CN104845696B - Method for preparing biomass pellet fuel by mulberry branch fermentation wastes - Google Patents

Method for preparing biomass pellet fuel by mulberry branch fermentation wastes Download PDF

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CN104845696B
CN104845696B CN201510258287.2A CN201510258287A CN104845696B CN 104845696 B CN104845696 B CN 104845696B CN 201510258287 A CN201510258287 A CN 201510258287A CN 104845696 B CN104845696 B CN 104845696B
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ramulus mori
mulberry branch
fermentation wastes
residue
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CN104845696A (en
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黎演明
黄志民
韦光贤
李俊晓
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Guangxi Guisen Biological Energy Technology Co ltd
Guangxi Academy of Sciences
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Guangxi Academy of Sciences
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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  • Processing Of Solid Wastes (AREA)

Abstract

本发明公开一种利用桑枝发酵废弃物制备生物质颗粒燃料的方法,该方法步骤为将桑枝发酵废弃物粉碎至1~3mm,木本植物剩余物粉碎至3~6mm;桑枝发酵废弃物粉末5~40份和木本植物剩余物粉末60~95份搅拌混合均匀后,加热干燥至含水率为14~25%,干燥好的物料送入压辊式环模成型。本发明通过对低热值的桑枝发酵废弃物和高热值的木本植物剩余物进行浮配,可以使生物质原料在更低的环模孔径长比条件下成型,减小环模磨损,并可以有效的提高颗粒燃料的成型率、产品密度、耐久度以及低位热值。The invention discloses a method for preparing biomass granular fuel by using mulberry branch fermentation waste. After stirring and mixing 5-40 parts of plant powder and 60-95 parts of woody plant residue powder, heat and dry to a moisture content of 14-25%, and the dried material is sent to a roller-type ring die for molding. In the present invention, by floating the mulberry branch fermentation waste with low calorific value and woody plant residues with high calorific value, the biomass raw material can be molded under the condition of a lower ring die aperture length ratio, reducing ring die wear and tear. It can effectively improve the molding rate, product density, durability and low calorific value of pellet fuel.

Description

利用桑枝发酵废弃物制备生物质颗粒燃料的方法Method for preparing biomass pellet fuel by using mulberry branch fermentation waste

技术领域technical field

本发明涉及燃料制备技术领域,具体涉及一种利用桑枝发酵废弃物制备生物质颗粒燃料的方法。The invention relates to the technical field of fuel preparation, in particular to a method for preparing biomass particle fuel from mulberry branch fermentation waste.

背景技术Background technique

煤、石油和天然气等不可再生化石资源构成了当今世界能源、化学品和材料工业的基石,为人类文明社会的繁荣做出了巨大贡献。随着社会的发展,人类对能源的需求越来越多,但是地球上化石资源的储藏量却是在逐渐减少,在当前石油资源正面临枯竭和环境保护意识越加强烈的形势下,对地球上最丰富的,具有可再生特性的生物质资源的高效利用已迫在眉睫。我国是农业大国,据2012年相关数字统计,我国农作物秸秆年产总量6.04亿吨,全国林产工业木材剩余物的数量为4000万立方米,造纸业产生的木材剩余物的数量约1万立方米,甘蔗渣的年产量约为4000万吨,这些行业的剩余物绝大部分沦为废弃物,传统的处理方法是在就地露天焚烧,焚烧的浓烟中含有机气融胶等颗粒物,可以形成PM2.5,在短时间内导致空气污染加重,形成雾霾,成为环境负担。Non-renewable fossil resources such as coal, oil and natural gas constitute the cornerstone of the energy, chemical and material industries in the world today, and have made great contributions to the prosperity of human civilized society. With the development of society, human beings demand more and more energy, but the reserves of fossil resources on the earth are gradually decreasing. Under the current situation that oil resources are facing depletion and the awareness of environmental protection is becoming stronger, the impact on the earth The most abundant and renewable biomass resource in the world is imminent. my country is a big agricultural country. According to relevant statistics in 2012, the total annual output of crop straw in my country is 604 million tons, the amount of wood residues in the national forestry industry is 40 million cubic meters, and the amount of wood residues produced by the paper industry is about 10,000 cubic meters. The annual output of rice and bagasse is about 40 million tons. Most of the residues in these industries are reduced to waste. The traditional treatment method is to burn them in the open air. PM2.5 can be formed, leading to aggravated air pollution in a short period of time, forming smog and becoming an environmental burden.

