CN104884653B - decorative member - Google Patents
decorative member Download PDFInfo
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- CN104884653B CN104884653B CN201380068735.1A CN201380068735A CN104884653B CN 104884653 B CN104884653 B CN 104884653B CN 201380068735 A CN201380068735 A CN 201380068735A CN 104884653 B CN104884653 B CN 104884653B
- Authority
- CN
- China
- Prior art keywords
- decorative element
- metal
- metallic luster
- surface roughness
- black
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 230000003746 surface roughness Effects 0.000 claims abstract description 26
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000012535 impurity Substances 0.000 claims abstract description 8
- 239000011230 binding agent Substances 0.000 claims abstract description 7
- 229910052751 metal Inorganic materials 0.000 abstract description 35
- 239000002184 metal Substances 0.000 abstract description 35
- 239000002932 luster Substances 0.000 abstract description 28
- 239000011195 cermet Substances 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 description 15
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 7
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 7
- 229910001928 zirconium oxide Inorganic materials 0.000 description 7
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000000956 alloy Substances 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 4
- 229910000428 cobalt oxide Inorganic materials 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000004566 building material Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- UPWOEMHINGJHOB-UHFFFAOYSA-N oxo(oxocobaltiooxy)cobalt Chemical compound O=[Co]O[Co]=O UPWOEMHINGJHOB-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229910021281 Co3O4In Inorganic materials 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000007733 ion plating Methods 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/04—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbonitrides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/16—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on nitrides
-
- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44C—PERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
- A44C27/00—Making jewellery or other personal adornments
- A44C27/001—Materials for manufacturing jewellery
- A44C27/002—Metallic materials
- A44C27/003—Metallic alloys
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Powder Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Adornments (AREA)
- Ceramic Products (AREA)
Abstract
The invention provides a decorative member that produces a blackish luster derived from metal while demonstrating superior wear resistance and having a reduced weight. The two features of wear resistance and reduced weight are achieved by applying, on a decorative member, a cermet constituted by a hard phase including at least two of TiCN, TiC, TiN, and MoC2 in a proportion of 70 to 97% by mass with the remainder being constituted by a binder phase and unavoidable impurities. It is also possible to provide a user-friendly decorative member that satisfies all of wear resistance, reduced weight, and blackish metallic luster by finishing the surface roughness of the decorative member to a mirror finish state.
Description
Technical field
The present invention relates to decorative element, the decorative element presents and is suitable to dress ornament decorative element, clock and watch decorative element, builds
The decorative elements such as timber-used decorative element, kitchen appliance decorative element, household electrical appliances decorative element and automobile decorative element
Metallic luster, the invention particularly relates to be applied to watch case, watchband pearl and the clock and watch dress of the metallic luster of beauty can be presented
Trim.
Background technology
At present, in the clock and watch and bullion shop in Europe, the clock and watch decorative element of black system attracts attention deeply, recently,
The clock and watch decorative element of black system becomes to become more and more popular.Most of decorative elements all adopt colour, and therein using black
The decorative element of colour system is used as since ancient times the formal color of comparison, and it can give people to bring simply and the sensation of nobleness,
Thus it is all the time all well received.By the black system metallic luster for presenting certain metal finish into mirror status
It is also one of them, the touch sense of its tone and metal has much popularity.
In this case, from the past till now, it has been proposed that various black systems decorative element.Example
Such as, in patent documentation 1, disclose as the monochromatic decorative element in black and white system with WC systems, TiC systems, NbC as mainly into
Divide and the monochromatic superhard alloy in black and white system.
In addition, a kind of decoration object with the zirconium oxide of black as main component is Patent Document 2 discloses, wherein,
The decoration object by the zirconic substrate (matrix) of 3wt%～70wt%, the cobalt oxide of 25wt%～50wt% and
Remainder is constituted, and the zirconium oxide is using in the oxide group constituted selected from yittrium oxide, magnesium oxide, cerium oxide and calcium oxide
At least one oxide it is stable after zirconium oxide, remainder includes the powder or spinel-type of cobalt oxide and ferrum oxide
The powder of CoFe204.
