CN104802252A - Wood enhancement and corrosion prevention modification liquid and preparation method thereof - Google Patents
Wood enhancement and corrosion prevention modification liquid and preparation method thereof Download PDFInfo
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- CN104802252A CN104802252A CN201510216380.7A CN201510216380A CN104802252A CN 104802252 A CN104802252 A CN 104802252A CN 201510216380 A CN201510216380 A CN 201510216380A CN 104802252 A CN104802252 A CN 104802252A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/50—Mixtures of different organic impregnating agents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/20—Removing fungi, molds or insects
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/30—Fireproofing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/70—Hydrophobation treatment
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- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The invention relates to the technical field of wood modification, in particular to a wood enhancement and corrosion prevention modification liquid and a preparation method thereof. The wood enhancement and corrosion prevention modification liquid comprises the following raw materials in parts by weight: 10-30 parts of melamine modified urea resin, 4-8 parts of dextrin, 1-5 parts of a nano modifier, 0.5-1.5 parts of a preservative, 1-5 parts of auxiliaries and 60-100 parts of water. According to the wood enhancement and corrosion prevention modification liquid, the intensity and the corrosion resistance of woods can be improved; furthermore, the insect bite, mildewing, water, flame, deformation and cracking prevention performance of the modified woods are greatly improved; the density, the hardness, the anti-bending intensity and the elastic modulus are higher, so that the use performance of the woods can be improved, and the service life of the woods is prolonged. The wood enhancement and corrosion prevention modification liquid has natural properties of heat insulation, temperature adjustment, humidity adjustment and the like, is colorful and bright and is high in physical stripe third dimension; a plate looks transparent and natural.
Description
Technical field
The present invention relates to Wood Property Improvement field, be specifically related to a kind of timber and strengthen anticorrosion modification liquid and preparation method thereof.
Background technology
Along with the development of national economic development and the raising of living standards of the people, the demand of people to timber is increasing.And the enforcement of wildwood protected project, make timber supply and demand contradiction more outstanding.For alleviating imbalance between supply and demand, China has built large-area Industrial Plantation.Although artificial forest wood has the advantages such as fast growing, the physical and mechanical property of artificial fast-growing woods timber is poor, and density is low, and material is soft, easily produces dry-shrinkage deformed.
In order to expand the range of application of artificial forest wood, improve the economic worth of artificial forest wood, people carry out modification by various method to artificial fast-growing woods timber.What current research was more is adopt thermosetting resin to carry out impregnation process to timber, and thermoset synthetic resin after hardening resistance to water is strong, do not run off, and intensity is high, is heated and does not soften, be applicable to impregnated timber.Synthetic resin for impregnated timber must have the low feature of viscosity, otherwise fully cannot flood timber.The height of the degree of polymerization is the principal element of decision tree impregnate with tallow treatment effect quality, so should adopt the initial stage resin of low polymerization degree.Existing many dissimilar resins can successfully be polymerized, as phenolic resins (PF), Lauxite (UF), melamino-formaldehyde (MF) and isocyanates etc. at wood internal at present.Concrete impregnation process mode be by timber pickling in the resin solution of water-soluble low molecular weight, resin to diffuse in wood cell and makes timber increase-volume, drying removing moisture, resin solidifies due to heating, generate water-fast polymer, deposition is filled in cell, or occurs crosslinked with wood components, thus make that density of wood increases, hardness and intensity improves, dimensional stability improvement.
Along with the enhancing of people's environmental consciousness, Wooden modifying expert invests the heat treatment wood of comparatively environmental protection sight, is mainly carbonized wood, utilizes high temperature (about 200 DEG C) to process timber, improve wood dimensional stability, wherein more typically have following four kinds of Technologies for Heating Processing:
1, the Thermwood technique of Finland
Thermwood process divides 3 stages to carry out: the first stage, and adopt heat and steam that timber in dry kiln is heated up, and at high temperature drying makes the humidity of timber reduce to zero, the temperature of dry kiln is rapidly heated to about 100 DEG C, is steadily warming up to 130 DEG C afterwards; Second stage is the high-temperature thermal treatment timber stage, and the temperature namely in dry kiln raises and remains 185 DEG C ~ 230 DEG C, after reaching target temperature, keeps heat treatment 2h ~ 3h at such a temperature; Phase III is cooling and conditioning stage, lowers the temperature by timber water injection system after heat treatment; When temperature is reduced to 80 DEG C ~ 90 DEG C, readjusts humidity and make moisture content reach 4% ~ 7%.It is pine, China fir, poplar and birch that Thermwood technique mainly processes seeds.Timber after heat treatment is mainly used in outdoor, such as: deck, fence, garden furniture, door, window etc.Indoor as kitchen furniture, main hall and panel etc.
