CN107601954A - A kind of cement grinding aid and preparation method thereof - Google Patents
A kind of cement grinding aid and preparation method thereof Download PDFInfo
- Publication number
- CN107601954A CN107601954A CN201711103054.0A CN201711103054A CN107601954A CN 107601954 A CN107601954 A CN 107601954A CN 201711103054 A CN201711103054 A CN 201711103054A CN 107601954 A CN107601954 A CN 107601954A
- Authority
- CN
- China
- Prior art keywords
- cement
- grinding aid
- cement grinding
- microcrystalline cellulose
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004568 cement Substances 0.000 title claims abstract description 102
- 238000000227 grinding Methods 0.000 title claims abstract description 58
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 66
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229920000168 Microcrystalline cellulose Polymers 0.000 claims abstract description 22
- 235000019813 microcrystalline cellulose Nutrition 0.000 claims abstract description 22
- 239000008108 microcrystalline cellulose Substances 0.000 claims abstract description 22
- 229940016286 microcrystalline cellulose Drugs 0.000 claims abstract description 22
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims abstract description 22
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims abstract description 21
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims abstract description 19
- -1 fatty acid ester Chemical class 0.000 claims abstract description 19
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 18
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 18
- 239000000194 fatty acid Substances 0.000 claims abstract description 18
- 229930195729 fatty acid Natural products 0.000 claims abstract description 18
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 18
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 10
- 238000009826 distribution Methods 0.000 abstract description 9
- 230000036571 hydration Effects 0.000 abstract description 5
- 238000006703 hydration reaction Methods 0.000 abstract description 5
- 230000008901 benefit Effects 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 4
- 230000009467 reduction Effects 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 239000004567 concrete Substances 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 230000036541 health Effects 0.000 abstract description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 2
- 239000011707 mineral Substances 0.000 abstract description 2
- 230000001627 detrimental effect Effects 0.000 abstract 1
- 239000000523 sample Substances 0.000 description 8
- 239000007788 liquid Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 239000012496 blank sample Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000011161 development Methods 0.000 description 3
- PCHPORCSPXIHLZ-UHFFFAOYSA-N diphenhydramine hydrochloride Chemical compound [Cl-].C=1C=CC=CC=1C(OCC[NH+](C)C)C1=CC=CC=C1 PCHPORCSPXIHLZ-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 241000370738 Chlorion Species 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229940102253 isopropanolamine Drugs 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Landscapes
- Disintegrating Or Milling (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a kind of cement grinding aid and preparation method thereof, cement grinding aid includes the component of following mass content：Polyethylene glycol 5 10%, sorbierite 5 10%, polyglyceryl fatty acid ester 1 3%, diethanol monoisopropanolamine 5 10%, triisopropanolamine 5 10%, sodium hydroxide 1 5%, Sodium Polyacrylate 2 8%, microcrystalline cellulose 1 5%, remainder is water.The beneficial effects of the invention are as follows：The present invention does not fill the material for influenceing concrete performance and building service life and being detrimental to health, safety and environmental protection；It can be acted synergistically between each raw material, be advantageous to the reduction of cement fineness, ensure its rational size distribution, reduce the early hydration rate of heat release of Adding Mineral Admixtures cement and improve strength of cement；In the case where ensureing strength of cement and use condition, production cost can be reduced, improves the economic benefit and social benefit of cement production enterprise.
Description
Technical field
The present invention relates to cement additive field, more particularly to a kind of cement grinding aid and preparation method thereof.
Background technology
Cement is increasingly becoming the basis of human lives' development as the construction material that purposes is most wide, usage amount is maximum, and
Within coming few decades, cement will be the primary building material of social development.With the development and progress of cement industry, improve
Cement performance and quality have a variety of methods, and commonly used is to fill cement grinding aid among the process of cement grinding.It is logical
The mill efficiency of grinding machine can be significantly improved by crossing admixture cement grinding aid, reduce power consumption and steel ball loss, improve cement production
Amount.
