CN104899634A - Insect prevention RFID tag for archive management - Google Patents

Insect prevention RFID tag for archive management Download PDF

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Publication number
CN104899634A
CN104899634A CN201510341835.8A CN201510341835A CN104899634A CN 104899634 A CN104899634 A CN 104899634A CN 201510341835 A CN201510341835 A CN 201510341835A CN 104899634 A CN104899634 A CN 104899634A
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China
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insect protected
tag
body part
frame
tag body
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CN104899634B (en
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张楠
李长红
韩伟
宗卫华
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Qingdao University
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Qingdao University
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Abstract

The invention provides an insect prevention RFID tag for archive management. The insect prevention RFID label for archive management includes a tag antenna, a tag chip and an external packaging base material, the external packaging base material includes a frame 1 and a tag body part 2, the tag antenna and the tag chip are arranged inside the tag body part 2, and the tag body part 2 is externally coated with an insect prevention composition 3. The invention also provides a method for manufacturing the insect prevention RFID tag for archive management. Alkaline plants such as shrubalthea, costustoot and Michelia figo in the insect prevention composition 3 can effectively adsorb or remove acidic substances, and have positive effects on whiteness and the degree of polymerization of paper, thereby effectively slowing down paper aging.

Description

A kind of file administration insect protected RFID label tag
Technical field
The invention belongs to file administration apparatus field, particularly relate to a kind of archives of paper quality insect protected label and method for making.
Background technology
At present, the many acid-free paper flour paste bond processings by strawboard, kraft or function singleness of the harness that archives, historical relic generally use are made, or leave in there is no scientific and technological content wooden filing container, in file cabinet, but these cartons and wooden box inflammable, easily infested.In order to insect protected; archives, books, historical relic department generally adopt the chemicals such as camphor, naphthalene to prevent; kill with the toxic drugs such as oxirane, Celfume; although there is protective effect to historical relic to a certain extent; but these chemical reagent pollute historical relic body and working environment, infringement health.
Application number is the Chinese patent " archives and books insect-proof agent " of 92107251.1, the coptis, mature gleditsiae, Chinese prickly ash and leaded mineral substance medicine is utilized to make ink-like or pasty product, employing brushing mode utilizes paper to make page protecting paper or employing mode of smearing makes bonding agent on spine, the taste of smear on archives or books is relied on to reach the object of Vermins-expelling vermins-proof, the method safety and environmental protection, effectiveness is lasting, but need on filing, to smear the workload that invention product considerably increases Archives Work personnel at every part, waste time and energy.Therefore, people was had on forefathers basis, to invent new technology and applied for patent CN201310537555 afterwards, the preparation method of the anti-worm-eaten composition of a kind of archives of paper quality, (1) prepare burden: first take perillaseed leaf straw 20% ~ 30% by weight percentage respectively, dried peppermint leaf straw 10% ~ 20%, florists chrysanthemum leaf straw 5% ~ 10%, fennel leaf straw 10% ~ 20% and calcium lime powder 30% ~ 50%, each plant material is cut respectively and is cut into the strip or sheet that physical dimension is 1 ~ 10mm, after mixing under normal temperature shady spot dry in the air to moisture lower than 12% plant mixture; (2) composition preparation: the plant mixture of drying in step (1) is put into comminutor and be ground into the powder that particle diameter is less than 1mm and obtain plant powder, plant powder and calcium lime powder are placed in container, stir to obtain the mixed powder of plant powder and calcium lime powder, i.e. the anti-worm-eaten composition of archives of paper quality; Again through box processed and packaging i.e. obtained archives of paper quality insect protected box.
This scheme solves the problem of insect protected protection against the tide, but although effect is pretty good to be generally through the insect protected composition 3 observing this invention of discovery employing for a long time, but in document shelf of being everlasting, leave dead angle on the one hand, cannot cover whole archives, the file cabinet particularly had is airtight, or is also provided with filing container, at this time deinsectization effect is poorer, the holding time of said composition is not long simultaneously, often will change, and can not large-scale production cannot go into operation.
Composition is bad to acidic materials treatment effect on the other hand, and the acidic materials most important enemy that is paperys, in modern slurrying and paper-making process, use a large amount of acidic chemical adjuvants, thus make persistent with stronger acidity, accelerate the hydrolysis reaction of paper fibre, make paper embrittlement flavescence, physical strength decline, until embrittlement is pulverized.Acidic materials are ubiquitous, the material that all and paper are close, acidic materials all can be caused to move among paper, accelerating the aging of paper as deposited in containing the file of acidic materials, box.So also need to improve for the problem of paper aging.The Microscopic of paper aging: the chemical constitution of cellulose, hemicellulose and lignin changes; Macro manifestations: paper yellowing, whiteness declines; Physical strength declines; Acidity rising pH value reduces.