2, the Plato Wood technique of Holland
Plato Wood technique not only can process greenwood but also can process air-dired wood, this technique divides four steps to carry out: the first step, hydrothermal treatment consists (hydrothermolysis): under condition of normal pressure, is placed in the wet environment that temperature is 160 DEG C ~ 190 DEG C by timber, process 4h ~ 5h; Second step, the drying of wood: with 3 days ~ 5 day time, with conventional drying processes by the drying of wood to moisture content lower than 10%; 3rd step, heat treatment: timber is heated to 170 DEG C ~ 190 DEG C, the processing time is 14h ~ 16h; 4th step, normally improves wood equilibrium moisture content, and what make it with atmospheric environment is suitable.This processing method by Arnhem (Holland) factory application in commercially producing, yearly productive capacity reaches 35000m3.
3, the state-owned two kinds of production technologies of method: Rectification technique and Boisperdure technique
Rectification technique processes timber in the nitrogen of 200 DEG C ~ 240 DEG C, and the moisture content of process material is 12%; And Boisperdure technique is rapid draing greenwood in the steam of 200 DEG C ~ 240 DEG C.
4, the OHT treatment process of Germany
OHT treatment process adopts oil as heat-treatment medium, at high temperature processes timber.First timber is put into a closed container being full of deep fat and process 18h ~ 24h.Oil has good heat conduction and anoxybiotic ability.But unfavorable conditions is, immersion wood internal makes wood weight increase by 50% ~ 70% by oil, and heat-treated wood has greasy smell.
Above-mentioned four kinds of heat treatment process are numerous and diverse, process conditions are harsh, control difficulty, the stability of product quality is difficult to ensure, some treatment process also need special heat-treatment medium, such as: the Rectification technique of France needs nitrogen, the OHT treatment process of Germany needs oil as heat-treatment medium.
Although timber is through the modified stability that can improve its size of heat treatment, equilibrium moisture content in timber declines, corrosion resistant performance also increases to some extent, and bonding capacity improves, and wood color deepens, improve the timber outward appearance that outward appearance is poor, but the physical and mechanical property of timber after heat treatment declines, strength of wood value declines comparatively large, as: bending strength reduces, degradation under surface wettability, and existing improved wood is anticorrosion poor, limits the range of application of carbonized wood to a great extent.
Summary of the invention
In order to overcome the shortcoming and defect existed in prior art, a kind of timber is the object of the present invention is to provide to strengthen anticorrosion modification liquid, this modification liquid can improve intensity and the antiseptic property of timber, and modified wood preservation from decay moth, anti-mildew, waterproof, fire-retardant, anti-deformation and crack resistence performance are improved significantly; Its density, hardness, bending strength and elastic modelling quantity are all better, can promote the serviceability of timber and the service life of prolonging wood; Also have the natural qualities such as partiting thermal insulation, temperature adjustment and damping, bright in colour, bright, physics striped third dimension is strong, the penetrating nature of sheet material color.
Another object of the present invention is to provide a kind of timber to strengthen the preparation method of anticorrosion modification liquid, this preparation method's technique is simple, and convenient operation and control, steady quality, production efficiency is high, can large-scale industrial production.
Object of the present invention is achieved through the following technical solutions: a kind of timber strengthens anticorrosion modification liquid, comprises the raw material of following weight portion:
Cyanurotriamide modified urea resin 10-30 part
Dextrin 4-8 part
Nano modifier 1-5 part
Anticorrisive agent 0.5-1.5 part
Auxiliary agent 1-5 part
Water 60-100 part.
Modification liquid of the present invention can improve intensity and the antiseptic property of timber, and modified wood preservation from decay moth, anti-mildew, waterproof, fire-retardant, anti-deformation and crack resistence performance are improved significantly; Its density, hardness, bending strength and elastic modelling quantity are all better, can promote the serviceability of timber and the service life of prolonging wood; Also have the natural qualities such as partiting thermal insulation, temperature adjustment and damping, bright in colour, bright, physics striped third dimension is strong, the penetrating nature of sheet material color.
Preferably, the preparation of described cyanurotriamide modified urea resin comprises the steps:
A, prepare raw material according to following weight: melamine 350 ~ 450, methyl alcohol 180 ~ 240, formaldehyde 500 ~ 540, urea 50 ~ 150;
B, melamine and formaldehyde are added in reactor, the pH value that NaOH regulates melamine and formaldehyde mixed solution is added after stirring, heat temperature raising reacts, obtained reactant liquor, wherein, pH value after adjustment is 9.1 ~ 9.5, and reaction temperature is 75 DEG C ~ 85 DEG C, and the reaction time is 30 ~ 50min;
C, make reacting liquid temperature in reactor remain 65 DEG C ~ 75 DEG C, then add pH value >=12 that sodium hydroxide solution regulates reactant liquor;
D, in reactor, add methyl alcohol and first urea carries out modified-reaction, reduce the temperature to 60 DEG C of reactor ~ 70 DEG C after reaction 50 ~ 70min, obtain cooling fluid; The addition of first urea is the 10-80% of urea total amount;
E, add hydrochloric acid, regulate pH value to 8.5 ~ 9.5 of cooling fluid, then add the urea of surplus, stir, urea is dissolved, obtains mixed liquor;
F, add hydrochloric acid and regulate pH value to 7 ~ 8 of mixed liquor, then mixed liquor is kept to be under the condition of 55 DEG C ~ 65 DEG C, react that in reactor, to add sodium hydroxide solution adjust ph after 40 ~ 80min be 10 ~ 11 in temperature, cooling discharge, obtained cyanurotriamide modified urea resin.
