CN104800872B - A kind of formaldehyde fumigation sterilization method and its chlorination equipment - Google Patents

A kind of formaldehyde fumigation sterilization method and its chlorination equipment Download PDF

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Publication number
CN104800872B
CN104800872B CN201510162963.6A CN201510162963A CN104800872B CN 104800872 B CN104800872 B CN 104800872B CN 201510162963 A CN201510162963 A CN 201510162963A CN 104800872 B CN104800872 B CN 104800872B
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formaldehyde
groove
potassium permanganate
formalin
time delay
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CN104800872A (en
Inventor
曲继广
何亚卓
宋立军
蒋德光
张旭
景胜伍
石永浩
关兴志
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Shijiazhuang No 4 Pharmaceutical Co Ltd
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Shijiazhuang No 4 Pharmaceutical Co Ltd
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Abstract

The present invention disclose a kind of formaldehyde fumigation sterilization method and its chlorination equipment, and it can be very good to control the time of contact of formaldehyde and potassium permanganate, formaldehyde is reacted completely, it is ensured that formaldehyde liquid is without residue reaching the effect to the fumigation of closed room;Formaldehyde is set to be reacted after operating personnel leave clean room with potassium permanganate;Whole disinfecting process is set to avoid the generation of naked light, it is ensured that the safety of operating personnel.