Summary of the invention
In order to solve the problems of the technologies described above, the invention provides a kind of coverage large, vermins-proof effect is good, and anti-paper aging ability is strong, applicable industrial file administration insect protected RFID label tag:
File administration insect protected RFID label tag, comprise label antenna, label chip and outer enclosure base material, described outer enclosure base material comprises frame 1 and tag body part 2, it is inner that described label antenna and described label chip are arranged at described tag body part 2, and described tag body part 2 outside scribbles insect protected composition 3.
Preferably, the edge of described outer enclosure base material is provided with protruding frame 1.
Preferably, insect protected composition 3 comprises the following raw material according to weight parts: banksia rose 10-12 part, rose of Sharon 8-12 part, with a smile 8-12 part, cactus 20-25 part, perillaseed 10-15 part, peppermint 8-14 part, chrysanthemum 8-10 part, golden cypress 8-10 part, soda-lime 50-80 part.
Further, described frame 1 comprises frame 1 body and is arranged at described frame 1 body and is made up of cardboard or hardboard, described frame 1 body and the adhesion of described tag body part 2.
Further, described frame 1 and tag body part 2 are structure as a whole, and described frame 1 is provided with sealing strip 4 with tag body part 2 junction, and described frame 1 is double-deck bag shaped structure, and described frame 1 Inner Constitution air bag, described air bag is provided with charging connector.
Preferably, described frame 1 inside is filled with batten, and the xsect of described frame 1 is triangle or semicircle.
Present invention also offers a kind of production method of file administration insect protected RFID label tag, comprise the following steps:
Step S1: make label body, be formed in the tag body part 2 of outer enclosure base material by label chip, label antenna, described outer enclosure base material is divided into frame 1 and tag body part 2;
Step S2: make frame 1, first making cardboard or plank make frame 1 again with tag body part 2 edge adhesion or directly tag body part 2 is integrally formed frame 1, and main part and frame 1 sealing strip 4 are separated;
Step S3: make insect protected composition 3, by the banksia rose, the rose of Sharon, with a smile, cactus, perillaseed, peppermint, chrysanthemum, golden cypress, be crushed to 25 ~ 30 orders, add ethanol after mixing, backflow 2h, filters, obtains filtrate; Brazil wax, laurel wax, George Simond haze tallow are heated to molten condition, the filtrate of gained and propolis, soda-lime are added wherein, revolve after mixing and steam removing alcohol solvent.
Step S4: coating insect protected composition 3, the insect protected composition 3 obtained by step S3 is coated in the outside surface of tag body part 2.
Preferably, described step S2 comprises: with three pieces of planks or three pieces of inter-adhesive formation triangular prisms of cardboard, then by four described triangular prism head and the tail Adhesion formation rectangles, then the bottom surface of the same side of four triangular prisms of rectangle will be formed with the adhesion of tag body part 2 phase.
Preferably, described step S2 comprises: described tag body part 2 is double-decker, in the edge near described tag body part 2, sealing strip 4 is set, tag body part 2 is divided into inside and outside by sealing strip 4, and described inside is also as tag body part 2, and described outside is as frame 1, described frame 1 is double-deck bag shaped structure, described frame 1 Inner Constitution air bag, charging connector installed by described air bag, then inflation forms protruding frame 1 in charging connector.
Beneficial effect of the present invention:
1, the rose of Sharon, the banksia rose in insect protected composition 3, the alkaline soil plant such as to have a smile on one's face and can effectively adsorb or remove acidic materials, the rose of Sharon can remove sulphuric dioxide, chlorine etc. and reduce the pH value that paper harmful gas significantly can slow down paper, simultaneously to the whiteness of paper, the degree of polymerization has positive effect, effectively slows down paper aging.
2, conventional art is compared, file administration insect protected RFID label tag is combined with each file pouch or filing container, each file pouch or filing container can be covered, coverage is large, accomplish substantially without dead angle, the corner that infested mouldy place is more not easily noted, particularly when adopting airtight file cabinet filing container, insect-proof agent is difficult to work, and the present invention does not exist this problem.Simultaneously cactus, soda-lime composition can effective absorption surface dust dry air simultaneously, the durability degree of raising paper.The Conservation environment of archives can be improved greatly, moth Earthquake occurrence probability is dropped to minimum.
