Invention content
The object of the present invention is to provide:A kind of gypsum compositions;Gypsum mechanograph, such as building block, especially composite base self-insurance
Warm building block and steel skeleton steel wire (or glass fiber mesh) high-strength light anticracking plasterboard more particularly to steel skeleton steel wire (or
Glass fiber mesh) high-strength light anticracking gypsum lath;And their preparation method.The present invention can improve heat insulation building block
Heat-insulating property, guarantee are laid bricks intensity, water-fast, and freeze proof impermeability is good and light-weight, the gas in all directions of building block or plank
The Density Distribution uniform in size and bubble of bubble or abscess is uniform.
The present inventor by a large amount of experiment, attempted a large amount of inorganic raw material for example kaolin, bentonite, sepiolite,
Float stone, perlite etc. carry out formula design, overcome still unsatisfactoryly in the patent that the present inventor had previously applied
The defect (i.e. the non-uniformity problem of bubble or the non-uniformity problem of density) of disclosed building block product.Then it attempts to use
Organic material to seek to break through, as a result surprisingly, it is found that, by the disclosed concrete material before the present inventor
Elastomer powder or elastomer particles (or, rubber powder or rubber grain) is further used to be used as additive or auxiliary agent, not only significantly
The uniformity of the uniform in size and distribution density of bubble or abscess in building block is improved, and improves the even density of bubble
Property, collapse is significantly reduced, the inner skeleton structure of building block is changed, same intensity is being realized compared with disclosed building block before this
In the case of further mitigate weight (density of building block) or realized under same building block weight (density of building block) higher
Intensity, in addition, further improving heat-insulating property and anti-freezing property.At the same time, other performance such as water resistance or anti-is not influenced
Softening performance.Adding elastomer powder or in the case of rubber powder, or even foaming agent is not added can obtain high intensity and matter yet
Light building block (or laying bricks).It is further preferred that in formula further addition selected from inorganic short fiber reinforced material and organic
As filler or additive, rubber powder is combined short fiber reinforced material in short fiber reinforced material with reinforcing fiber, can
Intensity is not only improved, but also the proportion or density (or making dry density) of mechanograph (such as building block or plank) can be further improved
Uniformity;Organic flock is especially added in formula, further mitigates quality, improves the effect of the uniformity of mechanograph
Fruit can be more preferable.
According to the first embodiment of the present invention, a kind of gypsum compositions for building (A) are provided, it includes with the following group
Point:
Semi-hydrated gypsum:210-580 parts by weight, preferably 250-540 part, more preferable 270-510 parts by weight;
Portland cement:75-280 parts by weight, preferably 100-250 part, more preferable 120-230 parts by weight;
Flyash:80-380 parts by weight, 110-360 parts by weight, preferably 130-340 part, more preferable 150-320 parts by weight,
More preferable 170-300 parts by weight;
Elastomer powder:5-100 parts by weight, preferably 7-90 parts by weight, more preferable 10-80 parts by weight, further preferred 12-
70 parts by weight, still further preferred 15-60 parts by weight, more preferable 20-50 parts by weight;
Water-reducing agent:
1.5-40 parts by weight, preferably 4-30 parts by weight, more preferable 6-20 parts by weight, more preferable 8-16 parts by weight
Foaming agent:
0 parts by weight or 0.1-30 parts by weight, preferably 0.25-28 parts by weight, preferably 0.4-22 parts by weight, more preferable 0.45-
12 parts by weight, further preferred 0.5-7 parts by weight, still further preferably 0.55-6 parts by weight, preferably 0.60-4 parts by weight are more excellent
0.65-3.0 parts by weight are selected, it is 0.7-1.8 parts more preferable;With
Water:In right amount
Wherein (i.e. described is appropriate, such as 750-1300 parts by weight, such as 850-1200 parts by weight or 900- for the dosage of water
1100 parts by weight) the above above-mentioned raw materials component in addition to water should be made to be formed by mixture (i.e. concrete, or slurry with water
Material) wet density within the scope of 1.4-1.85 tons/cubic meter, preferably within the scope of 1.5-1.75 tons/cubic meter, preferably exist
Within the scope of 1.55-1.70 tons/cubic meter, preferably within the scope of 1.6-1.65 tons/cubic meter.
Preferably, above-mentioned composition further includes:
Short fiber reinforced material 10-200 parts by weight, preferably 30-170 parts by weight, further preferred 50-150 parts by weight, into
The preferred 60-130 parts by weight of one step, more preferable 70-110 parts by weight, still more preferable 80-100 parts by weight.
Here the average length of short fiber reinforced material is 100um (micron) -5.0mm, preferably 150um-4.0mm, more
It is preferred that 200um-3.0mm, still further 250um-2.0mm, more preferable 300um-1.5mm, still more preferable 350um-
1.0mm, more preferable 400um-800um.
Staple fiber plays a part of cloth muscle and reduces micro-crack.Generally, short fiber reinforced material is selected from inorganic staple fiber
Reinforcing material and organic short fiber reinforcing material.From mitigate quality and improve mechanograph so-called uniformity consider, it is preferable to use
Organic short fiber reinforcing material.Preferably, organic short fiber reinforcing material is selected from plant fiber or synthetic polymer staple fiber.
Wherein, plant fiber is selected from lignocellulosic, wood powder, flaxen fiber (powder), palm fibre (powder) or other similar plant fibers.
The synthetic polymer staple fiber is selected from polyamide, polyester etc., more preferably using the polyamides of the waste of polymeric fiber of recycling such as recycling
Amine or polyester.These staple fibers have average length defined above.
It is further preferred that above-mentioned composition further includes:
SILICA FUME 10-300 parts by weight, preferably 20-250 parts by weight, further preferred 30-200 parts by weight, further preferably
35-150 parts by weight, more preferable 40-120 parts by weight, still more preferable 50-80 parts by weight.