Cement grinding aid divides powdery cement grinding aid and liquid cement grinding additive.Because powdery cement grinding aid needs to fill
Amount it is higher, and powdery cement grinding aid is more using technical pure compound organic salt and inorganic salts as primary raw material, can cause to give birth to
The chloride ion in cement content that output is come is higher, it is difficult to reaches grinding aid addition in new nation's standard and is no more than cement weight
0.5% and chloride ion in cement content should be not more than 0.06% requirement, and the salt ion content of liquid cement grinding additive is low,
And it is convenient that it is added, therefore application of the liquid cement grinding additive in current manufacture of cement is than wide.But existing liquid
Body cement grinding aid also has the following disadvantages：Grinding aid product cost is higher；Potent fruit is carried not to the cement of large dosage lime stone
Substantially；Containing harmful components such as the chlorions for having an impact building service life；Grinding aid quality is unstable, and volume is big, so as to lead
Cause cement quality fluctuation.
The content of the invention
For insufficient existing for existing cement industry, the invention provides a kind of cost is low, addition content is few, without chlorion and
There are the cement grinding aid and preparation method of preferable stimulation effect to strength of cement；Cement grinding aid provided by the invention has production
The characteristics of process is simple and convenient to operate and production efficiency is high.
In order to realize foregoing invention purpose, the invention provides a kind of cement grinding aid, by the group of following mass percent
It is grouped into：Polyethylene glycol 5-10%, sorbierite 5-10%, polyglyceryl fatty acid ester 1-3%, diethanol monoisopropanolamine 5-10%, three
Isopropanolamine 5-10%, sodium hydroxide 1-5%, Sodium Polyacrylate 2-8%, microcrystalline cellulose 1-5%, remainder are water.
Preferably, present invention also offers a kind of cement grinding aid, it is made up of the component of following mass percent：It is poly-
Ethylene glycol 6-9%, sorbierite 6-9%, polyglyceryl fatty acid ester 1-2%, diethanol monoisopropanolamine 6-9%, triisopropanolamine 6-9%,
Sodium hydroxide 2-4%, Sodium Polyacrylate 3-7%, microcrystalline cellulose 2-4%, remainder are water.
Preferably, present invention also offers a kind of cement grinding aid, it is made up of the component of following mass percent：It is poly-
Ethylene glycol 8%, sorbierite 8%, polyglyceryl fatty acid ester 1%, diethanol monoisopropanolamine 8%, triisopropanolamine 6%, sodium hydroxide
3%th, Sodium Polyacrylate 5%, microcrystalline cellulose 3%, remainder is water.
Preferably, present invention also offers a kind of cement grinding aid, it is made up of the component of following mass percent：It is poly-
Ethylene glycol 9%, sorbierite 7%, polyglyceryl fatty acid ester 2%, diethanol monoisopropanolamine 7%, triisopropanolamine 7%, sodium hydroxide
4%th, Sodium Polyacrylate 4%, microcrystalline cellulose 2%, remainder are water.
Preferably, present invention also offers a kind of cement grinding aid, it is made up of the component of following mass percent：It is poly-
Ethylene glycol 6%, sorbierite 9%, polyglyceryl fatty acid ester 3%, diethanol monoisopropanolamine 9%, triisopropanolamine 6%, sodium hydroxide
5%th, Sodium Polyacrylate 3%, microcrystalline cellulose 4%, remainder are water.
In order to preferably realize foregoing invention purpose, present invention also offers a kind of preparation method of cement grinding aid, bag
Include following steps：
Step 1：Sodium hydroxide is weighed according to the mass percent, and is dissolved in the water of the mass percent, is stirred
Afterwards, room temperature, obtained solution one are down to；
Step 2：Sodium Polyacrylate is weighed according to the mass percent, is dissolved in the solution one, after having dissolved, stirring is equal
It is even, obtained solution two；
Step 3：Weighed according to the percetage by weight other in addition to sodium hydroxide, Sodium Polyacrylate and microcrystalline cellulose
Raw material, sequentially add in the solution two, stir, obtained solution three；
Step 4：Microcrystalline cellulose is weighed according to the percetage by weight, and adds the solution three, is stirred, water is made
Cement grinding aids.
The beneficial effects of the invention are as follows：The present invention, which does not fill, to be influenceed concrete performance and building service life and endangers people
The material of body health, safety and environmental protection；It can be acted synergistically between each raw material, be advantageous to the reduction of cement fineness, ensure its grain
Degree is reasonably distributed, reduced the early hydration rate of heat release of Adding Mineral Admixtures cement and improves strength of cement；Ensureing cement
Under intensity and use condition, production cost can be reduced, improves the economic benefit and social benefit of cement production enterprise.
