CN104861403A - Corrosion-resistant antifungal shock-absorbing wave-proof sleeve - Google Patents
Corrosion-resistant antifungal shock-absorbing wave-proof sleeve Download PDFInfo
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- CN104861403A CN104861403A CN201510233892.4A CN201510233892A CN104861403A CN 104861403 A CN104861403 A CN 104861403A CN 201510233892 A CN201510233892 A CN 201510233892A CN 104861403 A CN104861403 A CN 104861403A
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Abstract
The invention discloses a corrosion-resistant antifungal shock-absorbing wave-proof sleeve. The corrosion-resistant antifungal shock-absorbing wave-proof sleeve comprises a thread core and a coat for covering the thread core; the coat comprises acrylic resin, polyisobuten, tripoli powder, nylon fiber, silicate and solvent; relative to 100 parts of the acrylic resin by weight, the content of the polyisobuten is 20-70 parts by weight, the content of the tripoli powder is 5-20 parts by weight, the content of the nylon fiber is 1-10 parts by weight, the content of the silicate is 1-10 parts by weight, and the content of the solvent is 30-80 parts by weight. Through the design, the manufactured wave-proof sleeve has good corrosion-resistant performance and anti-mold performance under the precondition of ensuring good using performances (such as the shielding performance), and is capable of greatly prolonging the service life, and reducing the using cost.
Description
Technical field
The present invention relates to electric wire and cable material field, particularly, relate to the anti-ripple cover of corrosion-resistant antifungal shock-absorbing type.
Background technology
The application of electric wire in daily productive life is very extensive, and the scope used also is very widely, thus its outside coated anti-ripple cover is often placed on the position of circumstance complication in actual use, product is then very easily caused to corrode or mildew under some environment, thus greatly can reduce its shield effectiveness and other use propertieies, thus make troubles to actual use.
Therefore, provide a kind of and have good corrosion resistance nature and have the performance of moistureproof and mildewproof, have longer work-ing life, the anti-ripple cover of corrosion-resistant antifungal shock-absorbing type greatly saving use cost is the problem that the present invention needs solution badly.
Summary of the invention
For above-mentioned prior art, to the object of the invention is to overcome in prior art electric wire because of its use range wider, thus it is caused in use, the anti-ripple cover on its surface especially coated is very easily corroded, and be easy to mildew, and then greatly reduce the problem in its use properties and work-ing life, thus provide a kind of and there is good corrosion resistance nature and there is the performance of moistureproof and mildewproof, there is longer work-ing life, greatly save the anti-ripple cover of corrosion-resistant antifungal shock-absorbing type of use cost.
To achieve these goals, the invention provides the anti-ripple cover of a kind of corrosion-resistant antifungal shock-absorbing type, wherein, described corrosion-resistant antifungal shock-absorbing type anti-ripple cover comprises the epidermis of core and coated described core, wherein, described epidermis comprises acrylic resin, polyisobutene, tripoli powder, nylon fiber, silicate and solvent; Wherein,
Relative to the described acrylic resin of 100 weight parts, the content of described polyisobutene is 20-70 weight part, the content of described tripoli powder is 5-20 weight part, the content of described nylon fiber is 1-10 weight part, the content of described silicate is 1-10 weight part, and the content of described solvent is 30-80 weight part.
Pass through technique scheme, the present invention is by acrylic resin, polyisobutene, tripoli powder, nylon fiber, carry out melting after silicate and solvent, after then the mixture after above-mentioned melting being made the coated core of epidermis, the above-mentioned core braiding being coated with epidermis is formed anti-ripple cover, and then make this anti-ripple cover be coated with the obtained epidermis of said mixture because of its top layer, thus make its can guarantee there is the prerequisite of the use propertieies such as good shielding under, there is good corrosion resistance nature and fungicidal properties, thus considerably increase its work-ing life, and then its use cost is reduced greatly.
Other features and advantages of the present invention are described in detail in embodiment part subsequently.
Embodiment
Below the specific embodiment of the present invention is described in detail.Should be understood that, embodiment described herein, only for instruction and explanation of the present invention, is not limited to the present invention.
The invention provides the anti-ripple cover of a kind of corrosion-resistant antifungal shock-absorbing type, wherein, described corrosion-resistant antifungal shock-absorbing type anti-ripple cover comprises the epidermis of core and coated described core, and wherein, described epidermis comprises acrylic resin, polyisobutene, tripoli powder, nylon fiber, silicate and solvent; Wherein,
Relative to the described acrylic resin of 100 weight parts, the content of described polyisobutene is 20-70 weight part, the content of described tripoli powder is 5-20 weight part, the content of described nylon fiber is 1-10 weight part, the content of described silicate is 1-10 weight part, and the content of described solvent is 30-80 weight part.