It is further preferred that above-mentioned composition further includes:
Antifreezing agent 1-100 parts by weight, preferably 3-80 parts by weight, more preferable 5-60 parts by weight, further preferred 7-50 weight
Part, it is still preferred that 8-40 parts by weight, most preferably 9-20 parts by weight, still further preferably 8-12 parts.
The average particle size that the elastomer powder or elastomer particles (or, rubber powder or rubber grain) used in application has
For:1.25um to 600um, preferably 1.5um to 550um, preferably 5um to 500um, further preferred 8um to 450um, more preferably
12um to 420um, still more preferable 15um to 400um, preferably 20um to 380um, particularly preferred 25um to 350um, more preferably
30um to 320um, more preferable 40um to 280um, more preferable 50um to 250um, such as 100um, 150um, 200um.
Above-mentioned composition can be used to form gypsum mechanograph (B):Such as gypsum block or lay bricks, as composite base self-heat conserving is built
Block is laid bricks;Or such as gypsum sheet material, such as steel skeleton steel wire (or glass fiber mesh) high-strength light anticracking gypsum lath.The stone
Cream mechanograph (such as building block lay bricks or plank) be after being mixed by the composition pour into a mould and harden and it is molding.More
It says to body, it is to be poured into a mould and hardened after being mixed with water by the raw material components in composition in addition to water and molding.Usually
Cast and hardening in mold (or mould tire).The mechanograph (such as building block) be rendered as cuboid, the square bodily form, cylindrical,
(it includes tri-prismoid, four prisms cylinder, pentagonal prism body, hexagonal prism, seven prisms, eight prisms, nine prisms to the prism bodily form
Body, ten prisms, etc.).The mechanograph can also be rendered as the form of plank, such as rectangular item is presented in two principal planes
The square plank of square is presented in plank or two principal planes.Both planks are also referred to as the building block of broad sense.Size is less
Building block can be rendered as the form of laying bricks, and larger-size building block can be rendered as broad form.
Therefore, according to the second embodiment of the present invention, a kind of building block (B) is provided, such as gypsum block or is laid bricks, such as
Composite base heat insulation building block is laid bricks;The building block is cast (such as pouring into a mould in a mold) after being mixed by above-mentioned composition
With hardening and it is molding.More specifically, which is that the above-mentioned raw materials component by water with more than in addition to water is mixed
It is molding with being then poured into mold and hardening.
In the present invention, the wet density (i.e. the ratio of mud) for limiting mixture (or concrete) is in order to ensure taking into account molding
The Lightness and high intensity of product.By exploring, the rational ratio of mud requires the wet density of each cubic meter of concrete in 1.4-
Within the scope of 1.85 tons/cubic metre.Excessive water is added, and mechanograph (such as building block) intensity will be made to significantly reduce, and very few water is added,
Mechanograph can not ensure Lightness requirement.
" elastomer " is used interchangeably with " rubber " in this application.
There is no particular/special requirement, elastomer described here for the type of elastomer powder or rubber powder used herein
It is the upperseat concept of rubber.That is, should " elastomer " refer to synthesis rubber (such as butadiene rubber, isoprene rubber,
EP rubbers, butyl rubber etc.), synthetic elastomer (such as polyurethane elastomer) or natural rubber and its mixture.From cost
Consider, it is preferred that elastomer powder selects the particulate matter or powder of scrap rubber or useless elastomer.For example, rubber powder is from waste and old wheel
The scrap rubber of tire is process.Alternatively, rubber powder from rubber or tyre production leftover pieces or waste material prepare.Or rubber powder
It is process from the scrap rubber of waste and old daily necessities.
In general, in the said combination composition formula of the present invention, be more than when the additive amount of elastomer powder or rubber powder or
When equal to 10 parts by weight, foaming agent can be added or not add even, and when the additive amount of elastomer powder or rubber powder is in 5-10 weights
When measuring within the scope of part, it is necessary to add foaming agent and can be only achieved ideal Lightness wanted with what ideal intensity was taken into account simultaneously
It asks, preferably adds the foaming agent of 0.25-28 parts by weight.In addition, when addition more than or equal to 5 parts by weight elastomer powder or
When rubber powder, preferable antifreezing effect can be also obtained in the case where not adding antifreezing agent, and works as elastomer powder or rubber powder
Additive amount be greater than or equal to 10 parts by weight when, ideal antifreezing effect can be obtained in the case where not adding antifreezing agent.Such as
Fruit needs, and can not only reduce the dosage of foaming agent by adding elastomer powder or rubber powder, therefore reduce foaming agent for mould
The influence of certain performances of product (such as building block), and the dosage of flyash can be reduced, if such as using 1 parts by weight elasticity
Body powder or rubber powder can then reduce the flyash dosage of (or corresponding to) 5-7 parts by weight (such as 6 parts by weight).
According to the third embodiment the present invention, it provides a kind of from above-mentioned gypsum compositions preparation building block for building
(B) method, this method include:The formula of composition according to the invention, by water and other raw material components (examples in addition to water
Such as it is added in mixing arrangement or equipment) it is stirred mixing, gained mixture is cast in die for molding and hardens one section
It time (such as 2-10 minutes), then demoulds and obtains building block, i.e.,:
In mixing apparatus water (i.e. described is appropriate, such as 750-1300 parts by weight, such as 850-1200 parts by weight, or
The water-reducing agent and foaming agent of above-mentioned dosage are added in 900-1100), semi-hydrated gypsum, the silicate of above-mentioned dosage is then added
Cement, flyash and elastomer powder, stirring, cast (such as being poured into mold) are molded and make its hardening, then demould, obtain
The mechanograph;
Wherein the dosage of water should make above-mentioned raw materials and water be formed by the wet density of mixture 1.4-1.85 ton/stand
Within the scope of square rice, preferably within the scope of 1.5-1.75 tons/cubic meter, preferably within the scope of 1.55-1.70 tons/cubic meter, preferably
Within the scope of 1.6-1.65 tons/cubic meter.
Preferably, the short fiber reinforced material of above-mentioned dosage is also added before stirring.
