CN104910678A - Ultraviolet light-cured offset printing ink with LED as light source - Google Patents
Ultraviolet light-cured offset printing ink with LED as light source Download PDFInfo
- Publication number
- CN104910678A CN104910678A CN201510274131.3A CN201510274131A CN104910678A CN 104910678 A CN104910678 A CN 104910678A CN 201510274131 A CN201510274131 A CN 201510274131A CN 104910678 A CN104910678 A CN 104910678A
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- Prior art keywords
- light source
- printing ink
- offset printing
- led
- acrylate
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses an ultraviolet light-cured offset printing ink with LED as a light source. The ultraviolet light-cured offset printing ink comprises, by weight, 20 to 30 parts of pigment, 55 to 75 parts of radiation-cured resin, 1 to 7 parts of a photoinitiator, 0 to 3 parts of wax, 0.1 to 5 parts of an active diluent and 0.5 to 4 parts of an auxiliary agent. The UV-LED light-cured printing ink has the following characteristics: the printing ink is applicable to offset printing; electric energy consumed in curing is about 1/4 of electric energy consumed by a common ultraviolet lamp; emission of CO2 is substantially reduced; ozone is not generated; etc. The printing ink is completely dried under the printing condition of a curing speed of 40 to 200 m/min and enables printed lines to be clear; and after curing, each performance index (adhesion, friction resistance, chemical resistance and the like) of the printing ink accords with requirements on printing of securities.
Description
Technical field
The present invention relates to optic-solidified adhesive printing ink.
Background technology
LED is the UV-curing of light source is a kind of low-yield curing light source, usually has pointolite, line source and area source.It is made up of several near-ultraviolet ray chips, is different from illumination White-light LED chip, and it can launch the ultraviolet of 375nm, 385nm, 390nm or 395nm, is cured UV ink.It has the following advantages: LED, compared with ultraviolet light curing, only needs the power consumption of about 1/4, can save energy consumption cost, greatly reduce CO
2quantity discharged.Because LED heating is few, for the printing of the printable fabric of the poor heat resistance such as plastic film and the heat affecting of printing press little, paper loss and machine ages weaken thereupon.LED light source element life-span compared with UV-lamp is about its 12 times, and replacing light source frequency significantly reduces, and consumptive material also reduces thereupon.LED can accomplish to open instantaneously or close, and without the need to the necessary preheating of UV lamp mode and temperature fall time, operating efficiency is improved.Due to UV irradiation equipment and relevant corollary apparatus closely, without the need to that larger mechanical erection space and piping installation in the past, arrange simple easily.No matter economically or environmental angle consider, UV-LED photocuring system all will replace traditional UV high voltage mercury lamp cure system.
At present; ultraviolet cured offset printing ink generally adopts UV high voltage mercury lamp to be cured; have that energy consumption is high, thermal value is large, work-ing life is short, be unfavorable for the defects such as environment protection; and common UV flexographic ink dry difficulty under UV-LED light source, so need one newly developed can under UV-LED light source quick-drying flexographic ink.
Summary of the invention
The object of this invention is to provide a kind of take LED as the ultraviolet cured offset printing ink of light source, to overcome the defect that prior art exists.
The ultraviolet cured offset printing ink of described with LED is light source, parts by weight are:
Preferably, the ultraviolet cured offset printing ink of described with LED is light source, parts by weight are:
Described pigment is the general pigment of ink area;
Described radiation curing resin is one or more the combination such as sulfhydryl modified polyester acrylate and urethane acrylate, polyester acrylate, polyether acrylate, epoxy acrylate.The LED01 of preferred sulfhydryl modified polyester acrylate You Zhan new company, urethane acrylate has UA9033, UA9030 of BASF AG, EB8254, EB8415, EB8602 of profound new company, polyester acrylate has the LR9004 of BASF, profound new EB830 etc.
