CN104787988B - Intelligent sewage treatment unit and the method processing sewage - Google Patents

Intelligent sewage treatment unit and the method processing sewage Download PDF

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Publication number
CN104787988B
CN104787988B CN201510203298.0A CN201510203298A CN104787988B CN 104787988 B CN104787988 B CN 104787988B CN 201510203298 A CN201510203298 A CN 201510203298A CN 104787988 B CN104787988 B CN 104787988B
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oxidation reactor
sewage
contact oxidation
performance bio
bio contact
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CN104787988A (en
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杨帆
和朋
李军
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Yang Fan
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Zhejiang Bo Ya Environmental Protection Equipment Co Ltd
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Abstract

The invention provides a kind of intelligent sewage treatment unit and the method processing sewage. Device includes: pretreatment system, high-performance bio contact oxidation reactor, settling tank and advanced treatment system; High-energy physics oxidation reactor it is provided with in pretreatment system; It is provided with chelated surface iron ion in high-performance bio contact oxidation reactor and is coated with biomembranous carrier material; Advanced treatment system includes electrolysis unit and high-energy physics oxidation reactor; Pretreatment system, high-performance bio contact oxidation reactor, settling tank, advanced treatment system sequentially connect. A kind of method processing sewage: carry out direct oxidation process with high-energy physics oxidation reactor in pretreatment system; Carrier material and microbial decomposition Organic substance; Settling tank retains activated sludge and carrier material; Advanced treatment system carries out direct oxidation process; Detect rear discharge up to standard. Use the intelligent sewage treatment unit that the application provides and the method processing sewage, it is possible to efficiently, the process sewage of low cost.

Description

Intelligent sewage treatment unit and the method processing sewage
Technical field
The present invention relates to sewage treatment area, in particular to a kind of method of intelligent sewage treatment unit and process sewage.
Background technology
In recent years, along with the high development of China's economy, people's environmental consciousness improves constantly, and many small towns start to build sewage treatment plant.
Present sewage treatment unit, including sewage treatment unit body and cistern, and it is arranged on intrinsic first sedimentation tank of sewage treatment unit, and it is arranged on the intrinsic anaerobic pond of sewage treatment unit, and it is arranged on the intrinsic anoxic pond of sewage treatment unit, and it is arranged on the intrinsic Aerobic Pond of sewage treatment unit, and it is arranged on intrinsic second sedimentation tank of sewage treatment unit, and it is arranged on the intrinsic Filtration Adsorption storehouse of sewage treatment unit, and it is arranged on the intrinsic sterilization pool of sewage treatment unit, anaerobic pond, it is equipped with biologic packing material in anoxic pond and Aerobic Pond, sterilization pool inner bottom part is provided with apparatus for ultraviolet disinfection.
But, due to small towns sewage disposal small scale, water quality, the water yield change greatly, and alternative applicable technology is few. Town government ability to shoulder economically is weak, maintenance management technical staff's operational management experience famine, therefore small towns does not adopt the process technique adapted mostly, but adopts and indiscriminately imitate large and medium-sized scale urban sewage treatment process and design parameter, causes construction investment and operating cost too high.
In view of this, the special proposition present invention.
Summary of the invention
The first object of the present invention is in that to provide a kind of intelligent sewage treatment unit, and described intelligent sewage treatment unit has that strong adaptability, attended operation be simple, stable effluent quality, the advantages such as installation cost is low, running cost is few.
The second object of the present invention is in that to provide a kind of method processing sewage, and the method has that waste water processes is short, efficiency advantages of higher.
In order to realize the above-mentioned purpose of the present invention, spy by the following technical solutions:
A kind of intelligent sewage treatment unit, including: pretreatment system, high-performance bio contact oxidation reactor, settling tank and advanced treatment system;
The high-energy physics oxidation reactor launching gamma ray it is provided with in described pretreatment system;
Being provided with carrier material in described high-performance bio contact oxidation reactor, described surfaces of carrier materials is chelated with iron ion, and described carrier material is also wrapped on the biomembrane for retaining activated sludge and larger molecular organics; The bacterium solution containing aerobic microbiological, facultative biological flora, obligate anaerobe is added in described high-performance bio contact oxidation reactor;
Described settling tank retains the activated sludge and carrier material that come off in described high-performance bio contact oxidation reactor by action of gravity;
Described advanced treatment system includes electrolysis unit and described high-energy physics oxidation reactor;
Described pretreatment system, described high-performance bio contact oxidation reactor, described settling tank, described advanced treatment system sequentially connect.
