CN104791041B - A kind of cylinder cover of automobile engine - Google Patents

A kind of cylinder cover of automobile engine Download PDF

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Publication number
CN104791041B
CN104791041B CN201510252101.2A CN201510252101A CN104791041B CN 104791041 B CN104791041 B CN 104791041B CN 201510252101 A CN201510252101 A CN 201510252101A CN 104791041 B CN104791041 B CN 104791041B
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inlet valve
incubated
temperature
carried out
coating
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CN104791041A (en
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周兰兰
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Zhejiang Kaiji Automobile Spare Parts Manufacture Co., Ltd.
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Shengzhou Yiyuan Investment Management Co ltd
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Priority to CN201710967541.5A priority patent/CN107794459B/en
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/34—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23P—METAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
    • B23P15/00—Making specific metal objects by operations not covered by a single other subclass or a group in this subclass
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18—Hardening; Quenching with or without subsequent tempering
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/04—Hardening by cooling below 0 degrees Celsius
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/0068—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for particular articles not mentioned below
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C27/00—Alloys based on rhenium or a refractory metal not mentioned in groups C22C14/00 or C22C16/00
    • C22C27/04—Alloys based on tungsten or molybdenum
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/52—Ferrous alloys, e.g. steel alloys containing chromium with nickel with cobalt
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06—Metallic material
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • C23C4/131—Wire arc spraying
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/28—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases more than one element being applied in one step
    • C23C8/30—Carbo-nitriding
    • C23C8/32—Carbo-nitriding of ferrous surfaces
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01L—CYCLICALLY OPERATING VALVES FOR MACHINES OR ENGINES
    • F01L3/00—Lift-valve, i.e. cut-off apparatus with closure members having at least a component of their opening and closing motion perpendicular to the closing faces; Parts or accessories thereof
    • F01L3/02—Selecting particular materials for valve-members or valve-seats; Valve-members or valve-seats composed of two or more materials
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
    • F02F1/00—Cylinders; Cylinder heads 
    • F02F1/24—Cylinder heads
    • F02F1/42—Shape or arrangement of intake or exhaust channels in cylinder heads

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Heat Treatment Of Articles (AREA)
  • Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)

Abstract

A kind of cylinder cover of automobile engine, cylinder head include the inlet valve seat ring for being used for the air inlet door part of engine charge and being engaged with air inlet door part, and hardness and intensity that carbo-nitriding heat treatment improves inlet valve are carried out to engine valve, avoids the occurrence of hot spot；Handle that the engine valve conical surface reaches higher wearability and impact resistance, corresponding fatigue behaviour are also improved by built-up welding.

Description

A kind of cylinder cover of automobile engine
Technical field
The present invention relates to a kind of cylinder cover of automobile engine, belongs to automobile engine accessory technical field.
Background technology
Automobile inlet and exhaust valve and inlet and exhaust valve seat ring are the basic parts of cylinder, and the quality of its quality directly affects hair The main performance index such as motivation power and oil consumption, it is very big to the reliability effect of engine.Inlet and exhaust valve and inlet and exhaust valve seat ring Working environment it is severe, it not only bears high speed impact load, and to be worked under the conditions of with etchant gas, thus send out Motivation inlet and exhaust valve and inlet and exhaust valve seat ring have become the consumable accessory for needing often to change, therefore improve valve and valve retainer Use quality and the life-span be one and need to solve the problems, such as.
The content of the invention
A kind of cylinder cover of automobile engine, cylinder head include for engine charge air inlet door part and with inlet valve portion The inlet valve seat ring that part is engaged,
Inlet valve seat ring chemical element forms（Percentage by weight）：C:0.06-0.07 ﹪, Si：2-3 ﹪, Cu：1-2 ﹪, W：0.8-0.9 ﹪, Cr：0.4-0.5 ﹪, Ni：0.2-0.3 ﹪, Nb：0.2-0.3 ﹪, V：0.1-0.2 ﹪, Ti：0.07- 0.08 ﹪, Al：0.05-0.06 ﹪, Mn：0.02-0.03 ﹪, Mg：0.02-0.03 ﹪, Mo：0.01-0.02 ﹪, Ce：0.01- 0.02 ﹪, surplus are Fe and inevitable impurity；
