CN104898192A - Silver plating reflector glass for solar thermal power generation and preparation method of the same - Google Patents
Silver plating reflector glass for solar thermal power generation and preparation method of the same Download PDFInfo
- Publication number
- CN104898192A CN104898192A CN201510345205.8A CN201510345205A CN104898192A CN 104898192 A CN104898192 A CN 104898192A CN 201510345205 A CN201510345205 A CN 201510345205A CN 104898192 A CN104898192 A CN 104898192A
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- Prior art keywords
- glass
- silver
- solar energy
- film layer
- power
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/08—Mirrors
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/08—Mirrors
- G02B5/10—Mirrors with curved faces
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Optical Elements Other Than Lenses (AREA)
Abstract
Silver plating reflector glass for solar thermal power generation and a preparation method of the same. A surface of glass is plated with a silver film layer through a chemical reaction, thereby greatly improving reflectivity of the glass, and the reflectivity can reach over 95%. The sequence of steps of the preparation method is as follows: cleaning, polishing, sensibilization and activating treatment are performed on a glass substrate; a silver nitrate ammonia solution and a reducing agent are sprayed on a surface of glass at the same time, and through a redox reaction of 2 to 3 minutes, silver ions in the silver nitrate ammonia solution is reduced to metallic silver which is precipitated on the surface of the glass, thereby forming a silver film layer reflecting film; the silver film layer is passivated; the silver film layer is plated with a copper film layer; a primer layer is sprayed on the copper film layer; a finish layer is sprayed on the primer layer; and reflector glass is obtained by cleaning.
Description
Technical field
The invention belongs to chemical material technical field, is solar energy reflection looking glass and technology of preparing specifically.
Background technology
Solar energy thermal-power-generating can reduce carbon emission, is the extremely wide technology of application prospect, its cost low, and be easy to realize industrialization, can network compatible with network system, the light reflectivity improving solar energy thermal-power-generating is the problem needing to solve.
Summary of the invention
Silvered reflective looking glass that the invention provides a kind of solar energy thermal-power-generating and preparation method thereof.
Technical scheme of the present invention is: a kind of silvered reflective looking glass of solar energy thermal-power-generating, plates silver film by chemical reaction at glass substrate surface, improves its reflectivity, also has the protective seam of copper film layer, prime coat, top coat layer at this silver film outward; Mirror glass reflectivity after silver-plated reaches more than 95%; For adapting to butterfly, slot type, tower type solar energy thermal power generation type, mirror glass can be the forms such as single parabola, hyperbolic paraboloid, plane.
Further technical scheme is: a kind of silvered mirror method for glass preparation of solar energy thermal-power-generating, be following steps order: by glass substrate cleaning, polishing, sensitization, activation process, the adhesion of glass surface and silver film can be improved, improve the adhesive strength of silver film and glass surface, raising silver film serviceable life; Silver nitrate ammonia solution and reductive agent are sprayed to glass surface simultaneously, and through 2-3 minute redox reaction, in silver nitrate ammonia solution, silver ion was reduced into argent and is deposited in glass substrate surface, formed silver film reflectance coating; By this silver film passivation, the bond strength of itself and copper film layer can be improved; Copper facing rete on this silver film, can protect the effect of silver film scratching, scratch; Primer spray layer on this copper film layer, can play rainproof, corrosion protection result; Spray plane enamelled coating on this prime coat, can play the effect of rainproof, corrosion protection, sand prevention; Cleaning.
The silvered reflective looking glass of the solar energy thermal-power-generating that this method obtains, sunshine reflectivity can reach more than 95%, and anticorrosion, anti-oxidant, antistripping, sand-proof, be applicable to outdoor rugged surroundings Long-Time Service, there is higher practical value and economic worth.
Accompanying drawing explanation
Fig. 1 is the silvered mirror glass section schematic diagram of solar energy thermal-power-generating;
Fig. 2 is the silvered mirror method for glass preparation schematic flow sheet of solar energy thermal-power-generating.
Glass substrate 1, silver film 2, copper film layer 3, prime coat 4, top coat layer 5, mirror glass 6.
Embodiment
For making to have a better understanding and awareness step of the present invention and content, as shown in Figure 1, 2, coordinate detailed description as follows by preferred embodiment:
Glass substrate 1, by chemical reaction silver film 2 on glass substrate 1 plated surface, improves its reflectivity, at the outer protective seam also having copper film layer 3, prime coat 4, top coat layer 5 of this silver film 2, and shape journey final finished mirror glass 6; Specular reflectance after silver-plated reaches more than 95%, and anticorrosion, anti-oxidant, antistripping, sand-proof, be applicable to outdoor rugged surroundings Long-Time Service, there is higher practical value and economic worth; For adapting to butterfly, slot type, tower type thermal generation type, mirror glass 6 can be the forms such as single parabola, hyperbolic paraboloid, plane.
How to obtain the silvered reflective looking glass of above-mentioned solar energy thermal-power-generating, be following steps preparation method: glass substrate 1 is cleaned, polishing, sensitization, activation process, the adhesion of glass substrate 1 surface and silver film 2 can be improved, improve the adhesive strength of silver film 2 and glass substrate 1, improve silver film 2 serviceable life; Silver nitrate ammonia solution and reductive agent are sprayed to simultaneously glass substrate 1 surface, through 2-3 minute redox reaction, in silver nitrate ammonia solution, silver ion was reduced into argent and is deposited in glass substrate 1 surface, forms silver film 2 reflectance coating; By this silver film 2 passivation, the bond strength of itself and copper film layer can be improved; Copper facing rete 3 on this silver film 2, can play the effect of protection silver film 2 scratching, scratch; Primer spray layer 4 on this copper film layer 3, can play rainproof, corrosion protection result; Spray plane enamelled coating 5 on this prime coat, can play the effect of rainproof, corrosion protection, sand prevention; Mirror glass 6 is obtained after cleaning.
Claims (5)
1. a silvered reflective looking glass for solar energy thermal-power-generating, is characterized in that plating silver film by chemical reaction at glass substrate surface, improves its reflectivity, also has the protective seam of copper film layer, prime coat, top coat layer at this silver film outward.
2. the silvered reflective looking glass of solar energy thermal-power-generating according to claim 1, is characterized in that mirror glass is single parabola.
3. the silvered reflective looking glass of solar energy thermal-power-generating according to claim 1, is characterized in that mirror glass is hyperbolic paraboloid.
4. the silvered reflective looking glass of solar energy thermal-power-generating according to claim 1, is characterized in that mirror glass is plane.
5. a silvered mirror method for glass preparation for solar energy thermal-power-generating, is characterized in that following steps:
The first step is by glass substrate cleaning, polishing, sensitization, activation process;
Silver nitrate ammonia solution and reductive agent are sprayed to the glass substrate surface that the first step obtains by second step simultaneously, and through 2-3 minute redox reaction, in silver nitrate ammonia solution, silver ion was reduced into argent and is deposited in glass substrate surface, form silver film reflectance coating;
The silver film that 3rd step passivation second step obtains;
Copper facing rete on the silver film that 4th step obtains in the 3rd step;
Primer spray layer on the copper film layer that 5th step obtains in the 4th step;
Spray plane enamelled coating on the prime coat that 6th step obtains in the 5th step;
7th step cleaning.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510345205.8A CN104898192A (en) | 2015-06-19 | 2015-06-19 | Silver plating reflector glass for solar thermal power generation and preparation method of the same |
Applications Claiming Priority (1)
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CN201510345205.8A CN104898192A (en) | 2015-06-19 | 2015-06-19 | Silver plating reflector glass for solar thermal power generation and preparation method of the same |
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CN104898192A true CN104898192A (en) | 2015-09-09 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201510345205.8A Pending CN104898192A (en) | 2015-06-19 | 2015-06-19 | Silver plating reflector glass for solar thermal power generation and preparation method of the same |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020199631A1 (en) * | 2019-04-04 | 2020-10-08 | 四川钟顺太阳能开发有限公司 | Selective reflector for photovoltaic module and manufacturing method therefor |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1301882A (en) * | 1999-12-29 | 2001-07-04 | 国家建材局秦皇岛玻璃工业研究设计院 | Silver mirror reduction preparation |
CN201518063U (en) * | 2009-07-07 | 2010-06-30 | 王洪国 | Solar thermal power generation high reflecting glass silver mirror |
CN102419459A (en) * | 2011-11-25 | 2012-04-18 | 林嘉宏 | Solar reflecting glass silver mirror and manufacturing technology of the same |
CN103123401A (en) * | 2013-03-20 | 2013-05-29 | 台玻悦达太阳能镜板有限公司 | Novel solar reflecting mirror and manufacturing process thereof |
-
2015
- 2015-06-19 CN CN201510345205.8A patent/CN104898192A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1301882A (en) * | 1999-12-29 | 2001-07-04 | 国家建材局秦皇岛玻璃工业研究设计院 | Silver mirror reduction preparation |
CN201518063U (en) * | 2009-07-07 | 2010-06-30 | 王洪国 | Solar thermal power generation high reflecting glass silver mirror |
CN102419459A (en) * | 2011-11-25 | 2012-04-18 | 林嘉宏 | Solar reflecting glass silver mirror and manufacturing technology of the same |
CN103123401A (en) * | 2013-03-20 | 2013-05-29 | 台玻悦达太阳能镜板有限公司 | Novel solar reflecting mirror and manufacturing process thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020199631A1 (en) * | 2019-04-04 | 2020-10-08 | 四川钟顺太阳能开发有限公司 | Selective reflector for photovoltaic module and manufacturing method therefor |
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Application publication date: 20150909 |
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