生物质固体成型燃料是一种典型的生物质固体成型燃料,具有高效、洁净、点火容易、CO2零排放等优点,可替代煤炭等化石燃料应用于炊事、供暖等民用领域和锅炉燃烧、发电等工业领域。2011年3月16日发布的《中华人民共和国国民经济和社会发展第十二个五年规划纲要》提出,结合城市大气环境治理,大力推动城市燃煤锅炉改造为生物质成型燃料锅炉,减少城市燃煤量,扩大规模化的生物质成型燃料市场;到2015年,生物质成型燃料年利用量达到1000万吨,相应替代化石能源500万吨标准煤。Biomass solid briquette fuel is a typical biomass solid briquette fuel. It has the advantages of high efficiency, cleanliness, easy ignition, and zero CO2 emission. It can replace coal and other fossil fuels and be used in cooking, heating and other civil fields, as well as boiler combustion and power generation. industrial field. The "Outline of the Twelfth Five-Year Plan for National Economic and Social Development of the People's Republic of China" issued on March 16, 2011 proposes to vigorously promote the transformation of urban coal-fired boilers into biomass briquette fuel boilers in combination with urban atmospheric environment governance, reducing urban Coal consumption, expanding the large-scale biomass briquette fuel market; by 2015, the annual utilization of biomass briquette fuel will reach 10 million tons, correspondingly replacing 5 million tons of standard coal of fossil energy.

目前,我国的生物质固体成型燃料加工行业在原料配比方面普遍存在原料取材单一、成型效率差以及产品品质不达标等问题,如专利CN201010267758.3,专利名称桑枝成型燃料的制造方法,该专利技术方案为将桑枝95-97份和助燃剂3-5份,经粉碎,混合,在压力为50-250MPa,温度为70-250℃的条件下成型。该技术以单一的木薯秆、桑枝、木材边角料等木本生物质原料压制颗粒成型燃料,由于单一木本生物质的内部结构较为坚硬,容易导致成型机的主要部件损坏,缩短了成型机的使用寿命。At present, my country's biomass solid briquette fuel processing industry generally has problems such as single raw material selection, poor molding efficiency, and substandard product quality in terms of raw material ratio, such as patent CN201010267758. The patented technical solution is to grind 95-97 parts of mulberry branches and 3-5 parts of combustion accelerant, mix them, and shape them under the conditions of a pressure of 50-250 MPa and a temperature of 70-250°C. This technology uses single woody biomass raw materials such as cassava stalks, mulberry branches, and wood scraps to press pellets into fuel. Because the internal structure of single woody biomass is relatively hard, it is easy to cause damage to the main components of the molding machine and shorten the life of the molding machine. service life.

发明内容Contents of the invention

本发明提供一种利用桑枝发酵废弃物制备生物质颗粒燃料的配方和工艺,通过对低热值的桑枝发酵废弃物和高热值的木本植物剩余物进行浮配,可以使生物质原料在更低的环模孔径长比条件下成型,减小环模磨损,并可以有效的提高颗粒燃料的成型率、产品密度、耐久度以及低位热值,解决现有生物质成型燃料存在的原料取材单一性,压制成型率低、燃烧值差、燃烧不充分等问题。The invention provides a formula and process for preparing biomass granular fuel by using mulberry branch fermentation waste. By floating the mulberry branch fermentation waste with low calorific value and the woody plant residue with high calorific value, the biomass raw material can be made Molding under the condition of lower ring die aperture length ratio reduces the wear of ring die, and can effectively improve the molding rate, product density, durability and low calorific value of pellet fuel, and solve the raw material selection of existing biomass molding fuel Uniformity, low compression molding rate, poor combustion value, insufficient combustion and other problems.

为了实现上述目的,本发明采用了以下技术方案:一种利用桑枝发酵废弃物制备生物质颗粒燃料的方法,以桑枝废弃物和木本植物剩余物为原料,包括以下步骤:In order to achieve the above object, the present invention adopts the following technical solutions: a method for preparing biomass pellet fuel by using mulberry branch fermentation waste, using mulberry branch waste and woody plant residues as raw materials, comprising the following steps:

1)粉碎:将桑枝发酵废弃物粉碎至 1~3mm,木本植物剩余物粉碎至3~6mm;1) Crushing: crush the fermented waste of mulberry branches to 1~3mm, and crush the residues of woody plants to 3~6mm;

2)搅拌混合:按照重量份数比,将步骤1)得到桑枝发酵废弃物粉末5~40份和木本植物剩余物粉末60~95份搅拌混合均匀;2) Stirring and mixing: According to the ratio of parts by weight, 5-40 parts of mulberry branch fermentation waste powder obtained in step 1) and 60-95 parts of woody plant residue powder are stirred and mixed evenly;

3)干燥:将步骤2)混合均匀的物料加热干燥至含水率为14~25%;其中优选含水率为16±0.5 %;3) Drying: heat and dry the homogeneously mixed material in step 2) until the moisture content is 14~25%; the preferred moisture content is 16±0.5%;

4)压制成型:将步骤3)干燥好的物料送入压辊式环模成型机压制成无孔实心圆柱型、密度在1.0~1.4 g/cm3的生物质颗粒燃料。4) Compression forming: Send the dried material in step 3) into a roller ring die forming machine to form a non-porous solid cylindrical biomass pellet fuel with a density of 1.0~1.4 g/cm 3 .