Suction valve cone coil preparation method：Comprise the following steps：According to aforementioned proportion alloyage, raw material melting, cast, take off After mould, obtained valve retainer base substrate is sent into heating furnace, is warming up to 900 DEG C, 75 DEG C/h of heating rate, is incubated 3 hours, it Water hardening afterwards, base substrate is heated again and is incubated 5 hours at 620 DEG C, comes out of the stove and is air-cooled to room temperature；Base substrate is put into liquid nitrogen at deep cooling Reason 10 minutes, goes back up to room temperature in atmosphere；Base substrate is finely machined afterwards,
Tungsten carbide system coating is coated to the inlet valve seat ring after fine machining；Tungsten carbide based material layer includes（Weight Amount）：80 parts of tungsten carbide, silica 10-20 parts, the valve retainer after coating is heated, and is warming up to 600 DEG C, heating rate 200 DEG C/h, be incubated 10 hours, after be air-cooled to room temperature, obtain final inlet valve seat ring,
Manufacture inlet valve concretely comprises the following steps：
According to the elemental constituent of inlet valve material of main part carry out melting, after cast, obtain blank, inlet valve material of main part For：C0.13-0.27%, Si3.4-4%, Mn0.8-0.95%, P≤0.035%, S≤0.035%, Ti1.2-1.9%, Cr 5-7%, W 3-4%, Ni2.8-3.24%, Co 1-1.2%, surplus are Fe and inevitable impurity；
Blank is forged using electric upset forging, final forging temperature is 900 DEG C, and forging deformation amount is controlled in 65%-85%, jumping-up speed For 10mm/s；
Multistage quenching-and-tempering process is carried out after forging：The water quenching after 1050-1080 DEG C of insulation 10s, 450-500 DEG C is returned Fire；Then oil quenching after 980-1010 DEG C of insulation 10s, 430-440 DEG C of tempering；Oil quenching after last 950-970 DEG C of insulation 10s, 380- 410 DEG C of tempering；
Carried out after heat treatment to workpiece machining,
Carbo-nitriding heat treatment is carried out to workpiece surface after machining, oozes process by force：950-980 DEG C of scope of temperature, carbon Gesture and nitrogen gesture take level Four step, carbon potential 0.4-0.6%, nitrogen gesture 1.2-1.4%, are incubated 3h, then rise carbon potential to 0.7-0.9%, Nitrogen gesture is reduced to 1.0-1.1%, insulation 2h, then raises carbon potential to 1.0-1.1%, nitrogen gesture is reduced to 0.7-0.9%, is incubated 2h, finally Carbon potential is raised to 1.2-1.6%, nitrogen gesture is reduced to 0.4-0.5%, is incubated 2.5h；It is diffused after oozing by force, diffusion process：Control stove Temperature is down to 900-920 DEG C, is incubated 3h, is cooled to 820-850 DEG C, is incubated 4h, diffusion process carbon-potential control 1.2~1.3% it Between, nitrogen potential control is between 1.0~1.1%；It is air-cooled to room temperature；Quenched after diffusion, quenching process：Oil is carried out at 850 DEG C Quench, Oil-temperature control is at 70 DEG C；Cleaning process：Component surface oil stain is removed, rinse liquid temperature is controlled at 50 DEG C；Tempering：Carry out Lonneal, control 180 DEG C of furnace temperature, minute time 150-200.
Workpiece conical surface grinding is processed,
Conical surface built-up welding is carried out to workpiece after conical surface grinding processing, conical surface bead-welding technology is：150-200 DEG C of preheating, it is non-diverting Arc voltage 20V, untransferable arc electric current 50A；The distance 10-12mm of nozzle and workpiece surface, Slow cooling after the completion of welding；Built-up welding Layer material is：Co 38.5-40%, Ni 0.68-0.95%, B 0.1-0.25%, Ta 0.2-0.6%, Sn 1-3%, Gd 0.12- 0.26%, C 0.05-0.13%, surplus W；
Workpiece surface is polished
To workpiece surface coated with tungsten carbide coating, coating layer thickness about 10-15 microns after workpiece surface polishing；It is being carbonized afterwards The outer covering aluminum oxide coating of tungsten coating, coating layer thickness about 5-10 microns, obtains inlet valve.
A kind of described cylinder cover of automobile engine, inlet valve seat ring chemical element composition are（Percentage by weight）：C: 0.06 ﹪, Si：2 ﹪, Cu：1 ﹪, W：0.8 ﹪, Cr：0.4 ﹪, Ni：0.2 ﹪, Nb：0.2 ﹪, V：0.1 ﹪, Ti：0.07 ﹪, Al： 0.05 ﹪, Mn：0.02 ﹪, Mg：0.02 ﹪, Mo：0.01 ﹪, Ce：0.01 ﹪, surplus are Fe and inevitable impurity.
A kind of described cylinder cover of automobile engine, inlet valve seat ring chemical element composition are（Percentage by weight）：C: 0.07 ﹪, Si：3 ﹪, Cu：2 ﹪, W：0.9 ﹪, Cr：0.5 ﹪, Ni：0.3 ﹪, Nb：0.3 ﹪, V：0.2 ﹪, Ti： 0.08 ﹪, Al：0.06 ﹪, Mn：0.03 ﹪, Mg：0.03 ﹪, Mo：0.02 ﹪, Ce：0.02 ﹪, surplus are Fe and can not The impurity avoided.
A kind of described cylinder cover of automobile engine, inlet valve seat ring chemical element composition are（Percentage by weight）：C: 0.065 ﹪, Si：2.5 ﹪, Cu：1.5 ﹪, W：0.85 ﹪, Cr：0.45 ﹪, Ni：0.25 ﹪, Nb：0.25 ﹪, V：0.15 ﹪, Ti： 0.075 ﹪, Al：0.055 ﹪, Mn：0.025 ﹪, Mg：0.025 ﹪, Mo：0.015 ﹪, Ce：0.015 ﹪, surplus are Fe and can not The impurity avoided.