3, insect protected composition 3 is combined with RFID label tag, simple but the excellent of technique, need not extra spraying insecticide or put insect protected object, normally paste or folder put into the file pouch or filing container that have double-layer interlayer when only need put in storage, without the need to follow-up deinsectization process, save labour turnover, very convenient.
4, this insect protected composition 3 is made wax-like, and the holding time is long and easy to carry, suitable for mass production, only RFID label tag need be coated this insect protected composition 3, easy to use.The composition of this insect protected simultaneously 3 uses, reserve temperature is-20 DEG C to 60 DEG C, good satisfied temperature requirement.Preparation is simple simultaneously, simple to operate, storage convenience.
5, file administration insect protected RFID label tag does not contain harmful ingredients, and it is good to discharge fragrance anthelminthic effect, and the compositions such as the banksia rose, the rose of Sharon, chrysanthemum are useful to human body.
6, RFID label tag of the present invention is when the effectiveness of insect protected composition 3 reduces, effect of insect protected is replied by recoating upper insect protected composition 3, because be provided with frame 1, so when applying, be not easy the place be applied to beyond label, maintain the clean and tidy of file pouch and archive office, decrease environmental pollution, easily find position during coating simultaneously, can not be coated onto outside label easily, improve efficiency.
Accompanying drawing explanation
Fig. 1 is the structural representation of file administration insect protected RFID label tag;
Fig. 2 file administration the structure schematic diagram of insect protected RFID label tag and enlarged drawing;
Fig. 3 is the cross-sectional view of file administration insect protected RFID label tag;
Fig. 4 is the cross-sectional view of file administration insect protected RFID label tag;
Fig. 5 is the process flow diagram of the manufacture method of file administration insect protected RFID label tag.
Embodiment
Below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
Embodiment 1
As shown in Figure 1, file administration insect protected RFID label tag, comprise label antenna, label chip and outer enclosure base material, described outer enclosure base material comprises frame 1 and tag body part 2, it is inner that described label antenna and described label chip are arranged at described tag body part 2, and described tag body part 2 outside scribbles insect protected composition 3.Described frame 1 is made up of cardboard or hardboard, described frame 1 and the adhesion of described tag body part 2.
File administration insect protected RFID label tag, wherein label chip, label antenna are formed on substrate, and substrate utilizes the materials such as PET (polyethylene terephthalate), PVC, PE or paper to form.Label chip is formed at the central authorities on the surface of substrate, and label chip has transmission and reception unit, control part and storer.Store intrinsic cognizance code (unique ID) in memory, read write line is to the reading of unique ID of RFID label tag, undertaken by radio communication (wireless messages exchange) by RFID label tag antenna, this wireless messages exchanges wave mode and way of electromagnetic induction.Label antenna is dipole antenna, is formed at the both sides of label chip, and label antenna is by implementing the formation such as etching and Solder-Paste Printing on a surface of a substrate.Described substrate is outer enclosure base material.
Described outer enclosure base material can also adopt the one in phenolics, vibrin, polyamide, tygon, polystyrene, teflon.
The bottom surface of outer enclosure base material is provided with and adopts polyurethane or acrylate copolymer as the foaming sorbing material of bulk composition as gum layer, this gum layer material composition is not containing formaldehyde very environmental protection, and gum layer also can select other silica gel, rubber etc. to have the material of adhesive action as gum layer.
Or described file administration insect protected RFID label tag is adhesive label, bonding agent is scribbled at outside encapsulation base material bottom surface, it is a kind of base stock made in garlic skin paper, kraft, polyester, art paper, tygon below bonding agent, base stock has buffer action to bonding agent, to ensure that outer enclosure base material can be easy to strip down from base stock.
Described insect protected composition 3, comprises the following raw material according to weight parts: propolis 8 parts, Brazil wax 75 parts, laurel wax 25 parts, George Simond haze tallow 45 parts, the banksia rose 10 parts, the rose of Sharon 12 parts, with a smile 12 parts, 20 parts, cactus, perillaseed 10 parts, peppermint 14 parts, chrysanthemum 10 parts, golden cypress 10 parts, soda-lime 50 parts.
