CN104805375B - A kind of ultra thick gauge high tenacity X80 pipeline steel and its manufacture method - Google Patents

A kind of ultra thick gauge high tenacity X80 pipeline steel and its manufacture method Download PDF

Info

Publication number
CN104805375B
CN104805375B CN201510153571.3A CN201510153571A CN104805375B CN 104805375 B CN104805375 B CN 104805375B CN 201510153571 A CN201510153571 A CN 201510153571A CN 104805375 B CN104805375 B CN 104805375B
Authority
CN
China
Prior art keywords
less
steel plate
steel
rolling
thickness
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201510153571.3A
Other languages
Chinese (zh)
Other versions
CN104805375A (en
Inventor
蒋昌林
李国忠
林涛
胡建国
李经涛
石艾来
方寿玉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangyin Xingcheng Special Steel Works Co Ltd
Original Assignee
Jiangyin Xingcheng Special Steel Works Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangyin Xingcheng Special Steel Works Co Ltd filed Critical Jiangyin Xingcheng Special Steel Works Co Ltd
Priority to CN201510153571.3A priority Critical patent/CN104805375B/en
Publication of CN104805375A publication Critical patent/CN104805375A/en
Application granted granted Critical
Publication of CN104805375B publication Critical patent/CN104805375B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/58Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/08Ferrous alloys, e.g. steel alloys containing nickel
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/16Ferrous alloys, e.g. steel alloys containing copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium

Abstract

The invention discloses ultra thick gauge high tenacity X80 pipeline steel, the chemical composition of this steel plate is C0.02~0.06% by mass percentage, Mn1.6~1.9%, Si0.1~0.35%, S≤0.0006%, P≤0.010%, Nb0.055~0.08%, Ti0.008~0.03%, V≤0.008%, Al≤0.06%, N≤0.010%, O≤0.006%, Mo≤0.15%, Cu≤0.20%, Ni0.2~0.4%, Cr≤0.35%, Ca≤0.01%, balance of Fe and inevitable impurity element;The thickness of described steel plate be 30mm and more than.The manufacturing process flow of steel plate is smelting, continuous casting → heat → roll → cool down, and thoroughly solves ultra thick gauge X80 low temperature block hammer performance requirement technical barrier using special component and specific T MCP technique.

