CN104860573A - Liquid cement grinding aid - Google Patents

Liquid cement grinding aid Download PDF

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Publication number
CN104860573A
CN104860573A CN201510277267.XA CN201510277267A CN104860573A CN 104860573 A CN104860573 A CN 104860573A CN 201510277267 A CN201510277267 A CN 201510277267A CN 104860573 A CN104860573 A CN 104860573A
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CN
China
Prior art keywords
cement grinding
sodium
liquid cement
grinding aid
sulfonic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN201510277267.XA
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Chinese (zh)
Inventor
李琪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huzhou Hua Lun Auxiliary Agent Science And Technology Ltd
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Huzhou Hua Lun Auxiliary Agent Science And Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Priority to CN201510277267.XA priority Critical patent/CN104860573A/en
Publication of CN104860573A publication Critical patent/CN104860573A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a liquid cement grinding aid, and belongs to the technical field of cement grinding aids. The liquid cement grinding aid is prepared from the following raw materials in percentage by weight: 15-22% of triethanolamine, 10-15% of dodecylbenzene, 10-15% of p-aminobenzene sulfonic acid, 1-3% of a sodium salt water reducing agent of aminobenzene sulfonic acid, 3-5% of sorbitol, 5-10% of triisopropanolamine, 3-5% of hydroxypropyl methyl cellulose, 3-5% of sodium lignin sulfonate, 5-10% of sodium humate, and the balance of water. According to the liquid cement grinding aid, through reasonable proportion of the raw materials, on the premise of less amount of admixture, the yield within a unit time can be up to 15% above, the cement strength can be increased to 3 MPa above for three days, and the cement strength can be increased to 5 MPa above for 28 days.

Description

A kind of liquid cement grinding additive
Technical field
The invention belongs to cement grinding aid technical field, be specifically related to a kind of liquid cement grinding additive.
Background technology
Cement grinding aid is a kind of chemical additive improving cement grinding effect and performance, can significantly improve cement unit-hour output, each length of time strength of cement, improve its mobility.Cement grinding aid significantly can reduce the electrostatic adhesion bag ball phenomenon formed in grinding process, and can reduce the again coalescent trend of the ultra-fine grain formed in grinding process.Cement grinding aid also significantly can improve cement fluidity, improves the grinding effect of grinding machine and the grinding efficiency of powder separating machine, thus reduces grinding energy.The cement using grinding aid to produce has the coalescent trend of lower compacting, thus is conducive to the handling of cement, and can reduce the wall cling phenomenon of cement silo.
But cement grinding aid volume of the prior art is 0.08 ~ 0.1%, and volume is large, and exists and carry that to produce efficiency not high, to the early strength of cement and the later strength DeGrain that improve Wingdale.
Summary of the invention
For prior art Problems existing, the object of the invention is to design the technical scheme that a kind of liquid cement grinding additive is provided.
Described a kind of liquid cement grinding additive, is characterized in that being made up of the raw material of following weight percent: the sodium salt water reducer 1 ~ 3% of trolamine 15 ~ 22%, dodecylbenzene 10 ~ 15%, Sulphanilic Acid 10 ~ 15%, aniline sulfonic acid, sorbyl alcohol 3 ~ 5%, tri-isopropanolamine 5 ~ 10%, Vltra tears 3 ~ 5%, sodium lignosulfonate 3 ~ 5%, sodium humate 5 ~ 10%, surplus are water.
Described a kind of liquid cement grinding additive, is characterized in that being made up of the raw material of following weight percent: the sodium salt water reducer 2 ~ 3% of trolamine 16 ~ 20%, dodecylbenzene 12 ~ 14%, Sulphanilic Acid 12 ~ 14%, aniline sulfonic acid, sorbyl alcohol 3 ~ 4%, tri-isopropanolamine 6 ~ 8%, Vltra tears 3 ~ 4%, sodium lignosulfonate 3 ~ 4%, sodium humate 6 ~ 8%, surplus are water.
Described a kind of liquid cement grinding additive, is characterized in that being made up of the raw material of following weight part: the sodium salt water reducer 3% of trolamine 18%, dodecylbenzene 13%, Sulphanilic Acid 13%, aniline sulfonic acid, sorbyl alcohol 4%, tri-isopropanolamine 7%, Vltra tears 4%, sodium lignosulfonate 3%, sodium humate 7%, surplus are water.
The preparation method of above-mentioned a kind of liquid cement grinding additive: the hot water injecting 30 ~ 40 DEG C in a kettle., then the raw material of described weight percent is added, stir.
Above-mentioned a kind of liquid cement grinding additive, by the rational proportion of each raw material, under the prerequisite that volume is few, the output improved in the unit time reaches more than 15%, within 3 days, can improve more than strength of cement 3MPa, within 28 days, can improve strength of cement 5 more than MPa.
Embodiment
The present invention is further illustrated below in conjunction with embodiment.
Embodiment 1:
The sodium salt water reducer 3% of trolamine 18%, dodecylbenzene 13%, Sulphanilic Acid 13%, aniline sulfonic acid, sorbyl alcohol 4%, tri-isopropanolamine 7%, Vltra tears 4%, sodium lignosulfonate 3%, sodium humate 7%, surplus are water.
Embodiment 2:
The sodium salt water reducer 1% of trolamine 15%, dodecylbenzene 10%, Sulphanilic Acid 10%, aniline sulfonic acid, sorbyl alcohol 3%, tri-isopropanolamine 5%, Vltra tears 3%, sodium lignosulfonate 3%, sodium humate 5%, surplus are water.
Embodiment 3:
The sodium salt water reducer 3% of trolamine 22%, dodecylbenzene 15%, Sulphanilic Acid 15%, aniline sulfonic acid, sorbyl alcohol 5%, tri-isopropanolamine 10%, Vltra tears 5%, sodium lignosulfonate 5%, sodium humate 10%, surplus are water.
Embodiment 4:
The sodium salt water reducer 2% of trolamine 16%, dodecylbenzene 12%, Sulphanilic Acid 12%, aniline sulfonic acid, sorbyl alcohol 3%, tri-isopropanolamine 6%, Vltra tears 3%, sodium lignosulfonate 3%, sodium humate 6%, surplus are water.
Embodiment 5:
The sodium salt water reducer 3% of trolamine 20%, dodecylbenzene 14%, Sulphanilic Acid 14%, aniline sulfonic acid, sorbyl alcohol 4%, tri-isopropanolamine 8%, Vltra tears 4%, sodium lignosulfonate 4%, sodium humate 8%, surplus are water.
Test example:
What use grinding machine model to be 3.2M × 13M band roll squeezer closes stream mill P.C32.5, and proportioning is: grog 65%, Wingdale 15%, slag 8%, flyash 10%, gypsum 2%, and the Testing index of the cement operating mode and physicals of mixing each grinding aid sees the following form.

Claims (3)

1. a liquid cement grinding additive, is characterized in that being made up of the raw material of following weight percent: the sodium salt water reducer 1 ~ 3% of trolamine 15 ~ 22%, dodecylbenzene 10 ~ 15%, Sulphanilic Acid 10 ~ 15%, aniline sulfonic acid, sorbyl alcohol 3 ~ 5%, tri-isopropanolamine 5 ~ 10%, Vltra tears 3 ~ 5%, sodium lignosulfonate 3 ~ 5%, sodium humate 5 ~ 10%, surplus are water.
2. a kind of liquid cement grinding additive as claimed in claim 1, is characterized in that being made up of the raw material of following weight percent: the sodium salt water reducer 2 ~ 3% of trolamine 16 ~ 20%, dodecylbenzene 12 ~ 14%, Sulphanilic Acid 12 ~ 14%, aniline sulfonic acid, sorbyl alcohol 3 ~ 4%, tri-isopropanolamine 6 ~ 8%, Vltra tears 3 ~ 4%, sodium lignosulfonate 3 ~ 4%, sodium humate 6 ~ 8%, surplus are water.
3. a kind of liquid cement grinding additive as claimed in claim 1, is characterized in that being made up of the raw material of following weight part: the sodium salt water reducer 3% of trolamine 18%, dodecylbenzene 13%, Sulphanilic Acid 13%, aniline sulfonic acid, sorbyl alcohol 4%, tri-isopropanolamine 7%, Vltra tears 4%, sodium lignosulfonate 3%, sodium humate 7%, surplus are water.
CN201510277267.XA 2015-05-27 2015-05-27 Liquid cement grinding aid Pending CN104860573A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510277267.XA CN104860573A (en) 2015-05-27 2015-05-27 Liquid cement grinding aid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510277267.XA CN104860573A (en) 2015-05-27 2015-05-27 Liquid cement grinding aid

Publications (1)

Publication Number Publication Date
CN104860573A true CN104860573A (en) 2015-08-26

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CN201510277267.XA Pending CN104860573A (en) 2015-05-27 2015-05-27 Liquid cement grinding aid

Country Status (1)

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CN (1) CN104860573A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110922943A (en) * 2019-11-26 2020-03-27 贺州学院 Inorganic powder grinding aid and preparation method thereof
CN115028379A (en) * 2022-05-20 2022-09-09 湖南中岩建材科技有限公司 Cement raw material grinding aid and preparation method and application thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009131240A1 (en) * 2008-04-24 2009-10-29 ダブリュー・アール・グレイス・アンド・カンパニーーコネチカット Concrete or mortar admixture composition
CN101643338A (en) * 2008-08-08 2010-02-10 孙贵阳 Liquid grinding aid
CN102126843A (en) * 2011-04-19 2011-07-20 鲁南中联水泥有限公司 Cement grinding aid and preparation method thereof
CN103265223A (en) * 2013-06-03 2013-08-28 东南大学 Cement grinding aid
CN104556780A (en) * 2013-10-23 2015-04-29 赵明贵 Liquid cement grinding aid

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009131240A1 (en) * 2008-04-24 2009-10-29 ダブリュー・アール・グレイス・アンド・カンパニーーコネチカット Concrete or mortar admixture composition
CN101643338A (en) * 2008-08-08 2010-02-10 孙贵阳 Liquid grinding aid
CN102126843A (en) * 2011-04-19 2011-07-20 鲁南中联水泥有限公司 Cement grinding aid and preparation method thereof
CN103265223A (en) * 2013-06-03 2013-08-28 东南大学 Cement grinding aid
CN104556780A (en) * 2013-10-23 2015-04-29 赵明贵 Liquid cement grinding aid

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110922943A (en) * 2019-11-26 2020-03-27 贺州学院 Inorganic powder grinding aid and preparation method thereof
CN115028379A (en) * 2022-05-20 2022-09-09 湖南中岩建材科技有限公司 Cement raw material grinding aid and preparation method and application thereof

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Application publication date: 20150826

RJ01 Rejection of invention patent application after publication