CN104805318A - Preparation method of spherical TC4 particle reinforced AZ91 magnesium matrix composite - Google Patents
Preparation method of spherical TC4 particle reinforced AZ91 magnesium matrix composite Download PDFInfo
- Publication number
- CN104805318A CN104805318A CN201510178251.3A CN201510178251A CN104805318A CN 104805318 A CN104805318 A CN 104805318A CN 201510178251 A CN201510178251 A CN 201510178251A CN 104805318 A CN104805318 A CN 104805318A
- Authority
- CN
- China
- Prior art keywords
- spherical
- matrix composite
- preparation
- magnesium matrix
- particulate reinforced
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002245 particle Substances 0.000 title claims abstract description 58
- 239000002131 composite material Substances 0.000 title claims abstract description 46
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 239000011777 magnesium Substances 0.000 title claims abstract description 36
- 229910052749 magnesium Inorganic materials 0.000 title claims abstract description 36
- 239000011159 matrix material Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 23
- 238000003756 stirring Methods 0.000 claims abstract description 22
- 238000001816 cooling Methods 0.000 claims abstract description 15
- 239000007787 solid Substances 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims description 16
- 238000004062 sedimentation Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 238000000048 melt cooling Methods 0.000 claims 1
- 238000002525 ultrasonication Methods 0.000 claims 1
- 238000009210 therapy by ultrasound Methods 0.000 abstract description 12
- 239000000155 melt Substances 0.000 description 7
- 229910001069 Ti alloy Inorganic materials 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 230000005484 gravity Effects 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000012669 compression test Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910019018 Mg 2 Si Inorganic materials 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Manufacture Of Alloys Or Alloy Compounds (AREA)
- Powder Metallurgy (AREA)
Abstract
Description
技术领域technical field
本发明涉及球形TC4颗粒与AZ91基体界面反应的控制，使二者间有良好的界面结合，从而获得良好综合性能的复合材料。The invention relates to the control of the interface reaction between the spherical TC4 particles and the AZ91 matrix, so that the two can have a good interface combination, thereby obtaining a composite material with good comprehensive performance.
背景技术Background technique
目前普遍采用陶瓷颗粒作为镁基复合材料的增强体，如SiC、B4C、TiC、TiC、Al2O3、Y2O3、TiO2、Mg2Si等，但是由于SiC等陶瓷相与基体之间的润湿性不好导致材料的性能不好。而钛和镁之间的润湿性特别好，且物理化学性质相似，因此本发明采用Ti颗粒作为复合材料的增强体，有望可以得到强度高和塑韧性好的镁基复合材料。At present, ceramic particles are generally used as reinforcements of magnesium-based composites, such as SiC, B 4 C, TiC, TiC, Al 2 O 3 , Y 2 O 3 , TiO 2 , Mg 2 Si, etc. Poor wetting between the substrates leads to poor performance of the material. The wettability between titanium and magnesium is particularly good, and the physical and chemical properties are similar, so the present invention uses Ti particles as the reinforcement of the composite material, and it is expected to obtain a magnesium-based composite material with high strength and good plasticity and toughness.
发明内容Contents of the invention
本发明的目的是为了提供一种制备TC4/镁基复合材料的新方法：将TC4颗粒加入到AZ91熔体中，使颗粒在重力下子沉降，控制沉降的时间，随后用水冷系统将熔体快速冷却，从而得到高体积分数且颗粒呈梯度分布的镁基复合材料。The purpose of the present invention is to provide a new method for preparing TC4/magnesium-based composite materials: TC4 particles are added to the AZ91 melt, the particles are subsidence under gravity, and the time of sedimentation is controlled, and then the melt is quickly cooled by water cooling system Cooling, so as to obtain a magnesium-based composite material with a high volume fraction and a gradient distribution of particles.