Brief description of the drawings
Fig. 1 is the hydration heat of cement temperature curve of the blank sample of contrast experiment one of the present invention and test sample.
Fig. 2 is the hydration heat of cement heat release rate profile of the blank sample of contrast experiment one of the present invention and test sample.
Fig. 3 is the control sample cement of contrast experiment two of the present invention and each age compression strength correlation curve from sample preparation cement.
Embodiment
The invention provides a kind of cement grinding aid, from polyethylene glycol, sorbierite, polyglyceryl fatty acid ester, diethanol
The effect of monoisopropanolamine and triisopropanolamine, grinding aid and activity excitation is preferable；With powder porous microcrystalline cellulose phase interworking
Close, effectively reduce the reunion of particle in powder process；Again work is cooperateed with enhancing components such as sodium hydroxide and Sodium Polyacrylates
With, be advantageous to the reduction of cement fineness, ensure its rational size distribution, improve strength of cement.
For the technical characterstic for illustrating this programme can be understood, below by embodiment, this programme is illustrated.
Embodiment 1
The embodiments of the invention provide a kind of cement grinding aid, the component of following mass content is included：Polyethylene glycol 8%, sorbierite
8%th, polyglyceryl fatty acid ester 1%, diethanol monoisopropanolamine 8%, triisopropanolamine 6%, sodium hydroxide 3%, Sodium Polyacrylate 5%,
Microcrystalline cellulose 3%, remainder are water.
Follow the steps below preparation：
Step 1：Sodium hydroxide is weighed according to 3% proportioning, and is dissolved in the water of prescription quality percentage, after stirring, is down to room
Temperature, obtained solution one；
Step 2：Sodium Polyacrylate is weighed according to 5% proportioning, is dissolved in the solution one, after having dissolved, stirs, be made molten
Liquid two；
Step 3：Weigh polyethylene glycol 8%, sorbierite 8%, polyglyceryl fatty acid ester 1%, diethanol monoisopropanolamine 8%, three isopropyls
Hydramine 6%, sequentially add in the solution two, stir, obtained solution three；
Step 4：Microcrystalline cellulose is weighed according to 3% proportioning, and adds the solution three, stirs, cement grinding aid is made.
Embodiment 2
The embodiments of the invention provide a kind of cement grinding aid, the component of following mass content is included：Polyethylene glycol 9%, sorbierite
7%th, polyglyceryl fatty acid ester 2%, diethanol monoisopropanolamine 7%, triisopropanolamine 7%, sodium hydroxide 4%, Sodium Polyacrylate 4%,
Microcrystalline cellulose 2%, remainder are water.
Follow the steps below preparation：
Step 1：Sodium hydroxide is weighed according to 4% proportioning, and is dissolved in the water of prescription quality percentage, after stirring, is down to room
Temperature, obtained solution one；
Step 2：Sodium Polyacrylate is weighed according to 4% proportioning, is dissolved in the solution one, after having dissolved, stirs, be made molten
Liquid two；
Step 3：Weigh polyethylene glycol 9%, sorbierite 7%, polyglyceryl fatty acid ester 2%, diethanol monoisopropanolamine 7%, three isopropyls
Hydramine 7%, sequentially add in the solution two, stir, obtained solution three；
Step 4：Microcrystalline cellulose is weighed according to 2% proportioning, and adds the solution three, stirs, cement grinding aid is made.
Embodiment 3
The embodiments of the invention provide a kind of cement grinding aid, the component of following mass content is included：Polyethylene glycol 6%, sorbierite
9%th, polyglyceryl fatty acid ester 3%, diethanol monoisopropanolamine 9%, triisopropanolamine 6%, sodium hydroxide 5%, Sodium Polyacrylate 3%,
Microcrystalline cellulose 4%, remainder are water.
