CN104910512B - A kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound and preparation method thereof - Google Patents
A kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound and preparation method thereof Download PDFInfo
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- CN104910512B CN104910512B CN201510269603.6A CN201510269603A CN104910512B CN 104910512 B CN104910512 B CN 104910512B CN 201510269603 A CN201510269603 A CN 201510269603A CN 104910512 B CN104910512 B CN 104910512B
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- antioxidant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound and preparation method thereof, it is made up of the raw material of following mass fraction：35 60 parts of polypropylene, 5 10 parts of polyketone resin, 20 30 parts of POE, 10 30 parts of wear resistant filler, 38 parts of toughener, 0.3 1.5 parts of anti-aging auxiliary agent.The preparation method of the PP Pipe Compound, step is：Various raw materials are well mixed, melting extrusion.The PP Pipe Compound of the present invention, with preferable frictional behaviour and hardness, and ageing-resistant performance is preferably, is suitable for as outdoor exercises floor PP Pipe Compound.
Description
Technical field
The present invention relates to a kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound and preparation method thereof.
Background technology
The main base material of present outdoor flooring is all PP, elastomer, filler and other additives is then added, using this
The floor of material shaping is all partially hard, so influences very much feel.And in motion process, often occur that jerk etc. is acted,
Its skidproof effect of harder material is also general, in rainy day or snowy day, moves and easily falls down on this floor.
Therefore, need a kind of anti-slip material for floor surface of exploitation badly, there can be preferable combination with the PP of bottom.
The content of the invention
It is an object of the invention to a kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound and preparation method thereof.
The technical solution used in the present invention is：
A kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound, it is made up of the raw material of following mass fraction：Polypropylene
35-60 parts, 5-10 parts of polyketone resin, 20-30 parts of POE, 10-30 parts of wear resistant filler, 3-8 parts of toughener, anti-aging auxiliary agent
0.3-1.5 parts.
Described wear resistant filler is at least one of calcium sulfate crystal whiskers, talcum powder, ceramic powder.
Described polypropylene is the polyacrylic mixture of two kinds of different melt flow rates.
Described polypropylene is the polypropylene that melt flow rate (MFR) is 1-10g/10min and 20-60g/10min polypropylene
According to mass ratio（0-0.2）：1 mixture.
Described toughener be EVA, CPE, MBS, ACR, SEBS, SBS, EAA, EEA, EPR, EPDM, NBR, TPE in extremely
Few one kind.
Described anti-aging auxiliary agent is antioxidant, the mixture of UV auxiliary agents.
Described anti-aging auxiliary agent is antioxidant, UV auxiliary agents according to mass ratio（1-3）：1 mixture.
Described antioxidant is phosphite ester kind antioxidant, Hinered phenols antioxidant, monothioester kind antioxidant, compound antioxygen
At least one of agent；Described UV auxiliary agents are benzophenone UV auxiliary agents, benzotriazole UV auxiliary agents, benzoic acids UV auxiliary agents
At least one of.
Described antioxidant is Hinered phenols antioxidant and phosphite ester kind antioxidant according to mass ratio 1:(1-3) composition
Mixture.
A kind of preparation method of high flowing soft anti-skidding outdoor floor PP Pipe Compound, step is：Various raw materials are well mixed,
Melting extrusion.
The beneficial effects of the invention are as follows：The PP Pipe Compound of the present invention, with preferable anti-wear performance and hardness, and resistance to ag(e)ing
Preferably it can be suitable for as outdoor exercises floor PP Pipe Compound.
Specifically：
In the formula system of the present invention, by introducing wear resistant filler：I.e. in calcium sulfate crystal whiskers, talcum powder, ceramic powder extremely
Few one kind；And introduce the remarkable polyketone resin of performance so that the composite that formula system of the invention is prepared have compared with
Good performance, which is particularly, possesses outstanding anti-wear performance.
Embodiment
A kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound, it is made up of the raw material of following mass fraction：Polypropylene
35-60 parts, 5-10 parts of polyketone resin, 20-30 parts of POE, 10-30 parts of wear resistant filler, 3-8 parts of toughener, anti-aging auxiliary agent
0.3-1.5 parts.
It is preferred that, described wear resistant filler is at least one of calcium sulfate crystal whiskers, talcum powder, ceramic powder.
It is preferred that, described polypropylene is the polyacrylic mixture of two kinds of different melt flow rates.
It is preferred that, described polypropylene is the polypropylene and 20-60g/10min that melt flow rate (MFR) is 1-10g/10min
Polypropylene according to mass ratio（0-0.2）：1 mixture.
It is preferred that, described toughener is EVA, CPE, MBS, ACR, SEBS, SBS, EAA, EEA, EPR, EPDM, NBR,
At least one of TPE.
