CN104842677A - Flexographic printing plate and method of manufacturing liquid crystal display device using the same - Google Patents

Flexographic printing plate and method of manufacturing liquid crystal display device using the same Download PDF

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Publication number
CN104842677A
CN104842677A CN201510005225.0A CN201510005225A CN104842677A CN 104842677 A CN104842677 A CN 104842677A CN 201510005225 A CN201510005225 A CN 201510005225A CN 104842677 A CN104842677 A CN 104842677A
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CN
China
Prior art keywords
liquid crystal
printing plate
printing
roughness
flexible printing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
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CN201510005225.0A
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Chinese (zh)
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CN104842677B (en
Inventor
越智淳
田所信彦
洼田匠志
森康広
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Japanese trader Na Kang Tektronix Co., Ltd
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Japanese Trader Na Kang Tektronix Co Ltd
Sumitomo Rubber Industries Ltd
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Publication of CN104842677A publication Critical patent/CN104842677A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41NPRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
    • B41N1/00Printing plates or foils; Materials therefor
    • B41N1/04Printing plates or foils; Materials therefor metallic
    • B41N1/06Printing plates or foils; Materials therefor metallic for relief printing or intaglio printing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00Inking and printing with a printer's forme
    • B41M1/02Letterpress printing, e.g. book printing
    • B41M1/04Flexographic printing
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1337Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers

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  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Mathematical Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Liquid Crystal (AREA)
  • Printing Plates And Materials Therefor (AREA)
  • Printing Methods (AREA)

Abstract

The invention provides a flexographic printing plate and a method of manufacturing a liquid crystal display device using the same. The flexographic printing plate sets the installation face directed towards a plate cylinder as a rough face with an average roughness Ra of a roughness curve being ranging from 0.02 mu m to 0.06 mu m, a maximum height roughness Rz being ranging from 0.25 mu m to 1.60 mu m, a ten-point average roughness RzJIS being ranging from 0.20 mu m to 0.80 mu m. The method of manufacturing the liquid crystal display device comprises the steps of using the flexographic printing plate and forming a substrate liquid alignment film for a liquid panel through flexible printing. Even if the flexographic printing plate has a large area, the flexographic printing plate can be easily installed and dismounted relative to the plate cylinder. The printing face arranged on the surface of the plate cylinder has excellent flatness and is thus suitably used for printing of the liquid alignment film for the liquid crystal display device. Furthermore, repeated printing will not result in deviation on the surface of the plate cylinder.

