CN104906141A - Method for separation of soluble edible calcium from pearls - Google Patents
Method for separation of soluble edible calcium from pearls Download PDFInfo
- Publication number
- CN104906141A CN104906141A CN201410097037.0A CN201410097037A CN104906141A CN 104906141 A CN104906141 A CN 104906141A CN 201410097037 A CN201410097037 A CN 201410097037A CN 104906141 A CN104906141 A CN 104906141A
- Authority
- CN
- China
- Prior art keywords
- calcium
- margarita
- obtaining
- edible calcium
- deionized water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Seasonings (AREA)
Abstract
The invention relates to a method for separation of soluble edible calcium from pearls. The steps include: 1) grinding pearls to nanoscale, adding deionized water, microemusifying the pearl powder through collaboration of pressure and temperature; and 2) subjecting the pearl powder emulsion to electrodialysis, loading deionized water in a concentrated water pool, loading pearl powder emulsion in a freshwater pool, and conducting cyclic decalcification to obtain a calcium containing salt, which can be used as the soluble edible calcium or soluble edible calcium raw material. Due to employment of the scheme, the method can finely separate efficacy components from pearl powder and separate soluble edible calcium so as to improve the pearl powder human calcium absorption effect. The method is simple, improves the production efficiency and product yield, and can effectively reduce sewage discharge.
Description
Technical field
The present invention relates to Margarita processing method, particularly relate to and a kind ofly from Margarita, be separated the method for solvable edible calcium of obtaining.
Summary of the invention
Calcium supplementing product tends to natural prodcuts day by day, Margarita powder is natural since ancient times and possesses the Chinese medicine of effect of replenishing the calcium, wherein calcium exists with biomass calcium carbonate, current discovery can not obtain the absorption of effective release and human body, therefore, biomass calcium carbonate is become the liquid calcium of solubility by the present invention under the dipping of food acids, reaches the absorbable form of human body, improves the effect that Margarita powder is replenished the calcium.
Chinese invention patent (application number: 93117551.8 applyings date: 1993-09-18) disclose a kind of with Margarita and Margarita layer powder for raw material through and organic acid reaction, with sodium hydroxide neutralization, filter, concentrated, crystallization, drying, be ground into the method for powder preparation Margarita calcium and gained Margarita calcium thereof.This product contains the calcium of about 20%wt, and several amino acids, soluble in water, is easy to absorption of human body, is the desirable calcium source that human body supplements calcium.
Chinese invention patent (application number: 200710035508.5 applyings date: 2007-08-03) discloses a kind of water-soluble mixing active pearl calcium and preparation method thereof, and it comprises the steps: 1. Margarita and Carnis Anodonta seu crislaria pulverized and rub mixing; 2. the colloid mill that adds water becomes mixture slurry; 3. enzyme enzymolysis is added; 4. adopt negative pressure filtration, obtain filtrate 1; 5. filtering residue is put into acid hydrolysis tank, add appropriate lactic acid, heat up and stir 0.5 ~ 1 hour; 6. negative pressure filtration is adopted to obtain filtrate 2; 7. by step 6. in the filtering residue that obtains put into acid hydrolysis tank, add proper amount of edible phosphoric acid, to stir after hydrolysed filtrate to obtain hydrolyzed solution 3; 8. merging filtrate 1, filtrate 2 and hydrolyzed solution 3, stirs and regulates pH value to 5 ~ 6, water solublity mixing pearl calcium liquor of the present invention; 9. by step 8. in concentrated, the crushed after being dried of the calcium liquid that obtains become powder, namely become water-soluble mixing active pearl calcium powder.
Chinese invention patent (application number: 200910186567.1 applyings date: 2009-11-27) discloses a kind of preparation method and application product thereof of high-quality water soluble pearl calcium powder.The preparation method of described water soluble pearl calcium powder comprises the following steps: select Margarita freshwater mussel coarse powder, and make filter cake.By weight 0.05-2.95: 2.95-0.05 (Margarita: Margarita layer powder), add drinking water, mix and blend enters and Chan mill, be incorporated in slurry after rinsing mill body with a little drinking water again, enter in enzymatic vessel, intensification adds food grade bacillus subtilis neutral proteinase, carries out enzymolysis, and filtrate is Moriamin S (claiming A liquid).Filter cake is put in acid hydrolysis tank, adds lactic acid, heats up, stirs lower hydrolysis, can stop, regulate pH6.3-6.6 after solid content dissolves substantially, and after filtration, filtrate is water soluble pearl calcium liquor (claiming B liquid), sloughs water of crystallization become anhydride at 120 DEG C.A, B liquid is mixed spray-dried one-tenth water soluble Margarita powder.