Pretreatment system adopts the Technology of high-energy physics direct oxidation, and treatment effeciency is high, high treating effect, it is possible to effectively kill bacterial virus; Membrane separation technique is organically combined by high-performance bio contact oxidation reactor with biotechnology, it utilizes biomembrane the amount of activated mud in biodegradability regulating reservoir and larger molecular organics to be retained, the application of the carrier material of high-specific surface area replaces the second pond in activated sludge process, carry out solid-liquid separation, be effectively accomplished the purpose of mud-water separation. Carrier material in high-performance bio contact oxidation reactor has done innovation research, grafting microcell technology on the carrier material of high-specific surface area, the iron ion of biological cotton chelated surface is soaked mutually formed by ferrum carbon, biological cotton, ethanol, described iron ion includes Fe2+ and Fe3+, biooxidation reactions and electrochemistry are combined on the same vector, make the long strand Organic substance of polypeptide by chain rupture open loop, be more suitable for the nitrated decomposition of microorganism; Settling tank retains the activated sludge and carrier material that come off in high-performance bio contact oxidation reactor by action of gravity.
Carrier material is biological cotton, amount of activated mud in biodegradability regulating reservoir and larger molecular organics are retained by the biomembrane of biological cotton upper cladding, add the bacterium solution containing aerobic microbiological, facultative biological flora, obligate anaerobe in high-performance bio contact oxidation reactor, actually occur following processing procedure:
First stage Aerobic biological process: aerobic microbiological absorbs the oxygen part in natural air, maintains metabolism, reaches the purpose of oxidation Decomposition. In this elementary reaction, all will be removed for harmful substances such as the ammonia nitrogen in sewage, nitrite, nitrate, thiocyanogens. Aeration pump can also be increased as attachment device according to the needs of practical situation, provide necessary oxygen to device.
Second stage is held concurrently oxygen biological treatment: oxygen biological treatment of holding concurrently is actually according to the biological decomposition mechanism of hydrolysis acidification, by the facultative biological flora cultivated, Organic substance and the chromophoric group of the difficult degradation in sewage is decomposed, is disintegrated, raising biodegradability.
Three phases anaerobic bio-treated: sewage has turned out facultative biological flora at second stage, these organic compound are as electron acceptor, being taken as the biodegradation process of electron donor, Organic substance is converted to the end products based on volatile fatty acid simultaneously.Acidization is dependent on zymogenous bacteria substantial amounts of, diversified and completes, in antibacterial, major part is obligate anaerobe and facultative anaerobe, amphimicrobe is when reactor is subject to the impact of oxygen, energy is oxygen depleted rapidly, keep the lower oxidation reduction potential of sewage, safeguard the service condition of methanogen, sewage is carried out deep oxidation degraded.
Four-stage biological micro-electrolysis aoxidizes: biological micro-electrolysis is dependent on the sequestration iron ion on bio-carrier (biological cotton) surface and has high chemically active H, Fe2+ what the souring stage of water body produced nascent state, make the long chain organic compound chain rupture in water body convert to the intermediate of little strand, improve the biodegradability of water body.
Advanced treatment system ensures the stably reaching standard of effluent quality, by the waste water of advanced treating, can be used for plant irrigation, rinse the reuses such as road surface. Electrolysis unit used in this application is purchased from market.
The cardinal principle of the high-energy physics oxidation reactor in pretreatment system and advanced treatment system is: high energy particle direct oxidation technology is on electrochemical basis, metal electrode is modified, under external electric field, in anodic coating, electronics starts to migrate, and drives particle, ion motion. Charged particle is gathered, and under induction excites, aqueous solution is bombarded, sorts by bunchy, it is thus achieved that the oxidative free radical thing of newborn situation, chloride ion is excited into hypochlorous acid. Pollutant oxidation in water body is decomposed by these oxidizing species. Under extra electric field state, electronics is to cathodic migration, and negative electrode release hydrogen atom is to the pollutant oxidation reduction reaction in water body.