After cyanurotriamide modified urea resin impregnated timber of the present invention, resin to diffuse in wood cell and makes timber increase-volume, drying removing moisture, resin solidifies due to heating, generate water-fast polymer, deposition is filled in cell, or occurs crosslinked with wood components, thus make that density of wood increases, hardness and intensity improves, dimensional stability improvement.
Preferably, the mixture that is made up of with weight ratio 1-3:1 nano silicon and nano titanium oxide of described nano modifier.The present invention is by adopting nano silicon and nano titanium oxide as the composite use of nano modifier, and to control its weight ratio be 1-3:1, can improve intensity and the hardness of timber.
Preferably, described anticorrisive agent is DDAC.The present invention, by adopting DDAC as anticorrisive agent, can improve the preservation of timber against decay performance.
Described auxiliary agent is made up of the raw material of following weight portion: nano-tourmaline powder 0.5-0.9 part, sodium carboxymethyl starch 6-8 part, ethoxy urea 12-16 part, lithium metasilicate 1-2 part, radix bupleuri oil 1-2 part, neopelex 2-4 part and water 30-50 part; Its preparation method is: first sodium carboxymethyl starch, ethoxy urea, lithium metasilicate, neopelex are mixed with water, be stirred to mixed material to dissolve completely, add radix bupleuri oil subsequently, dispersed with stirring 40-50min, finally add nano-tourmaline powder, the mixed solution ball milling 1-1.5h obtained, obtains stabilizing solution, obtained auxiliary agent.
Auxiliary agent of the present invention is by adopting above-mentioned raw materials, and the strict weight proportion controlling each raw material, can improve intensity and the toughness of timber, and improves the preservation of timber against decay, Anti-moth-eating, anti-mildew, waterproof, anti-deformation and crack resistence performance.
Preferably, described modification liquid also comprises the raw material of following weight portion: cocoanut fatty acid diethanolamide 1-3 part, organo montmorillonite 1-2 part, polyvinyl alcohol 1-2 part, Nafusaku 0.5-1.5 part, guaiacol 0.5-1.5 part, cellulose ether 0.8-1.2 part, zinc chloride 1-2 part and calcium sulfate 0.4-0.8 part.The interpolation of above-mentioned raw materials makes maceration extract penetration of the present invention strong, be evenly distributed, and stable performance, hygroscopicity is little, not easily runs off after infiltrating through timber, modified effect is lasting, do not affect the grain of wood and color and luster, the mechanical properties such as modified strength of wood, toughness obtain certain lifting, and safety is fire-retardant, make the timber floor obtained durable in use, security performance is high.
Preferably, the mixture that is made up of with weight ratio 2-4:1 sodium-based montmorillonite and softex kw of described organo montmorillonite.
Object of the present invention is achieved through the following technical solutions: a kind of timber strengthens the preparation method of anticorrosion modification liquid, cyanurotriamide modified urea resin, dextrin are added to the water together with nano modifier, be heated to 70-80 DEG C, be stirred to after material dissolves dispersion completely, add anticorrisive agent and auxiliary agent again, 2-3h is stirred, obtained modification liquid with the rotating speed of 1600-1800 rev/min.Another object of the present invention is achieved through the following technical solutions: a kind of timber strengthens the preparation method of flame-retardant modified liquid, cyanurotriamide modified urea resin, dextrin are added to the water together with nano modifier, be heated to 70-80 DEG C, be stirred to after material dissolves dispersion completely, add fire retardant and auxiliary agent again, 2-3h is stirred, obtained modification liquid with the rotating speed of 1600-1800 rev/min.
Preparation method's technique of the present invention is simple, and convenient operation and control, steady quality, production efficiency is high, can large-scale industrial production.
Beneficial effect of the present invention is: modification liquid of the present invention can improve intensity and the antiseptic property of timber, and modified wood preservation from decay moth, anti-mildew, waterproof, fire-retardant, anti-deformation and crack resistence performance are improved significantly; Its density, hardness, bending strength and elastic modelling quantity are all better, can promote the serviceability of timber and the service life of prolonging wood; Also have the natural qualities such as partiting thermal insulation, temperature adjustment and damping, bright in colour, bright, physics striped third dimension is strong, the penetrating nature of sheet material color.