Description

A kind of ultra thick gauge high tenacity X80 pipeline steel and its manufacture method
Technical field
The present invention relates to X80 pipeline steel manufactures field and in particular to a kind of thickness with superior low temperature block hammer performance Degree is not less than X80 pipeline steel and its manufacture method of 30mm.
Background technology
At present in the energy of world demand, fossil energy also accounts for the principal status of public economy in energy resource structure, in recent years World Economics Rapidly increase the rapidly growth greatly having driven fossil energy demand, this has been also greatly facilitate sending out of long distance delivery pipeline Exhibition, for improving transfer efficiency, reduces investment, the development trend of distance petroleum gas delivering pipe line steel be to high intensity or Superelevation grade of steel develops.The pipe line steel highest grade of steel that countries in the world use at present is X80 steel-grade.For improving discharge pressure, X80 steel-grade Develop to think gauge direction, current section of tubing has started to using thickness more than 30mm wall thickness X80 pipe line steel, and from now on can A large amount of employings.
The domestic research to X80 level pipeline steel at present is just many.
As mentioned this in patent No. CN101845596B, the production above X80 of 20-35 mm is applied to using Plate Production mode Pipe line steel, this patent has following features:1)S≤0.05% in composition design, S is harmful element, and actually thickness is less than 20mmX80 pipe line steel S content all controls 0.005% and less, and it is especially special thick that too high S can seriously damage Pipeline Steel Toughness Steel plate block hammer performance requires;Ni≤0.20%, usual Ni content raising exceedes to the toughness especially thickness improving pipe line steel The X80 pipe line steel of 30mm is favourable;2)This patent critical process window in rolling mill practice is very wide, and this is to below 23mm grade of steel Can impact less, but to pipe line steel above with 30mm thickness specification, then performance is difficult to ensure that, especially block hammer performance, practice card Bright, it is difficult to meet thickness specification in more than 30mm block hammer performance requirement using this technique and composition.
As mentioned this application patent in Patent No. CN103225047A, production thickness is applied to using Plate Production mode It is not less than 26.5mm specification X80 pipe line steel, this patent application has following features:1)In steel plate composition, Mo is not less than 0.15%, super In the case of think gauge, increase the sensitivity that Mo can bring the tissues such as a shellfish, this is unfavorable to block hammer performance, also corresponding increasing is closed simultaneously Golden cost;Nb content is 0.025-0.055%, and too low Nb content is in heavy slab roll control Austenite Grain Growth and refinement Effect produced by ferrite crystal grain aspect is less;2)In subsequent rolling mill practice with Patent No. CN101845596B in mention Similar, process window is very wide, it is difficult to ensure that block hammer performance, this is also embodied in my practice.
In fact, thickness specification is a universally acknowledged difficult problem in the block hammer performance of more than 30mm X80 pipe line steel, both domestic and external Research shows, block hammer performance is except, in addition to the factor such as the tissue in steel and ambient temperature, also having close pass with the thickness of steel plate System, and increase with thickness, more sensitive to thickness!This is referred to as thickness effect!For solving the thickness effect under ultra thick gauge, need It is designed from tissue, that is, control and be controlled on organization type and crystal grain thinning.
The present invention is based on above-mentioned design philosophy, in conjunction with current equipment, specific for obtaining specific tissue proposition Composition design, and according to this composition characteristic, formulate specific TMCP technique.
Content of the invention
The X80 pipe line steel more than 30mm for the think gauge X80 pipe line steel particularly thickness needs the low-temperature flexibility meeting harshness to want Ask, particularly not higher than -15 DEG C DWTT of temperature section of shear of dropping hammer requires, and is the technical barrier generally acknowledged in the world.For solving to be somebody's turn to do Technical barrier is the invention provides a kind of produce the X80 pipeline steel that thickness is more than 30mm and its manufacture method, super for obtaining Think gauge and meet low temperature DWTT block hammer performance, in addition to improving composition design, adopts special producing technique in production technology, from And obtain excellent low temperature block hammer performance, meanwhile, technique adjustment is simple, and lumber recovery also can be improved.
The technical scheme that present invention solution above-mentioned technical problem is adopted is that a kind of ultra thick gauge high tenacity X80 pipeline is used Steel plate it is characterised in that:The chemical composition of this steel plate is C by mass percentage:0.02~0.06%, Mn:1.6~1.9%, Si:0.1~0.35%, S:≤ 0.0006%, P:≤ 0.010%, Nb:0.055~0.08%, Ti:0.008~0.03%, V:≤ 0.008%, Al:≤ 0.06%, N:≤ 0.010%, O:≤ 0.006%, Mo:≤ 0.15%, Cu:≤ 0.20%, Ni:0.2~ 0.4%, Cr≤0.35%, Ca:≤ 0.01%, balance of Fe and inevitable impurity element;The thickness of described steel plate is 30mm and more than.