Chinese invention patent (application number: 201310383763.4 applyings date: 2013-08-29) discloses the method utilizing pearl shell to prepare soluble Margarita calcium.First pearl shell is prepared into suspension; again edible alkali and taurine are prepared into solution respectively; edible alkali solution is heated to 55-85 DEG C; with the volume ratio that suspension and edible alkali solution are 1:3-6; suspension is added mix homogeneously in edible alkali solution; keep 55-85 DEG C of constant temperature 60-72 hour; then be the ratio of 1:3-6 with the volume ratio of suspension and taurine solution; add taurine solution mix homogeneously; until pearl shell fine powder dissolves completely obtain calcifying solution, after concentrated, drying and get final product.
Above-mentioned method is all adopt acidolysis to prepare organic acid calcium salt, is needed through multiple working procedure, and produces unnecessary acidolysis waste material, be unfavorable for the abundant recovery of calcium salt, also easily produce environmental wastewater simultaneously, be unfavorable for environmental protection by acidolysis.
Summary of the invention
In order to solve above-mentioned technical problem, the object of this invention is to provide and a kind ofly from Margarita, be separated the method for solvable edible calcium of obtaining, the method can from Margarita powder fine separation functional component, and be separated acquisition soluble edible calcium, to improve the effect that Margarita powder human calcium absorbs, method is simple, improves production efficiency and product yield, and effectively can reduce sewage discharge.
In order to realize above-mentioned object, present invention employs following technical scheme:
From Margarita, be separated the method obtaining solvable edible calcium, the method comprises the following steps:
1) by crushing pearl to nanoscale, then add the deionized water of 5 ~ 10 parts, collaborative by pressure 0.5 ~ 20MPa and temperature 30 ~ 60 DEG C, Margarita powder carried out microemulsified;
2) then Margarita powder emulsion is carried out electrodialysis, electrodialysis selection pressure is 30 ~ 40V, flow velocity 60 ~ 80L/h, dense pond dress deionized water, fresh-water pool dress Margarita powder emulsion, the volume ratio of deionized water and Margarita powder emulsion is 1:15 ~ 1:2, carries out circulation decalcification 1 ~ 3h, and decalcification obtains containing calcium salt as solvable edible calcium or solvable edible calcium raw material.
As preferably, the granularity of described Margarita powder is 10 ~ 100nm.
As preferably, the volume ratio of described deionized water and Margarita powder emulsion is 1:10 ~ 1:2.
As further improvement, acquisition is filtered containing calcium salt soln and obtains the transparent stillness of night, sterilization treatment, sterile filling, be Margarita soluble liquid calcium.
As further improvement, acquisition is made powdery pearl protein health product and cosmetic material containing the grinding of calcium salt soln vacuum drying.
The present invention is owing to have employed above-mentioned technical scheme, method can from Margarita powder fine separation functional component, and be separated acquisition soluble edible calcium, to improve the effect that Margarita powder human calcium absorbs, method is simple, improve production efficiency and product yield, and effectively can reduce sewage discharge.
Accompanying drawing explanation
Fig. 1 is the conductance profile figure of method in 15min sampling and measuring Margarita powder emulsion of embodiment 1.
Fig. 2 is the calcium salt content curve chart of method in 15min sampling and measuring Margarita powder emulsion of embodiment 1.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further details, but the present invention is not limited only to following examples.
embodiment 1
A kind ofly from Margarita, be separated the method for solvable edible calcium of obtaining, comprise following raw material and step: by crushing pearl to nanoscale 10 ~ 100nm, then add the deionized water of 6 parts, collaborative by pressure 1MPa and temperature 50 C, Margarita powder is carried out microemulsified, then Margarita powder emulsion is carried out electrodialysis, selection pressure is 30 ~ 40V, flow velocity 60 ~ 80L/h, dense pond dress deionized water 5L, fresh-water pool dress Margarita powder emulsion 15L, carries out circulation decalcification Ca
2+1 ~ 3h, the electrical conductivity in 15min sampling and measuring Margarita powder emulsion and calcium salt content, measurement result as depicted in figs. 1 and 2.Acquisition is filtered containing calcium salt soln and obtains the transparent stillness of night, sterilization treatment, sterile filling, be Margarita soluble liquid calcium.