A kind of described cylinder cover of automobile engine, inlet valve material of main part are：C0.13%, Si3.4%, Mn0.8%, P≤ 0.035%, S≤0.035%, Ti1.2%, Cr 5%, W 3%, Ni2.8%, Co 1%, surplus are Fe and inevitable impurity.
A kind of described cylinder cover of automobile engine, inlet valve material of main part are：C 0.27%, Si 4%, Mn 0.95%, P ≤ 0.035%, S≤0.035%, Ti 1.9%, Cr 7%, W 4%, Ni 3.24%, Co 1.2%, surplus be Fe and inevitably it is miscellaneous Matter.
A kind of described cylinder cover of automobile engine, inlet valve material of main part are：C0.2%, Si 3.7%, Mn 0.9%, P≤ 0.035%, S≤0.035%, Ti 1.5%, Cr 6%, W 3.5%, Ni 3%, Co 1.1%, surplus are Fe and inevitable impurity.
A kind of described Motor Engine Cylinder lid, weld overlay materials are：Co 38.5%, Ni 0.68%, B 0.1%, Ta 0.2%, Sn 1%, Gd 0.12%, C 0.05%, surplus W.
A kind of described Motor Engine Cylinder lid, weld overlay materials are：Co 40%, Ni 0.95%, B 0.25%, Ta 0.6%, Sn 3%, Gd 0.26%, C 0.13%, surplus W.
A kind of described cylinder cover of automobile engine, weld overlay materials are：Co 39%, Ni 0.8%, B 0.2%, Ta 0.4%, Sn 2%, Gd 0.2%, C 0.1%, surplus W.
Foregoing invention content is relative to the beneficial effect of prior art：1）Ferrous alloy material of the present invention can be abundant Meet the intensity requirement of engine valve material of main part；2）Carbo-nitriding heat treatment is carried out to engine valve and improves inlet valve Hardness and intensity, avoid the occurrence of hot spot； 3）By built-up welding handle the engine valve conical surface reach higher wearability with Impact resistance, corresponding fatigue behaviour are also improved；4）By the anti-corrosion, resistance to for engine valve applying coating, improving material High temperature, anti-wear performance.5）Inlet valve seat ring carries out subzero treatment and improves its impact resistance and fatigue behaviour；5）Respectively to suction valve cone Circle and engine valve, which are coated two coatings of coating and cooperated, reaches the effect of small wear extent.
Embodiment
In order to which technical characteristic, purpose and the effect of the present invention is more clearly understood, now describe the present invention's in detail Embodiment.
Embodiment 1
A kind of cylinder cover of automobile engine, cylinder head include for engine charge air inlet door part and with inlet valve portion The inlet valve seat ring that part is engaged,
Inlet valve seat ring chemical element forms（Percentage by weight）：C:0.06 ﹪, Si：2 ﹪, Cu：1 ﹪, W：0.8 ﹪, Cr：0.4 ﹪, Ni：0.2 ﹪, Nb：0.2 ﹪, V：0.1 ﹪, Ti：0.07 ﹪, Al：0.05 ﹪, Mn：0.02 ﹪, Mg：0.02 ﹪, Mo：0.01 ﹪, Ce：0.01 ﹪, surplus are Fe and inevitable impurity；
Suction valve cone coil preparation method：Comprise the following steps：According to aforementioned proportion alloyage, raw material melting, cast, take off After mould, obtained valve retainer base substrate is sent into heating furnace, is warming up to 900 DEG C, 75 DEG C/h of heating rate, is incubated 3 hours, it Water hardening afterwards, base substrate is heated again and is incubated 5 hours at 620 DEG C, comes out of the stove and is air-cooled to room temperature；Base substrate is put into liquid nitrogen at deep cooling Reason 10 minutes, goes back up to room temperature in atmosphere；Base substrate is finely machined afterwards,
Tungsten carbide system coating is coated to the inlet valve seat ring after fine machining；Tungsten carbide based material layer includes（Weight Amount）：80 parts of tungsten carbide, 10 parts of silica, the valve retainer after coating is heated, and is warming up to 600 DEG C, heating rate 200 DEG C/h, be incubated 10 hours, after be air-cooled to room temperature, obtain final inlet valve seat ring,
Manufacture inlet valve concretely comprises the following steps：
According to the elemental constituent of inlet valve material of main part carry out melting, after cast, obtain blank, inlet valve material of main part For：C0.13%, Si3.4%, Mn0.8%, P≤0.035%, S≤0.035%, Ti1.2%, Cr 5%, W 3%, Ni2.8%, Co 1% are remaining Measure as Fe and inevitable impurity；
Blank is forged using electric upset forging, final forging temperature is 900 DEG C, and forging deformation amount is controlled in 65%-85%, jumping-up speed For 10mm/s；
Multistage quenching-and-tempering process is carried out after forging：The water quenching after 1050 DEG C of insulation 10s, 450 DEG C of tempering；Then 980 DEG C insulation 10s after oil quenching, 430 DEG C tempering；Oil quenching after last 950 DEG C of insulations 10s, 380 DEG C of tempering；
Carried out after heat treatment to workpiece machining,
Carbo-nitriding heat treatment is carried out to workpiece surface after machining, oozes process by force：950-980 DEG C of scope of temperature, carbon Gesture and nitrogen gesture take level Four step, carbon potential 0.4-0.6%, nitrogen gesture 1.2-1.4%, are incubated 3h, then rise carbon potential to 0.7-0.9%, Nitrogen gesture is reduced to 1.0-1.1%, insulation 2h, then raises carbon potential to 1.0-1.1%, nitrogen gesture is reduced to 0.7-0.9%, is incubated 2h, finally Carbon potential is raised to 1.2-1.6%, nitrogen gesture is reduced to 0.4-0.5%, is incubated 2.5h；It is diffused after oozing by force, diffusion process：Control stove Temperature is down to 900-920 DEG C, is incubated 3h, is cooled to 820-850 DEG C, is incubated 4h, diffusion process carbon-potential control 1.2~1.3% it Between, nitrogen potential control is between 1.0~1.1%；It is air-cooled to room temperature；Quenched after diffusion, quenching process：Oil is carried out at 850 DEG C Quench, Oil-temperature control is at 70 DEG C；Cleaning process：Component surface oil stain is removed, rinse liquid temperature is controlled at 50 DEG C；Tempering：Carry out Lonneal, control 180 DEG C of furnace temperature, minute time 150-200.