本发明用自沉降的方法使颗粒在重力的作用下沉降，随后迅速水冷凝固，从而得到颗粒呈梯度分布的铸态复合材料，使材料能够更加适用于人们的需求。The invention uses a self-sedimentation method to make the particles settle under the action of gravity, and then rapidly water-cools and solidifies, thereby obtaining the as-cast composite material with the particles distributed in a gradient, so that the material can be more suitable for people's needs.
本发明的一种球形TC4颗粒增强AZ91镁基复合材料的制备方法，它包括以下步骤：A kind of spherical TC4 particle of the present invention strengthens the preparation method of AZ91 magnesium-based composite material, it comprises the following steps:
一、TC4颗粒预热：将TC4颗粒在50～100℃下预热30～60min；1. Preheating of TC4 particles: Preheat TC4 particles at 50-100°C for 30-60 minutes;
二、半固态搅拌：首先将AZ91加热至560～620℃，使AZ91熔化至半固态状态，然后将步骤一预热的TC4颗粒以120g/min的速度加入到AZ91半固态熔体中，边加边搅拌，加完后再继续搅拌20～30min，得混合体；2. Semi-solid stirring: first heat AZ91 to 560-620°C to melt AZ91 to a semi-solid state, then add the TC4 particles preheated in step 1 into the AZ91 semi-solid melt at a speed of 120g/min, adding While stirring, continue to stir for 20-30 minutes after adding to obtain a mixture;
三、超声处理：将步骤二得到的混合体进行超声处理，超声波频率为20kHz，超声时间为20～30min；3. Ultrasonic treatment: Ultrasonic treatment is performed on the mixture obtained in step 2, the ultrasonic frequency is 20kHz, and the ultrasonic time is 20-30min;
四、自沉降：将步骤三超声处理后的混合物自然静置20～30min，使球形TC4颗粒沉降；4. Self-sedimentation: Let the mixture after the ultrasonic treatment in step 3 stand naturally for 20-30 minutes to make the spherical TC4 particles settle;
五、冷却：将步骤四中沉降处理的熔体冷却，获得铸态的复合材料，即完成所述的球形TC4颗粒增强AZ91镁基复合材料。5. Cooling: cooling the melt treated in step 4 to obtain the as-cast composite material, that is, to complete the spherical TC4 particle-reinforced AZ91 magnesium-based composite material.
本发明包含以下优点：The present invention comprises the following advantages:
本发明采用自沉降法制备了钛合金颗粒增强镁基复合材料，将镁合金先升温后降温形成半固态，然后将事先预热好的钛合金颗粒倒入到半固态熔体中同时进行半固态搅拌，搅拌预定时间后把混合熔体升温至液态，随后进行超声波处理，并将熔体在水冷系统中冷却得到铸态复合材料。The invention adopts the self-sedimentation method to prepare the titanium alloy particle reinforced magnesium-based composite material. The magnesium alloy is first heated up and then cooled to form a semi-solid state, and then the preheated titanium alloy particles are poured into the semi-solid melt at the same time to carry out the semi-solid state. Stirring, after stirring for a predetermined time, the temperature of the mixed melt is raised to a liquid state, followed by ultrasonic treatment, and the melt is cooled in a water cooling system to obtain an as-cast composite material.
(1)本发明在制备过程中要对钛合金颗粒进行加热烘干，且预热温度为100℃～200℃，预热时间为20min～50min，这样既可以减少吸附在颗粒表面的气体量，提高颗粒与合金基体之间的润湿性，有利于颗粒的分散，又不至于使钛合金颗粒氧化严重，如果预热温度过高，就会使颗粒表面形成致密的TiO2层，这种陶瓷相就间隔了钛合金颗粒和基体之间的结合，会导致颗粒与基体之间界面结合较差；(1) In the preparation process of the present invention, titanium alloy particles should be heated and dried, and the preheating temperature is 100°C to 200°C, and the preheating time is 20min to 50min, so that the amount of gas adsorbed on the particle surface can be reduced, Improve the wettability between the particles and the alloy matrix, which is conducive to the dispersion of the particles, and will not cause serious oxidation of the titanium alloy particles. If the preheating temperature is too high, a dense TiO2 layer will be formed on the surface of the particles. This ceramic The phase space between the titanium alloy particles and the matrix will lead to poor interfacial bonding between the particles and the matrix;
(2)本发明采用液态方法制备复合材料，这是因为钛颗粒和镁基体的润湿性很好，相比于用粉末冶金的方法，这种方法到的复合材料颗粒与基体间的界面结合较好。(2) The present invention adopts liquid method to prepare composite material, and this is because the wettability of titanium particle and magnesium matrix is very good, compared with the method with powder metallurgy, the interface between the composite material particle that this method arrives and matrix is combined better.
