CN104891956A - Tourmaline-containing high temperature resistant special ceramic and preparation method thereof - Google Patents
Tourmaline-containing high temperature resistant special ceramic and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a tourmaline-containing high temperature resistant special ceramic and a preparation method thereof, the tourmaline-containing high temperature resistant special ceramic comprises the following components by mass: 3.6-3.8% of phyllite, 2.5-2.8% of calcium oxide, 12.5-12.8% of tourmaline, 3.2-3.5% of zinc oxide, 1.5-1.8% of manganese dioxide, 5.6-5.8% of purple sand mud, 11.5-11.8% of kaolin, 8.5-9.2% of rutile, 3.6-3.8% of nickel powder, 2.5-2.7% of aluminium powder, 1.2-1.5% of additives, 1.2-1.5% of rare earth, 3.5-3.8% of talcum powder, and balance of clay.
Description
Technical field
The invention belongs to ceramic, relate to a kind of fire resistant special type containing tourmalinite pottery and preparation method thereof.
Background technology
The material of current passage, pipeline has aluminum alloy materials, pottery etc., and aluminum alloy materials wears no resistance, and conduit evanescence, affects precision of color separation, and often change, cost is high; Stupalith fragility used is at present large, and wear resistance is not too high, and cold-hot does not stimulate, and resistance to acids and bases is poor, and therefore need research wear resistance good, the stupalith of hardness is high, good toughness, and vibration resistance is heat-resisting, corrosion-resistant excellent performance of Denging, to reduce costs.
Summary of the invention
Technical problem to be solved by this invention is, overcomes the shortcoming of prior art, provides a kind of fire resistant special type containing tourmalinite pottery and preparation method thereof, not only intensity is high, good toughness, vibration resistance, heat-resisting, corrosion-resistant, smooth surface, outward appearance is good, and cost is low, long service life, and its preparation method is provided, method is simple, and improve the quality of products, production efficiency is high.
In order to solve above technical problem, the invention provides a kind of fire resistant special type containing tourmalinite pottery, should be by mass percentage containing the component of the fire resistant special type pottery of tourmalinite: phyllite: 3.6-3.8%, calcium oxide: 2.5-2.8%, tourmalinite: 12.5-12.8%, zinc oxide: 3.2-3.5%, Manganse Dioxide: 1.5-1.8%, purple clay: 5.6-5.8%, kaolin: 11.5-11.8%, rutile: 8.5-9.2%, nickel powder: 3.6-3.8%, aluminium powder: 2.5-2.7%, auxiliary agent: 1.2-1.5%, rare earth: 1.2-1.5%, talcum powder: 3.5-3.8%, surplus is clay,
The component of rare earth is by mass percentage: praseodymium: 8.5-8.8%, thulium: 12.2-12.5%, lutetium: 7.4-7.6%, neodymium: 15.4-15.8%, promethium: 3.3-3.5%, samarium: 7.2-7.5%, europium: 1.2-1.5%, terbium: 7.2-7.5%, surplus is holmium and inevitable impurity;
The component of auxiliary agent is counted by weight: talcum powder: 8-12 part, quartz: 3-5 part, kaolinite: 6-8 part, deionized water: 20-25 part, bortz powder: 8-10 part, titanium dioxide: 2-7 part, clay: 12-15 part;
The preparation method of auxiliary agent is: by talcum powder, quartz and kaolinite co-grinding, cross 40 mesh sieves, obtain powders A, then bortz powder, clay and titanium dioxide co-grinding, cross 70 mesh sieves, obtain powder B, powders A and powder B are uniformly mixed with the ratio of 4:3, stir 10 minutes, then add deionized water and stirring and react 35 minutes, then filter, dry, pulverize, cross 100 mesh sieves, under helium atmosphere, after calcining 2-3 hour at being heated to 900-920 DEG C, air cooling, to room temperature, is then pulverized, cross 120 mesh sieves, can auxiliary agent be obtained.