In addition, the zirconia ceramicss and the decorative element using the zirconia ceramicss of black are Patent Document 3 discloses, its
In, the zirconia ceramicss are characterised by：Its by 40wt%～70wt% cobalt oxide (CoO, Co2O3、Co3O4In at least appoint
Meaning is a kind of) and coloring agent composition, wherein, the coloring agent is by ferrum oxide (Fe2O3) and chromium oxide (Cr2O3) constitute, also, it is above-mentioned
The amount of ferrum oxide is 15wt%～30wt%, and the amount of above-mentioned cobalt oxide is 40wt%～70wt%.
【Prior art literature】
【Patent documentation】
Patent documentation 1：JP Publication, JP No. 60-4051 number
Patent documentation 2：JP Publication, special permission the 3714563rd
Patent documentation 3：JP Publication, special permission the 4960070th
The content of the invention
But, the superhard alloy disclosed in patent documentation 1, although with the black and white produced by superhard metal and golden system
Metallic luster, but, because it is formed by superhard metal, thus density is up to 12.8g/m3～14.3g/m3, so as to use
With person cannot be worn on for a long time.
In addition, the decoration object with black zirconia as main component disclosed in patent documentation 2, possesses zirconium oxide former
The mechanical property of some high intensity or high tenacity etc., and density is relatively low, is 6.0g/cm3But, because its tone is micro-
Black tone in cyan and the black from zirconia ceramicss, therefore, it does not contain metal so as to not possess from metal
Black system gloss.
In addition, the black zirconia ceramics disclosed in patent documentation 3 are in the black tone for being referred to as pole black, density is
5.9g/cm3～6.1g/cm3But, because it is to utilize ceramics made by metal-free material, thus black cannot be reproduced
The metallic luster of system and metal touch sense.Further, since raw material is zirconium oxide, thus Vickers hardness is less than the dimension of superhard alloy
Family name's hardness 1450Hv.
The present invention is completed in view of the above problems, be its object is to offer one kind and is had and superhard metal equal extent
Outstanding wearability and lightweight, use so as to be suitable to long-time, and the black system tone from metal is presented, and have
Distinctive smooth touch of metal is felt, the decorative element of the enjoyment thus, it is possible to obtain feeling of high class and U.S..
The present invention decorative element be made up of hard phase and remainder, the hard phase with more than 70wt% and 97wt% with
Under ratio contain TiCN, TiC, TiN, MoC2In more than at least two, remainder includes Binder Phase and inevitably
Impurity, the decorative element is characterised by：Wearability is outstanding, lightweight, also, the surface roughness Ra on the decorative element surface
For less than 0.008 μm.
In addition, the decorative element of the present invention is in the decorative element of above-mentioned composition, surface roughness is Ra at 0.004 μm
Below and Rz is below 0.02 μm.
(invention effect)
The present invention decorative element be made up of hard phase and remainder, the hard phase with more than 70wt% and 97wt% with
Under ratio contain TiCN, TiC, TiN, MoC2In more than at least two, remainder includes Binder Phase and inevitably
Impurity, the wearability of the decorative element is outstanding and lightweight, also, the surface roughness Ra of the decorative element 0.008 μm with
Under.
By by TiCN, TiC, TiN, MoC2In more than at least two composition, apparent density can be decreased to 6.1g/
cm3It is below and equal with zirconium oxide or equal light with Shangdi, even if so as to owner's long periods of wear is using being not easy to fatigue, and
And, because vickers hardness hv is more than 1450, thus possess the wearability with superhard metal equal extent, so as to decorative element not
It is easily damaged.