It is preferred that, described anti-aging auxiliary agent is antioxidant, the mixture of UV auxiliary agents.
It is further preferred that described anti-aging auxiliary agent be antioxidant, UV auxiliary agents according to mass ratio（1-3）：1 mixing
Thing.
It is preferred that, described antioxidant is phosphite ester kind antioxidant, Hinered phenols antioxidant, monothioester kind antioxidant,
At least one of composite antioxidant.
It is further preferred that described antioxidant is Hinered phenols antioxidant and phosphite ester kind antioxidant according to mass ratio
1:The mixture of (1-3) composition.
It is preferred that, described UV auxiliary agents are benzophenone UV auxiliary agents, benzotriazole UV auxiliary agents, benzoic acids UV auxiliary agents
At least one of.
It is this kind high flowing soft anti-skidding outdoor floor PP Pipe Compound preparation method be：Various raw materials are well mixed, melted
Extrusion.
The formula and performance of the present invention are described further with reference to specific embodiment：
Embodiment 1：
A kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound, it is formulated composition and performance such as following table：
Table 1：
Embodiment 2：
A kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound, it is formulated composition and performance such as following table：
Table 2：
Embodiment 3：
A kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound, it is formulated composition and performance such as following table：
Table 3：
Claims (3)
1. a kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound, it is characterised in that：It is the raw material group by following mass fraction
Into：35-60 parts of polypropylene, 5-10 parts of polyketone resin, 20-30 parts of POE DF8200,10-30 parts of wear resistant filler, Tekron TK-
3-8 parts of 1956A TPE, anti-aging auxiliary agent 0.3-1.5 parts；
Described polypropylene be the polypropylene that melt flow rate (MFR) is 1-10g/10min and 20-60g/10min polypropylene according to
Mass ratio (0-0.2)：1 mixture；
Described wear resistant filler is at least one of calcium sulfate crystal whiskers, talcum powder, ceramic powder；
Described anti-aging auxiliary agent is antioxidant, UV auxiliary agents according to mass ratio (1-3)：1 mixture；Described antioxidant be by
Phenolic antioxidant is hindered with phosphite ester kind antioxidant according to mass ratio 1:The mixture of (1-3) composition.
2. a kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound according to claim 1, it is characterised in that：Described UV
Auxiliary agent is at least one of benzophenone UV auxiliary agents, benzotriazole UV auxiliary agents, benzoic acids UV auxiliary agents.
3. a kind of preparation method of high flowing soft anti-skidding outdoor floor PP Pipe Compound described in claim 1, it is characterised in that：Step
Suddenly it is：Various raw materials are well mixed, melting extrusion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510269603.6A CN104910512B (en) | 2015-05-25 | 2015-05-25 | A kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510269603.6A CN104910512B (en) | 2015-05-25 | 2015-05-25 | A kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104910512A CN104910512A (en) | 2015-09-16 |
| CN104910512B true CN104910512B (en) | 2017-11-03 |
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| CN201510269603.6A Active CN104910512B (en) | 2015-05-25 | 2015-05-25 | A kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound and preparation method thereof |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108343211A (en) * | 2018-03-24 | 2018-07-31 | 河南三公利华体育科技有限公司 | The environmentally friendly soft floors PP of one kind and its production method |
| CN109762245B (en) * | 2018-12-05 | 2021-09-10 | 金发科技股份有限公司 | Long-term thermal-oxidative-aging-resistant polypropylene composition and preparation method thereof |
| CN109627579A (en) * | 2018-12-07 | 2019-04-16 | 广州市聚赛龙工程塑料股份有限公司 | A kind of antipollution high abrasion polypropylene material and preparation method thereof |
| CN109486015B (en) * | 2018-12-07 | 2021-08-13 | 广州市聚赛龙工程塑料股份有限公司 | Fiber-reinforced polypropylene material and preparation method thereof |
| CN113943457A (en) * | 2021-11-12 | 2022-01-18 | 阿姆斯壮地面材料（中国）有限公司 | Preparation process of environment-friendly homogeneous permeable floor |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102020808A (en) * | 2010-12-15 | 2011-04-20 | 广州合成材料研究院有限公司 | Polypropylene sports floor special material for outdoors |
| CN102746639A (en) * | 2011-04-19 | 2012-10-24 | 现代自动车株式会社 | Composition of polyketone with high impact strength |
-
2015
- 2015-05-25 CN CN201510269603.6A patent/CN104910512B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102020808A (en) * | 2010-12-15 | 2011-04-20 | 广州合成材料研究院有限公司 | Polypropylene sports floor special material for outdoors |
| CN102746639A (en) * | 2011-04-19 | 2012-10-24 | 现代自动车株式会社 | Composition of polyketone with high impact strength |
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| CN104910512A (en) | 2015-09-16 |
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