CN104878606B - A kind of fabric smooth agent and preparation method thereof - Google Patents
A kind of fabric smooth agent and preparation method thereof Download PDFInfo
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- CN104878606B CN104878606B CN201510233459.0A CN201510233459A CN104878606B CN 104878606 B CN104878606 B CN 104878606B CN 201510233459 A CN201510233459 A CN 201510233459A CN 104878606 B CN104878606 B CN 104878606B
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Abstract
The invention discloses a kind of fabric smooth agent and preparation method thereof.Above-mentioned fabrics smooth agent, is made up of the component comprising following parts by weight：0.02 0.8 parts of 45 60 parts of dimethicone, double 8 11 parts of (phenyldimethicones) methyl silanols, 58 parts of dimethylformamide, three 37 parts of (trifluoro propyl) trimethyl cyclotrisiloxane, 35 parts of silica, 0.5 1.8 parts of triethylene tetramine and adipic dihydrazide.Present invention also offers the preparation method of above-mentioned fabrics smooth agent.
Description
Technical field
The invention belongs to fabric additive agent field, more particularly to a kind of fabric smooth agent and preparation method thereof.
Background technology
Smoothing agent for fabric can make fabric have excellent glossiness, Bearable dry and wet wipe, pliability, and smoothing agent for fabric adheres to
Power is strong, waterproof anti-soil, fast drying, high-low temperature resistant, the smooth exquisiteness of feel.
In order that fabric has soft, lubrication feel, it is necessary to add fabric additive in the processing procedure of fabric, than
Such as smooth agent, additions of smooth agent can make fabric face have good flexibility and a smooth feel, and conventional fabric is put down
Lubrication prescription mainly has dimethicone, but this organosilicon is not firm enough without the combination between active group, and fabric, easily de-
Fall, so that the feel of fabric is influenceed, meanwhile, the smooth agent of silicon class is poor under easy appearance stabilization in storing process, to use environment
It is required that it is high, easily exist the problem of performance is lost caused by storage is improper.
The content of the invention
For above-mentioned demand, invention especially provides a kind of fabric smooth agent and preparation method thereof.The fabric is used
Smooth agent has excellent Lubricity, it is adaptable to the manufactured goods of various fibers, fabric can be played it is good soft, smooth and
The effect of light, while can also be had certain effect to the antistatic property tool of fabric.
The purpose of the present invention can be achieved through the following technical solutions：
A kind of fabric smooth agent, is made up of the component comprising following parts by weight：
The component also includes 2- heptadecyl imidazole 0-1.2 parts by weight.
The component also includes sodium pyrophosphate 0-0.5 parts by weight.
The silica is Nano particles of silicon dioxide.
A diameter of 18-45 nanometers of the Nano particles of silicon dioxide.
A kind of preparation method of fabric smooth agent, this method comprises the following steps：
(1) dimethicone 45-60 parts by weight, dimethylformamide 5-8 parts by weight, silica 3-5 parts by weight are weighed
With triethylene tetramine 0.5-1.8 parts by weight, it is well mixed, adds double-(phenyldimethicones) methyl silanol 8-11 weight
Part, three (trifluoro propyl) trimethyl cyclotrisiloxane 3-7 parts by weight, are mixed 8-15 minutes in high-speed shearing machine；
(2) be slowly added at 55-75 DEG C, under homogenizer stirring condition 2- heptadecyl imidazole 0-1.2 parts by weight,
The mixture of sodium pyrophosphate 0-0.5 parts by weight and adipic dihydrazide 0.02-0.8 parts by weight, 1.5-3 is incubated at 50-70 DEG C
Hour, obtain fabric smooth agent.
The stir speed (S.S.) of the homogenizer is 1800-2500 revs/min.
Compared with prior art, its advantage is the present invention：
(1) fabric smooth agent of the invention is due to adding double-(phenyldimethicones) methyl silanol and three (three
Fluoropropyl) trimethyl cyclotrisiloxane, make smooth agent that there is soft, smooth effect.
(2) fabric of the invention adds adipic dihydrazide and dimethylformamide with smooth agent, makes it have good
Stability, can be adhered to well with fabric, with good soft effect.
(3) the materials safety environmental protection of fabric smooth agent of the invention, and obtained smooth agent stability is good.
(4) fabric smooth agent of the invention, its preparation method is simple, it is easy to industrialized production.
Embodiment
The present invention is further illustrated with reference to embodiments.
Embodiment 1
(1) dimethicone 60kg, dimethylformamide 5kg, a diameter of 18 nanometers of silica 3kg and three second are weighed
Alkene tetramine 0.5kg, is well mixed, and adds double-(phenyldimethicones) methyl silanol 8kg, three (trifluoro propyl) trimethyls
Cyclotrisiloxane 3kg, is mixed 8 minutes in high-speed shearing machine；
(2) at 55 DEG C, in homogenizer to be slowly added to 2- heptadecyls under 1800 revs/min of stirring condition
Imidazoles 1.2kg, sodium pyrophosphate 0.5kg and adipic dihydrazide 0.02kg mixture, are incubated 3 hours at 50 DEG C, are knitted
Thing smooth agent.
The performance test results that fabric smooth agent is made are as shown in table 1.
Embodiment 2
(1) dimethicone 60kg, dimethylformamide 8kg, a diameter of 18 nanometers of silica 3kg and three second are weighed
Alkene tetramine 0.5kg, is well mixed, and adds double-(phenyldimethicones) methyl silanol 11kg, three (trifluoro propyl) trimethyls
Cyclotrisiloxane 3kg, is mixed 8 minutes in high-speed shearing machine；
(2) at 55 DEG C, in homogenizer to be slowly added to 2- heptadecyls under 1800 revs/min of stirring condition
Imidazoles 1.2kg, sodium pyrophosphate 0.5kg and adipic dihydrazide 0.02kg mixture, are incubated 3 hours at 50 DEG C, are knitted
Thing smooth agent.
The performance test results that fabric smooth agent is made are as shown in table 1.
Embodiment 3
(1) dimethicone 45kg, dimethylformamide 5kg, a diameter of 45 nanometers of silica 5kg and three second are weighed
Alkene tetramine 1.8kg, is well mixed, and adds double-(phenyldimethicones) methyl silanol 8kg, three (trifluoro propyl) trimethyls
Cyclotrisiloxane 3kg, is mixed 8 minutes in high-speed shearing machine；
(2) at 75 DEG C, in homogenizer to be slowly added to 2- heptadecyls under 2500 revs/min of stirring condition
Imidazoles 1.2kg, sodium pyrophosphate 0.5kg and adipic dihydrazide 0.8kg mixture, are incubated 1.5 hours at 70 DEG C, are knitted
Thing smooth agent.
The performance test results that fabric smooth agent is made are as shown in table 1.
Embodiment 4
(1) dimethicone 45kg, dimethylformamide 5kg, a diameter of 45 nanometers of silica 5kg and three second are weighed
Alkene tetramine 0.5-1.8kg, is well mixed, and adds double-(phenyldimethicones) methyl silanol 8kg, three (trifluoro propyls) three
Methyl cyclotrisiloxane 7kg, is mixed 15 minutes in high-speed shearing machine；
(2) at 75 DEG C, in homogenizer to be slowly added to 2- heptadecyls under 2500 revs/min of stirring condition
Imidazoles 1.2kg, sodium pyrophosphate 0.5kg and adipic dihydrazide 0.8kg mixture, are incubated 1.5 hours at 70 DEG C, are knitted
Thing smooth agent.
The performance test results that fabric smooth agent is made are as shown in table 1.
Embodiment 5
(1) dimethicone 50kg, dimethylformamide 6kg, a diameter of 25 nanometers of silica 4kg and three second are weighed
Alkene tetramine 1.5kg, is well mixed, and adds double-(phenyldimethicones) methyl silanol 10kg, three (trifluoro propyl) trimethyls
Cyclotrisiloxane 5kg, is mixed 10 minutes in high-speed shearing machine；
(2) at 65 DEG C, in homogenizer to be slowly added to the acyl of adipic acid two under 2000 revs/min of stirring condition
Hydrazine 0.5kg, is incubated 2 hours at 50 DEG C, obtains fabric smooth agent.
The performance test results that fabric smooth agent is made are as shown in table 1.
Comparative example
Dimethicone 50kg, dimethylformamide 6kg and three (trifluoro propyl) trimethyl cyclotrisiloxane 5kg are weighed,
Mixed 10 minutes in high-speed shearing machine；Sodium hydroxide 0.5kg is slowly added under stirring condition in 65 DEG C, homogenizer,
2 hours are incubated at 50 DEG C, fabric smooth agent is obtained.
Table 1
The invention is not restricted to embodiment here, those skilled in the art do not depart from the present invention according to the announcement of the present invention
The improvement and modification that category is made all should be within protection scope of the present invention.
Claims (2)
1. a kind of fabric smooth agent, it is characterised in that be made up of the component comprising following parts by weight：
45-60 parts of dimethicone,
Double -8-11 parts of (phenyldimethicones) methyl silanol,
5-8 parts of dimethylformamide,
Three 3-7 parts of (trifluoro propyl) trimethyl cyclotrisiloxane,
3-5 parts of silica,
0.5-1.8 parts of triethylene tetramine,
0.02-0.8 parts of adipic dihydrazide；
The component also includes 2- heptadecyl imidazole 0-1.2 parts by weight；
The component also includes sodium pyrophosphate 0-0.5 parts by weight；
The silica is Nano particles of silicon dioxide；
A diameter of 18-45 nanometers of the Nano particles of silicon dioxide；
A kind of described fabric is prepared with smooth agent by following preparation methods：
(1) dimethicone 45-60 parts by weight, dimethylformamide 5-8 parts by weight, silica 3-5 parts by weight and three are weighed
Ethene tetramine 0.5-1.8 parts by weight, are well mixed, and add double-(phenyldimethicones) methyl silanol 8-11 parts by weight, three
(trifluoro propyl) trimethyl cyclotrisiloxane 3-7 parts by weight, are mixed 8-15 minutes in high-speed shearing machine；
(2) 2- heptadecyl imidazole 0-1.2 parts by weight, burnt phosphorus are slowly added at 55-75 DEG C, under homogenizer stirring condition
The mixture of sour sodium 0-0.5 parts by weight and adipic dihydrazide 0.02-0.8 parts by weight, 1.5-3 hours are incubated at 50-70 DEG C,
Obtain fabric smooth agent.
2. a kind of fabric smooth agent according to claim 1, it is characterised in that the stir speed (S.S.) of the homogenizer
For 1800-2500 revs/min.
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| CN201510233459.0A CN104878606B (en) | 2015-05-08 | 2015-05-08 | A kind of fabric smooth agent and preparation method thereof |
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| CN201510233459.0A CN104878606B (en) | 2015-05-08 | 2015-05-08 | A kind of fabric smooth agent and preparation method thereof |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109930391A (en) * | 2019-02-28 | 2019-06-25 | 常州市雄图纺织有限公司 | A kind of high evenness smoothing agent for fabric |
| CN112663332A (en) * | 2020-12-23 | 2021-04-16 | 南通恒润新材料科技有限公司 | Preparation method of high-stability high-temperature-resistant smoothing agent |
| CN114232346A (en) * | 2021-12-30 | 2022-03-25 | 广东三兴高新材料科技有限公司 | Smoothing agent for fabric and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1584191A (en) * | 2004-05-28 | 2005-02-23 | 刘国平 | Nanometer softening smoothing agent and preparing method thereof |
| CN100412262C (en) * | 2006-09-07 | 2008-08-20 | 浙江传化股份有限公司 | Method for preparing smoothing agent for fabric of organosilicon |
| CN101235592A (en) * | 2008-03-07 | 2008-08-06 | 吴江市良燕纺织助剂厂 | Terylene FDY nano spinning finish and its preparing process |
| CN102102297A (en) * | 2009-12-22 | 2011-06-22 | 河南瑞贝卡发制品股份有限公司 | Afterfinishing smoothing agent for synthetic fiber |
| CN102912640B (en) * | 2012-10-25 | 2014-06-25 | 上虞市皇马化学有限公司 | Crude-oil polyester industrial yarn finish and preparation method thereof |
| CN104313884B (en) * | 2014-10-20 | 2016-08-31 | 江苏金牛华尔车服饰有限公司 | Fabric smooth agent |
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