embodiment 2
A kind ofly from Margarita, be separated the method for solvable edible calcium of obtaining, comprise following raw material and step: by crushing pearl to nanoscale 10 ~ 100nm, then add the deionized water of 10 parts, collaborative by pressure 10MPa and temperature 40 DEG C, Margarita powder is carried out microemulsified, then Margarita powder emulsion is carried out electrodialysis, selection pressure is 30 ~ 40V, flow velocity 60 ~ 80L/h, dense pond dress deionized water 5L, fresh-water pool dress Margarita powder emulsion 10L, carries out circulation decalcification Ca
2+2h.Obtain and make powdery pearl protein health product and cosmetic material containing the grinding of calcium salt soln vacuum drying.
embodiment 3
A kind ofly from Margarita, be separated the method for solvable edible calcium of obtaining, comprise following raw material and step: by crushing pearl to nanoscale 10 ~ 100nm, then add the deionized water of 10 parts, collaborative by pressure 15MPa and temperature 30 DEG C, Margarita powder is carried out microemulsified, then Margarita powder emulsion is carried out electrodialysis, selection pressure is 30 ~ 40V, flow velocity 60 ~ 80L/h, dense pond dress deionized water 2L, fresh-water pool dress Margarita powder emulsion 10L, carries out circulation decalcification Ca
2+2h.Obtain and make powdery pearl protein health product and cosmetic material containing the grinding of calcium salt soln vacuum drying.
Claims (5)
1. from Margarita, be separated the method obtaining solvable edible calcium, it is characterized in that the method comprises the following steps:
1) by crushing pearl to nanoscale, then add the deionized water of 5 ~ 10 parts, collaborative by pressure 0.5 ~ 20MPa and temperature 30 ~ 60 DEG C, Margarita powder carried out microemulsified;
2) then Margarita powder emulsion is carried out electrodialysis, electrodialysis selection pressure is 30 ~ 40V, flow velocity 60 ~ 80L/h, dense pond dress deionized water, fresh-water pool dress Margarita powder emulsion, the volume ratio of deionized water and Margarita powder emulsion is 1:15 ~ 1:2, carries out circulation decalcification 1 ~ 3h, and decalcification obtains containing calcium salt soln as solvable edible calcium or solvable edible calcium raw material.
2. according to claim 1ly a kind ofly from Margarita, be separated the method for solvable edible calcium of obtaining, it is characterized in that the granularity of Margarita powder is 10 ~ 100nm.
3. according to claim 1ly a kind ofly from Margarita, be separated the method for solvable edible calcium of obtaining, it is characterized in that the volume ratio of deionized water and Margarita powder emulsion is 1:10 ~ 1:2.
4. according to claim 1ly a kind ofly from Margarita, be separated the method for solvable edible calcium of obtaining, it is characterized in that obtaining filtering containing calcium salt soln and obtain the transparent stillness of night, sterilization treatment, sterile filling, be Margarita soluble liquid calcium.