Description

A kind of formaldehyde fumigation sterilization method and its chlorination equipment
Technical field
The present invention relates to a kind of formaldehyde fumigation sterilization method, the invention further relates to a kind of formaldehyde fumigation chlorination equipment.
Background technology
The formaldehyde fumigation disinfection way for using at present is to add in rustless steel container formaldehyde, and container is placed on support, is used Alcolhol burner is heated, and formaldehyde is evaporated in the method for indoor fumigation, and the shortcoming of the method is that operation link is cumbersome, there is safety Hidden danger:The method need to be lighted after alcolhol burner, and operating personnel just may exit off room, and now formaldehyde has begun to volatilization, can be right The operator's health not withdrawn from a room produces influence, or even causes formaldehyde poisoning symptom, severe formaldehyde poisoning entail dangers to life; Alcolhol burner is naked light, easily causes disaster hidden-trouble.
The content of the invention
In order to solve the above mentioned problem existing for prior art, the invention provides a kind of formaldehyde fumigation sterilization method and its Chlorination equipment, is carried out disinfection using chemical principle, and it can be very good to control the time of contact of formaldehyde and potassium permanganate, to make Formaldehyde reaction is complete, it is ensured that formaldehyde liquid noresidue is reaching the effect to the fumigation of closed room;Make formaldehyde and Gao Meng Sour potassium is reacted after operating personnel open 30 seconds of valve, and the time for leaving clean room is reserved to operating personnel, and And whole disinfecting process avoids the generation of naked light, it is ensured that the safety of operating personnel.
The technical scheme is that so constitute:
A kind of formaldehyde fumigation sterilization method, it is characterised in that comprise the following steps:Formalin is through formaldehyde trench bottom aperture It flow to the formaldehyde transfer pipeline with valve;Opening valve makes formalin flow into time delay groove and control formalin flow velocity size; Formalin is flow in time delay groove through formaldehyde transfer pipeline;When height of the formalin in time delay groove reaches spillway hole highly When, formalin flows out from spillway hole, flow in the potassium permanganate groove equipped with potassium permanganate solid;Formalin and potassium permanganate Solid contact is reacted, formaldehyde gas release, and fumigation is carried out to closed room.Described formalin concentration is 36%, the liquid-solid ratio of formalin and potassium permanganate solid is 25:1(V:W);At least through 30 seconds formalin after opening valve Beginning reacts with potassium permanganate solid.
Present invention also offers a kind of chlorination equipment for above-mentioned formaldehyde fumigation sterilization method, it is characterised in that including Formaldehyde groove, support, potassium permanganate groove, time delay groove and formaldehyde transfer pipeline, the formaldehyde trench bottom depressed area are provided with aperture;It is described The bottom of formaldehyde groove is fixed on above support;One end of the formaldehyde transfer pipeline is connected to formaldehyde trench bottom and is communicated with aperture, The other end of formaldehyde transfer pipeline is stretched into potassium permanganate groove sidewall, and lower section is provided with the time delay for being fixed on potassium permanganate trench bottom Groove;The formaldehyde transfer pipeline is provided with valve;The time delay groove side is provided with spillway hole.
Preferably, the interior diameter ratio of hole diameter and formaldehyde transfer pipeline is 1:10.
Preferably, the time delay groove is cylinder or cuboid, and formaldehyde transfer pipeline stretches into length in potassium permanganate groove sidewall Spend the cell body without departing from time delay groove.
Preferably, the spillway hole is highly apart from time delay trench bottom 1-1.3cm, a diameter of 0.2- of spillway hole 0.4cm。
Preferably, the formaldehyde groove is cylinder;Support is square or cuboid, and at least one side is movable to tear open Unload;Potassium permanganate groove is rectangle or square.
Preferably, one end of the formaldehyde transfer pipeline is welded on formaldehyde trench bottom and is communicated with aperture, and hole diameter is 1.0mm, the interior diameter of formaldehyde transfer pipeline is 1.0cm.
Preferably, it is a cuboid after support and the combination of potassium permanganate groove.
Preferably, the chlorination equipment material is stainless steel.
The present invention has buffered the reaction of formalin and potassium permanganate solid by time delay groove, and spillway hole therein is even more control The time of formalin and potassium permanganate solid contact is made, clean room has been left there is provided the time to operating personnel.
Now inventor is described as follows in the development of existing equipment:
Experiment for the first time is improved:
It is electrically operated valve that the present invention is initially use, due to inconvenient operation, electrically operated valve is removed afterwards, installs hand-operated valve Door, realizes artificial control chemical reaction.The method is simple and convenient, but it is still very violent to chemically react.
Second experiment is improved:
The hole diameter of formaldehyde trench bottom depressed area is set to 1.5mm;Valve is opened, and formalin 2-3s flows into permanganic acid In potassium groove, there is acutely chemical reaction.
Third time experiment is improved:
The hole diameter of formaldehyde trench bottom depressed area is improved to by 1.0mm using the drill bit redrilling of 1.0mm, reaction is acute Strong degree is substantially reduced.
Inventor is found that while that response intensity can be controlled by improving hole diameter, but general clean area fumigation All put the formaldehyde fumigation chlorination equipment of more than 2, can not be reached if only above-mentioned improvement is carried out operating personnel safety from The effect at the scene of opening, being then determined as the present invention increases time delay groove, delays the reaction time of formalin and potassium permanganate solid, Reach operating personnel and leave the requirement reacted after clean room.Comprise the following steps that:
A. assume that operating personnel need the time of 30s to withdraw stifling scene, measuring formalin by beaker passes through formaldehyde The liquid volume of transfer pipeline stream 30s calculates the volume of time delay groove.
