CN104893583A - Cultural relic surface acid/alkali-corrosion-resistant coating and preparation method thereof - Google Patents
Cultural relic surface acid/alkali-corrosion-resistant coating and preparation method thereof Download PDFInfo
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- CN104893583A CN104893583A CN201510263963.5A CN201510263963A CN104893583A CN 104893583 A CN104893583 A CN 104893583A CN 201510263963 A CN201510263963 A CN 201510263963A CN 104893583 A CN104893583 A CN 104893583A
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D197/00—Coating compositions based on lignin-containing materials
- C09D197/02—Lignocellulosic material, e.g. wood, straw or bagasse
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/382—Boron-containing compounds and nitrogen
- C08K2003/385—Binary compounds of nitrogen with boron
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Engineering & Computer Science (AREA)
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- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The invention discloses a cultural relic surface acid/alkali-corrosion-resistant coating and a preparation method thereof. The cultural relic surface acid/alkali-corrosion-resistant coating is prepared from the following raw materials in parts by weight: 22-55 parts of quartz sand, 12-40 parts of petroleum coke, 14-26 parts of wood dust, 1-9 parts of sodium chloride, 12-28 parts of boron nitride, 1-13 parts of fine-grain aluminum oxide, 2-9 parts of nano zinc oxide, 15-35 parts of isopropanol and 25-60 parts of water. Compared with the prior art, the cultural relic surface acid/alkali-corrosion-resistant coating can be directly sprayed to the product surface, is simple to operate, harmless to the environment and easy to clean, and is nontoxic. The cultural relic surface acid/alkali-corrosion-resistant coating can prevent the acid/alkali corrosion on the iron cultural relic surface.
Description
Technical field
The present invention relates to chemical coating field, particularly relate to a kind of cultural artifact surface acid-alkali-corrosive-resisting coating and preparation method thereof.
Background technology
China is the country of the iron of invention smelting the earliest technology in the world, has just occurred the farm implements be made up of the pig iron and weapons in the Spring and Autumn and the Warring States Periods.Because ironware has harder and sharper than bronze, therefore, ironware after occurring just gradually instead of bronze work, thus human society is striden into the advanced iron period.In physical environment, ironware is difficult to preserve more than bronze work, because the Nature comparison of iron is active, chemical stability is poorer than the metal such as copper, lead, and it is very easily corroded, so intact ironware wants much less than bronze.And the ironware occurred before 20th century is all cast iron or the pig iron, they are mainly for the manufacture of daily apparatus and means of production.These ironwares all become historical relic now, and the history that they were studied before 20th century for us has very great help.Due to the restriction of early stage smelting technology, these ironware self structure are uneven, impurity is more, character is also unstable, are more prone to corrosion, so will protect them.
Generally speaking, the mode that protecting ferruginous historical relics often adopts is surperficial closure, namely adopts the guard method of isolated air, will scribble the ironware closure of inhibiter in a subenvironment.Because general inhibiter has certain volatility, in order to allow its long-term role, usually select suitable Protective agent, by inhibiter closure between ironware and Protective agent.Excellent surperficial Protective agent can make iron cultural relic on the basis of inhibition, obtain better weather-proof effect.Current domestic and international application is protecting materials organic and/or inorganic materials and organic materials widely.Inorganic materials protection has use inorganic inhibitor, phosphoric acid salt protection method, tannate protection method etc.Organic materials mainly refers to the polymkeric substance being applicable to coating.Polymkeric substance has better protected effect than inorganic materials, and therefore Application comparison is extensive.At present, the organic materials extensively adopted both at home and abroad has paraffin, epoxy resin, acrylic resin, silicone resin and matrix material.
The understanding of iron cultural relic mechanism of corrosion is conducive to we are more scientific protects historical relic.For each part iron cultural relic, its age is different with residing environment, and mechanism of corrosion is different, and guard method adopted thus is also different accordingly.Certain achievement is achieved to the research of iron cultural relic mechanism of corrosion and resist technology, but has need further discussion.
Summary of the invention
The technical problem solved: the invention provides a kind of cultural artifact surface acid-alkali-corrosive-resisting coating and preparation method thereof, by the method becoming aqua to spray Raw material processing, prepare one and can be sprayed directly on ironware cultural relic surface, form one deck acid-alkali-corrosive-resisting coating closely.
To achieve these goals, the present invention is by the following technical solutions:
A kind of cultural artifact surface acid-alkali-corrosive-resisting coating, makes primarily of following raw materials by weight portion proportioning: quartz sand 22 ~ 55 parts, refinery coke 12 ~ 40 parts, wood chip 14 ~ 26 parts, 1 ~ 9 part, sodium-chlor, boron nitride 12 ~ 28 parts, fine-grained alumina 1 ~ 13 part, nano zine oxide 2 ~ 9 parts, Virahol 15 ~ 35 parts, 25 ~ 60 parts, water.
As a preferred embodiment of the present invention, described cultural artifact surface acid-alkali-corrosive-resisting coating is made primarily of following raw materials by weight portion proportioning: quartz sand 48 parts, refinery coke 35 parts, wood chip 22 parts, 7 parts, sodium-chlor, boron nitride 22 parts, fine-grained alumina 11 parts, nano zine oxide 7 parts, Virahol 30 parts, 50 parts, water.
A preparation method for cultural artifact surface acid-alkali-corrosive-resisting coating, comprises following steps:
(1) quartz sand, refinery coke and wood chip are pulverized, powder diameter is 650 ~ 800 orders;
(2) powder step (1) obtained, sodium chloride powder, fine-grained alumina powder, nano-zinc oxide powder add in high temperature resistance furnace, radiation heating, and temperature maintains 1050 ~ 1400 DEG C, 1 ~ 2.5 hour;
(3) powdered mixture obtained in step (2) being added to the water with boron nitride after 6 ~ 12:1 mixes, adding Virahol wherein while stirring, cultural artifact surface acid-alkali-corrosive-resisting coating can be obtained to all dissolving.
As a preferred embodiment of the present invention, quartz sand, refinery coke and wood chip are pulverized in (1) by step, and powder diameter is 780 orders.
As a preferred embodiment of the present invention, powder step (1) obtained in step (2), sodium chloride powder, fine-grained alumina powder, nano-zinc oxide powder add in high temperature resistance furnace, radiation heating, and temperature maintains 1200 DEG C, 2.2 hours.
As a preferred embodiment of the present invention, in step (3), the powdered mixture obtained in step (2) being added to the water with boron nitride after 11:1 mixes, adding Virahol wherein while stirring, cultural artifact surface acid-alkali-corrosive-resisting coating can be obtained to all dissolving.
beneficial effect
Compared with prior art, following technique effect can be brought after the present invention adopts above technical scheme:
First, cultural artifact surface acid-alkali-corrosive-resisting coating prepared by the present invention directly can be sprayed to product surface, easy and simple to handle and environmental sound, nontoxic, easy cleaning;
Secondly, cultural artifact surface acid-alkali-corrosive-resisting coating prepared by the present invention can prevent the acid and alkali corrosion on iron cultural relic surface.
Embodiment
Embodiment 1:
A kind of cultural artifact surface acid-alkali-corrosive-resisting coating, makes primarily of following raw materials by weight portion proportioning: quartz sand 22 parts, refinery coke 12 parts, wood chip 14 parts, 1 part, sodium-chlor, boron nitride 12 parts, fine-grained alumina 1 part, nano zine oxide 2 parts, Virahol 15 parts, 25 parts, water.
A preparation method for cultural artifact surface acid-alkali-corrosive-resisting coating, comprises following steps:
(1) quartz sand, refinery coke and wood chip are pulverized, powder diameter is 650 orders;
(2) powder step (1) obtained, sodium chloride powder, fine-grained alumina powder, nano-zinc oxide powder add in high temperature resistance furnace, radiation heating, and temperature maintains 1050 DEG C, 1 hour;
(3) powdered mixture obtained in step (2) being added to the water with boron nitride after 6:1 mixes, adding Virahol wherein while stirring, cultural artifact surface acid-alkali-corrosive-resisting coating can be obtained to all dissolving.
Embodiment 2:
A kind of cultural artifact surface acid-alkali-corrosive-resisting coating, makes primarily of following raw materials by weight portion proportioning: quartz sand 48 parts, refinery coke 35 parts, wood chip 22 parts, 7 parts, sodium-chlor, boron nitride 22 parts, fine-grained alumina 11 parts, nano zine oxide 7 parts, Virahol 30 parts, 50 parts, water.
A preparation method for cultural artifact surface acid-alkali-corrosive-resisting coating, comprises following steps:
(1) quartz sand, refinery coke and wood chip are pulverized, powder diameter is 780 orders;
(2) powder step (1) obtained, sodium chloride powder, fine-grained alumina powder, nano-zinc oxide powder add in high temperature resistance furnace, radiation heating, and temperature maintains 1200 DEG C, 2.2 hours;
(3) powdered mixture obtained in step (2) being added to the water with boron nitride after 11:1 mixes, adding Virahol wherein while stirring, cultural artifact surface acid-alkali-corrosive-resisting coating can be obtained to all dissolving.
Embodiment 3:
A kind of cultural artifact surface acid-alkali-corrosive-resisting coating, makes primarily of following raw materials by weight portion proportioning: quartz sand 55 parts, refinery coke 40 parts, wood chip 26 parts, 9 parts, sodium-chlor, boron nitride 28 parts, fine-grained alumina 13 parts, nano zine oxide 9 parts, Virahol 35 parts, 60 parts, water.