Preferably, described intelligent sewage treatment unit also includes for storing sewage and the regulating reservoir of preliminary treatment sewage, and the outlet of described regulating reservoir connects with the entrance of described pretreatment system.
Sewage can be stored by regulating reservoir, and carries out preliminary process, for instance microbial decomposition, sedimentation etc. so that the handlability of the water body entering follow up device improves. Water pump it is additionally provided with, in order to by sewage transport to pretreatment system in regulating reservoir.
It is further preferred that described intelligent sewage treatment unit also includes the sludge recirculation system for discharging the deposit in described intelligent sewage treatment unit.
In the process processed, all can there is the sedimentation of solids and accumulate in the various piece in intelligent sewage treatment unit, use sludge recirculation system, it is possible to discharged by these deposits, it is to avoid the obstruction of device, it is ensured that plant running is normally, efficiently.
It is further preferred that the outlet of described sludge recirculation system connects with described regulating reservoir.
Sludge recirculation system is connected with regulating reservoir, conveniently deposit is uniformly processed on the one hand, it is to avoid the problem that plant running brings secondary pollution; On the other hand, can the active substance in follow-up various piece be returned in regulating reservoir, strengthen the effect of regulating reservoir preliminary treatment, such as, part microorganism (mainly anaerobic hydrolysis desired microorganisms) in high-performance bio contact oxidation reactor can return to regulating reservoir along with deposit, and this part microorganism can strengthen the preliminary exposition effect occurred in regulating reservoir.
Alternatively, described pretreatment system is provided with the first bed mud outlet, and described first bed mud outlet connects with described sludge recirculation system; Described high-performance bio contact oxidation reactor is provided with the second bed mud outlet, and described second bed mud outlet connects with described sludge recirculation system;Described settling tank is provided with the 3rd bed mud outlet, and described 3rd bed mud outlet connects with described sludge recirculation system.
Various piece is all connected with sludge recirculation system, it is possible to fully ensure that the deposit to whole device processes; Through pretreatment system, high-performance bio contact oxidation reactor, settling tank process, the deposit existed in advanced treatment system can seldom, and advanced treatment system can selectively arrange bed mud outlet.
The outlet of above-mentioned bed mud is all preferably provided at the bottom in the short transverse of various piece, it is simple to deposit gathers under gravity and discharges, and also allows for the cleaning of device.
Preferably, the entrance of described pretreatment system arranges top in its height direction, and the outlet of described pretreatment system arranges low side in its height direction.
So arranging and be advantageous in that, sewage quickly can carry out pretreatment by pretreatment system under gravity, it is also possible to ensures the smoothness of pretreatment system operating. In other implementations, the entrance and exit of pretreatment system can be changed according to practical situation.
It is further preferred that the entrance of described high-performance bio contact oxidation reactor arranges side, lower section in its height direction, the outlet of described high-performance bio contact oxidation reactor arranges upper side in its height direction.
The interior process to sewage of high-performance bio contact oxidation reactor is the core of whole processing procedure, and above-mentioned setting ensure that the sewage time of staying in high-performance bio contact oxidation reactor.
The application is a kind of method processing sewage also, and described method includes the following step being sequentially carried out:
The gamma ray that sewage produces with high-energy physics oxidation reactor in pretreatment system carries out direct oxidation process;
Enter afterwards in high-performance bio contact oxidation reactor, the carrier material in high-performance bio contact oxidation reactor and the microorganism combined effect added in described high-performance bio contact oxidation reactor, decompose the Organic substance in sewage;
The activated sludge and carrier material that come off in described high-performance bio contact oxidation reactor is retained in settling tank;
Sewage processes with electrolysis unit and high-energy physics oxidation reactor in advanced treatment system;
Discharge after detection water body is up to standard.
Larger molecular organics in sewage is carried out pre-oxidation decomposition by pretreatment system, improves the efficiency of subsequent treatment; Sewage is carried out separation fully, resolution process by high-performance bio contact oxidation reactor, and major part pollutant are processed; The activated sludge and carrier material that come off in high-performance bio contact oxidation reactor is retained, it is prevented that aforementioned substances, along with water body flow discharger, causes process not up to standard in settling tank; Advanced treatment system mainly plays sterilizing and ensures the effect of water quality treatment stably reaching standard.
