CN104893407A - Black laser printing ink and production method thereof - Google Patents

Black laser printing ink and production method thereof Download PDF

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Publication number
CN104893407A
CN104893407A CN201510285177.5A CN201510285177A CN104893407A CN 104893407 A CN104893407 A CN 104893407A CN 201510285177 A CN201510285177 A CN 201510285177A CN 104893407 A CN104893407 A CN 104893407A
Authority
CN
China
Prior art keywords
printing ink
laser printing
black
black laser
production method
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510285177.5A
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Chinese (zh)
Inventor
王允强
孙胜晓
梁玉成
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZIBO TAOZHENG CERAMIC PIGMENT Co Ltd
Original Assignee
ZIBO TAOZHENG CERAMIC PIGMENT Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ZIBO TAOZHENG CERAMIC PIGMENT Co Ltd filed Critical ZIBO TAOZHENG CERAMIC PIGMENT Co Ltd
Priority to CN201510285177.5A priority Critical patent/CN104893407A/en
Publication of CN104893407A publication Critical patent/CN104893407A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent

Abstract

The invention discloses a black laser printing ink and a production method thereof. The black laser printing ink comprises the following raw materials in parts by weight: 15-25 parts of black toner, 20-30 parts of low-temperature fluxing agent, 40-50 parts of vapor-phase silicon and 3-5 parts of volatile liquid. The black laser printing ink fills up the blank in the domestic market, and effectively solves the problem of toxic volatile substances; the volatilized gas is nontoxic, and can implement disinfection and sterilization; and the out-of-date ink can be recycled.

Description

A kind of black laser printing ink and production method
Technical field
The present invention relates to a kind of laser printing ink, particularly relate to a kind of black laser printing ink and production method.
Background technology
Along with development and the application of laser technology, laser printing also reaches its maturity.Laser ink is a kind of consumptive material of laser printing, can be applicable to the decoration of the materials such as pottery, glass, resin.The quality of ink is directly connected to the effect of decoration.But laser printing ink now on the market most monopolize by foreign technology, domestic seldom have producer to relate to the industry.Import laser ink is not only expensive, and the inner toxicity volatile component containing a large amount of similar ammonia taste, in use, to human body and environment all very unfavorable.Ink, can only waste treatment once expired, causes a large amount of wastes of resource.
Due to technical monopoly, the sand mill price in addition making ink is relatively high, and this just causes, and to enter laser ink industry threshold higher, and this is also the major reason that laser ink difficulty has breakthrough.
Summary of the invention
The invention provides a kind of black laser printing ink and production method thereof, in order to fill up domestic market blank, also efficiently solve the problem of poisonous volatilization, the gas volatilized is not only nontoxic, and can disinfection, and expired ink also can be recycled.
The invention provides a kind of black laser printing ink, comprise black toner, low temperature flux, gas-phase silicon, volatile liquid and auxiliary agent, above-mentioned raw materials is (15-25) by weight: (20-30): (3-5): (40-50): (3-5).
Black laser printing ink as above, selected volatile liquid is dehydrated alcohol.
Black laser printing ink as above, selected black colorant formula is as follows:
Cr 2O 3 30-35；
Fe 2O 3 30-35；
NiO 10-15；
CoO 10-30；
MnO 23-5；
K 2O 0.1-0.5；
Na 2O 0.2-0.5；
CaO 0.3-0.5。
Black laser printing ink as above, selected low temperature flux formula is as follows:
Al 2O 350-58；
SiO 2 8-10；
Fe 2O 3＜0.5；
CaO 8-10；
Li 2O 5-8；
K 2O 3-10；
Na 2O 2-5；
B 2O 36-10。
Black laser printing ink as above, selected auxiliary agent is dispersion agent, and this dispersion agent is high molecular weight epoxy ethane epoxy propane multipolymer, and containing nucleophilic group.
The invention provides a kind of manufacture black laser printing ink described above, its production stage comprises:
(1) first black toner, low temperature flux, volatile liquid and auxiliary agent are mixed in proportion, and then slowly add gas-phase silicon, while add, limit is stirred;
(2) after stirring, material is put into sand mill and grinds, be ground to D100 < 10um;
(3) carry out filter at low temperature after taking-up, filtration temperature controls below 10 DEG C;
(4), after filtering, detect with laser printer.
Black laser printing ink as above, selected volatile liquid is dehydrated alcohol.
Black laser printing ink as above, selected black colorant formula is as follows:
Cr 2O 3 30-35；
Fe 2O 3 30-35；
NiO 10-15；
CoO 10-30；
MnO 23-5；
K 2O 0.1-0.5；
Na 2O 0.2-0.5；
CaO 0.3-0.5。
Black laser printing ink as above, selected low temperature flux formula is as follows:
Al 2O 350-58；
SiO 2 8-10；
Fe 2O 3＜0.5；
CaO 8-10；
Li 2O 5-8；
K 2O 3-10；
Na 2O 2-5；
B 2O 36-10。
Black laser printing ink as above, selected auxiliary agent is dispersion agent, and this dispersion agent is high molecular weight epoxy ethane epoxy propane multipolymer, and containing nucleophilic group.
Black laser printing ink production method as above, the equipment for grinding is sand mill.
Compared with prior art, the present invention adopts nontoxic material, and adopt ethanol to be easy volatile liquid, really efficiently solve the problem of poisonous volatilization, the gas volatilized is not only nontoxic, and can disinfection, and expired ink also can be recycled, the material that the present invention uses is simple and easy to get, greatly reduces production cost.
Embodiment
For making the object of the embodiment of the present invention, technical scheme and advantage clearly, below in conjunction with embodiment, the technical scheme in the present invention is clearly and completely described, obviously, described embodiment is the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
A kind of black laser printing ink of the present embodiment, comprise black toner, low temperature flux, gas-phase silicon, volatile liquid and auxiliary agent, above-mentioned raw materials is (15-25) by weight: (20-30): (3-5): (40-50): (3-5).
Black laser printing ink as above, selected volatile liquid is dehydrated alcohol.
Black laser printing ink as above, selected black colorant formula is as follows:
Cr 2O 3 30-35；
Fe 2O 3 30-35；
NiO 10-15；
CoO 10-30；
MnO 23-5；
K 2O 0.1-0.5；
Na 2O 0.2-0.5；
CaO 0.3-0.5。
Black laser printing ink as above, selected low temperature flux formula is as follows:
Al 2O 350-58；
SiO 2 8-10；
Fe 2O 3＜0.5；
CaO 8-10；
Li 2O 5-8；
K 2O 3-10；
Na 2O 2-5；
B 2O 36-10。
Black laser printing ink as above, selected auxiliary agent is dispersion agent, and this dispersion agent is high molecular weight epoxy ethane epoxy propane multipolymer, and containing nucleophilic group.
The invention provides a kind of manufacture black laser printing ink described above, its production stage comprises:
(1) first black toner, low temperature flux, volatile liquid and auxiliary agent are mixed in proportion, and then slowly add gas-phase silicon, while add, limit is stirred;
(2) after stirring, material is put into sand mill and grinds, be ground to D100 < 10um;
(3) carry out filter at low temperature after taking-up, filtration temperature controls below 10 DEG C;
(4), after filtering, detect with laser printer.
Black laser printing ink as above, selected volatile liquid is dehydrated alcohol.
Black laser printing ink as above, selected black colorant formula is as follows:
Cr 2O 3 30-35；
Fe 2O 3 30-35；
NiO 10-15；
CoO 10-30；
MnO 23-5；
K 2O 0.1-0.5；
Na 2O 0.2-0.5；
CaO 0.3-0.5。
Black laser printing ink as above, selected low temperature flux formula is as follows:
Al 2O 350-58；
SiO 2 8-10；
Fe 2O 3＜0.5；
CaO 8-10；
Li 2O 5-8；
K 2O 3-10；
Na 2O 2-5；
B 2O 36-10。
Black laser printing ink as above, selected auxiliary agent is dispersion agent, and this dispersion agent is high molecular weight epoxy ethane epoxy propane multipolymer, and containing nucleophilic group.
Black laser printing ink production method as above, the equipment for grinding is sand mill.
Embodiment 1:
Get black toner 15 parts, low temperature flux 30 parts, gas-phase silicon 5 parts, dehydrated alcohol 45 parts, polyvinylpyrrolidone 5 parts, first mixes black toner, low temperature flux, dehydrated alcohol and SYNPERONIC PE/F68, then slowly add gas-phase silicon, stir while adding, after stirring, enter sand mill, grinding detects granularity, when D100 < 10um, releases, then carry out filter at low temperature, control temperature is lower than 10 DEG C.Filter and terminate, sample thief carries out laser printing detection, contrast color, firmness etc., qualified rear filling.
Embodiment 2:
Get black toner 20 parts, low temperature flux 25 parts, gas-phase silicon 4 parts, dehydrated alcohol 46 parts, glyceryl monostearate 5 parts, first mixes black toner, low temperature flux, dehydrated alcohol and SYNPERONIC PE/F68, then slowly add gas-phase silicon, stir while adding, after stirring, enter sand mill, grinding detects granularity, when D100 < 10um, releases, then carry out filter at low temperature, control temperature is lower than 10 DEG C.Filter and terminate, sample thief carries out laser printing detection, contrast color, firmness etc., qualified rear filling.
Embodiment 3:
Get black toner 25 parts, low temperature flux 20 parts, gas-phase silicon 4.5 parts, dehydrated alcohol 46 parts, polyethylene wax4.5 part, first black toner, low temperature flux, dehydrated alcohol and SYNPERONIC PE/F68 are mixed, then slowly add gas-phase silicon, stir while adding, after stirring, enter sand mill, grinding detects granularity, when D100 < 10um, releases, then carry out filter at low temperature, control temperature is lower than 10 DEG C.Filter and terminate, sample thief carries out laser printing detection, contrast color, firmness etc., qualified rear filling.
The foregoing is only one embodiment of the invention, do not limit the present invention, the technical scheme that the mode that all employings are equal to replacement or equivalent transformation obtains, all drop in protection scope of the present invention.

Claims (10)

1. a black laser printing ink, comprise black toner, low temperature flux, gas-phase silicon, volatile liquid and auxiliary agent, above-mentioned raw materials is (15-25) by weight: (20-30): (3-5): (40-50): (3-5).
2. a kind of black laser printing ink according to claims 1, is characterized in that, selected volatile liquid is dehydrated alcohol.
3. a kind of black laser printing ink according to claims 1, is characterized in that, selected black colorant formula is as follows:
Cr 2O 3 30-35；
Fe 2O 3 30-35；
NiO 10-15；
CoO 10-30；
MnO 23-5；
K 2O 0.1-0.5；
Na 2O 0.2-0.5；
CaO 0.3-0.5。
4. a kind of black laser printing ink according to claims 1, is characterized in that, selected low temperature flux formula is as follows:
Al 2O 350-58；
SiO 2 8-10；
Fe 2O 3＜0.5；
CaO 8-10；
Li 2O 5-8；
K 2O 3-10；
Na 2O 2-5；
B 2O 36-10。
5. a kind of black laser printing ink according to claims 1, is characterized in that, selected auxiliary agent is dispersion agent, and this dispersion agent is high molecular weight epoxy ethane epoxy propane multipolymer, and containing nucleophilic group.
6. a production method for black laser printing ink, is characterized in that, its production stage comprises:
(1) first black toner, low temperature flux, volatile liquid and auxiliary agent are mixed in proportion, and then slowly add gas-phase silicon, while add, limit is stirred;
(2) after stirring, material is put into sand mill and grinds, be ground to D100 < 10um;
(3) carry out filter at low temperature after taking-up, filtration temperature controls below 10 DEG C;
(4), after filtering, detect with laser printer.
7. the production method of a kind of black laser printing ink according to claims 6, is characterized in that, selected volatile liquid is dehydrated alcohol.
8. the production method of a kind of black laser printing ink according to claims 6, is characterized in that, selected black colorant formula is as follows:
Cr 2O 3 30-35；
Fe 2O 3 30-35；
NiO 10-15；
CoO 10-30；
MnO 23-5；
K 2O 0.1-0.5；
Na 2O 0.2-0.5；
CaO 0.3-0.5。
9. the production method of a kind of black laser printing ink according to claims 6, is characterized in that, selected low temperature flux formula is as follows:
Al 2O 350-58；
SiO 2 8-10；
Fe 2O 3＜0.5；
CaO 8-10；
Li 2O 5-8；
K 2O 3-10；
Na 2O 2-5；
B 2O 36-10。
10. the production method of a kind of black laser printing ink according to claims 6, is characterized in that, selected auxiliary agent is dispersion agent, and this dispersion agent is high molecular weight epoxy ethane epoxy propane multipolymer, and containing nucleophilic group.
CN201510285177.5A 2015-05-29 2015-05-29 Black laser printing ink and production method thereof Pending CN104893407A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510285177.5A CN104893407A (en) 2015-05-29 2015-05-29 Black laser printing ink and production method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510285177.5A CN104893407A (en) 2015-05-29 2015-05-29 Black laser printing ink and production method thereof

Publications (1)

Publication Number Publication Date
CN104893407A true CN104893407A (en) 2015-09-09

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Application Number Title Priority Date Filing Date
CN201510285177.5A Pending CN104893407A (en) 2015-05-29 2015-05-29 Black laser printing ink and production method thereof

Country Status (1)

Country Link
CN (1) CN104893407A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106433290A (en) * 2016-09-13 2017-02-22 山东镭泽智能科技有限公司 Blue laser printing ink and preparing method thereof
CN113278323A (en) * 2021-07-02 2021-08-20 山东陶正新材料科技有限公司 Water-based black laser printing paste with good wettability

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102368144A (en) * 2011-10-26 2012-03-07 无锡佳腾磁性粉有限公司 Back high-temperature resistant ceramic toner and preparation method thereof
CN102381047A (en) * 2011-08-08 2012-03-21 信益陶瓷(中国)有限公司 Noncontact continuous printing method for ceramic surface
CN103342917A (en) * 2013-07-04 2013-10-09 西安电子科技大学 Yellow ceramic ink for ink-jet printing
CN104133352A (en) * 2014-08-09 2014-11-05 鲁继烈 Toner for laser printers

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102381047A (en) * 2011-08-08 2012-03-21 信益陶瓷(中国)有限公司 Noncontact continuous printing method for ceramic surface
CN102368144A (en) * 2011-10-26 2012-03-07 无锡佳腾磁性粉有限公司 Back high-temperature resistant ceramic toner and preparation method thereof
CN103342917A (en) * 2013-07-04 2013-10-09 西安电子科技大学 Yellow ceramic ink for ink-jet printing
CN104133352A (en) * 2014-08-09 2014-11-05 鲁继烈 Toner for laser printers

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106433290A (en) * 2016-09-13 2017-02-22 山东镭泽智能科技有限公司 Blue laser printing ink and preparing method thereof
CN113278323A (en) * 2021-07-02 2021-08-20 山东陶正新材料科技有限公司 Water-based black laser printing paste with good wettability

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Application publication date: 20150909

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