CN104831541A - Visible infrared anti-counterfeiting mark and preparation method thereof - Google Patents

Visible infrared anti-counterfeiting mark and preparation method thereof Download PDF

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Publication number
CN104831541A
CN104831541A CN201510218399.5A CN201510218399A CN104831541A CN 104831541 A CN104831541 A CN 104831541A CN 201510218399 A CN201510218399 A CN 201510218399A CN 104831541 A CN104831541 A CN 104831541A
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China
Prior art keywords
visible
counterfeiting
shipping mark
infrared anti
visible infrared
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Granted
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CN201510218399.5A
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Chinese (zh)
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CN104831541B (en
Inventor
王国忠
程福奎
薛矛
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Guangdong Kangpai Huanchuang Technology Co ltd
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Guangdong Esquel Textiles Co Ltd
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Priority to CN201510218399.5A priority Critical patent/CN104831541B/en
Publication of CN104831541A publication Critical patent/CN104831541A/en
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Abstract

The invention discloses a visible infrared anti-counterfeiting mark. The mark comprises a substrate, the substrate is coated with a visible infrared anti-counterfeiting coat, and the anti-counterfeiting coat comprises 0.1-3wt% of a visible infrared anti-counterfeiting composition, 0.3-1wt% of an anti-settling agent and 96-99.6wt% of an ink or a polyurethane coating or an acrylate coating; and the visible infrared anti-counterfeiting composition is composed of sodium fluoride, yttrium fluoride and ytterbium fluoride. A button made by adopting the specific visible infrared anti-counterfeiting coat generates a macroscopic obvious bright spot under irradiation of infrared light with specific wavelength of 980nm, and the bright spot can be identified under a fluorescent lamp or outdoors with not strong light, so identification in dark environment is not needed, and a very good anti-counterfeiting effect is realized.