作为本发明的进一步限定,所述的桑枝发酵废弃物其组分包括:桑枝80~90份、木薯酒精废渣7~15份、氧化钙1~5份、硫酸钙0.5~3份。其优选方案为桑枝85重量份、木薯酒精废渣12重量份、氧化钙2重量份以及硫酸钙1重量份。以上所用到的桑枝发酵废弃物可以是桑枝屑为主要成分、用来栽培各种菌菇后的废弃物。As a further limitation of the present invention, the components of the mulberry branch fermentation waste include: 80-90 parts of mulberry branch, 7-15 parts of cassava alcohol waste residue, 1-5 parts of calcium oxide, and 0.5-3 parts of calcium sulfate. Its preferred scheme is 85 parts by weight of mulberry branches, 12 parts by weight of cassava alcohol waste residue, 2 parts by weight of calcium oxide and 1 part by weight of calcium sulfate. The mulberry branch fermentation waste used above can be the waste after the mulberry branch scraps are used as the main component to cultivate various mushrooms.

作为本发明的进一步限定,其特征在于,所述的木本植物剩余物为桑枝、桉树皮、松木屑中的一种或是它们的组合物。生物质颗粒燃料的优选原料组成包括12~15重量份桑枝发酵废弃物、80~85重量份的桉树皮和5~8重量份的松木屑。As a further limitation of the present invention, it is characterized in that the woody plant residue is one of mulberry branches, eucalyptus bark, and pine sawdust or a combination thereof. The preferred raw material composition of the biomass granular fuel includes 12-15 parts by weight of mulberry branch fermentation waste, 80-85 parts by weight of eucalyptus bark and 5-8 parts by weight of pine wood chips.

作为本发明的进一步限定,所述的压辊式环模成型机的环模孔长径比为3.5~5:1之间。As a further limitation of the present invention, the ring die hole aspect ratio of the pressure roller ring die forming machine is between 3.5 and 5:1.

作为本发明的进一步限定,所述的生物质颗粒燃料直径为6~8mm。优选直径为8mm,长度为30~40 mm的实心圆柱体。生物质木屑颗粒燃料的粒度直接影响到燃烧速度和煅烧带的厚度,为了保证物料在煅烧带有足够的停留时间,燃料粒度与物料粒度有一定的比例。燃料粒度过小,燃烧速度过快,使高温带过于集中,生料在高温带停留时间过短,烧成时的主要反应来不及进行,影响烧成质量,即燃烧热值、燃烧率和热效率降低、灰分增加。燃料粒度也不易过大,会导致燃烧速度减慢,煅烧带拉长,火力不集中,降低煅烧带温度。As a further limitation of the present invention, the diameter of the biomass particle fuel is 6-8 mm. A solid cylinder with a diameter of 8 mm and a length of 30 to 40 mm is preferred. The particle size of biomass wood pellet fuel directly affects the burning speed and the thickness of the calcination zone. In order to ensure sufficient residence time of the material in the calcination zone, the particle size of the fuel has a certain ratio to the particle size of the material. The particle size of the fuel is too small and the combustion speed is too fast, so that the high temperature zone is too concentrated, the residence time of the raw material in the high temperature zone is too short, the main reaction during firing is too late, and the firing quality is affected, that is, the combustion calorific value, combustion rate and thermal efficiency are reduced. , Ash increased. The particle size of the fuel is not easy to be too large, which will slow down the combustion speed, elongate the calcination zone, and the firepower will not be concentrated, which will reduce the temperature of the calcination zone.

为了使本发明公开充分,本发明技术方案实现的原理为:桑枝发酵废弃物是经过多种微生物的发酵作用,纤维素、半纤维素和木质等均已被不同程度的降解,在压制成型过程中具有更好的流动性和粘性,起到良好的润滑和粘结作用,可填充到原材料的空隙中,将原材料的各组分紧密结合在一起,有效的提高颗粒燃料的成型率、产品密度和耐久度。此外,桑枝发酵废弃物中含有少量的氧化钙和硫酸钙,在燃烧过程中可与Si、K等元素反应生成新的化合物,提高积灰软化温度,从而具有抗结渣效果。与此同时,本发明辅以适当质量份的高燃烧热值的木本植物剩余物进行混合浮配,使生物质颗粒燃料产品的燃烧热值符合使用标准。In order to make the disclosure of the present invention sufficient, the principle of the realization of the technical solution of the present invention is: the mulberry branch fermentation waste is fermented by various microorganisms, and the cellulose, hemicellulose and wood have been degraded to varying degrees. It has better fluidity and viscosity during the process, and plays a good role in lubrication and bonding. It can be filled into the gaps of raw materials, and the components of raw materials are closely combined to effectively improve the molding rate and product quality of pellet fuel. density and durability. In addition, the mulberry branch fermentation waste contains a small amount of calcium oxide and calcium sulfate, which can react with Si, K and other elements during the combustion process to form new compounds, which can increase the softening temperature of ash deposits and thus have an anti-slagging effect. At the same time, the present invention mixes and floats woody plant residues with a high combustion calorific value in an appropriate mass portion, so that the combustion calorific value of the biomass particle fuel product meets the use standard.

