CN104910512A - High flow soft antiskid outdoor floor special material and preparation method thereof - Google Patents
High flow soft antiskid outdoor floor special material and preparation method thereof Download PDFInfo
- Publication number
- CN104910512A CN104910512A CN201510269603.6A CN201510269603A CN104910512A CN 104910512 A CN104910512 A CN 104910512A CN 201510269603 A CN201510269603 A CN 201510269603A CN 104910512 A CN104910512 A CN 104910512A
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- outdoor floor
- auxiliary agent
- pipe compound
- soft anti
- polypropylene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a high flow soft antiskid outdoor floor special material and a preparation method thereof. The high flow soft antiskid outdoor floor special material is composed of the following raw materials by mass: 35-60 parts of polypropylene, 5-10 parts of polyketone resin, 20-30 parts of POE, 10-30 parts of wear-resistant filler, 3-8 parts of a flexibilizer, and 0.3-1.5 parts of an anti-aging aid. The preparation method of the special material includes the steps of: mixing the raw materials evenly and carrying out melt extrusion. The special material provided by the invention has good friction performance and hardness, and has good ageing resistance, thus being suitable to serve as the outdoor floor special material.
Description
Technical field
The present invention relates to a kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound and preparation method thereof.
Background technology
The main base material of present outdoor flooring is all PP, then adds elastomerics, filler and other additives, adopts the floor of this forming materials all partially hard, so very affects feel.And in moving process, often there will be anxious stopping and wait action, its skidproof effect of harder material is also general, in rainy day or snow sky, moves in this floor and very easily falls down.
Therefore, need a kind of anti-slip material for floor surface of exploitation badly, good combination can be had with the PP of bottom.
Summary of the invention
The object of the invention is to a kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound and preparation method thereof.
The technical solution used in the present invention is:
A kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound, it is made up of the raw material of following mass fraction: polypropylene 35-60 part, polyketone resin 5-10 part, POE 20-30 part, wear resistant filler 10-30 part, toughner 3-8 part, anti-aging auxiliary agent 0.3-1.5 part.
Described wear resistant filler is at least one in calcium sulfate crystal whiskers, talcum powder, ceramics powder.
Described polypropylene is the polyacrylic mixture of two kinds of different melt flow rates.
Described polypropylene to be melt flow rate (MFR) the be polypropylene of 1-10g/10min and the polypropylene of 20-60g/10min are according to mass ratio (0-0.2): the mixture of 1.
Described toughner is at least one in EVA, CPE, MBS, ACR, SEBS, SBS, EAA, EEA, EPR, EPDM, NBR, TPE.
Described anti-aging auxiliary agent is the mixture of oxidation inhibitor, UV auxiliary agent.
Described anti-aging auxiliary agent be oxidation inhibitor, UV auxiliary agent according to mass ratio (1-3): the mixture of 1.
Described oxidation inhibitor is at least one in phosphite ester kind antioxidant, Hinered phenols antioxidant, monothioester kind antioxidant, composite antioxidant; Described UV auxiliary agent is at least one in benzophenone UV auxiliary agent, benzotriazole category UV auxiliary agent, benzoic acids UV auxiliary agent.
Described oxidation inhibitor is that Hinered phenols antioxidant and phosphite ester kind antioxidant are according to mass ratio 1:(1-3) mixture that forms.
A preparation method for high flowing soft anti-skidding outdoor floor PP Pipe Compound, step is: mixed by various raw material, melt extrude.
The invention has the beneficial effects as follows: PP Pipe Compound of the present invention, there is good wear resisting property and hardness, and ageing-resistant performance is better, is suitable for as outdoor activity floor PP Pipe Compound.
Concrete:
In formula system of the present invention, by introducing wear resistant filler: at least one namely in calcium sulfate crystal whiskers, talcum powder, ceramics powder; And introduce the polyketone resin of performance brilliance, the matrix material that formula system of the present invention is prepared has good performance and particularly possesses outstanding wear resisting property.
Embodiment
A kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound, it is made up of the raw material of following mass fraction: polypropylene 35-60 part, polyketone resin 5-10 part, POE 20-30 part, wear resistant filler 10-30 part, toughner 3-8 part, anti-aging auxiliary agent 0.3-1.5 part.
Preferably, described wear resistant filler is at least one in calcium sulfate crystal whiskers, talcum powder, ceramics powder.
Preferably, described polypropylene is the polyacrylic mixture of two kinds of different melt flow rates.
Preferably, described polypropylene to be melt flow rate (MFR) the be polypropylene of 1-10g/10min and the polypropylene of 20-60g/10min are according to mass ratio (0-0.2): the mixture of 1.
Preferably, described toughner is at least one in EVA, CPE, MBS, ACR, SEBS, SBS, EAA, EEA, EPR, EPDM, NBR, TPE.
Preferably, described anti-aging auxiliary agent is the mixture of oxidation inhibitor, UV auxiliary agent.
Further preferred, described anti-aging auxiliary agent be oxidation inhibitor, UV auxiliary agent according to mass ratio (1-3): the mixture of 1.
Preferably, described oxidation inhibitor is at least one in phosphite ester kind antioxidant, Hinered phenols antioxidant, monothioester kind antioxidant, composite antioxidant.
Further preferred, described oxidation inhibitor is that Hinered phenols antioxidant and phosphite ester kind antioxidant are according to mass ratio 1:(1-3) mixture that forms.
Preferably, described UV auxiliary agent is at least one in benzophenone UV auxiliary agent, benzotriazole category UV auxiliary agent, benzoic acids UV auxiliary agent.
The preparation method of this kind high flowing soft anti-skidding outdoor floor PP Pipe Compound is: mixed by various raw material, melt extrude.
Below in conjunction with specific embodiment, formula of the present invention and performance are described further:
embodiment 1:
A kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound, its formula composition and performance is as following table:
table 1:
embodiment 2:
A kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound, its formula composition and performance is as following table:
table 2:
embodiment 3:
A kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound, its formula composition and performance is as following table:
table 3:
Claims (10)
1. a high flowing soft anti-skidding outdoor floor PP Pipe Compound, is characterized in that: it is made up of the raw material of following mass fraction: polypropylene 35-60 part, polyketone resin 5-10 part, POE 20-30 part, wear resistant filler 10-30 part, toughner 3-8 part, anti-aging auxiliary agent 0.3-1.5 part.
2. a kind of high flowing according to claim 1 soft anti-skidding outdoor floor PP Pipe Compound, is characterized in that: described wear resistant filler is at least one in calcium sulfate crystal whiskers, talcum powder, ceramics powder.
3. a kind of high flowing according to claim 1 soft anti-skidding outdoor floor PP Pipe Compound, is characterized in that: described polypropylene is the polyacrylic mixture of two kinds of different melt flow rates.
4. the one height flowing soft anti-skidding outdoor floor PP Pipe Compound according to claim 1 or 3, is characterized in that: described polypropylene to be melt flow rate (MFR) the be polypropylene of 1-10g/10min and the polypropylene of 20-60g/10min are according to mass ratio (0-0.2): the mixture of 1.
5. the one height flowing soft anti-skidding outdoor floor PP Pipe Compound according to any one of claim 1-3, is characterized in that: described toughner is at least one in EVA, CPE, MBS, ACR, SEBS, SBS, EAA, EEA, EPR, EPDM, NBR, TPE.
6. a kind of high flowing according to claim 5 soft anti-skidding outdoor floor PP Pipe Compound, is characterized in that: described anti-aging auxiliary agent is the mixture of oxidation inhibitor, UV auxiliary agent.
7. a kind of high flowing according to claim 6 soft anti-skidding outdoor floor PP Pipe Compound, is characterized in that: described anti-aging auxiliary agent be oxidation inhibitor, UV auxiliary agent according to mass ratio (1-3): the mixture of 1.
8. the one height flowing soft anti-skidding outdoor floor PP Pipe Compound according to claim 6 or 7, is characterized in that: described oxidation inhibitor is at least one in phosphite ester kind antioxidant, Hinered phenols antioxidant, monothioester kind antioxidant, composite antioxidant; Described UV auxiliary agent is at least one in benzophenone UV auxiliary agent, benzotriazole category UV auxiliary agent, benzoic acids UV auxiliary agent.
9. a kind of high flowing according to claim 8 soft anti-skidding outdoor floor PP Pipe Compound, is characterized in that: described oxidation inhibitor is that Hinered phenols antioxidant and phosphite ester kind antioxidant are according to mass ratio 1:(1-3) mixture that forms.
10. the preparation method of a kind of soft anti-skidding outdoor floor of high flowing according to claim 1 PP Pipe Compound, is characterized in that: step is: mixed by various raw material, melt extrude.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510269603.6A CN104910512B (en) | 2015-05-25 | 2015-05-25 | A kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510269603.6A CN104910512B (en) | 2015-05-25 | 2015-05-25 | A kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound and preparation method thereof |
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| Publication Number | Publication Date |
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| CN104910512A true CN104910512A (en) | 2015-09-16 |
| CN104910512B CN104910512B (en) | 2017-11-03 |
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| CN201510269603.6A Active CN104910512B (en) | 2015-05-25 | 2015-05-25 | A kind of high flowing soft anti-skidding outdoor floor PP Pipe Compound and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108343211A (en) * | 2018-03-24 | 2018-07-31 | 河南三公利华体育科技有限公司 | The environmentally friendly soft floors PP of one kind and its production method |
| CN109486015A (en) * | 2018-12-07 | 2019-03-19 | 广州市聚赛龙工程塑料股份有限公司 | A kind of fibre-reinforced polypropylene material and preparation method thereof |
| CN109627579A (en) * | 2018-12-07 | 2019-04-16 | 广州市聚赛龙工程塑料股份有限公司 | A kind of antipollution high abrasion polypropylene material and preparation method thereof |
| CN109762245A (en) * | 2018-12-05 | 2019-05-17 | 金发科技股份有限公司 | One kind resisting long-term thermo-oxidative ageing polypropene composition and preparation method thereof |
| CN113943457A (en) * | 2021-11-12 | 2022-01-18 | 阿姆斯壮地面材料（中国）有限公司 | Preparation process of environment-friendly homogeneous permeable floor |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102020808A (en) * | 2010-12-15 | 2011-04-20 | 广州合成材料研究院有限公司 | Polypropylene sports floor special material for outdoors |
| CN102746639A (en) * | 2011-04-19 | 2012-10-24 | 现代自动车株式会社 | Composition of polyketone with high impact strength |
-
2015
- 2015-05-25 CN CN201510269603.6A patent/CN104910512B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102020808A (en) * | 2010-12-15 | 2011-04-20 | 广州合成材料研究院有限公司 | Polypropylene sports floor special material for outdoors |
| CN102746639A (en) * | 2011-04-19 | 2012-10-24 | 现代自动车株式会社 | Composition of polyketone with high impact strength |
Non-Patent Citations (2)
| Title |
|---|
| 汪多仁: "《现代高分子材料生产及应用手册》", 31 May 2002, 中国石化出版社 * |
| 罗河胜编: "《塑料材料手册》", 31 March 2010, 广东科技出版社 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108343211A (en) * | 2018-03-24 | 2018-07-31 | 河南三公利华体育科技有限公司 | The environmentally friendly soft floors PP of one kind and its production method |
| CN109762245A (en) * | 2018-12-05 | 2019-05-17 | 金发科技股份有限公司 | One kind resisting long-term thermo-oxidative ageing polypropene composition and preparation method thereof |
| WO2020114319A1 (en) * | 2018-12-05 | 2020-06-11 | 金发科技股份有限公司 | Long-term thermo-oxidative aging-resistant polypropylene composition and preparation method thereof |
| CN109762245B (en) * | 2018-12-05 | 2021-09-10 | 金发科技股份有限公司 | Long-term thermal-oxidative-aging-resistant polypropylene composition and preparation method thereof |
| CN109486015A (en) * | 2018-12-07 | 2019-03-19 | 广州市聚赛龙工程塑料股份有限公司 | A kind of fibre-reinforced polypropylene material and preparation method thereof |
| CN109627579A (en) * | 2018-12-07 | 2019-04-16 | 广州市聚赛龙工程塑料股份有限公司 | A kind of antipollution high abrasion polypropylene material and preparation method thereof |
| CN109486015B (en) * | 2018-12-07 | 2021-08-13 | 广州市聚赛龙工程塑料股份有限公司 | Fiber-reinforced polypropylene material and preparation method thereof |
| CN113943457A (en) * | 2021-11-12 | 2022-01-18 | 阿姆斯壮地面材料（中国）有限公司 | Preparation process of environment-friendly homogeneous permeable floor |
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| Publication number | Publication date |
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| CN104910512B (en) | 2017-11-03 |
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