Further, by making surface roughness Ra below 0.008 μm, using the teaching of the invention it is possible to provide touch sense well and diffuse-reflectance degree is little,
And the decorative element of the metallic luster of presentation black system.Thus, the metallic luster by black system and the touch sense of metal, make
The dress ornament of clock and watch shell, watchband pearl, brooch, necklace, earrings, ring, tie clip, tie-pin, souvenir badge, spectacle-frame, button etc. is used
Decorative element；The building materials ornament materials of decorative ground, wall, the ceramic tile OR gate handle of ceiling etc.；The kitchen of soupspoon, fork etc.
Room utensil decorative element；Or other household electrical appliances decorative elements, automobile decorative element popularity in the market are uprised, especially
It uprises clock and watch shell, the popularity of watchband pearl.
The ceramic metal decorative element of the present invention, is more preferably formed as Ra below 0.004 μm and Rz by surface roughness
Below 0.02 μm, so that the direct reflection on decorative element surface is more than diffuse-reflectance, thus do not exist because of the unrestrained of visible ray
Reflection and the white that causes, present the metallic luster of black system, also, realize full of decorative element itself have it is thick and heavy
The metallic luster of sense and be suitable to the smooth touch sense of skin such that it is able to further obtain feeling of high class, beautiful enjoyment and
Spiritual comfort, and be expected to improve the popularity in market.
Description of the drawings
The state of the decorative element of non-mirror surface state is shown in Fig. 1.
The state of the decorative element of mirror status is shown in Fig. 2.
Illustrate in Fig. 3 using atomic force microscope (Japanese SEIKO Instruments Inc. productions, Nanopics
1000) it is amplified to the state of the decorative element of the non-mirror surface state after 500 times.
Illustrate in Fig. 4 using atomic force microscope (Japanese SEIKO Instruments Inc. productions, Nanopics
1000) state of the decorative element of the mirror status being amplified to after 500 times.
Fig. 5 is the axonometric chart of a configuration example of the clock and watch shell of the clock and watch decorative element for being denoted as the present invention.
Fig. 6 is the figure of a configuration example of the watchband of the clock and watch decorative element that medelling is denoted as the present invention.
Specific embodiment
Hereinafter, for the example of embodiment of the present invention is illustrated.
The present invention decorative element be made up of hard phase (hard phase) and remainder, the hard phase with 70wt% with
The ratio of upper and below 97wt% contains TiC, TiCN, TiN, MoC2In at least any two or more materials, remainder bag
Binder Phase (binding phase) and inevitable impurity (unavoidable impurities) are included, the decorative element
It is characterised by：Wearability is outstanding and lightweight, and the surface roughness Ra of the decorative element is below 0.008 μm.
In order to obtain that the metallic luster of black system is presented, and wearability is outstanding and lightweight such that it is able to make for a long time
Decorative element, the present inventors for various raw materials be repeated test after find, by will by hard phase and remaining
The ceramic metal that part is constituted is configured to decorative element, and the surface roughness Ra of ceramic metal decorative element is refined to
Less than 0.008 μm such that it is able to which the owner to pursuing decorative value brings feeling of high class, beautiful enjoyment, spiritual comfort etc., and
Black system tone rather well received on nearest market can be presented, wherein, above-mentioned hard phase is with more than 70wt% and 97wt%
Following ratio contains TiC, TiCN, TiN, MoC2In more than at least two, above-mentioned remainder includes Binder Phase and can not
The impurity for avoiding.
In addition, " wearability is outstanding " described in the present invention refers to：The Vickers hardness of the metal surface of decorative element exists
More than 1450.By with TiC, TiCN, TiN, MoC2In more than at least two as main component, can be formed as desired
Vickers hardness.
In addition, " lightweight " described in the present invention is referred to：The density of decorative element is in 6.1g/cm3Below.By not making
With TaC, PbC, WC equimolecular quantity up to raw material of 192g, 219g, 195g respectively, can realize desired less close
Degree.
In addition, the surface roughness Ra in the present invention is using laser microscope or atomic force microscope (Japan
SEIKO Instruments Inc. productions, Nanopics 1000) roughness measured.By by the surface of decorative element
Roughness Ra is refined to less than 0.008 μm such that it is able to be finish-machined to the mirror status that visible ray is specularly reflected.
According to Fig. 1～Fig. 2 for mirror status are illustrated with the difference of non-mirror surface state.Fig. 1 is that Ra is more than 0.008 μm
Non-mirror surface state decorative element surface photo, Fig. 2 is the decorative element surface of the mirror status that Ra is less than 0.008 μm
Photo.
The metal surface of the non-mirror surface state of Fig. 1 is fuzzy in dull, and the shape whitened because of the diffuse-reflectance of light
State, the metal surface of the mirror status of Fig. 2 in the bright and clearly state of gloss, it follows that in the mirror-like of Fig. 2
Under state, the metallic luster of black system can be presented.
In addition, the present inventors has found：By changing ceramic-metallic surface roughness, resulting metal can be changed
The degree of the metallic luster of ceramics, especially surface roughness be changed into Ra less than 0.004 μm and Rz below 0.02 μm when, it is golden
Belong to the widely different of gloss.Now, using atomic force microscope (Japanese SEIKO Instruments Inc. production,
Nanopics 1000) carry out measurement surface roughness Ra, measure Rz using laser microscope.
Fig. 3 and Fig. 4 be respectively using atomic force microscope (Japanese SEIKO Instruments Inc. production,
Nanopics 1000) 40 μm of regions of parts surface are amplified after photo.Wherein, Fig. 3 represents that surface roughness Ra is more than
The apparent condition of 0.004 μm of ceramic metal decorative element, Fig. 4 represents metal pottery of the surface roughness Ra below 0.004 μm
The apparent condition of porcelain decorative element.
Understand after Fig. 3 and Fig. 4 are compared：In the minute surface being refined to surface roughness Ra below 0.004 μm,
The diffuse-reflectance of visible ray further tails off, and there are black portions.It follows that surface roughness is more little, more can present
The metallic luster of black system.
In addition, the relation between Rz and metallic luster is as shown in table 1.Illustrate what is measured using laser microscope in table 1
The value of each ceramic-metallic surface roughness Ra and Rz and the actual surface state being visually observed.
【Table 1】
As shown in Table 1：When surface roughness Ra is up to more than 0.01 μm, apparent condition is in non-mirror surface state, works as surface
When roughness Ra is changed into less than 0.004 μm, apparent condition is mirrored state.Further, arithmetic average roughness Ra is not only, from gold
From the point of view of five higher positions of metal surface and 10 mean roughness Rz of five lower positions, existed by being refined to Ra
Less than 0.004 μm and Rz below 0.02 μm, can present the black system metallic luster gorgeous almost without diffuse-reflectance.
Therefore, the surface roughness of metal surface is lower, then regular reflection (the regular of metal surface
Reflection it is) more, so as to can more present more bright metallic luster.The surface roughness of metal surface is preferably Ra
Below 0.008 μm, in this case, the few black system metallic luster of diffuse-reflectance can be presented.Further, the surface of metal surface
Roughness is more preferably Ra below 0.004 μm and Rz is below 0.02 μm, in this case, can present almost without diffuse-reflectance
And gorgeous black system metallic luster.
By being finish-machined to above-mentioned any one surface roughness Ra, Rz, metal surface can be suppressed to produce the unrestrained anti-of light
Penetrate, so as to present the metallic luster of black system, and the smooth touch sense of metal can be reproduced, therefore, feeling of high class increases,
And the enjoyment of U.S. also increases.
Then, for of manufacture method of the ceramic metal decorative element of the present invention illustrates.
The ceramic metal decorative element of the present invention, the shape of decorative element that can be by the way that ceramic metal to be configured to specify
And obtain, wherein, in the ceramic metal containing more than 70wt% and below 97wt% TiC or TiCN and MoC2, its remaining part
Dividing includes Binder Phase and inevitable impurity.In addition, manufacturing process is not particularly limited, it is possible to use extrusion molding, injection
The methods such as shaping, sintering, grinding, grinding, eletroforming, Electrolyzed Processing, spark machined, Laser Processing.
For example, in an embodiment of the present invention, ceramic metal is configured to the clock and watch shown in Fig. 5, Fig. 6 using said method
Shell or the shape of watchband pearl (band piece).
In addition, processed by implementing to add to above-mentioned clock and watch shell or above-mentioned watchband pearl after forming, so as to be finish-machined to be in
The mirror status of existing metallic luster.Method for being finish-machined to the mirror status of presentation metallic luster is not particularly limited, can
It is in the present embodiment, raw by batch with using methods such as etching, evaporation, plating, grinding, cleaning, Laser Processing, ion platings
Produce easily and can disposably complete chamfering or rounding (rounding) tumbling (barrel polishing) and
It is finish-machined to mirror status.
In the clock and watch shell of the present embodiment or watchband pearl, by the way that surface roughness is refined to into Ra more than 0.004 μm
And less than or equal to 0.008 μm, so as to present the metallic luster of black system, in addition, by the way that surface roughness is refined to into Ra
It it is less than 0.02 μm for less than 0.004 μm and Rz, so as to deeper black system metallic luster is presented.In theory it is considered that surface
Most deep black system metallic luster is presented when roughness is Ra=0.000 μm and Rz=0.00 μm.
In addition, the specification of the clock and watch shell, watchband pearl in embodiments of the invention is as follows：Apparent density is 5.8g/cm3, dimension
Family name's hardness is 1570Hv, and weight is light substantially in the same manner with zirconium oxide, and Vickers hardness is hardness more than superhard alloy, so as to all
Person's life-time service is not easy to fatigue, and clock and watch shell, watchband pearl be not easily damaged.
So obtained clock and watch shell or watchband pearl, due to being finish-machined to that the minute surface of metallic luster is presented, therefore, it is possible to
There is provided with feeling of high class and be obtained the clock and watch decorative element of the enjoyment of U.S..
In addition, the present invention is not limited to clock and watch decorative element, it is also possible to suitable for brooch, necklace, earrings, ring, neck
Dress ornament decorative element with folder, tie-pin, souvenir badge, spectacle-frame, button etc.；Decorative ground, wall, the ceramic tile of ceiling or
The building materials decorative element of person's door handle etc.；The kitchen appliance decorative element of soupspoon, fork etc.；Or other household electrical appliances dresses
In trim, automobile decorative element.
Also, ceramic metal decorative element provided by the present invention, wearability is outstanding, hardness is high and not easily damaged, weight
Gently can for a long time use, and metallic luster is presented.
Claims (2)
1. a kind of decorative element, it is made up of hard phase and remainder, wherein, the hard phase with more than 70wt% and
The ratio of below 97wt% contains TiCN, TiC, TiN, MoC2In more than at least two, the remainder include Binder Phase
With inevitable impurity,
The decorative element is characterised by,
Lightweight and wearability is outstanding, also, the surface roughness Ra of the decorative element is below 0.008 μm.
2. decorative element as claimed in claim 1, it is characterised in that
The surface roughness of the decorative element is for Ra is below 0.004 μm and Rz is below 0.02 μm.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013005322 | 2013-01-16 | ||
| JP2013-005322 | 2013-01-16 | ||
| PCT/JP2013/084832 WO2014112314A1 (en) | 2013-01-16 | 2013-12-26 | Decorative member |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104884653A CN104884653A (en) | 2015-09-02 |
| CN104884653B true CN104884653B (en) | 2017-04-26 |
Family
ID=51209416
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201380068735.1A Expired - Fee Related CN104884653B (en) | 2013-01-16 | 2013-12-26 | decorative member |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP2947166A4 (en) |
| JP (1) | JP6343795B2 (en) |
| KR (1) | KR20150104116A (en) |
| CN (1) | CN104884653B (en) |
| HK (1) | HK1211324A1 (en) |
| WO (1) | WO2014112314A1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107587022B (en) * | 2017-08-10 | 2019-10-18 | 东莞华晶粉末冶金有限公司 | A kind of ceramic tool material, cutter and manufacturing method |
| EP3968098A1 (en) * | 2020-09-09 | 2022-03-16 | The Swatch Group Research and Development Ltd | Decorative item made of cermet |
| EP3974405A1 (en) * | 2020-09-25 | 2022-03-30 | The Swatch Group Research and Development Ltd | Ceramic decorative item |
| NL2029278B1 (en) * | 2021-09-29 | 2023-04-06 | Champion Link Int Corp | Decorative panel and method for producing decorative panel |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS604051A (en) | 1983-06-22 | 1985-01-10 | セイコーエプソン株式会社 | Polychrome carbide alloy for ornamental member |
| JPH0368738A (en) * | 1989-08-07 | 1991-03-25 | Kyocera Corp | Hard sintered alloy |
| JP2722118B2 (en) * | 1989-08-07 | 1998-03-04 | 京セラ株式会社 | Titanium carbide based silver sintered alloy |
| JPH0551255A (en) * | 1991-08-23 | 1993-03-02 | Toshiba Corp | Ceramic parts for decoration |
| CH687680A5 (en) | 1994-04-19 | 1997-01-31 | Asulab Sa | A method of manufacturing an article by Black zirconia and black decorative article obtained by this process. |
| CN1172168A (en) * | 1996-07-30 | 1998-02-04 | 大韩重石株式会社 | Ultra-hard alloy for wrist watch and decoration |
| JP4596692B2 (en) * | 2001-06-28 | 2010-12-08 | 京セラ株式会社 | Sintered alloy and manufacturing method thereof |
| JP4977033B2 (en) * | 2005-11-15 | 2012-07-18 | 日本タングステン株式会社 | Mechanical seal ring |
| JP4960070B2 (en) | 2006-11-28 | 2012-06-27 | 京セラ株式会社 | Black ceramics, decorative parts for watches using the same, and methods for producing the black ceramics |
| JP5094875B2 (en) * | 2007-11-28 | 2012-12-12 | 京セラ株式会社 | Ceramics for decorative parts and decorative parts using the same |
| JP5864421B2 (en) * | 2011-03-07 | 2016-02-17 | 住友電工ハードメタル株式会社 | Materials for decorative parts |
| JP5829563B2 (en) * | 2011-03-30 | 2015-12-09 | 京セラ株式会社 | Silicon nitride-based sintered body and decorative part using the same |
| CN102766793B (en) * | 2012-07-31 | 2015-04-08 | 自贡硬质合金有限责任公司 | Cermet material and preparation method thereof |
-
2013
- 2013-12-26 KR KR1020157019110A patent/KR20150104116A/en not_active Application Discontinuation
- 2013-12-26 CN CN201380068735.1A patent/CN104884653B/en not_active Expired - Fee Related
- 2013-12-26 JP JP2014557380A patent/JP6343795B2/en not_active Expired - Fee Related
- 2013-12-26 EP EP13871905.9A patent/EP2947166A4/en not_active Withdrawn
- 2013-12-26 WO PCT/JP2013/084832 patent/WO2014112314A1/en active Application Filing
-
2015
- 2015-11-26 HK HK15111666.3A patent/HK1211324A1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR20150104116A (en) | 2015-09-14 |
| JPWO2014112314A1 (en) | 2017-01-19 |
| CN104884653A (en) | 2015-09-02 |
| EP2947166A4 (en) | 2016-11-09 |
| EP2947166A1 (en) | 2015-11-25 |
| WO2014112314A1 (en) | 2014-07-24 |
| JP6343795B2 (en) | 2018-06-20 |
| HK1211324A1 (en) | 2016-05-20 |
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