本发明通过上述方案取得良好的技术效果:The present invention obtains good technical effect through above-mentioned scheme:

(1)使用桑枝发酵废弃物作为生物质颗粒燃料的部分原料,可以使生物质原料在更低的环模孔径长比条件下成型,减小环模磨损,延长成型机的寿命。并可有效的提高颗粒燃料的成型率、产品密度、耐久度以及结渣情况。(1) Using mulberry branch fermentation waste as part of the raw material of biomass pellet fuel can make the biomass raw material molded under the condition of lower ring die aperture length ratio, reduce ring die wear and prolong the life of the molding machine. And it can effectively improve the molding rate, product density, durability and slagging of pellet fuel.

(2)桉树皮、桑枝以及松木屑均为大宗的木本植物剩余物,来源广,价格便宜。本发明所述的颗粒燃料在制造过程中不添加其他胶黏剂,工艺过程简单,适合产业化生产。(2) Eucalyptus bark, mulberry branches and pine sawdust are bulk woody plant residues with wide sources and cheap prices. The granular fuel of the present invention does not add other adhesives in the manufacturing process, the process is simple, and it is suitable for industrial production.

(3)原料之一松木屑也是原料的重要组成,松木屑中含有丰富的油质松脂,有一定粘性和助燃性,可改善生物质颗粒燃料的燃烧性能。(3) Pine sawdust, one of the raw materials, is also an important component of raw materials. Pine sawdust is rich in oily turpentine, which has certain viscosity and combustion-supporting properties, and can improve the combustion performance of biomass pellet fuel.

具体实施方式detailed description

下面结合具体的实施例,对本发明作进一步的阐述,但不限于这些具体的实施例,而所用的实施例均按上述的步骤操作。Below in conjunction with specific embodiment, the present invention is further elaborated, but not limited to these specific embodiment, and the embodiment used all operates according to above-mentioned steps.

实施例1:Example 1:

将桑枝发酵废弃物、木本植物剩余物原料按下述参数分别进行粉碎。The mulberry branch fermentation waste and woody plant residue raw materials are respectively pulverized according to the following parameters.

桑枝发酵废弃物:颗粒的长度小于2 mm;桉树皮:颗粒的长度小于5 mm;松木屑:颗粒的长度小于3 mm。本实施例中桑枝发酵废弃物中组分为:桑枝90份、木薯酒精废渣7份、氧化钙1份、硫酸钙2份。Mulberry branch fermentation waste: the length of the particles is less than 2 mm; eucalyptus bark: the length of the particles is less than 5 mm; pine sawdust: the length of the particles is less than 3 mm. The components in the fermentation waste of mulberry branch in this embodiment are: 90 parts of mulberry branch, 7 parts of cassava alcohol waste residue, 1 part of calcium oxide, and 2 parts of calcium sulfate.

在计量斗的辅助下按重量份数称料,将12重量份的桑枝发酵废弃物、81重量份的桉树皮颗粒和7重量份的松木屑搅拌混合均匀后送入气流干燥室加热干燥至含水率为16.0%左右,最后经输送机送入压辊式环模型压块成型机中,在环模压孔长径比为4:1的条件下进行连续挤压成直径为8 mm,长度为32 mm的圆柱型颗粒,自然冷却后包装即得生物质颗粒燃料。经计算,按上述的制造方法,产品成型率能达到97.4%,产品密度为1.13 g/cm3,灰分为3.62 %,空气干燥基低位发热量为4146.9 kcal/kg。Weighing by weight under the assistance of measuring hopper, 12 weight parts of mulberry branch fermentation waste, 81 weight parts of eucalyptus bark particles and 7 weight parts of pine wood chips are stirred and mixed, and then sent into the airflow drying chamber to be heated and dried to The moisture content is about 16.0%, and finally sent to the roller-type ring mold briquetting machine by the conveyor, and continuously extruded under the condition that the ring mold hole length-to-diameter ratio is 4:1 to a diameter of 8 mm and a length of 32 mm cylindrical pellets, packaged after natural cooling to obtain biomass pellet fuel. According to the calculation, according to the above-mentioned manufacturing method, the molding rate of the product can reach 97.4%, the product density is 1.13 g/cm 3 , the ash content is 3.62%, and the low-level calorific value of the air-dried basis is 4146.9 kcal/kg.

实施例2:Example 2:

将桑枝发酵废弃物、木本植物剩余物原料按下述参数分别进行粉碎。The mulberry branch fermentation waste and woody plant residue raw materials are respectively pulverized according to the following parameters.

桑枝发酵废弃物:颗粒的长度1~2 mm;桑枝:颗粒的长度小于4 mm;松木屑:颗粒的长度小于3 mm。本实施例中桑枝发酵废弃物中组分为:桑枝80份、木薯酒精废渣15份、氧化钙4.5份、硫酸钙0.5份。Mulberry branch fermentation waste: particle length 1-2 mm; mulberry branch: particle length less than 4 mm; pine sawdust: particle length less than 3 mm. The components in the fermentation waste of mulberry branch in this embodiment are: 80 parts of mulberry branch, 15 parts of cassava alcohol waste residue, 4.5 parts of calcium oxide, and 0.5 part of calcium sulfate.