(3)本发明可以通过自沉降的方法使颗粒在重力的作用下沉降，并获得在高度方向上颗粒呈梯度分布的梯度复合材料。(3) The present invention can make the particles settle under the action of gravity through the self-sedimentation method, and obtain the gradient composite material in which the particles are distributed in a gradient in the height direction.
(4)本发明可以制备较高体积分数的复合材料。(4) The present invention can prepare composite materials with higher volume fraction.
附图说明Description of drawings
图1是本发明得到的TC4颗粒增强AZ91镁基复合材料的光学显微镜照片(OM)照片；Fig. 1 is the optical microscope photo (OM) photo of the TC4 particle that the present invention obtains strengthens the AZ91 magnesium-based composite material;
图2是本发明制备的TC4颗粒增强AZ91镁基复合材料的扫描电子显微镜的照片(SEM)照片；Fig. 2 is the photo (SEM) photo of the scanning electron microscope of the TC4 particle reinforced AZ91 magnesium-based composite material prepared by the present invention;
图3是本发明制备的TC4颗粒增强AZ91镁基复合材料的拉伸试样的断口扫描(SEM)照片；Fig. 3 is the fracture scanning (SEM) photograph of the tensile sample of TC4 particle reinforced AZ91 magnesium-based composite material prepared by the present invention;
图4是本发明制备的TC4颗粒增强AZ91镁基复合材料和AZ91合金的压缩试验曲线。Fig. 4 is the compression test curve of the TC4 particle reinforced AZ91 magnesium-based composite material and AZ91 alloy prepared by the present invention.
具体实施方式Detailed ways
具体实施方式一：本实施方式的一种球形TC4颗粒增强AZ91镁基复合材料的制备方法，它包括以下步骤：Specific embodiment one: the preparation method of a kind of spherical TC4 particle reinforced AZ91 magnesium-based composite material of the present embodiment, it comprises the following steps:
一、TC4颗粒预热：将TC4颗粒在50～100℃下预热30～60min；1. Preheating of TC4 particles: Preheat TC4 particles at 50-100°C for 30-60 minutes;
二、半固态搅拌：首先将AZ91加热至560～620℃，使AZ91熔化至半固态状态，然后将步骤一预热的TC4颗粒以120g/min的速度加入到AZ91半固态熔体中，边加边搅拌，加完后再继续搅拌20～30min，得混合体；2. Semi-solid stirring: first heat AZ91 to 560-620°C to melt AZ91 to a semi-solid state, then add the TC4 particles preheated in step 1 into the AZ91 semi-solid melt at a speed of 120g/min, adding While stirring, continue to stir for 20-30 minutes after adding to obtain a mixture;
三、超声处理：将步骤二得到的混合体进行超声处理，超声波频率为20kHz，超声时间为20～30min；3. Ultrasonic treatment: Ultrasonic treatment is performed on the mixture obtained in step 2, the ultrasonic frequency is 20kHz, and the ultrasonic time is 20-30min;
四、自沉降：将步骤三超声处理后的混合物自然静置20～30min，使球形TC4颗粒沉降；4. Self-sedimentation: Let the mixture after the ultrasonic treatment in step 3 stand naturally for 20-30 minutes to make the spherical TC4 particles settle;
五、冷却：将步骤四中沉降处理的熔体冷却，获得铸态的复合材料，即完成所述的球形TC4颗粒增强AZ91镁基复合材料。5. Cooling: cooling the melt treated in step 4 to obtain the as-cast composite material, that is, to complete the spherical TC4 particle-reinforced AZ91 magnesium-based composite material.
具体实施方式二：本实施方式与具体实施方式一不同的是：步骤一中所述的颗粒预热温度为60℃～100℃。其它与具体实施方式一相同。Embodiment 2: The difference between this embodiment and Embodiment 1 is that the particle preheating temperature in step 1 is 60°C-100°C. Others are the same as in the first embodiment.
具体实施方式三：本实施方式与具体实施方式一不同的是：步骤一中所述的颗粒预热温度为70℃～100℃。其它与具体实施方式一相同。Embodiment 3: The difference between this embodiment and Embodiment 1 is that the particle preheating temperature in step 1 is 70°C to 100°C. Others are the same as in the first embodiment.
具体实施方式四：本实施方式与具体实施方式一不同的是：步骤一中所述的颗粒预热温度为80℃～100℃。其它与具体实施方式一相同。Embodiment 4: The difference between this embodiment and Embodiment 1 is that the particle preheating temperature in Step 1 is 80°C-100°C. Others are the same as in the first embodiment.
具体实施方式五：本实施方式与具体实施方式一不同的是：步骤一中所述的颗粒预热温度为90℃～100℃。其它与具体实施方式一相同。Embodiment 5: This embodiment is different from Embodiment 1 in that: the particle preheating temperature in step 1 is 90°C-100°C. Others are the same as in the first embodiment.
具体实施方式六：本实施方式与具体实施方式一不同的是：步骤二中将AZ91加热至570～610℃。其它与具体实施方式一相同。Embodiment 6: This embodiment is different from Embodiment 1 in that: in step 2, AZ91 is heated to 570-610°C. Others are the same as in the first embodiment.
具体实施方式七：本实施方式与具体实施方式一不同的是：步骤二中将AZ91加热至580～600℃。其它与具体实施方式一相同。Embodiment 7: This embodiment is different from Embodiment 1 in that: in step 2, AZ91 is heated to 580-600°C. Others are the same as in the first embodiment.
具体实施方式八：本实施方式与具体实施方式一不同的是：步骤二中将AZ91加热至590～600℃。其它与具体实施方式一相同。Embodiment 8: This embodiment is different from Embodiment 1 in that: in step 2, AZ91 is heated to 590-600°C. Others are the same as in the first embodiment.
具体实施方式九：本实施方式与具体实施方式一不同的是：步骤二中所述的搅拌过程用十字型搅拌桨，搅拌速度为1000r/min。其它与具体实施方式一相同。Embodiment 9: This embodiment is different from Embodiment 1 in that: the stirring process described in step 2 uses a cross-shaped stirring paddle, and the stirring speed is 1000 r/min. Others are the same as in the first embodiment.
具体实施方式十：本实施方式与具体实施方式一不同的是：步骤三中混合体进行超声处理前，先将步骤二中的混合体升温到690℃，然后再进行超声波处理。其它与具体实施方式一相同。Embodiment 10: This embodiment is different from Embodiment 1 in that: before the mixture in step 3 is subjected to ultrasonic treatment, the temperature of the mixture in step 2 is first raised to 690° C., and then the mixture is subjected to ultrasonic treatment. Others are the same as in the first embodiment.
具体实施方式十一：本实施方式与具体实施方式一不同的是：步骤三中所述的超声处理的超声波频率为20kHz，超声时间为20min。其它与具体实施方式一相同。Embodiment 11: This embodiment is different from Embodiment 1 in that: the ultrasonic frequency of the ultrasonic treatment described in Step 3 is 20 kHz, and the ultrasonic time is 20 min. Others are the same as in the first embodiment.
具体实施方式十二：本实施方式与具体实施方式一不同的是：步骤四中所述的自沉降过程的温度为690℃，沉降时间为20min。其它与具体实施方式一相同。Embodiment 12: This embodiment is different from Embodiment 1 in that: the temperature of the self-settling process described in step 4 is 690° C., and the settling time is 20 minutes. Others are the same as in the first embodiment.
具体实施方式十三：本实施方式与具体实施方式一不同的是：步骤五中将混合物冷却过程利用的是循环水冷系统进行的。其它与具体实施方式一相同。Specific Embodiment Thirteen: The difference between this embodiment and specific embodiment 1 is that the process of cooling the mixture in step 5 is carried out by a circulating water cooling system. Others are the same as in the first embodiment.
下面结合本发明的内容提供以下实施例：Provide following embodiment below in conjunction with content of the present invention:
实施例1：Example 1:
取624g直径为109μm-150μm的TC4球形颗粒放到一个瓷质的杯子里，置杯子与100℃的电阻加热炉中保持30min；Take 624g of TC4 spherical particles with a diameter of 109μm-150μm into a porcelain cup, and place the cup in a resistance heating furnace at 100°C for 30min;
与此同时把质量为1000g的AZ91合金在720℃熔化并逐步降温到580℃(半固态)；随后将搅拌桨伸到熔体液面下适当位置，启动搅拌桨，将预热好的颗粒取出缓慢加入到熔体中，这个过程要调整转速使颗粒能够顺利的进入到熔体中，待颗粒加完后匀速搅拌(1000r/min)，搅拌20min，然后把温度升高到690℃，停止搅拌；随后卸下搅拌桨，开始超声处理，预设超声波频率为20kHz，输出功率为700W，此过程进行20min；随后将熔体在重力场中静置20min，最后迅速将承装熔体的坩埚放到水冷系统中冷却，该水冷系统利用的是循环水冷却，只需一分钟即可得到铸态的TC4颗粒增强AZ91镁基复合材料。将复合材料放在扫描电镜和光学纤维镜下观察。At the same time, melt the AZ91 alloy with a mass of 1000g at 720°C and gradually cool it down to 580°C (semi-solid); then extend the stirring paddle to an appropriate position under the melt surface, start the stirring paddle, and take out the preheated particles Slowly add to the melt. During this process, the speed should be adjusted so that the particles can enter the melt smoothly. After the particles are added, stir at a constant speed (1000r/min) for 20 minutes, then raise the temperature to 690°C and stop stirring. Then remove the stirring paddle and start ultrasonic treatment. The preset ultrasonic frequency is 20kHz and the output power is 700W. To cool in the water cooling system, the water cooling system uses circulating water cooling, and it only takes one minute to get the cast TC4 particle reinforced AZ91 magnesium matrix composite material. The composite was observed under a scanning electron microscope and a fiber optic microscope.
本实施例得到的TC4颗粒增强AZ91镁基复合材料的光学显微镜照片(OM)照片如图1所示；TC4颗粒增强AZ91镁基复合材料的扫描电子显微镜的照片(SEM)照片如图2所示；TC4颗粒增强AZ91镁基复合材料的拉伸试样的断口扫描(SEM)照片如图2所示；TC4颗粒增强AZ91镁基复合材料和AZ91合金的压缩试验曲线如图4所示。The photomicrograph (OM) of the TC4 particle reinforced AZ91 magnesium-based composite material obtained in this embodiment is shown in Figure 1; the photo of the scanning electron microscope (SEM) photo of the TC4 particle reinforced AZ91 magnesium-based composite material is shown in Figure 2 ; TC4 particle reinforced AZ91 magnesium matrix composite tensile specimen fracture scanning (SEM) photos shown in Figure 2; TC4 particle reinforced AZ91 magnesium matrix composite and AZ91 alloy compression test curves are shown in Figure 4.
由上述可知，本实施例的方法能够制备出较高体积分数的复合材料。It can be known from the above that the method of this embodiment can prepare composite materials with a relatively high volume fraction.
Claims (10)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510178251.3A CN104805318B (en) | 2015-04-15 | 2015-04-15 | Preparation method of spherical TC4 particle reinforced AZ91 magnesium matrix composite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510178251.3A CN104805318B (en) | 2015-04-15 | 2015-04-15 | Preparation method of spherical TC4 particle reinforced AZ91 magnesium matrix composite |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104805318A true CN104805318A (en) | 2015-07-29 |
| CN104805318B CN104805318B (en) | 2017-02-22 |
Family
ID=53690512
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510178251.3A Active CN104805318B (en) | 2015-04-15 | 2015-04-15 | Preparation method of spherical TC4 particle reinforced AZ91 magnesium matrix composite |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104805318B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108179412A (en) * | 2018-01-25 | 2018-06-19 | 成都青石激光科技有限公司 | The method for preparing spheric granules composite material |
| CN108677053A (en) * | 2018-06-22 | 2018-10-19 | 太原理工大学 | A kind of preparation method for handing over frequency ultrasonic coupling hot pressing infiltration porous ceramics enhancing magnesium-based composite material |
| CN109022859A (en) * | 2018-09-17 | 2018-12-18 | 太原理工大学 | A kind of preparation method of nano-titanium particulate reinforcement magnesium-based composite material |
| CN112342445A (en) * | 2020-09-10 | 2021-02-09 | 上海航天精密机械研究所 | High-strength plastic magnesium-based composite material and preparation method thereof |
| CN113046592A (en) * | 2021-03-16 | 2021-06-29 | 南昌航空大学 | In-situ synthesis device and method for aluminum-based composite material with enhanced particle gradient distribution |
| CN113373359A (en) * | 2021-06-23 | 2021-09-10 | 贵州大学 | Layered gradient structure particle reinforced magnesium matrix composite material and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000001639A1 (en) * | 1998-07-01 | 2000-01-13 | Foseco International Limited | Refractory compositions |
| CN1676645A (en) * | 2005-04-14 | 2005-10-05 | 北京科技大学 | Nanoparticle-reinforced high-strength and toughness cast magnesium alloy and its preparation and forming process |
| CN102943198A (en) * | 2012-12-05 | 2013-02-27 | 哈尔滨工业大学 | Preparation method of double-size silicon carbide particle hybrid reinforced magnesium matrix composite material |
| CN103789590A (en) * | 2014-03-04 | 2014-05-14 | 哈尔滨工业大学 | Preparation method of particle-reinforced magnesium-based composite material |
-
2015
- 2015-04-15 CN CN201510178251.3A patent/CN104805318B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000001639A1 (en) * | 1998-07-01 | 2000-01-13 | Foseco International Limited | Refractory compositions |
| CN1676645A (en) * | 2005-04-14 | 2005-10-05 | 北京科技大学 | Nanoparticle-reinforced high-strength and toughness cast magnesium alloy and its preparation and forming process |
| CN102943198A (en) * | 2012-12-05 | 2013-02-27 | 哈尔滨工业大学 | Preparation method of double-size silicon carbide particle hybrid reinforced magnesium matrix composite material |
| CN103789590A (en) * | 2014-03-04 | 2014-05-14 | 哈尔滨工业大学 | Preparation method of particle-reinforced magnesium-based composite material |
Non-Patent Citations (1)
| Title |
|---|
| 郗雨林 等: "钛合金颗粒增强镁基复合材料的制备与性能", 《稀有技术材料与工程》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108179412A (en) * | 2018-01-25 | 2018-06-19 | 成都青石激光科技有限公司 | The method for preparing spheric granules composite material |
| CN108677053A (en) * | 2018-06-22 | 2018-10-19 | 太原理工大学 | A kind of preparation method for handing over frequency ultrasonic coupling hot pressing infiltration porous ceramics enhancing magnesium-based composite material |
| CN109022859A (en) * | 2018-09-17 | 2018-12-18 | 太原理工大学 | A kind of preparation method of nano-titanium particulate reinforcement magnesium-based composite material |
| CN112342445A (en) * | 2020-09-10 | 2021-02-09 | 上海航天精密机械研究所 | High-strength plastic magnesium-based composite material and preparation method thereof |
| CN113046592A (en) * | 2021-03-16 | 2021-06-29 | 南昌航空大学 | In-situ synthesis device and method for aluminum-based composite material with enhanced particle gradient distribution |
| CN113046592B (en) * | 2021-03-16 | 2024-07-02 | 南昌航空大学 | In-situ synthesis device and method for aluminum-based composite material with reinforced particle gradient distribution |
| CN113373359A (en) * | 2021-06-23 | 2021-09-10 | 贵州大学 | Layered gradient structure particle reinforced magnesium matrix composite material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104805318B (en) | 2017-02-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104805318B (en) | Preparation method of spherical TC4 particle reinforced AZ91 magnesium matrix composite | |
| CN104789804B (en) | A kind of titanium alloy particle strengthens the preparation method of magnesium-based composite material | |
| CN104388764B (en) | Aluminum matrix composite that a kind of high-entropy alloy strengthens and preparation method thereof | |
| CN103789590B (en) | The preparation method of particle reinforced magnesium base compound material | |
| CN104928531B (en) | A kind of homogenization TiAl alloy lamellar microstructure and preparation method thereof | |
| CN109554572B (en) | Multi-scale ceramic particle-mixed high-elasticity-modulus high-strength aluminum alloy and preparation method thereof | |
| CN105861904B (en) | A kind of B4The preparation method of C/Al composites | |
| CN103194630A (en) | Preparation method of SiCp/Al composite material with high volume fraction | |
| CN109609814B (en) | High-strength aluminum alloy with high elastic modulus mixed with double-scale ceramic particles and preparation method thereof | |
| CN109022859A (en) | A kind of preparation method of nano-titanium particulate reinforcement magnesium-based composite material | |
| WO2023231419A1 (en) | Titanium particle reinforced magnesium-based composite material and preparation method therefor | |
| CN102943198B (en) | Preparation method of double-size silicon carbide particle hybrid reinforced magnesium matrix composite material | |
| CN104532032B (en) | A method for preparing semi-solid slurry of nano-alumina reinforced aluminum matrix composites based on composite vibration technology | |
| CN102864361B (en) | SiC enhanced aluminum-based composite material for spacecraft and preparation method thereof | |
| Birsen et al. | Microstructure and wear characteristics of hybrid reinforced (ex-situ SiC–in-situ Mg2Si) Al matrix composites produced by vacuum infiltration method | |
| CN1995418A (en) | Preparation method of granule-mixed reinforced aluminium-based composite material | |
| CN104073675B (en) | The preprocess method of silicon-carbide particle for a kind of aluminum matrix composite | |
| CN110453113B (en) | A kind of method of cesium oxide modified graphene reinforced aluminum alloy composite material | |
| KR101326498B1 (en) | Method for manufacturing nano-particle reinforced metal matrix composites and the metal matrix composite | |
| CN102925723B (en) | Method for preparing particle-reinforced aluminum matrix composites | |
| CN104532033B (en) | A kind of preparation method of nano aluminium oxide reinforced aluminum matrix composites semi solid slurry | |
| CN102080197A (en) | Method for coating surface of reinforcement in composite material | |
| CN106544549A (en) | A kind of preparation method of the double yardstick TiC particle enhanced aluminum-based composite materials of micro-nano | |
| CN104532030A (en) | Method for preparing nano-aluminum-nitride particle reinforced aluminum-based composite semi-solid slurry based on ultrasonic treatment | |
| CN115490538B (en) | Preparation method of alumina/glass composite material and application of alumina/glass composite material in repairing internal cracks of alumina ceramic |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |