CN104852075B - A kind of glass flow pattern of vanadium cell heap - Google Patents

A kind of glass flow pattern of vanadium cell heap Download PDF

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Publication number
CN104852075B
CN104852075B CN201510180287.5A CN201510180287A CN104852075B CN 104852075 B CN104852075 B CN 104852075B CN 201510180287 A CN201510180287 A CN 201510180287A CN 104852075 B CN104852075 B CN 104852075B
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China
Prior art keywords
pile
electrolyte
series connection
end plate
dividing plate
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CN201510180287.5A
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CN104852075A (en
Inventor
王焱
陈明东
梁君
薛慧婷
李小江
李霁
禹争光
杨德存
白润东
宋冬梅
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DEC Dongfang Turbine Co Ltd
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DEC Dongfang Turbine Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/18Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465Details of groupings of fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

The invention discloses a kind of glass flow pattern of vanadium cell heap, it is characterised in that:Including the first series connection single battery group and the second series connection single battery group, the first series connection single battery group and the second series connection single battery group are separated by pile central dividing plate, and two ends are respectively mounted pile end plate;The pile central dividing plate has electrolyte passage, and respectively leads to the electrolyte inside passage of the first series connection single battery group and the second series connection single battery group, finally comes together in pile central dividing plate;The pile end plate has electrolyte passage to lead to the series connection single battery group of respective side, finally comes together in respective pile end plate;The electrolyte polarity of the pile central dividing plate and the electrolyte opposite polarity of pile end plate.The series connection that the structure design is substantially two small-sized vanadium redox flow battery heaps is fit.It can not only reduce the caused leakage current of multiple monocells directly series connection, and also the vanadium cell heap for two entities of design is connected again reduces cost.It is simple in construction, easy later maintenance.