In the above-mentioned methods, it is preferred that also add the SILICA FUME of above-mentioned dosage before stirring.
In the above-mentioned methods, it is preferred that also add the antifreezing agent of above-mentioned dosage before stirring.
Preferably, drying or natural curing are further carried out after the hardening, obtain building block of the present invention (B),
Such as composite base heat insulation building block.
4th embodiment according to the present invention provides a kind of from above-mentioned gypsum compositions (A) preparation for building
Steel skeleton plaster mold panel (C), wherein plank (C) is that rectangular plank is presented in opposite two principal planes (a and b)
(such as the high-strength anticracking gypsum lath of steel skeleton steel wire net light or steel skeleton glass fiber mesh high-strength light anticracking plaster strip
Plate) or opposite two principal planes (a and b) square plank (such as the high-strength anticracking of steel skeleton steel wire net light of square is presented
Gypsum pros plank or steel skeleton glass fiber mesh high-strength light anticracking gypsum pros plank), it is through the following steps that prepare
's:(1) prefabricated three-dimensional steel skeleton is put into plate forming mold (or mould tire), (2) are each by above-mentioned composition (A)
A component is stirred mixing (such as be added in mixer and be stirred mixing), obtains slurry or wet mixture;Then
(3) gained slurry or wet mixture are poured into above-mentioned mold and allow slurry hardening a period of time (such as 2-10 minutes or 3-6
Minute or 3-5 minutes), it then demoulds, obtains steel skeleton plaster mold panel (C) product.
5th embodiment according to the present invention provides a kind of from above-mentioned gypsum compositions (A) preparation for building
The method of steel skeleton plaster mold panel (C), wherein plank (C) are that rectangular item is presented in opposite two principal planes (a and b)
Plank (such as the high-strength anticracking gypsum lath of steel skeleton steel wire net light or steel skeleton glass fiber mesh high-strength light anticracking gypsum
Batten) or opposite two principal planes (a and b) the square plank of square is presented (such as steel skeleton steel wire net light is high-strength anti-
Split gypsum pros plank or steel skeleton glass fiber mesh high-strength light anticracking gypsum pros plank), this method includes following step
Suddenly:(1) prefabricated three-dimensional steel skeleton is put into plate forming mold (or mould tire), (2) are by each of above-mentioned composition
Component, which is added in mixer, to be stirred, and slurry or wet mixture are obtained;(3) gained slurry or wet mixture are poured into
It placed in the above-mentioned mold of steel skeleton and allow slurry hardening a period of time (such as 2-10 minutes or 3-6 minutes or 3-5 minutes),
(4) it demoulds, obtains steel skeleton plaster mold panel (C) product.
When the addition elastomer powder (or rubber powder) in composition (A) and short fiber reinforced material, molding can be improved
The intensity of product, while by elastomer powder (or rubber powder) relaxation plank internal stress being conducive to that plate surface generation is avoided to split
Line.
6th embodiment according to the present invention provides the reinforcing bar prepared from a kind of gypsum compositions for building (A ')
Frame plaster mold panel (C '), the composition (A ') include:
Semi-hydrated gypsum 210-580 parts by weight, preferably 250-540 parts, more preferable 270-510 parts by weight;
Portland cement 75-280 parts by weight, preferably 100-250 parts, more preferable 120-230 parts by weight;
Flyash 110-380 parts by weight, preferably 150-340 parts, more preferable 170-320 parts by weight;
Water-reducing agent
1.5-40 parts by weight, preferably 4-30 parts by weight, more preferable 6-20 parts by weight, more preferable 8-16 parts by weight
Foaming agent
0.25-28 parts by weight, preferably 0.4-22 parts by weight, more preferable 0.45-12 parts by weight, further preferred 0.5-7 weights
Amount part, still further preferably 0.55-6 parts by weight, preferably 0.60-4 parts by weight, more preferable 0.65-3.0 parts by weight, more preferably
0.7-1.8 parts;With
Water:In right amount
The dosage (i.e. described is appropriate, such as 750-1200 parts by weight, such as 850-1000 parts by weight) of wherein water should make
It obtains the above above-mentioned raw materials component in addition to water and is formed by the wet density of mixture (i.e. concrete or slurry) in 1.4- with water
Within the scope of 1.85 tons/cubic metre, preferably within the scope of 1.5-1.75 tons/cubic meter, preferably in 1.55-1.70 tons/cubic meter model
In enclosing, preferably within the scope of 1.6-1.65 tons/cubic meter;
Wherein plank (C ') is that rectangular plank (such as steel skeleton steel wire is presented in opposite two principal planes (a and b)
Net (or glass fiber mesh) high-strength light anticracking gypsum lath) or opposite two principal planes (a and b) presentation squares are just
Square plate material, it through the following steps that prepare:(1) prefabricated three-dimensional steel skeleton is put into plate forming mold (or mould
Tire) in, each component of above-mentioned composition (A ') is added in mixer by (2) to be stirred, and slurry or wet mixture are obtained;
(3) gained slurry or wet mixture are poured into above-mentioned mold and allow slurry hardening a period of time (such as 2-10 minutes or 3-6
Minute or 3-5 minutes), and (4) demoulding, obtain steel skeleton plaster mold panel (C ') product.
Preferably, above-mentioned composition (A ') further includes:
Above-described short fiber reinforced material:10-200 parts by weight, preferably 30-170 parts by weight, further preferred 50-
150 parts by weight, further preferred 60-130 parts by weight, more preferable 70-110 parts by weight, still more preferable 80-100 parts by weight.
When the addition short fiber reinforced material in composition (A '), the intensity of plank (C ') can be improved, while one
Determine to advantageously reduce the crackle on the surface plank (C ') in degree.Staple fiber plays a part of cloth muscle and reduces micro-crack.