Preferably, the processing procedure in described high-performance bio contact oxidation reactor particularly as follows:
Activated sludge is separated by the biomembrane that the carrier material in high-performance bio contact oxidation reactor is coated with larger molecular organics; Sewage is processed by the aerobic microbiological in addition high-performance bio contact oxidation reactor, facultative biological flora, obligate anaerobe; Under the effect of the iron ion of described surfaces of carrier materials chelating so that the polypeptide long strand Organic substance chain rupture open loop in sewage.
High-performance bio contact oxidation reactor is by the quaternity of activated sludge with bio-contact oxidation, biology aerobic and bio anaerobic, oxidation degradation and electrochemistry, purification of water quality and Treatment of Sludge, and high treating effect, speed are fast.
Alternatively, described method is further comprising the steps of:
Before described pretreatment system processes, sewage carries out sedimentation and anaerobe resolution process in regulating reservoir;
Deposit bottom described pretreatment system, described high-performance bio contact oxidation reactor, described settling tank is returned in described regulating reservoir by sludge recirculation system.
The pretreatment of regulating reservoir ensure that the biochemical treatment of the water body entering follow up device improves, and can reduce the solid pollutant and impurity that enter device, it is to avoid device blocks, the cycle of operation of extension fixture.
Compared with prior art, the invention have the benefit that
(1) strong adaptability, attended operation be simple, stable effluent quality;
(2) cost is low, floor space is little, maintenance cost is low;
(3) the area use that process demand is less it is suitable for.
Accompanying drawing explanation
In order to be illustrated more clearly that the embodiment of the present invention or technical scheme of the prior art, the accompanying drawing used required in embodiment or description of the prior art will be briefly described below.
The schematic diagram of the intelligent sewage treatment unit that Fig. 1 provides for the embodiment of the present application 1.
In figure: 1. pretreatment system; 2. high-performance bio contact oxidation reactor; 3. settling tank; 4. advanced treatment system; 5. sludge recirculation system; 10. the first bed mud outlet; 20. the second bed mud outlet; 30. the 3rd bed mud outlet.
Detailed description of the invention
Below in conjunction with embodiment, embodiment of the present invention are described in detail, it will be appreciated by those skilled in the art that the following example is merely to illustrate the present invention, and are not construed as restriction the scope of the present invention. Unreceipted actual conditions person in embodiment, conventionally the condition of condition or manufacturer's suggestion carries out. Agents useful for same or the unreceipted production firm person of instrument, be and can pass through the commercially available conventional products bought and obtain.
The application is mainly through combining iron ion on biological cotton (carrier material) surface of biomembrane, sequestration and microbial, then under the high energy particle effect that high-energy physics oxidation reactor excites, carry out sterilizing, and then under multiple action, sewage is processed.
Embodiment 1
As it is shown in figure 1, a kind of intelligent sewage treatment unit, including pretreatment system 1, high-performance bio contact oxidation reactor 2, settling tank 3, advanced treatment system 4 and sludge recirculation system 5. With the displaying direction of accompanying drawing 1 for benchmark, the entrance of pretreatment system 1 arranges top in its height direction, and the outlet of pretreatment system 1 arranges low side in its height direction; The entrance of high-performance bio contact oxidation reactor 2 arranges lower left in its height direction, and the outlet of high-performance bio contact oxidation reactor 2 arranges in the middle part of upper right in its height direction; The entrance of settling tank 3 arranges lower left in its height direction, and the outlet of settling tank 3 arranges upper right in its height direction.
In other implementations, the position of the gateway of various piece can change.
Being provided with high-energy physics oxidation reactor in pretreatment system 1, high-energy physics oxidation reactor launches gamma ray mainly by high-energy particle bombardment. More particularly by high energy particle direct oxidation technology (producing a kind of ray by bombarding), sewage is carried out pretreatment, the long-chain cyclic organic materials in water body is made to obtain open loop and chain rupture (macromolecular mass becomes little molecule), to improve the biodegradability (making antibacterial be easier to phagocytosis and digestion) of subsequent bio membrane reactor.
