CN104845483B - A kind of high adhesion force high-strength anti-flaming water paint - Google Patents
A kind of high adhesion force high-strength anti-flaming water paint Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
- C09D133/16—Homopolymers or copolymers of esters containing halogen atoms
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/22—Esters containing halogen
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The invention discloses a kind of high adhesion force high-strength anti-flaming water paint, its raw material includes by weight：52 55 parts of nucleocapsid fluorine polyacrylate solution, 15 18 parts of chlorosulfonated polyethylene, 36 parts of ethylene propylene diene rubber, 15 18 parts of improved silica, 7 10 parts of attapulgite, 69 parts of zeolite powder, 1.5 2.5 parts of barium sulfate, 2 3.5 parts of tripolycyanamide, 34 parts of ethylene glycol, 25 parts of dispersant, 1.3 1.6 parts of defoamer, 0.8 1.2 parts of coalescents, 1.2 1.5 parts of advection agent, 0.7 1 parts of flow assistants, 2 2.5 parts of thickening agent, 20 40 parts of deionized water.Adhesive force height of the present invention, good flame retardation effect, intensity are high, and the features such as have that good waterproof performance, weather resistance are strong, easily brush.
Description
Technical field
The present invention relates to technical field of aqueous paint, more particularly to a kind of high adhesion force high-strength anti-flaming water paint.
Background technology
It is referred to as water paint using water as the coating of disperse medium, including water soluble paint, water-reducible coating, moisture dissipates
Property coating.Water paint adhesive force, intensity is not high in the market, and mechanical performance and fire resistance be not strong；Fluorion is introduced
In acrylate, so that product is the focus side of current research the advantages of possessing excellent weatherability, water proofing property, mechanical performance
To how developing a kind of new coating that can overcome water paint shortcoming using this new material, become current research
Emphasis direction.
The content of the invention
Based on the technical problem that background technology is present, the present invention proposes a kind of high adhesion force high-strength anti-flaming aqueouss and applies
Material, adhesive force height, good flame retardation effect, intensity are high, and have good waterproof performance, weather resistance by force, the features such as easily brush.
A kind of high adhesion force high-strength anti-flaming water paint proposed by the present invention, its raw material include by weight：Nucleocapsid fluorine
Polyacrylate solution 52-55 part, chlorosulfonated polyethylene 15-18 parts, ethylene propylene diene rubber 3-6 parts, improved silica 15-18
Part, attapulgite 7-10 parts, zeolite powder 6-9 parts, barium sulfate 1.5-2.5 parts, tripolycyanamide 2-3.5 parts, ethylene glycol 3-4 parts, point
Powder 2-5 parts, defoamer 1.3-1.6 parts, coalescents 0.8-1.2 parts, advection agent 1.2-1.5 part, flow assistants 0.7-1 parts,
Thickening agent 2-2.5 parts, deionized water 20-40 parts.
Preferably, nucleocapsid fluorine polyacrylate solution, chlorosulfonated polyethylene, the weight ratio of ethylene propylene diene rubber are 53-54：
16-17：4-5 parts.
Preferably, its raw material includes by weight：Nucleocapsid fluorine polyacrylate solution 53-54 part, chlorosulfonated polyethylene 16-
17 parts, ethylene propylene diene rubber 4-5 parts, improved silica 16-17 parts, attapulgite 8-9 parts, zeolite powder 7-8 parts, barium sulfate
1.8-2.2 parts, tripolycyanamide 2.6-3.2 parts, ethylene glycol 3.3-3.7 parts, dispersant 3-4 parts, defoamer 1.4-1.5 parts, film forming
Auxiliary agent 0.9-1.1 parts, advection agent 1.3-1.4 part, flow assistants 0.8-0.9 parts, thickening agent 2.2-2.3 parts, deionized water 25-30
Part.