Preferably, the composition (A ') further includes:SILICA FUME 10-300 parts by weight, preferably 20-250 parts by weight, into one
Walk preferred 30-200 parts by weight, further preferred 35-150 parts by weight, more preferable 40-120 parts by weight, still more preferable 50-80
Parts by weight.
Preferably, the composition (A ') further includes:Antifreezing agent 1-100 parts by weight, preferably 3-80 parts by weight, more preferable 5-
60 parts by weight, further preferred 7-50 parts by weight, it is still preferred that 8-40 parts by weight, most preferably 9-20 parts by weight, further excellent
Select 8-12 parts.
The inventors discovered that among the composite formula range of the present invention, mechanograph (such as building block or plank) is being improved
Intensity and water resistance, anti-freezing property, softening resistant performance etc., the dosage of the SILICA FUME of a parts by weight be equivalent to 4-6 weights
Measure the dosage of the portland cement of part (such as about 5 parts by weight).
There is no particular/special requirement, the prior art for the antifreezing agent used in all embodiments of above and below in the present invention
The middle antifreezing agent used is used equally in the present invention.Such as it is divided into freezing point reduction type and surfactant type, Hunan pioneer's building materials
The XF types antifreezing agent (tripartite confrontation board) of Co., Ltd's production, the model of Shandong Province Accessories during Binzhou Bincheng District Xin Yuan Chemical Co., Ltd.s production
For the antifreezing agent of SC_2008AR or PG-Z type early strength antifreezing agents.The K-15 types of Beijing Huaqian New Technology Co., Ltd.'s production are prevented
Freeze agent (magnificent thousand boards).
The present inventor only adds foaming agent on the basis of CN102432262A and generates a large amount of bubble in building block, hair
The dry density of existing building block can further decrease, and achieve the purpose that quality is lighter, still, intensity, water resistance, the frost resistance of building block
The performances such as energy, softening resistant performance are still unsatisfactory.
A kind of building block is disclosed in 201310524565.5 (CN103553532A) of the present inventor, wherein is not made
In the case of with borax, specific water-reducing agent and specific foaming agent are used cooperatively, can realize ideal reaction condition, and
And lead to the internal structure of mixture and the optimization formed (by obtained after raw material plus water mixing).
Then, the experiment that thousands of times or more are passed through on the basis of CN103553532A, for a large amount of raw material and its use
Amount is selected, and elastomer powder or rubber powder are further used, in obtained mechanograph (such as building block) bubble or abscess
Evenly, the performance of mechanograph further increases, and especially also adds short fiber reinforced material together for size and density (or quantity),
The uniformity for further improving the proportion and density (dry density) of mechanograph, especially when preparing large-sized plank.One
Aspect, the wet density that raw material is formed by mixture (i.e. slurry) with water arrive 1600-1650kg/ cubic metres without stringent control,
It can further expand, even up to 1.4-1.85 tons/square metre range;On the other hand, mechanograph (refers to:Building block or plank
Non-metallic part) dry density (or proportion) 300-1050kg/m can be further reduced to3, it is preferably decreased to 350-
1000kg/m3, more preferably it is reduced to 400-950kg/m3, it is, however, still able to maintain high performance, such as intensity, water resistance,
The performances such as anti-freezing property, softening resistant performance are held at ideal level.
The mechanograph obtained by the embodiments above of the present invention (refers to:The non-metallic part of plank) or building block pressure resistance
Degree is able to maintain that in 5-20Mpa, preferably 6-18Mpa, preferably 7-16Mpa, more preferable 8-14Mpa, more preferable 9-13Mpa, more excellent
Select 10-12Mpa ranges.In addition, the thermal coefficient of mechanograph (such as building block, such as composite base heat insulation building block) is 0.05-0.2
Watt/square metre is spent;Preferably 0.06-0.18 watts/square metre degree, more preferable 0.07-0.16 watts/square metre of degree are more excellent
0.08-0.14 watts/square metre of degree is selected, more preferable 0.085-0.13 watts/square metre is spent, more preferable 0.09-0.12 watts/square
Meter Du.The thermal coefficient of mechanograph can be adjusted according to specific needs.
The mechanograph of the present invention (refers to:The non-metallic part of plank) or the proportion of building block be 300-1050kg/m3, preferably
350-1000kg/m3, preferably 400-950kg/m3, more preferable 450-900kg/m3, more preferable 500-850kg/m3, more preferably
550-800kg/m3, further preferred 600-750kg/m3。
When preparing steel skeleton steel wire gypsum sheet material (mechanograph), mechanograph of the invention (refers to:The non-metal portion of plank
Point) density or dry density can be further decreased, such as in 200-700kg/m3, 300-600kg/m3Or 350-500kg/m3's
Range, although compression strength may be decreased to 8-13.0Mpa, 9-12.5Mpa or 10-12.0Mpa, heat-insulating property is but shown
It writes and improves, such as thermal coefficient is 0.015-0.09 watts/square metre of degree;Preferably 0.02-0.08 watts/square metre degree, more
It is preferred that 0.03-0.075 watts/square metre of degree, more preferable 0.035-0.075 watts/square metre of degree, more preferable 0.04-0.07 watts/
Square metre degree, it is more preferable 0.045-0.065 watts/square metre degree.
In addition, especially also being made together by the way that water-reducing agent and foaming agent to be used cooperatively with elastomer powder in composition (A)
With short fiber reinforced material, or even without using antifreeze, mechanograph that the present invention obtains has good freeze proof
Performance, wherein frost resistance sufficiently achieve:Can resist 20 more than period freeze thawing, preferably 30 more than the period, more preferably above 40
A period, the further preferred freeze thawing more than 50 periods.If adding antifreeze in the feed, can further increase most
The anti-freezing property of finished product building block.
The selection of foaming agent for being used in the above and below embodiment of the present invention is not particularly restricted,
It can use and have those of function of foaming or generate foam foaming agent, such as can generally use surfactant or dioxygen
Water, which is to be selected from anion surfactant, in cationic surfactant and nonionic surfactant
One or two or more.Preferably these surfactants have the function of foaming.As foaming agent, from cost consideration
Or consider from cost performance, it is preferable to use anion surfactant, such as lauryl sodium sulfate or neopelex.
Use surfactant or hydrogen peroxide as foaming agent in the raw material of the present invention, they all have the work(to foam
Energy.The presence of these foaming agents may change the surface tension of paste-like mixture (or wet mixture), enhance material
The ability for shifting (mass transfer) or permeating or spreading each other, allows active material to be filled with the lattice defect in semi-hydrated gypsum or sky
Gap excites the reactivity between various raw materials.The wet mixture (slurry material) that the present invention obtains is after cast through too short
Short 2-3 minutes achieve that initial solidification, can fully be demoulded by 3-8 minutes or 4-7 minutes.So short solidification when
Between so that the invention is particularly suited to large-scale industrial production light gypsum mechanographs, such as building block or such as reinforcing bar
Frame steel wire (or glass fiber mesh) high-strength light anticracking gypsum lath or plank.
Selection for the water-reducing agent used in the above and below embodiment of the present invention, can use and be selected from sulfonation
Melamine formaldehyde polymer resin type(SM)One or both of water-reducing agent, naphthalene water reducer or polycarboxylate water-reducer or
More kinds of (such as three kinds).
Mechanograph of the present invention long-term (such as -5 years 1 month) impregnates not to soften in water.The mechanograph of the present invention
Xuan≤0.8 softening system Shuo≤0.7, You.
Preferably, the semi-hydrated gypsum used in the present invention derives from the phosphorus obtained as waste residue when processing phosphorus ore
Gypsum or industrial residue-desulfurated plaster of thermal power plant.
In this application, the wet density (i.e. the ratio of mud) for limiting mixture (or concrete), is in order to ensure taking into account lightweight
Property and high intensity.By exploring, the rational ratio of mud requires the wet density of each cubic meter of concrete in 1.4-1.85 tons/cube
In rice range.Excessive water is added, and block strength will be made to significantly reduce, and very few water is added, and building block can not ensure Lightness want
It asks.
In any of the above described technical solution of the application, it is preferred that prefabricated three-dimensional steel skeleton is that appearance profile is presented
A kind of three-dimensional steel skeleton of hexahedron, the skeleton have opposite two main planar portions (a ' and b '), the two principal planes
Rectangle or square is presented.Any one principal plane be by with four edges rectangular main frame or with the rectangular of four edges
What steel framework was constituted.At least one of the two main planar portions (a ' and b ') of steel skeleton (such as a ' and/or b ') is by side
The main frame (there is vertical edge S1 and horizontal edge S2) and crosspiece 3 (horizontal bar 3) and/or stud (vertical muscle) of shape and optional diagonal brace
3 (oblique muscle) are constituted, or by rectangular main frame (having vertical edge S1 and horizontal edge S2) and diagonal brace 3 (oblique muscle) and optional cross
3 (horizontal bars) of shelves and/or optional stud 3 (vertical muscle) are constituted, or only (have vertical edge S1 and horizontal edge by rectangular main frame
S2 it) forms.Generally, it can be arranged or be not provided with crosspiece (horizontal bar) and/or stud in the non-master surface portion of three-dimensional steel skeleton
(vertical muscle) and optional diagonal brace (oblique muscle).
In the context of this application, it is " optional " statement be with or without, indicate carry out or without." main frame " with
" steel framework " is used interchangeably.
Preferably, in respectively constitute opposite two main planar portions (a ' and b ') two of prefabricated three-dimensional steel skeleton
Steel wire or glass fibers are laid on the inside of at least one of a main frame (or steel framework) main frame (or steel framework) or inner surface
Tie up net.Generally, any one layer of steel wire or glass fiber mesh clamped by one or more pairs of steel clamp bars (3) or clamp,
And these clamp bars are welded on the inside or side for the rectangular main frame for constituting steel skeleton principal plane a ' or b ', in addition, steel wire
It can also be directly welded on the inside or side of main frame (or steel framework).Generally, as clamp bar (3), using thin round steel
Or band steel, it is preferred to use thin round steel (such as diameter 2-4mm).Therefore, by the mould that placed prefabricated three-dimensional steel skeleton
Pouring gypsum composition in tool, is hardened, and demoulding, has obtained steel skeleton steel wire or glass fiber mesh high-strength light anticracking
Gypsum sheet material (C) product.Wherein steel wire or glass fiber mesh is embedded in two main surfaces of plank and at least one of works as it
It is interior.Clamp bar described here can also be regarded as crosspiece or horizontal bar, or be regarded as diagonal brace or oblique muscle.
In this application, steel wire is not particularly limited, such as 20-100 steel wires can be used, such as 30
Silk, 40,50,60,70 or 80 steel wires are, it is preferable to use 50 and 60 steel wires.
In the steel skeleton of above-described hexahedron, the seamed edge of the hexahedral main frame generally uses angle steel bar
Material, round steel web or band steel web.Preferably, which uses angle steel web.
Constitute two main frames of opposite two main planar portions (a ' and b ') each other by it is multiple (such as 4-16,
6-12) connecting component (7) connects.The connecting component (7) can be, such as:A) have with the steel of main frame it is identical or
The connection of different size and shape steel (such as angle steel, round steel or piece steel), preferably thinner steel bar, b) timber item or
Wooden sheet or b) plastic strip or piece, including engineering plastic material strip or piece.The connection type of connecting component (7) and main frame include but
It is not limited to:1) connecting component is inserted in the casing that is welded on main frame (round, square or three is for example presented in casing tube internal hole section
It is angular) in, optionally it can also further be reinforced to prevent connecting component from set with screw or tenon or snap close piece or bolt or fastener
It is detached from the endoporus of pipe;2) through-hole in connecting component is aligned with the through-hole on main frame, two is fixed using nut and screw
Person;3) connection is soldered to the both ends of steel (especially thinner steel bar) on the corresponding position of two main frames respectively.