Improved wood intensity after the modification liquid process that the present invention obtains is high, and bending strength is up to 167Mpa, and Deflection Modulus of Elasticity is up to 18049Mpa; Good stability of the dimension, not yielding, anti-drying shrinkage ability increases, and radial absolutely dry shrinkage is lower than 5.6%, and tangential absolutely dry shrinkage is lower than 7.1%; Ability that moisture-resistant is swollen increases, and radial bulking factor is lower than 5.5%, and tangential bulking factor is lower than 7.0%; Hardness is high, and wearability is good, and footpath surface hardness is up to 2447, and string surface hardness is up to 2358N.
Preparation method's technique of the present invention is simple, and convenient operation and control, steady quality, production efficiency is high, can large-scale industrial production.
Detailed description of the invention
For the ease of the understanding of those skilled in the art, below in conjunction with embodiment, the present invention is further illustrated, and the content that embodiment is mentioned not is limitation of the invention.
Embodiment 1
A kind of timber strengthens anticorrosion modification liquid, comprises the raw material of following weight portion:
Cyanurotriamide modified urea resin 10 parts
4 parts, dextrin
Nano modifier 1 part
Anticorrisive agent 0.5 part
Auxiliary agent 1 part
60 parts, water.
The preparation of described cyanurotriamide modified urea resin comprises the steps:
A, prepare raw material according to following weight: melamine 350, methyl alcohol 180, formaldehyde 500, urea 50;
B, add in reactor by melamine and formaldehyde, add the pH value that NaOH regulates melamine and formaldehyde mixed solution after stirring, heat temperature raising reacts, obtained reactant liquor, wherein, the pH value after adjustment is 9.1, reaction temperature is 75 DEG C, and the reaction time is 30min;
C, make reacting liquid temperature in reactor remain 65 DEG C, then add pH value >=12 that sodium hydroxide solution regulates reactant liquor;
D, in reactor, add methyl alcohol and first urea carries out modified-reaction, reduce the temperature to 60 DEG C of reactor after reaction 50min, obtain cooling fluid; The addition of first urea is 10% of urea total amount;
E, add hydrochloric acid, regulate the pH value to 8.5 of cooling fluid, then add the urea of surplus, stir, urea is dissolved, obtains mixed liquor;
F, add hydrochloric acid and regulate the pH value to 7 of mixed liquor, then keep mixed liquor to be that in reactor, to add sodium hydroxide solution adjust ph after reacting 40min under the condition of 55 DEG C be 10 in temperature, cooling discharge, obtained cyanurotriamide modified urea resin.
The mixture that described nano modifier is made up of with weight ratio 1:1 nano silicon and nano titanium oxide.
Described anticorrisive agent is DDAC.
Described auxiliary agent is made up of the raw material of following weight portion: 0.5 part, nano-tourmaline powder, sodium carboxymethyl starch 6 parts, 12 parts, ethoxy urea, lithium metasilicate 1 part, radix bupleuri oil 1 part, neopelex 2 parts and 30 parts, water; Its preparation method is: first sodium carboxymethyl starch, ethoxy urea, lithium metasilicate, neopelex are mixed with water, be stirred to mixed material to dissolve completely, add radix bupleuri oil subsequently, dispersed with stirring 40min, finally add nano-tourmaline powder, the mixed solution ball milling 1h obtained, obtains stabilizing solution, obtained auxiliary agent.
Described modification liquid also comprises the raw material of following weight portion: cocoanut fatty acid diethanolamide 1 part, organo montmorillonite 1 part, polyvinyl alcohol 1 part, Nafusaku 0.5 part, guaiacol 0.5 part, cellulose ether 0.8 part, zinc chloride 1 part and 0.4 part, calcium sulfate.
The mixture that described organo montmorillonite is made up of with weight ratio 2:1 sodium-based montmorillonite and softex kw.
Timber strengthens a preparation method for anticorrosion modification liquid, cyanurotriamide modified urea resin, dextrin is added to the water together with nano modifier, is heated to 70 DEG C, be stirred to after material dissolves dispersion completely, add anticorrisive agent and auxiliary agent again, stir 2h with the rotating speed of 1600 revs/min, obtained modification liquid.
Embodiment 2
A kind of timber strengthens anticorrosion modification liquid, comprises the raw material of following weight portion:
Cyanurotriamide modified urea resin 15 parts
5 parts, dextrin
Nano modifier 2 parts
Anticorrisive agent 0.7 part
Auxiliary agent 2 parts
70 parts, water.
The preparation of described cyanurotriamide modified urea resin comprises the steps:
A, prepare raw material according to following weight: melamine 375, methyl alcohol 190, formaldehyde 510, urea 75;
B, add in reactor by melamine and formaldehyde, add the pH value that NaOH regulates melamine and formaldehyde mixed solution after stirring, heat temperature raising reacts, obtained reactant liquor, wherein, the pH value after adjustment is 9.2, reaction temperature is 77 DEG C, and the reaction time is 35min;
C, make reacting liquid temperature in reactor remain 67 DEG C, then add pH value >=12 that sodium hydroxide solution regulates reactant liquor;
D, in reactor, add methyl alcohol and first urea carries out modified-reaction, reduce the temperature to 62 DEG C of reactor after reaction 55min, obtain cooling fluid; The addition of first urea is 30% of urea total amount;
E, add hydrochloric acid, regulate the pH value to 8.7 of cooling fluid, then add the urea of surplus, stir, urea is dissolved, obtains mixed liquor;
F, add hydrochloric acid and regulate the pH value to 7.2 of mixed liquor, then keep mixed liquor to be that in reactor, to add sodium hydroxide solution adjust ph after reacting 50min under the condition of 57 DEG C be 10.2 in temperature, cooling discharge, obtained cyanurotriamide modified urea resin.
The mixture that described nano modifier is made up of with weight ratio 1.5:1 nano silicon and nano titanium oxide.
Described anticorrisive agent is DDAC.
Described auxiliary agent is made up of the raw material of following weight portion: 0.6 part, nano-tourmaline powder, sodium carboxymethyl starch 6.5 parts, 13 parts, ethoxy urea, lithium metasilicate 1.2 parts, radix bupleuri oil 1.2 parts, neopelex 2.5 parts and 35 parts, water; Its preparation method is: first sodium carboxymethyl starch, ethoxy urea, lithium metasilicate, neopelex are mixed with water, be stirred to mixed material to dissolve completely, add radix bupleuri oil subsequently, dispersed with stirring 42min, finally add nano-tourmaline powder, the mixed solution ball milling 1.1h obtained, obtains stabilizing solution, obtained auxiliary agent.
Described modification liquid also comprises the raw material of following weight portion: cocoanut fatty acid diethanolamide 1.5 parts, organo montmorillonite 1.2 parts, polyvinyl alcohol 1.2 parts, Nafusaku 0.7 part, guaiacol 0.7 part, cellulose ether 0.9 part, zinc chloride 1.2 parts and 0.5 part, calcium sulfate.
The mixture that described organo montmorillonite is made up of with weight ratio 2.5:1 sodium-based montmorillonite and softex kw.
A kind of timber strengthens the preparation method of anticorrosion modification liquid, cyanurotriamide modified urea resin, dextrin are added to the water together with nano modifier, be heated to 72 DEG C, be stirred to after material dissolves dispersion completely, add anticorrisive agent and auxiliary agent again, 2.5h is stirred, obtained modification liquid with the rotating speed of 1650 revs/min.
Embodiment 3
A kind of timber strengthens anticorrosion modification liquid, comprises the raw material of following weight portion:
Cyanurotriamide modified urea resin 20 parts
6 parts, dextrin
Nano modifier 3 parts
Anticorrisive agent 1 part
Auxiliary agent 3 parts
80 parts, water.
The preparation of described cyanurotriamide modified urea resin comprises the steps:
A, prepare raw material according to following weight: melamine 400, methyl alcohol 210, formaldehyde 520, urea 100;
B, add in reactor by melamine and formaldehyde, add the pH value that NaOH regulates melamine and formaldehyde mixed solution after stirring, heat temperature raising reacts, obtained reactant liquor, wherein, the pH value after adjustment is 9.3, reaction temperature is 80 DEG C, and the reaction time is 40min;
C, make reacting liquid temperature in reactor remain 70 DEG C, then add pH value >=12 that sodium hydroxide solution regulates reactant liquor;
D, in reactor, add methyl alcohol and first urea carries out modified-reaction, reduce the temperature to 65 DEG C of reactor after reaction 60min, obtain cooling fluid; The addition of first urea is 45% of urea total amount;
E, add hydrochloric acid, regulate the pH value to 9 of cooling fluid, then add the urea of surplus, stir, urea is dissolved, obtains mixed liquor;
F, add hydrochloric acid and regulate the pH value to 7.5 of mixed liquor, then keep mixed liquor to be that in reactor, to add sodium hydroxide solution adjust ph after reacting 60min under the condition of 60 DEG C be 10.5 in temperature, cooling discharge, obtained cyanurotriamide modified urea resin.
The mixture that described nano modifier is made up of with weight ratio 2:1 nano silicon and nano titanium oxide.
Described anticorrisive agent is DDAC.