Preferably, in the preparation process of nucleocapsid fluorine polyacrylate solution, go by weight by 60-65 part deionized waters,
3.2-3.5 part dodecylbenzene sodium sulfonate, 1.6-1.8 parts sodium bicarbonate add the first reaction vessel, stir and are warming up to
70-75 DEG C, continuously add 8-10 part butyl acrylate, 4-6 part styrene, 2.2-2.5 parts isobornyl methacrylate and
1.1-1.4 part Ammonium persulfate .s, raise the first reaction vessel temperature to 80-83 DEG C and are incubated 32-35min and obtain material A；To containing
14-17 part dodecafluoroheptyl methacrylates, 5-8 parts butyl acrylate and 0.8-1.2 are added in first reaction vessel of material A
Part Ammonium persulfate., it is 6.5-7 to be cooled to room temperature and adjust pH value after insulation 3-6h, obtains nucleocapsid fluorine polyacrylate solution.
Preferably, in the preparation process of nucleocapsid fluorine polyacrylate solution, go by weight by 62-63 part deionized waters,
3.3-3.4 part dodecylbenzene sodium sulfonate, 1.6-1.7 parts sodium bicarbonate add the first reaction vessel, stir and are warming up to
72-73 DEG C, continuously add 8.5-9 part butyl acrylate, 4.5-5 part styrene, 2.3-2.4 parts isobornyl methacrylate and
1.2-1.3 part Ammonium persulfate .s, raise the first reaction vessel temperature to 81-82 DEG C and are incubated 33-34min and obtain material A；To containing
15-16 part dodecafluoroheptyl methacrylates, 6-7 parts butyl acrylate and 0.9-1.1 are added in first reaction vessel of material A
Part Ammonium persulfate., it is 6.6-6.8 to be cooled to room temperature and adjust pH value after insulation 4-5h, obtains nucleocapsid fluorine polyacrylate solution.
Preferably, in the preparation process of improved silica, by weight by 22-25 part tetraethyl orthosilicates, 36-39 part nothings
Water-ethanol adds the first reaction vessel, raises the first reaction vessel and its contents temperature to 50-55 DEG C, continues addition quality point
Number is ammonia, 14-17 parts deionized water and 7-10 part dehydrated alcohol of 20-22wt%, after insulation 6-8h, adds 12-14 part silicon
Alkane coupling agent kh-570 is simultaneously incubated 3-5h and obtains material A, with after absolute ethanol washing material A 3-5 time and being concentrated to give modified two
Silicon oxide.
Preferably, in improved silica, solids content is 30-40%.
Preferably, in the preparation process of improved silica, by weight by 23-24 part tetraethyl orthosilicates, 37-38 part nothings
Water-ethanol adds the first reaction vessel, raises the first reaction vessel and its contents temperature to 51-53 DEG C, continues addition quality point
Number is ammonia, 15-16 parts deionized water and 8-9 part dehydrated alcohol of 20.5-21wt%, after insulation 6.5-7h, adds 13-13.5
Part Silane coupling reagent KH-570 is simultaneously incubated 3.2-3.5h and obtains material A, afterwards and is concentrated to give with absolute ethanol washing material A 3-4 time
To improved silica.
Preferably, in improved silica, solids content is 34-38%.
The present invention is using nucleocapsid fluorine polyacrylate solution, chlorosulfonated polyethylene, ethylene propylene diene rubber as film forming matter quality structure
Into water dispersible water paint, with good dispersion, adhesive force is high, weatherability is strong, corrosion resistance and good, intensity are high, shearing resistance
The characteristics of shear force performance is strong；In the preparation process of nucleocapsid fluorine polyacrylate solution, by semi-continuous seed emulsion copolymerization,
In the presence of initiator ammonium persulfate, prepare with butyl acrylate, styrene, isobornyl methacrylate as core, methyl-prop
The hud typed fluorine-contaninig polyacrylate emulsion of ten difluoro heptyl ester of olefin(e) acid, butyl acrylate for shell, as fluorion electronegativity is big, C-
F keys are stablized and fluorine-containing side chain is orientated outwardly, can form shielding protection to fluorine-contaninig polyacrylate main chain and interior molecules, so as to big
Chemical inertness of the invention, weatherability, oil resistant resistance to water are improve greatly, meanwhile, C-F key bond lengths are short, bond energy big, so as to significantly carry
The high mechanical property of the present invention, therefore the present invention has the characteristics of after tack is good, film-forming temperature is low, filming performance is excellent and thing
Physicochemical stability is high, satisfactory mechanical property；The improved silica of addition, attapulgite, zeolite powder further increase this
The weatherability of invention, water resistance, adhesive force and intensity, wherein silicon dioxide Jing Silane coupling reagent KH-570s graft modification are obtained
Solids content has the splendid compatibility with nucleocapsid fluorine polyacrylate solution for the improved silica of 30-40%, works as the present invention
When receiving external force effect, improved silica can be uniformly distributed external force, prevent the present invention as intermolecular crosslinking points of the invention
Rupture, further enhances mechanical performance, water proofing property and the shock resistance of the present invention；Ethylene glycol due to containing abundant hydroxyl,
For crosslinking points are provided between solution molecule, the present invention is made to possess higher crosslinking degree, it is steady so as to accelerate response speed, enhancing solution
It is qualitative, and greatly strengthen the antiseptic property and pliability of the present invention；The use of barium sulfate, tripolycyanamide, greatly strengthen
The fire resistance of the present invention.
Specific embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of high adhesion force high-strength anti-flaming water paint proposed by the present invention, its raw material include by weight：Nucleocapsid fluorine
55 parts of polyacrylate solution, 15 parts of chlorosulfonated polyethylene, 6 parts of ethylene propylene diene rubber, 15 parts of improved silica, attapulgite
10 parts, 6 parts of zeolite powder, 2.5 parts of barium sulfate, 2 parts of tripolycyanamide, 4 parts of ethylene glycol, 2 parts of dispersant, 1.6 parts of defoamer, film forming is helped
0.8 part of agent, 1.5 parts of advection agent, 0.7 part of flow assistants, 2.5 parts of thickening agent, 20 parts of deionized water；
In the preparation process of nucleocapsid fluorine polyacrylate solution, gone 65 parts of deionized waters, 3.2 parts of dodecanes by weight
Base benzene sulfonic acid sodium salt, 1.8 parts of sodium bicarbonate add the first reaction vessel, stir and are warming up to 70 DEG C, continuously add 10 part third
Olefin(e) acid butyl ester, 4 parts of styrene, 2.5 parts of isobornyl methacrylates and 1.1 parts of Ammonium persulfate .s, raise the first reaction vessel temperature
Spend to 83 DEG C and be incubated 32min and obtain material A；17 parts of methacrylic acids ten are added in the first reaction vessel containing material A
Difluoro heptyl ester, 5 parts of butyl acrylate and 1.2 parts of Ammonium persulfate .s, it is 7 to be cooled to room temperature and adjust pH value after insulation 3h, obtains core
Shell fluorine polyacrylate solution；
In the preparation process of improved silica, 22 parts of tetraethyl orthosilicates, 39 parts of dehydrated alcohol are added into the by weight
One reaction vessel, raises the first reaction vessel and its contents temperature to 50 DEG C, continues ammonia of the addition mass fraction for 22wt%
Water, 14 parts of deionized waters and 10 parts of dehydrated alcohol, after insulation 6h, add 14 parts of Silane coupling reagent KH-570s and are incubated 3h and obtain thing
Material A, with after absolute ethanol washing material A 5 times and being concentrated to give improved silica；Wherein, in improved silica, solid contains
Measure as 30%.
Embodiment 2
A kind of high adhesion force high-strength anti-flaming water paint proposed by the present invention, its raw material include by weight：Nucleocapsid fluorine
52 parts of polyacrylate solution, 18 parts of chlorosulfonated polyethylene, 3 parts of ethylene propylene diene rubber, 18 parts of improved silica, attapulgite
7 parts, 9 parts of zeolite powder, 1.5 parts of barium sulfate, 3.5 parts of tripolycyanamide, 3 parts of ethylene glycol, 5 parts of dispersant, 1.3 parts of defoamer, film forming
1.2 parts of auxiliary agent, 1.2 parts of advection agent, 1 part of flow assistants, 2 parts of thickening agent, 40 parts of deionized water；
In the preparation process of nucleocapsid fluorine polyacrylate solution, gone 60 parts of deionized waters, 3.5 parts of dodecanes by weight
Base benzene sulfonic acid sodium salt, 1.6 parts of sodium bicarbonate add the first reaction vessel, stir and are warming up to 75 DEG C, continuously add 8 parts of propylene
Acid butyl ester, 6 parts of styrene, 2.2 parts of isobornyl methacrylates and 1.4 parts of Ammonium persulfate .s, raise the first reaction vessel temperature
To 80 DEG C and it is incubated 35min and obtains material A；14 parts of methacrylic acids 12 are added in the first reaction vessel containing material A
Fluorine heptyl ester, 8 parts of butyl acrylate and 0.8 part of Ammonium persulfate., it is 6.5 to be cooled to room temperature and adjust pH value after insulation 6h, obtains core
Shell fluorine polyacrylate solution；
In the preparation process of improved silica, 25 parts of tetraethyl orthosilicates, 36 parts of dehydrated alcohol are added into the by weight
One reaction vessel, raises the first reaction vessel and its contents temperature to 55 DEG C, continues ammonia of the addition mass fraction for 20wt%
Water, 17 parts of deionized waters and 7 parts of dehydrated alcohol, after insulation 8h, add 12 parts of Silane coupling reagent KH-570s and are incubated 5h and obtain thing
Material A, with after absolute ethanol washing material A 3 times and being concentrated to give improved silica；Wherein, in improved silica, solid contains
Measure as 40%.
Embodiment 3
A kind of high adhesion force high-strength anti-flaming water paint proposed by the present invention, its raw material include by weight：Nucleocapsid fluorine
54 parts of polyacrylate solution, 16 parts of chlorosulfonated polyethylene, 5 parts of ethylene propylene diene rubber, 16 parts of improved silica, attapulgite
9 parts, 7 parts of zeolite powder, 2.2 parts of barium sulfate, 2.6 parts of tripolycyanamide, 3.7 parts of ethylene glycol, 3 parts of dispersant, 1.5 parts of defoamer, into
0.9 part of film auxiliary agent, 1.4 parts of advection agent, 0.8 part of flow assistants, 2.3 parts of thickening agent, 25 parts of deionized water；
In the preparation process of nucleocapsid fluorine polyacrylate solution, gone 63 parts of deionized waters, 3.3 parts of dodecanes by weight
Base benzene sulfonic acid sodium salt, 1.7 parts of sodium bicarbonate add the first reaction vessel, stir and are warming up to 72 DEG C, continuously add 9 parts of propylene
Acid butyl ester, 4.5 parts of styrene, 2.4 parts of isobornyl methacrylates and 1.2 parts of Ammonium persulfate .s, raise the first reaction vessel temperature
Spend to 82 DEG C and be incubated 33min and obtain material A；16 parts of methacrylic acids ten are added in the first reaction vessel containing material A
Difluoro heptyl ester, 6 parts of butyl acrylate and 1.1 parts of Ammonium persulfate .s, it is 6.8 to be cooled to room temperature and adjust pH value after insulation 4h, is obtained
Nucleocapsid fluorine polyacrylate solution；
In the preparation process of improved silica, 23 parts of tetraethyl orthosilicates, 38 parts of dehydrated alcohol are added into the by weight
One reaction vessel, raises the first reaction vessel and its contents temperature to 51 DEG C, continues ammonia of the addition mass fraction for 21wt%
Water, 15 parts of deionized waters and 9 parts of dehydrated alcohol, after insulation 6.5h, add 13.5 parts of Silane coupling reagent KH-570s and are incubated 3.2h
Material A is obtained, with after absolute ethanol washing material A 4 times and being concentrated to give improved silica；Wherein, in improved silica
Solids content is 34%.
