CN104805433A - High strength coating for metal surface and preparation method of high strength coating - Google Patents

High strength coating for metal surface and preparation method of high strength coating Download PDF

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CN104805433A
CN104805433A CN201510203340.9A CN201510203340A CN104805433A CN 104805433 A CN104805433 A CN 104805433A CN 201510203340 A CN201510203340 A CN 201510203340A CN 104805433 A CN104805433 A CN 104805433A
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auxiliary agent
parts
powder
zinc
pulverize
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吴明
黄莉
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Suzhou Tong Ming Machinery Co Ltd
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Suzhou Tong Ming Machinery Co Ltd
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Abstract

The invention discloses a high strength coating for metal surface and a preparation method of the high strength coating. The high strength coating comprises the following ingredients by weight percent: 0.42-0.45 percent of carbon, 0.6-0.8 percent of boron, 9.5-9.8 percent of chrome, 3.2-3.5 percent of titanium, 5.5-5.8 percent of sodium, 2.5-2.8 percent of scandium, 2.2-2.5 percent of niobium, 1.4-1.6 percent of zirconium, 0.2-0.4 percent of barium, 0.2-0.4 percent of tungsten, 1.2-1.5 percent of zinc, 2.5-2.8 percent of samarium, 3.2-3.7 percent of neodymium, 0.3-0.5 percent of promethium, 0.2-0.4 percent of europium, 9.2-9.5 percent of gadolinium, 0.2-0.8 percent of aluminum, 2.4-2.6 percent of auxiliaries and the balance of ferrum.

Description

A kind of high-strength coating for metallic surface and preparation method thereof
Technical field
The invention belongs to metal field, relate to a kind of high-strength coating for metallic surface and preparation method thereof.
Background technology
Along with the progress of society and the development of science and technology, metal products is more and more extensive in the utilization of the various fields of recent life of industry, agricultural and people, also gives social creativity increasing value simultaneously.Current, metal products is faced with a lot of problem, and wherein strength problem is the problem that metal products must face and solve, and in order to improve the intensity, wear-resisting and high temperature resistant of metal products, people are realized by metallic coating fast in surface of metal product usually; But produce metallic coating still to have problems, as: production cost is high, work-ing life is short, heat-resistant antifriction performance is low, popularizing application prospect is little.
Summary of the invention
Technical problem to be solved by this invention is, overcomes the shortcoming of prior art, provides a kind of high-strength coating for metallic surface and preparation method thereof, not only intensity is high, resistance to corrosion and resistance of oxidation extremely strong, and the rub resistance ability on its surface improves greatly, reduces its wearing and tearing, increase its work-ing life, excellent adsorption, and preparation method is provided, method is simple, cost is low, and production efficiency is high.
In order to solve above technical problem, the invention provides a kind of high-strength coating for metallic surface, the component of this high-strength coating is by mass percentage: carbon: 0.42-0.45%, boron: 0.6-0.8%, chromium: 9.5-9.8%, titanium: 3.2-3.5%, sodium: 5.5-5.8%, scandium: 2.5-2.8%, niobium: 2.2-2.5%, zirconium: 1.4-1.6%, barium: 0.2-0.4%, tungsten: 0.2-0.4%, zinc: 1.2-1.5%, samarium: 2.5-2.8%, neodymium: 3.2-3.7%, promethium: 0.3-0.5%, europium: 0.2-0.4%, gadolinium: 9.2-9.5%, aluminium: 0.2-0.8%, auxiliary agent: 2.4-2.6%, surplus is iron,
The component of auxiliary agent is counted by weight: zircon: 5-8 part, kaolinite: 12-14 part, clay: 17-19 part, copper powder: 4-6 part, nickel powder: 3-5 part, zinc powder: 1-3 part;
The preparation method of auxiliary agent is: the mixing of zircon, kaolinite, clay, copper powder, nickel powder and zinc powder sent in ball mill and pulverize, cross 40 mesh sieves, obtain powder particle, then heating temperatures is calcined 2-3 after individual hour at 710-720 DEG C, air cooling is to room temperature, then pulverize, cross 100 mesh sieves, can auxiliary agent be obtained.
The present invention is also provided for the preparation method of the high-strength coating of metallic surface, and concrete preparation method is as follows:
Step (1): carbon, boron, chromium, titanium, sodium, scandium, niobium, zirconium, barium, tungsten, zinc, aluminium and ferro element are put into smelting furnace, then after furnace temperature being risen to 620-630 DEG C, insulation 1-3 hour, then temperature is risen to 1150-1160 DEG C, put into samarium, neodymium, promethium, europium, gadolinium rare earth element, stir, insulation 3-5 hour, then air cooling is to 350-360 DEG C, then air cooling is to room temperature;
Step (2): through the refining of LF stove, temperature is increased to 1420-1430 DEG C, and puts into auxiliary agent, insulation 3-5h, omnidistance nitrogen blowing stirs, and then cools the temperature to as 670-680 DEG C; Then water-cooled is cooled to 350-360 DEG C with the speed of 7-10 DEG C/s, and then air cooling is to room temperature;
Step (3): the metal that step (2) obtains is put into ball mill, temperature is increased to 420-450 DEG C, insulation 1-3 hour, then start ball mill abrasive dust, then temperature is increased to 820-830 DEG C, insulation 1-2 hour, be reduced to 550-560 DEG C, pulverize, cross 100 mesh sieves, obtain powder particle B;
Step (4): it is 1-3mm that the powder particle B in step (3) is sprayed into metallic surface thickness, is then heated to 750-770 DEG C, insulation 1-2 hour, then cool the temperature to 220-250 DEG C, insulation 1-2 hour, air cooling is to room temperature.
The technical scheme that the present invention limits further is:
The aforesaid high-strength coating for metallic surface, the component of this high-strength coating is by mass percentage: carbon: 0.42%, boron: 0.6%, chromium: 9.5%, titanium: 3.2%, sodium: 5.5%, scandium: 2.5%, niobium: 2.2%, zirconium: 1.4%, barium: 0.2%, tungsten: 0.2%, zinc: 1.2%, samarium: 2.5%, neodymium: 3.2%, promethium: 0.3%, europium: 0.2%, gadolinium: 9.2%, aluminium: 0.2%, auxiliary agent: 2.4%, surplus is iron;
The component of auxiliary agent is counted by weight: zircon: 5 parts, kaolinite: 12 parts, clay: 17 parts, copper powder: 4 parts, nickel powder: 3 parts, zinc powder: 1 part;
The preparation method of auxiliary agent is: the mixing of zircon, kaolinite, clay, copper powder, nickel powder and zinc powder sent in ball mill and pulverize, cross 40 mesh sieves, obtain powder particle, then by calcining at heating temperatures to 710 DEG C after 2 hours, air cooling is to room temperature, then pulverize, cross 100 mesh sieves, can auxiliary agent be obtained.
The aforesaid high-strength coating for metallic surface, the component of this high-strength coating is by mass percentage: carbon: 0.45%, boron: 0.8%, chromium: 9.8%, titanium: 3.5%, sodium: 5.8%, scandium: 2.8%, niobium: 2.5%, zirconium: 1.6%, barium: 0.4%, tungsten: 0.4%, zinc: 1.5%, samarium: 2.8%, neodymium: 3.7%, promethium: 0.5%, europium: 0.4%, gadolinium: 9.5%, aluminium: 0.8%, auxiliary agent: 2.6%, surplus is iron;
The component of auxiliary agent is counted by weight: zircon: 8 parts, kaolinite: 14 parts, clay: 19 parts, copper powder: 6 parts, nickel powder: 5 parts, zinc powder: 3 parts;
The preparation method of auxiliary agent is: the mixing of zircon, kaolinite, clay, copper powder, nickel powder and zinc powder sent in ball mill and pulverize, cross 40 mesh sieves, obtain powder particle, then by calcining at heating temperatures to 720 DEG C after 3 hours, air cooling is to room temperature, then pulverize, cross 100 mesh sieves, can auxiliary agent be obtained.
The aforesaid high-strength coating for metallic surface, the component of this high-strength coating is by mass percentage: carbon: 0.44%, boron: 0.7%, chromium: 9.7%, titanium: 3.3%, sodium: 5.6%, scandium: 2.7%, niobium: 2.4%, zirconium: 1.5%, barium: 0.3%, tungsten: 0.3%, zinc: 1.4%, samarium: 2.7%, neodymium: 3.5%, promethium: 0.4%, europium: 0.3%, gadolinium: 9.4%, aluminium: 0.6%, auxiliary agent: 2.5%, surplus is iron;
The component of auxiliary agent is counted by weight: zircon: 7 parts, kaolinite: 13 parts, clay: 18 parts, copper powder: 5 parts, nickel powder: 4 parts, zinc powder: 2 parts;
The preparation method of auxiliary agent is: the mixing of zircon, kaolinite, clay, copper powder, nickel powder and zinc powder sent in ball mill and pulverize, cross 40 mesh sieves, obtain powder particle, then by calcining at heating temperatures to 715 DEG C after 2 hours, air cooling is to room temperature, then pulverize, cross 100 mesh sieves, can auxiliary agent be obtained.
The invention has the beneficial effects as follows: this coating not only intensity is high, resistance to corrosion and resistance of oxidation extremely strong, and the rub resistance ability on its surface improves greatly, reduces its wearing and tearing, increase its work-ing life, excellent adsorption, and preparation method is provided, method is simple, and cost is low, and production efficiency is high; Titanium elements is added in its floating coat, erosion resistance and intensity can be improved, add niobium element, energy crystal grain thinning in thermal treatment, can strengthen its intensity, toughness, anticorrosive, the wear-resisting and load that withstands shocks etc., add tungsten and aluminium element, energy crystal grain thinning and its superheated susceptivity of reduction and temper brittleness, improve intensity, resistant to hydrogen under weather-resistant and high temperature, nitrogen, ammonia corrosion can be improved, add chromium and zinc element, its wear-resisting ability ability can be improved and increase its intensity, improve its fusing point, increase ability and the resistance of oxidation of high temperature resistance; And add the samarium in rare earth element, neodymium, promethium, europium, gadolinium element, can in heat treatment process crystal grain thinning, form fine and close crystalline structure, increase intensity and the crocking resistance of coating, and in auxiliary agent, with the addition of clay, copper powder and nickel powder, the effect of catalyzer can be played in process of production, enhance productivity and increase intensity and the crocking resistance of coating.
Embodiment
embodiment 1
A kind of high-strength coating for metallic surface that the present embodiment provides, the component of this high-strength coating is by mass percentage: carbon: 0.42%, boron: 0.6%, chromium: 9.5%, titanium: 3.2%, sodium: 5.5%, scandium: 2.5%, niobium: 2.2%, zirconium: 1.4%, barium: 0.2%, tungsten: 0.2%, zinc: 1.2%, samarium: 2.5%, neodymium: 3.2%, promethium: 0.3%, europium: 0.2%, gadolinium: 9.2%, aluminium: 0.2%, auxiliary agent: 2.4%, surplus is iron;
The component of auxiliary agent is counted by weight: zircon: 5 parts, kaolinite: 12 parts, clay: 17 parts, copper powder: 4 parts, nickel powder: 3 parts, zinc powder: 1 part;
The preparation method of auxiliary agent is: the mixing of zircon, kaolinite, clay, copper powder, nickel powder and zinc powder sent in ball mill and pulverize, cross 40 mesh sieves, obtain powder particle, then by calcining at heating temperatures to 710 DEG C after 2 hours, air cooling is to room temperature, then pulverize, cross 100 mesh sieves, can auxiliary agent be obtained.
The present embodiment is also provided for the preparation method of the high-strength coating of metallic surface, and concrete preparation method is as follows:
Step (1): carbon, boron, chromium, titanium, sodium, scandium, niobium, zirconium, barium, tungsten, zinc, aluminium and ferro element are put into smelting furnace, then after furnace temperature being risen to 620 DEG C, be incubated 1 hour, then temperature is risen to 1150 DEG C, put into samarium, neodymium, promethium, europium, gadolinium rare earth element, stir, be incubated 3 hours, then air cooling to 350 DEG C, then air cooling is to room temperature;
Step (2): through the refining of LF stove, temperature is increased to 1420 DEG C, and puts into auxiliary agent, insulation 3h, omnidistance nitrogen blowing stirs, and then cooling the temperature to is 670 DEG C; Then water-cooled is cooled to 350 DEG C with the speed of 7 DEG C/s, and then air cooling is to room temperature;
Step (3): the metal that step (2) obtains is put into ball mill, temperature is increased to 420 DEG C, is incubated 1 hour, then starts ball mill abrasive dust, again temperature is increased to 820 DEG C, is incubated 1 hour, is being reduced to 550 DEG C, pulverize, cross 100 mesh sieves, obtain powder particle B;
Step (4): it is 1mm that the powder particle B in step (3) is sprayed into metallic surface thickness, is then heated to 750 DEG C, is incubated 1 hour, then cools the temperature to 220 DEG C, and be incubated 1 hour, air cooling is to room temperature.
embodiment 2
A kind of high-strength coating for metallic surface that the present embodiment provides, the component of this high-strength coating is by mass percentage: carbon: 0.45%, boron: 0.8%, chromium: 9.8%, titanium: 3.5%, sodium: 5.8%, scandium: 2.8%, niobium: 2.5%, zirconium: 1.6%, barium: 0.4%, tungsten: 0.4%, zinc: 1.5%, samarium: 2.8%, neodymium: 3.7%, promethium: 0.5%, europium: 0.4%, gadolinium: 9.5%, aluminium: 0.8%, auxiliary agent: 2.6%, surplus is iron;
The component of auxiliary agent is counted by weight: zircon: 8 parts, kaolinite: 14 parts, clay: 19 parts, copper powder: 6 parts, nickel powder: 5 parts, zinc powder: 3 parts;
The preparation method of auxiliary agent is: the mixing of zircon, kaolinite, clay, copper powder, nickel powder and zinc powder sent in ball mill and pulverize, cross 40 mesh sieves, obtain powder particle, then by calcining at heating temperatures to 720 DEG C after 3 hours, air cooling is to room temperature, then pulverize, cross 100 mesh sieves, can auxiliary agent be obtained.
The present embodiment is also provided for the preparation method of the high-strength coating of metallic surface, and concrete preparation method is as follows:
Step (1): carbon, boron, chromium, titanium, sodium, scandium, niobium, zirconium, barium, tungsten, zinc, aluminium and ferro element are put into smelting furnace, then after furnace temperature being risen to 630 DEG C, be incubated 3 hours, then temperature is risen to 1160 DEG C, put into samarium, neodymium, promethium, europium, gadolinium rare earth element, stir, be incubated 5 hours, then air cooling to 360 DEG C, then air cooling is to room temperature;
Step (2): through the refining of LF stove, temperature is increased to 1430 DEG C, and puts into auxiliary agent, insulation 5h, omnidistance nitrogen blowing stirs, and then cooling the temperature to is 680 DEG C; Then water-cooled is cooled to 360 DEG C with the speed of 10 DEG C/s, and then air cooling is to room temperature;
Step (3): the metal that step (2) obtains is put into ball mill, temperature is increased to 450 DEG C, is incubated 3 hours, then starts ball mill abrasive dust, again temperature is increased to 830 DEG C, is incubated 2 hours, is being reduced to 560 DEG C, pulverize, cross 100 mesh sieves, obtain powder particle B;
Step (4): it is 3mm that the powder particle B in step (3) is sprayed into metallic surface thickness, is then heated to 770 DEG C, is incubated 2 hours, then cools the temperature to 250 DEG C, and be incubated 2 hours, air cooling is to room temperature.
embodiment 3
A kind of high-strength coating for metallic surface that the present embodiment provides, the component of this high-strength coating is by mass percentage: carbon: 0.44%, boron: 0.7%, chromium: 9.7%, titanium: 3.3%, sodium: 5.6%, scandium: 2.7%, niobium: 2.4%, zirconium: 1.5%, barium: 0.3%, tungsten: 0.3%, zinc: 1.4%, samarium: 2.7%, neodymium: 3.5%, promethium: 0.4%, europium: 0.3%, gadolinium: 9.4%, aluminium: 0.6%, auxiliary agent: 2.5%, surplus is iron;
The component of auxiliary agent is counted by weight: zircon: 7 parts, kaolinite: 13 parts, clay: 18 parts, copper powder: 5 parts, nickel powder: 4 parts, zinc powder: 2 parts;
The preparation method of auxiliary agent is: the mixing of zircon, kaolinite, clay, copper powder, nickel powder and zinc powder sent in ball mill and pulverize, cross 40 mesh sieves, obtain powder particle, then by calcining at heating temperatures to 715 DEG C after 2 hours, air cooling is to room temperature, then pulverize, cross 100 mesh sieves, can auxiliary agent be obtained.
The present embodiment is also provided for the preparation method of the high-strength coating of metallic surface, and concrete preparation method is as follows:
Step (1): carbon, boron, chromium, titanium, sodium, scandium, niobium, zirconium, barium, tungsten, zinc, aluminium and ferro element are put into smelting furnace, then after furnace temperature being risen to 628 DEG C, be incubated 2 hours, then temperature is risen to 1158 DEG C, put into samarium, neodymium, promethium, europium, gadolinium rare earth element, stir, be incubated 4 hours, then air cooling to 358 DEG C, then air cooling is to room temperature;
Step (2): through the refining of LF stove, temperature is increased to 1428 DEG C, and puts into auxiliary agent, insulation 4h, omnidistance nitrogen blowing stirs, and then cooling the temperature to is 675 DEG C; Then water-cooled is cooled to 356 DEG C with the speed of 8 DEG C/s, and then air cooling is to room temperature;
Step (3): the metal that step (2) obtains is put into ball mill, temperature is increased to 428 DEG C, is incubated 2 hours, then starts ball mill abrasive dust, again temperature is increased to 826 DEG C, is incubated 2 hours, is being reduced to 557 DEG C, pulverize, cross 100 mesh sieves, obtain powder particle B;
Step (4): it is 2mm that the powder particle B in step (3) is sprayed into metallic surface thickness, is then heated to 760 DEG C, is incubated 2 hours, then cools the temperature to 230 DEG C, and be incubated 1 hour, air cooling is to room temperature.