Follow the steps below preparation：
Step 1：Sodium hydroxide is weighed according to 5% proportioning, and is dissolved in the water of prescription quality percentage, after stirring, is down to room
Temperature, obtained solution one；
Step 2：Sodium Polyacrylate is weighed according to 3% proportioning, is dissolved in the solution one, after having dissolved, stirs, be made molten
Liquid two；
Step 3：Weigh polyethylene glycol 6%, sorbierite 9%, polyglyceryl fatty acid ester 3%, diethanol monoisopropanolamine 9%, three isopropyls
Hydramine 6%, sequentially add in the solution two, stir, obtained solution three；
Step 4：Microcrystalline cellulose is weighed according to 4% proportioning, and adds the solution three, stirs, cement grinding aid is made.
Contrast experiment one
The test sample produced respectively with not filling the blank sample of cement grinding aid with the cement grinding aid provided using embodiment 1-3
1-3 carries out contrast test.
The material and the cement grinding aid of 0.1% volume that 95% clinker that our company is commonly used and 5% gypsum form
Grinding 30min in Ф 500mm*500mm cement ball mill is added to together, and blank sample cement and test sample water is made after going out mill
Mud, then determine size distribution, hydration heat of cement and the cement physical properties of cement.Pass through the measure to its physical property, water
Mud granularity distribution result is as shown in table 1, and as depicted in figs. 1 and 2, cement physical properties are as shown in table 2 for hydrated cementitious heating curve.
The size distribution of the cement of table 1
Influence of the cement grinding aid of table 2 to cement performance
From in table 1-2 and Fig. 1-2, after the cement grinding aid of the present invention is added, the grain composition of cement is more reasonable, water
Mud fineness reduce, specific surface area increase, fill grinding aid hydrated cementitious speed accelerate, its 3d and 28d solidification after pressure resistance
Degree has significant raising.
Contrast experiment two
Cement grinding aid sample and the cement grinding aid production using embodiment 1-3 as a comparison of certain commercially available brand is respectively adopted
42.5 cement carry out contrast test.
The material that 70% clinker, 5% gypsum and 25% slag powders that our company is commonly used form is mixed with 0.1%
The cement grinding aid of amount is added to grinding 30min in Ф 500mm*500mm cement ball mill together, goes out after mill obtained pair respectively
Than sample cement and from sample preparation 1-3 cement, the size distribution of cement and each age strength of cement are then determined.By to its thing
The measure of rationality energy, cement granularity distribution result is as shown in table 3, and each age strength of cement is as shown in Figure 3.
The size distribution of the cement of table 3
From table 3 and Fig. 3, cement grinding aid of the invention is applied in cement grinding, and with using certain brand cement
The cement of agent production is contrasted, and the cement fineness produced using the cement grinding aid of the present invention is smaller, specific surface area is bigger, water
The size distribution of mud more optimizes, the later stage compression strength of cement is significantly improved.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and
Within principle, any modification, equivalent substitution and improvements made etc., it should be included in the scope of the protection.
Claims (6)
1. a kind of cement grinding aid, it is characterised in that be made up of the raw material of following mass percent：Polyethylene glycol 5-10%, sorb
Alcohol 5-10%, polyglyceryl fatty acid ester 1-3%, diethanol monoisopropanolamine 5-10%, triisopropanolamine 5-10%, sodium hydroxide 1-
5%th, Sodium Polyacrylate 2-8%, microcrystalline cellulose 1-5%, remainder are water.
2. cement grinding aid according to claim 1, it is characterised in that be made up of the component of following mass percent：It is poly-
Ethylene glycol 6-9%, sorbierite 6-9%, polyglyceryl fatty acid ester 1-2%, diethanol monoisopropanolamine 6-9%, triisopropanolamine 6-9%,
Sodium hydroxide 2-4%, Sodium Polyacrylate 3-7%, microcrystalline cellulose 2-4%, remainder are water.
3. cement grinding aid according to claim 1 or 2, it is characterised in that be made up of the component of following mass percent：
Polyethylene glycol 8%, sorbierite 8%, polyglyceryl fatty acid ester 1%, diethanol monoisopropanolamine 8%, triisopropanolamine 6%, sodium hydroxide
3%th, Sodium Polyacrylate 5%, microcrystalline cellulose 3%, remainder are water.
4. cement grinding aid according to claim 1 or 2, it is characterised in that be made up of the component of following mass percent：
Polyethylene glycol 9%, sorbierite 7%, polyglyceryl fatty acid ester 2%, diethanol monoisopropanolamine 7%, triisopropanolamine 7%, sodium hydroxide
4%th, Sodium Polyacrylate 4%, microcrystalline cellulose 2%, remainder are water.