在计量斗的辅助下按重量份数称料,将18重量份的桑枝发酵废弃物、72重量份的桉树皮颗粒和10重量份的松木屑搅拌混合均匀后送入气流干燥室加热干燥至含水率为17.5 %左右,最后经输送机送入压辊式环模型压块成型机中,在环模压孔长径比为4.5:1的条件下进行连续挤压成直径为8 mm,长度为36 mm的圆柱型颗粒,自然冷却后包装即得生物质颗粒燃料。经计算,按上述的制造方法,产品成型率能达到96.8 %,产品密度为1.19 g/cm3,灰分为2.56 %,空气干燥基低位发热量为4266.6 kcal/kg。Weighing by parts by weight under the assistance of a measuring hopper, the mulberry branch fermentation waste of 18 parts by weight, the eucalyptus bark particles of 72 parts by weight and the pine chips of 10 parts by weight are stirred and mixed and sent into the airflow drying chamber to be heated and dried to The water content is about 17.5%, and finally sent to the roller-type ring mold briquetting machine through the conveyor, and continuously extruded under the condition of the ring mold hole length-to-diameter ratio of 4.5:1 to a diameter of 8 mm and a length of 36 mm cylindrical pellets, after natural cooling, packaged to obtain biomass pellet fuel. According to the calculation, according to the above-mentioned manufacturing method, the molding rate of the product can reach 96.8%, the product density is 1.19 g/cm 3 , the ash content is 2.56%, and the low-level calorific value of the air-dried basis is 4266.6 kcal/kg.

实施例3:Example 3:

将桑枝发酵废弃物、木本植物剩余物原料按下述参数分别进行粉碎。桑枝发酵废弃物:颗粒的长度2 mm;桉树皮:颗粒的长度6 mm;桑枝:颗粒的长度4 mm;松木屑:颗粒的长度4 mm。本实施例中桑枝发酵废弃物中组分为:桑枝85份、木薯酒精废渣10份、氧化钙2份、硫酸钙3份。The mulberry branch fermentation waste and woody plant residue raw materials are respectively pulverized according to the following parameters. Mulberry branch fermentation waste: particle length 2 mm; eucalyptus bark: particle length 6 mm; mulberry branch: particle length 4 mm; pine sawdust: particle length 4 mm. The components in the fermentation waste of mulberry branch in this embodiment are: 85 parts of mulberry branch, 10 parts of cassava alcohol waste residue, 2 parts of calcium oxide, and 3 parts of calcium sulfate.

在计量斗的辅助下按重量份数称料,将18重量份的桑枝发酵废弃物、32重量份的桉树皮颗粒、35重量份的桑枝和15重量份的松木屑搅拌混合均匀后送入气流干燥室加热干燥至含水率为16.5 %左右,最后经输送机送入压辊式环模型压块成型机中,在环模压孔长径比为4.2:1的条件下进行连续挤压成直径为6 mm,长度为25~30 mm的圆柱型颗粒,自然冷却后包装即得生物质颗粒燃料。经计算,按上述的制造方法,产品成型率能达到97.0%,产品密度为1.16 g/cm3,灰分为3.06 %,空气干燥基低位发热量为4216.6 kcal/kg。Weighing by weight parts under the assistance of the measuring hopper, the mulberry branch of 18 parts by weight, the eucalyptus bark particle of 32 parts by weight, the mulberry branch of 35 parts by weight and the pine sawdust of 15 parts by weight are evenly mixed and then sent It is heated and dried in the airflow drying chamber until the moisture content is about 16.5%, and finally sent to the roller-type ring model briquetting machine through the conveyor, and is continuously extruded under the condition that the length-to-diameter ratio of the ring mold hole is 4.2:1. Cylindrical particles with a diameter of 6 mm and a length of 25-30 mm are packaged after natural cooling to obtain biomass pellet fuel. According to the calculation, according to the above-mentioned manufacturing method, the molding rate of the product can reach 97.0%, the product density is 1.16 g/cm 3 , the ash content is 3.06%, and the low-level calorific value is 4216.6 kcal/kg on an air-dried basis.

实施例4Example 4

将桑枝发酵废弃物、木本植物剩余物原料按下述参数分别进行粉碎。The mulberry branch fermentation waste and woody plant residue raw materials are respectively pulverized according to the following parameters.

桑枝发酵废弃物:颗粒的长度1 mm;桉树皮:颗粒的长度、桑枝、松木屑:颗粒的长度3 mm。本实施例中桑枝发酵废弃物中组分为:桑枝82份、木薯酒精废渣13份、氧化钙2份、硫酸钙3份。Mulberry branch fermentation waste: the length of the particle is 1 mm; Eucalyptus bark: the length of the particle; mulberry branch and pine sawdust: the length of the particle is 3 mm. The components in the fermentation waste of mulberry branch in this embodiment are: 82 parts of mulberry branch, 13 parts of cassava alcohol waste residue, 2 parts of calcium oxide, and 3 parts of calcium sulfate.

在计量斗的辅助下按重量份数称料,将40重量份的桑枝发酵废弃物、30重量份的桉树皮颗粒、30重量份的桑枝搅拌混合均匀后送入气流干燥室加热干燥至含水率为16.5 %左右,最后经输送机送入压辊式环模型压块成型机中,在环模压孔长径比为3.5:1的条件下进行连续挤压成直径为7mm,长度为24.5mm的圆柱型颗粒,自然冷却后包装即得生物质颗粒燃料。经计算,按上述的制造方法,产品成型率能达到96.0 %,产品密度为1.0g/cm3,灰分为3.3 %,空气干燥基低位发热量为4420.2 kcal/kg。Under the assistance of measuring hopper, weigh by weight, send into the airflow drying chamber after being mixed evenly with 40 parts by weight of mulberry branch fermentation waste, 30 parts by weight of eucalyptus bark particles, and 30 parts by weight of mulberry branch. The moisture content is about 16.5%, and finally sent to the roller-type ring model briquetting machine by the conveyor, and continuously extruded under the condition of the ring mold hole length-to-diameter ratio of 3.5:1 to a diameter of 7mm and a length of 24.5 mm cylindrical pellets, which are packaged after natural cooling to obtain biomass pellet fuel. According to the calculation, according to the above-mentioned manufacturing method, the molding rate of the product can reach 96.0%, the product density is 1.0g/cm 3 , the ash content is 3.3%, and the low-level calorific value of the air-dried basis is 4420.2 kcal/kg.

实施例5Example 5

将桑枝发酵废弃物、木本植物剩余物原料按下述参数分别进行粉碎。The mulberry branch fermentation waste and woody plant residue raw materials are respectively pulverized according to the following parameters.

桑枝发酵废弃物:颗粒的长度小于2 mm;桉树皮、桑枝、松木屑:颗粒的长度3 mm。本实施例中桑枝发酵废弃物中组分为:桑枝80份、木薯酒精废渣7份、氧化钙10份、硫酸钙3份。Mulberry branch fermentation waste: the length of the particles is less than 2 mm; eucalyptus bark, mulberry branches, and pine sawdust: the length of the particles is 3 mm. The components in the fermentation waste of mulberry branch in this embodiment are: 80 parts of mulberry branch, 7 parts of cassava alcohol waste residue, 10 parts of calcium oxide, and 3 parts of calcium sulfate.

在计量斗的辅助下按重量份数称料,将5重量份的桑枝发酵废弃物、30重量份的桉树皮颗粒、50重量份的桑枝和15重量份的松木屑搅拌混合均匀后送入气流干燥室加热干燥至含水率为25 %左右,最后经输送机送入压辊式环模型压块成型机中,在环模压孔长径比为5:1的条件下进行连续挤压成直径为6.5mm,长度为32.5 mm的圆柱型颗粒,自然冷却后包装即得生物质颗粒燃料。经计算,按上述的制造方法,产品成型率能达到97.5 %,产品密度为1.4g/cm3,灰分为2.95 %,空气干燥基低位发热量为4320.0 kcal/kg。With the assistance of a measuring hopper, weigh in parts by weight, stir and mix the mulberry branch fermentation waste of 5 parts by weight, the eucalyptus bark particles of 30 parts by weight, the mulberry branches of 50 parts by weight and the pine wood chips of 15 parts by weight and send It is heated and dried in the air-flow drying chamber until the moisture content is about 25%, and finally sent to the roller-type ring mold briquetting machine through the conveyor, and is continuously extruded under the condition that the length-to-diameter ratio of the ring mold hole is 5:1. Cylindrical pellets with a diameter of 6.5 mm and a length of 32.5 mm are packaged after natural cooling to obtain biomass pellet fuel. According to the calculation, according to the above manufacturing method, the molding rate of the product can reach 97.5%, the product density is 1.4g/cm 3 , the ash content is 2.95%, and the low-level calorific value is 4320.0 kcal/kg on an air-dried basis.

实施例6Example 6

将桑枝发酵废弃物、木本植物剩余物原料按下述参数分别进行粉碎。The mulberry branch fermentation waste and woody plant residue raw materials are respectively pulverized according to the following parameters.

桑枝发酵废弃物:颗粒的长度3 mm;桉树皮、松木屑:颗粒的长度6 mm。本实施例中桑枝发酵废弃物中组分为:桑枝86份、木薯酒精废渣7份、氧化钙4.5份、硫酸钙2.5份。Mulberry branch fermentation waste: the length of the particles is 3 mm; eucalyptus bark and pine sawdust: the length of the particles is 6 mm. The components in the fermentation waste of mulberry branch in this embodiment are: 86 parts of mulberry branch, 7 parts of cassava alcohol waste residue, 4.5 parts of calcium oxide, and 2.5 parts of calcium sulfate.