Further, the thickness of described steel plate is 30~35mm;Grain size reach 11 grades and more than;Yield strength is not less than 560Mpa;Tensile strength is not less than 660Mpa;Elongation percentage is not less than 25%;- 25 DEG C of ballistic works are not less than 400J;- 40 DEG C of ballistic works It is not less than 350J;- 60 DEG C of ballistic works are not less than 300J;- 15 DEG C of sections of shear of dropping hammer are not less than 85%;- 20 DEG C of sections of shear of dropping hammer It is not less than 75%.
In the present invention, the composition design thought of ultra thick gauge low-temperature high-toughness X80 pipe line steel steel plate is based on using appropriate C, Mn, by adding the micro alloying elements such as micro Nb, V, Ti, add the elements such as a small amount of Mo, Cu, Ni, then by changing Good TMCP technique, with the final low-temperature high-toughness ensureing ultra thick gauge X80 pipeline steel, especially has excellent DWTT Block hammer performance, the chemical composition of steel plate is related such that:
C:It is most economical, most basic intensified element in steel, steel can be significantly improved by solution strengthening and precipitation strength Intensity, but the toughness to steel and ductility and welding performance bring adverse effect, and the development trend of therefore pipe line steel is continuous fall Low C content, it is contemplated that the matching relationship of intensity and toughness, C content is controlled 0.02~0.06%.
Mn:Improve the intensity of steel by solution strengthening, be to make up because C content reduces in pipe line steel to cause loss of strength Topmost element, Mn still expands the element of γ phase region simultaneously, it is possible to decrease γ → α phase transition temperature of steel, contributes to obtaining carefully Little phase-change product, can improve the toughness of steel, reduce tough brittle transition temperature, and Mn is also the quenching degree element improving steel.This Bright middle Mn content designs in 1.6~1.9% scopes.
Nb:It is one of topmost micro alloying element in modern micro alloyed steel particularly pipe line steel, to crystal grain refinement Effect clearly.By the Nb in the solid solution towing of Nb and course of hot rolling(C,N)Strain induced precipitate can hinder deformation difficult to understand The recovery and recrystallization of family name's body, makes the deformed austeaite that Unhydrated cement rolls be changed in phase transformation through TMCP and tiny mutually sells of one's property Thing, so that steel has high intensity and high tenacity, the present invention mainly determines Nb content range by the relation of C and Nb content.
V:There is higher precipitation strength and weaker Grain Refinement Effect, in tri- kinds of microalloies of Nb, V, Ti under normalizing state When changing elements compounding use, V acts primarily as precipitation strength effect, and the present invention passes through to add certain V, gives full play to V in steel Precipitation strength acts on, but too high V will weaken the toughness of steel, and the therefore present invention controls V≤0.008%.
Ti:It is strong solid N element, the stoichiometric proportion of Ti/N is 3.42, and the Ti using 0.02% about can fix in steel The N of below 60ppm, can form TiN precipitated phase during sheet billet continuous casting, and this tiny precipitated phase can effectively stop slab The growing up of austenite crystal in heating process, is favorably improved solid solubility in austenite for the Nb, can improve sweating heat simultaneously The impact flexibility of the zone of influence, is indispensable element in pipe line steel.
Mo:The formation first separating out ferritic phase during γ → α phase transformation can be postponed, promote the main unit that acicular ferrite is formed Element, to controlling phase transformation to play an important role, is also the quenching degree element improving steel simultaneously, in certain rate of cooling and whole cold temperature The lower certain Mo of interpolation that passes through of degree can obtain obvious acicular ferrite or bainite structure.
S、P:It is that in pipe line steel, inevitable impurity element it is desirable to more low better, processed by super-low sulfur and Ca and changes Oxide morphology can make pipe line steel have very high impact flexibility.
Cu、Ni:The intensity of steel can be improved by solution strengthening, Ni adds the toughness that on the one hand can improve steel, changes simultaneously The red brittleness that kind Cu easily causes in steel.
Cr:The addition of Cr can improve the quenching degree of steel, belong to intensity and improve element, and relatively economical.
The technical scheme that the present invention solves another technical problem is to provide a kind of above-mentioned ultra thick gauge high tenacity X80 pipeline to use The manufacture method of steel plate, concrete technology step is as follows:
First by raw materials for metallurgy successively through KR molten iron pretreatment, converter smelting, LF refine, RH vacuum refining and continuous casting, Produce meet chemical composition require, thickness be 350mm and above continuous casting billet;Continuous casting billet is again heated to 1180~1230 DEG C, insulation 6.5h and above it is ensured that Nb carbonitride solid solution suppresses austenite crystal too to grow up simultaneously;Carry out two ranks after coming out of the stove Section rolling:First stage rolls for recrystallization zone, and finishing temperature control, at 1050~1100 DEG C, controls even during recrystallization zone rolling The single pass reduction ratio of continuous two to three passages is not less than 22%;Second stage is the rolling of non-recrystallization zone, and start rolling temperature controls 820~960 DEG C, non-recrystallization zone adds up reduction ratio and is not less than 55%, ensures finishing temperature control in phase transformation critical temperature simultaneously Ar3 ± 15 DEG C,;Then cooling metal sheets, begin to cool down temperature control and are not higher than 760 DEG C, terminate chilling temperature be controlled to 350~ 500 DEG C, rate of cooling is 10~30 DEG C/s;, steel plate subsequently naturally cools to room temperature.
Key one step in above-mentioned steel plate preparation method is that non-recrystallization zone rolls in addition to requiring Strain Accumulation, is also important to Ask and carry out final pass rolling near phase critical point Ar3, by deformation-induced ferrite transformation so that along steel plate thickness portion Position, the partial austenitic of particularly steel plate center portion is changed into very tiny ferrite, thus each phase composition ratio in optimizing tissue Example, obtains excellent toughness.Because thick steel plates center portion is higher than surface of steel plate temperature, and center portion specific surface cooling when cooling down Slowly, steel plate center portion and surface temperature difference are big, often form granular bainite microstructure thick in a large number in center portion, and this tissue is to dropping hammer Performance is very unfavorable, and therefore core structure optimization is extremely difficult always, how to reduce the granular bayesian of think gauge Pipeline Steel Plate center portion Body burden, raising block hammer performance is one and significantly works.By rolling near strain accumulation+final pass Ar3, profit With strain induced ferrite phase transformation so that particularly center portion very fine ferrite crystal grain in whole thickness direction separates out, thus excellent Change whole thickness direction tissue, obtain excellent ultra thick gauge X80 block hammer performance.
The X80 steel plate of think gauge of the present invention need not follow-up hardening and tempering process, simplify technique, be favorably improved production efficiency.
Compared with prior art, the present invention has following features: 1)By adjusting the alloying component of X80 pipe line steel, make to fit In production more than 30mm spy's think gauge X80 pipe line steel, and match with specific T MCP technique in process for making, produce more than 30mm Special think gauge X80 steel plate, makes steel plate finished product have an excellent low-temperature flexibility, the block hammer performance of particularly -15 DEG C and temperature below; 2)This invention specific T MCP process is simple, lumber recovery is high;3)Super thick is thoroughly solved using special component and specific T MCP technique Specification X80 low temperature block hammer performance requires technical barrier.
Brief description
Fig. 1 is the organization chart of the embodiment of the present invention 1 light plate.
Specific embodiment
Below in conjunction with accompanying drawing, embodiment, the present invention is described in further detail.
Embodiment 1
The thickness of the ultra thick gauge high tenacity X80 pipeline steel of the present embodiment is 30mm, and its chemical composition presses quality hundred Ratio is divided to be calculated as:C:0.02%, Mn:1.9%, Si:0.25%, S:0.0005%, P:0.01%, Nb:0.055%, Ti:0.018%, V: 0.007%, Al:0.030%, Mo+Cu+Ni+Cr≤0.65%, N≤0.010%, O:≤ 0.006%, Ca:≤ 0.01%, surplus For Fe and inevitable impurity element.
The manufacturing process of this X80 pipeline steel is, by above-mentioned steel plate finished product chemical constituent configuration raw materials for metallurgy and according to Secondary through KR molten iron pretreatment, converter smelting, LF refine, RH vacuum refining and continuous casting, produce meet chemical composition require, thick Spend for 370mm about continuous casting billet.Continuous casting billet is again heated to 1180 DEG C, is incubated 7.5 hours;Carry out two benches after coming out of the stove to roll System:First stage rolls for recrystallization zone, and finishing temperature control, at 1050~1100 DEG C, controls continuous two during recrystallization zone rolling Single pass reduction ratio to three passages is not less than 22%, and accumulative deformation rate is 15~55%;Second stage is the rolling of non-recrystallization zone, Start rolling temperature is controlled to 820~960 DEG C, and accumulated deformation rate is 55%, finishing temperature control in phase transformation critical temperature, that is, 760 DEG C; Then cooling metal sheets, begin to cool down temperature control and are not higher than 760 DEG C, and rate of cooling is 19 DEG C/s, and terminating chilling temperature is 500 DEG C, it is finally cooled to room temperature and obtain steel plate finished product.
The X80 pipeline steel of the 30mm thickness being obtained via above-mentioned manufacturing process, grain size has reached more than 11.0 grades, main To be existed with acicular ferrite phase, as shown in figure 1, excellent combination property, its mechanical performance refers to table 1.
Embodiment 2
The thickness of the ultra thick gauge high tenacity X80 pipeline steel of the present embodiment is 35mm, and its chemical composition presses quality hundred Ratio is divided to be calculated as:C:0.06%, Mn:1.65%, Si:0.15%, S:0.0005%, P:0.008%, Nb:0.070%, Ti:0.018%, V: 0.008%, Al:0.028%, Mo+Cu+Ni+Cr≤0.65%, N≤0.010%, O:≤ 0.006%, Ca:≤ 0.01%, surplus For Fe and inevitable impurity element.