Embodiment 4
A kind of high adhesion force high-strength anti-flaming water paint proposed by the present invention, its raw material include by weight：Nucleocapsid fluorine
53 parts of polyacrylate solution, 17 parts of chlorosulfonated polyethylene, 4 parts of ethylene propylene diene rubber, 17 parts of improved silica, attapulgite
8 parts, 8 parts of zeolite powder, 1.8 parts of barium sulfate, 3.2 parts of tripolycyanamide, 3.3 parts of ethylene glycol, 4 parts of dispersant, 1.4 parts of defoamer, into
1.1 parts of film auxiliary agent, 1.3 parts of advection agent, 0.9 part of flow assistants, 2.2 parts of thickening agent, 30 parts of deionized water；
In the preparation process of nucleocapsid fluorine polyacrylate solution, gone 62 parts of deionized waters, 3.4 parts of dodecanes by weight
Base benzene sulfonic acid sodium salt, 1.6 parts of sodium bicarbonate add the first reaction vessel, stir and are warming up to 73 DEG C, continuously add 8.5 part third
Olefin(e) acid butyl ester, 5 parts of styrene, 2.3 parts of isobornyl methacrylates and 1.3 parts of Ammonium persulfate .s, raise the first reaction vessel temperature
Spend to 81 DEG C and be incubated 34min and obtain material A；15 parts of methacrylic acids ten are added in the first reaction vessel containing material A
Difluoro heptyl ester, 7 parts of butyl acrylate and 0.9 part of Ammonium persulfate., it is 6.6 to be cooled to room temperature and adjust pH value after insulation 5h, is obtained
Nucleocapsid fluorine polyacrylate solution；
In the preparation process of improved silica, 24 parts of tetraethyl orthosilicates, 37 parts of dehydrated alcohol are added into the by weight
One reaction vessel, raises the first reaction vessel and its contents temperature to 53 DEG C, continues addition mass fraction for 20.5wt%'s
Ammonia, 16 parts of deionized waters and 8 parts of dehydrated alcohol, after insulation 7h, add 13 parts of Silane coupling reagent KH-570s and are incubated 3.5h and obtain
To material A, with after absolute ethanol washing material A 3 times and being concentrated to give improved silica；Wherein, it is solid in improved silica
Body content is 38%.
Performance test is carried out to embodiment 1-4, the commercially available water paint of certain money is chosen as a control group, testing result is as follows：
Water contact angle is to determine contact angle numerical value of the water in coating surface using contact angle instrument, and water contact angle is bigger,
The hydrophobicity of coating is stronger, water resistance is better.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept equivalent or change in addition, should all be included within the scope of the present invention.