在计量斗的辅助下按重量份数称料,将20重量份的桑枝发酵废弃物、40重量份的桉树皮颗粒、40重量份的松木屑搅拌混合均匀后送入气流干燥室加热干燥至含水率为17.5%左右,最后经输送机送入压辊式环模型压块成型机中,在环模压孔长径比为4:1的条件下进行连续挤压成直径为6 mm,长度为24 mm的圆柱型颗粒,自然冷却后包装即得生物质颗粒燃料。经计算,按上述的制造方法,产品成型率能达到98.0 %,产品密度为1.4 g/cm3,灰分为3.20 %,空气干燥基低位发热量为4325.0kcal/kg。Weighing by weight parts under the assistance of measuring hopper, 20 weight parts of mulberry branch fermentation waste, 40 weight parts of eucalyptus bark particles, 40 weight parts of pine wood chips are stirred and mixed and then sent into the airflow drying chamber to be heated and dried to The moisture content is about 17.5%, and finally sent to the roller-type ring mold briquetting machine through the conveyor, and is continuously extruded under the condition that the length-to-diameter ratio of the ring mold hole is 4:1 to form a diameter of 6 mm and a length of 24 mm cylindrical pellets, packaged after natural cooling to obtain biomass pellet fuel. According to the calculation, according to the above-mentioned manufacturing method, the molding rate of the product can reach 98.0%, the product density is 1.4 g/cm 3 , the ash content is 3.20%, and the low-level calorific value of the air-dried basis is 4325.0kcal/kg.

实施例7Example 7

将桑枝发酵废弃物、木本植物剩余物原料按下述参数分别进行粉碎。The mulberry branch fermentation waste and woody plant residue raw materials are respectively pulverized according to the following parameters.

桑枝发酵废弃物:颗粒的长度2~3 mm;桉树皮:颗粒的长度4 mm。本实施例中桑枝发酵废弃物中组分为:桑枝85份、木薯酒精废渣10份、氧化钙2份、硫酸钙3份。Mulberry branch fermentation waste: the length of the particles is 2-3 mm; Eucalyptus bark: the length of the particles is 4 mm. The components in the fermentation waste of mulberry branch in this embodiment are: 85 parts of mulberry branch, 10 parts of cassava alcohol waste residue, 2 parts of calcium oxide, and 3 parts of calcium sulfate.

在计量斗的辅助下按重量份数称料,将30重量份的桑枝发酵废弃物、70重量份的桉树皮颗粒搅拌混合均匀后送入气流干燥室加热干燥至含水率为16.5 %左右,最后经输送机送入压辊式环模型压块成型机中,在环模压孔长径比为4.5:1的条件下进行连续挤压成直径为7mm,长度为31.5mm的圆柱型颗粒,自然冷却后包装即得生物质颗粒燃料。经计算,按上述的制造方法,产品成型率能达到97.2 %,产品密度为1.35 g/cm3,灰分为3.36 %,空气干燥基低位发热量为4185.6 kcal/kg。Under the assistance of measuring hopper, weigh by parts by weight, the mulberry branch fermentation waste of 30 parts by weight, the eucalyptus bark particle of 70 parts by weight are stirred and mixed, and then sent into the airflow drying chamber to be heated and dried to about 16.5% moisture content, Finally, it is sent to the roller-type ring mold briquetting machine through the conveyor, and is continuously extruded into cylindrical particles with a diameter of 7mm and a length of 31.5mm under the condition that the aspect ratio of the ring mold hole is 4.5:1. After cooling, it is packaged to obtain the biomass pellet fuel. According to the calculation, according to the above-mentioned manufacturing method, the molding rate of the product can reach 97.2%, the product density is 1.35 g/cm 3 , the ash content is 3.36%, and the low-level calorific value is 4185.6 kcal/kg on an air-dried basis.

实施例8Example 8

将桑枝发酵废弃物、木本植物剩余物原料按下述参数分别进行粉碎。The mulberry branch fermentation waste and woody plant residue raw materials are respectively pulverized according to the following parameters.

桑枝发酵废弃物:颗粒的长度2.5 mm;松木屑:颗粒的长度5 mm。本实施例中桑枝发酵废弃物中组分为:桑枝90份、木薯酒精废渣8份、氧化钙1份、硫酸钙1份。Mulberry branch fermentation waste: the length of the particles is 2.5 mm; pine sawdust: the length of the particles is 5 mm. The components in the fermentation waste of mulberry branch in this embodiment are: 90 parts of mulberry branch, 8 parts of cassava alcohol waste residue, 1 part of calcium oxide, and 1 part of calcium sulfate.

在计量斗的辅助下按重量份数称料,将35重量份的桑枝发酵废弃物、65重量份的松木屑搅拌混合均匀后送入气流干燥室加热干燥至含水率为18.5 %左右,最后经输送机送入压辊式环模型压块成型机中,在环模压孔长径比为3.5:1的条件下进行连续挤压成直径为8 mm,长度为28 mm的圆柱型颗粒,自然冷却后包装即得生物质颗粒燃料。经计算,按上述的制造方法,产品成型率能达到98.2 %,产品密度为1.25 g/cm3,灰分为3.10 %,空气干燥基低位发热量为4200.0kcal/kg。With the assistance of the measuring hopper, weigh the materials in parts by weight, stir and mix the mulberry branch fermentation waste of 35 parts by weight and the pine sawdust of 65 parts by weight, and then send them into the airflow drying chamber to heat and dry to about 18.5% moisture content, and finally It is sent to the roller-type ring model briquetting machine by the conveyor, and is continuously extruded into cylindrical particles with a diameter of 8 mm and a length of 28 mm under the condition that the aspect ratio of the ring mold hole is 3.5:1. After cooling, it is packaged to obtain the biomass pellet fuel. According to the calculation, according to the above-mentioned manufacturing method, the molding rate of the product can reach 98.2%, the product density is 1.25 g/cm 3 , the ash content is 3.10%, and the low-level calorific value is 4200.0kcal/kg on an air-dried basis.

实施例9Example 9

将桑枝发酵废弃物、木本植物剩余物原料按下述参数分别进行粉碎。The mulberry branch fermentation waste and woody plant residue raw materials are respectively pulverized according to the following parameters.

桑枝发酵废弃物:颗粒的长度2 mm;桑枝、松木屑:颗粒的长度3 mm。本实施例中桑枝发酵废弃物中组分为:桑枝88份、木薯酒精废渣7份、氧化钙2.5份、硫酸钙2.5份。Mulberry branch fermentation waste: the particle length is 2 mm; mulberry branch and pine sawdust: the particle length is 3 mm. The components in the fermentation waste of mulberry branch in this embodiment are: 88 parts of mulberry branch, 7 parts of cassava alcohol waste residue, 2.5 parts of calcium oxide, and 2.5 parts of calcium sulfate.

在计量斗的辅助下按重量份数称料,将40重量份的桑枝发酵废弃物、30重量份的桑枝和30重量份的松木屑搅拌混合均匀后送入气流干燥室加热干燥至含水率为20.5 %左右,最后经输送机送入压辊式环模型压块成型机中,在环模压孔长径比为5:1的条件下进行连续挤压成直径为7.5 mm,长度为37.5mm的圆柱型颗粒,自然冷却后包装即得生物质颗粒燃料。经计算,按上述的制造方法,产品成型率能达到98.8 %,产品密度为1.36 g/cm3,灰分为3.26 %,空气干燥基低位发热量为4256.5 kcal/kg。With the aid of a measuring hopper, weigh in parts by weight, stir and mix 40 parts by weight of mulberry branch fermentation waste, 30 parts by weight of mulberry branch and 30 parts by weight of pine wood chips, and then send them into the airflow drying chamber to heat and dry to moisture content The rate is about 20.5%, and finally sent to the roller-type ring model briquetting machine by the conveyor, and continuously extruded under the condition that the length-to-diameter ratio of the ring mold hole is 5:1, the diameter is 7.5 mm, and the length is 37.5 mm. mm cylindrical pellets, which are packaged after natural cooling to obtain biomass pellet fuel. According to the calculation, according to the above-mentioned manufacturing method, the molding rate of the product can reach 98.8%, the product density is 1.36 g/cm 3 , the ash content is 3.26%, and the low-level calorific value is 4256.5 kcal/kg on an air-dried basis.

Claims (4)

1. a kind of method that utilization Ramulus Mori fermentation wastes prepare biomass granule fuel, it is characterised in that with Ramulus Mori garbage It is raw material with xylophyta residue, comprises the following steps:
1)Crush:Ramulus Mori fermentation wastes are crushed to into 1 ~ 3mm, xylophyta residue is crushed to 3 ~ 6mm;
2)Stirring mixing:According to ratio of weight and number, by step 1)Obtain 5 ~ 40 parts of Ramulus Mori fermentation wastes powder and xylophyta 60 ~ 95 parts of residue powder is uniformly mixed;
3)It is dried:By step 2)The material heat drying of mix homogeneously to moisture content is 14 ~ 25%;
4)It is compressing:By step 3)Dried material send into roller ring die forming machine be pressed into non-porous solid cylinder, Density is in 1.0 ~ 1.4g/cm3Biomass granule fuel;
The ring nib draw ratio of described roller ring die forming machine is 3.5 ~ 5:Between 1;
Described its component of Ramulus Mori fermentation wastes includes:80 ~ 90 parts of Ramulus Mori, 7 ~ 15 parts of cassava alcohol waste residue, calcium oxide 1 ~ 5 Part, 0.5 ~ 3 part of calcium sulfate.
2. the method that utilization Ramulus Mori fermentation wastes according to claim 1 prepare biomass granule fuel, its feature exists In described its component of Ramulus Mori fermentation wastes includes:80 ~ 90 parts of Ramulus Mori, 7 ~ 15 parts of cassava alcohol waste residue, 1 ~ 5 part of calcium oxide, 0.5 ~ 3 part of calcium sulfate.
3. the method that utilization Ramulus Mori fermentation wastes according to claim 1 prepare biomass granule fuel, its feature exists In described xylophyta residue is one kind or combinations thereof thing in Ramulus Mori, mallee bark, pine sawdust.
4. the method that utilization Ramulus Mori fermentation wastes according to claim 1 prepare biomass granule fuel, its feature exists In a diameter of 6 ~ 8mm of described biomass granule fuel.
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