Above-mentioned design is by by acrylic resin, polyisobutene, tripoli powder, nylon fiber, carry out melting after silicate and solvent, after then the mixture after above-mentioned melting being made the coated core of epidermis, the above-mentioned core braiding being coated with epidermis is formed anti-ripple cover, and then make this anti-ripple cover be coated with the obtained epidermis of said mixture because of its top layer, thus make its can guarantee there is the prerequisite of the use propertieies such as good shielding under, there is good corrosion resistance nature and fungicidal properties, thus considerably increase its work-ing life, and then its use cost is reduced greatly.Described core can be the core type that this area routine uses, and such as, can be zinc-plated soft copper or fine copper etc., seldom for example at this.
Certainly, fusion process here can be prepared according to the melting mode of this area routine, such as, being placed in temperature is carry out melting under the environment of 200-400 DEG C, the type that is then extruded into forms epidermis, and other modes that can realize all can use at this, thus differ one to illustrate.
Here used solvent can be the type of solvent that this area routine uses, and such as, can be ethanol, toluene, methylene dichloride etc., not repeat one by one at this.
Better corrosion resistance nature and fungicidal properties is possessed in order to make the anti-ripple cover obtained, one of the present invention preferred embodiment in, relative to the described acrylic resin of 100 weight parts, the content of described polyisobutene is 40-60 weight part, the content of described tripoli powder is 10-15 weight part, the content of described nylon fiber is 5-7 weight part, and the content of described silicate is 5-7 weight part, and the content of described solvent is 50-60 weight part.
Described acrylic resin can be the acrylic resin type that this area routine uses, certainly, one of the present invention more preferred embodiment in, in order to make the shielding properties of the anti-ripple cover obtained better, described acrylic resin can be chosen as the acrylic resin type that number-average molecular weight is 80000-120000.
Described polyisobutene can be chosen as the polyisobutene type that this area routine uses, certainly, in order to the anti-ripple cover use properties making to obtain is better, such as, under ensureing the prerequisite of good shielding properties, there is lighter weight etc., one of the present invention more preferred embodiment in, described polyisobutene can be chosen as the polyisobutene type that weight-average molecular weight is 100000-200000.
Certainly, in order to the melting thing mixing obtained after making melting is more even, one of the present invention preferred embodiment in, the particle diameter of described tripoli powder can be further defined to 0.2-0.6mm.Certainly, the tripoli powder of other particle diameters also can use in the present invention.
Similarly, more even in order to make to mix rear melting thing, one of the present invention more preferred embodiment in, the length of described nylon fiber can be further defined to 1-10mm.
In order to make the anti-ripple cover obtained have better use properties, further improve its work-ing life, one of the present invention preferred embodiment in, the anti-ripple cover of described corrosion-resistant antifungal shock-absorbing type can also comprise solidifying agent and anti-aging agent.
The addition of described solidifying agent and described anti-aging agent can add according to the addition of this area routine, certainly, in order to save cost as far as possible, and ensure that its use properties is more superior, one of the present invention preferred embodiment in, relative to the described acrylic resin of 100 weight parts, the content of described solidifying agent is 10-20 weight part, and the content of described anti-aging agent is 1-5 weight part.
Certainly, after making the coated core of this epidermis, make that there is the performances such as good corrosion-resistant and mildew-resistant under cost-saving prerequisite, one of the present invention more preferred embodiment in, the diameter of described core can be set to 10:1-5 with the ratio of the thickness of described epidermis.Certainly, core here can regulate its diameter according to actual needs.
Below will be described the present invention by embodiment.In following examples, described acrylic resin is the commercially available product that Jinan Xin Ruiyuan Chemical Co., Ltd. produces, described polyisobutene is the weight-average molecular weight that Jining 101 Chemical Co., Ltd. produces is the commercially available product of 107000, described silicate is the commercially available magnesium aluminum silicate that riverhead, Jinan Chemical Co., Ltd. produces, and described copper cash, described tripoli powder, described nylon fiber, described ethanol, described solidifying agent and described anti-aging agent are conventional commercial product.
Embodiment 1
The mixing of 100g acrylic resin, 40g polyisobutene, 10g tripoli powder, 5g nylon fiber, 5g silicate, 50g ethanol, 10g solidifying agent and 1g anti-aging agent being placed on temperature is melting under the environment of 200 DEG C, then extrusion moulding obtains epidermis, by the coated copper cash of above-mentioned obtained epidermis, many braids are formed the corrosion-resistant antifungal shock-absorbing type anti-ripple cover A1 that knitting tightness is not less than 80% by obtained litzendraht.