Workpiece conical surface grinding is processed,
Conical surface built-up welding is carried out to workpiece after conical surface grinding processing, conical surface bead-welding technology is：150-200 DEG C of preheating, it is non-diverting Arc voltage 20V, untransferable arc electric current 50A；The distance 10-12mm of nozzle and workpiece surface, Slow cooling after the completion of welding；Built-up welding Layer material is：Co 38.5%, Ni 0.68%, B 0.1%, Ta 0.2%, Sn 1%, Gd 0.12%, C 0.05%, surplus W；
Workpiece surface is polished
To workpiece surface coated with tungsten carbide coating, about 10 microns of coating layer thickness after workpiece surface polishing；Afterwards in tungsten carbide The outer covering aluminum oxide coating of coating, about 5 microns of coating layer thickness, obtains inlet valve.
Embodiment 2
A kind of cylinder cover of automobile engine, cylinder head include for engine charge air inlet door part and with inlet valve portion The inlet valve seat ring that part is engaged,
Inlet valve seat ring chemical element forms（Percentage by weight）：C:0.07 ﹪, Si：3 ﹪, Cu：2 ﹪, W： 0.9 ﹪, Cr：0.5 ﹪, Ni：0.3 ﹪, Nb：0.3 ﹪, V：0.2 ﹪, Ti：0.08 ﹪, Al：0.06 ﹪, Mn： 0.03 ﹪, Mg：0.03 ﹪, Mo：0.02 ﹪, Ce：0.02 ﹪, surplus are Fe and inevitable impurity；
Suction valve cone coil preparation method：Comprise the following steps：According to aforementioned proportion alloyage, raw material melting, cast, take off After mould, obtained valve retainer base substrate is sent into heating furnace, is warming up to 900 DEG C, 75 DEG C/h of heating rate, is incubated 3 hours, it Water hardening afterwards, base substrate is heated again and is incubated 5 hours at 620 DEG C, comes out of the stove and is air-cooled to room temperature；Base substrate is put into liquid nitrogen at deep cooling Reason 10 minutes, goes back up to room temperature in atmosphere；Base substrate is finely machined afterwards,
Tungsten carbide system coating is coated to the inlet valve seat ring after fine machining；Tungsten carbide based material layer includes（Weight Amount）：80 parts of tungsten carbide, 20 parts of silica, the valve retainer after coating is heated, and is warming up to 600 DEG C, heating rate 200 DEG C/h, be incubated 10 hours, after be air-cooled to room temperature, obtain final inlet valve seat ring,
Manufacture inlet valve concretely comprises the following steps：
According to the elemental constituent of inlet valve material of main part carry out melting, after cast, obtain blank, inlet valve material of main part For：C 0.27%, Si 4%, Mn 0.95%, P≤0.035%, S≤0.035%, Ti 1.9%, Cr 7%, W 4%, Ni 3.24%, Co 1.2%, surplus is Fe and inevitable impurity；
Blank is forged using electric upset forging, final forging temperature is 900 DEG C, and forging deformation amount is controlled in 65%-85%, jumping-up speed For 10mm/s；
Multistage quenching-and-tempering process is carried out after forging：The water quenching after 1080 DEG C of insulation 10s, 500 DEG C of tempering；Then Oil quenching after 1010 DEG C of insulation 10s, 440 DEG C of tempering；Oil quenching after last 970 DEG C of insulations 10s, 410 DEG C of tempering；
Carried out after heat treatment to workpiece machining,
Carbo-nitriding heat treatment is carried out to workpiece surface after machining, oozes process by force：950-980 DEG C of scope of temperature, carbon Gesture and nitrogen gesture take level Four step, carbon potential 0.4-0.6%, nitrogen gesture 1.2-1.4%, are incubated 3h, then rise carbon potential to 0.7-0.9%, Nitrogen gesture is reduced to 1.0-1.1%, insulation 2h, then raises carbon potential to 1.0-1.1%, nitrogen gesture is reduced to 0.7-0.9%, is incubated 2h, finally Carbon potential is raised to 1.2-1.6%, nitrogen gesture is reduced to 0.4-0.5%, is incubated 2.5h；It is diffused after oozing by force, diffusion process：Control stove Temperature is down to 900-920 DEG C, is incubated 3h, is cooled to 820-850 DEG C, is incubated 4h, diffusion process carbon-potential control 1.2~1.3% it Between, nitrogen potential control is between 1.0~1.1%；It is air-cooled to room temperature；Quenched after diffusion, quenching process：Oil is carried out at 850 DEG C Quench, Oil-temperature control is at 70 DEG C；Cleaning process：Component surface oil stain is removed, rinse liquid temperature is controlled at 50 DEG C；Tempering：Carry out Lonneal, control 180 DEG C of furnace temperature, minute time 150-200.