Above embodiment is only and technological thought of the present invention is described, can not limit protection scope of the present invention with this, and every technological thought proposed according to the present invention, any change that technical scheme basis is done, all falls within scope.

Claims (5)

1. the high-strength coating for metallic surface, it is characterized in that: the component of this high-strength coating is by mass percentage: carbon: 0.42-0.45%, boron: 0.6-0.8%, chromium: 9.5-9.8%, titanium: 3.2-3.5%, sodium: 5.5-5.8%, scandium: 2.5-2.8%, niobium: 2.2-2.5%, zirconium: 1.4-1.6%, barium: 0.2-0.4%, tungsten: 0.2-0.4%, zinc: 1.2-1.5%, samarium: 2.5-2.8%, neodymium: 3.2-3.7%, promethium: 0.3-0.5%, europium: 0.2-0.4%, gadolinium: 9.2-9.5%, aluminium: 0.2-0.8%, auxiliary agent: 2.4-2.6%, surplus is iron;
The component of described auxiliary agent is counted by weight: zircon: 5-8 part, kaolinite: 12-14 part, clay: 17-19 part, copper powder: 4-6 part, nickel powder: 3-5 part, zinc powder: 1-3 part;
The preparation method of described auxiliary agent is: the mixing of zircon, kaolinite, clay, copper powder, nickel powder and zinc powder sent in ball mill and pulverize, cross 40 mesh sieves, obtain powder particle, then heating temperatures is calcined 2-3 after individual hour at 710-720 DEG C, air cooling is to room temperature, then pulverize, cross 100 mesh sieves, can auxiliary agent be obtained.
2. the high-strength coating for metallic surface according to claim 1, is characterized in that: the component of this high-strength coating is by mass percentage: carbon: 0.42%, boron: 0.6%, chromium: 9.5%, titanium: 3.2%, sodium: 5.5%, scandium: 2.5%, niobium: 2.2%, zirconium: 1.4%, barium: 0.2%, tungsten: 0.2%, zinc: 1.2%, samarium: 2.5%, neodymium: 3.2%, promethium: 0.3%, europium: 0.2%, gadolinium: 9.2%, aluminium: 0.2%, auxiliary agent: 2.4%, surplus is iron;
The component of described auxiliary agent is counted by weight: zircon: 5 parts, kaolinite: 12 parts, clay: 17 parts, copper powder: 4 parts, nickel powder: 3 parts, zinc powder: 1 part;
The preparation method of described auxiliary agent is: the mixing of zircon, kaolinite, clay, copper powder, nickel powder and zinc powder sent in ball mill and pulverize, cross 40 mesh sieves, obtain powder particle, then by calcining at heating temperatures to 710 DEG C after 2 hours, air cooling is to room temperature, then pulverize, cross 100 mesh sieves, can auxiliary agent be obtained.
3. the high-strength coating for metallic surface according to claim 1, is characterized in that: the component of this high-strength coating is by mass percentage: carbon: 0.45%, boron: 0.8%, chromium: 9.8%, titanium: 3.5%, sodium: 5.8%, scandium: 2.8%, niobium: 2.5%, zirconium: 1.6%, barium: 0.4%, tungsten: 0.4%, zinc: 1.5%, samarium: 2.8%, neodymium: 3.7%, promethium: 0.5%, europium: 0.4%, gadolinium: 9.5%, aluminium: 0.8%, auxiliary agent: 2.6%, surplus is iron;
The component of described auxiliary agent is counted by weight: zircon: 8 parts, kaolinite: 14 parts, clay: 19 parts, copper powder: 6 parts, nickel powder: 5 parts, zinc powder: 3 parts;
The preparation method of described auxiliary agent is: the mixing of zircon, kaolinite, clay, copper powder, nickel powder and zinc powder sent in ball mill and pulverize, cross 40 mesh sieves, obtain powder particle, then by calcining at heating temperatures to 720 DEG C after 3 hours, air cooling is to room temperature, then pulverize, cross 100 mesh sieves, can auxiliary agent be obtained.
4. the high-strength coating for metallic surface according to claim 1, is characterized in that: the component of this high-strength coating is by mass percentage: carbon: 0.44%, boron: 0.7%, chromium: 9.7%, titanium: 3.3%, sodium: 5.6%, scandium: 2.7%, niobium: 2.4%, zirconium: 1.5%, barium: 0.3%, tungsten: 0.3%, zinc: 1.4%, samarium: 2.7%, neodymium: 3.5%, promethium: 0.4%, europium: 0.3%, gadolinium: 9.4%, aluminium: 0.6%, auxiliary agent: 2.5%, surplus is iron;
The component of described auxiliary agent is counted by weight: zircon: 7 parts, kaolinite: 13 parts, clay: 18 parts, copper powder: 5 parts, nickel powder: 4 parts, zinc powder: 2 parts;
The preparation method of described auxiliary agent is: the mixing of zircon, kaolinite, clay, copper powder, nickel powder and zinc powder sent in ball mill and pulverize, cross 40 mesh sieves, obtain powder particle, then by calcining at heating temperatures to 715 DEG C after 2 hours, air cooling is to room temperature, then pulverize, cross 100 mesh sieves, can auxiliary agent be obtained.
5. for a preparation method for the high-strength coating of metallic surface, it is characterized in that, concrete preparation method is as follows:
Step (1): carbon, boron, chromium, titanium, sodium, scandium, niobium, zirconium, barium, tungsten, zinc, aluminium and ferro element are put into smelting furnace, then after furnace temperature being risen to 620-630 DEG C, insulation 1-3 hour, then temperature is risen to 1150-1160 DEG C, put into samarium, neodymium, promethium, europium, gadolinium rare earth element, stir, insulation 3-5 hour, then air cooling is to 350-360 DEG C, then air cooling is to room temperature;
Step (2): through the refining of LF stove, temperature is increased to 1420-1430 DEG C, and puts into auxiliary agent, insulation 3-5h, omnidistance nitrogen blowing stirs, and then cools the temperature to as 670-680 DEG C; Then water-cooled is cooled to 350-360 DEG C with the speed of 7-10 DEG C/s, and then air cooling is to room temperature;
Step (3): the metal that step (2) obtains is put into ball mill, temperature is increased to 420-450 DEG C, insulation 1-3 hour, then start ball mill abrasive dust, then temperature is increased to 820-830 DEG C, insulation 1-2 hour, be reduced to 550-560 DEG C, pulverize, cross 100 mesh sieves, obtain powder particle B;
Step (4): it is 1-3mm that the powder particle B in step (3) is sprayed into metallic surface thickness, is then heated to 750-770 DEG C, insulation 1-2 hour, then cool the temperature to 220-250 DEG C, insulation 1-2 hour, air cooling is to room temperature.
CN201510203340.9A 2015-04-27 2015-04-27 High strength coating for metal surface and preparation method of high strength coating Pending CN104805433A (en)

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CN102218857A (en) * 2011-05-27 2011-10-19 合肥金四达科技有限公司 Composite material coated with SiC-Fe based alloy layer and preparation method of composite material
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CN105154792A (en) * 2015-09-07 2015-12-16 南京腾达五金制品有限公司 High temperature resistant alloy coating for cutter and preparation method high temperature resistant alloy coating
CN105244784A (en) * 2015-11-10 2016-01-13 鼎圣电气有限公司 High-low-voltage switch cabinet having dust removing function
CN105368099A (en) * 2015-11-12 2016-03-02 江苏宇恒电气有限公司 High-strength coating for surface of switch cabinet
CN105400324A (en) * 2015-11-12 2016-03-16 江苏宇恒电气有限公司 Corrosion-resistant high-low voltage switch cabinet
CN105506612A (en) * 2016-01-15 2016-04-20 盐城法尔机械有限公司 High-strength valve for steam
CN105508686A (en) * 2016-01-15 2016-04-20 盐城法尔机械有限公司 Safety valve used at high temperature and pressure
CN105508687A (en) * 2016-01-15 2016-04-20 盐城法尔机械有限公司 Safety valve with high corrosion resistance
CN106756575A (en) * 2016-12-12 2017-05-31 苏州陈恒织造有限公司 A kind of high pressure resistant warp sizing machine shower nozzle of shock resistance
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