t-butylphenyl salicylate 0.2 part, HMPA 0.4 part, 2500 object silica 1s 5 parts, 5000 object water-ground limestones 10 parts, 1500 10 parts, object aluminium hydroxides, 3000 order talcum powder 5 parts, 2500 order dry powders 40 parts, everbright fast red 0.01 part, medium chrome yellow medium yellow 0.5 part composition.
Embodiment 5 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting unsaturated polyester resin 100 parts in advance, 1000 object lignocelluloses 1.5 parts, 1250 object Natvosols 1 part, 1500 object Vltra tearss 2.5 parts, 2000 object nickel stearates 4 parts, 3000 object lithium stearates 5 parts, p-t-butylphenyl salicylate 0.1 part, ESCALOL 567 0.2 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.5 part, 2500 object silicon-dioxide 80 parts, 2000 object water-ground limestones 15 parts, 3000 15 parts, object aluminium hydroxides, 2000 order talcum powder 2 parts, 1500 order dry powders 20 parts, Lithol Red 0.1 part composition.
Embodiment 6 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting unsaturated polyester resin 100 parts in advance, 1500 object lignocelluloses 2 parts, 1000 order Walocel MT 20.000PVs 3 parts, 1000 object Vltra tearss 3 parts, 2000 object aluminum stearates 3 parts, 1000 object nickel stearates 2 parts, ESCALOL 567 0.45 part, HMPA 0.05 part, 3000 object silicon-dioxide 5 parts, 4500 object water-ground limestones 15 parts, 5000 10 parts, object aluminium hydroxides, 5000 order dry powders 15 parts, titanium dioxide 7 parts composition.
Embodiment 7 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting unsaturated polyester resin 100 parts in advance, 1500 object lignocelluloses 4 parts, 1500 order Walocel MT 20.000PVs 1 part, 1000 order Natvosols 1 part, 1250 object Vltra tearss 3 parts, 1500 object aluminum stearates 3 parts, 3000 object barium stearates 2 parts, 1000 object nickel stearates 1 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.3 part, HMPA 0.7 part, 4000 object silicon-dioxide 20 parts, 2500 object water-ground limestones 30 parts, 3000 40 parts, object aluminium hydroxides, 1000 order talcum powder 5 parts, 2000 order dry powders 20 parts, red iron oxide 0.8 part composition.
Embodiment 8 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting unsaturated polyester resin 100 parts in advance, 1000 object lignocelluloses 4 parts, 1500 object Natvosols 2 parts, 2000 object aluminum stearates 3 parts, 3000 object lithium stearates 1 part, 3000 object nickel stearates 3 parts, p-t-butylphenyl salicylate 0.1 part, ESCALOL 567 0.8 part, HMPA 0.1 part, 2500 object silicon-dioxide 20 parts, 2000 object water-ground limestones 140 parts, 3,000 20 parts, object aluminium hydroxides, 1500 order dry powders 20 parts, chromoxide green 2 parts composition.
Embodiment 9 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting unsaturated polyester resin 100 parts in advance, 1000 object lignocelluloses 3 parts, 1500 order Walocel MT 20.000PVs 3 parts, 1000 order Natvosols 1 part, 1500 object aluminum stearates 4 parts, 2500 object barium stearates 3 parts, 3000 object lithium stearates 3 parts, p-t-butylphenyl salicylate 0.4 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.3 part, HMPA 0.1 part, 5000 object silicon-dioxide 60 parts, 1500 object water-ground limestones 15 parts, 1000 20 parts, object aluminium hydroxides, 1250 order talcum powder 10 parts, 2000 order dry powders 20 parts, carbon black 1 part composition.
Embodiment 10 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting unsaturated polyester resin 100 parts in advance, 1500 object lignocelluloses 4 parts, 1250 object Walocel MT 20.000PVs 4 parts, 2500 object nickel stearates 5 parts, 1250 object barium stearates 4 parts, 3000 order lithium stearates 6 parts, ESCALOL 567 0.1 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.4 part, HMPA 0.1 part, 1500 object silica 1s 5 parts, 1000 object water-ground limestones 15 parts, 2500 50 parts, object aluminium hydroxides, 1250 order dry powders 10 parts, iron oxide yellow 3 parts composition.
Embodiment 11 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting unsaturated polyester resin 100 parts in advance, 1000 object lignocelluloses 4 parts, 1500 order Walocel MT 20.000PVs 3 parts, 1000 order Vltra tearss 3 parts, 2000 object barium stearates 3 parts, 2000 object nickel stearates 4 parts, p-t-butylphenyl salicylate 0.4 part, ESCALOL 567 0.1 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.3 part, HMPA 0.1 part, 2000 object silicon-dioxide 2 parts, 3500 object water-ground limestones 8 parts, 4000 3 parts, object aluminium hydroxides, 1250 order talcum powder 2 parts, 2000 order dry powders 5 parts, chromoxide green 0.5 part, fluorescent yellow 2.5 parts, phthalocyanine green 1 part composition.
Embodiment 12 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting unsaturated polyester resin 100 parts in advance, 1000 object lignocelluloses 5 parts, 1250 object Walocel MT 20.000PVs 3.5 parts, 1000 object aluminum stearates 3 parts, 1500 object barium stearates 3 parts, 3000 object lithium stearates 3 parts, 2000 order nickel stearates 5 parts, p-t-butylphenyl salicylate 0.2 part, ESCALOL 567 0.3 part, 5000 object silica 1s 40 parts, 2500 object water-ground limestones 20 parts, 1500 20 parts, object aluminium hydroxides, 1500 order dry powders 20 parts, red iron oxide 1 part, everbright fast red 2 parts composition.
Embodiment 13 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting unsaturated polyester resin 100 parts in advance, 1000 object lignocelluloses 2.5 parts, 1500 object Vltra tearss 4 parts, 1250 object nickel stearates 7 parts, 3000 object lithium stearates 6 parts, p-t-butylphenyl salicylate 0.25 part, ESCALOL 567 0.1 part, HMPA 0.5 part, 4000 object silicon-dioxide 20 parts, 1500 object water-ground limestones 20 parts, 3000 20 parts, object aluminium hydroxides, 4000 order dry powders 140 parts, phthalocyanine blue 0.5 part, 0.5 part, ultramarine, titanium dioxide 6 parts composition.
Embodiment 14 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting unsaturated polyester resin 100 parts in advance, 1250 object lignocelluloses 2.5 parts, 1000 object Natvosols 1 part, 1500 object Vltra tearss 4 parts, 3000 object barium stearates 2 parts, 1500 object nickel stearates 5 parts, 1500 object lithium stearates 2 parts, p-t-butylphenyl salicylate 0.15 part, ESCALOL 567 0.2 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.4 part, 5000 object silicon-dioxide 5 parts, 2500 object water-ground limestones 15 parts, 5000 5 parts, object aluminium hydroxides, 3000 order talcum powder 2 parts, 1500 order dry powder 7 parts compositions.
Embodiment 15 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting unsaturated polyester resin 100 parts in advance, 1000 object lignocelluloses 2 parts, 1500 order Walocel MT 20.000PVs 3.5 parts, 1000 order Natvosols 2 parts, 2000 object aluminum stearates 1 part, 1500 object barium stearates 7 parts, 1000 object nickel stearates 1 part, 1500 object lithium stearates 1 part, ESCALOL 567 0.2 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.15 part, HMPA 0.2 part, 1500 object silicon-dioxide 40 parts, 4000 object water-ground limestones 8 parts, 3000 10 parts, object aluminium hydroxides, 1000 order dry powders 10 parts, iron oxide yellow 0.6 part, red iron oxide 2 parts, medium chrome yellow medium yellow 1 part composition.
Embodiment 16 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting unsaturated polyester resin 100 parts in advance, 1000 object lignocelluloses 4.5 parts, 1250 object Natvosols 2.5 parts, 1500 object aluminum stearates 2 parts, 2000 object lithium stearates 2 parts, 1500 object nickel stearates 4 parts, p-t-butylphenyl salicylate 0.35 part, ESCALOL 567 0.1 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.2 part, HMPA 0.1 part, 1500 object silicon-dioxide 20 parts, 5000 object water-ground limestones 120 parts, 5000 20 parts, object aluminium hydroxides, 3000 order talcum powder 20 parts, 1500 order dry powders 20 parts, chromoxide green 1 part, 0.1 part, ultramarine composition.
Embodiment 17 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting unsaturated polyester resin 100 parts in advance, 1500 object lignocelluloses 3.5 parts, 1000 object Walocel MT 20.000PVs 1 part, 1500 object Natvosols 1 part, 1500 object aluminum stearates 3 parts, 2500 object barium stearates 4 parts, 3000 object lithium stearates 6 parts, p-t-butylphenyl salicylate 0.1 part, ESCALOL 567 0.2 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.5 part, 5000 object silicon-dioxide 35 parts, 4000 object water-ground limestones 15 parts, 1250 60 parts, object aluminium hydroxides, 2000 order dry powders 40 parts, Lithol Red 0.05 part, fluorescent yellow 0.5 part composition.
Embodiment 18 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting unsaturated polyester resin 100 parts in advance, 1250 object lignocelluloses 5 parts, 1250 object Walocel MT 20.000PVs 4 parts, 1000 object aluminum stearates 4 parts, 2000 object nickel stearates 2.5 parts, ESCALOL 567 0.4 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.3 part, 1500 object silica 1s 4 parts, 3500 object water-ground limestones 2 parts, 5000 2 parts, object aluminium hydroxides, 2500 order dry powders 2 parts, phthalocyanine blue 1 part, fluorescent yellow 5 parts composition.
Embodiment 19 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting unsaturated polyester resin 100 parts in advance, 1000 object lignocelluloses 2 parts, 1500 order Walocel MT 20.000PVs 4 parts, 1000 object Vltra tearss 2 parts, 2500 object nickel stearates 4 parts, 1500 object barium stearates 4 parts, 2500 order lithium stearates 3 parts, p-t-butylphenyl salicylate 0.2 part, HMPA 0.4 part, 2000 object silicon-dioxide 50 parts, 4000 object water-ground limestones 100 parts, 1,500 20 parts, object aluminium hydroxides, 1500 order talcum powder 5 parts, 3000 order dry powder 25 parts compositions.
Embodiment 20 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting unsaturated polyester resin 100 parts in advance, 1500 object lignocelluloses 2 parts, 1250 order Walocel MT 20.000PVs 1 part, 1250 order Natvosols 1 part, 1000 object Vltra tearss 1 part, 1000 object aluminum stearates 4 parts, 3000 object lithium stearates 2 parts, p-t-butylphenyl salicylate 0.4 part, ESCALOL 567 0.4 part, 2000 object silicon-dioxide 20 parts, 1000 object water-ground limestones 20 parts, 3000 15 parts, object aluminium hydroxides, 2000 order dry powders 85 parts, fluorescent yellow 0.8 part, titanium dioxide 4 parts composition.
Embodiment 21 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting unsaturated polyester resin 100 parts in advance, 1500 object lignocelluloses 2 parts, 1250 order Walocel MT 20.000PVs 2 parts, 1000 order Vltra tearss 1 part, 1500 object aluminum stearates 5 parts, 3000 object barium stearates 7 parts, p-t-butylphenyl salicylate 0.1 part, ESCALOL 567 0.1 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.7 part, HMPA 0.1 part, 1000 object silica 1s 3 parts, 2500 object water-ground limestones 10 parts, 1000 60 parts, object aluminium hydroxides, 1250 order talcum powder 7 parts, 5000 order dry powders 10 parts, carbon black 0.01 part, red iron oxide 4 parts, medium chrome yellow medium yellow 1 part composition.
Embodiment 22 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting unsaturated polyester resin 100 parts in advance, 1000 object lignocelluloses 5.5 parts, 1500 object Natvosols 4.5 parts, 2000 object aluminum stearates 2 parts, 2500 object nickel stearates 3 parts, p-t-butylphenyl salicylate 0.3 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.4 part, HMPA 0.2 part, 4000 object silicon-dioxide 40 parts, 4000 object water-ground limestones 30 parts, 3000 40 parts, object aluminium hydroxides, 2500 order talcum powder 15 parts, 2000 order dry powders 40 parts, 0.05 part, ultramarine, iron oxide yellow 0.1 part composition.
Choose raw material by the proportioning of the stone material seamless binding glue in above-described embodiment, under the negative pressure state of 0.08-0.1MPa, to be not less than the rotating speed high-speed stirring of 1500r/min, obtain stone material seamless binding glue of the present invention.
Left standstill under 25 DEG C of conditions by gained stone material seamless binding glue in above-described embodiment, observation colloid phase-splitting situation, record leaves standstill the phase-splitting time.
Get gained stone material seamless binding glue in 100 weight part above-described embodiments, be blended into 3 weight part solidifying agent and mix and stir, according to JC/T989-2006 method, Mechanics Performance Testing is carried out to stone material seamless binding adhesive curing thing.
According to GB/T14522-2008 method, ultraviolet ageing test is carried out to above-mentioned stone material seamless binding adhesive curing thing, the results are shown in following table:
The present invention is not limited to above-mentioned embodiment, and for those skilled in the art, under the premise without departing from the principles of the invention, can also make some improvements and modifications, these improvements and modifications are also considered as within protection scope of the present invention.The content be not described in detail in this specification sheets belongs to the known prior art of professional and technical personnel in the field.
Claims (11)
1. stone material seamless binding glue, is characterized in that: count by weight, comprises pre-promotion unsaturated polyester resin 100 parts, toughener 3-10 part, antisettling agent 5-15 part, UV light absorber 0.5-1 part, filler 20-200 part, pigment 0-7 part.
2. stone material seamless binding glue according to claim 1, is characterized in that: described toughener is made up of the lignocellulose of 25 ~ 75% and the modification lignocellulose of 25 ~ 75% by weight percentage.