Under normal circumstances, the difference between combination of the above object (A) and composition (A ') or the main distinction are that the former uses
Elastomer powder or rubber powder.
When in two main frames in opposite two main planar portions (a ' and b ') of composition of prefabricated three-dimensional steel skeleton
At least one main frame or steel framework inside or inner surface on be laid with steel wire or when glass fiber mesh, although in the above
A kind of gypsum compositions for building (A ') in without using elastomer powder or rubber powder, still, due to from the composition
Steel wire or glass fiber mesh are embedded in the main surface of the steel skeleton plaster mold panel (C ') of preparation, which has very
Good Anti-cracking effect.Moreover, the intensity of plank is significantly improved.
Length and width of the length of dies cavity with wide size slightly larger than steel skeleton, are advisable with just accommodating steel skeleton.It is preferred that
, in molding gypsum sheet material, the main frame of steel skeleton or the four edges of steel framework constitute the four edges of plank.If made
Angle steel is used with the main frame of steel skeleton or the four edges of steel framework, then the angle steel of the four edges of main frame or steel framework constitutes plank
Four seamed edges or four sides for having corner angle.
The mold or mould tire that use in this application are not required particularly, such as can be bimodulus lobeds, it is such as right
Open form.
In the present invention, as three-dimensional steel skeleton, the prefabricated three-dimensional steel skeleton that hexahedron is presented in appearance profile can be commonly used,
The skeleton has opposite two main planar portions (a ' and b ').The skeleton is:
1) rectangular three-dimensional steel skeleton is presented in two opposite principal planes.It is used to form plank.Three-dimensional steel skeleton
Thickness t=3-40cm, preferably t=3.5-30cm, more preferable 4-20cm, such as 8,12,16cm.The length l=of three-dimensional steel skeleton
0.5-7m, preferably l=1.0-5m, more preferable l=1.5-4m, further preferably=2.5-3.5 meters, it is 2.7-3.0 meters more preferable.It is three-dimensional
Width w=0.2-3m of steel skeleton, preferably w=0.3-2.5m, more preferable w=0.4-2.0m, more preferable w=0.45-1.5m, more preferably
W=0.5-1.2m, preferably 0.6-1.0m.
2) the three-dimensional steel skeleton of square is presented in two opposite principal planes.It is used to form square plank.Three-dimensional reinforcing bar
Thickness t=3-40cm of frame, preferably t=3.5-30cm, more preferable 4-20cm, such as 8,12,16cm.The square of three-dimensional steel skeleton
Length of side l=w=0.5-7m of principal plane, preferably l=1.0-5m, more preferable l=1.5-4m, further preferably=2.5-3.5 meters, it is more excellent
Select 2.7-3.0 meters.
In the present invention, plank C or C ' has two main surfaces of a and b.The plank is:
C1:Plank
It is investigated from the principal plane of plank, the length l=0.5-7m of plank, preferably l=1.0-5m, more preferable l=1.5-
4m, further preferably=2.5-3.5 meters, it is 2.7-3.0 meters more preferable.Width w=0.2-3m, the preferably w=0.3-2.5m of plank,
More preferable w=0.4-2.0m, more preferable w=0.45-1.5m, more preferable w=0.5-1.2m, preferably 0.6-1.0m.Plate thickness
(i.e. wall thickness) t=3-40cm, preferably t=3.5-30cm, more preferable 4-20cm, such as 8,12,16cm.
C2:The plank of square is presented in two opposite principal planes
Length of side l=w=0.5-7m of plank principal plane, preferably l=1.0-5m, more preferable l=1.5-4m, further preferably=
2.5-3.5 rice, 2.7-3.0 meters more preferable.Plate thickness (i.e. wall thickness) t=3-40cm, preferably t=3.5-30cm, more preferable 4-
20cm, for example, 8,12,16cm.
In terms of the principal plane of plank mechanograph, the trace of steel wire can be seen or not see, this is embedded depending on steel wire
Depth.
When erectting placement, the three-dimensional steel skeleton of a plank mechanograph is used to form with the main frame for including four edges.
Can also have horizontal bar and/or vertical muscle, or there is diagonal bar, or there is oblique muscle, these oblique muscle construct diamond shape grid.
In casting and constructing, steel skeleton is positioned in mold.Such as the processing for plank:Steel skeleton is positioned over
In mold, wherein vertically, the length and thickness direction of steel skeleton are horizontally oriented the width of steel skeleton.Steel wire
Or glass fiber mesh is located within side.Slurry is poured into a mould from the top of mold or from the top of steel skeleton.
In this application, usually releasing agent is coated in mould inner surface before casting.It is de- for what is used in mold
Mould agent does not have particular/special requirement, and the releasing agent used in the prior art can be used in the present invention, such as SOFT SOAP releasing agent.
In situations where it is preferred, further including in combination of the above object (A) or composition (A '):
Pulverized slag 20-200 parts by weight, preferably 40-150 parts by weight, more preferable 60-120 parts by weight.
Can also include in combination of the above object (A) or composition (A '):
Grain slag powder 20-200 parts by weight, preferably 40-150 parts by weight, more preferable 60-120 parts by weight.
In situations where it is preferred, the plank of the present invention is that have steel skeleton watch box, there is steel wire (or glass fiber mesh) mask,
With a kind of anticracking gypsum sheet material or batten for having appropriate fiber cloth muscle.
7th embodiment according to the present invention provides above-mentioned steel skeleton plaster mold panel (C or C ') as building
The purposes of object interior wall or exterior wall.