Preparation process is, proportionally by the banksia rose, the rose of Sharon, with a smile, cactus, perillaseed, peppermint, chrysanthemum, golden cypress, be crushed to 25 ~ 30 orders, add ethanol after mixing, backflow 2h, filters, obtain filtrate; Again Brazil wax, laurel wax, George Simond haze tallow are heated to molten condition, above-mentioned obtained filtrate, propolis, soda-lime are added wherein, revolve after mixing and steam removing alcohol solvent, namely obtain the insect protected composition 3 of the present embodiment.
As shown in Figure 2, preferably, with three pieces of planks or three pieces of inter-adhesive formation triangular prisms of cardboard, again by two tip cut-off angles at 45 ° of each triangular prism, then by four described triangular prism head and the tail Adhesion formation rectangles, as shown in Figure 3, then the bottom surface of the same side of four triangular prisms of rectangle will be formed with the adhesion of tag body part 2 phase.Be easy to like this find needs the position of coating to be not easy again to be coated onto outside label when subsequent coated insect protected composition 3 simultaneously, has both improve efficiency and has additionally reduced environmental pollution simultaneously.
Do not limit, also a slice cardboard or plank and an arc plate can be adopted, by arc plate and the cardboard of below or a wherein limit of plank Adhesion formation frame 1, now xsect is semicircle, other three limit ways of frame 1 are identical, again the two ends on ready-made every bar limit are cut into 45° angle, then by the adhesion of four edges head and the tail.The xsect on every bar limit of described frame 1 is triangle or semicircle.
As shown in Figure 4, preferably, described tag body part 2 is the double-decker of pro and con, described label antenna, label chip is arranged at the middle position in tag body part 2, described tag body part 2 place of keeping to the side is provided with a circle sealing strip 4, tag body part 2 is divided into inside and outside by sealing strip 4, described inside is also as tag body part 2, described outside is as frame 1, described frame 1 is double-deck bag shaped structure, described frame 1 Inner Constitution air bag, charging connector installed by described air bag, in charging connector, inflation forms protruding frame 1 again.While raising the efficiency, decreasing environmental pollution, there is very much certain crushing resistance, be not easy to damage.
Preferably, under the stickup of file administration insect protected RFID label tag can occur in the filing container or file pouch or archives folder situation having and make, in the bookbinding of archives warehouse-in, or the destruction of documents, transfer, when rebinding, RFID label tag is pasted onto some positions of archives folder front cover, or filing container, file pouch a certain position of outside surface, by the reading of RFID card-reading apparatus to RFID label tag, realize the identification to archives and management.
Preferably, in filing container manufacturing process, filing container is double-deck front cover, and leave opening in the same position of double-deck front cover, opening part between double-deck front cover file administration insect protected RFID label tag being implanted to filing container, and with the edge adhesive seal of bonding agent by the opening of file administration insect protected RFID label tag and the double-deck front cover before and after it, make file administration insect protected RFID label tag be fixed in the intermediate course of filing container front cover.
Preferably, during archives warehouse-in, file administration insect protected RFID label tag is attached on file pouch or filing container, or directly with the file pouch of file administration insect protected RFID label tag of the present invention or filing container, then file pouch or filing container are positioned in airtight file cabinet or filing container, even if file administration insect protected RFID label tag of the present invention also well can play insect protected, the effect of anti-paper aging in confined conditions.
As shown in Figure 5, a kind of method for making of file administration insect protected RFID label tag, comprises the following steps:
Step S1: make tag body part 2, be formed in the tag body part 2 of outer enclosure base material by label chip, label antenna, described outer enclosure base material is divided into frame 1 and tag body part 2;
Step S2: make frame 1, first make frame 1 again with tag body part 2 edge adhesion or directly tag body part 2 is integrally formed frame 1 with cardboard or plank, main part and frame 1 sealing strip 4 are separated;
Step S3: make insect protected composition 3, first take the following raw material comprised according to weight parts: propolis 8 parts, Brazil wax 75 parts, laurel wax 25 parts, George Simond haze tallow 45 parts, the banksia rose 10 parts, the rose of Sharon 12 parts, with a smile 12 parts, 20 parts, cactus, perillaseed 10 parts, peppermint 14 parts, chrysanthemum 10 parts, golden cypress 10 parts, soda-lime 50 parts; By the banksia rose, the rose of Sharon, with a smile, cactus, perillaseed, peppermint, chrysanthemum, golden cypress, be crushed to 25 ~ 30 orders, add ethanol after mixing, backflow 2h, filters, obtains filtrate; Again Brazil wax, laurel wax, George Simond haze tallow are heated to molten condition, then the filtrate of gained and propolis, soda-lime are added wherein, revolve after mixing and steam removing alcohol solvent.