The manufacturing process of this X80 pipeline steel is, by above-mentioned steel plate finished product chemical constituent configuration raw materials for metallurgy and according to Secondary through KR molten iron pretreatment, converter smelting, LF refine, RH vacuum refining and continuous casting, produce meet chemical composition require, thick Spend for 370mm about continuous casting billet.Continuous casting billet is again heated to 1200 DEG C, is incubated 7 hours;Carry out two-phase control rolling after coming out of the stove: First stage be recrystallization zone rolling, finishing temperature control at 1050~1100 DEG C, recrystallization zone rolling when control continuous two to The single pass reduction ratio of three passages is not less than 22%, and accumulative deformation rate is 16~50%;Second stage is the rolling of non-recrystallization zone, opens Roll temperature control be 820~960 DEG C, accumulative deformation rate be 60%, finishing temperature control near phase transformation critical temperature Ar3, that is, 755℃;Then cooling metal sheets, begin to cool down temperature control and are not higher than 760 DEG C, and rate of cooling is 10 DEG C/s, terminate cooling temperature Spend for 350 DEG C, be finally cooled to room temperature and obtain final product steel plate finished product.
The X80 pipeline steel of the 35mm thickness being obtained via above-mentioned manufacturing process, grain size has reached more than 11.0 grades, main To be existed with acicular ferrite phase, excellent combination property, its mechanical performance refers to table 1.
Embodiment 3
The thickness of the ultra thick gauge high tenacity X80 pipeline steel of the present embodiment is 33mm, and its chemical composition presses quality hundred Ratio is divided to be calculated as:C:0.04%, Mn:1.75%, Si:0.23%, S:0.0005%, P:0.009%, Nb:0.080%, Ti:0.018%, V: 0.007%, Al:0.030%, Mo+Cu+Ni+Cr≤0.65%, N≤0.010%, O:≤ 0.006%, Ca:≤ 0.01%, surplus For Fe and inevitable impurity element.
The manufacturing process of this X80 pipeline steel is, by above-mentioned steel plate finished product chemical constituent configuration raw materials for metallurgy and according to Secondary through KR molten iron pretreatment, converter smelting, LF refine, RH vacuum refining and continuous casting, produce meet chemical composition require, thick Spend for 350mm about continuous casting billet.Continuous casting billet is again heated to 1183 DEG C, is incubated 7 hours;Carry out two-phase control rolling after coming out of the stove: First stage be recrystallization zone rolling, finishing temperature control at 1050~1100 DEG C, recrystallization zone rolling when control continuous two to The single pass reduction ratio of three passages is not less than 22%, and accumulative deformation rate is 19~40%;Second stage is the rolling of non-recrystallization zone, opens Roll temperature control be 820~960 DEG C, accumulative deformation rate be 62%, finishing temperature control near phase transformation critical temperature Ar3, that is, 775℃;Then cooling metal sheets, begin to cool down temperature control and are not higher than 760 DEG C, and rate of cooling is 15 DEG C/s, terminate cooling temperature Spend for 400 DEG C, be finally cooled to room temperature and obtain final product steel plate finished product.
The X80 pipeline steel of the 33mm thickness being obtained via above-mentioned manufacturing process, grain size has reached more than 11.0 grades, main To be existed with acicular ferrite phase, excellent combination property, its mechanical performance refers to table 1.
Embodiment 4
The thickness of the ultra thick gauge high tenacity X80 pipeline steel of the present embodiment is 35mm, and its chemical composition presses quality hundred Ratio is divided to be calculated as:C:0.05%, Mn:1.73%, Si:0.25%, S:0.0015%, P:0.007%, Nb:0.065%, Ti:0.018%, V: 0.008%, Al:0.035%, Mo+Cu+Ni+Cr≤0.65%, N≤0.010%, O:≤ 0.006%, Ca:≤ 0.01%, surplus For Fe and inevitable impurity element.
The manufacturing process of this X80 pipeline steel is, by above-mentioned steel plate finished product chemical constituent configuration raw materials for metallurgy and according to Secondary through KR molten iron pretreatment, converter smelting, LF refine, RH vacuum refining and continuous casting, produce meet chemical composition require, thick Spend for 350mm about continuous casting billet.Continuous casting billet is again heated to 1210 DEG C, is incubated 8 hours;Carry out two-phase control rolling after coming out of the stove: First stage be recrystallization zone rolling, finishing temperature control at 1050~1100 DEG C, recrystallization zone rolling when control continuous two to The single pass reduction ratio of three passages is not less than 22%, and accumulative deformation rate is 21~57%;Second stage is the rolling of non-recrystallization zone, opens Roll temperature control be 820~960 DEG C, accumulative deformation rate be 68%, finishing temperature control near phase transformation critical temperature Ar3, that is, 770℃;Then cooling metal sheets, begin to cool down temperature control and are not higher than 760 DEG C, and rate of cooling is 13 DEG C/s, terminate cooling temperature Spend for 450 DEG C, be finally cooled to room temperature and obtain final product steel plate finished product.
The X80 pipeline steel of the 35mm thickness being obtained via above-mentioned manufacturing process, grain size has reached more than 11.0 grades, main To be existed with acicular ferrite phase, excellent combination property, its mechanical performance refers to table 1.
The mechanical performance of the steel plate that each embodiment of table 1 is produced