Described auxiliary agent is made up of the raw material of following weight portion: 0.7 part, nano-tourmaline powder, sodium carboxymethyl starch 7 parts, 14 parts, ethoxy urea, lithium metasilicate 1.5 parts, radix bupleuri oil 1.5 parts, neopelex 3 parts and 40 parts, water; Its preparation method is: first sodium carboxymethyl starch, ethoxy urea, lithium metasilicate, neopelex are mixed with water, be stirred to mixed material to dissolve completely, add radix bupleuri oil subsequently, dispersed with stirring 45min, finally add nano-tourmaline powder, the mixed solution ball milling 1.3h obtained, obtains stabilizing solution, obtained auxiliary agent.
Described modification liquid also comprises the raw material of following weight portion: cocoanut fatty acid diethanolamide 2 parts, organo montmorillonite 1.5 parts, polyvinyl alcohol 1.5 parts, Nafusaku 1 part, guaiacol 1 part, cellulose ether 1 part, zinc chloride 1.5 parts and 0.6 part, calcium sulfate.
The mixture that described organo montmorillonite is made up of with weight ratio 3:1 sodium-based montmorillonite and softex kw.
A kind of timber strengthens the preparation method of anticorrosion modification liquid, cyanurotriamide modified urea resin, dextrin are added to the water together with nano modifier, be heated to 75 DEG C, be stirred to after material dissolves dispersion completely, add anticorrisive agent and auxiliary agent again, 2.5h is stirred, obtained modification liquid with the rotating speed of 1700 revs/min.
Embodiment 4
A kind of timber strengthens anticorrosion modification liquid, comprises the raw material of following weight portion:
Cyanurotriamide modified urea resin 25 parts
7 parts, dextrin
Nano modifier 3 parts
Anticorrisive agent 1.2 parts
Auxiliary agent 4 parts
90 parts, water.
The preparation of described cyanurotriamide modified urea resin comprises the steps:
A, prepare raw material according to following weight: melamine 425, methyl alcohol 225, formaldehyde 530, urea 125;
B, add in reactor by melamine and formaldehyde, add the pH value that NaOH regulates melamine and formaldehyde mixed solution after stirring, heat temperature raising reacts, obtained reactant liquor, wherein, the pH value after adjustment is 9.4, reaction temperature is 82 DEG C, and the reaction time is 45min;
C, make reacting liquid temperature in reactor remain 72 DEG C, then add pH value >=12 that sodium hydroxide solution regulates reactant liquor;
D, in reactor, add methyl alcohol and first urea carries out modified-reaction, reduce the temperature to 68 DEG C of reactor after reaction 65min, obtain cooling fluid; The addition of first urea is 60% of urea total amount;
E, add hydrochloric acid, regulate the pH value to 9.2 of cooling fluid, then add the urea of surplus, stir, urea is dissolved, obtains mixed liquor;
F, add hydrochloric acid and regulate the pH value to 7.8 of mixed liquor, then keep mixed liquor to be that in reactor, to add sodium hydroxide solution adjust ph after reacting 70min under the condition of 62 DEG C be 10.8 in temperature, cooling discharge, obtained cyanurotriamide modified urea resin.
The mixture that described nano modifier is made up of with weight ratio 2.5:1 nano silicon and nano titanium oxide.
Described anticorrisive agent is DDAC.
Described auxiliary agent is made up of the raw material of following weight portion: 0.8 part, nano-tourmaline powder, sodium carboxymethyl starch 7.5 parts, 15 parts, ethoxy urea, lithium metasilicate 1.8 parts, radix bupleuri oil 1.8 parts, neopelex 3.5 parts and 45 parts, water; Its preparation method is: first sodium carboxymethyl starch, ethoxy urea, lithium metasilicate, neopelex are mixed with water, be stirred to mixed material to dissolve completely, add radix bupleuri oil subsequently, dispersed with stirring 48min, finally add nano-tourmaline powder, the mixed solution ball milling 1.4h obtained, obtains stabilizing solution, obtained auxiliary agent.
Described modification liquid also comprises the raw material of following weight portion: cocoanut fatty acid diethanolamide 2.5 parts, organo montmorillonite 1.8 parts, polyvinyl alcohol 1.8 parts, Nafusaku 1.2 parts, guaiacol 1.2 parts, cellulose ether 1.1 parts, zinc chloride 1.8 parts and 0.7 part, calcium sulfate.
The mixture that described organo montmorillonite is made up of with weight ratio 3.5:1 sodium-based montmorillonite and softex kw.
A kind of timber strengthens the preparation method of anticorrosion modification liquid, cyanurotriamide modified urea resin, dextrin are added to the water together with nano modifier, be heated to 78 DEG C, be stirred to after material dissolves dispersion completely, add anticorrisive agent and auxiliary agent again, 2.5h is stirred, obtained modification liquid with the rotating speed of 1750 revs/min.
Embodiment 5
A kind of timber strengthens anticorrosion modification liquid, comprises the raw material of following weight portion:
Cyanurotriamide modified urea resin 30 parts
8 parts, dextrin
Nano modifier 5 parts
Anticorrisive agent 1.5 parts
Auxiliary agent 5 parts
100 parts, water.
The preparation of described cyanurotriamide modified urea resin comprises the steps:
A, prepare raw material according to following weight: melamine 450, methyl alcohol 240, formaldehyde 540, urea 150;
B, add in reactor by melamine and formaldehyde, add the pH value that NaOH regulates melamine and formaldehyde mixed solution after stirring, heat temperature raising reacts, obtained reactant liquor, wherein, the pH value after adjustment is 9.5, reaction temperature is 85 DEG C, and the reaction time is 50min;
C, make reacting liquid temperature in reactor remain 75 DEG C, then add pH value >=12 that sodium hydroxide solution regulates reactant liquor;
D, in reactor, add methyl alcohol and first urea carries out modified-reaction, reduce the temperature to 70 DEG C of reactor after reaction 70min, obtain cooling fluid; The addition of first urea is 80% of urea total amount;
E, add hydrochloric acid, regulate the pH value to 9.5 of cooling fluid, then add the urea of surplus, stir, urea is dissolved, obtains mixed liquor;
F, add hydrochloric acid and regulate the pH value to 8 of mixed liquor, then keep mixed liquor to be that in reactor, to add sodium hydroxide solution adjust ph after reacting 80min under the condition of 65 DEG C be 11 in temperature, cooling discharge, obtained cyanurotriamide modified urea resin.
The mixture that described nano modifier is made up of with weight ratio 3:1 nano silicon and nano titanium oxide.
Described anticorrisive agent is DDAC.
Described auxiliary agent is made up of the raw material of following weight portion: 0.9 part, nano-tourmaline powder, sodium carboxymethyl starch 8 parts, 16 parts, ethoxy urea, lithium metasilicate 2 parts, radix bupleuri oil 2 parts, neopelex 4 parts and 50 parts, water; Its preparation method is: first sodium carboxymethyl starch, ethoxy urea, lithium metasilicate, neopelex are mixed with water, be stirred to mixed material to dissolve completely, add radix bupleuri oil subsequently, dispersed with stirring 50min, finally add nano-tourmaline powder, the mixed solution ball milling 1.5h obtained, obtains stabilizing solution, obtained auxiliary agent.
Described modification liquid also comprises the raw material of following weight portion: cocoanut fatty acid diethanolamide 3 parts, organo montmorillonite 2 parts, polyvinyl alcohol 2 parts, Nafusaku 1.5 parts, guaiacol 1.5 parts, cellulose ether 1.2 parts, zinc chloride 2 parts and 0.8 part, calcium sulfate.
The mixture that described organo montmorillonite is made up of with weight ratio 4:1 sodium-based montmorillonite and softex kw.
Timber strengthens a preparation method for anticorrosion modification liquid, cyanurotriamide modified urea resin, dextrin is added to the water together with nano modifier, is heated to 80 DEG C, be stirred to after material dissolves dispersion completely, add anticorrisive agent and auxiliary agent again, stir 3h with the rotating speed of 1800 revs/min, obtained modification liquid.
The mechanical and physical performance of the improved wood after the modification liquid process that embodiment 1-5 obtains is as shown in table 1:
Table 1
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Bending strength (Mpa) | 162 | 165 | 167 | 166 | 164 |
| Deflection Modulus of Elasticity (Mpa) | 17914 | 17965 | 18049 | 18037 | 17983 |
| Radial absolutely dry shrinkage (%) | 6.2 | 6.0 | 5.6 | 5.8 | 6.1 |
| Tangential absolutely dry shrinkage (%) | 7.9 | 7.4 | 7.1 | 7.5 | 7.7 |
| Radial bulking factor (%) | 6.1 | 5.9 | 5.5 | 5.7 | 6.0 |
| Tangential bulking factor (%) | 7.8 | 7.4 | 7.0 | 7.2 | 7.6 |
| Footpath surface hardness (N) | 2411 | 2438 | 2447 | 2430 | 2379 |
| String surface hardness (N) | 2330 | 2339 | 2358 | 2347 | 2334 |
As can be seen from the above table, the improved wood intensity after the modification liquid process that the present invention obtains is high, and bending strength is up to 167Mpa, and Deflection Modulus of Elasticity is up to 18049Mpa; Good stability of the dimension, not yielding, anti-drying shrinkage ability increases, and radial absolutely dry shrinkage is lower than 5.6%, and tangential absolutely dry shrinkage is lower than 7.1%; Ability that moisture-resistant is swollen increases, and radial bulking factor is lower than 5.5%, and tangential bulking factor is lower than 7.0%; Hardness is high, and wearability is good, and footpath surface hardness is up to 2447, and string surface hardness is up to 2358N.
Above-described embodiment is the present invention's preferably implementation, and in addition, the present invention can also realize by alternate manner, and any apparent replacement is all within protection scope of the present invention without departing from the inventive concept of the premise.
Claims (8)
1. timber strengthens an anticorrosion modification liquid, it is characterized in that: the raw material comprising following weight portion:
Cyanurotriamide modified urea resin 10-30 part
Dextrin 4-8 part
Nano modifier 1-5 part
Anticorrisive agent 0.5-1.5 part
Auxiliary agent 1-5 part
Water 60-100 part.
2. a kind of timber according to claim 1 strengthens anticorrosion modification liquid, it is characterized in that: the preparation of described cyanurotriamide modified urea resin comprises the steps:
A, prepare raw material according to following weight: melamine 350 ~ 450, methyl alcohol 180 ~ 240, formaldehyde 500 ~ 540, urea 50 ~ 150;
B, melamine and formaldehyde are added in reactor, the pH value that NaOH regulates melamine and formaldehyde mixed solution is added after stirring, heat temperature raising reacts, obtained reactant liquor, wherein, pH value after adjustment is 9.1 ~ 9.5, and reaction temperature is 75 DEG C ~ 85 DEG C, and the reaction time is 30 ~ 50min;
C, make reacting liquid temperature in reactor remain 65 DEG C ~ 75 DEG C, then add pH value >=12 that sodium hydroxide solution regulates reactant liquor;
D, in reactor, add methyl alcohol and first urea carries out modified-reaction, reduce the temperature to 60 DEG C of reactor ~ 70 DEG C after reaction 50 ~ 70min, obtain cooling fluid; The addition of first urea is the 10-80% of urea total amount;
E, add hydrochloric acid, regulate pH value to 8.5 ~ 9.5 of cooling fluid, then add the urea of surplus, stir, urea is dissolved, obtains mixed liquor;
F, add hydrochloric acid and regulate pH value to 7 ~ 8 of mixed liquor, then mixed liquor is kept to be under the condition of 55 DEG C ~ 65 DEG C, react that in reactor, to add sodium hydroxide solution adjust ph after 40 ~ 80min be 10 ~ 11 in temperature, cooling discharge, obtained cyanurotriamide modified urea resin.
3. a kind of timber according to claim 1 strengthens anticorrosion modification liquid, it is characterized in that: the mixture that described nano modifier is made up of with weight ratio 1-3:1 nano silicon and nano titanium oxide.
4. a kind of timber according to claim 1 strengthens anticorrosion modification liquid, it is characterized in that: described anticorrisive agent is DDAC.
5. a kind of timber according to claim 1 strengthens anticorrosion modification liquid, it is characterized in that: described auxiliary agent is made up of the raw material of following weight portion: nano-tourmaline powder 0.5-0.9 part, sodium carboxymethyl starch 6-8 part, ethoxy urea 12-16 part, lithium metasilicate 1-2 part, radix bupleuri oil 1-2 part, neopelex 2-4 part and water 30-50 part; Its preparation method is: first sodium carboxymethyl starch, ethoxy urea, lithium metasilicate, neopelex are mixed with water, be stirred to mixed material to dissolve completely, add radix bupleuri oil subsequently, dispersed with stirring 40-50min, finally add nano-tourmaline powder, the mixed solution ball milling 1-1.5h obtained, obtains stabilizing solution, obtained auxiliary agent.
6. a kind of timber according to claim 1 strengthens anticorrosion modification liquid, it is characterized in that: described modification liquid also comprises the raw material of following weight portion: cocoanut fatty acid diethanolamide 1-3 part, organo montmorillonite 1-2 part, polyvinyl alcohol 1-2 part, Nafusaku 0.5-1.5 part, guaiacol 0.5-1.5 part, cellulose ether 0.8-1.2 part, zinc chloride 1-2 part and calcium sulfate 0.4-0.8 part.
7. a kind of timber according to claim 6 strengthens anticorrosion modification liquid, it is characterized in that: the mixture that described organo montmorillonite is made up of with weight ratio 2-4:1 sodium-based montmorillonite and softex kw.
8. a kind of timber as described in any one of claim 1-7 strengthens the preparation method of anticorrosion modification liquid, it is characterized in that: cyanurotriamide modified urea resin, dextrin are added to the water together with nano modifier, be heated to 70-80 DEG C, be stirred to after material dissolves dispersion completely, add anticorrisive agent and auxiliary agent again, 2-3h is stirred, obtained modification liquid with the rotating speed of 1600-1800 rev/min.
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| CN107471355A (en) * | 2017-09-11 | 2017-12-15 | 阜南县猛发工艺品有限公司 | A kind of processing method of Eucalyptus handicraft |
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