CN104830062A - High-toughness and high-oil-resistant silicone rubber slurry used for preparing ultrathin sealing rubber layer and doped with nano carbon and preparation method thereof - Google Patents

Abstract

The invention relates to the field of silicone rubber composite processing and particularly relates to high-toughness and high-oil-resistant silicone rubber slurry used for preparing an ultrathin sealing rubber layer and doped with nano carbon and a preparation method thereof. The silicone rubber slurry is prepared from following raw materials, by weight: 5-7 parts of dioctyl phthalate, 1-2 parts of carbon nano tubes, 30-40 parts of methylbenzene, 12-16 parts of mica powder in 400-600 meshes, 1-2 parts of dihydroxydiphenylsilane, 15-18 parts of cyclohexane, 6-9 parts of liquid polysulfide rubber, 1-1.5 parts of maleic anhydride, 22-26 parts of silicone raw rubber, 0.1-0.2 parts of a defoaming agent, 0.5-1 part of 2,5-dimethyl-2,5-bis(tert-butyl-peroxyl)hexane, 0.1-0.2 parts of an adhesive 2260, 4-5 parts of a color master batch, 0.1-0.2 parts of an anti-oxidizing agent and 0.2-0.3 parts of an amino silane coupling agent. Compared with a conventional silicone rubber, the silicone rubber slurry is improved in performances. The mixed slurry is high in stability and is convenient to use in silk-screen printing. A vulcanized rubber layer can be as low as 0.05 mm in thickness, is excellent in toughness and strength, allows secondary processing, is economic and high-effective, is oil-resistant and abrasion-resistant, is durable in sealing effect, and is excellent in sealing effect on oil materials, liquids and such fluids.

Description

A kind of doping carbon nanometer high tenacity high resistance oil silicone rubber rubber cement for the preparation of Ultrathin sealed rubber layer and preparation method thereof

Technical field

The present invention relates to silicon rubber Compound Machining field, be specifically related to a kind of doping carbon nanometer high tenacity high resistance oil silicone rubber rubber cement for the preparation of Ultrathin sealed rubber layer and preparation method thereof.

Background technology

Ultra-thin rubber layer packing technique refers to that one is produced on the sealing member production technology of the upper ultra-thin rubber bodies of sulfuration of skeleton (metal sheet etc.).This product surface has very thin, the rubber layer of bonding by Vulcanization, sealed muscle is made on the surface of this layer of vulcanized rubber or edge, make it to oil plant, the fluids such as liquid produce sealing function, ultra-thin rubber layer wherein assembles fastening reliability and has more advantage than traditional part, fastening better reliability is assembled under equal moment of torsion, failure conditions reduces, effectively alleviate the weight of overall spare and accessory parts, than traditional sealing member, there is apparent advantage, and the ultra-thin rubber layer developing excellent property becomes the vital link of this ultra-thin rubber layer packing technique use properties kind of guarantee.

Silicon rubber has the advantages such as Nai Gaore, cold-resistant, good toughness, environmental protection and is widely adopted in the seal, but confirm through experimental result repeatedly, when preparing ultra-thin silicon glue-line, common solid silicone has following shortcoming: (1) premolding silica gel part is difficult to control, pendulum glue difficulty, production efficiency is low, be unfavorable for batch productization, the product layer of silica gel thickness that (2) are made exceeds, and can not reach design requirements; Liquid silica gel is used also to have following shortcoming: (1) liquid silica gel is made up of body and two, solidifying agent, can mix before using, need use within the regular hour, not so can solidify and lose use value, (2) ultra-thin rubber seal technology needs to make sealed muscle on rubber layer, and just can not it be machined after it has solidified, do not reach design requirements, (3) low strength of liquid silica gel, it weakens the sealing function of the fluid such as oil plant, liquid.Therefore, in order to the silastic-layer of the excellent ultrathin of processability, need to need on from raw material to technique to make further improvement.

Summary of the invention

The object of the invention is to, a kind of doping carbon nanometer high tenacity high resistance oil silicone rubber rubber cement for the preparation of Ultrathin sealed rubber layer and preparation method thereof is provided, this modified silicon rubber rubber cement improves the processing characteristics of traditional silicon rubber, and possess excellent mechanical property, be easy to put glue, sealing effectiveness is excellent; To achieve these goals, the technical solution used in the present invention is as follows:

A kind of doping carbon nanometer high tenacity high resistance oil silicone rubber rubber cement for the preparation of Ultrathin sealed rubber layer and preparation method thereof, it is characterized in that, described silicon rubber cement is made up of the raw material of following weight part: dioctyl ester 5-7, carbon nanotube 1-2, toluene 30-40, 400-600 order mica powder 12-16, Diphenylsilanediol 1-2, hexanaphthene 15-18, liquid polysulphide rubber 6-9, maleic anhydride 1-1.5, silica gel rubber 22-26, defoamer 0.1-0.2, two two or five vulcanizing agent 0.5-1, caking agent 2260 0.1-0.2, colour batch 4-5, oxidation inhibitor 0.1-0.2, amino silicane coupling agent 0.2-0.3,

The preparation method of described silicon rubber cement is:

(1) first carbon nanotube is mixed with mica powder, mixture is warming up to 550-650 DEG C with the temperature rise rate of 5-8 DEG C/min, room temperature is cooled to this understanding after roasting 4-5h, microscale powder must be activated, to drop in hexanaphthene after mixed powder and maleic anhydride, amino silicane coupling agent blending dispersion 20-30min subsequently, be uniformly mixed 50-60min, obtain mixed slurry for subsequent use;

(2) silica gel rubber, liquid polysulphide rubber are dropped in toluene solution, be stirred to after dissolving mixing completely, add step (1) gained mixed slurry, after continuing to be uniformly mixed 30-40min, add other leftover materials, be stirred to material and mix completely and get final product.

The modified silicon rubber rubber cement that the present invention prepares possesses following advantage:

(1) carbon nanotube-mica powder micro-scale filler of the surface grafting maleic anhydride, adulterated in rubber cement, activation homogenate is formed in advance in hexanaphthene, the consistency of this homogenate and silica gel mixing solutions is better, the rubber cement structure formed is more fine and close, intensity and rheological increase, and the mode of silk screen printing can be adopted to realize mass production.

(2), rubber cement retention period is long, can not lose use value because of solidification, and silk-screen remains silica gel and can collect and reuse, and material use efficiency is high.

(3) do not affect sulfidation after, by modes such as bakings making the organic solvent volatilizations such as toluene, can secondary processing be carried out.

(4), after sulfuration layer of silica gel thickness can be low to moderate 0.05mm, and strength high toughness is good, and oil resistant is wear-resisting, and sealing effectiveness not easily lost efficacy lastingly, has excellent sealing function to the fluid such as oil plant, liquid.

Embodiment

Embodiment

The rubber cement of the present embodiment is made up of the raw material of following weight part: dioctyl ester 6, carbon nanotube 1.5, toluene 35,500 order mica powder 15, Diphenylsilanediol 1.2, hexanaphthene 16, liquid polysulphide rubber 8, maleic anhydride 1.2, silica gel rubber 24, defoamer 0.1, two two or five vulcanizing agents 0.8, caking agent 2,260 0.1, colour batch 4, oxidation inhibitor 0.1, amino silicane coupling agent 0.2.

The preparation method of this rubber cement is:

(1) first carbon nanotube is mixed with mica powder, mixture is warming up to 550-650 DEG C with the temperature rise rate of 5-8 DEG C/min, room temperature is cooled to this understanding after roasting 5h, microscale powder must be activated, to drop in hexanaphthene after mixed powder and maleic anhydride, amino silicane coupling agent blending dispersion 30min subsequently, be uniformly mixed 50min, obtain mixed slurry for subsequent use;

(2) silica gel rubber, liquid polysulphide rubber are dropped in toluene solution, be stirred to after dissolving mixing completely, add step (1) gained mixed slurry, after continuing to be uniformly mixed 40min, add other leftover materials, be stirred to material and mix completely and get final product.

The performance test results of the thick rubber layer of 0.05mm that the rubber cement obtained by the present embodiment is formed is:

Test item	Detected result
		Shore hardness (degree)	62
Tensile strength at yield (MPa)	8.5
		Elongation at break (%)	380
100% tensile modulus (MPa)	3.0
		Compression set rate (22h × 175 DEG C)	10.2％
Low-temperature test (-25 DEG C × 3min)	Without damaged

Oil resistant test (resistance to 903 tests, 150 DEG C × 70h):

Changes in hardness (degree)	-4
		Tensile strength at yield velocity of variation (%)	-4.02％
Elongation at break velocity of variation (%)	-9.5％
		Volume change (%)	4.3％

Hot air burn-in test (175 DEG C × 168h):

Changes in hardness (degree)	4
		Tensile strength at yield velocity of variation (%)	4.52％
Elongation at break velocity of variation (%)	-7.5％

Claims (2)

1. doping carbon nanometer high tenacity high resistance oil silicone rubber rubber cement for the preparation of Ultrathin sealed rubber layer and preparation method thereof, it is characterized in that, described silicon rubber cement is made up of the raw material of following weight part: dioctyl ester 5-7, carbon nanotube 1-2, toluene 30-40, 400-600 order mica powder 12-16, Diphenylsilanediol 1-2, hexanaphthene 15-18, liquid polysulphide rubber 6-9, maleic anhydride 1-1.5, silica gel rubber 22-26, defoamer 0.1-0.2, two two or five vulcanizing agent 0.5-1, caking agent 2260 0.1-0.2, colour batch 4-5, oxidation inhibitor 0.1-0.2, amino silicane coupling agent 0.2-0.3.

2. a kind of doping carbon nanometer high tenacity high resistance oil silicone rubber rubber cement for the preparation of Ultrathin sealed rubber layer and preparation method thereof as claimed in claim 1, its preparation method is:

(1) first carbon nanotube is mixed with mica powder, mixture is warming up to 550-650 DEG C with the temperature rise rate of 5-8 DEG C/min, room temperature is cooled to this understanding after roasting 4-5h, microscale powder must be activated, to drop in hexanaphthene after mixed powder and maleic anhydride, amino silicane coupling agent blending dispersion 20-30min subsequently, be uniformly mixed 50-60min, obtain mixed slurry for subsequent use;

(2) silica gel rubber, liquid polysulphide rubber are dropped in toluene solution, be stirred to after dissolving mixing completely, add step (1) gained mixed slurry, after continuing to be uniformly mixed 30-40min, add other leftover materials, be stirred to material and mix completely and get final product.