Preferably, described radiation curing resin is the mixture of sulfhydryl modified polyester acrylate, urethane acrylate, polyester acrylate, amine modified polyether acrylate and sour modified methyl acrylic, with the total weight of described radiation curing resin, the weight percent of each resin is:
The per-cent sum of each component is 100%;
Described amine modified polyether acrylate can adopt BASF AG's trade mark to be the product of PO94F;
Described sour modified methyl acrylic can adopt the profound new company trade mark to be the product of EB 168;
Described light trigger is the one such as 2,2-dimethoxy-1,2-diphenylethan, benzophenone, alpha-alcohol ketone, 1-hydroxy-cyciohexyl ketone, alpha-amino group ketone, acylphosphanes, phenylglyoxylic acid ester or its combination.The ultraviolet light wavelength that UV-LED light source is launched is single, and the initiator of Selective absorber wavelength within the scope of 375nm-395nm is comparatively suitable.The absorption peak of the diacyl phosphine Irg819 of BASF AG is 370nm, 405nm, shares separately or with other kind initiators, has high Ultraviolet Light, particularly suitable UV-LED light source irradiation.Alpha-amino group ketone absorption peak can to 440nm, and alpha-alcohol ketone absorption peak can to 420nm, one or more mixed can UV curing-LED ink effectively;
Preferably, described initiator is the mixture of alpha-alcohol ketone and monoacyl phosphine or diacyl phosphine, and weight ratio is:
Alpha-alcohol ketone: monoacyl phosphine or diacyl phosphine 1: 2 ~ 1:2.5;
Described wax is polyethylene wax, expense one holder wax, Poly Propylene Wax, tetrafluoroethylene wax, modification micro mist wax etc.PINNACLE 1555, LANCO 1588, the LANCO PEW 1555 etc. of preferred La You Lubrizol Corp..
Described reactive thinner is the one such as ethoxy acrylate, phenoxyethyl acrylate, bisphenol a diacrylate, hexanediyl ester, polyester acrylate, Viscoat 295, polyether acrylate or its combination.Above reactive thinner reactive behavior is strong, can produce high crosslink density solidified oil layer of ink, and appropriate interpolation can reduce the viscosity of system, can accelerate again the curing speed of UV-LED optic-solidified adhesive printing ink.The preferred Viscoat 295 of You Zhan new company, the tripropylene glycol diacrylate etc. of BASF AG.
Described auxiliary agent is adhesion promoter or stopper, and described adhesion promoter is sour modified methyl acrylic compound, as the EB168 of profound new company;
Described stopper is selected from para benzoquinone, as the Irgastab UV 22 of BASF AG;
Described LED light source is pointolite, line source or area source;
The emission band of described LED light curing light source is one or more in 375nm, 385nm, 390nm or 395nm, and the power of light source is greater than 10W/cm
2;
Preparation method of the present invention, comprises the steps:
Be blended in batching kettle by above-mentioned formula, after 1000rpm/min stirs 30 minutes, strangle three-roller fully mill and treat that ink fineness is less than 5um through cloth, can obtain described take LED as the ultraviolet cured offset printing ink of light source;
The UV-LED optic-solidified adhesive printing ink that the present invention obtains in the initiator combination of high band by selecting polyfunctionality acrylic polymer, absorption peak, coupling low power 375nm, 385nm, 390nm and 395nm light source, be completely dry under the printing condition of 40-200m/min at curing speed, and svelteness, curing performance is excellent, is applicable to the high speed printing of 40-200m/min.
UV-LED light-curable ink of the present invention has following characteristics: this ink is applicable to offset printing, and the electric energy consumed during solidification only needs common uv lamp about 1/4, greatly reduces CO
2quantity discharged; Do not produce the advantages such as ozone.This ink is completely dry under curing speed is the printing condition of 40-200m/min, and svelteness.After solidification, property indices (sticking power, antifriction, chemical resistant properties etc.) meets the printing demand of Valued Securities.
Embodiment
Embodiment 1
Formula sees the following form, and amounts of components is weight part.
Sulfhydryl modified polyester acrylate is LED01.
Urethane acrylate is EB8602.
Polyester acrylate is EB830.
Amine modified polyether acrylate is PO94F.
Acid modified methyl acrylic is EB168.
α-amido ketone is Irgacure 379.
Monoacyl phosphine is Darocur TPO.
Polyethylene wax is PEW1555.
Para benzoquinone is UV22.
Preparation method: be blended in batching kettle by above-mentioned formula, after 1000rpm/min stirs 30 minutes, strangles three-roller through cloth and fully mills and treat that ink fineness is less than 5um, can obtain offset printing UV-LED ink.
The UV-LED optic-solidified adhesive printing ink prepared, viscosity is 23.5Pas, and thixotroping circle area is 4.5E+05, (30 DEG C, HAAKE RV1 rheometer, 1 degree of cone-plate, shearing rate is 300s-1), under the print speed of 200m/min, ink machine stability is good, printing complete drying, the lines flow smoothly, and figure line is clear.Printing acid-fast alkali-proof heat-proof water, resistance to zellon, ethyl acetate, clorox equal solvent, resistance to fold 16 traces come off lower than 10% (the IGT-NBS tester of resistance to fold).
Application method is as follows:
UV-LED light source power is 12W/cm
2, optical source wavelength is 395nm, is dry complete, svelteness under the printing condition of 180m/min at curing speed.
Embodiment 2
Sulfhydryl modified polyester acrylate is LED01.
Urethane acrylate is EB284.
Polyester acrylate is EB546.
Viscoat 295 is TMPTA.
Amine modified polyether acrylate is PO94F.
Acid modified methyl acrylic is EB168.
Alpha-alcohol ketone is Darocur 1173.
Diacyl phosphine is Irgacure 819.
Poly Propylene Wax is LANCO 1588.
Para benzoquinone is UV22.
Preparation method: be blended in batching kettle by above-mentioned formula, after 1000rpm/min stirs 30 minutes, strangles three-roller through cloth and fully mills and treat that ink fineness is less than 5um, can obtain offset printing UV-LED ink.
The UV-LED optic-solidified adhesive printing ink prepared, viscosity is 24.2Pas, and thixotroping circle area is 6.2E+05, (30 DEG C, HAAKE RV1 rheometer, 1 degree of cone-plate, shearing rate is 300s-1), under the print speed of 200m/min, ink machine stability is good, printing complete drying, the lines flow smoothly, and figure line is clear.Printing acid-fast alkali-proof heat-proof water, resistance to zellon, ethyl acetate, clorox equal solvent, resistance to fold 16 traces come off lower than 10% (the IGT-NBS tester of resistance to fold).
Application method is as follows:
UV-LED light source power is 12W/cm
2, optical source wavelength is 395nm, is dry complete, svelteness under the printing condition of 180m/min at curing speed.
Claims (10)
1. be the ultraviolet cured offset printing ink of light source with LED, it is characterized in that, parts by weight are:
2. according to claim 1 take LED as the ultraviolet cured offset printing ink of light source, and parts by weight are:
3. according to claim 1 and 2 take LED as the ultraviolet cured offset printing ink of light source, it is characterized in that, described radiation curing resin is one or more the combination in sulfhydryl modified polyester acrylate and urethane acrylate, polyester acrylate, polyether acrylate, epoxy acrylate.
4. according to claim 3 take LED as the ultraviolet cured offset printing ink of light source, and described radiation curing resin is the mixture of sulfhydryl modified polyester acrylate, urethane acrylate, polyester acrylate, amine modified polyether acrylate and sour modified methyl acrylic.
5. according to claim 4 take LED as the ultraviolet cured offset printing ink of light source, and with the total weight of described radiation curing resin, the weight percent of each resin is:
The per-cent sum of each component is 100%.
6. according to claim 1 and 2 take LED as the ultraviolet cured offset printing ink of light source; it is characterized in that; described light trigger is 2; one in 2-dimethoxy-1,2-diphenylethan, benzophenone, alpha-alcohol ketone, 1-hydroxy-cyciohexyl ketone, alpha-amino group ketone, acylphosphanes, phenylglyoxylic acid ester or its combination.
7. according to claim 6 take LED as the ultraviolet cured offset printing ink of light source; it is characterized in that; described initiator is the mixture of alpha-alcohol ketone and monoacyl phosphine or diacyl phosphine, and weight ratio is: alpha-alcohol ketone: monoacyl phosphine or diacyl phosphine 1: 2 ~ 1:2.5.
8. according to claim 1 and 2 take LED as the ultraviolet cured offset printing ink of light source, it is characterized in that, described wax is polyethylene wax, expense one holder wax, Poly Propylene Wax, tetrafluoroethylene wax or modification micro mist wax, described auxiliary agent is adhesion promoter or stopper, described adhesion promoter is sour modified methyl acrylic, and described stopper is selected from para benzoquinone.
9. according to claim 1 and 2 take LED as the ultraviolet cured offset printing ink of light source, it is characterized in that, described reactive thinner is one in ethoxy acrylate, phenoxyethyl acrylate, bisphenol a diacrylate, hexanediyl ester, polyester acrylate, Viscoat 295, polyether acrylate or its combination.
10. according to claim 1 and 2 take LED as the ultraviolet cured offset printing ink of light source, and it is characterized in that, described LED light source is pointolite, line source or area source; The emission band of described LED light curing light source is one or more in 375nm, 385nm, 390nm or 395nm, and the power of light source is greater than 10W/cm
2.
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|---|---|---|---|
| CN201510274131.3A CN104910678B (en) | 2015-05-26 | 2015-05-26 | Ultraviolet cured offset printing ink with LED as light source |
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| CN201510274131.3A CN104910678B (en) | 2015-05-26 | 2015-05-26 | Ultraviolet cured offset printing ink with LED as light source |
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| CN104910678A true CN104910678A (en) | 2015-09-16 |
| CN104910678B CN104910678B (en) | 2017-06-27 |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105566916A (en) * | 2016-02-23 | 2016-05-11 | 上海应用技术学院 | Rapidly-curable luminous 3D printing photosensitive adhesive and preparation method thereof |
| CN105566915A (en) * | 2016-02-23 | 2016-05-11 | 上海应用技术学院 | Improved luminous 3D printing photosensitive adhesive and preparation method thereof |
| CN105602345A (en) * | 2016-04-05 | 2016-05-25 | 湖北科亿华科技有限公司 | LED-UV photocuring black ink-jet ink and preparation method thereof |
| CN105602255A (en) * | 2016-01-13 | 2016-05-25 | 上海应用技术学院 | Luminous 3D (three-dimensional) printing photosensitive adhesive and method for preparing same |
| CN105885524A (en) * | 2016-06-20 | 2016-08-24 | 上海飞凯光电材料股份有限公司 | UV (ultraviolet)-LED curing ink and preparation method and application thereof |
| CN106752317A (en) * | 2017-02-07 | 2017-05-31 | 张耀忠 | A kind of LED UV cured printing inks |
| CN107090207A (en) * | 2017-06-07 | 2017-08-25 | 深圳美联兴科技股份有限公司 | A kind of stamping resistance LED UV tin graphed sheet offset inks |
| CN109135413A (en) * | 2018-07-06 | 2019-01-04 | 深圳市海中辉新材料科技有限公司 | A kind of mute sand oil ink of LED-UV offset printing and preparation method thereof |
| CN109504164A (en) * | 2018-12-18 | 2019-03-22 | 深圳市深赛尔股份有限公司 | A kind of LED light curing metal decorating ink and preparation method thereof |
| JP2019056089A (en) * | 2017-09-22 | 2019-04-11 | Ｄｉｃグラフィックス株式会社 | Active energy ray-curable coating varnish and printed matter |
| CN109897225A (en) * | 2019-01-29 | 2019-06-18 | 东莞职业技术学院 | A kind of pigment derivative, colour UV Photocurable composition and preparation method thereof |
| CN109913029A (en) * | 2018-09-30 | 2019-06-21 | 中山市中益油墨涂料有限公司 | A kind of tetra- color ink of LED of intaglio printing and preparation method thereof |
| KR20200065524A (en) * | 2018-11-30 | 2020-06-09 | 한국다이요잉크 주식회사 | Ink composition for uv led curing |
| CN112980239A (en) * | 2021-03-25 | 2021-06-18 | 中钞油墨有限公司 | LED-UV (light-emitting diode-ultraviolet) curing embossing printing ink |
| CN113943521A (en) * | 2020-07-17 | 2022-01-18 | 广东华润涂料有限公司 | Anti-yellowing UV-LED curable coating composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102863848A (en) * | 2012-09-03 | 2013-01-09 | 杭华油墨化学有限公司 | Ultraviolet-light-emitting diode (UV-LED) low-energy cured printing ink |
| CN103540188A (en) * | 2012-07-10 | 2014-01-29 | 上海麟多祈化工科技有限公司 | Aqueous long-wave-ultraviolet-drying package printing ink |
-
2015
- 2015-05-26 CN CN201510274131.3A patent/CN104910678B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103540188A (en) * | 2012-07-10 | 2014-01-29 | 上海麟多祈化工科技有限公司 | Aqueous long-wave-ultraviolet-drying package printing ink |
| CN102863848A (en) * | 2012-09-03 | 2013-01-09 | 杭华油墨化学有限公司 | Ultraviolet-light-emitting diode (UV-LED) low-energy cured printing ink |
Cited By (20)
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| CN105602255A (en) * | 2016-01-13 | 2016-05-25 | 上海应用技术学院 | Luminous 3D (three-dimensional) printing photosensitive adhesive and method for preparing same |
| CN105602255B (en) * | 2016-01-13 | 2018-03-20 | 上海应用技术学院 | Noctilucence 3D printing light-sensitive emulsion and preparation method thereof |
| CN105566915A (en) * | 2016-02-23 | 2016-05-11 | 上海应用技术学院 | Improved luminous 3D printing photosensitive adhesive and preparation method thereof |
| CN105566915B (en) * | 2016-02-23 | 2018-04-06 | 上海应用技术学院 | Improved noctilucence 3D printing light-sensitive emulsion and preparation method thereof |
| CN105566916B (en) * | 2016-02-23 | 2018-04-06 | 上海应用技术学院 | A kind of quick-setting noctilucence 3D printing light-sensitive emulsion and preparation method thereof |
| CN105566916A (en) * | 2016-02-23 | 2016-05-11 | 上海应用技术学院 | Rapidly-curable luminous 3D printing photosensitive adhesive and preparation method thereof |
| CN105602345A (en) * | 2016-04-05 | 2016-05-25 | 湖北科亿华科技有限公司 | LED-UV photocuring black ink-jet ink and preparation method thereof |
| CN105885524A (en) * | 2016-06-20 | 2016-08-24 | 上海飞凯光电材料股份有限公司 | UV (ultraviolet)-LED curing ink and preparation method and application thereof |
| CN106752317A (en) * | 2017-02-07 | 2017-05-31 | 张耀忠 | A kind of LED UV cured printing inks |
| CN107090207A (en) * | 2017-06-07 | 2017-08-25 | 深圳美联兴科技股份有限公司 | A kind of stamping resistance LED UV tin graphed sheet offset inks |
| JP2019056089A (en) * | 2017-09-22 | 2019-04-11 | Ｄｉｃグラフィックス株式会社 | Active energy ray-curable coating varnish and printed matter |
| CN109135413A (en) * | 2018-07-06 | 2019-01-04 | 深圳市海中辉新材料科技有限公司 | A kind of mute sand oil ink of LED-UV offset printing and preparation method thereof |
| CN109913029A (en) * | 2018-09-30 | 2019-06-21 | 中山市中益油墨涂料有限公司 | A kind of tetra- color ink of LED of intaglio printing and preparation method thereof |
| KR20200065524A (en) * | 2018-11-30 | 2020-06-09 | 한국다이요잉크 주식회사 | Ink composition for uv led curing |
| CN109504164A (en) * | 2018-12-18 | 2019-03-22 | 深圳市深赛尔股份有限公司 | A kind of LED light curing metal decorating ink and preparation method thereof |
| CN109504164B (en) * | 2018-12-18 | 2022-01-04 | 深圳市深赛尔股份有限公司 | LED photocuring tin printing ink and preparation method thereof |
| CN109897225A (en) * | 2019-01-29 | 2019-06-18 | 东莞职业技术学院 | A kind of pigment derivative, colour UV Photocurable composition and preparation method thereof |
| CN109897225B (en) * | 2019-01-29 | 2022-04-12 | 东莞职业技术学院 | Pigment derivative, colored UV (ultraviolet) photocuring composition and preparation method thereof |
| CN113943521A (en) * | 2020-07-17 | 2022-01-18 | 广东华润涂料有限公司 | Anti-yellowing UV-LED curable coating composition |
| CN112980239A (en) * | 2021-03-25 | 2021-06-18 | 中钞油墨有限公司 | LED-UV (light-emitting diode-ultraviolet) curing embossing printing ink |
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Address after: 288 Xiuyan Road, Pudong New Area, Shanghai, 201315 Patentee after: CHINA BANKNOTE INK Co.,Ltd. Patentee after: China Banknote Printing and Minting Group Co.,Ltd. Address before: 288 Xiuyan Road, Pudong New Area, Shanghai, 201315 Patentee before: CHINA BANKNOTE INK Co.,Ltd. Patentee before: CHINA BANKNOTE PRINTING AND MINTING Corp. |