Step S4: coating insect protected composition 3, the insect protected composition 3 obtained by step S3 is by being coated in the upper surface of tag body part 2 after extruding in brush or container.
Embodiment 2
File administration insect protected RFID label tag, comprise label antenna, label chip and outer enclosure base material, described outer enclosure base material comprises frame 1 and tag body part 2, it is inner that described label antenna and described label chip are arranged at described tag body part 2, and described tag body part 2 outside scribbles insect protected composition 3.
Described insect protected composition 3, comprises the following raw material according to weight parts: propolis 8 parts, Brazil wax 80 parts, laurel wax 30 parts, George Simond haze tallow 40 parts, the banksia rose 10 parts, the rose of Sharon 8 parts, with a smile 11 parts, 25 parts, cactus, perillaseed 15 parts, peppermint 8 parts, chrysanthemum 8 parts, golden cypress 8 parts, soda-lime 80 parts.
The preparation method of the insect protected composition 3 of the present embodiment is identical with the preparation method of embodiment 1; The structure of file administration insect protected RFID label tag is identical with the structure of embodiment 1, and difference is that each component concentration of insect protected composition 3 is different.Other is identical with the method for embodiment 1 except each component concentration of insect protected composition 3 for the manufacture method of file administration insect protected RFID label tag.
Embodiment 3
File administration insect protected RFID label tag, comprise label antenna, label chip and outer enclosure base material, described outer enclosure base material comprises frame 1 and tag body part 2, it is inner that described label antenna and described label chip are arranged at described tag body part 2, and described tag body part 2 outside scribbles insect protected composition 3.
Described insect protected composition 3, comprises the following raw material according to weight parts: propolis 12 parts, Brazil wax 90 parts, laurel wax 25 parts, George Simond haze tallow 35 parts, the banksia rose 10 parts, the rose of Sharon 9 parts, with a smile 10 parts, 21 parts, cactus, perillaseed 12 parts, peppermint 13 parts, chrysanthemum 10 parts, golden cypress 9 parts, soda-lime 60 parts.
The preparation method of the insect protected composition 3 of the present embodiment is identical with the preparation method of embodiment 1; The structure of file administration insect protected RFID label tag is identical with the structure of embodiment 1, and difference is that each component concentration of insect protected composition 3 is different.Other is identical with the method for embodiment 1 except each component concentration of insect protected composition 3 for the manufacture method of file administration insect protected RFID label tag.
Embodiment 4
File administration insect protected RFID label tag, comprise label antenna, label chip and outer enclosure base material, described outer enclosure base material comprises frame 1 and tag body part 2, it is inner that described label antenna and described label chip are arranged at described tag body part 2, and described tag body part 2 outside scribbles insect protected composition 3.
Described insect protected composition 3, comprises the following raw material according to weight parts: propolis 16 parts, Brazil wax 60 parts, laurel wax 15 parts, George Simond haze tallow 45 parts, the banksia rose 11 parts, the rose of Sharon 10 parts, with a smile 9 parts, 22 parts, cactus, perillaseed 13 parts, peppermint 12 parts, chrysanthemum 9 parts, golden cypress 8 parts, soda-lime 65 parts.
The preparation method of the insect protected composition 3 of the present embodiment is identical with the preparation method of embodiment 1; The structure of file administration insect protected RFID label tag is identical with the structure of embodiment 1, and difference is that each component concentration of insect protected composition 3 is different.Other is identical with the method for embodiment 1 except each component concentration of insect protected composition 3 for the manufacture method of file administration insect protected RFID label tag.
Embodiment 5
File administration insect protected RFID label tag, comprise label antenna, label chip and outer enclosure base material, described outer enclosure base material comprises frame 1 and tag body part 2, it is inner that described label antenna and described label chip are arranged at described tag body part 2, and described tag body part 2 outside scribbles insect protected composition 3.
Insect protected composition 3, comprises the following raw material according to weight parts: propolis 20 parts, Brazil wax 70 parts, laurel wax 20 parts, George Simond haze tallow 50 parts, the banksia rose 12 parts, the rose of Sharon 11 parts, with a smile 8 parts, 23 parts, cactus, perillaseed 14 parts, peppermint 11 parts, chrysanthemum 11 parts, golden cypress 9 parts, soda-lime 70 parts.
The preparation method of the insect protected composition 3 of the present embodiment is identical with the preparation method of embodiment 1; The structure of file administration insect protected RFID label tag is identical with the structure of embodiment 1, and difference is that each component concentration of insect protected composition 3 is different.Other is identical with the method for embodiment 1 except each component concentration of insect protected composition 3 for the manufacture method of file administration insect protected RFID label tag.
Embodiment 6
File administration insect protected RFID label tag, comprise label antenna, label chip and outer enclosure base material, described outer enclosure base material comprises frame 1 and tag body part 2, it is inner that described label antenna and described label chip are arranged at described tag body part 2, and described tag body part 2 outside scribbles insect protected composition 3.
Insect protected composition 3, comprises the following raw material according to weight parts: propolis 20 parts, Brazil wax 70 parts, laurel wax 20 parts, George Simond haze tallow 50 parts, the banksia rose 12 parts, the rose of Sharon 11 parts, with a smile 8 parts, 24 parts, cactus, perillaseed 11 parts, peppermint 10 parts, chrysanthemum 8 parts, golden cypress 9 parts, soda-lime 60 parts.
The preparation method of the insect protected composition 3 of the present embodiment is identical with the preparation method of embodiment 1; The structure of file administration insect protected RFID label tag is identical with the structure of embodiment 1, and difference is that each component concentration of insect protected composition 3 is different.Other is identical with the method for embodiment 1 except each component concentration of insect protected composition 3 for the manufacture method of file administration insect protected RFID label tag.
Comparative example
First take perillaseed leaf straw 20% by weight percentage respectively, dried peppermint leaf straw 10%, florists chrysanthemum leaf straw 5%, fennel leaf straw 10% and calcium lime powder 30%, each plant material is cut respectively and is cut into the strip or sheet that physical dimension is 5mm, after mixing under normal temperature shady spot dry in the air to moisture lower than 12% plant mixture; The plant mixture of drying in above-mentioned steps is put into comminutor to be ground into the powder that particle diameter is less than 1mm and to obtain plant powder, plant powder and calcium lime powder are placed in container, stir to obtain the mixed powder of plant powder and calcium lime powder, i.e. the anti-worm-eaten composition of archives of paper quality.
Using insect protected composition 3 obtained for the embodiment of the present invention 1 as A reagent, using anti-for archives of paper quality worm-eaten composition as B reagent, get A reagent and the B reagent of equal in quality, test according to archives insect-proof agent insect protected determination method national standard DA/T 27-2000, test result is as follows.
" ☆ ☆ ☆ ☆ ☆ " represents that anti-insect effect is very good, and " ☆ ☆ ☆ ☆ " represents anti-insect respond well,
" ☆ ☆ ☆ " represents that anti-insect effect is general, and " ☆ ☆ " represents that anti-insect effect is bad, and " ☆ " represents anti-insect weak effect, and "-" indicates without anti-insect effect.
Wherein " very good, good " is in archives insect-proof agent insect protected determination method standard DA/T 27-2000 " outstanding ", " generally " is in DA/T 27-2000 " qualified ", " bad, poor " is in DA/T 27-2000 " defective ".
Therefrom can find out that the pest-resistant effect of staying of A reagent is better than B reagent, especially A reagent is very effective for the control of death watch beetle.
The antiageing effect of insect protected composition 3 is tested, is divided into three experiments.
Experiment one: the reagent A of 80g and 50g pattern product are placed in independent glass container;
Experiment two: the reagent B of 80g is placed in independent glass container with 50g pattern product respectively;
Experiment three: 50g pattern product are placed in independent glass container.
These three parts of pattern product three parts of selecting the same folder of putting in storage for 2010 to split into, control the temperature of three experiments at 20 DEG C, humidity is 50%.
Following test is carried out to detect degree of aging to the pattern product in three experiments: the degree of polymerization index of pattern product is measured; The pH value of pattern product is tested; The whiteness of pattern product is tested.
By test, we obtain the change of the numerical value such as the degree of polymerization, pH value, whiteness of testing rear pattern product, by relatively assessing the degree of aging of pattern product.
Measure the degree of polymerization index of pattern product, the kinematic viscosity after adopting measurement paper fiber to be dissolved in cupri-ethylene diamine solution, then extrapolate the degree of polymerization of paper, its national measurement standard is GB/T1548-2004.