Claims (2)

1. a kind of ultra thick gauge high tenacity X80 pipeline steel it is characterised in that:The chemical composition of this steel plate is by mass percentage It is calculated as C:0.02~0.06%, Mn:1.6~1.9%, Si:0.1~0.35%, S:≤ 0.0006%, P:≤ 0.010%, Nb:0.055 ~0.08%, Ti:0.008~0.03%, V:≤ 0.008%, Al:≤ 0.06%, N:≤ 0.010%, O:≤ 0.006%, Mo:≤ 0.15%, Cu:≤ 0.20%, Ni:0.2~0.4%, Cr≤0.35%, Ca:≤ 0.01%, balance of Fe and inevitably Impurity element;The thickness of described steel plate be 30mm and more than;
The manufacturing technology steps of steel plate are as follows:First by raw materials for metallurgy successively through KR molten iron pretreatment, converter smelting, LF refine, RH vacuum refining and continuous casting, produce and meet that chemical composition requires, thickness is continuous casting billet not less than 350mm;By continuous casting billet again It is heated to 1180~1230 DEG C, insulation is not less than 6.5 hours;Carry out two-phase control rolling after coming out of the stove:First stage is recrystallization zone Rolling, finishing temperature control, at 1050~1100 DEG C, controls the single pass of continuous two to three passages to depress during recrystallization zone rolling Rate is not less than 22%;Second stage is the rolling of non-recrystallization zone, and start rolling temperature controls at 820~960 DEG C, and non-recrystallization zone adds up Reduction ratio is not less than 55%, and finishing temperature control is in phase transformation critical temperature Ar3 ± 15 DEG C;Then cooling metal sheets, begin to cool down temperature It is controlled to not higher than 760 DEG C, terminates chilling temperature and be controlled to 350~500 DEG C, rate of cooling is 10~30 DEG C/s;Subsequently cool down Obtain final product steel plate finished product to room temperature.
2. ultra thick gauge high tenacity X80 pipeline steel according to claim 1 it is characterised in that:The thickness of described steel plate Spend for 30~35mm;Grain size reach 11 grades and more than;Yield strength is not less than 560Mpa;Tensile strength is not less than 660Mpa; Elongation percentage is not less than 25%;- 25 DEG C of ballistic works are not less than 400J;- 40 DEG C of ballistic works are not less than 350J;- 60 DEG C of ballistic works are not less than 300J;- 15 DEG C of sections of shear of dropping hammer are not less than 85%;- 20 DEG C of sections of shear of dropping hammer are not less than 75%.
CN201510153571.3A 2015-04-02 2015-04-02 A kind of ultra thick gauge high tenacity X80 pipeline steel and its manufacture method Active CN104805375B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510153571.3A CN104805375B (en) 2015-04-02 2015-04-02 A kind of ultra thick gauge high tenacity X80 pipeline steel and its manufacture method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510153571.3A CN104805375B (en) 2015-04-02 2015-04-02 A kind of ultra thick gauge high tenacity X80 pipeline steel and its manufacture method

Publications (2)

Publication Number Publication Date
CN104805375A CN104805375A (en) 2015-07-29
CN104805375B true CN104805375B (en) 2017-03-01

Family

ID=53690567

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510153571.3A Active CN104805375B (en) 2015-04-02 2015-04-02 A kind of ultra thick gauge high tenacity X80 pipeline steel and its manufacture method

Country Status (1)

Country Link
CN (1) CN104805375B (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104789863B (en) * 2015-03-20 2017-01-18 宝山钢铁股份有限公司 X80 pipeline steel with good anti-strain aging property, pipeline pipe and manufacturing method of pipeline pipe
CN105950972A (en) * 2016-05-13 2016-09-21 江阴兴澄特种钢铁有限公司 Thick-specification X80 pipeline steel plate with process time being shortened and manufacturing method thereof
CN105803327B (en) * 2016-05-13 2018-02-23 江阴兴澄特种钢铁有限公司 The X90 Pipeline Steel Plates and its manufacture method of a kind of economical hic resistance
CN106222562A (en) * 2016-09-26 2016-12-14 南京钢铁股份有限公司 A kind of manufacture method of heavy wall large-caliber high-steel grade pipe line steel
CN106834932A (en) * 2016-12-05 2017-06-13 马鞍山钢铁股份有限公司 A kind of low-carbon (LC) X80 pipe line steels coiled sheet and its manufacture method
JP6665822B2 (en) * 2017-03-30 2020-03-13 Jfeスチール株式会社 High strength steel sheet for sour resistant line pipe, method for producing the same, and high strength steel pipe using high strength steel sheet for sour resistant line pipe
CN109128065B (en) * 2018-09-25 2020-07-21 湖南华菱湘潭钢铁有限公司 Production method of medium-thickness steel plate for deep sea pipeline
CN109762976A (en) * 2018-12-29 2019-05-17 江阴兴澄特种钢铁有限公司 A kind of efficient pipe line steel production method for obtaining low yield strength ratio performance
CN109680135B (en) * 2019-02-19 2021-02-26 武汉钢铁有限公司 X80 hot-rolled coil with thickness larger than or equal to 22mm for pipeline and production method
CN110331347A (en) * 2019-06-22 2019-10-15 江阴兴澄特种钢铁有限公司 A kind of super 40mm low-temperature high-toughness X80 steel-grade Pipeline Steel Plate of low-carbon-equivalent thickness and its manufacturing method
CN110331343A (en) * 2019-06-22 2019-10-15 江阴兴澄特种钢铁有限公司 A kind of low yield strength ratio X80MO Submarine pipeline steel plate and its manufacturing method
CN111910131B (en) * 2020-06-28 2022-03-22 江阴兴澄特种钢铁有限公司 Steel plate for X100 pipeline for low-temperature deep sea drilling marine riser and manufacturing method thereof
CN112126849B (en) * 2020-08-21 2022-05-31 中国科学院金属研究所 X90 pipeline steel with high strength and toughness and containing rare earth La and Ce elements and rolling method thereof
CN113046630B (en) * 2021-02-07 2022-05-17 首钢集团有限公司 Thick pipeline steel and preparation method thereof
CN113549824A (en) * 2021-06-29 2021-10-26 武汉钢铁有限公司 Hot continuous rolling limit thickness specification high-strength pipeline steel plate coil and manufacturing method thereof
CN114058978B (en) * 2021-11-10 2023-03-31 国家石油天然气管网集团有限公司 X80 pipeline steel with low-temperature toughness