Workpiece conical surface grinding is processed,
Conical surface built-up welding is carried out to workpiece after conical surface grinding processing, conical surface bead-welding technology is：150-200 DEG C of preheating, it is non-diverting Arc voltage 20V, untransferable arc electric current 50A；The distance 10-12mm of nozzle and workpiece surface, Slow cooling after the completion of welding；Built-up welding Layer material is：Co 40%, Ni 0.95%, B 0.25%, Ta 0.6%, Sn 3%, Gd 0.26%, C 0.13%, surplus W；
Workpiece surface is polished
To workpiece surface coated with tungsten carbide coating, about 15 microns of coating layer thickness after workpiece surface polishing；Afterwards in tungsten carbide The outer covering aluminum oxide coating of coating, about 10 microns of coating layer thickness, obtains inlet valve.
Embodiment 3
A kind of cylinder cover of automobile engine, cylinder head include for engine charge air inlet door part and with inlet valve portion The inlet valve seat ring that part is engaged,
Inlet valve seat ring chemical element forms（Percentage by weight）：C:0.065 ﹪, Si：2.5 ﹪, Cu：1.5 ﹪, W： 0.85 ﹪, Cr：0.45 ﹪, Ni：0.25 ﹪, Nb：0.25 ﹪, V：0.15 ﹪, Ti：0.075 ﹪, Al：0.055 ﹪, Mn： 0.025 ﹪, Mg：0.025 ﹪, Mo：0.015 ﹪, Ce：0.015 ﹪, surplus are Fe and inevitable impurity；
Suction valve cone coil preparation method：Comprise the following steps：According to aforementioned proportion alloyage, raw material melting, cast, take off After mould, obtained valve retainer base substrate is sent into heating furnace, is warming up to 900 DEG C, 75 DEG C/h of heating rate, is incubated 3 hours, it Water hardening afterwards, base substrate is heated again and is incubated 5 hours at 620 DEG C, comes out of the stove and is air-cooled to room temperature；Base substrate is put into liquid nitrogen at deep cooling Reason 10 minutes, goes back up to room temperature in atmosphere；Base substrate is finely machined afterwards,
Tungsten carbide system coating is coated to the inlet valve seat ring after fine machining；Tungsten carbide based material layer includes（Weight Amount）：80 parts of tungsten carbide, 15 parts of silica, the valve retainer after coating is heated, and is warming up to 600 DEG C, heating rate 200 DEG C/h, be incubated 10 hours, after be air-cooled to room temperature, obtain final inlet valve seat ring,
Manufacture inlet valve concretely comprises the following steps：
According to the elemental constituent of inlet valve material of main part carry out melting, after cast, obtain blank, inlet valve material of main part For：C0.2%, Si 3.7%, Mn 0.9%, P≤0.035%, S≤0.035%, Ti 1.5%, Cr 6%, W 3.5%, Ni 3%, Co 1.1%, surplus is Fe and inevitable impurity；
Blank is forged using electric upset forging, final forging temperature is 900 DEG C, and forging deformation amount is controlled in 65%-85%, jumping-up speed For 10mm/s；
Multistage quenching-and-tempering process is carried out after forging：The water quenching after 1070 DEG C of insulation 10s, 470 DEG C of tempering；Then 990 DEG C insulation 10s after oil quenching, 435 DEG C tempering；Oil quenching after last 960 DEG C of insulations 10s, 390 DEG C of tempering；
Carried out after heat treatment to workpiece machining,
Carbo-nitriding heat treatment is carried out to workpiece surface after machining, oozes process by force：950-980 DEG C of scope of temperature, carbon Gesture and nitrogen gesture take level Four step, carbon potential 0.4-0.6%, nitrogen gesture 1.2-1.4%, are incubated 3h, then rise carbon potential to 0.7-0.9%, Nitrogen gesture is reduced to 1.0-1.1%, insulation 2h, then raises carbon potential to 1.0-1.1%, nitrogen gesture is reduced to 0.7-0.9%, is incubated 2h, finally Carbon potential is raised to 1.2-1.6%, nitrogen gesture is reduced to 0.4-0.5%, is incubated 2.5h；It is diffused after oozing by force, diffusion process：Control stove Temperature is down to 900-920 DEG C, is incubated 3h, is cooled to 820-850 DEG C, is incubated 4h, diffusion process carbon-potential control 1.2~1.3% it Between, nitrogen potential control is between 1.0~1.1%；It is air-cooled to room temperature；Quenched after diffusion, quenching process：Oil is carried out at 850 DEG C Quench, Oil-temperature control is at 70 DEG C；Cleaning process：Component surface oil stain is removed, rinse liquid temperature is controlled at 50 DEG C；Tempering：Carry out Lonneal, control 180 DEG C of furnace temperature, minute time 150-200.