Testing the whiteness of pattern product, is use WSB-II leucometer pattern product to carry out measuring brightness.
The pH value of pattern product is tested, use pH value test pen, this test pen bromcresol green is dissolved in the 0.1N sodium hydroxide solution of 1/20 ~ 1/5 (V-/V), makes the solution of concentration 0.075% ~ 0.20% (W/V), then poured in water-color paintbrush by solution and use.When measuring stationery archives and documents and materials, will try pen at Archives Edge without writing place stroke gently, slightly put a moment, liquid medicine contrasts with Standard colour board after infiltrating, and reads the pH value of measured object.
Three forms are three experimental results of testing below.
Table 1: experiment one
Time/year, the moon Interval/moon PH The degree of polymerization Whiteness/%
2013.4 0 6.7 494.3 95
2013.7 3 6.7 474.6 94
2013.11 6 6.7 461.9 92
2014.2 9 6.6 438.7 91
2013.5 12 6.6 422.4 91
2014.8 15 6.6 406.3 90
2014.11 18 6.6 401.2 88
2015.2 21 6.6 398.6 86
Table 2: experiment two
Time/year, the moon Interval/moon PH The degree of polymerization Whiteness
2013.4 0 6.7 493.3 95
2013.7 3 6.7 471.6 93
2013.11 6 6.6 446.9 93
2014.2 9 6.6 427.7 91
2013.5 12 6.6 410.6 89
2014.8 15 6.5 396.5 87
2014.11 18 6.5 383.2 84
2015.2 21 6.5 374.6 80
Table 3: experiment three
Time/year, the moon Interval/moon PH The degree of polymerization Whiteness/%
2013.4 0 6.7 493.9 95
2013.7 3 6.7 474.8 94
2013.11 6 6.6 442.9 93
2014.2 9 6.6 423.2 91
2013.5 12 6.6 409.4 90
2014.8 15 6.5 394.9 84
2014.11 18 6.5 384.7 81
2015.2 21 6.5 373.1 79
Analyzed by above test result.After the experiment of 22 months, PH aspect, the pH value change of experiment 1 is 0.1 comparatively stable, and experiment two and experiment three are completely the same for being 0.2.Degree of polymerization aspect experiment one has dropped to 398.6 from 494.3 and have dropped 97.7, experiment two have dropped 118.7, experiment three have dropped 119.8, the degree of polymerization 1.1 after the paper sample experiments of experiment two and experiment three, be more or less the same, and test one and differ 21 respectively with 22.1 with experiment two and differ more, illustrate that the present invention has the effect slowing down degree of polymerization reduction to pattern product.Whiteness aspect also clearly, experiment one drops to 86% from 95% and have dropped 9%, and test two with experiment and three have dropped 15% and 16% respectively, experiment one with test two, three and differ comparatively greatly, illustrate that insect protected composition 3 of the present invention is to slow down effect in paper yellow more obvious.
To sum up carry out considering discovery experiment one i.e. insect protected composition 3 of the present invention from pH value, the degree of polymerization, whiteness three aspects there is the effect of good anti-paper aging.
Above-mentioned explanation illustrate and describes the preferred embodiments of the present invention, as previously mentioned, be to be understood that the present invention is not limited to the form disclosed by this paper, should not regard the eliminating to other embodiments as, and can be used for other combinations various, amendment and environment, and can in invention contemplated scope described herein, changed by the technology of above-mentioned instruction or association area or knowledge.And the change that those skilled in the art carry out and change do not depart from the spirit and scope of the present invention, then all should in the protection domain of claims of the present invention.

Claims (10)

1. a file administration insect protected RFID label tag, comprise label antenna, label chip and outer enclosure base material, described outer enclosure base material comprises frame (1) and tag body part (2), it is inner that described label antenna and described label chip are arranged at described tag body part (2), it is characterized in that: described tag body part (2) outside scribbles insect protected composition (3).
2. file administration insect protected RFID label tag as claimed in claim 1, is characterized in that: the edge of described outer enclosure base material is provided with protruding frame (1).
3. file administration insect protected RFID label tag as claimed in claim 1, is characterized in that: insect protected composition (3) comprises the following raw material according to weight parts: banksia rose 10-12 part, rose of Sharon 8-12 part, with a smile 8-12 part, cactus 20-25 part, perillaseed 10-15 part, peppermint 8-14 part, chrysanthemum 8-10 part, golden cypress 8-10 part, soda-lime 50-80 part.