Being provided with carrier material in high-performance bio contact oxidation reactor 2, surfaces of carrier materials is chelated with iron ion, and carrier material is also wrapped on the biomembrane for retaining activated sludge and larger molecular organics; The bacterium solution containing aerobic microbiological, facultative biological flora, obligate anaerobe is added in high-performance bio contact oxidation reactor.
Settling tank 3 is essentially identical with existing settling tank, mainly through action of gravity, the solid such as mud, impurity is retained.
Advanced treatment system 4 uses the electrolysis system that sewage disposal is conventional, it is ensured that the water quality of process excellent and stable.
Pretreatment system 1 is provided with the first bed mud outlet 10, and the first bed mud outlet 10 connects with sludge recirculation system 5; High-performance bio contact oxidation reactor 2 is provided with the second bed mud outlet 20, and the second bed mud outlet 20 connects with sludge recirculation system 5; Settling tank 3 is provided with the 3rd bed mud outlet 30, and the 3rd bed mud outlet 30 connects with sludge recirculation system 5.
Sludge recirculation system 5 is made up of conventional pipeline and valve.
When using said apparatus to process sewage, substantially process is as described below:
First being sent in said apparatus by sewage sewage pump, sewage is carried out pretreatment by the high-energy physics oxidation reactor in pretreatment system 1;
Sewage flows in device, and the activated sludge in sewage is separated by the biomembrane of carrier material cladding with larger molecular organics. what in high-performance bio contact oxidation reactor 2, addition prepared in advance contains the aerobic microbiological (antibacterial that sewage disposal is conventional, actinomycetes, fungus, protozoacide and micro-metazoa etc.) and facultative biological flora, obligate anaerobe (the mainly escherichia coli of enterobacteriaceae, aerobacteria, Bacillus proteus etc.) bacterium solution (bacterium solution is mainly through white sugar, the allotment such as bio-feritlizer and additive forms), rely on the flowing of sewage, various microorganism adsorptions are on the surface of carrier material, aerobic microbiological maintains metabolism, reach the purpose of oxidation Decomposition. in this elementary reaction, all will be removed for harmful substances such as the ammonia nitrogen in sewage, nitrite, nitrate, thiocyanogens,
Organic substance and the chromophoric group of the difficult degradation in sewage are decomposed, disintegrate by the facultative biological flora of second stage, improve biodegradability.
Sewage has turned out facultative biological flora at second stage, and these organic compound, as electron acceptor, are taken as the biodegradation process of electron donor simultaneously, and Organic substance is converted to the end products based on volatile fatty acid. Acidization is dependent on zymogenous bacteria substantial amounts of, diversified and completes, in antibacterial, major part is obligate anaerobe and facultative anaerobe, amphimicrobe is when reactor is subject to the impact of oxygen, energy is oxygen depleted rapidly, keep the lower oxidation reduction potential of sewage, safeguard the service condition of methanogen, sewage is carried out deep oxidation degraded.
The biological micro-electrolysis of four-stage be dependent on the sequestration iron ion on biological carrier materials surface water body souring stage produce nascent state there is high chemically active H, Fe2+, make the long chain organic compound chain rupture in water body convert to the intermediate of little strand, improve the biodegradability of water body. In whole course of reaction, electrochemistry is participating in synergism all the time.
Activated sludge and carrier material is retained in settling tank;
Sewage processes with electrolysis system in advanced treatment system;
Whether the water after finally detection process meets discharging standards, discharge after up to standard.
Embodiment 2
On the basis of embodiment 1, in other preferred embodiment, intelligent sewage treatment unit also includes regulating reservoir (not shown in figure 1). Sludge recirculation system 5 connects with regulating reservoir. Sewage can be stored by regulating reservoir, and carries out preliminary process, for instance microbial decomposition, sedimentation etc. so that the handlability of the water body entering follow up device improves.
Compared with existing several sewage water treatment methods, the application has that floor space is little, expense is low, steady operation and other merits, referring specifically to table 1 below.
Table 1 the application is compared with the prior art
By upper table 1 it can be seen that use the intelligent sewage treatment unit that the application provides and the method processing sewage, it is possible to efficiently, the process sewage of low cost.
The intelligent sewage treatment unit that the application provides, its intelligence degree is high, and maintenance is simple, operation cost is low.
Although illustrate and describing the present invention with specific embodiment, however it will be appreciated that may be made that when without departing substantially from the spirit and scope of the present invention many other change and amendment. It is, therefore, intended that include all such changes and modifications belonging in the scope of the invention in the following claims.

Claims (10)

1. an intelligent sewage treatment unit, it is characterised in that including: pretreatment system, high-performance bio contact oxidation reactor, settling tank and advanced treatment system;
The high-energy physics oxidation reactor launching gamma ray it is provided with in described pretreatment system;
Being provided with carrier material in described high-performance bio contact oxidation reactor, described surfaces of carrier materials is chelated with iron ion, and described carrier material is also wrapped on the biomembrane for retaining activated sludge and larger molecular organics; The bacterium solution containing aerobic microbiological, facultative biological flora, obligate anaerobe is added in described high-performance bio contact oxidation reactor;
Described settling tank retains the activated sludge and carrier material that come off in described high-performance bio contact oxidation reactor by action of gravity;
Described advanced treatment system includes electrolysis unit and described high-energy physics oxidation reactor;
Described pretreatment system, described high-performance bio contact oxidation reactor, described settling tank, described advanced treatment system sequentially connect.
2. intelligent sewage treatment unit according to claim 1, it is characterised in that also including for storing sewage and the regulating reservoir of preliminary treatment sewage, the outlet of described regulating reservoir connects with the entrance of described pretreatment system.
3. intelligent sewage treatment unit according to claim 2, it is characterised in that also include the sludge recirculation system for discharging the deposit in described intelligent sewage treatment unit.
4. intelligent sewage treatment unit according to claim 3, it is characterised in that the outlet of described sludge recirculation system connects with described regulating reservoir.
5. the intelligent sewage treatment unit according to claim 3 or 4, it is characterised in that described pretreatment system is provided with the first bed mud outlet, and described first bed mud outlet connects with described sludge recirculation system; Described high-performance bio contact oxidation reactor is provided with the second bed mud outlet, and described second bed mud outlet connects with described sludge recirculation system; Described settling tank is provided with the 3rd bed mud outlet, and described 3rd bed mud outlet connects with described sludge recirculation system.
6. intelligent sewage treatment unit according to claim 1, it is characterised in that the entrance of described pretreatment system arranges top in its height direction, and the outlet of described pretreatment system arranges low side in its height direction.
7. intelligent sewage treatment unit according to claim 6, it is characterized in that, the entrance of described high-performance bio contact oxidation reactor arranges side, lower section in its height direction, and the outlet of described high-performance bio contact oxidation reactor arranges upper side in its height direction.
8. the method processing sewage, it is characterised in that described method includes the following step being sequentially carried out:
The gamma ray that sewage produces with high-energy physics oxidation reactor in pretreatment system carries out direct oxidation process;
Enter afterwards in high-performance bio contact oxidation reactor, the carrier material in high-performance bio contact oxidation reactor and the microorganism combined effect added in described high-performance bio contact oxidation reactor, decompose the Organic substance in sewage;
The activated sludge and carrier material that come off in described high-performance bio contact oxidation reactor is retained in settling tank;
Sewage processes with electrolysis unit and described high-energy physics oxidation reactor in advanced treatment system;
Discharge after detection water body is up to standard.
9. method according to claim 8, it is characterised in that processing procedure in described high-performance bio contact oxidation reactor particularly as follows:
Activated sludge is separated by the biomembrane that the carrier material in high-performance bio contact oxidation reactor is coated with larger molecular organics; Sewage is processed by the aerobic microbiological in addition high-performance bio contact oxidation reactor, facultative biological flora, obligate anaerobe; Under the effect of the iron ion of described surfaces of carrier materials chelating so that the polypeptide long strand Organic substance chain rupture open loop in sewage.
10. method according to claim 8 or claim 9, it is characterised in that further comprising the steps of:
Before described pretreatment system processes, sewage carries out sedimentation and anaerobe resolution process in regulating reservoir;
Deposit bottom described pretreatment system, described high-performance bio contact oxidation reactor and described settling tank is returned in described regulating reservoir by sludge recirculation system.
CN201510203298.0A 2015-04-27 2015-04-27 Intelligent sewage treatment unit and the method processing sewage Active CN104787988B (en)

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