A preparation method for cultural artifact surface acid-alkali-corrosive-resisting coating, comprises following steps:
(1) quartz sand, refinery coke and wood chip are pulverized, powder diameter is 800 orders;
(2) powder step (1) obtained, sodium chloride powder, fine-grained alumina powder, nano-zinc oxide powder add in high temperature resistance furnace, radiation heating, and temperature maintains 1400 DEG C, 2.5 hours;
(3) powdered mixture obtained in step (2) being added to the water with boron nitride after 12:1 mixes, adding Virahol wherein while stirring, cultural artifact surface acid-alkali-corrosive-resisting coating can be obtained to all dissolving.
After the cultural artifact surface acid-alkali-corrosive-resisting coating prepared above-described embodiment 1 ~ 3 detects, result is as follows:
Claims (6)
1. a cultural artifact surface acid-alkali-corrosive-resisting coating, it is characterized in that, make primarily of following raw materials by weight portion proportioning: quartz sand 22 ~ 55 parts, refinery coke 12 ~ 40 parts, wood chip 14 ~ 26 parts, 1 ~ 9 part, sodium-chlor, boron nitride 12 ~ 28 parts, fine-grained alumina 1 ~ 13 part, nano zine oxide 2 ~ 9 parts, Virahol 15 ~ 35 parts, 25 ~ 60 parts, water.
2. a kind of cultural artifact surface acid-alkali-corrosive-resisting coating according to claim 1, it is characterized in that, make primarily of following raw materials by weight portion proportioning: quartz sand 48 parts, refinery coke 35 parts, wood chip 22 parts, 7 parts, sodium-chlor, boron nitride 22 parts, fine-grained alumina 11 parts, nano zine oxide 7 parts, Virahol 30 parts, 50 parts, water.
3. the preparation method of a kind of cultural artifact surface acid-alkali-corrosive-resisting coating according to claim 1, is characterized in that, comprise following steps:
(1) quartz sand, refinery coke and wood chip are pulverized, powder diameter is 650 ~ 800 orders;
(2) powder step (1) obtained, sodium chloride powder, fine-grained alumina powder, nano-zinc oxide powder add in high temperature resistance furnace, radiation heating, and temperature maintains 1050 ~ 1400 DEG C, 1 ~ 2.5 hour;
(3) powdered mixture obtained in step (2) being added to the water with boron nitride after 6 ~ 12:1 mixes, adding Virahol wherein while stirring, cultural artifact surface acid-alkali-corrosive-resisting coating can be obtained to all dissolving.
4. the preparation method of a kind of cultural artifact surface acid-alkali-corrosive-resisting coating according to claim 3, it is characterized in that, quartz sand, refinery coke and wood chip are pulverized in (1) by step, and powder diameter is 780 orders.
5. the preparation method of a kind of cultural artifact surface acid-alkali-corrosive-resisting coating according to claim 3, it is characterized in that, powder step (1) obtained in step (2), sodium chloride powder, fine-grained alumina powder, nano-zinc oxide powder add in high temperature resistance furnace, radiation heating, temperature maintains 1200 DEG C, 2.2 hours.
6. the preparation method of a kind of cultural artifact surface acid-alkali-corrosive-resisting coating according to claim 3, it is characterized in that, in step (3), the powdered mixture obtained in step (2) is added to the water after 11:1 mixes with boron nitride, adding Virahol wherein while stirring, cultural artifact surface acid-alkali-corrosive-resisting coating can be obtained to all dissolving.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510263963.5A CN104893583A (en) | 2015-05-22 | 2015-05-22 | Cultural relic surface acid/alkali-corrosion-resistant coating and preparation method thereof |
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| CN201510263963.5A CN104893583A (en) | 2015-05-22 | 2015-05-22 | Cultural relic surface acid/alkali-corrosion-resistant coating and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115124894A (en) * | 2022-08-10 | 2022-09-30 | 扬州五里雾文化创意产业发展有限公司 | Preparation method of cultural relic surface sealing and protecting material |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103555086A (en) * | 2013-10-29 | 2014-02-05 | 陕西师范大学 | Earthen ruins return repair protecting agent |
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- 2015-05-22 CN CN201510263963.5A patent/CN104893583A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103555086A (en) * | 2013-10-29 | 2014-02-05 | 陕西师范大学 | Earthen ruins return repair protecting agent |
Non-Patent Citations (2)
| Title |
|---|
| 杨其新等: "《隧道及地下工程喷膜防水》", 28 February 2010, 西南交通大学出版社 * |
| 翁宇庆等: "《特殊钢在先进装备制造业应用中的战略研究》", 30 November 2012, 冶金工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115124894A (en) * | 2022-08-10 | 2022-09-30 | 扬州五里雾文化创意产业发展有限公司 | Preparation method of cultural relic surface sealing and protecting material |
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Application publication date: 20150909 |