The present invention also provides the preparation method of the fire resistant special type pottery containing tourmalinite, and concrete preparation method is as follows:
Step (1): phyllite, calcium oxide, tourmalinite and zinc oxide are mixed, then put into ball mill abrasive dust, cross 40 mesh sieves, then Manganse Dioxide, purple clay, kaolin and rutile are sent into ball milling 8-10 hour in ball mill, then temperature is increased to 620-630 DEG C, insulation 1-3 hour, and then add auxiliary agent, rare earth, talcum powder and clay, and temperature is increased to 870-880 DEG C, calcining 2-4 hour, then be milled to powder, cross 100 mesh sieves, obtain powder particle A;
Step (2): by powder particle A using nitrogen as shielding gas, at 960-965 DEG C, calcine 1-3 hour, then air cooling is to room temperature, sends into ball mill abrasive dust, crosses 120 mesh sieves, obtains powder particle B;
Step (3): the powder particle B that nickel powder, aluminium powder and step (2) obtain is mixed and stirred, is heated to 1010-1020 DEG C, and calcines 1-3 hour, pulverizes, and crosses 120 mesh sieves, obtains powder particle C;
Step (4): the powder particle C obtain step (3) and water are in the ratio ball milling 15-18 hour of 2.4:2, and then moulding, in the atmosphere of helium, at 830-840 DEG C of temperature lower calcination 3-5 hour, again temperature is increased to 1170-1180 DEG C, insulation 2-3 hour, last air cooling is to room temperature.
The technical scheme that the present invention limits further is:
The aforesaid pottery of the fire resistant special type containing tourmalinite, should be containing the component of the fire resistant special type pottery of tourmalinite: phyllite: 3.6%, calcium oxide: 2.5% by mass percentage, tourmalinite: 12.5%, zinc oxide: 3.2%, Manganse Dioxide: 1.5%, purple clay: 5.6%, kaolin: 11.5%, rutile: 8.5%, nickel powder: 3.6%, aluminium powder: 2.5%, auxiliary agent: 1.2%, rare earth: 1.2%, talcum powder: 3.5%, surplus is clay;
The component of rare earth is by mass percentage: praseodymium: 8.5%, thulium: 12.2%, lutetium: 7.4%, neodymium: 15.4%, promethium: 3.3%, samarium: 7.2%, europium: 1.2%, terbium: 7.2%, and surplus is holmium and inevitable impurity;
The component of auxiliary agent is counted by weight: talcum powder: 8 parts, quartz: 3 parts, kaolinite: 6 parts, deionized water: 20 parts, bortz powder: 8 parts, titanium dioxide: 2 parts, clay: 12 parts;
The preparation method of auxiliary agent is: by talcum powder, quartz and kaolinite co-grinding, cross 40 mesh sieves, obtain powders A, then bortz powder, clay and titanium dioxide co-grinding, cross 70 mesh sieves, obtain powder B, powders A and powder B are uniformly mixed with the ratio of 4:3, stir 10 minutes, then add deionized water and stirring and react 35 minutes, then filter, dry, pulverize, cross 100 mesh sieves, under helium atmosphere, calcine after 2 hours at being heated to 900 DEG C, air cooling, to room temperature, is then pulverized, cross 120 mesh sieves, can auxiliary agent be obtained.
The aforesaid pottery of the fire resistant special type containing tourmalinite, should be containing the component of the fire resistant special type pottery of tourmalinite: phyllite: 3.8%, calcium oxide: 2.8% by mass percentage, tourmalinite: 12.8%, zinc oxide: 3.5%, Manganse Dioxide: 1.8%, purple clay: 5.8%, kaolin: 11.8%, rutile: 9.2%, nickel powder: 3.8%, aluminium powder: 2.7%, auxiliary agent: 1.5%, rare earth: 1.5%, talcum powder: 3.8%, surplus is clay;
The component of rare earth is by mass percentage: praseodymium: 8.8%, thulium: 12.5%, lutetium: 7.6%, neodymium: 15.8%, promethium: 3.5%, samarium: 7.5%, europium: 1.5%, terbium: 7.5%, and surplus is holmium and inevitable impurity;
The component of auxiliary agent is counted by weight: talcum powder: 12 parts, quartz: 5 parts, kaolinite: 8 parts, deionized water: 25 parts, bortz powder: 10 parts, titanium dioxide: 7 parts, clay: 15 parts;
The preparation method of auxiliary agent is: by talcum powder, quartz and kaolinite co-grinding, cross 40 mesh sieves, obtain powders A, then bortz powder, clay and titanium dioxide co-grinding, cross 70 mesh sieves, obtain powder B, powders A and powder B are uniformly mixed with the ratio of 4:3, stir 10 minutes, then add deionized water and stirring and react 35 minutes, then filter, dry, pulverize, cross 100 mesh sieves, under helium atmosphere, calcine after 3 hours at being heated to 920 DEG C, air cooling, to room temperature, is then pulverized, cross 120 mesh sieves, can auxiliary agent be obtained.