Claims (8)
1. a kind of high adhesion force high-strength anti-flaming water paint, it is characterised in that its raw material includes by weight：Nucleocapsid fluorine poly- third
Olefin(e) acid ester solution 52-55 parts, chlorosulfonated polyethylene 15-18 parts, ethylene propylene diene rubber 3-6 parts, improved silica 15-18 parts,
Attapulgite 7-10 parts, zeolite powder 6-9 parts, barium sulfate 1.5-2.5 parts, tripolycyanamide 2-3.5 parts, ethylene glycol 3-4 parts, dispersant
2-5 parts, defoamer 1.3-1.6 parts, coalescents 0.8-1.2 parts, advection agent 1.2-1.5 part, flow assistants 0.7-1 parts, thickening
Agent 2-2.5 parts, deionized water 20-40 parts；
In the preparation process of nucleocapsid fluorine polyacrylate solution, by weight by 60-65 part deionized waters, 3.2-3.5 parts 12
Sodium alkyl benzene sulfonate, 1.6-1.8 parts sodium bicarbonate add the first reaction vessel, stir and be warming up to 70-75 DEG C, continue to add
Enter 8-10 part butyl acrylate, 4-6 part styrene, 2.2-2.5 parts isobornyl methacrylate and 1.1-1.4 part persulfuric acid
Ammonium, raises the first reaction vessel temperature to 80-83 DEG C and is incubated 32-35min and obtains material A；React to containing material A first
14-17 part dodecafluoroheptyl methacrylates, 5-8 parts butyl acrylate and 0.8-1.2 part Ammonium persulfate .s, insulation are added in container
It is 6.5-7 that room temperature is cooled to after 3-6h and pH value is adjusted, and obtains nucleocapsid fluorine polyacrylate solution.
2. high adhesion force high-strength anti-flaming water paint according to claim 1, it is characterised in that nucleocapsid fluorine polyacrylate
Solution, chlorosulfonated polyethylene, the weight ratio of ethylene propylene diene rubber are 53-54：16-17：4-5.
3. high adhesion force high-strength anti-flaming water paint according to claim 1 or claim 2, it is characterised in that its raw material is by weight
Part includes：Nucleocapsid fluorine polyacrylate solution 53-54 part, chlorosulfonated polyethylene 16-17 parts, ethylene propylene diene rubber 4-5 parts are modified
Silica 1 6-17 parts, attapulgite 8-9 parts, zeolite powder 7-8 parts, barium sulfate 1.8-2.2 parts, tripolycyanamide 2.6-3.2 parts,
Ethylene glycol 3.3-3.7 parts, dispersant 3-4 parts, defoamer 1.4-1.5 parts, coalescents 0.9-1.1 parts, advection agent 1.3-1.4
Part, flow assistants 0.8-0.9 parts, thickening agent 2.2-2.3 parts, deionized water 25-30 parts.
4. high adhesion force high-strength anti-flaming water paint according to claim 1 or claim 2, it is characterised in that nucleocapsid fluorine polypropylene
In the preparation process of acid esters solution, by weight by 62-63 part deionized waters, 3.3-3.4 part dodecylbenzene sodium sulfonate, 1.6-
1.7 parts of sodium bicarbonate add the first reaction vessel, stir and are warming up to 72-73 DEG C, continuously add 8.5-9 part acrylic acid fourths
Ester, 4.5-5 part styrene, 2.3-2.4 parts isobornyl methacrylate and 1.2-1.3 part Ammonium persulfate .s, raise first and react
Vessel temp is to 81-82 DEG C and is incubated 33-34min and obtains material A；15-16 is added in the first reaction vessel containing material A
Part dodecafluoroheptyl methacrylate, 6-7 parts butyl acrylate and 0.9-1.1 part Ammonium persulfate .s, are cooled to room after insulation 4-5h
Temperature simultaneously adjusts pH value for 6.6-6.8, obtains nucleocapsid fluorine polyacrylate solution.
5. high adhesion force high-strength anti-flaming water paint according to claim 1 or claim 2, it is characterised in that improved silica
Preparation process in, by weight by 22-25 part tetraethyl orthosilicates, 36-39 parts dehydrated alcohol add the first reaction vessel, raise
, to 50-55 DEG C, it is the ammonia of 20-22wt%, 14-17 parts to continue addition mass fraction for first reaction vessel and its contents temperature
Deionized water and 7-10 part dehydrated alcohol, after insulation 6-8h, add 12-14 parts Silane coupling reagent KH-570 and are incubated 3-5h and obtain
Material A, with after absolute ethanol washing material A 3-5 time and being concentrated to give improved silica.
6. high adhesion force high-strength anti-flaming water paint according to claim 1 or claim 2, it is characterised in that improved silica
Preparation process in, in improved silica solids content be 30-40%.