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101397625B (en) * 2007-09-24 2011-04-13 宝山钢铁股份有限公司 Superfine grain steel sheet with yield strength of 420 MPa grade and method for producing the same
CN102172619A (en) * 2010-12-31 2011-09-07 武汉钢铁(集团)公司 Hot rolling process capable of improving high-grade thick pipeline steel fracture toughness
CN103658170B (en) * 2012-09-26 2015-11-18 中国石油天然气集团公司 The milling method of pipe line steel and steel pipe
JP6123713B2 (en) * 2014-03-17 2017-05-10 Jfeスチール株式会社 Thick-walled hot-rolled steel strip and method for producing the same
CN103981462A (en) * 2014-05-30 2014-08-13 秦皇岛首秦金属材料有限公司 Excellent-toughness large-wall-thickness X80 steel for low-temperature stations, and manufacturing method thereof
CN104109744B (en) * 2014-07-28 2016-11-09 攀钢集团西昌钢钒有限公司 The method improving pipeline steel block hammer performance

Also Published As

Publication number Publication date
CN104805375A (en) 2015-07-29

Similar Documents

Publication Publication Date Title
CN104805375B (en) A kind of ultra thick gauge high tenacity X80 pipeline steel and its manufacture method
CN105950973B (en) The excellent think gauge X80 pipeline steels of ultralow temperature block hammer performance and its manufacturing method
CN101613828B (en) Super-thick steel plate for low yield ratio buildings with 460 MPa grade yield strength and manufacturing method
US10378073B2 (en) High-toughness hot-rolling high-strength steel with yield strength of 800 MPa, and preparation method thereof
CN104220619B (en) Thick hot-rolled steel sheet and manufacture method thereof for the rectangular steel tube towards building structural element
CA3058488C (en) A x80 pipeline steel plate with high carbon equivalent and high toughness at low temperatures used for bent pipes as well as a manufacturing method thereof
CN105803327B (en) The X90 Pipeline Steel Plates and its manufacture method of a kind of economical hic resistance
CN104250713B (en) X80-grade large-deformation-resistant pipeline steel plate and manufacturing method thereof
CN103225047B (en) The X80 pipeline steel of thickness >=26.5mm and production method thereof
CN104805374B (en) A kind of thickness Q460E steel plate more than 120mm and manufacture method thereof
CN104789887B (en) A kind of ultra thick gauge hic resistance and anti-SSCCX65 Pipeline Steel Plate and its manufacture method
CN101381854B (en) Method for producing low carbon and high niobium content bainite high-strength steel plate
CN1318631C (en) Method for producing high strength high toughness X80 pipeline steel and its hot-rolled plate
CN104264064A (en) Extra-thick-gauge Q690 high-strength Structural steel plate and preparation method of structural steel plate
JP2021523304A (en) Hot-rolled high-toughness, low-temperature resistant H-shaped steel with 460 MPa grade yield strength and its manufacturing method
CN101994059A (en) Method for producing thin-wall X70 pipeline steel coiled plate with low cost
CN102373387A (en) Steel plate for large-strain cold-bent tube and manufacturing method thereof
CN111996461A (en) X70 pipeline coiled plate for microalloyed resistance welded pipe and production method thereof
CN103276315B (en) 900MPa-level ultrahigh-tenacity high-toughness pipeline steel plate and manufacturing method thereof
CN110331347A (en) A kind of super 40mm low-temperature high-toughness X80 steel-grade Pipeline Steel Plate of low-carbon-equivalent thickness and its manufacturing method
CN102400062A (en) X130 pipe line steel with low yield ratio and ultrahigh strength and manufacturing method of hot rolled flat plate of X130 pipe line steel
CN109957709A (en) One kind X70M Pipeline Steel Plate of large deformation containing V and its manufacturing method
CN105132822A (en) Pipeline steel excellent in CO2 corrosion resistance and production method
CN104073744B (en) The high tenacity X80 pipe line steel coiled sheet of thickness >=18.5mm and production method
CN104451446B (en) Thick-gauge, high-strength and high-toughness bainite engineering steel and production method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
EXSB Decision made by sipo to initiate substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant