CN104846259A - Push rod of tool switch - Google Patents

Push rod of tool switch Download PDF

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Publication number
CN104846259A
CN104846259A CN201510187117.XA CN201510187117A CN104846259A CN 104846259 A CN104846259 A CN 104846259A CN 201510187117 A CN201510187117 A CN 201510187117A CN 104846259 A CN104846259 A CN 104846259A
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China
Prior art keywords
powder
push rod
temperature
silicon nitride
nano
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Pending
Application number
CN201510187117.XA
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Chinese (zh)
Inventor
佐藤学
徐振武
菊池祥
骆建功
姜洪刚
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Hangzhou Ke Ming Electronics Co Ltd
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Hangzhou Ke Ming Electronics Co Ltd
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Priority to CN201510187117.XA priority Critical patent/CN104846259A/en
Publication of CN104846259A publication Critical patent/CN104846259A/en
Pending legal-status Critical Current

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Abstract

The invention belongs to the field of processing of mechanical materials, and discloses a push rod of a tool switch. The push rod is made of nanometer yttrium oxide, nanometer cerium oxide, glass fiber, graphite fiber, molybdenum powder, vanadium powder, coupled diatomite, modified attapulgite, modified silicon nitride, aluminum powder, copper powder and iron powder. The push rod has the advantages of good corrosion and friction resistance, high mechanical strength, small density, and simple and feasible making process.

Description

A kind of push rod of tool switch
Technical field
The invention belongs to mechanical material manufacture field, be specifically related to a kind of push rod of tool switch.
Background technology
The major parts of tool switch is trigger and push rod; Currently marketed trigger is widely used in the field such as Machine Tool Electric Appliance, hardware & tools, and wherein having many is the relatively large electrical equipment of power, as cutting machine etc., this kind of machine environment for use is generally poor, load is comparatively large, and longevity of service is therefore also higher to the requirement of switch.But tool switch great majority in the market cannot meet life requirements, mainly there is following problem: 1) alloy material of trigger or push rod adopts general alloy steel material, easily deform after long-time use, physical strength is inadequate, thus cause switch motion dumb, even lost efficacy; 2) during pushrod movement, contact wall back and forth, frictional force is comparatively large, and parts depreciation is serious; 3) acid and alkali-resistance brine corrosion aspect of performance is nowhere near, and needs to improve further.Prior art needs a kind of alloy material stable and reliable for performance to prepare push rod.
Summary of the invention
In order to overcome the deficiencies in the prior art, the invention provides a kind of push rod of tool switch, this push rod is avoided using general steel alloy material, possesses corrosion-resistant and crocking resistance preferably, and physical strength is high and density is little; Present invention also offers the preparation technology of above-mentioned push rod, simple possible, with low cost.
The object of the invention is to be achieved through the following technical solutions,
A push rod for tool switch, it is prepared from by following raw material:
Nano yttrium oxide, nano-cerium oxide, glass fibre, graphite fibre, molybdenum powder, vanadium powder, coupling diatomite, attapulgite modified, modification silicon nitride, aluminium powder, copper powder, iron powder.
Particularly, be prepared from by the raw material of following weight part:
Nano yttrium oxide 1-2 part, nano-cerium oxide 1-2 part, glass fibre 2-3 part, graphite fibre 3-4 part, molybdenum powder 5-6 part, vanadium powder 5-6 part, coupling diatomite 7-9 part, attapulgite modified 7-9 part, modification silicon nitride 10-12 part, aluminium powder 20-30 part, copper powder 50-60 part, iron powder 1000-1200 part.
Preferably, the particle diameter of nano yttrium oxide or nano-cerium oxide is 10-20nm; The diameter of glass fibre or graphite fibre is 5-10um, and length is 30-50um; Molybdenum powder, vanadium powder, aluminium powder, the particle diameter of copper powder and iron powder is 300 orders;
Preferably, the diatomaceous preparation method of described coupling is: diatomite being ground to particle diameter is 300 object powder, silane coupling agent KH-560 and diatomite is added to successively in ethanol, 500 turns/min stirs 30min, dried 5 hours by batch mixing 80 DEG C, grinding, to obtain final product again; Described silane coupling agent KH-560, ethanol and diatomaceous mass ratio are 1:20:10.
Described attapulgite modified preparation method is: added to by attapulgite in stirred reactor, and then add the 1M hydrochloric acid of 2 times of weight, 200 turns/min stirs 5min, centrifugal segregation supernatant liquid, and dry, being ground to particle diameter is 300 orders, to obtain final product.
The preparation method of described modification silicon nitride is: silicon nitride is delivered to ball mill, and being milled to particle diameter is 300 order powder, then powder is placed in container, adds properties-correcting agent subsequently, and 1000 turns/min centrifugal mixer 10min, to obtain final product; Described properties-correcting agent mixes obtained by isopropyl titanate, water and acetone according to the weight ratio of 1:2:1; The addition of described properties-correcting agent is one of percentage of silicon nitride quality.
The preparation method of above-mentioned push rod comprises the steps:
Each raw material for standby is taken according to weight part;
By nano yttrium oxide, nano-cerium oxide, molybdenum powder, vanadium powder, coupling diatomite, attapulgite modified, modification silicon nitride, aluminium powder, copper powder and iron powder, add to successively in stirred reactor, 500 turns/min stirs 10min, static 30min, then adds glass fibre and graphite fibre, 300 turns/min stirs 5min, obtains mixture;
The furnace temperature of electric arc furnace is risen to 450-550 DEG C, then adds mixture, be heated to 1300-1400 DEG C, insulation 50-60min;
The refining of LF stove, refining temperature is 1650-1700 DEG C, and the time, whole process was carried out under nitrogen protection at 80-120min; After refining completes, carry out degassed with vacuum degassing furnace, degassing temperature is 1520-1530 DEG C, vacuum tightness 40-45 handkerchief, and degassing time is at 80-120min;
Degassed complete after, be chilled to room temperature with the rate of temperature fall of 10 DEG C/s, adopt carry out preliminary hot rolling, preliminary hot-rolled temperature is 1100-1200 DEG C, after preliminary hot rolling completes, be chilled to room temperature with the rate of temperature fall of 15 DEG C/s, then carry out secondary hot rolling, the temperature of secondary hot rolling is 850 DEG C, after second heat rolls into, be chilled to 150-200 DEG C with the rate of temperature fall of 15 DEG C/s, insulation 3-4h, finally be chilled to room temperature with the rate of temperature fall of 20 DEG C/s, obtain final product.
The invention also discloses a kind of performance preferably alloy material, raw material composition and preparation method are as above.
The beneficial effect that the present invention obtains mainly comprises:
The present invention uses nano yttrium oxide and nano-cerium oxide component evenly, and granularity is little, is formed and fills the air strengthening, can improve intensity, also possess certain lubrication; The present invention, by carrying out modification to silicon nitride, improves the dispersion effect of silicon nitride, avoids accumulation; Coupling diatomite and the convex Attapulgite of modification fill the effect strengthening, improve antiwear and antifriction ability and softening temperature to body material; The present invention is by selecting various raw metal, and reasonable ratio, makes the physical strength of product, unit elongation and wear resistance increase; By adding glass fibre and graphite fibre, make the uniformity coefficient in length and breadth of interiors of products weave construction, powdered alloy is uniformly dispersed, and substantially increases wear resistance and corrosion resistance.
Embodiment
Technical scheme in the application is understood better in order to make those skilled in the art person, below in conjunction with the application's specific embodiment, carry out clearly, intactly describing to the present invention, obviously, described embodiment is only some embodiments of the present application, instead of whole embodiments.Based on the embodiment in the application, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, should belong to the scope of protection of the invention.
Embodiment 1
A push rod for tool switch, it is prepared from by the raw material of following weight part:
Nano yttrium oxide 1 part, nano-cerium oxide 1 part, 2 parts, glass fibre, graphite fibre 3 parts, molybdenum powder 5 parts, vanadium powder 5 parts, 7 parts, coupling diatomite, attapulgite modified 7 parts, modification silicon nitride 10 parts, aluminium powder 20 parts, copper powder 50 parts, iron powder 1000 parts.
The particle diameter of described nano yttrium oxide or nano-cerium oxide is 10nm; The diameter of described glass fibre or graphite fibre is 5um, and length is 30um; Molybdenum powder, vanadium powder, aluminium powder, the particle diameter of copper powder and iron powder is 300 orders;
The diatomaceous preparation method of described coupling is: diatomite being ground to particle diameter is 300 object powder, and silane coupling agent KH-560 and diatomite are added to successively in ethanol, 500 turns/min stirs 30min, then is dried 5 hours by batch mixing 80 DEG C, and grinding, to obtain final product; Described silane coupling agent KH-560, ethanol and diatomaceous mass ratio are 1:20:10.
Described attapulgite modified preparation method is: added to by attapulgite in stirred reactor, and then add the 1M hydrochloric acid of 2 times of weight, 200 turns/min stirs 5min, centrifugal segregation supernatant liquid, and dry, being ground to particle diameter is 300 orders, to obtain final product.
The preparation method of described modification silicon nitride is: silicon nitride is delivered to ball mill, and being milled to particle diameter is 300 order powder, then powder is placed in container, adds properties-correcting agent subsequently, and 1000 turns/min centrifugal mixer 10min, to obtain final product; Described properties-correcting agent mixes obtained by isopropyl titanate, water and acetone according to the weight ratio of 1:2:1; The addition of described properties-correcting agent is one of percentage of silicon nitride quality.
The preparation method of above-mentioned push rod comprises the steps:
Each raw material for standby is taken according to weight part;
By nano yttrium oxide, nano-cerium oxide, molybdenum powder, vanadium powder, coupling diatomite, attapulgite modified, modification silicon nitride, aluminium powder, copper powder and iron powder, add to successively in stirred reactor, 500 turns/min stirs 10min, static 30min, then adds glass fibre and graphite fibre, 300 turns/min stirs 5min, obtains mixture;
The furnace temperature of electric arc furnace is risen to 450 DEG C, then adds mixture, be heated to 1300 DEG C, insulation 50min;
LF stove (ladle refining furnace) refining, refining temperature is 1650 DEG C, and the time, whole process was carried out under nitrogen protection at 120min; After refining completes, carry out degassed with vacuum degassing furnace, degassing temperature is 1520 DEG C, vacuum tightness 40 handkerchief, and degassing time is at 80min;
Degassed complete after, be chilled to room temperature with the rate of temperature fall of 10 DEG C/s, adopt carry out preliminary hot rolling, preliminary hot-rolled temperature is 1100-1200 DEG C, after preliminary hot rolling completes, be chilled to room temperature with the rate of temperature fall of 15 DEG C/s, then carry out secondary hot rolling, the temperature of secondary hot rolling is 850 DEG C, after second heat rolls into, be chilled to 150 DEG C with the rate of temperature fall of 15 DEG C/s, insulation 3h, finally be chilled to room temperature with the rate of temperature fall of 20 DEG C/s, obtain final product.
Embodiment 2
A push rod for tool switch, it is prepared from by the raw material of following weight part:
Nano yttrium oxide 2 parts, nano-cerium oxide 2 parts, 3 parts, glass fibre, graphite fibre 4 parts, molybdenum powder 6 parts, vanadium powder 6 parts, 9 parts, coupling diatomite, attapulgite modified 9 parts, modification silicon nitride 12 parts, aluminium powder 30 parts, copper powder 60 parts, iron powder 1200 parts.
Wherein, the particle diameter of nano yttrium oxide or nano-cerium oxide is 20nm; The diameter of glass fibre or graphite fibre is 10um, and length is 50um; Molybdenum powder, vanadium powder, aluminium powder, the particle diameter of copper powder and iron powder is 300 orders;
The diatomaceous preparation method of described coupling is: diatomite being ground to particle diameter is 300 object powder, and silane coupling agent KH-560 and diatomite are added to successively in ethanol, 500 turns/min stirs 30min, then is dried 5 hours by batch mixing 80 DEG C, and grinding, to obtain final product; Described silane coupling agent KH-560, ethanol and diatomaceous mass ratio are 1:20:10.
Described attapulgite modified preparation method is: added to by attapulgite in stirred reactor, and then add the 1M hydrochloric acid of 2 times of weight, 200 turns/min stirs 5min, centrifugal segregation supernatant liquid, and dry, being ground to particle diameter is 300 orders, to obtain final product.
The preparation method of described modification silicon nitride is: silicon nitride is delivered to ball mill, and being milled to particle diameter is 300 order powder, then powder is placed in container, adds properties-correcting agent subsequently, and 1000 turns/min centrifugal mixer 10min, to obtain final product; Described properties-correcting agent mixes obtained by isopropyl titanate, water and acetone according to the weight ratio of 1:2:1; The addition of described properties-correcting agent is one of percentage of silicon nitride quality.
The preparation method of above-mentioned push rod comprises the steps:
Each raw material for standby is taken according to weight part;
By nano yttrium oxide, nano-cerium oxide, molybdenum powder, vanadium powder, coupling diatomite, attapulgite modified, modification silicon nitride, aluminium powder, copper powder and iron powder, add to successively in stirred reactor, 500 turns/min stirs 10min, static 30min, then adds glass fibre and graphite fibre, 300 turns/min stirs 5min, obtains mixture;
The furnace temperature of electric arc furnace is risen to 550 DEG C, then adds mixture, be heated to 1400 DEG C, insulation 60min;
The refining of LF stove, refining temperature is 1700 DEG C, and the time, whole process was carried out under nitrogen protection at 80min; After refining completes, carry out degassed with vacuum degassing furnace, degassing temperature is 1530 DEG C, vacuum tightness 45 handkerchief, and degassing time is at 120min;
Degassed complete after, be chilled to room temperature with the rate of temperature fall of 10 DEG C/s, adopt carry out preliminary hot rolling, preliminary hot-rolled temperature is 1100-1200 DEG C, after preliminary hot rolling completes, be chilled to room temperature with the rate of temperature fall of 15 DEG C/s, then carry out secondary hot rolling, the temperature of secondary hot rolling is 850 DEG C, after second heat rolls into, be chilled to 200 DEG C with the rate of temperature fall of 15 DEG C/s, insulation 4h, finally be chilled to room temperature with the rate of temperature fall of 20 DEG C/s, obtain final product.
Embodiment 3
The performance test of push rod prepared by the present invention:
1. wear resisting property test: carry out YG6 bull ring under different rotating speeds, test load 100N, compared with carbide alloy YG 8, in table 1:
Table 1
Group Rotating speed 400rpm, wearing and tearing loss of weight Rotating speed 800rpm, wearing and tearing loss of weight
The embodiment of the present invention 1 0.15 0.78
The embodiment of the present invention 2 0.14 0.76
YG8 0.21 1.07
2. corrosion resistance nature test:
A. in 60% nitric acid, 50 h run are corroded:
The embodiment of the present invention 1: surface is by slight erosion, and form Grey Rough surface, about 1% region becomes numb shape iron rust layer;
Steel as matrix material: most surfaces becomes canescence, more than 40% region forms red point-like rust staining.
B. in natural sea-water, 100 h run are corroded:
The embodiment of the present invention 2: surperficial pole slight erosion, more than 98% keeps light; About 2% region becomes beige spot;
Steel as matrix material: surface becomes grey black rust staining.
3. measuring mechanical property: the GCr15 steel alloy adopting market conventional as a control group, arranges three groups respectively: 1 is embodiment 1 group, and 2 is embodiment 2 groups, and 3 is control group; Concrete test-results is as following table 2:
Table 2
Conclusion: push rod material prepared by the present invention shows good performance in tensile strength, bending strength, elongation after fracture and ballistic work etc., meets the market requirement completely.
Although above done detailed explanation with general explanation and embodiment to this case, on basis of the present invention, can make some modifications or improvements it, this will be apparent to those skilled in the art.Therefore, amendment done without departing from theon the basis of the spirit of the present invention or improvement, all belong to the scope of protection of present invention.

Claims (4)

1. a push rod for tool switch, it is prepared from by following raw material: nano yttrium oxide, nano-cerium oxide, glass fibre, graphite fibre, molybdenum powder, vanadium powder, coupling diatomite, attapulgite modified, modification silicon nitride, aluminium powder, copper powder, iron powder.
2. push rod according to claim 1, is characterized in that, described push rod is prepared from by the raw material of following weight part:
Nano yttrium oxide 1-2 part, nano-cerium oxide 1-2 part, glass fibre 2-3 part, graphite fibre 3-4 part, molybdenum powder 5-6 part, vanadium powder 5-6 part, coupling diatomite 7-9 part, attapulgite modified 7-9 part, modification silicon nitride 10-12 part, aluminium powder 20-30 part, copper powder 50-60 part, iron powder 1000-1200 part.
3. push rod according to claim 2, is characterized in that, the particle diameter of described nano yttrium oxide or nano-cerium oxide is 10-20nm; The diameter of described glass fibre or graphite fibre is 5-10um, and length is 30-50um; Described molybdenum powder, vanadium powder, aluminium powder, the particle diameter of copper powder or iron powder is 300 orders;
The diatomaceous preparation method of described coupling is: diatomite being ground to particle diameter is 300 object powder, and silane coupling agent KH-560 and diatomite are added to successively in ethanol, 500 turns/min stirs 30min, then is dried 5 hours by batch mixing 80 DEG C, and grinding, to obtain final product; Described silane coupling agent KH-560, ethanol and diatomaceous mass ratio are 1:20:10;
Described attapulgite modified preparation method is: added to by attapulgite in stirred reactor, and then add the 1M hydrochloric acid of 2 times of weight, 200 turns/min stirs 5min, centrifugal segregation supernatant liquid, and dry, being ground to particle diameter is 300 orders, to obtain final product;
The preparation method of described modification silicon nitride is: silicon nitride is delivered to ball mill, and being milled to particle diameter is 300 order powder, then powder is placed in container, adds properties-correcting agent subsequently, and 1000 turns/min centrifugal mixer 10min, to obtain final product; Described properties-correcting agent mixes obtained by isopropyl titanate, water and acetone according to the weight ratio of 1:2:1; The addition of described properties-correcting agent is one of percentage of silicon nitride quality.
4. the push rod according to Claims 2 or 3, is characterized in that, the preparation method of described push rod comprises the steps:
1) each raw material for standby is taken according to weight part;
2) by nano yttrium oxide, nano-cerium oxide, molybdenum powder, vanadium powder, coupling diatomite, attapulgite modified, modification silicon nitride, aluminium powder, copper powder and iron powder, add to successively in stirred reactor, 500 turns/min stirs 10min, static 30min, then adds glass fibre and graphite fibre, 300 turns/min stirs 5min, obtains mixture;
3) furnace temperature of electric arc furnace is risen to 450-550 DEG C, then add mixture, be heated to 1300-1400 DEG C, insulation 50-60min; Adopt the refining of LF stove subsequently, refining temperature is 1650-1700 DEG C, and the time, whole process was carried out under nitrogen protection at 80-120min; After refining completes, carry out degassed with vacuum degassing furnace, degassing temperature is 1520-1530 DEG C, vacuum tightness 40-45 handkerchief, and degassing time is at 80-120min;
4) degassed complete after, be chilled to room temperature with the rate of temperature fall of 10 DEG C/s, adopt carry out preliminary hot rolling, preliminary hot-rolled temperature is 1100-1200 DEG C, after preliminary hot rolling completes, be chilled to room temperature with the rate of temperature fall of 15 DEG C/s, then carry out secondary hot rolling, the temperature of secondary hot rolling is 850 DEG C, after second heat rolls into, be chilled to 150-200 DEG C with the rate of temperature fall of 15 DEG C/s, insulation 3-4h, finally be chilled to room temperature with the rate of temperature fall of 20 DEG C/s, obtain final product.
CN201510187117.XA 2015-04-20 2015-04-20 Push rod of tool switch Pending CN104846259A (en)

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