The aforesaid pottery of the fire resistant special type containing tourmalinite, should be containing the component of the fire resistant special type pottery of tourmalinite: phyllite: 3.7%, calcium oxide: 2.7% by mass percentage, tourmalinite: 12.7%, zinc oxide: 3.3%, Manganse Dioxide: 1.7%, purple clay: 5.7%, kaolin: 11.7%, rutile: 8.7%, nickel powder: 3.7%, aluminium powder: 2.6%, auxiliary agent: 1.4%, rare earth: 1.4%, talcum powder: 3.7%, surplus is clay;
The component of rare earth is by mass percentage: praseodymium: 8.7%, thulium: 12.4%, lutetium: 7.5%, neodymium: 15.7%, promethium: 3.4%, samarium: 7.4%, europium: 1.4%, terbium: 7.4%, and surplus is holmium and inevitable impurity;
The component of auxiliary agent is counted by weight: talcum powder: 9 parts, quartz: 4 parts, kaolinite: 7 parts, deionized water: 22 parts, bortz powder: 9 parts, titanium dioxide: 5 parts, clay: 14 parts;
The preparation method of auxiliary agent is: by talcum powder, quartz and kaolinite co-grinding, cross 40 mesh sieves, obtain powders A, then bortz powder, clay and titanium dioxide co-grinding, cross 70 mesh sieves, obtain powder B, powders A and powder B are uniformly mixed with the ratio of 4:3, stir 10 minutes, then add deionized water and stirring and react 35 minutes, then filter, dry, pulverize, cross 100 mesh sieves, under helium atmosphere, calcine after 2 hours at being heated to 910 DEG C, air cooling, to room temperature, is then pulverized, cross 120 mesh sieves, can auxiliary agent be obtained.
The invention has the beneficial effects as follows: in pottery, add tourmalinite, the advantage of tourmalinite can not only be utilized: 1. produce negative ion, 2. brine electrolysis, 3. reduce water molecules bundle, 4. emitting far infrared ray, 5. containing effective trace mineral, water treatment can not only be used for, hydrotherapy can also be used for and support health care, makeup, textile industry product etc., of many uses, and the performance of pottery can be increased, as " intensity, toughness, vibration resistance, heat-resisting, corrosion-resistant etc., reduce costs, add the work-ing life of pottery, by increasing zinc oxide, Manganse Dioxide, the elements such as nickel powder, reduce the fragility of pottery, increase its toughness and intensity, smooth surface is beautiful, increase the competitive power of product, add rare earth can promote to form metallic element rapid aggregation, form fine and close grain structure, gain in strength, and by preparation method, can reduce costs, save process period, improve productivity effect.
Embodiment
embodiment 1
A kind of pottery of the fire resistant special type containing tourmalinite that the present embodiment provides, should be containing the component of the fire resistant special type pottery of tourmalinite: phyllite: 3.6%, calcium oxide: 2.5% by mass percentage, tourmalinite: 12.5%, zinc oxide: 3.2%, Manganse Dioxide: 1.5%, purple clay: 5.6%, kaolin: 11.5%, rutile: 8.5%, nickel powder: 3.6%, aluminium powder: 2.5%, auxiliary agent: 1.2%, rare earth: 1.2%, talcum powder: 3.5%, surplus is clay;
The component of rare earth is by mass percentage: praseodymium: 8.5%, thulium: 12.2%, lutetium: 7.4%, neodymium: 15.4%, promethium: 3.3%, samarium: 7.2%, europium: 1.2%, terbium: 7.2%, and surplus is holmium and inevitable impurity;
The component of auxiliary agent is counted by weight: talcum powder: 8 parts, quartz: 3 parts, kaolinite: 6 parts, deionized water: 20 parts, bortz powder: 8 parts, titanium dioxide: 2 parts, clay: 12 parts;
The preparation method of auxiliary agent is: by talcum powder, quartz and kaolinite co-grinding, cross 40 mesh sieves, obtain powders A, then bortz powder, clay and titanium dioxide co-grinding, cross 70 mesh sieves, obtain powder B, powders A and powder B are uniformly mixed with the ratio of 4:3, stir 10 minutes, then add deionized water and stirring and react 35 minutes, then filter, dry, pulverize, cross 100 mesh sieves, under helium atmosphere, calcine after 2 hours at being heated to 900 DEG C, air cooling, to room temperature, is then pulverized, cross 120 mesh sieves, can auxiliary agent be obtained.