B. because flow into time delay groove formalin volume exceed time delay sump volume when take place chemical reaction, it is necessary to Gap, control formalin outflow time delay groove and the time of potassium permanganate solid reaction are outputed in the corresponding position of time delay groove, lead to Overtesting determines a diameter of 0.2-0.4cm of gap, makes valve that chemical reaction takes place by the time of 30s after opening, this Can just there is the safe escape time of 30s after sample operating personnel opening valve.4th experiment is improved:
Appropriate formaldehyde and potassium permanganate are poured into formaldehyde groove and potassium permanganate groove respectively, meter is started while opening valve When, chemically reacted after 30s, illustrate that time delay groove and gap can reach the effect for delaying above-mentioned reaction.But off-test Find to remain formaldehyde in time delay groove afterwards, illustrate not reacted fully.It is fully anti-to reach to need adjustment spillway hole height The requirement answered.
The height (h spillway holes) of computation delay groove spillway hole, measurement reaction terminates the height (h mixing) of rear mixed solution, React the formalin in time delay groove then needs h mixing > h spillway holes completely.
Mix removing residue formaldehyde solution conditions in the time delay groove poor with h spillway holes different height, experiment knot by testing measuring and calculating h Fruit is shown in Table 1.Experiment explanation h mixing should be higher than that h spillway holes 15mm, and to reach, the reaction of the formalin in time delay groove is complete to be required, Determine that spillway hole is highly 1-1.3cm.
Table 1
Brief description of the drawings
Fig. 1 is the structural representation of chlorination equipment of the present invention
Fig. 2 is the top view of chlorination equipment of the present invention
Specific embodiment
With reference to accompanying drawing 1-2, present invention is described:
Embodiment 1
Height of the formaldehyde groove (1) apart from ground is 38cm, and the aperture (2) in bottom notch area is directly through being 1mm, formaldehyde groove (1) Bottom be fixed on support (3) above, support (3) is square, the movable dismounting at least one side, support (3) and Gao Meng It is a cuboid after sour potassium groove (4) combination, the interior diameter of formaldehyde transfer pipeline (7) is 1cm, the one of formaldehyde transfer pipeline (7) End is welded on formaldehyde groove (1) bottom and is communicated with aperture (2), and the other end of formaldehyde transfer pipeline (7) is in potassium permanganate groove (4) side wall Stretch into, lower section is provided with the time delay groove (5) for being fixed on potassium permanganate trench bottom, and formaldehyde transfer pipeline (7) is in potassium permanganate groove (4) side Without departing from the cell body of time delay groove (5), formaldehyde transfer pipeline (7) is provided with valve (8) to wall built-in length, and time delay groove (5) side sets There is spillway hole (6), spillway hole (6) is highly apart from time delay trench bottom 1.3cm, a diameter of 0.4cm.
Preferably, the time delay groove is cylinder or cuboid.
Preferably, formaldehyde groove is cylinder, and potassium permanganate groove is rectangle or square.
Formalin and potassium permanganate solid are poured into formaldehyde groove (1) and potassium permanganate groove (4) respectively, described formaldehyde is molten Liquid concentration is 36%, and the liquid-solid ratio of formalin and potassium permanganate solid is 25:1(V:W).Formalin is small through formaldehyde trench bottom Hole (2) flow to the formaldehyde transfer pipeline (7) with valve (8);Opening valve (8) makes formalin flow into time delay groove and control formaldehyde Solution flow rate size;Formalin is flow in time delay groove (5) through formaldehyde transfer pipeline (7);When formalin is in time delay groove (5) Height when reaching spillway hole (6) height, formalin flows out from spillway hole (6), flow to the Gao Meng equipped with potassium permanganate solid In sour potassium groove (4);Formalin is reacted with potassium permanganate solid contact, formaldehyde gas release, and closed room is smoked Steam sterilization.Valve is opened to start to be reacted with potassium permanganate solid by 30 seconds formalin.
Embodiment 2
Height of the formaldehyde groove (1) apart from ground is 45cm, and the aperture (2) in bottom notch area is directly through being 1mm, formaldehyde groove (1) Bottom be fixed on support (3) above, support (3) is cuboid, the movable dismounting at least one side, support (3) and Gao Meng It is a cuboid after sour potassium groove (4) combination, the interior diameter of formaldehyde transfer pipeline (7) is 1cm, the one of formaldehyde transfer pipeline (7) End is welded on formaldehyde groove (1) bottom and is communicated with aperture (2), and the other end of formaldehyde transfer pipeline (7) is in potassium permanganate groove (4) side wall Stretch into, lower section is provided with the time delay groove (5) for being fixed on potassium permanganate trench bottom, and formaldehyde transfer pipeline (7) is in potassium permanganate groove (4) side Without departing from the cell body of time delay groove (5), formaldehyde transfer pipeline (7) is provided with valve (8) to wall built-in length, and time delay groove (5) side sets There is spillway hole (6), spillway hole (6) is highly apart from time delay trench bottom 1cm, a diameter of 0.2cm.
Preferably, the time delay groove is cylinder or cuboid.
Preferably, formaldehyde groove is cylinder, and potassium permanganate groove is rectangle or square.
Formalin and potassium permanganate solid are poured into formaldehyde groove (1) and potassium permanganate groove (4) respectively, described formaldehyde is molten Liquid concentration is 36%, and the liquid-solid ratio of formalin and potassium permanganate solid is 25:1(V:W).Formalin is small through formaldehyde trench bottom Hole (2) flow to the formaldehyde transfer pipeline (7) with valve (8);Opening valve (8) makes formalin flow into time delay groove and control formaldehyde Solution flow rate size;Formalin is flow in time delay groove (5) through formaldehyde transfer pipeline (7);When formalin is in time delay groove (5) Height when reaching spillway hole (6) height, formalin flows out from spillway hole (6), flow to the Gao Meng equipped with potassium permanganate solid In sour potassium groove (4);Formalin is reacted with potassium permanganate solid contact, formaldehyde gas release, and closed room is smoked Steam sterilization.Valve is opened to start to be reacted with potassium permanganate solid by 40 seconds formalin.

Claims (11)

1. a kind of formaldehyde fumigation sterilization method, it is characterised in that comprise the following steps:Formalin is through formaldehyde trench bottom aperture stream To the formaldehyde transfer pipeline with valve;Opening valve makes formalin flow into time delay groove and control formalin flow velocity size;First Aldehyde solution is flow in time delay groove through formaldehyde transfer pipeline;When height of the formalin in time delay groove reaches spillway hole height, Formalin flows out from spillway hole, flow in the potassium permanganate groove equipped with potassium permanganate solid;Formalin is consolidated with potassium permanganate Body contact is reacted, formaldehyde gas release, and fumigation is carried out to closed room.
2. formaldehyde fumigation sterilization method as claimed in claim 1, it is characterised in that described formalin concentration is 36%, The liquid-solid ratio of formalin and potassium permanganate solid is 25:1(V:W).
3. formaldehyde fumigation sterilization method as claimed in claim 1, it is characterised in that open after valve at least through 30 seconds formaldehyde Solution starts to be reacted with potassium permanganate solid.
4. a kind of formaldehyde fumigation chlorination equipment, it is characterised in that including formaldehyde groove (1), support (3), potassium permanganate groove (4), prolong Time slot (5) and formaldehyde transfer pipeline (7), formaldehyde groove (1) the bottom notch area are provided with aperture (2);The bottom of the formaldehyde groove (1) Portion is fixed on support (3) above;One end of the formaldehyde transfer pipeline (7) is connected to formaldehyde groove (1) bottom with aperture (2) phase Logical, the other end of formaldehyde transfer pipeline (7) is stretched into potassium permanganate groove (4) side wall, and lower section is provided with and is fixed on potassium permanganate groove (4) The time delay groove (5) of bottom;The formaldehyde transfer pipeline (7) is provided with valve (8);Time delay groove (5) side is provided with spillway hole (6)。
5. chlorination equipment as claimed in claim 4, it is characterised in that aperture (2) diameter and formaldehyde transfer pipeline (7) it is interior straight Footpath ratio is 1:10.
6. chlorination equipment as claimed in claim 4, it is characterised in that the time delay groove (5) is cylinder or cuboid, formaldehyde Transfer pipeline (7) is in cell body of potassium permanganate groove (4) the side wall built-in length without departing from time delay groove (5).
7. chlorination equipment as claimed in claim 4, it is characterised in that the spillway hole (6) is highly apart from time delay trench bottom 1-1.3cm, a diameter of 0.2-0.4cm of the spillway hole (6).
8. chlorination equipment as claimed in claim 4, it is characterised in that the formaldehyde groove (1) is cylinder;Support (3) is for just Cube or cuboid, the movable dismounting at least one side;Potassium permanganate groove (4) is rectangle or square.
9. chlorination equipment as claimed in claim 5, it is characterised in that one end of the formaldehyde transfer pipeline (7) is welded on first Aldehyde groove (1) bottom communicates with aperture (2), aperture (2) a diameter of 1.0mm, and the interior diameter of formaldehyde transfer pipeline (7) is 1.0cm.
10. chlorination equipment as claimed in claim 8, it is characterised in that be after support (3) and potassium permanganate groove (4) combination Individual cuboid.
11. chlorination equipments as claimed in claim 4, it is characterised in that the chlorination equipment material is stainless steel.
CN201510162963.6A 2015-04-08 2015-04-08 A kind of formaldehyde fumigation sterilization method and its chlorination equipment Active CN104800872B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105031683B (en) * 2015-08-12 2018-07-13 南阳师范学院 Fumigation method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2418877Y (en) * 1999-11-09 2001-02-14 桂茶华 Disposable fumigation sterilizing pot
CN201996878U (en) * 2011-02-28 2011-10-05 刘德江 Efficient fuming fumigator
CN204542953U (en) * 2015-04-08 2015-08-12 石家庄四药有限公司 A kind of formaldehyde fumigation decontaminating apparatus

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03109069A (en) * 1989-09-22 1991-05-09 Nippon Soda Co Ltd Fumigating sterilization

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2418877Y (en) * 1999-11-09 2001-02-14 桂茶华 Disposable fumigation sterilizing pot
CN201996878U (en) * 2011-02-28 2011-10-05 刘德江 Efficient fuming fumigator
CN204542953U (en) * 2015-04-08 2015-08-12 石家庄四药有限公司 A kind of formaldehyde fumigation decontaminating apparatus

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Address after: 050035 No. 518, Huai'an East Road, high tech Industrial Development Zone, Shijiazhuang City, Hebei Province

Patentee after: SHIJIAZHUANG NO.4 PHARMACEUTICAL Co.,Ltd.

Address before: 050035 No.288, Zhujiang Avenue, Shijiazhuang hi tech Industrial Development Zone, Shijiazhuang City, Hebei Province

Patentee before: SHIJIAZHUANG NO.4 PHARMACEUTICAL Co.,Ltd.