5. according to claim 1ly a kind ofly from Margarita, be separated the method for solvable edible calcium of obtaining, it is characterized in that obtaining and make powdery pearl protein health product and cosmetic material containing the grinding of calcium salt soln vacuum drying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410097037.0A CN104906141B (en) | 2014-03-14 | 2014-03-14 | A method of the isolated solvable edible calcium from pearl |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410097037.0A CN104906141B (en) | 2014-03-14 | 2014-03-14 | A method of the isolated solvable edible calcium from pearl |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104906141A true CN104906141A (en) | 2015-09-16 |
| CN104906141B CN104906141B (en) | 2019-05-21 |
Family
ID=54075860
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410097037.0A Active CN104906141B (en) | 2014-03-14 | 2014-03-14 | A method of the isolated solvable edible calcium from pearl |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104906141B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1086713A (en) * | 1993-09-18 | 1994-05-18 | 邵阳市宝庆营养制剂厂 | Margarita calcium and preparation method |
| CN101720917A (en) * | 2009-11-27 | 2010-06-09 | 吴文惠 | Preparation method of high-quality water soluble pearl calcium powder and application products thereof |
| CN103333222A (en) * | 2013-07-10 | 2013-10-02 | 浙江长生鸟珍珠生物科技有限公司 | Pearl natural active peptide having whitening efficacy, and extraction method and application thereof |
-
2014
- 2014-03-14 CN CN201410097037.0A patent/CN104906141B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1086713A (en) * | 1993-09-18 | 1994-05-18 | 邵阳市宝庆营养制剂厂 | Margarita calcium and preparation method |
| CN101720917A (en) * | 2009-11-27 | 2010-06-09 | 吴文惠 | Preparation method of high-quality water soluble pearl calcium powder and application products thereof |
| CN103333222A (en) * | 2013-07-10 | 2013-10-02 | 浙江长生鸟珍珠生物科技有限公司 | Pearl natural active peptide having whitening efficacy, and extraction method and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 杨璇璇等: "电渗析稀汁脱钙及钙盐废水再生糖用树脂的研究", 《食品与发酵工业》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104906141B (en) | 2019-05-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104905242B (en) | It is a kind of that the method for preparing the solvable edible calcium of pearl and pearl composite whitening factor solutions is separated from pearl | |
| CN103843970B (en) | Production method for preparing ossein oligopeptide meal, bone oil and bone meal | |
| CN102020705B (en) | Method for preparing spirulina protein isolate | |
| CN104222999A (en) | Composition, preparation and application of novel low sodium salt | |
| CN101724677A (en) | Method for extracting collagen polypeptide and hydroxyapatite in fish scales by cooking hot extrusion | |
| CN106349742B (en) | A kind of film processing system and treatment process of extraction Semen Maydis polypeptide and corn yellow OB | |
| CN102488074B (en) | Method for extracting oyster peptide | |
| CN104738384A (en) | Preparation method of hydrolyzed protein peptide product | |
| CN102696989A (en) | Manufacture method of natural coconut powder | |
| CN104911239A (en) | Method for enzymolysis separation of pearl active polypeptide from pearl protein | |
| CN103636914A (en) | Oyster peptide extraction method | |
| CN106174436A (en) | A kind of preparation method of complex enzyme hydrolysis fishbone hormone | |
| CN102429215B (en) | Linolenic acid microcapsules and preparation method thereof | |
| CN102839047A (en) | Method for extracting fish oil and producing taurine seafood condiments by using hairtail and leftovers of hairtail | |
| CN104017101B (en) | A kind of preparation method of Dihuang polysaccharide | |
| CN101836723A (en) | Method for preparing superfine shrimp sauce and shrimp meal from shrimp heads and dried shrimps | |
| KR20090013244A (en) | Nanosize caco3 and receptivity calcium making method | |
| CN106119328A (en) | A kind of high-quality shrimp oligopeptide powder, preparation method thereof of applicable industrialized production | |
| CN104906141A (en) | Method for separation of soluble edible calcium from pearls | |
| CN103284260A (en) | California walnut dew containing endopleura and preparation method thereof | |
| CN105018557A (en) | Preparation method of pumpkin seed meal small peptides | |
| CN104163877B (en) | The preparation method of chondroitin sulfate | |
| JP7423803B2 (en) | Process method for efficiently producing carnosine-rich compounds | |
| CN106085251A (en) | A kind of method extracting gelatin from Ctenopharyngodon idellus fish skin | |
| CN105385743A (en) | Method for preparing marine protein peptide through continuous enzymolysis |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 313200 Pearl Street 99, Mogan Mountain high tech Industrial Development Zone, Huzhou, Zhejiang Applicant after: Ou Shi overflows Biological Co., Ltd. Address before: 313200 No. 518 Zhongxing North Road, Wu Kang Town, Deqing County, Huzhou, Zhejiang Applicant before: Zhejiang Osmun Biological Co., Ltd. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Wang Jing Inventor after: Yang Anquan Inventor after: Zhang Lihua Inventor after: Luo Jianfen Inventor after: Xie Min Inventor before: Yang Anquan Inventor before: Wang Jing Inventor before: Zhang Lihua Inventor before: Luo Jianfen Inventor before: Xie Min |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A method for separating soluble edible calcium from Pearl Effective date of registration: 20210729 Granted publication date: 20190521 Pledgee: Agricultural Bank of China Limited Deqing County sub branch Pledgor: OSM Biology Co.,Ltd. Registration number: Y2021330001041 |