4. file administration insect protected RFID label tag as claimed in claim 1, is characterized in that: described frame (1) is made up of cardboard or hardboard, described frame (1) body and described tag body part (2) adhesion.
5. file administration insect protected RFID label tag as claimed in claim 1, it is characterized in that: described frame (1) and tag body part (2) are structure as a whole, described frame (1) and tag body part (2) junction are provided with sealing strip (4), described frame (1) is double-deck bag shaped structure, described frame (1) Inner Constitution air bag, described air bag is provided with charging connector.
6. file administration insect protected RFID label tag as claimed in claim 1, is characterized in that: described outer enclosure base material is self-adhesive paper, and described self-adhesive paper comprises facial tissue, and described facial tissue is a kind of in art paper, PET or PVC, PE, PET material.
7. file administration insect protected RFID label tag as claimed in claim 1, it is characterized in that: described frame (1) inside is filled with batten, the xsect of described frame (1) is triangle or semicircle.
8. a method for making for file administration insect protected RFID label tag as claimed in claim 1, is characterized in that, comprise the steps:
Step S1: make tag body part (2), be formed in the tag body part (2) of outer enclosure base material by label chip, label antenna, described outer enclosure base material is divided into frame (1) and tag body part (2);
Step S2: make frame (1), first make frame (1) again with tag body part (2) edge adhesion or directly tag body part (2) is integrally formed frame (1) with cardboard or plank, main part and frame (1) use sealing strip (4) are separated;
Step S3: make insect protected composition (3), insect protected composition (3) comprises the following raw material according to weight parts: banksia rose 10-12 part, rose of Sharon 8-12 part, with a smile 8-12 part, cactus 20-25 part, perillaseed 10-15 part, peppermint 8-14 part, chrysanthemum 8-10 part, golden cypress 8-10 part, soda-lime 50-80 part, by the banksia rose, the rose of Sharon, with a smile, cactus, perillaseed, peppermint, chrysanthemum, golden cypress, be crushed to 25 ~ 30 orders, ethanol is added after mixing, backflow 2h, filter, obtain filtrate; Brazil wax, laurel wax, George Simond haze tallow are heated to molten condition, the filtrate of gained and propolis, soda-lime are added wherein, revolve after mixing and steam removing alcohol solvent; Step S4: coating insect protected composition (3), is coated in the outside surface of tag body part (2) by the insect protected composition (3) that step S3 is obtained.
9. the file administration method for making of insect protected RFID label tag as claimed in claim 8, it is characterized in that: described step S2 comprises: with three pieces of planks or three pieces of inter-adhesive formation triangular prisms of cardboard, again by two tip cut-off angles at 45 ° of each triangular prism, then by four described triangular prism head and the tail Adhesion formation rectangles, then the bottom surface of the same side of four triangular prisms of rectangle will be formed with tag body part (2) phase adhesion.
10. the file administration as claimed in claim 8 method for making of insect protected RFID label tag, it is characterized in that: described step S2 comprises: described tag body part (2) is double-decker, in the edge near described tag body part (2), one circle sealing strip (4) is set, tag body part (2) is divided into inside and outside by sealing strip (4), described inside is also as tag body part (2), described outside is as frame (1), described frame (1) is double-deck bag shaped structure, described frame (1) Inner Constitution air bag, charging connector installed by described air bag, in charging connector, inflation forms protruding frame (1) again.
CN201510341835.8A 2015-06-19 2015-06-19 A kind of file administration insect prevention RFID label tag Expired - Fee Related CN104899634B (en)

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CN106904378A (en) * 2017-04-19 2017-06-30 顺丰速运有限公司 A kind of interior visible seal type container bag and its application method

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CN201405591Y (en) * 2009-05-21 2010-02-17 殷万芹 Vacuum-pumping file bag
CN201967575U (en) * 2011-03-23 2011-09-14 陈文鼎 Mildewproof bar code
CN103548889A (en) * 2013-11-04 2014-02-05 青岛大学 Worm-eating prevention composition for paper archives

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CN201405591Y (en) * 2009-05-21 2010-02-17 殷万芹 Vacuum-pumping file bag
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* Cited by examiner, † Cited by third party
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CN106904378A (en) * 2017-04-19 2017-06-30 顺丰速运有限公司 A kind of interior visible seal type container bag and its application method
CN106904378B (en) * 2017-04-19 2021-02-19 顺丰速运有限公司 Internal visual sealed container bag and using method thereof

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