5. cement grinding aid according to claim 1 or 2, it is characterised in that be made up of the component of following mass percent：
Polyethylene glycol 6%, sorbierite 9%, polyglyceryl fatty acid ester 3%, diethanol monoisopropanolamine 9%, triisopropanolamine 6%, sodium hydroxide
5%th, Sodium Polyacrylate 3%, microcrystalline cellulose 4%, remainder are water.
6. the preparation method of a kind of cement grinding aid as described in claim any one of 1-5, it is characterised in that including following step
Suddenly：
Step 1：Sodium hydroxide is weighed according to the mass percent, and is dissolved in the water of the mass percent, is stirred
Afterwards, room temperature, obtained solution one are down to；
Step 2：Sodium Polyacrylate is weighed according to the mass percent, is dissolved in the solution one, after having dissolved, stirring is equal
It is even, obtained solution two；
Step 3：Weighed according to the percetage by weight other in addition to sodium hydroxide, Sodium Polyacrylate and microcrystalline cellulose
Raw material, sequentially add in the solution two, stir, obtained solution three；
Step 4：Microcrystalline cellulose is weighed according to the percetage by weight, and adds the solution three, is stirred, water is made
Cement grinding aids.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711103054.0A CN107601954B (en) | 2017-11-10 | 2017-11-10 | A kind of cement grinding aid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711103054.0A CN107601954B (en) | 2017-11-10 | 2017-11-10 | A kind of cement grinding aid and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107601954A true CN107601954A (en) | 2018-01-19 |
| CN107601954B CN107601954B (en) | 2019-11-12 |
Family
ID=61086116
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711103054.0A Active CN107601954B (en) | 2017-11-10 | 2017-11-10 | A kind of cement grinding aid and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107601954B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109320129A (en) * | 2018-10-22 | 2019-02-12 | 惠州市三化新技术有限公司 | A kind of lignocellulose type cement grinding aid and preparation method thereof |
| CN111470796A (en) * | 2020-03-31 | 2020-07-31 | 辽宁天宝华瑞建材有限公司 | Cement grinding aid |
| CN112174570A (en) * | 2020-10-10 | 2021-01-05 | 江苏润天建材有限公司 | Environment-friendly cement grinding aid and preparation method thereof |
| CN114163162A (en) * | 2021-12-24 | 2022-03-11 | 常州坚鹏建材有限公司 | A kind of mineral powder hardening grinding aid and grinding aid process thereof |
| CN114477844A (en) * | 2022-02-14 | 2022-05-13 | 株洲宏信科技发展有限公司 | Cement raw material grinding aid and preparation method and application thereof |
| CN115784646A (en) * | 2022-12-27 | 2023-03-14 | 中国铁道科学研究院集团有限公司铁道建筑研究所 | A kind of low-heat and low-shrinkage Portland cement and its preparation method |
| CN116730647A (en) * | 2023-02-07 | 2023-09-12 | 临沂德艺科技发展有限公司 | A kind of cement activation enhancer and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080216716A1 (en) * | 2003-12-03 | 2008-09-11 | Mikhail Tselner | Fresh Concrete and Admixture for Fresh Concrete |
| CN102126843A (en) * | 2011-04-19 | 2011-07-20 | 鲁南中联水泥有限公司 | Cement grinding aid and preparation method thereof |
| CN106365497A (en) * | 2016-08-22 | 2017-02-01 | 桂林新艺制冷设备有限责任公司 | High-efficiency cement grinding aid and cement thereof |
-
2017
- 2017-11-10 CN CN201711103054.0A patent/CN107601954B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080216716A1 (en) * | 2003-12-03 | 2008-09-11 | Mikhail Tselner | Fresh Concrete and Admixture for Fresh Concrete |
| CN102126843A (en) * | 2011-04-19 | 2011-07-20 | 鲁南中联水泥有限公司 | Cement grinding aid and preparation method thereof |
| CN106365497A (en) * | 2016-08-22 | 2017-02-01 | 桂林新艺制冷设备有限责任公司 | High-efficiency cement grinding aid and cement thereof |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109320129A (en) * | 2018-10-22 | 2019-02-12 | 惠州市三化新技术有限公司 | A kind of lignocellulose type cement grinding aid and preparation method thereof |
| CN111470796A (en) * | 2020-03-31 | 2020-07-31 | 辽宁天宝华瑞建材有限公司 | Cement grinding aid |
| CN112174570A (en) * | 2020-10-10 | 2021-01-05 | 江苏润天建材有限公司 | Environment-friendly cement grinding aid and preparation method thereof |
| CN112174570B (en) * | 2020-10-10 | 2022-05-03 | 江苏润天建材有限公司 | Environment-friendly cement grinding aid and preparation method thereof |
| CN114163162A (en) * | 2021-12-24 | 2022-03-11 | 常州坚鹏建材有限公司 | A kind of mineral powder hardening grinding aid and grinding aid process thereof |
| CN114163162B (en) * | 2021-12-24 | 2022-08-09 | 常州坚鹏建材有限公司 | Mineral powder hardening grinding aid and grinding-aid process thereof |
| CN114477844A (en) * | 2022-02-14 | 2022-05-13 | 株洲宏信科技发展有限公司 | Cement raw material grinding aid and preparation method and application thereof |
| CN114477844B (en) * | 2022-02-14 | 2022-11-04 | 株洲宏信科技发展有限公司 | Cement raw meal grinding aid and preparation method and application thereof |
| CN115784646A (en) * | 2022-12-27 | 2023-03-14 | 中国铁道科学研究院集团有限公司铁道建筑研究所 | A kind of low-heat and low-shrinkage Portland cement and its preparation method |
| CN115784646B (en) * | 2022-12-27 | 2024-05-28 | 中国铁道科学研究院集团有限公司铁道建筑研究所 | A kind of low heat and low shrinkage silicate cement and preparation method thereof |
| CN116730647A (en) * | 2023-02-07 | 2023-09-12 | 临沂德艺科技发展有限公司 | A kind of cement activation enhancer and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107601954B (en) | 2019-11-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107601954A (en) | A kind of cement grinding aid and preparation method thereof | |
| CN102731010B (en) | Reinforced premix mortar moisture-retention thickening agent and preparation method thereof | |
| CN102126843B (en) | Cement grinding aid and preparation method thereof | |
| CN103601381B (en) | Green high-performance cement and production method thereof | |
| CN103896512B (en) | A shielding agent for improving the negative effect of clay on the cement concrete system mixed with polycarboxylate superplasticizer and its application method | |
| CN106242349A (en) | A kind of granite stone powder complex mineral blending material and preparation method thereof | |
| CN105731855A (en) | Vertical mill slag grinding aid and preparation method thereof | |
| CN103145360A (en) | Viscosity modifier for high or ultrahigh-strength concrete | |
| CN101328028A (en) | A kind of composite hydraulic gelling material | |
| CN103771752A (en) | Composite cement grinding aid | |
| CN106380110B (en) | A kind of graphene oxide is modified cement grinding aid and preparation method thereof | |
| CN112876125A (en) | Cement grinding aid and high early strength cement using same | |
| CN107746198A (en) | A kind of scrap glass powder composite blend and preparation method thereof | |
| CN113121171A (en) | Radiation-proof self-compacting concrete and preparation method thereof | |
| CN104743952A (en) | Activated grinding aid for high titanium slag powder grinding and preparation method thereof | |
| CN105541166A (en) | Grinding aid for composite silicate cement with high limestone doping amount and preparation method thereof | |
| CN104478329A (en) | Preparation method for producing autoclaved aerated concrete block by using antimony ore tailing | |
| CN102863160A (en) | Composite solid excitant and salic gelling material prepared by same | |
| CN109534704A (en) | A kind of Making Use of Tailings preparing cement using golden tailing utilizes method | |
| CN103979828B (en) | A kind of slag base concrete admixture function regulator and preparation method thereof | |
| CN105330189B (en) | Low cost cement prepared by activating flyash agent and its application flyash activator | |
| CN103588409B (en) | Desulphurization building gypsum retardant and preparation method thereof | |
| CN106587867B (en) | Block prepared from river sand as raw material and preparation method thereof | |
| CN102633458A (en) | Cement mixed material containing coal ash and method for preparing cement mixed material | |
| CN106186961B (en) | A kind of coal mine rubber solid material and its spoil lotion |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |