CN104789042A - UV-aging-resistant metal ink and preparation method thereof - Google Patents
UV-aging-resistant metal ink and preparation method thereof Download PDFInfo
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- CN104789042A CN104789042A CN201510210921.5A CN201510210921A CN104789042A CN 104789042 A CN104789042 A CN 104789042A CN 201510210921 A CN201510210921 A CN 201510210921A CN 104789042 A CN104789042 A CN 104789042A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/108—Hydrocarbon resins
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention belongs to the technical field of inks, and particularly relates to a UV-aging-resistant metal ink and a preparation method thereof. The UV-aging-resistant metal ink is prepared from the following raw materials in parts by weight: 10-20 parts of water-based polyurethane resin, 20-30 parts of chlorinated polypropylene resin, 30-50 parts of water-based acrylic resin, 5-20 parts of soybean oil, 15-25 parts of metal pigment, 5-15 parts of ethanol, 1-5 parts of chitosan-graphene composite material, 1-5 parts of assistant, 1-5 parts of hollow glass microsphere and 1-2 parts of nano titanium dioxide. The raw materials are compatible, and the UV-aging-resistant metal ink has favorable UV aging resistance.
Description
Technical field
The present invention relates to technical field of ink, particularly relate to aging metal ink of a kind of uv-resistant and preparation method thereof.
Background technology
Metal ink refers to, with the ink of metallic pigment preparation, have the gloss of metal, and namely gold ink in general, silver-colored ink are this kind of ink.Pigment mainly bronze and the silver powder (copper powder and aluminium powder) of metal ink, also can add other pigment of people to produce the ink with particular color, be referred to as coloring metal ink.Copper powder easily turns black in reaction of Salmon-Saxl time acid with wherein containing trace at low-melting ink vehicle; Sulphur effect after printing and in air also can slowly tarnish, and therefore, Jin Mo also can adopt aluminium powder to add dyestuff to do pigment, and just gloss is slightly poor.
Along with the continuous progress of people's living standard, require constantly to promote to the uv-resistant aging resistance of metal ink itself, therefore the aging performance need that waits of the uv-resistant of existing metal ink improves.
Summary of the invention
The object of the invention is to provide for the deficiencies in the prior art the metal ink that a kind of uv-resistant aging resistance is good.
Another object of the present invention is the preparation method providing the metal ink that a kind of uv-resistant is aging for the deficiencies in the prior art.
The present invention is achieved through the following technical solutions.
The metal ink that uv-resistant is aging, it comprises the raw material of following weight part: waterborne polyurethane resin 10-20 part, chlorinated polypropylene 20-30 part, water-borne acrylic resin 30-50 part, soybean oil 5-20 part, metallic pigment 15-25 part, ethanol 5-15 part, chitosan-graphene composite material 1-5 part, auxiliary agent 1-5 part, hollow glass micropearl 1-5 part, nano titanium oxide 1-2 part.Metallic pigment are any one or two or more mixtures in bronze, silver powder, aluminium powder, copper powder, zinc powder and Stainless Steel Powder.
Particularly, it comprises the raw material of following weight part: waterborne polyurethane resin 10-15 part, chlorinated polypropylene 26-30 part, water-borne acrylic resin 30-40 part, soybean oil 13-20 part, metallic pigment 15-20 part, ethanol 5-10 part, chitosan-graphene composite material 1-3 part, auxiliary agent 4-5 part, hollow glass micropearl 1-3 part, nano titanium oxide 1-2 part.
Particularly, it comprises the raw material of following weight part: waterborne polyurethane resin 16-20 part, chlorinated polypropylene 20-25 part, water-borne acrylic resin 41-50 part, soybean oil 5-12 part, metallic pigment 21-25 part, ethanol 11-15 part, chitosan-graphene composite material 4-5 part, auxiliary agent 1-3 part, hollow glass micropearl 4-5 part, nano titanium oxide 1-2 part.
Particularly, it comprises the raw material of following weight part: waterborne polyurethane resin 13-18 part, chlorinated polypropylene 23-27 part, water-borne acrylic resin 36-43 part, soybean oil 9-15 part, metallic pigment 18-22 part, ethanol 9-12 part, chitosan-graphene composite material 2-3 part, auxiliary agent 2-3 part, hollow glass micropearl 2-3 part, nano titanium oxide 1-2 part.
Particularly, it also comprises dextrin 1-3 weight part.Dextrin has good mobility, stronger adhesive capacity and adsorptive power, can permeate, act synergistically with other raw material, improve the physicals of metal ink in raw material, improves the stability of metal ink.
Particularly, auxiliary agent comprises defoamer, tensio-active agent, silicon wax emulsion.Defoamer is silicone antifoam agent or natural fats and oils; Tensio-active agent is silicon system tensio-active agent or fluorine system tensio-active agent.
The preparation method of the metal ink that a kind of uv-resistant is aging, preparation process is as follows: by above-mentioned weight part, first nano titanium oxide is mixed with ethanol, add waterborne polyurethane resin, chlorinated polypropylene, water-borne acrylic resin under whipped state, after mixing, dispersion, grinding, add chitosan-graphene composite material, ultrasonic grinding 30-40 minute, add all the other raw materials, after stirring, obtain the metal ink that uv-resistant is aging.
the present invention has following beneficial effect:the metal ink that uv-resistant of the present invention is aging, has the following advantages: glycan-graphene composite material has larger specific surface area, has the synergy of enhancing between chitosan and Graphene; The effect of nano titanium oxide shielding ultraviolet rays is strong, has good dispersiveness and weathering resistance, prevents ultraviolet infringement; Chitosan-graphene composite material and hollow glass micropearl, nano titanium oxide act synergistically and effectively delay ultraviolet ageing.The each raw material of the present invention reaches the object of mutual tolerance, and uv-resistant aging resistance is good.
Embodiment
Below in conjunction with embodiment, the present invention is described in detail.
embodiment 1.
The metal ink that uv-resistant is aging, it comprises the raw material of following weight part: waterborne polyurethane resin 10 parts, chlorinated polypropylene 26 parts, water-borne acrylic resin 40 parts, soybean oil 20 parts, metallic pigment 15 parts, ethanol 5 parts, chitosan-graphene composite material 3 parts, auxiliary agent 5 parts, hollow glass micropearl 1 part, nano titanium oxide 2 parts.Metallic pigment are bronze, and auxiliary agent comprises defoamer 3 parts, 1 part, tensio-active agent, silicon wax emulsion 1 part.Defoamer is silicone antifoam agent (as organic silicon modified by polyether) or natural fats and oils; Tensio-active agent is silicon system tensio-active agent or fluorine system tensio-active agent.
The preparation method of the metal ink that a kind of uv-resistant is aging, preparation process is as follows: by above-mentioned weight part, first nano titanium oxide is mixed with ethanol, add waterborne polyurethane resin, chlorinated polypropylene, water-borne acrylic resin under whipped state, after mixing, dispersion, grinding, add chitosan-graphene composite material, ultrasonic grinding 30 minutes, adds all the other raw materials, after stirring, obtain the metal ink that uv-resistant is aging.
embodiment 2.
The difference of the present embodiment and embodiment 1 is: the metal ink that a kind of uv-resistant is aging, and it comprises the raw material of following weight part: waterborne polyurethane resin 15 parts, chlorinated polypropylene 30 parts, water-borne acrylic resin 30 parts, soybean oil 13 parts, metallic pigment 20 parts, ethanol 5 parts, chitosan-graphene composite material 3 parts, auxiliary agent 4 parts, hollow glass micropearl 3 parts, nano titanium oxide 1 part.Auxiliary agent comprises defoamer 1 part, 2 parts, tensio-active agent, silicon wax emulsion 1 part.Metallic pigment are silver powder, and defoamer is silicone antifoam agent (as organic silicon modified by polyether); Tensio-active agent is silicon system tensio-active agent.
The preparation method of the metal ink that a kind of uv-resistant is aging, preparation process is as follows: by above-mentioned weight part, first nano titanium oxide is mixed with ethanol, add waterborne polyurethane resin, chlorinated polypropylene, water-borne acrylic resin under whipped state, after mixing, dispersion, grinding, add chitosan-graphene composite material, ultrasonic grinding 33 minutes, adds all the other raw materials, after stirring, obtain the metal ink that uv-resistant is aging.
embodiment 3.
The difference of the present embodiment and embodiment 1 is: the metal ink that a kind of uv-resistant is aging, and it comprises the raw material of following weight part: waterborne polyurethane resin 16 parts, chlorinated polypropylene 25 parts, water-borne acrylic resin 41 parts, soybean oil 12 parts, metallic pigment 21 parts, ethanol 15 parts, chitosan-graphene composite material 4 parts, auxiliary agent 3 parts, hollow glass micropearl 4 parts, nano titanium oxide 2 parts.Auxiliary agent comprises defoamer 1 part, 1 part, tensio-active agent, silicon wax emulsion 1 part.Metallic pigment comprise aluminium powder 7 parts, bronze 7 parts, 7 parts, silver powder, and defoamer is natural fats and oils; Tensio-active agent is fluorine system tensio-active agent.
The preparation method of the metal ink that a kind of uv-resistant is aging, preparation process is as follows: by above-mentioned weight part, first nano titanium oxide is mixed with ethanol, add waterborne polyurethane resin, chlorinated polypropylene, water-borne acrylic resin under whipped state, after mixing, dispersion, grinding, add chitosan-graphene composite material, ultrasonic grinding 36 minutes, adds all the other raw materials, after stirring, obtain the metal ink that uv-resistant is aging.
embodiment 4.
The difference of the present embodiment and embodiment 1 is: the metal ink that a kind of uv-resistant is aging, and it comprises the raw material of following weight part: waterborne polyurethane resin 20 parts, chlorinated polypropylene 20 parts, water-borne acrylic resin 50 parts, soybean oil 5 parts, metallic pigment 25 parts, ethanol 11 parts, chitosan-graphene composite material 5 parts, auxiliary agent 1 part, hollow glass micropearl 5 parts, nano titanium oxide 1 part.Metallic pigment are copper powder, and auxiliary agent comprises defoamer 0.1 part, 0.2 part, tensio-active agent, silicon wax emulsion 0.7 part.
The preparation method of the metal ink that a kind of uv-resistant is aging, preparation process is as follows: by above-mentioned weight part, first nano titanium oxide is mixed with ethanol, add waterborne polyurethane resin, chlorinated polypropylene, water-borne acrylic resin under whipped state, after mixing, dispersion, grinding, add chitosan-graphene composite material, ultrasonic grinding 38 minutes, adds all the other raw materials, after stirring, obtain the metal ink that uv-resistant is aging.
embodiment 5.
The difference of the present embodiment and embodiment 1 is: the metal ink that a kind of uv-resistant is aging, and it comprises the raw material of following weight part: waterborne polyurethane resin 13 parts, chlorinated polypropylene 27 parts, water-borne acrylic resin 36 parts, soybean oil 15 parts, metallic pigment 18 parts, ethanol 12 parts, chitosan-graphene composite material 2 parts, auxiliary agent 3 parts, hollow glass micropearl 2 parts, nano titanium oxide 2 parts, dextrin 1 weight part.Auxiliary agent comprises defoamer 0.5 part, 1 part, tensio-active agent, silicon wax emulsion 1.5 parts.
The preparation method of the metal ink that a kind of uv-resistant is aging, preparation process is as follows: by above-mentioned weight part, first nano titanium oxide is mixed with ethanol, add waterborne polyurethane resin, chlorinated polypropylene, water-borne acrylic resin under whipped state, after mixing, dispersion, grinding, add chitosan-graphene composite material, ultrasonic grinding 40 minutes, adds all the other raw materials, after stirring, obtain the metal ink that uv-resistant is aging.
The metal ink that uv-resistant prepared by Application Example 1-5 is aging carries out performance measurement, as table 1.
Table 1
Finally should be noted that; above embodiment is only in order to illustrate technical scheme of the present invention; but not limiting the scope of the invention; although done to explain to the present invention with reference to preferred embodiment; those of ordinary skill in the art is to be understood that; can modify to technical scheme of the present invention or equivalent replacement, and not depart from essence and the scope of technical solution of the present invention.
Claims (7)
1. the metal ink that a uv-resistant is aging, it is characterized in that, it comprises the raw material of following weight part: waterborne polyurethane resin 10-20 part, chlorinated polypropylene 20-30 part, water-borne acrylic resin 30-50 part, soybean oil 5-20 part, metallic pigment 15-25 part, ethanol 5-15 part, chitosan-graphene composite material 1-5 part, auxiliary agent 1-5 part, hollow glass micropearl 1-5 part, nano titanium oxide 1-2 part.