Description

Visible infrared anti-false shipping mark and preparation method thereof
Technical field
The present invention relates to garment accessories technical field, particularly relate to a kind of visible infrared anti-false shipping mark and preparation method thereof.
Background technology
At present, most of reputable brand owner has dropped into a large amount of time and huge financial resources in the construction of brand image and value, but low-quality goods infringement brand image damage brand value, brand owner is suffered heavy losses.On the other hand, the raising of production technology and universal fraud threshold is reduced day by day, high-tech development makes common anti-counterfeiting technology means become easily to imitate and crack.As noctilucence is false proof, Ultraluminescence is false proof, the common counterfeit protection measures such as temperature sensing color changing is false proof, and the raw material of the anti-fake scheme implemented is easy to get, and is easily cracked and copys.Particularly in clothes and garment accessories field, the brand clothing of personation is becoming increasingly rampant and brand business there is no effective anti-counterfeit recognition means.
Therefore be necessary to take more effective anti-counterfeiting technology.
Summary of the invention
Based on this, the object of this invention is to provide a kind of visible infrared anti-false shipping mark.
Concrete technical scheme is as follows:
A kind of visible infrared anti-false shipping mark, comprises base material, described base material is coated with the outer security coating of visible red, and the raw material of the percentage by weight of the outer security coating of described visible red is composed as follows:
The outer anti-counterfeiting combination 0.1-3% of visible red
Anti-settling agent 0.3-1%
Ink or polyurethane coating or acrylate paint 96-99.6%;
The outer anti-counterfeiting combination of described visible red is by sodium fluoride, yttrium fluoride and fluoridize ytterbium and form.
Wherein in an embodiment, the outer anti-counterfeiting combination of described visible red is sodium fluoride, the yttrium fluoride of 18.5 ~ 21.5:56.0 ~ 58.0:20.5 ~ 25.5 by weight part ratio and fluoridizes ytterbium and form.
An embodiment is marine wherein, and described ink is nylon ink, water-based polyurethane ink or UV ink.
Wherein in an embodiment, described anti-settling agent is castor oil derivative, organic modified bentonite, Tissuemat E, superfine silicon dioxide or imvite organic derivative.
Wherein in an embodiment, the material of described base material is selected from cotton, woven dacron or cotton-polyester blend cloth.
Another object of the present invention is to provide the preparation method of above-mentioned visible infrared anti-false shipping mark.
Concrete technical scheme is as follows:
The preparation method of above-mentioned visible infrared anti-false shipping mark, comprises the steps:
(1) preliminary treatment is carried out to base material, ensure that substrate surface is totally pollution-free;
(2) by each component mixing and stirring in outer for above-mentioned visible red security coating, adopt the mode of serigraphy or spraying to be coated in described substrate surface, after air dry, namely obtain described visible infrared anti-false shipping mark.
Wherein in an embodiment, the thickness of the outer security coating of described visible red is 10-100 μm.
Beneficial effect of the present invention is as follows:
The present invention adopts the outer security coating of specific visible red, the button prepared is under the Infrared irradiation of 980nm specific wavelength, macroscopic obvious bright spot can be produced, this bright spot is not that very strong open air can recognize at fluorescent lamp and light, without the need to identifying in dark surrounds, there is good antifalse effect.
Accompanying drawing explanation
Fig. 1 is the structural representation of the visible infrared anti-false shipping mark of embodiment 1;
Fig. 2 is the photo figure of the visible infrared anti-false shipping mark of embodiment 1 in 980nm infrared light detection;
Fig. 3 is the photo figure of the visible infrared anti-false shipping mark of embodiment 2 in 980nm infrared light detection.
Detailed description of the invention
By the following examples the application is further elaborated.
Ink is nylon ink, water-based polyurethane ink or UV ink, purchased from middle beneficial ink.
Anti-settling agent is castor oil derivative, organic modified bentonite, Tissuemat E, superfine silicon dioxide or imvite organic derivative, commercially availablely buys.
Polyurethane coating or acrylate paint, purchased from Chinese painting.
Embodiment 1
The visible infrared anti-false shipping mark of a kind of silk-screen of the present embodiment adularescent pattern, comprises cotton base material and thickness is 100 μm of outer security coatings (as shown in Figure 1) of visible red being printed on white pattern.
The raw material of the percentage by weight of the outer security coating of described visible red is composed as follows:
The outer anti-counterfeiting combination 2% of visible red
Anti-settling agent 1%
Ink or polyurethane coating or acrylate paint 97%;
The outer anti-counterfeiting combination of described visible red is sodium fluoride, the yttrium fluoride of 20.5:57:22.5 by weight part ratio and fluoridizes ytterbium and form.
The preparation method of above-mentioned visible infrared anti-false shipping mark, comprises the steps:
(1) base material treatment: base material is carried out preliminary treatment, ensures that substrate surface is totally pollution-free;
(2) print: stir after each raw material mixing of outer for above-mentioned visible red security coating, printed by screen printing mode or be sprayed on the pretreated shipping mark surface of step (1).
(3) shaping: the shipping mark described in step (2) printing or the shipping mark air dry that spray namely being obtained with visible red antifalse effect outward.
Detect: use the infrared laser pen of 980nm to detect, obvious bright spot can be seen from naked eyes, as shown in Figure 2.
Embodiment 2
A kind of false proof shipping mark being printed with red pattern of the present embodiment, comprising woven dacron or polycot blend fabric and thickness is the outer security coating of visible red that 10 ~ 100um is printed on red pattern.
The raw material of the percentage by weight of the outer security coating of described visible red is composed as follows:
The outer anti-counterfeiting combination 1% of visible red
Anti-settling agent 0.5%
Ink or polyurethane coating or acrylate paint 98.5%;
The outer anti-counterfeiting combination of described visible red is sodium fluoride, the yttrium fluoride of 18.5:56:25.5 by weight part ratio and fluoridizes ytterbium and form.
The preparation method of above-mentioned visible infrared anti-false shipping mark, comprises the steps:
(1) base material treatment: base material is carried out preliminary treatment, ensures that substrate surface is totally pollution-free;
(2) print: stir after each raw material mixing of outer for above-mentioned visible red security coating, printed by screen printing mode or be sprayed on the pretreated shipping mark surface of step (1).
(3) shaping: the shipping mark described in step (2) printing or the shipping mark air dry that spray namely being obtained with visible red antifalse effect outward.
Detect: use the infrared laser pen of 980nm to detect, obvious bright spot can be seen from naked eyes, as shown in Figure 3
Comparative example 1
The visible infrared anti-false shipping mark of a kind of silk-screen of the present embodiment adularescent pattern, comprises cotton base material and thickness is 100 μm of outer security coatings of visible red being printed on white pattern.
The raw material of the percentage by weight of the outer security coating of described visible red is composed as follows:
Visible infrared anti-false powder 2%
Anti-settling agent 1%
Ink or polyurethane coating or acrylate paint 97%;
Described visible infrared anti-false powder is perylene compounds.
The preparation method of above-mentioned visible infrared anti-false shipping mark, comprises the steps:
(1) base material treatment: base material is carried out preliminary treatment, ensures that substrate surface is totally pollution-free;
(2) print: stir after each raw material mixing of outer for above-mentioned visible red security coating, printed by screen printing mode or be sprayed on the pretreated shipping mark surface of step (1).
(3) shaping: the shipping mark described in step (2) printing or the shipping mark air dry that spray namely being obtained with visible red antifalse effect outward.
Detect: use the infrared laser pen of 980nm to detect, find no obvious bright spot.
Comparative example 2
A kind of silk-screen of the present embodiment has the visible infrared anti-false shipping mark of blue colored pattern, and comprising cotton base material and thickness is 100 μm of outer security coatings of visible red being printed on blue color patterns.
The raw material of the percentage by weight of the outer security coating of described visible red is composed as follows:
The outer anti-counterfeiting combination 2% of visible red
Anti-settling agent 1%
Ink or polyurethane coating or acrylate paint 97%;
The outer anti-counterfeiting combination of described visible red is sodium fluoride, the yttrium fluoride of 15:40:45 by weight part ratio and fluoridizes ytterbium and form.
The preparation method of above-mentioned visible infrared anti-false shipping mark, comprises the steps:
(1) base material treatment: base material is carried out preliminary treatment, ensures that substrate surface is totally pollution-free;
(2) print: stir after each raw material mixing of outer for above-mentioned visible red security coating, printed by screen printing mode or be sprayed on the pretreated shipping mark surface of step (1).
(3) shaping: the shipping mark described in step (2) printing or the shipping mark air dry that spray namely being obtained with visible red antifalse effect outward.
Detect: use the infrared laser pen of 980nm to detect, obvious bright spot could be found in dark surrounds.
Each technical characteristic of the above embodiment can combine arbitrarily, for making description succinct, the all possible combination of each technical characteristic in above-described embodiment is not all described, but, as long as the combination of these technical characteristics does not exist contradiction, be all considered to be the scope that this description is recorded.
The above embodiment only have expressed several embodiment of the present invention, and it describes comparatively concrete and detailed, but can not therefore be construed as limiting the scope of the patent.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.

Claims (7)

1. a visible infrared anti-false shipping mark, is characterized in that, comprise base material, described base material is coated with the outer security coating of visible red, and the raw material of the percentage by weight of the outer security coating of described visible red is composed as follows:
The outer anti-counterfeiting combination 0.1-3% of visible red
Anti-settling agent 0.3-1%
Ink or polyurethane coating or acrylate paint 96-99.6%;
The outer anti-counterfeiting combination of described visible red is by sodium fluoride, yttrium fluoride and fluoridize ytterbium and form.
2. visible infrared anti-false shipping mark according to claim 1, is characterized in that, the outer anti-counterfeiting combination of described visible red is sodium fluoride, the yttrium fluoride of 18.5 ~ 21.5:56.0 ~ 58.0:20.5 ~ 25.5 by weight part ratio and fluoridizes ytterbium and form.
3. the visible infrared anti-false shipping mark according to any one of claim 1-2, is characterized in that, described ink is nylon ink, water-based polyurethane ink or UV ink.
4. the visible infrared anti-false shipping mark according to any one of claim 1-2, is characterized in that, described anti-settling agent is castor oil derivative, organic modified bentonite, Tissuemat E, superfine silicon dioxide or imvite organic derivative.
5. the visible infrared anti-false shipping mark according to any one of claim 1-2, is characterized in that, the material of described base material is selected from cotton, woven dacron or cotton-polyester blend cloth.
6. the preparation method of the visible infrared anti-false shipping mark according to any one of claim 1-5, is characterized in that, comprise the steps:
(1) preliminary treatment is carried out to base material, ensure that substrate surface is totally pollution-free;
(2) by each component mixing and stirring in outer for the visible red described in any one of claim 1-5 security coating, adopt the mode of serigraphy or spraying to be coated in described substrate surface, after air dry, namely obtain described visible infrared anti-false shipping mark.
7. preparation method according to claim 6, is characterized in that, the thickness of the outer security coating of described visible red is 10-100 μm.
CN201510218399.5A 2015-04-30 2015-04-30 Visible infrared anti-false shipping mark and preparation method thereof Active CN104831541B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105525417A (en) * 2016-02-23 2016-04-27 广东溢达纺织有限公司 Polyester woven label and preparation method thereof
CN105908513A (en) * 2016-06-27 2016-08-31 广东溢达纺织有限公司 Anti-fake yarns and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1376759A (en) * 2002-04-15 2002-10-30 清华大学 Nano-class conversion fluorescence material on fluoride matrix and its preparing process
US20100261263A1 (en) * 2009-03-18 2010-10-14 Duke University Up and down conversion systems for production of emitted light from various energy sources
CN101864605A (en) * 2010-06-09 2010-10-20 蚌埠市瑞进防伪材料科技有限公司 Near-infrared absorption counterfeit fiber and preparation method thereof
KR20120015111A (en) * 2010-08-11 2012-02-21 고려대학교 산학협력단 Energy up-conversion materials for dye-sensitized solar cells
KR20140145836A (en) * 2013-06-14 2014-12-24 한국조폐공사 Manufacturing Method of Functional Rregenerated Cellulose Fiber

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1376759A (en) * 2002-04-15 2002-10-30 清华大学 Nano-class conversion fluorescence material on fluoride matrix and its preparing process
US20100261263A1 (en) * 2009-03-18 2010-10-14 Duke University Up and down conversion systems for production of emitted light from various energy sources
CN101864605A (en) * 2010-06-09 2010-10-20 蚌埠市瑞进防伪材料科技有限公司 Near-infrared absorption counterfeit fiber and preparation method thereof
KR20120015111A (en) * 2010-08-11 2012-02-21 고려대학교 산학협력단 Energy up-conversion materials for dye-sensitized solar cells
KR20140145836A (en) * 2013-06-14 2014-12-24 한국조폐공사 Manufacturing Method of Functional Rregenerated Cellulose Fiber

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105525417A (en) * 2016-02-23 2016-04-27 广东溢达纺织有限公司 Polyester woven label and preparation method thereof
CN105908513A (en) * 2016-06-27 2016-08-31 广东溢达纺织有限公司 Anti-fake yarns and preparation method thereof
CN105908513B (en) * 2016-06-27 2018-04-17 广东溢达纺织有限公司 False proof yarn and preparation method thereof

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Effective date of registration: 20230310

Address after: No. 38, Mingli Road, Hecheng Street, Gaoming District, Foshan City, Guangdong Province, 528500 (residence application)

Patentee after: Guangdong Kangpai Huanchuang Technology Co.,Ltd.

Address before: 528500 Guangdong city of Foshan province river export processing zone

Patentee before: Guangdong Esquel Textile Co.,Ltd.