Embodiment 2
The mixing of 100g acrylic resin, 60g polyisobutene, 15g tripoli powder, 7g nylon fiber, 7g silicate, 60g ethanol, 20g solidifying agent and 5g anti-aging agent being placed on temperature is melting under the environment of 400 DEG C, then extrusion moulding obtains epidermis, by the coated copper cash of above-mentioned obtained epidermis, many braids are formed the corrosion-resistant antifungal shock-absorbing type anti-ripple cover A2 that knitting tightness is not less than 80% by obtained litzendraht.
Embodiment 3
The mixing of 100g acrylic resin, 50g polyisobutene, 12g tripoli powder, 6g nylon fiber, 6g silicate, 55g ethanol, 15g solidifying agent and 3g anti-aging agent being placed on temperature is melting under the environment of 300 DEG C, then extrusion moulding obtains epidermis, by the coated copper cash of above-mentioned obtained epidermis, many braids are formed the corrosion-resistant antifungal shock-absorbing type anti-ripple cover A3 that knitting tightness is not less than 80% by obtained litzendraht.
Embodiment 4
Be prepared according to the preparation method of embodiment 1, unlike, the consumption of described polyisobutene is 20g, the consumption of described tripoli powder is 5g, the consumption of described nylon fiber is 1g, and the consumption of described silicate is 1g, and the consumption of described ethanol is 30g, do not add solidifying agent and anti-aging agent, obtained corrosion-resistant antifungal shock-absorbing type anti-ripple cover A4.
Embodiment 5
Be prepared according to the preparation method of embodiment 2, unlike, the consumption of described polyisobutene is 70g, the consumption of described tripoli powder is 20g, the consumption of described nylon fiber is 10g, and the consumption of described silicate is 10g, and the consumption of described ethanol is 80g, do not add solidifying agent and anti-aging agent, obtained corrosion-resistant antifungal shock-absorbing type anti-ripple cover A5.
Comparative example 1
Be prepared according to the preparation method of embodiment 3, unlike, the consumption of described polyisobutene is 10g, the consumption of described tripoli powder is 2g, and the consumption of described nylon fiber is 0.5g, and the consumption of described silicate is 0.5g, the consumption of described ethanol is 10g, obtained anti-ripple cover D1.
Comparative example 2
Be prepared according to the preparation method of embodiment 3, unlike, the consumption of described polyisobutene is 100g, the consumption of described tripoli powder is 30g, and the consumption of described nylon fiber is 20g, and the consumption of described silicate is 20g, the consumption of described ethanol is 100g, obtained anti-ripple cover D2.
Comparative example 3
The trade mark that Quanxing Cable Co., Ltd., Jiangsu produces is that the tinned wird of TZXP weaves anti-ripple cover D3.
Test case
Detect its corrosion resistance nature after above-mentioned A1-A5 and D1-D3 being carried out respectively acid mist test 72h, be positioned over humidity is place under the environment of 85% to observe its surface after 6 months and whether have mould simultaneously; Get above-mentioned anti-ripple cover covered electric cable cable respectively and be placed on the identical vibratory screening apparatus of vibrational frequency and vibrate, connect amplitude detection apparatus at the other end of electric wire, detect its amplitude, the result obtained is as shown in table 1.
Table 1
Numbering | Acid mist is tested | Mould detects | Amplitude (mm) |
A1 | Surface is corroded as seen without naked eyes | Surface is without the visible obviously bacterial plaque of naked eyes | 0.3 |
A2 | Surface is corroded as seen without naked eyes | There is slight bacterial plaque on surface | 0.2 |
A3 | Surface is corroded as seen without naked eyes | Surface is without the visible obviously bacterial plaque of naked eyes | 0.3 |
A4 | There is pole slight erosion in surface | There is slight bacterial plaque on surface | 1 |
A5 | There is pole slight erosion in surface | There is slight bacterial plaque on surface | 2 |
D1 | Surface occurs that big area is corroded | There is bacterial plaque in surface big area | 10 |
D2 | Surface occurs that big area is corroded | Surface facet is long-pending there is bacterial plaque | 8 |
D3 | There is corrosion in surface portion | There is more bacterial plaque on surface | 5 |
Can be found out by table 1, anti-ripple obtained within the scope of the present invention overlaps its corrosion resistance nature and is better than conventional commercial product, and Anti-mildew capability is also better than conventional commercial product, when receiving external force vibration, it can damping effectively, thus protect the electric wire of inner fit, the anti-ripple cover obtained outward in the scope of the invention does not then possess this good use properties, corrosion-resistant and antifungal and the damping performance of anti-ripple cover obtained in preferable range of the present invention are then more excellent, thus the use range that the anti-ripple that this invention obtains overlaps obtains and expands greatly, and result of use is more excellent.
More than describe the preferred embodiment of the present invention in detail; but the present invention is not limited to the detail in above-mentioned embodiment, within the scope of technical conceive of the present invention; can carry out multiple simple variant to technical scheme of the present invention, these simple variant all belong to protection scope of the present invention.
It should be noted that in addition, each concrete technical characteristic described in above-mentioned embodiment, in reconcilable situation, can be combined by any suitable mode, in order to avoid unnecessary repetition, the present invention illustrates no longer separately to various possible array mode.
In addition, also can carry out arbitrary combination between various different embodiment of the present invention, as long as it is without prejudice to thought of the present invention, it should be considered as content disclosed in this invention equally.
Claims (9)
1. the anti-ripple cover of corrosion-resistant antifungal shock-absorbing type, it is characterized in that, described corrosion-resistant antifungal shock-absorbing type anti-ripple cover comprises the epidermis of core and coated described core, and wherein, described epidermis comprises acrylic resin, polyisobutene, tripoli powder, nylon fiber, silicate and solvent; Wherein,
Relative to the described acrylic resin of 100 weight parts, the content of described polyisobutene is 20-70 weight part, the content of described tripoli powder is 5-20 weight part, the content of described nylon fiber is 1-10 weight part, the content of described silicate is 1-10 weight part, and the content of described solvent is 30-80 weight part.
2. the anti-ripple cover of corrosion-resistant antifungal shock-absorbing type according to claim 1, wherein, relative to the described acrylic resin of 100 weight parts, the content of described polyisobutene is 40-60 weight part, the content of described tripoli powder is 10-15 weight part, the content of described nylon fiber is 5-7 weight part, and the content of described silicate is 5-7 weight part, and the content of described solvent is 50-60 weight part.
3. the anti-ripple cover of corrosion-resistant antifungal shock-absorbing type according to claim 1 and 2, wherein, the number-average molecular weight of described acrylic resin is 80000-120000.
4. the anti-ripple cover of corrosion-resistant antifungal shock-absorbing type according to claim 1 and 2, wherein, the weight-average molecular weight of described polyisobutene is 100000-200000.
5. the anti-ripple cover of corrosion-resistant antifungal shock-absorbing type according to claim 1 and 2, wherein, the particle diameter of described tripoli powder is 0.2-0.6mm.
6. the anti-ripple cover of corrosion-resistant antifungal shock-absorbing type according to claim 1 and 2, wherein, the length of described nylon fiber is 1-10mm.
7. the anti-ripple cover of corrosion-resistant antifungal shock-absorbing type according to claim 1 and 2, wherein, the anti-ripple cover of described corrosion-resistant antifungal shock-absorbing type also comprises solidifying agent and anti-aging agent.
8. the anti-ripple cover of corrosion-resistant antifungal shock-absorbing type according to claim 7, wherein, relative to the described acrylic resin of 100 weight parts, the content of described solidifying agent is 10-20 weight part, and the content of described anti-aging agent is 1-5 weight part.
9. the anti-ripple cover of corrosion-resistant antifungal shock-absorbing type according to claim 1 and 2, wherein, the diameter of described core is 10:1-5 with the ratio of the thickness of described epidermis.
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CN87107410A (en) * | 1986-12-31 | 1988-08-03 | Bp化学有限公司 | Filled elastomer blends |
CN1678862A (en) * | 2002-09-03 | 2005-10-05 | 株式会社日轮 | Vibration absorbing pipe |
CN201408954Y (en) * | 2009-03-16 | 2010-02-17 | 衡阳泰豪通信车辆有限公司 | Electric shelter and shielding processing structure of cabin penetrating cable thereof |
CN101710656A (en) * | 2009-12-03 | 2010-05-19 | 上海市塑料研究所 | Polytetrafluoroethylene wave-proof sleeve assembly and preparation method thereof |
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2015
- 2015-05-08 CN CN201510233892.4A patent/CN104861403A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN87107410A (en) * | 1986-12-31 | 1988-08-03 | Bp化学有限公司 | Filled elastomer blends |
CN1678862A (en) * | 2002-09-03 | 2005-10-05 | 株式会社日轮 | Vibration absorbing pipe |
CN201408954Y (en) * | 2009-03-16 | 2010-02-17 | 衡阳泰豪通信车辆有限公司 | Electric shelter and shielding processing structure of cabin penetrating cable thereof |
CN101710656A (en) * | 2009-12-03 | 2010-05-19 | 上海市塑料研究所 | Polytetrafluoroethylene wave-proof sleeve assembly and preparation method thereof |
Non-Patent Citations (2)
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Address after: 241000 Wuhu high tech Development Zone, Anhui, No. 15 Zhanghe Road Applicant after: WUHU SPACEFLIGHT SPECIAL CABLE FACTORY CO., LTD. Address before: 241000 Wuhu high tech Development Zone, Anhui, No. 15 Zhanghe Road Applicant before: Wuhu Aerospace Special Cable Factory |
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