2. the metal ink that uv-resistant according to claim 1 is aging, it is characterized in that, it comprises the raw material of following weight part: waterborne polyurethane resin 10-15 part, chlorinated polypropylene 26-30 part, water-borne acrylic resin 30-40 part, soybean oil 13-20 part, metallic pigment 15-20 part, ethanol 5-10 part, chitosan-graphene composite material 1-3 part, auxiliary agent 4-5 part, hollow glass micropearl 1-3 part, nano titanium oxide 1-2 part.
3. the metal ink that uv-resistant according to claim 1 is aging, it is characterized in that, it comprises the raw material of following weight part: waterborne polyurethane resin 16-20 part, chlorinated polypropylene 20-25 part, water-borne acrylic resin 41-50 part, soybean oil 5-12 part, metallic pigment 21-25 part, ethanol 11-15 part, chitosan-graphene composite material 4-5 part, auxiliary agent 1-3 part, hollow glass micropearl 4-5 part, nano titanium oxide 1-2 part.
4. the metal ink that uv-resistant according to claim 1 is aging, it is characterized in that, it comprises the raw material of following weight part: waterborne polyurethane resin 13-18 part, chlorinated polypropylene 23-27 part, water-borne acrylic resin 36-43 part, soybean oil 9-15 part, metallic pigment 18-22 part, ethanol 9-12 part, chitosan-graphene composite material 2-3 part, auxiliary agent 2-3 part, hollow glass micropearl 2-3 part, nano titanium oxide 1-2 part.
5. the metal ink that uv-resistant according to claim 1 is aging, is characterized in that, it also comprises dextrin 1-3 weight part.
6. the metal ink that uv-resistant according to claim 1 is aging, is characterized in that, auxiliary agent comprises defoamer, tensio-active agent, silicon wax emulsion.
7. the preparation method of the metal ink that the uv-resistant of claim 1 to 6 any one is aging, it is characterized in that, preparation process is as follows: by above-mentioned weight part, first nano titanium oxide is mixed with ethanol, waterborne polyurethane resin, chlorinated polypropylene, water-borne acrylic resin is added under whipped state, after mixing, dispersion, grinding, add chitosan-graphene composite material, ultrasonic grinding 30-40 minute, add all the other raw materials, after stirring, obtain the metal ink that uv-resistant is aging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510210921.5A CN104789042A (en) | 2015-04-29 | 2015-04-29 | UV-aging-resistant metal ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510210921.5A CN104789042A (en) | 2015-04-29 | 2015-04-29 | UV-aging-resistant metal ink and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN104789042A true CN104789042A (en) | 2015-07-22 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510210921.5A Pending CN104789042A (en) | 2015-04-29 | 2015-04-29 | UV-aging-resistant metal ink and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107793824A (en) * | 2017-11-28 | 2018-03-13 | 蚌埠昆仑彩印包装有限公司 | A kind of environmental printing ink and preparation method thereof |
| CN107793827A (en) * | 2017-11-28 | 2018-03-13 | 蚌埠昆仑彩印包装有限公司 | A kind of waterproof printing-ink and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102093781A (en) * | 2011-01-27 | 2011-06-15 | 广东天龙油墨集团股份有限公司 | Aqueous metal ink and preparation method thereof |
-
2015
- 2015-04-29 CN CN201510210921.5A patent/CN104789042A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102093781A (en) * | 2011-01-27 | 2011-06-15 | 广东天龙油墨集团股份有限公司 | Aqueous metal ink and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 任红轩等: "《纳米科技产品及应用—纳米产业揭秘》", 31 January 2010 * |
| 吴绍祖等: "《实用精细化工》", 31 January 1993 * |
| 陈建光: "壳聚糖/氧化石墨烯复合材料结构和性能研究", 《重庆电子工程职业学院学报》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107793824A (en) * | 2017-11-28 | 2018-03-13 | 蚌埠昆仑彩印包装有限公司 | A kind of environmental printing ink and preparation method thereof |
| CN107793827A (en) * | 2017-11-28 | 2018-03-13 | 蚌埠昆仑彩印包装有限公司 | A kind of waterproof printing-ink and preparation method thereof |
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