3. stone material seamless binding glue according to claim 2, is characterized in that: described modification lignocellulose is the one in Walocel MT 20.000PV, Natvosol, Vltra tears; Or described modification lignocellulose by Walocel MT 20.000PV, Natvosol, Vltra tears any two kinds form, often kind is 20 ~ 80% by the weight percent of modification lignocellulose gross weight; Or described modification lignocellulose is made up of Walocel MT 20.000PV, Natvosol, Vltra tears three kinds, often kind is 20 ~ 60% by the weight percent of modification lignocellulose gross weight.
4. stone material seamless binding glue according to claim 2, is characterized in that: described lignocellulose and the wooden cellulosic order number of modification are 1000-1500 order.
5. stone material seamless binding glue according to claim 1, is characterized in that: described antisettling agent by aluminum stearate, barium stearate, nickel stearate, lithium stearate any two kinds form, often kind of weight percent by antisettling agent gross weight is 10 ~ 90%; Or described antisettling agent by aluminum stearate, barium stearate, nickel stearate, lithium stearate any three kinds form, often kind of weight percent by antisettling agent gross weight is 10 ~ 80%; Or described antisettling agent is made up of aluminum stearate, barium stearate, nickel stearate, lithium stearate four kinds, often kind of weight percent by antisettling agent gross weight is 10 ~ 70%.
6. stone material seamless binding glue according to claim 5, is characterized in that: the order number of described antisettling agent is 1000-3000 order.
7. stone material seamless binding glue according to claim 1, it is characterized in that: described UV light absorber by p-t-butylphenyl salicylate, ESCALOL 567,2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole, HMPA any two kinds form, often kind of weight percent by antisettling agent gross weight is 10 ~ 90%; Or described UV light absorber by p-t-butylphenyl salicylate, ESCALOL 567,2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole, HMPA any three kinds form, often kind of weight percent by antisettling agent gross weight is 10 ~ 80%; Or described UV light absorber is made up of p-t-butylphenyl salicylate, ESCALOL 567,2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole, HMPA four kinds, often kind of weight percent by antisettling agent gross weight is 10 ~ 70%.
8. stone material seamless binding glue according to claim 1, it is characterized in that: described filler, by the weight percent meter of filler gross weight, comprises silica 1 0%-70%, water-ground limestone 10%-70%, aluminium hydroxide 10%-70%, talcum powder 0%-10%, dry powder 10%-70%.
9. stone material seamless binding glue according to claim 8, it is characterized in that: described silicon-dioxide order number is 1000-5000 order, water-ground limestone order number is 1000-5000 order, aluminium hydroxide order number is 1000-5000 order, talcous order number is 1000-3000 order, the order number of dry powder is 1000-5000 order, described filler whiteness >=90 °.
10. stone material seamless binding glue according to claim 1, is characterized in that: described pigment is one or more in titanium dioxide, carbon black, medium chrome yellow medium yellow, iron oxide yellow, red iron oxide, chromoxide green, ultramarine, phthalocyanine blue, phthalocyanine green, fluorescent yellow, everbright fast red, Lithol Red.
11. methods preparing stone material seamless binding glue described in arbitrary claim in claim 1-10, is characterized in that: comprise the following steps:
1) component is taken by above-mentioned raw materials parts by weight, for subsequent use;
2) by above-mentioned component vacuum tightness be 0.08-0.1Mpa, rotating speed be the negative pressure state being not less than 1500r/min under high-speed stirring even, churning time is 30-45 minute, namely obtains stone material seamless binding glue.
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| CN105441004A (en) * | 2015-12-01 | 2016-03-30 | 武汉市科达云石护理材料有限公司 | Flame-retardant vinyl type anchor adhesive |
| CN106833423A (en) * | 2017-03-22 | 2017-06-13 | 东莞市纳利光学材料有限公司 | One kind plus viscous anti-blue light composite membrane |
| CN109825233A (en) * | 2019-01-22 | 2019-05-31 | 管小梅 | A kind of preparation method of high-adhesion high intensity cloud stone glue |
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| CN104418558A (en) * | 2013-09-09 | 2015-03-18 | 北京唯众科技发展有限公司 | Preparation technology of environment-friendly thermal insulation composite building material |
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| CN1884372A (en) * | 2006-06-30 | 2006-12-27 | 王厚东 | Flame-proof antistatic resin anchoring agent |
| WO2009013064A2 (en) * | 2007-07-24 | 2009-01-29 | Evonik Degussa Gmbh | Coating material compositions |
| CN101921570A (en) * | 2009-06-12 | 2010-12-22 | 广东龙马化学有限公司 | Ceramic tile gap-filling adhesive |
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| CN109825233A (en) * | 2019-01-22 | 2019-05-31 | 管小梅 | A kind of preparation method of high-adhesion high intensity cloud stone glue |
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| CN104910847B (en) | 2017-08-08 |
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