Description

Flexible printing plate and use its manufacture method of liquid crystal display cells
Technical field
The present invention relates to the manufacture method of a kind of flexible printing plate being suitably used for being formed by flexible printing the liquid crystal orienting film of such as liquid crystal display cells etc. and the liquid crystal display cells using it.
Background technology
Require high painting film quality to be formed on the electrode forming surface of substrate for liquid crystal panel forming liquid crystal display cells (thickness is even as far as possible, and free of pinholes etc., and thin) liquid crystal orienting film, utilize the flexible printing method with the special domestic animal of good printing.
But the flexible printing plate used in known flexible printing is subject to the power of shear direction when being installed on and plate cylinder printing repeatedly, offset in the generation position, surface of this plate cylinder.
Namely, if flexible printing plate is subject to the power of shear direction when printing, slightly extend on the surface of plate cylinder, even if terminate along with printing and remove the power of shear direction, this extension is not restored completely yet and remains.And, along with print pass increases, extend accumulation and cause the position skew of version to expand.
Position skew has skew, the overall skew extending the spacing caused of printed patterns of printing original position, and these two kinds of positions skews all can produce.
Therefore, in order to prevent those positions from offseting, have studied the method (such as patent document 1 ~ patent document 4 etc.) using two-sided tape or sheet magnetic material etc. flexible printing plate to be firmly fixed at plate cylinder surface.
But, the main flow of the flexible printing plate such as, used in the printing of large-scale liquid crystal display liquid crystal orienting film is wherein while more than the large-area flexible printing plate of 1.5m, if described fixing means, then when plate cylinder is dismantled, expend the time, if be inserted with the adhesive linkage etc. of two-sided tape between plate cylinder and flexible printing plate, then the flatness of its thickness to the surface (printing surface) of flexible printing plate impacts.Therefore, exist as liquid crystal orienting film formation version etc. and unaccommodated problem.
The position skew caused to prevent described extension, be investigated the method on metal base flexible printing plate being laminated in also inductility, but for the basis by becoming this metal base metal sheet and for being installed on un-deviously on plate cylinder, particularly version more becomes and is then more not easy greatly.Therefore there are the following problems: the flexible printing plate with this stepped construction is as large-scale liquid crystal orienting film formation version etc. and be not suitable for.
[prior art document]
[patent document]
[patent document 1] Japanese Patent Laid-Open 5-271630 publication
[patent document 2] Japanese Patent Laid-Open 5-246012 publication
[patent document 3] Japanese Patent Laid-Open 7-9669 publication
[patent document 4] Japan Patent Beneficial 7-27843 publication
[patent document 5] Japanese Patent Laid-Open 5-278357 publication
Summary of the invention
[invention institute for solution problem]
The object of this invention is to provide a kind of flexible printing plate and use its manufacture method of liquid crystal display cells, even if described flexible printing plate large areaization also easily can install relative to plate cylinder, dismantle, and the flatness of printing surface when being installed on plate cylinder surface is excellent, is also difficult to produce position skew on plate cylinder surface even if repeatedly print.
[means of dealing with problems]
The present invention is a kind of flexible printing plate, it is formed as, and one side is printing surface, opposing face is towards the tabular of the installed surface of plate cylinder, described installed surface is the arithmetic average roughness Ra of roughness curve is more than 0.02 μm, less than 0.06 μm, maximum height roughness Rz is more than 0.25 μm, less than 1.60 μm, and 10 mean roughness Rz jISit is the matsurface of more than 0.20 μm, less than 0.80 μm.
And the present invention is a kind of manufacture method of liquid crystal display cells, it comprises the described flexible printing plate of use, is formed the step of the liquid crystal orienting film of substrate for liquid crystal panel by flexible printing.
[effect of invention]
A kind of flexible printing plate can be provided by the present invention and use its manufacture method of liquid crystal display cells, even if described flexible printing plate large areaization also easily can install relative to plate cylinder, dismantle, and the flatness of printing surface when being installed on plate cylinder surface is excellent, therefore be suitable for the printing of liquid crystal orienting film used for liquid crystal display element, be also difficult to produce position skew on plate cylinder surface even if repeatedly print in addition.
Detailed description of the invention
< flexible printing plate >
The feature of flexible printing plate of the present invention is: be formed as that one side is printing surface, opposing face is towards the tabular of the installed surface of plate cylinder, described installed surface is the arithmetic average roughness Ra of roughness curve is more than 0.02 μm, less than 0.06 μm, maximum height roughness Rz is more than 0.25 μm, less than 1.60 μm, and 10 mean roughness Rz jISit is the matsurface of more than 0.20 μm, less than 0.80 μm.
The installed surface connected with plate cylinder is set to even surface by existing flexible printing plate, be close contact on the surface of the plate cylinder being set to even surface equally strongly, therefore as noted, even if terminate along with printing and remove the power of shear direction, extend and also do not remove and accumulate, thus produce position skew.
If in contrast, utilize flexible printing plate of the present invention, then by the installed surface connected with plate cylinder being set to the matsurface meeting described characteristic, the contiguity power relative to plate cylinder surface can be lowered, moderately easily can slide relative to this surface.Therefore, when terminating along with printing and remove the power of shear direction, the extension of flexible printing plate can be removed, and can prevent this extension from accumulating and produce position skew.
And, flexible printing plate of the present invention, except being set to by installed surface except described matsurface, can be formed, without the need to metal base etc. in the same manner as existing flexible printing plate, in addition by being installed on plate cylinder surface with previously same installation method, without the need to using two-sided tape etc. and fixing.
Therefore, even if large areaization also can easily be carried out relative to the installation of plate cylinder, dismounting, and the flatness of printing surface when being installed on plate cylinder surface is excellent, is therefore suitable for the printing of liquid crystal orienting film used for liquid crystal display element.
In addition, in the present invention, by the arithmetic average roughness Ra of roughness curve, a maximum height roughness Rz and ten mean roughness Rz jISbeing defined in illustrated scope respectively is above due to following reason.
Namely, when any one not enough respective scope of described 3 kinds of roughness, the matsurfaceization of installed surface all can be insufficient, and the contiguity power for plate cylinder surface lowers, and fails to obtain the effect of moderately easily sliding for this surface.Therefore, when repeatedly printing, extending and accumulated and produce position skew.
On the other hand, when 3 kinds of roughness any a kind exceed respective scope, the matsurfaceization of installed surface all can be superfluous, and the contiguity power for plate cylinder surface becomes too low, too easily slides for this surface.Therefore, becoming easy extension when applying the power of shear direction when printing, particularly becoming the skew easily producing the spacing caused because printed patterns entirety extends.
Relative to this, by 3 kinds of roughness are all adjusted in respective scope, can bright making like that moderately lower relative to the contiguity power on plate cylinder surface as noted earlier, moderately easily slide for this surface, be also difficult to offset in the generation position, surface of plate cylinder even if can realize repeatedly printing.
In addition, in the present invention, described 3 kinds of roughness are represented by following value, described value is the assay method based on defined in Japanese Industrial Standards JIS B0601:2001 " geometrical property specification (the GPS)-surface texture of product: contour curve mode-term; definition and surface texture parameter ", the value that the laser microscope VK-9500 using Ji Ensi (KEYENCE) limited company to manufacture measures.
Flexible printing plate of the present invention, except being set to by installed surface except described matsurface, can be formed in the same manner as before.
Such as flexible printing plate is by manufacturing as under type: matsurface sheet material (as described in matsurface sheet material be the printing surface of this flexible printing plate is become consider any matsurface by capacitive etc. of ink) is separated predetermined distance with the enhancing sheet material of the installed surface forming flexible printing plate and remains parallel flat shape, clamp photosensitive polymer combination betwixt, irradiation ultraviolet radiation etc. and photosensitive polymer combination is hardened, then by matsurface sheet material stripping etc.
The flexible printing plate manufactured through described step has 2 Rotating fields being laminated with the hardened layer of the hardening thing comprising photosensitive polymer combination at the one side strengthening sheet material, the opposing face of the enhancing sheet material side of described hardened layer becomes printing surface, and the opposing face strengthening the hardened layer side of sheet material becomes installed surface.
The concaveconvex shape of the matsurface sheet material that printing surface transfer printing is peeled off and matsurface.
And in order to make installed surface become the matsurface meeting 3 kinds of illustrated roughness above, as enhancing sheet material, the enhancing sheet material that the opposing face being selected to the hardened layer side of installed surface makes described matsurface in advance uses.
Thus, even the large-area flexible printing plate corresponding with such as large-scale liquid crystal display, the whole face of its installed surface also can be made to become the uniform matsurface of satisfied 3 kinds of roughness.
This enhancing sheet material can use and comprise such as polyethylene (polyethylene, PE), polypropylene (polypropylene, PP), thermoplastic polyurethane's ethyl ester elastomer (thermoplasticpolyurethane elastomer, TPU), PET (polyethyleneterephthalate, PET), tetrafluoraoethylene-hexafluoropropylene copolymer (fluorinated ethylene propylene, the thermoplastic resin such as FEP), and its one side or two faces are the sheet material of the matsurface of satisfied 3 kinds of roughness.
As strengthening the concrete example of sheet material, include, for example Lu meter Le (Lumirror) (registration mark) S10 that east beautiful (TORAY) limited company manufactures [PET sheet, Ra:0.047 μm, Rz:1.064 μm, Rz jIS: 0.451 μm], Japan twists flax fibers and weave Cosmoshine (registration mark) A4300 [PET sheet, Ra:0.024 μm, Rz:0.516 μm, the Rz that limited company manufactures jIS: 0.291 μm] etc.
As photosensitive polymer combination, include, for example: comprise and there is 1,2-butadiene structure and the composition etc. at end with the prepolymer of vinyl double bond, vinyl unsaturated monomer and Photoepolymerizationinitiater initiater.
As Photoepolymerizationinitiater initiater, preferably styrax alkyl ether, it is below 500ppm that You Jiawei uses benzoic ratio in the total amount of photosensitive polymer combination, and this styrax becomes the reason of reacting consequently flexible printing plate yellow by the visible ray from fluorescent lamp etc.The flexible printing plate had excellent weather resistance of not yellow in the short time can be obtained thus.
The manufacture method > of < liquid crystal display cells
The present invention is the manufacture method of the liquid crystal display cells comprising following steps: use described flexible printing plate of the present invention, formed the liquid crystal orienting film of substrate for liquid crystal panel by flexible printing.
The liquid crystal display cells comprising following liquid crystal orienting film can be manufactured: described LCD alignment film thickness is even and the repeatability of thickness is also excellent by the present invention, and and free of pinholes, the skew that there is no the printing original position that the position based on flexible printing plate offsets in addition or the skew etc. of spacing caused due to the extension of printed patterns entirety.
Other steps of manufacture method of the present invention can be implemented in the same manner as before.
Namely, the transparent electrode layer corresponding with specifying matrix pattern etc. is formed on the surface of the transparency carriers such as glass substrate, forming liquid crystal orienting film additionally by using the flexible printing of flexible printing plate of the present invention, optionally by friction etc., orientation process being carried out to the surface of liquid crystal orienting film further and making substrate for liquid crystal panel.
Secondly, prepare 2 pieces of these substrate for liquid crystal panel, under the state of each transparent electrode layer position alignment, liquid crystal material is clamped between 2 pieces of substrate for liquid crystal panel, interfix and form duplexer, and arrange Polarizers if necessary in two of this duplexer outsides further and manufacture liquid crystal display cells.
[embodiment]
< embodiment 1 >
(enhancing sheet material)
As the enhancing sheet material of installed surface forming flexible printing plate, Lu meter Le (Lumirror) (registration mark) S10 of preparing 2 pieces of previously described Dong Li limited companies to manufacture [PET sheet, Ra:0.047 μm, Rz:1.064 μm, Rz jIS: 0.451 μm] in thickness be 250 μm sheet material laminating form.
(matsurface sheet material)
As matsurface sheet material, prepare the TPU exposed of the TPU sheet material having thickness to be the PET sheet of 100 μm at single-sided lamination [ great Cang Industries, Inc manufacture Silklon (registration mark) SNESS80-150 μm] surface as the matsurface sheet material in figuration face carrying out matsurface.
(manufacture of flexible printing plate)
Described enhancing sheet material and matsurface sheet material are separated the interval of about 2.4mm and remain parallel flat shape, clamp photosensitive polymer combination [the NK resin that Sumitomo Rubber Industries, Ltd. manufactures] betwixt, irradiation ultraviolet radiation and make photosensitive polymer combination harden after, by matsurface sheet material peel off and manufacturing flexible galley.
About the installed surface of this flexible printing plate, based on the surface texture of enhancing sheet material becoming its basis, arithmetic average roughness Ra is 0.047 μm, and maximum height roughness Rz is 1.064 μm, and 10 mean roughness Rz jISit is 0.451 μm.
< embodiment 2 >
As enhancing sheet material, Cosmoshine (registration mark) A4300 that the limited company for preparing 2 pieces of previously described Japan to twist flax fibers and weave manufactures [PET sheet, Ra:0.024 μm, Rz:0.516 μm, Rz jIS: 0.291 μm] in thickness be 250 μm sheet material laminating form.And, except using this enhancing sheet material, manufacturing flexible galley similarly to Example 1.
About the installed surface of this flexible printing plate, based on the surface texture of enhancing sheet material becoming its basis, arithmetic average roughness Ra is 0.024 μm, and maximum height roughness Rz is 0.516 μm, and 10 mean roughness Rz jISit is 0.291 μm.
< comparative example 1 >
As enhancing sheet material, prepare Lu meter Le (Lumirror) H10 [PET sheet, Ra:0.062 μm, Rz:1.642 μm, the Rz that 2 Kuai Dongli limited companies are manufactured jIS: 0.860 μm] in thickness be 250 μm sheet material laminating form.And, except using this enhancing sheet material, manufacturing flexible galley similarly to Example 1.
About the installed surface of this flexible printing plate, based on the surface texture of enhancing sheet material becoming its basis, arithmetic average roughness Ra is 0.062 μm, and maximum height roughness Rz is 1.642 μm, and 10 mean roughness Rz jISit is 0.860 μm.
< comparative example 2 >
As enhancing sheet material, prepare Lu meter Le (Lumirror) T60 [PET sheet, Ra:0.018 μm, Rz:0.218 μm, the Rz that 2 Kuai Dongli limited companies are manufactured jIS: 0.160 μm] in thickness be 250 μm sheet material laminating form.And, except using this enhancing sheet material, manufacturing flexible galley similarly to Example 1.
About the installed surface of this flexible printing plate, based on the surface texture of enhancing sheet material becoming its basis, arithmetic average roughness Ra is 0.018 μm, and maximum height roughness Rz is 0.218 μm, and 10 mean roughness Rz jISit is 0.160 μm.
< real machine test >
(flexible printing)
At flexible printing machine [Na Kang technical concern Co., Ltd (Nakan Techno Co., Ltd) the G3 machine manufactured] plate cylinder on manufactured flexible printing plate is installed in each embodiment, comparative example, carry out flexible printing on the surface of the glass substrate being formed with chromium vapor-deposited film.
In addition, on flexible printing plate, amount to 4 places at each 1 place of difference of the left and right of the left and right and printing end position of printing original position and form alignment mark (alignment mark) as printed patterns.
And, if offset without the position of flexible printing plate on the glass substrate, then at 4 places consistent with described alignment mark, patterning is carried out to alignment mark.
And, utilize the function of the image processing apparatus be assembled in flexible printing machine to set as follows: at the end of printing, new glass substrate with described alignment mark for benchmark and be arranged at home position.
(evaluation 1 of position skew)
The plate cylinder of described flexible printing machine is installed each flexible printing plate, behind the surface of 1000 pieces of glass substrates continuously print register mark, at the surface printing alignment mark of 1 piece of glass substrate, the skew (μm) of the printing original position that the side-play amount measuring the alignment mark of the printing original position of glass substrate and the print direction of alignment mark printed on it causes as the accumulation owing to extending.
And, printing original position printed by measurement and the distance between the alignment mark of end position, using its elongation relative to the print direction of original distance as the skew (μm) of spacing, the skew of described spacing is owing to causing based on the extension of the printed patterns entirety extending accumulation.
And the average evaluation being more than 1000 μm by the skew of printing original position is bad, is good by the average evaluation less than 1000 μm.And being that the average evaluation of more than 400 μm is bad by the skew of spacing, is good by the average evaluation less than 400 μm.
And, described any one is considered as existing owing to extending accumulation and the skew that causes for bad situation, is evaluated as bad, two kinds of all good situations are considered as without skew, are evaluated as good.
(the evaluation II of position skew)
The plate cylinder of described flexible printing machine is installed each flexible printing plate, measures the skew (μm) of printing original position from the printing initial stage of printing beginning the 1st piece ~ the 5th piece and the skew (μm) of spacing, obtain mean value respectively.
And the average evaluation being more than 1000 μm by the mean value of the skew of printing original position is bad, is good by the average evaluation less than 1000 μm.And being that the average evaluation of more than 400 μm is bad by the mean value of the skew of spacing, is good by the average evaluation less than 400 μm.
And, be the skew that bad situation is considered as existing the initial stage by described any one, be evaluated as bad, two kinds of all good situations are considered as without skew, be evaluated as good.
Above result is shown in table 1.
[table 1]
Table 1
Result according to the comparative example 1 of table 1: at arithmetic average roughness Ra, a maximum height roughness Rz and ten mean roughness Rz of the roughness curve of installed surface jISwhen all exceeding the scope of defined in the present invention, the matsurfaceization of installed surface is superfluous, contiguity power for plate cylinder surface becomes too low, too easily slide for this surface, its result applies the power of shear direction during when printing, cause the skew of spacing due to the extension of printed patterns entirety.
On the other hand, according to relatively fall 2 result: in the equal not enough the present invention of described 3 kinds of roughness when the scope of defined, the matsurface of installed surface is also insufficient, contiguity power for plate cylinder surface lowers and fails to obtain the effect of moderately easily sliding for this surface, although its result printing initial stage and no problem, but extend when repeatedly printing and accumulated, thus produce the position skew of printing original position.
Relative to this, result according to embodiment 1, embodiment 2: when described 3 kinds of roughness are all in scope given to this invention, the matsurfaceization appropriateness of installed surface, the skew of the spacing that can always the extension due to printed patterns entirety be caused after the printing initial stage to continuous printing or the position shift suppression of printing original position are in scope little as far as possible.

Claims (2)

1. a flexible printing plate, it is characterized in that: be formed as that one side is printing surface, opposing face is towards the tabular of the installed surface of plate cylinder, described installed surface is the arithmetic average roughness Ra of roughness curve is more than 0.02 μm, less than 0.06 μm, maximum height roughness Rz is more than 0.25 μm, less than 1.60 μm, and 10 mean roughness Rz jISit is the matsurface of more than 0.20 μm, less than 0.80 μm.
2. a manufacture method for liquid crystal display cells, is characterized in that: comprise and use flexible printing plate according to claim 1, formed the step of the liquid crystal orienting film of substrate for liquid crystal panel by flexible printing.
CN201510005225.0A 2014-02-17 2015-01-06 Flexographic printing plate and method of manufacturing liquid crystal display device using the same Active CN104842677B (en)

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JP2014027741A JP5702006B1 (en) 2014-02-17 2014-02-17 Flexographic printing plate and liquid crystal display device manufacturing method using the same
JP2014-027741 2014-02-17

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CN104842677B (en) 2017-05-10
KR20150097377A (en) 2015-08-26
TWI613092B (en) 2018-02-01

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