The present embodiment also provides the preparation method of the fire resistant special type pottery containing tourmalinite, and concrete preparation method is as follows:
Step (1): phyllite, calcium oxide, tourmalinite and zinc oxide are mixed, then put into ball mill abrasive dust, cross 40 mesh sieves, then Manganse Dioxide, purple clay, kaolin and rutile to be sent in ball mill ball milling 8 hours, then temperature is increased to 620 DEG C, be incubated 1 hour, and then add auxiliary agent, rare earth, talcum powder and clay, and temperature is increased to 870 DEG C, calcine 2 hours, then be milled to powder, cross 100 mesh sieves, obtain powder particle A;
Step (2): by powder particle A using nitrogen as shielding gas, calcine 1 hour at 960 DEG C, then air cooling is to room temperature, sends into ball mill abrasive dust, crosses 120 mesh sieves, obtains powder particle B;
Step (3): the powder particle B that nickel powder, aluminium powder and step (2) obtain is mixed and stirred, is heated to 1010 DEG C, and calcines 1 hour, pulverizes, and crosses 120 mesh sieves, obtains powder particle C;
Step (4): the powder particle C obtain step (3) and water are in the ratio ball milling 15 hours of 2.4:2, and then moulding, in the atmosphere of helium, 830 DEG C of temperature lower calcinations 3 hours, again temperature is increased to 1170 DEG C, be incubated 2 hours, last air cooling is to room temperature.
embodiment 2
A kind of pottery of the fire resistant special type containing tourmalinite that the present embodiment provides, should be containing the component of the fire resistant special type pottery of tourmalinite: phyllite: 3.8%, calcium oxide: 2.8% by mass percentage, tourmalinite: 12.8%, zinc oxide: 3.5%, Manganse Dioxide: 1.8%, purple clay: 5.8%, kaolin: 11.8%, rutile: 9.2%, nickel powder: 3.8%, aluminium powder: 2.7%, auxiliary agent: 1.5%, rare earth: 1.5%, talcum powder: 3.8%, surplus is clay;
The component of rare earth is by mass percentage: praseodymium: 8.8%, thulium: 12.5%, lutetium: 7.6%, neodymium: 15.8%, promethium: 3.5%, samarium: 7.5%, europium: 1.5%, terbium: 7.5%, and surplus is holmium and inevitable impurity;
The component of auxiliary agent is counted by weight: talcum powder: 12 parts, quartz: 5 parts, kaolinite: 8 parts, deionized water: 25 parts, bortz powder: 10 parts, titanium dioxide: 7 parts, clay: 15 parts;
The preparation method of auxiliary agent is: by talcum powder, quartz and kaolinite co-grinding, cross 40 mesh sieves, obtain powders A, then bortz powder, clay and titanium dioxide co-grinding, cross 70 mesh sieves, obtain powder B, powders A and powder B are uniformly mixed with the ratio of 4:3, stir 10 minutes, then add deionized water and stirring and react 35 minutes, then filter, dry, pulverize, cross 100 mesh sieves, under helium atmosphere, calcine after 3 hours at being heated to 920 DEG C, air cooling, to room temperature, is then pulverized, cross 120 mesh sieves, can auxiliary agent be obtained.
The present embodiment also provides the preparation method of the fire resistant special type pottery containing tourmalinite, and concrete preparation method is as follows:
Step (1): phyllite, calcium oxide, tourmalinite and zinc oxide are mixed, then put into ball mill abrasive dust, cross 40 mesh sieves, then Manganse Dioxide, purple clay, kaolin and rutile to be sent in ball mill ball milling 10 hours, then temperature is increased to 630 DEG C, be incubated 3 hours, and then add auxiliary agent, rare earth, talcum powder and clay, and temperature is increased to 880 DEG C, calcine 4 hours, then be milled to powder, cross 100 mesh sieves, obtain powder particle A;
Step (2): by powder particle A using nitrogen as shielding gas, calcine 3 hours at 965 DEG C, then air cooling is to room temperature, sends into ball mill abrasive dust, crosses 120 mesh sieves, obtains powder particle B;
Step (3): the powder particle B that nickel powder, aluminium powder and step (2) obtain is mixed and stirred, is heated to 1020 DEG C, and calcines 3 hours, pulverizes, and crosses 120 mesh sieves, obtains powder particle C;
Step (4): the powder particle C obtain step (3) and water are in the ratio ball milling 18 hours of 2.4:2, and then moulding, in the atmosphere of helium, 840 DEG C of temperature lower calcinations 5 hours, again temperature is increased to 1180 DEG C, be incubated 3 hours, last air cooling is to room temperature.
embodiment 3
A kind of pottery of the fire resistant special type containing tourmalinite that the present embodiment provides, should be containing the component of the fire resistant special type pottery of tourmalinite: phyllite: 3.7%, calcium oxide: 2.7% by mass percentage, tourmalinite: 12.7%, zinc oxide: 3.3%, Manganse Dioxide: 1.7%, purple clay: 5.7%, kaolin: 11.7%, rutile: 8.7%, nickel powder: 3.7%, aluminium powder: 2.6%, auxiliary agent: 1.4%, rare earth: 1.4%, talcum powder: 3.7%, surplus is clay;
The component of rare earth is by mass percentage: praseodymium: 8.7%, thulium: 12.4%, lutetium: 7.5%, neodymium: 15.7%, promethium: 3.4%, samarium: 7.4%, europium: 1.4%, terbium: 7.4%, and surplus is holmium and inevitable impurity;
The component of auxiliary agent is counted by weight: talcum powder: 9 parts, quartz: 4 parts, kaolinite: 7 parts, deionized water: 22 parts, bortz powder: 9 parts, titanium dioxide: 5 parts, clay: 14 parts;
The preparation method of auxiliary agent is: by talcum powder, quartz and kaolinite co-grinding, cross 40 mesh sieves, obtain powders A, then bortz powder, clay and titanium dioxide co-grinding, cross 70 mesh sieves, obtain powder B, powders A and powder B are uniformly mixed with the ratio of 4:3, stir 10 minutes, then add deionized water and stirring and react 35 minutes, then filter, dry, pulverize, cross 100 mesh sieves, under helium atmosphere, calcine after 2 hours at being heated to 910 DEG C, air cooling, to room temperature, is then pulverized, cross 120 mesh sieves, can auxiliary agent be obtained.
The present embodiment also provides the preparation method of the fire resistant special type pottery containing tourmalinite, and concrete preparation method is as follows:
Step (1): phyllite, calcium oxide, tourmalinite and zinc oxide are mixed, then put into ball mill abrasive dust, cross 40 mesh sieves, then Manganse Dioxide, purple clay, kaolin and rutile to be sent in ball mill ball milling 9 hours, then temperature is increased to 625 DEG C, be incubated 2 hours, and then add auxiliary agent, rare earth, talcum powder and clay, and temperature is increased to 878 DEG C, calcine 3 hours, then be milled to powder, cross 100 mesh sieves, obtain powder particle A;
Step (2): by powder particle A using nitrogen as shielding gas, calcine 2 hours at 962 DEG C, then air cooling is to room temperature, sends into ball mill abrasive dust, crosses 120 mesh sieves, obtains powder particle B;
Step (3): the powder particle B that nickel powder, aluminium powder and step (2) obtain is mixed and stirred, is heated to 1015 DEG C, and calcines 2 hours, pulverizes, and crosses 120 mesh sieves, obtains powder particle C;
Step (4): the powder particle C obtain step (3) and water are in the ratio ball milling 17 hours of 2.4:2, and then moulding, in the atmosphere of helium, 837 DEG C of temperature lower calcinations 4 hours, again temperature is increased to 1178 DEG C, be incubated 2.6 hours, last air cooling is to room temperature.
The pottery manufactured in above embodiment not only intensity is high, good toughness, and vibration resistance is heat-resisting, corrosion-resistant, smooth surface, and outward appearance is good, and cost is low, long service life, and provides its preparation method, and method is simple, and improve the quality of products, production efficiency is high.
Above embodiment is only and technological thought of the present invention is described, can not limit protection scope of the present invention with this, and every technological thought proposed according to the present invention, any change that technical scheme basis is done, all falls within scope.
Claims (5)
1. the pottery of the fire resistant special type containing tourmalinite, it is characterized in that: should be by mass percentage containing the component of the fire resistant special type pottery of tourmalinite: phyllite: 3.6-3.8%, calcium oxide: 2.5-2.8%, tourmalinite: 12.5-12.8%, zinc oxide: 3.2-3.5%, Manganse Dioxide: 1.5-1.8%, purple clay: 5.6-5.8%, kaolin: 11.5-11.8%, rutile: 8.5-9.2%, nickel powder: 3.6-3.8%, aluminium powder: 2.5-2.7%, auxiliary agent: 1.2-1.5%, rare earth: 1.2-1.5%, talcum powder: 3.5-3.8%, surplus is clay;
The component of described rare earth is by mass percentage: praseodymium: 8.5-8.8%, thulium: 12.2-12.5%, lutetium: 7.4-7.6%, neodymium: 15.4-15.8%, promethium: 3.3-3.5%, samarium: 7.2-7.5%, europium: 1.2-1.5%, terbium: 7.2-7.5%, surplus is holmium and inevitable impurity;
The component of described auxiliary agent is counted by weight: talcum powder: 8-12 part, quartz: 3-5 part, kaolinite: 6-8 part, deionized water: 20-25 part, bortz powder: 8-10 part, titanium dioxide: 2-7 part, clay: 12-15 part;
The preparation method of described auxiliary agent is: by talcum powder, quartz and kaolinite co-grinding, cross 40 mesh sieves, obtain powders A, then bortz powder, clay and titanium dioxide co-grinding, cross 70 mesh sieves, obtain powder B, powders A and powder B are uniformly mixed with the ratio of 4:3, stir 10 minutes, then add deionized water and stirring and react 35 minutes, then filter, dry, pulverize, cross 100 mesh sieves, under helium atmosphere, after calcining 2-3 hour at being heated to 900-920 DEG C, air cooling, to room temperature, is then pulverized, cross 120 mesh sieves, can auxiliary agent be obtained.
2. the pottery of the fire resistant special type containing tourmalinite according to claim 1, is characterized in that: should be by mass percentage containing the component of the fire resistant special type pottery of tourmalinite: phyllite: 3.6%, calcium oxide: 2.5%, tourmalinite: 12.5%, zinc oxide: 3.2%, Manganse Dioxide: 1.5%, purple clay: 5.6%, kaolin: 11.5%, rutile: 8.5%, nickel powder: 3.6%, aluminium powder: 2.5%, auxiliary agent: 1.2%, rare earth: 1.2%, talcum powder: 3.5%, surplus is clay;
The component of described rare earth is by mass percentage: praseodymium: 8.5%, thulium: 12.2%, lutetium: 7.4%, neodymium: 15.4%, promethium: 3.3%, samarium: 7.2%, europium: 1.2%, terbium: 7.2%, and surplus is holmium and inevitable impurity;
The component of described auxiliary agent is counted by weight: talcum powder: 8 parts, quartz: 3 parts, kaolinite: 6 parts, deionized water: 20 parts, bortz powder: 8 parts, titanium dioxide: 2 parts, clay: 12 parts;
The preparation method of described auxiliary agent is: by talcum powder, quartz and kaolinite co-grinding, cross 40 mesh sieves, obtain powders A, then bortz powder, clay and titanium dioxide co-grinding, cross 70 mesh sieves, obtain powder B, powders A and powder B are uniformly mixed with the ratio of 4:3, stir 10 minutes, then add deionized water and stirring and react 35 minutes, then filter, dry, pulverize, cross 100 mesh sieves, under helium atmosphere, calcine after 2 hours at being heated to 900 DEG C, air cooling, to room temperature, is then pulverized, cross 120 mesh sieves, can auxiliary agent be obtained.
3. the pottery of the fire resistant special type containing tourmalinite according to claim 1, is characterized in that: should be by mass percentage containing the component of the fire resistant special type pottery of tourmalinite: phyllite: 3.8%, calcium oxide: 2.8%, tourmalinite: 12.8%, zinc oxide: 3.5%, Manganse Dioxide: 1.8%, purple clay: 5.8%, kaolin: 11.8%, rutile: 9.2%, nickel powder: 3.8%, aluminium powder: 2.7%, auxiliary agent: 1.5%, rare earth: 1.5%, talcum powder: 3.8%, surplus is clay;
The component of described rare earth is by mass percentage: praseodymium: 8.8%, thulium: 12.5%, lutetium: 7.6%, neodymium: 15.8%, promethium: 3.5%, samarium: 7.5%, europium: 1.5%, terbium: 7.5%, and surplus is holmium and inevitable impurity;
The component of described auxiliary agent is counted by weight: talcum powder: 12 parts, quartz: 5 parts, kaolinite: 8 parts, deionized water: 25 parts, bortz powder: 10 parts, titanium dioxide: 7 parts, clay: 15 parts;
The preparation method of described auxiliary agent is: by talcum powder, quartz and kaolinite co-grinding, cross 40 mesh sieves, obtain powders A, then bortz powder, clay and titanium dioxide co-grinding, cross 70 mesh sieves, obtain powder B, powders A and powder B are uniformly mixed with the ratio of 4:3, stir 10 minutes, then add deionized water and stirring and react 35 minutes, then filter, dry, pulverize, cross 100 mesh sieves, under helium atmosphere, calcine after 3 hours at being heated to 920 DEG C, air cooling, to room temperature, is then pulverized, cross 120 mesh sieves, can auxiliary agent be obtained.
4. the pottery of the fire resistant special type containing tourmalinite according to claim 1, is characterized in that: should be by mass percentage containing the component of the fire resistant special type pottery of tourmalinite: phyllite: 3.7%, calcium oxide: 2.7%, tourmalinite: 12.7%, zinc oxide: 3.3%, Manganse Dioxide: 1.7%, purple clay: 5.7%, kaolin: 11.7%, rutile: 8.7%, nickel powder: 3.7%, aluminium powder: 2.6%, auxiliary agent: 1.4%, rare earth: 1.4%, talcum powder: 3.7%, surplus is clay;
The component of described rare earth is by mass percentage: praseodymium: 8.7%, thulium: 12.4%, lutetium: 7.5%, neodymium: 15.7%, promethium: 3.4%, samarium: 7.4%, europium: 1.4%, terbium: 7.4%, and surplus is holmium and inevitable impurity;
The component of described auxiliary agent is counted by weight: talcum powder: 9 parts, quartz: 4 parts, kaolinite: 7 parts, deionized water: 22 parts, bortz powder: 9 parts, titanium dioxide: 5 parts, clay: 14 parts;
The preparation method of described auxiliary agent is: by talcum powder, quartz and kaolinite co-grinding, cross 40 mesh sieves, obtain powders A, then bortz powder, clay and titanium dioxide co-grinding, cross 70 mesh sieves, obtain powder B, powders A and powder B are uniformly mixed with the ratio of 4:3, stir 10 minutes, then add deionized water and stirring and react 35 minutes, then filter, dry, pulverize, cross 100 mesh sieves, under helium atmosphere, calcine after 2 hours at being heated to 910 DEG C, air cooling, to room temperature, is then pulverized, cross 120 mesh sieves, can auxiliary agent be obtained.
5., containing a preparation method for the fire resistant special type pottery of tourmalinite, it is characterized in that, concrete preparation method is as follows:
Step (1): phyllite, calcium oxide, tourmalinite and zinc oxide are mixed, then put into ball mill abrasive dust, cross 40 mesh sieves, then Manganse Dioxide, purple clay, kaolin and rutile are sent into ball milling 8-10 hour in ball mill, then temperature is increased to 620-630 DEG C, insulation 1-3 hour, and then add auxiliary agent, rare earth, talcum powder and clay, and temperature is increased to 870-880 DEG C, calcining 2-4 hour, then be milled to powder, cross 100 mesh sieves, obtain powder particle A;
Step (2): by powder particle A using nitrogen as shielding gas, at 960-965 DEG C, calcine 1-3 hour, then air cooling is to room temperature, sends into ball mill abrasive dust, crosses 120 mesh sieves, obtains powder particle B;
Step (3): the powder particle B that nickel powder, aluminium powder and step (2) obtain is mixed and stirred, is heated to 1010-1020 DEG C, and calcines 1-3 hour, pulverizes, and crosses 120 mesh sieves, obtains powder particle C;
Step (4): the powder particle C obtain step (3) and water are in the ratio ball milling 15-18 hour of 2.4:2, and then moulding, in the atmosphere of helium, at 830-840 DEG C of temperature lower calcination 3-5 hour, again temperature is increased to 1170-1180 DEG C, insulation 2-3 hour, last air cooling is to room temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510203104.7A CN104891956A (en) | 2015-04-27 | 2015-04-27 | Tourmaline-containing high temperature resistant special ceramic and preparation method thereof |
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| CN201510203104.7A CN104891956A (en) | 2015-04-27 | 2015-04-27 | Tourmaline-containing high temperature resistant special ceramic and preparation method thereof |
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| CN105244828A (en) * | 2015-11-10 | 2016-01-13 | 鼎圣电气有限公司 | Low-voltage busway with rapid cooling function |
| CN105244829A (en) * | 2015-11-10 | 2016-01-13 | 鼎圣电气有限公司 | Low-voltage busway with rapid radiating function |
| CN105384425A (en) * | 2015-11-13 | 2016-03-09 | 江苏宇恒电气有限公司 | High-strength coating applied to surface of low-voltage bus duct |
| CN105420582A (en) * | 2015-12-04 | 2016-03-23 | 苏州市神龙门窗有限公司 | Ceramic coating wrapping aluminum alloy door window and heat treatment process of coating |
| CN105670925A (en) * | 2016-03-11 | 2016-06-15 | 江苏明昌生物科技有限公司 | Intelligent photosynthetic bacterium fermentation device for aquaculture |
| CN106587917A (en) * | 2016-12-14 | 2017-04-26 | 苏州纽东精密制造科技有限公司 | Decorative ceramic for automotive trims |
| CN106699115A (en) * | 2016-12-14 | 2017-05-24 | 苏州纽东精密制造科技有限公司 | Abrasion-resisting decorative ceramic for automotive interior decoration |
| CN111700299A (en) * | 2020-06-28 | 2020-09-25 | 潮州市泥香陶瓷新材料有限公司 | High-quality tobacco alcoholization equipment and use method thereof |
| CN113764682A (en) * | 2021-09-11 | 2021-12-07 | 东莞理工学院 | SMFC (surface Mount fiber channel) mangano-manganic oxide/tourmaline composite cathode and preparation method thereof |
| CN115073146A (en) * | 2022-06-10 | 2022-09-20 | 贵州群华九九特种陶瓷科技有限公司 | Ceramic capable of releasing negative oxygen ions, preparation method thereof and tea set |
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| CN105244828A (en) * | 2015-11-10 | 2016-01-13 | 鼎圣电气有限公司 | Low-voltage busway with rapid cooling function |
| CN105244829A (en) * | 2015-11-10 | 2016-01-13 | 鼎圣电气有限公司 | Low-voltage busway with rapid radiating function |
| CN105384425A (en) * | 2015-11-13 | 2016-03-09 | 江苏宇恒电气有限公司 | High-strength coating applied to surface of low-voltage bus duct |
| CN105420582A (en) * | 2015-12-04 | 2016-03-23 | 苏州市神龙门窗有限公司 | Ceramic coating wrapping aluminum alloy door window and heat treatment process of coating |
| CN105670925A (en) * | 2016-03-11 | 2016-06-15 | 江苏明昌生物科技有限公司 | Intelligent photosynthetic bacterium fermentation device for aquaculture |
| CN106587917A (en) * | 2016-12-14 | 2017-04-26 | 苏州纽东精密制造科技有限公司 | Decorative ceramic for automotive trims |
| CN106699115A (en) * | 2016-12-14 | 2017-05-24 | 苏州纽东精密制造科技有限公司 | Abrasion-resisting decorative ceramic for automotive interior decoration |
| CN111700299A (en) * | 2020-06-28 | 2020-09-25 | 潮州市泥香陶瓷新材料有限公司 | High-quality tobacco alcoholization equipment and use method thereof |
| CN113764682A (en) * | 2021-09-11 | 2021-12-07 | 东莞理工学院 | SMFC (surface Mount fiber channel) mangano-manganic oxide/tourmaline composite cathode and preparation method thereof |
| CN115073146A (en) * | 2022-06-10 | 2022-09-20 | 贵州群华九九特种陶瓷科技有限公司 | Ceramic capable of releasing negative oxygen ions, preparation method thereof and tea set |
| CN115073146B (en) * | 2022-06-10 | 2023-08-22 | 贵州群华九九特种陶瓷科技有限公司 | Ceramic capable of releasing negative oxygen ions, preparation method thereof and tea set |
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