Workpiece conical surface grinding is processed,
Conical surface built-up welding is carried out to workpiece after conical surface grinding processing, conical surface bead-welding technology is：150-200 DEG C of preheating, it is non-diverting Arc voltage 20V, untransferable arc electric current 50A；The distance 10-12mm of nozzle and workpiece surface, Slow cooling after the completion of welding；Built-up welding Layer material is：Co 39%, Ni 0.8%, B 0.2%, Ta 0.4%, Sn 2%, Gd 0.2%, C 0.1%, surplus W；
Workpiece surface is polished
To workpiece surface coated with tungsten carbide coating, about 13 microns of coating layer thickness after workpiece surface polishing；Afterwards in tungsten carbide The outer covering aluminum oxide coating of coating, about 7 microns of coating layer thickness, obtains inlet valve.
Embodiment 4
A kind of cylinder cover of automobile engine, cylinder head include for engine charge air inlet door part and with inlet valve portion The inlet valve seat ring that part is engaged,
Inlet valve seat ring chemical element forms（Percentage by weight）：C:0.062 ﹪, Si：2.3 ﹪, Cu：1.1 ﹪, W： 0.83 ﹪, Cr：0.44 ﹪, Ni：0.22 ﹪, Nb：0.22 ﹪, V：0.11 ﹪, Ti：0.071 ﹪, Al：0.054 ﹪, Mn： 0.023 ﹪, Mg：0.022 ﹪, Mo：0.013 ﹪, Ce：0.011 ﹪, surplus are Fe and inevitable impurity；
Suction valve cone coil preparation method：Comprise the following steps：According to aforementioned proportion alloyage, raw material melting, cast, take off After mould, obtained valve retainer base substrate is sent into heating furnace, is warming up to 900 DEG C, 75 DEG C/h of heating rate, is incubated 3 hours, it Water hardening afterwards, base substrate is heated again and is incubated 5 hours at 620 DEG C, comes out of the stove and is air-cooled to room temperature；Base substrate is put into liquid nitrogen at deep cooling Reason 10 minutes, goes back up to room temperature in atmosphere；Base substrate is finely machined afterwards,
Tungsten carbide system coating is coated to the inlet valve seat ring after fine machining；Tungsten carbide based material layer includes（Weight Amount）：80 parts of tungsten carbide, 12 parts of silica, the valve retainer after coating is heated, and is warming up to 600 DEG C, heating rate 200 DEG C/h, be incubated 10 hours, after be air-cooled to room temperature, obtain final inlet valve seat ring,
Manufacture inlet valve concretely comprises the following steps：
According to the elemental constituent of inlet valve material of main part carry out melting, after cast, obtain blank, inlet valve material of main part For：C0.14%, Si3.5%, Mn0.85%, P≤0.035%, S≤0.035%, Ti 1.3%, Cr 5.3%, W 3.2%, Ni 2.9%, Co 1.05%, surplus are Fe and inevitable impurity；
Blank is forged using electric upset forging, final forging temperature is 900 DEG C, and forging deformation amount is controlled in 65%-85%, jumping-up speed For 10mm/s；
Multistage quenching-and-tempering process is carried out after forging：The water quenching after 1055 DEG C of insulation 10s, 455 DEG C of tempering；Then 985 DEG C insulation 10s after oil quenching, 434 DEG C tempering；Oil quenching after last 953 DEG C of insulations 10s, 382 DEG C of tempering；
Carried out after heat treatment to workpiece machining,
Carbo-nitriding heat treatment is carried out to workpiece surface after machining, oozes process by force：950-980 DEG C of scope of temperature, carbon Gesture and nitrogen gesture take level Four step, carbon potential 0.4-0.6%, nitrogen gesture 1.2-1.4%, are incubated 3h, then rise carbon potential to 0.7-0.9%, Nitrogen gesture is reduced to 1.0-1.1%, insulation 2h, then raises carbon potential to 1.0-1.1%, nitrogen gesture is reduced to 0.7-0.9%, is incubated 2h, finally Carbon potential is raised to 1.2-1.6%, nitrogen gesture is reduced to 0.4-0.5%, is incubated 2.5h；It is diffused after oozing by force, diffusion process：Control stove Temperature is down to 900-920 DEG C, is incubated 3h, is cooled to 820-850 DEG C, is incubated 4h, diffusion process carbon-potential control 1.2~1.3% it Between, nitrogen potential control is between 1.0~1.1%；It is air-cooled to room temperature；Quenched after diffusion, quenching process：Oil is carried out at 850 DEG C Quench, Oil-temperature control is at 70 DEG C；Cleaning process：Component surface oil stain is removed, rinse liquid temperature is controlled at 50 DEG C；Tempering：Carry out Lonneal, control 180 DEG C of furnace temperature, minute time 150-200.