7. high adhesion force high-strength anti-flaming water paint according to claim 1 or claim 2, it is characterised in that improved silica
Preparation process in, by weight by 23-24 part tetraethyl orthosilicates, 37-38 parts dehydrated alcohol add the first reaction vessel, raise
, to 51-53 DEG C, it is the ammonia of 20.5-21wt%, 15-16 to continue addition mass fraction for first reaction vessel and its contents temperature
Part deionized water and 8-9 part dehydrated alcohol, after insulation 6.5-7h, add 13-13.5 parts Silane coupling reagent KH-570 to be simultaneously incubated
3.2-3.5h obtains material A, with after absolute ethanol washing material A 3-4 time and being concentrated to give improved silica.
8. high adhesion force high-strength anti-flaming water paint according to claim 1 or claim 2, it is characterised in that improved silica
Middle solids content is 34-38%.
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| CN106147445A (en) * | 2016-06-28 | 2016-11-23 | 合众（佛山）化工有限公司 | A kind of self-flame-retardant aqueous environmental protection coating material and preparation method |
| CN106117406B (en) * | 2016-06-28 | 2019-02-12 | 合众（佛山）化工有限公司 | A kind of self-flame-retardant modifying cinepazid emulsion and preparation method thereof |
| CN106147411A (en) * | 2016-08-13 | 2016-11-23 | 安庆市荷花化工有限责任公司 | A kind of shock resistance coating for fender and preparation method thereof |
| CN108300329A (en) * | 2017-07-31 | 2018-07-20 | 合肥泓定科技有限公司 | A kind of low-temperature resistance waterproof material and preparation method thereof |
| CN107523218A (en) * | 2017-07-31 | 2017-12-29 | 合肥泓定科技有限公司 | A kind of use for electronic products waterproof material and preparation method thereof |
| RU2675575C1 (en) * | 2017-12-25 | 2018-12-19 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Волгоградский государственный технический университет" (ВолгГТУ) | Composition for fire-retardant rubber coatings |
| RU2675558C1 (en) * | 2017-12-25 | 2018-12-19 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Волгоградский государственный технический университет" (ВолгГТУ) | Composition for fire-retardant rubber coatings |
| CN108118403A (en) * | 2017-12-28 | 2018-06-05 | 太和县昌泰毛发制品有限公司 | A kind of manufacture craft of the resistance to cleaning wig fiber of high intensity |
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| JP4530655B2 (en) * | 2003-04-15 | 2010-08-25 | 鹿島建設株式会社 | Foam fireproof paint |
| CN100503752C (en) * | 2005-09-05 | 2009-06-24 | 同济大学 | Ultra-thin expansion steel structure fire-proof paint capable of resisting hydrocarbons fire and preparation method thereof |
| CN101597454B (en) * | 2009-06-25 | 2011-08-17 | 裘陆军 | High weather resistance environment-friendly cable fire-refractory coating and preparation process thereof |
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| CN102850668A (en) * | 2012-09-24 | 2013-01-02 | 吴江市信许塑料鞋用配套有限公司 | Flame-retardant sole material |
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Effective date of registration: 20211229 Address after: 246000 No. 6, Maoqing Road, Daguan District, Anqing City, Anhui Province Patentee after: Anqing Kairui Chemical Technology Co.,Ltd. Address before: 242200 Xinhang Town Industrial Park, Guangde County, Xuancheng City, Anhui Province Patentee before: GUANGDE JIABAOLI CHEMICAL CO.,LTD. |
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Denomination of invention: A High Adhesion and High Strength Flame Retardant Waterborne Coatings Effective date of registration: 20221107 Granted publication date: 20170405 Pledgee: Anqing Daguan Sub branch of Huishang Bank Co.,Ltd. Pledgor: Anqing Kairui Chemical Technology Co.,Ltd. Registration number: Y2022980020824 |