Description

A kind of glass flow pattern of vanadium cell heap
Technical field
The present invention relates to technical field of new energy storage, specifically a kind of vanadium cell heap turnover glass flow pattern.
Background technology
Vanadium cell also known as vanadium redox battery, it is a kind of new green environment protection battery, and it can realization Learn can be with electric energy mutual conversion.Vanadium redox battery energy conversion efficiency is high, normal temperature operation, environment-friendly, and It is to prepare Large Copacity, scale energy storage device and storage energy size and electric pile structure etc. can be adjusted according to user's request One of preferred manner.
At present, high-power vanadium cell heap mode is prepared various, n cells in series or the series connection of several vanadium cell rickles all may be used To realize.But experiment shows that cells in series number is more, and pile internal leakage current is bigger, causes under vanadium cell heap efficiency Drop;Multiple vanadium cell rickle series connection can consume many raw material, cause cost to increase.
The content of the invention
The invention aims to overcome above-mentioned technical problem there is provided a kind of vanadium cell heap glass flow pattern, the structure was both Avoid n monocell from directly connecting, vanadium cell heap rickle series connection number is reduced again, cost is also reduced.
Realize the technical scheme is that:A kind of glass flow pattern of vanadium cell heap, including first series connection single battery group and Second series connection single battery group, the first series connection single battery group and the second series connection single battery group are separated by pile central dividing plate, and two End is respectively mounted pile end plate;The pile central dividing plate has an electrolyte passage, and respectively lead to the first series connection single battery group and The electrolyte inside passage of second series connection single battery group, finally comes together in pile central dividing plate;The pile end plate has electrolyte Passage leads to the electrolyte inside passage of the series connection single battery group of respective side, finally comes together in respective pile end plate;The electricity The electrolyte polarity of heap central dividing plate and the electrolyte opposite polarity of pile end plate.
The pile central dividing plate has side lower part of the central dividing plate electrolyte entrance in pile central dividing plate, has with upper lateral part Central dividing plate electrolyte outlet;The pile end plate has side lower part of the end plate electrolyte entrance in pile end plate, has with upper lateral part End plate electrolyte outlet.
The central dividing plate electrolyte entrance, central dividing plate electrolyte outlet and end plate electrolyte entrance, end plate electrolyte Export not homonymy.
The electrolyte passage of the pile end plate of the both sides is logical respective independent, does not interfere with each other.
The dividing plate thickeied is installed between the most middle monocell of vanadium cell heap additional, sky is provided for electrolyte side feed liquor Between, also the monocell of series connection is separated, leakage current is reduced.
Pile reinforcing plate is added on the outside of the pile end plate.
The beneficial effects of the invention are as follows:
1st, the present invention can not only reduce the caused leakage current of multiple monocells directly series connection, also be two entities of design Vanadium cell heap connect reduce cost again.
2nd, the positive and negative level inlet of pile and liquid return hole are arranged in pile both sides, reduce both positive and negative polarity fluid reservoir and pile The pipeline of connection, simple in construction, easy later maintenance.
Brief description of the drawings
Fig. 1 is the glass flow pattern schematic perspective view of vanadium cell heap of the present invention;
Fig. 2 is Fig. 1 rear perspective schematic diagram.
Label in figure:1-central dividing plate electrolyte outlet, 2-pile reinforcing plate, the 3-the first series connection single battery group, 4- Pile central dividing plate, the 5-the second series connection single battery group, 6-central dividing plate electrolyte entrance, 7-end plate electrolyte outlet, 8- Pile both sides end plate, 9-end plate electrolyte entrance.
Embodiment
As shown in Figure 1 and Figure 2, a kind of glass flow pattern of vanadium cell heap, including the first series connection single battery group 3 and second are connected Single battery group 5, the first series connection series connection of single battery group 3 and second single battery group 5 is separated by pile central dividing plate 4, two ends point An Zhuan not pile end plate 8;The pile central dividing plate 4 has electrolyte passage, and respectively leads to the first series connection single battery group 3 and The electrolyte inside passage of two series connection single battery groups 5, finally comes together in pile central dividing plate 4;The pile end plate 8 has electrolyte Passage leads to the electrolyte inside passage of the series connection single battery group of respective side, finally comes together in respective pile end plate 8;The electricity The electrolyte polarity of heap central dividing plate 4 is negative, and the electrolyte polarity of the pile end plate 8 is just.The pile central dividing plate 4 has Central dividing plate electrolyte entrance 6 has central dividing plate electrolyte outlet 1 in the side lower part of pile central dividing plate 4 with upper lateral part;It is described Pile end plate 8 has side lower part of the end plate electrolyte entrance 9 in pile end plate 8, has end plate electrolyte outlet 7 with upper lateral part.It is described Central dividing plate electrolyte entrance 6, central dividing plate electrolyte outlet 1 are different from end plate electrolyte entrance 9, end plate electrolyte outlet 7 Side, the entrance and exit of positive and negative electrode electrolyte is respectively distributed to the both sides of vanadium cell, can shorten vanadium cell heap and fluid reservoir it Between pipeline path, make the simple easy care of exterior line, and save corresponding cost.The electrolyte of the pile end plate 8 of the both sides Passage is logical respective independent, does not interfere with each other.The dividing plate thickeied is installed between the most middle monocell of vanadium cell heap additional, has been electrolyte Side feed liquor provides space, also separates the monocell of series connection, reduces leakage current.The outside of pile end plate 8 adds electricity Heap reinforcing plate 2.
The course of work of the present invention is:After the connection of vanadium cell heap peripheral tube road is finished, start control system, both positive and negative polarity electrolysis Liquid enters running status.It is negative(Or just)Pole electrolyte is entered by the central dividing plate electrolyte of the side of vanadium cell pile central dividing plate 4 Mouth 6 enters pile, then divides two-way to respectively enter the first series connection single battery group 3 and the second series connection single battery group 5, by battery It is negative in portion's branch road and circuit system, the first series connection series connection single battery group 5 of single battery group 3 and second(Or just)Pole electrolyte is in Space bar confluxes, and flows out, most afterwards through exterior line, flows back to negative finally by central dividing plate electrolyte outlet 1(Or just)Store up pole Flow container.
Just(Or it is negative)Pole electrolyte point end plate electrolyte entrance 9 of the two-way respectively from vanadium cell heap both sides end plate 8 enters vanadium Battery, just(Or it is negative)Pole electrolyte enters by monocell in the middle of pile inner flow passage flow direction after pile, and two-way is just(Or it is negative) Pole electrolyte is blocked by central dividing plate.The both sides of central dividing plate 4 are just(Or it is negative)Pole electrolyte by pile home loop structure again The end plate electrolyte outlet 7 in feed liquor direction is flowed back to respectively, is finally returned liquid and is flowed back to just through exterior line(Or it is negative)Pole fluid reservoir.

Claims (4)

1. a kind of glass flow pattern of vanadium cell heap, including the first series connection single battery group and the second series connection single battery group, described first Series connection single battery group and the second series connection single battery group are separated by pile central dividing plate, and two ends are respectively mounted pile end plate;Its feature It is:The pile central dividing plate has electrolyte passage, and respectively leads to the first series connection single battery group and the second series connection monocell The electrolyte inside passage of group, finally comes together in pile central dividing plate;The pile end plate has electrolyte passage to lead to respective one The electrolyte inside passage of the series connection single battery group of side, finally comes together in respective pile end plate;The electricity of the pile central dividing plate Solve liquid polarity and the electrolyte opposite polarity of pile end plate;The pile central dividing plate has central dividing plate electrolyte entrance in pile The side lower part of central dividing plate, has central dividing plate electrolyte outlet with upper lateral part;The pile end plate has end plate electrolyte entrance to exist The side lower part of pile end plate, has end plate electrolyte outlet with upper lateral part;The central dividing plate electrolyte entrance, central dividing plate electrolysis Liquid is exported and end plate electrolyte entrance, end plate electrolyte outlet not homonymy.
2. the glass flow pattern of vanadium cell heap according to claim 1, it is characterised in that:The electrolysis of the pile end plate of the both sides Liquid passage is logical respective independent, does not interfere with each other.
3. the glass flow pattern of vanadium cell heap according to claim 1, it is characterised in that:The most middle monocell of vanadium cell heap Between installed the dividing plate thickeied additional, provides space for electrolyte side feed liquor, also separates the monocell of series connection, drop low leakage electrode Stream.
4. the glass flow pattern of vanadium cell heap according to claim 1, it is characterised in that:Electricity is added on the outside of the pile end plate Heap reinforcing plate.
CN201510180287.5A 2015-04-16 2015-04-16 A kind of glass flow pattern of vanadium cell heap Active CN104852075B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510180287.5A CN104852075B (en) 2015-04-16 2015-04-16 A kind of glass flow pattern of vanadium cell heap

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Application Number Priority Date Filing Date Title
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CN104852075B true CN104852075B (en) 2017-07-28

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CN108539241B (en) * 2018-04-12 2020-09-29 四川星明能源环保科技有限公司 Leakage anti-splash collecting device and vanadium electrolyte galvanic pile

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CN2829110Y (en) * 2005-09-06 2006-10-18 上海神力科技有限公司 Energy-saving fuel battery stack with hydrogen supplier
JP2009016216A (en) * 2007-07-05 2009-01-22 Sumitomo Electric Ind Ltd Operation method of redox flow battery composed of plurality of modules
CN102136594A (en) * 2011-02-22 2011-07-27 上海林洋储能科技有限公司 Double-power liquid stream battery electric pile structure and liquid stream battery containing electric pile
US9231268B2 (en) * 2011-12-20 2016-01-05 United Technologies Corporation Flow battery system with standby mode
CN103354294B (en) * 2013-07-17 2016-03-30 大连融科储能技术发展有限公司 A kind of structure of pipeline of flow cell system

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