Workpiece conical surface grinding is processed,
Conical surface built-up welding is carried out to workpiece after conical surface grinding processing, conical surface bead-welding technology is：150-200 DEG C of preheating, it is non-diverting Arc voltage 20V, untransferable arc electric current 50A；The distance 10-12mm of nozzle and workpiece surface, Slow cooling after the completion of welding；Built-up welding Layer material is：Co 38.7%, Ni 0.7%, B 0.13%, Ta 0.25%, Sn 1.2%, Gd 0.15%, C 0.06%, surplus W；
Workpiece surface is polished
To workpiece surface coated with tungsten carbide coating, about 11 microns of coating layer thickness after workpiece surface polishing；Afterwards in tungsten carbide The outer covering aluminum oxide coating of coating, about 6 microns of coating layer thickness, obtains inlet valve.
Embodiment 5
A kind of cylinder cover of automobile engine, cylinder head include for engine charge air inlet door part and with inlet valve portion The inlet valve seat ring that part is engaged,
Inlet valve seat ring chemical element forms（Percentage by weight）：C:0.067 ﹪, Si：2.8 ﹪, Cu：1.9 ﹪, W： 0.87 ﹪, Cr：0.46 ﹪, Ni：0.27 ﹪, Nb：0.28 ﹪, V：0.19 ﹪, Ti：0.079 ﹪, Al：0.058 ﹪, Mn： 0.028 ﹪, Mg：0.027 ﹪, Mo：0.018 ﹪, Ce：0.017 ﹪, surplus are Fe and inevitable impurity；
Suction valve cone coil preparation method：Comprise the following steps：According to aforementioned proportion alloyage, raw material melting, cast, take off After mould, obtained valve retainer base substrate is sent into heating furnace, is warming up to 900 DEG C, 75 DEG C/h of heating rate, is incubated 3 hours, it Water hardening afterwards, base substrate is heated again and is incubated 5 hours at 620 DEG C, comes out of the stove and is air-cooled to room temperature；Base substrate is put into liquid nitrogen at deep cooling Reason 10 minutes, goes back up to room temperature in atmosphere；Base substrate is finely machined afterwards,
Tungsten carbide system coating is coated to the inlet valve seat ring after fine machining；Tungsten carbide based material layer includes（Weight Amount）：80 parts of tungsten carbide, 18 parts of silica, the valve retainer after coating is heated, and is warming up to 600 DEG C, heating rate 200 DEG C/h, be incubated 10 hours, after be air-cooled to room temperature, obtain final inlet valve seat ring,
Manufacture inlet valve concretely comprises the following steps：
According to the elemental constituent of inlet valve material of main part carry out melting, after cast, obtain blank, inlet valve material of main part For：C0.25%, Si 3.9%, Mn0.93%, P≤0.035%, S≤0.035%, Ti1.8%, Cr 6.7%, W 3.7%, Ni 3.1%, Co 1.17%, surplus are Fe and inevitable impurity；
Blank is forged using electric upset forging, final forging temperature is 900 DEG C, and forging deformation amount is controlled in 65%-85%, jumping-up speed For 10mm/s；
Multistage quenching-and-tempering process is carried out after forging：The water quenching after 1075 DEG C of insulation 10s, 490 DEG C of tempering；Then 1005 DEG C insulation 10s after oil quenching, 438 DEG C tempering；Oil quenching after last 965 DEG C of insulations 10s, 400 DEG C of tempering；
Carried out after heat treatment to workpiece machining,
Carbo-nitriding heat treatment is carried out to workpiece surface after machining, oozes process by force：950-980 DEG C of scope of temperature, carbon Gesture and nitrogen gesture take level Four step, carbon potential 0.4-0.6%, nitrogen gesture 1.2-1.4%, are incubated 3h, then rise carbon potential to 0.7-0.9%, Nitrogen gesture is reduced to 1.0-1.1%, insulation 2h, then raises carbon potential to 1.0-1.1%, nitrogen gesture is reduced to 0.7-0.9%, is incubated 2h, finally Carbon potential is raised to 1.2-1.6%, nitrogen gesture is reduced to 0.4-0.5%, is incubated 2.5h；It is diffused after oozing by force, diffusion process：Control stove Temperature is down to 900-920 DEG C, is incubated 3h, is cooled to 820-850 DEG C, is incubated 4h, diffusion process carbon-potential control 1.2~1.3% it Between, nitrogen potential control is between 1.0~1.1%；It is air-cooled to room temperature；Quenched after diffusion, quenching process：Oil is carried out at 850 DEG C Quench, Oil-temperature control is at 70 DEG C；Cleaning process：Component surface oil stain is removed, rinse liquid temperature is controlled at 50 DEG C；Tempering：Carry out Lonneal, control 180 DEG C of furnace temperature, minute time 150-200.
Workpiece conical surface grinding is processed,
Conical surface built-up welding is carried out to workpiece after conical surface grinding processing, conical surface bead-welding technology is：150-200 DEG C of preheating, it is non-diverting Arc voltage 20V, untransferable arc electric current 50A；The distance 10-12mm of nozzle and workpiece surface, Slow cooling after the completion of welding；Built-up welding Layer material is：Co 39.3%, Ni 0.92%, B 0.23%, Ta 0.55%, Sn 2.7%, Gd 0.24%, C 0.11%, surplus W；
Workpiece surface is polished
To workpiece surface coated with tungsten carbide coating, about 14 microns of coating layer thickness after workpiece surface polishing；Afterwards in tungsten carbide The outer covering aluminum oxide coating of coating, about 9 microns of coating layer thickness, obtains inlet valve.

Claims (1)

1. a kind of cylinder cover of automobile engine, cylinder head include for engine charge air inlet door part and with air inlet door part The inlet valve seat ring being engaged,
Inlet valve seat ring chemical element composition is weight percentage：C:0.07 ﹪, Si：3 ﹪, Cu：2 ﹪, W：0.9 ﹪, Cr： 0.5 ﹪, Ni：0.3 ﹪, Nb：0.3 ﹪, V：0.2 ﹪, Ti：0.08 ﹪, Al：0.06 ﹪, Mn：0.03 ﹪, Mg： 0.03 ﹪, Mo：0.02 ﹪, Ce：0.02 ﹪, surplus are Fe and inevitable impurity,
Suction valve cone coil preparation method：Comprise the following steps：According to aforementioned proportion alloyage, raw material melting, cast, the demoulding Afterwards, the valve retainer base substrate obtained is sent into heating furnace, is warming up to 900 DEG C, 75 DEG C/h of heating rate, is incubated 3 hours, afterwards Water hardening, base substrate is heated again and is incubated 5 hours at 620 DEG C, comes out of the stove and is air-cooled to room temperature；Base substrate is put into subzero treatment in liquid nitrogen 10 minutes, room temperature was gone back up in atmosphere；Base substrate is finely machined afterwards,
Tungsten carbide system coating is coated to the inlet valve seat ring after fine machining；Tungsten carbide based material layer includes weight：Carbon Change 80 parts of tungsten, silica 10-20 parts, the valve retainer after coating is heated, be warming up to 600 DEG C, 200 DEG C of heating rate/ Hour, be incubated 10 hours, after be air-cooled to room temperature, obtain final inlet valve seat ring,
Manufacture inlet valve concretely comprises the following steps：
According to the elemental constituent of inlet valve material of main part carry out melting, after cast, obtain blank, inlet valve material of main part is： C0.13-0.27%, Si3.4-4%, Mn0.8-0.95%, P≤0.035%, S≤0.035%, Ti1.2-1.9%, Cr 5-7%, W 3- 4%, Ni2.8-3.24%, Co 1-1.2%, surplus are Fe and inevitable impurity；
Blank is forged using electric upset forging, final forging temperature is 900 DEG C, and the control of forging deformation amount is in 65%-85%, jumping-up speed 10mm/s；
Multistage quenching-and-tempering process is carried out after forging：The water quenching after 1050-1080 DEG C of insulation 10s, 450-500 DEG C of tempering；So Oil quenching after 980-1010 DEG C of insulation 10s afterwards, 430-440 DEG C of tempering；Oil quenching after last 950-970 DEG C of insulation 10s, 380-410 DEG C Tempering；
Carried out after heat treatment to workpiece machining,
Carbo-nitriding heat treatment is carried out to workpiece surface after machining, oozes process by force：950-980 DEG C of scope of temperature, carbon potential and Nitrogen gesture takes level Four step, carbon potential 0.4-0.6%, nitrogen gesture 1.2-1.4%, is incubated 3h, then raises carbon potential to 0.7-0.9%, reduces Nitrogen gesture is to 1.0-1.1%, insulation 2h, then raises carbon potential to 1.0-1.1%, reduces nitrogen gesture to 0.7-0.9%, is incubated 2h, finally raises Carbon potential reduces nitrogen gesture to 0.4-0.5%, is incubated 2.5h to 1.2-1.6%；It is diffused after oozing by force, diffusion process：Control furnace temperature Be down to 900-920 DEG C, be incubated 3h, be cooled to 820-850 DEG C, be incubated 4h, diffusion process carbon-potential control between 1.2~1.3%, Nitrogen potential control is between 1.0~1.1%；It is air-cooled to room temperature；Quenched after diffusion, quenching process：Oil quenching, oil are carried out at 850 DEG C Temperature control system is at 70 DEG C；Cleaning process：Component surface oil stain is removed, rinse liquid temperature is controlled at 50 DEG C；Tempering：Low temperature is carried out to return Fire, 180 DEG C of furnace temperature of control, minute time 150-200,
Workpiece conical surface grinding is processed,
Conical surface built-up welding is carried out to workpiece after conical surface grinding processing, conical surface bead-welding technology is：150-200 DEG C of preheating, untransferable arc electricity Press 20V, untransferable arc electric current 50A；The distance 10-12mm of nozzle and workpiece surface, Slow cooling after the completion of welding；Overlay cladding material Expect be：Co 38.5%, Ni 0.68%, B 0.1%, Ta 0.2%, Sn 1%, Gd 0.12%, C 0.05%, surplus W
Workpiece surface is polished,
To workpiece surface coated with tungsten carbide coating, coating layer thickness 10-15 microns after workpiece surface polishing；Afterwards in tungsten carbide coating Outer covering aluminum oxide coating, coating layer thickness 5-10 microns, obtains inlet valve.
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