When the plank of the present invention is used for interior wall or exterior wall, when particularly for exterior wall, which can be made profiled piece.Make
For profiled piece, which includes window frame or doorframe, or the part (such as half) including window frame or doorframe or the plank are simultaneously
Including window frame and doorframe, or include a part (such as half) and doorframe for window frame simultaneously, or includes window frame and door simultaneously
A part (such as half) for frame.The plank of profiled piece form be by placing a kind of three-dimensional steel skeleton in mold, it is then past
Above-mentioned gypsum compositions are poured into a mould in mold and are hardened and molding, wherein three-dimensional steel skeleton has window frame or doorframe, or there is window
A part (such as half) for frame or a part (such as half) for doorframe or the solid steel skeleton have window frame and door simultaneously
Frame, or there is the part (such as half) and doorframe of window frame simultaneously, or there is the part (such as one including doorframe simultaneously
Half) and window frame.When in use, such as in the building course of building, a part for a window frame and the one of another window frame
Part constitutes a complete window frame each other by welding;Alternatively, one of a part for a doorframe and another doorframe
Divide and constitutes a complete doorframe each other by welding.
When the plank of the present invention is used for exterior wall, two main frames of steel skeleton pass through multiple thinner steel fasteners or wood
Material connector or plastic fastening (such as engineering plastics connector) connect.Connection type is as previously discussed.
In this application, " building block " is used interchangeably with " laying bricks "." antifreeze " is used interchangeably with " antifreezing agent ".
Each component has as follows in mechanograph (such as building block, such as composite base heat insulation building block, or such as plank) of the present invention
Effect and effect:
1) a variety of powders are compound, are conducive to have complementary advantages.After being converted to dihydrate gypsum after semi-hydrated gypsum chance water, due to lattice
Coarse, there are many holes in microstructure, its advantage is that thermal coefficient is low, good heat insulating.But the disadvantage is that water be easy from
Molded article surface is penetrated into, and leads to that mechanograph intensity is low, coefficient of softing is low, frost resistance is poor.To improve the intensity of mechanograph and freeze proof
Property, portland cement and flyash are added in formula, after above-mentioned substance is added, particle enters gypsum gap, and overall structure is made to become
Relatively compact, the water absorption rate decline of mechanograph is obtained, and integral strength improves, and is produced inside mechanograph when intensity resists frost enough
When raw swelling stress, mechanograph shows as frost resistance and greatly improves.The proportion of various formulas is controlled, adjusting that can be different is produced
The intensity and quality of product.
2) water-reducing agent is added in mixed process, can effectively activate the active matter in cement, flyash and SILICA FUME
Matter is conducive to improve its intensity.Water-reducing agent can effectively improve the structure of the formed mechanograph of mixed slurry simultaneously, it is made to become
To densification, intensity higher, the amount that water-reducing agent is added is different, and the structure laid bricks also can be different, and intensity changes correspondingly.
3) foaming substance and rubber powder are added in mixed process, mixed slurry can be promoted to be formed a large amount of mutual indepedent
Microbubble, function in addition to mitigate mechanograph unit weight other than, also can further improve the heat-insulating property of mechanograph.In existing skill
In art, be when conserving dry the evaporation of water by the microscopic bubble gap that occurs.Foaming substance is added, thus it is possible to vary lay bricks
Internal structure can preferably achieve the effect that high intensity and light with lesser amount of water, so as to just solve light weight and
High intensity this to antagonism.The amount of foaming agent is different, and the bubble laid bricks is also different.
Such as using lauryl sodium sulfate as foaming agent:0.1-30 parts by weight;It is preferred that 0.25-28 parts by weight;Into one
Walk preferred 0.3-22 parts by weight;Still further preferably 0.4-16 parts by weight;Still more preferably 0.4-10 parts by weight;Most preferably
0.5-4 parts by weight.If using hydrogen peroxide as foaming agent, during the reaction, the bubble of generation is more uniform, can use more
A small amount of water, and the intensity laid bricks can be improved, dosage is:0.1-30 parts by weight, preferably 0.25-28 parts by weight, preferably
0.4-22 parts by weight, more preferable 0.45-12 parts by weight, further preferred 0.5-7 parts by weight, still further preferably 0.55-6 weight
Part, preferably 0.60-4 parts by weight, more preferable 0.65-3.0 parts by weight are 0.7-1.8 parts more preferable;
4) it is to ensure that Lightness and high intensity, the rational ratio of mud are most important.In the prior art, excessive water adds
Enter, a large amount of foam is will produce during production, while also affecting the proportioning and induration of component, mechanograph will be made
Intensity significantly reduces, and very few water is added, and just must be added to the raw material dry powder more crossed, and mechanograph can not ensure Lightness requirement.
By exploring, reasonably the ratio of mud requires the wet density of each cubic meter of concrete in 1.4-1.85t, preferably 1.45-1.8t into
One step preferred 1.5-1.75t, still further preferably 1.55-1.7t, still more preferably 1.6-1.65t.
5) it is the intensity and frost resistance for improving mechanograph, portland cement and flyash is added in formula, can also be added micro-
Silica flour, after above-mentioned substance is added, particle enters gypsum gap, and overall structure is made to become relatively compact, under the water absorption rate of mechanograph
Drop, and integral strength improve, when intensity enough resists frost when mechanograph inside generate swelling stress when, and rubber powder with have
The addition of machine staple fiber can also eliminate microcosmic internal stress, and mechanograph shows as frost resistance and greatly improves.The addition of SILICA FUME
It can be 10-300 parts;It is preferred that 20-250 parts by weight, further preferred 30-200 parts by weight, further preferred 35-150 weight
Part, still more preferable 40-80 parts by weight;
6) anti-freezing property that antifreezing agent can preferably improve mechanograph or lay bricks is added in mixed process.Control appropriate
The proportion of antifreezing agent processed can improve resistance to frost in the case where not influencing the performance of intensity and lightweight.By exploring, antifreezing agent is added
Amount is 1-100 parts by weight;It is preferred that 3-80 parts by weight, more preferable 5-60 parts by weight, further preferred 7-50 parts by weight, it is still preferred that
8-40 parts by weight, most preferably 9-20 parts by weight;
7) elastomer powder or rubber powder are added before various raw materials are stirred, mix, in particular, addition short fiber reinforced
Material such as lignocellulosic, the two be combined so that when composition is cast in the vertical direction of mechanograph bubble size
Uniformly and the density (quantity) of bubble is also uniform, overcomes slurry bottom defoaming phenomenon when only using foaming agent and significantly lacks
It falls into.The anti-freezing property of mechanograph can also be improved by adding elastomer powder or rubber powder in the composition.Staple fiber plays cloth muscle
Act on and reduced together with elastomer powder the generation of micro-crack.
8) using in the main frame of at least one of opposite two main frames of two main planar portions (a ' and b ') of composition
The prefabricated three-dimensional steel skeleton of steel wire or glass fiber mesh is laid on the inside or inner surface of frame or steel framework, by placed this
Any of the above described a kind of composition of cast in the mold of steel skeleton, can prepare plank mechanograph, and the latter has excellent cracking resistance
Energy and intensity.Web plays a part of the thick crackle of control.
9) plank of the invention has the characteristics that:
(1) in the corner in six faces of gypsum lath, provided with the steel skeleton being welded into angle steel, which mainly has three
Big function:
A) prevent overlapping part from cracking, the overlap joint of conventional gypsum batten overlaps in such a way that birch wedge mutually agrees with, overlapping the slot
Binding material is generally completely different with the material of plate, when there is temperature stress, easily cracks along the both sides of overlapping the slot.Steel is arranged to reinforce
Afterwards, the connection between two plates be steel skeleton to steel skeleton, after mutually drawing close, only need spot welding.
B) prevent from hanging, transport, fill during collide with caused by unfilled corner lack side, make the forming after wall on batten.
C) certifiable quick for installation, after two plate splits, spot welding can position.
(2) it has been laid with steel wire or glass fiber mesh in the inside of steel skeleton, two of gypsum lath can be effectively prevented
Interarea cracks.The probability of cracking declines 90% or more.
(3) lignocellulosic is added in formula, increases the suppleness in plate, further reduce batten cracking can
It can property.
(4) it uses our company to be used for the above-mentioned gypsum compositions formula of heat insulation building block, can reach:
A) enhanced water resistance(Batten test block can long period of soaking in water dissipate do not feel like jelly, coefficient of softing is up to 80% or more.
B) high epistasis(The compression strength of batten test block is up to 10-12Mpa)
C) Lightness, general control dry density is in 800kg/m3Left and right, that is, 72kg/ ㎡ or so.If it is necessary, also controllable
System is in 600kg/m3That is, 54kg/ ㎡ or so.
D) high heat insulating ability, thermal coefficient after testing is in 0.09w/ ㎡ k or so.With good energy-saving effect.
E) solid slab is used, it can be ensured that its soundproof effect is first-class.
F) fire resistance is up to A grades, generally, can adhere at a high temperature of 1200 DEG C 2.5-3 hours.
(5) this product has good suitability for secondary processing(It can cut, can dig, punch not fragmentation).
(6) this product can ensure that house does not damage metope in secondary decoration with preheating embedding line, switch card.
(7) this product absorbs moisture content in dry weather moment releasing moisture content, wet weather, that is, has from work of breathing
Can, so for a kind of environmental walling, this lays the first stone to build green, ecology, livable house.
(8) since two interareas of batten or square plank are extremely bright and clean, it can be coloured directly on mounted metope and be
Decorative pattern processed, plays decorative effect, simplifies indoor secondary renovation process.
(9) the maximum advantage of this product be can Fast Installation, form the built speed to match with industrialized house.
The present invention prevents simple the defects of gypsum crystallization, structure is made to tend to by the microstructure of improvement mechanograph
Densification, meanwhile, and try to allow it there are countless uniform microbubbles, improve its self-heat conserving performance.Seem contradictory two kinds of trend
It is unified in a mixture, makes its heat insulating ability, Lightness, frost resistance, fire resistance and compression strength that can control at one
In the range of meeting high-quality mechanograph performance indicator, successfully solves fine and close and loose critical point, properties of product is made to have approached
It is beautiful.
The preparation method of mechanograph provided by the invention, with chemical gypsums such as trade waste-desulfurated plaster, ardealites or
Semi-hydrated gypsum and cement of the natural gypsum after calcining, flyash etc. are raw material, by adding multiple additives, water mixing are added to stir
Rear moulding by casting is mixed, sintering, the steam curing process of traditional building block (belonging to mechanograph) are eliminated.(such as lightweight is multiple for mechanograph obtained
Close the non-metallic part of base heat insulation building block or above-mentioned gypsum sheet material) light-weight (300-1050kg/m3, preferably 350-
1000kg/m3, preferably 400-950kg/m3, more preferable 450-900kg/m3, more preferable 500-850kg/m3, more preferable 550-
800kg/m3, further preferred 600-750kg/m3), compression strength it is high (in 5-20Mpa, preferably 6-18Mpa, preferably 7-16Mpa,
More preferable 8-14Mpa, more preferable 9-13Mpa, more preferable 10-12Mpa ranges.), frost resistance is good(20 periods can be resisted(According to
GB/T17671-1999《Cement mortar strength test method (ISO methods)》), preferably 25 periods, further preferred 30 periods,
The freeze thawing in still more preferably 40 periods), heat insulation effect is good, and (thermal coefficient is 0.05-0.2 watts/square metre of degree;Preferably
0.06-0.18 watts/square metre of degree, more preferable 0.07-0.16 watts/square metre of degree, more preferable 0.08-0.14 watts/square
Meter Du, more preferable 0.085-0.13 watts/square metre of degree, more preferable 0.09-0.12 watts/square metre of degree.), fire resistance rating
It is high(A grades), water resistance is strong(Can pass through 1 month, preferably 1 year, further preferred 5 years, still further preferably 10 years, more into one
Step preferably 20 years, more preferable 30 years, most preferably 70 years, immersion do not soften in water), and coefficient of softing is high(≤ 0.7, You Xuan≤
0.8, Jin mono- Xuan≤0.9 step You), thus be a kind of excellent building energy conservation materials for wall.