CN104830064A - High-strength silicone rubber slurry used for preparing ultrathin sealing rubber layer and doped with graphene oxide and preparation method thereof - Google Patents

Abstract

The invention relates to the field of silicone rubber composite processing and particularly relates to high-strength silicone rubber slurry used for preparing an ultrathin sealing rubber layer and doped with graphene oxide and a preparation method thereof. The silicone rubber slurry is prepared from following raw materials, by weight, 10-12 parts of nano fluorapatite, 20-25 parts of silicone raw rubber, 20-30 parts of methylbenzene, 3-5 parts of a color master batch, 2-3 parts of powdery graphene oxide, 0.1-0.2 parts of a defoaming agent, 10-14 parts of cyclohexane, 1-2 parts of hydroxyethyl methylacrylate, 0.5-0.8 parts of 2,5-dimethyl-2,5-bis(tert-butyl-peroxyl)hexane, 0.1-0.2 parts of an adhesive 2260, 0.1-0.2 parts of an anti-oxidizing agent and 0.2-0.3 parts of an amino silane coupling agent. Compared with a conventional silicone rubber, the silicone rubber slurry is improved in performances, is good in stability and is convenient to use in silk-screen printing. A vulcanized rubber layer can be as low as 0.05 mm in thickness, is stable in form, is good in adhesivity with a base material, is good in strength and size stability, is not liable to cause corrosion and further failure, and is excellent in sealing effect on oil materials, liquids and such fluids.

Description

High-strength silicone rubber rubber cement of a kind of doped with oxygen functionalized graphene for the preparation of Ultrathin sealed rubber layer and preparation method thereof

Technical field

The present invention relates to silicon rubber Compound Machining field, be specifically related to high-strength silicone rubber rubber cement of a kind of doped with oxygen functionalized graphene for the preparation of Ultrathin sealed rubber layer and preparation method thereof.

Background technology

Ultra-thin rubber layer packing technique refers to that one is produced on the sealing member production technology of the upper ultra-thin rubber bodies of sulfuration of skeleton (metal sheet etc.).This product surface has very thin, the rubber layer of bonding by Vulcanization, sealed muscle is made on the surface of this layer of vulcanized rubber or edge, make it to oil plant, the fluids such as liquid produce sealing function, ultra-thin rubber layer wherein assembles fastening reliability and has more advantage than traditional part, fastening better reliability is assembled under equal moment of torsion, failure conditions reduces, effectively alleviate the weight of overall spare and accessory parts, than traditional sealing member, there is apparent advantage, and the ultra-thin rubber layer developing excellent property becomes the vital link of this ultra-thin rubber layer packing technique use properties kind of guarantee.

Silicon rubber has the advantages such as Nai Gaore, cold-resistant, good toughness, environmental protection and is widely adopted in the seal, but confirm through experimental result repeatedly, when preparing ultra-thin silicon glue-line, common solid silicone has following shortcoming: (1) premolding silica gel part is difficult to control, pendulum glue difficulty, production efficiency is low, be unfavorable for batch productization, the product layer of silica gel thickness that (2) are made exceeds, and can not reach design requirements; Liquid silica gel is used also to have following shortcoming: (1) liquid silica gel is made up of body and two, solidifying agent, can mix before using, need use within the regular hour, not so can solidify and lose use value, (2) ultra-thin rubber seal technology needs to make sealed muscle on rubber layer, and just can not it be machined after it has solidified, do not reach design requirements, (3) low strength of liquid silica gel, it weakens the sealing function of the fluid such as oil plant, liquid.Therefore, in order to the silastic-layer of the excellent ultrathin of processability, need to need on from raw material to technique to make further improvement.

Summary of the invention

The object of the invention is to, high-strength silicone rubber rubber cement of a kind of doped with oxygen functionalized graphene for the preparation of Ultrathin sealed rubber layer and preparation method thereof is provided, this modified silicon rubber rubber cement improves the processing characteristics of traditional silicon rubber, possess excellent mechanical property, improve the sealing effectiveness of sealing member; To achieve these goals, the technical solution used in the present invention is as follows:

High-strength silicone rubber rubber cement of a kind of doped with oxygen functionalized graphene for the preparation of Ultrathin sealed rubber layer and preparation method thereof, it is characterized in that, described silicon rubber cement is made up of the raw material of following weight part: nanometer fluorapatite 10-12, silica gel rubber 20-25, toluene 20-30, colour batch 3-5, powdery graphene oxide 2-3, defoamer 0.1-0.2, hexanaphthene 10-14, hydroxyethyl methylacrylate 1-2, two two or five vulcanizing agent 0.5-0.8, caking agent 22600.1-0.2, oxidation inhibitor 0.1-0.2, amino silicane coupling agent 0.2-0.3;

The preparation method of described silicon rubber cement is:

(1) first nanometer fluorapatite is mixed with graphene oxide, mixture is warming up to 400-500 DEG C with the temperature rise rate of 5-8 DEG C/min, room temperature is cooled to this understanding after roasting 2-3h, microscale powder must be activated, subsequently mixed powder and hydroxyethyl methylacrylate, amino silicane coupling agent mixed grinding are dropped in hexanaphthene after disperseing 20-30min, be uniformly mixed 50-60min, obtain mixed slurry for subsequent use;

(2) silica gel rubber is dropped in toluene solution, be stirred to after it dissolves completely, add step (1) gained mixed slurry, after continuing to be uniformly mixed 30-40min, add other leftover materials, be stirred to material and mix completely and get final product.

The modified silicon rubber rubber cement that the present invention prepares possesses following advantage:

(1) the nanometer fluorapatite-graphene oxide micro-scale filler of the surface grafting hydroxyethyl methylacrylate, adulterated in rubber cement, activation homogenate is formed in advance in hexanaphthene, improve the consistency reactive behavior between raw material, ultimately improve silicon rubber use properties, obtained rubber cement uniform and smooth, thixotropy is good, and the mode of silk screen printing can be adopted to realize mass production.

(2), rubber cement retention period is long, can not lose use value because of solidification, and silk-screen remains silica gel and can collect and reuse, and material use efficiency is high.

(3) do not affect sulfidation after, by modes such as bakings making the organic solvent volatilizations such as toluene, can reprocess.

(4), after sulfuration layer of silica gel thickness can be low to moderate 0.05mm, the form stable of glue-line, and good with base material stickiness, strength high toughness is good, not easily corrosion failure, has excellent sealing function to the fluid such as oil plant, liquid.

Embodiment

Embodiment

The rubber cement of the present embodiment is made up of the raw material of following weight part: nanometer fluorapatite 11, silica gel rubber 24, toluene 28, colour batch 4, powdery graphene oxide 3, defoamer 0.1, hexanaphthene 13, hydroxyethyl methylacrylate 1.5, two two or five vulcanizing agents 0.6, caking agent 22600.1, oxidation inhibitor 0.1, amino silicane coupling agent 0.2.

The preparation method of this rubber cement is:

(1) first nanometer fluorapatite is mixed with graphene oxide, mixture is warming up to 400-500 DEG C with the temperature rise rate of 5-8 DEG C/min, room temperature is cooled to this understanding after roasting 3h, microscale powder must be activated, subsequently mixed powder and hydroxyethyl methylacrylate, amino silicane coupling agent mixed grinding are dropped in hexanaphthene after disperseing 30min, be uniformly mixed 60min, obtain mixed slurry for subsequent use;

(2) silica gel rubber is dropped in toluene solution, be stirred to after it dissolves completely, add step (1) gained mixed slurry, after continuing to be uniformly mixed 40min, add other leftover materials, be stirred to material and mix completely and get final product.

The performance test results of the thick rubber layer of 0.05mm that the rubber cement obtained by the present embodiment is formed is:

Test item	Detected result
		Shore hardness (degree)	62
Tensile strength at yield (MPa)	8.0
		Elongation at break (%)	348
100% tensile modulus (MPa)	3.3
		Compression set rate (22h × 175 DEG C)	10.4％
Low-temperature test (-25 DEG C × 3min)	Without damaged

Oil resistant test (resistance to 903 tests, 150 DEG C × 70h):

Changes in hardness (degree)	-4
		Tensile strength at yield velocity of variation (%)	-6.2％
Elongation at break velocity of variation (%)	-9.8％
		Volume change (%)	4.3％

Hot air burn-in test (175 DEG C × 168h):

Changes in hardness (degree)	3
		Tensile strength at yield velocity of variation (%)	3.5％
Elongation at break velocity of variation (%)	-10.6％

Claims (2)

1. high-strength silicone rubber rubber cement for the preparation of the doped with oxygen functionalized graphene of Ultrathin sealed rubber layer and preparation method thereof, it is characterized in that, described silicon rubber cement is made up of the raw material of following weight part: nanometer fluorapatite 10-12, silica gel rubber 20-25, toluene 20-30, colour batch 3-5, powdery graphene oxide 2-3, defoamer 0.1-0.2, hexanaphthene 10-14, hydroxyethyl methylacrylate 1-2, two two or five vulcanizing agent 0.5-0.8, caking agent 2260 0.1-0.2, oxidation inhibitor 0.1-0.2, amino silicane coupling agent 0.2-0.3.

2. the high-strength silicone rubber rubber cement and preparation method thereof of a kind of doped with oxygen functionalized graphene for the preparation of Ultrathin sealed rubber layer as claimed in claim 1, its preparation method is:

(1) first nanometer fluorapatite is mixed with graphene oxide, mixture is warming up to 400-500 DEG C with the temperature rise rate of 5-8 DEG C/min, room temperature is cooled to this understanding after roasting 2-3h, microscale powder must be activated, subsequently mixed powder and hydroxyethyl methylacrylate, amino silicane coupling agent mixed grinding are dropped in hexanaphthene after disperseing 20-30min, be uniformly mixed 50-60min, obtain mixed slurry for subsequent use;

(2) silica gel rubber is dropped in toluene solution, be stirred to after it dissolves completely, add step (1) gained mixed slurry, after continuing to be uniformly mixed 30-40min, add other leftover materials, be stirred to material and mix completely and get final product.