A kind of transmission case of automobile
Technical field
The present invention relates to a kind of transmission case of automobile, belongs to technical field of automobile.
Background technology
In the keen competition of world's automobile market, each state all to high-quality, high reliability, lightweight, energy-conservation, it is low into
This direction is developed.Lightweight is shown as in terms of material, part steel (ferrum) part is replaced with aluminium alloy, to reach automobile to high-quality
Amount, the requirement of the development of low cost;Science is shown as in process aspect, replaces traditional technique to carry to reach with advanced technologies
High semifinished product precision, reduces allowance, reduces raw materials consumption, the purpose of reduces cost.Further to expand aluminum alloy materials
In the utilization of vehicle structure and power assembly system, the preparation method and manufacturing process of existing aluminium alloy castings are difficult to meet
This requirement.
The content of the invention
The good speed change of a kind of process is simple that the present invention is aiming at the problems referred to above and proposes, low cost, corrosion resistance
Case.
A kind of transmission case of automobile, the change speed gear box includes lower box and upper box, and lower box is connected to form with upper box
Change speed gear box cavity, the upper box inner surface is coated with alumina series ceramic material layer, and the lower box inner surface coats aerobic
Change zirconium series ceramic material layer, upper box and nowel external surface are coated with machine silicon coating,
Upper box and lower box are aluminum alloy material, and aluminum alloy chemically is consisted of(Percentage by weight):Sn:13-14 ﹪,:
Cu 6-7 ﹪, Mg:2-3 ﹪, Si:1-2 ﹪, Ti:0.8-0.9 ﹪, Mn 0.6-0.7 ﹪, Fe:0.4-0.5 ﹪, Ni:0.2-
0.3 ﹪, Co:0.08-0.09 ﹪, Cr:0.06-0.07 ﹪, Ag:0.05-0.06 ﹪, Y:0.06-0.07 ﹪, Mo:0.08-
0.09 ﹪, balance of Al and inevitable impurity;
The preparation method of upper box and lower box:Comprise the following steps:According to above-mentioned aluminum alloy chemical composition dispensing, first will
Aluminium ingot is added in smelting furnace, and at 720 DEG C, after aluminium ingot fusing, temperature of aluminum liquid is raised to 730 DEG C and adds in the middle of stannum aluminum Control for Kiln Temperature
Alloy, after by furnace temperature be increased to 735 DEG C addition copper-aluminium master alloys;Afterwards furnace temperature is increased to into 740 DEG C of addition magnalium intermediate alloys
And pure silicon;Afterwards furnace temperature is increased to into 745 DEG C adds other alloying elements, rear furnace temperature to be increased to 760 DEG C, adds refine cleanser,
Refine cleanser addition is the 0.8% of furnace charge amount, stirs 40 minutes, stands 60 minutes, treats that slag is separated with molten metal, skims,
After add coverture, skim again after standing 30 minutes, upper box and lower box are poured into a mould respectively afterwards;Pouring temperature is
740℃;The upper box for obtaining and lower box carry out heat treatment:Upper box and lower box are heated first, is warming up to 560
DEG C, 50 DEG C/h of heating rate is incubated 2 hours, and Quenching Treatment is carried out afterwards, and hardening media is water, after quenching by upper box and
Lower box is heated to 500 DEG C from room temperature, 100 DEG C/h of heating rate, is incubated 7 hours, after be cooled to 300 DEG C, rate of temperature fall 50
DEG C/h, be incubated 3 hours, after be cooled to 200 DEG C again, 50 DEG C/h of rate of temperature fall is incubated 9 hours, after be air cooled to room temperature;
The refine cleanser includes:Aluminum chloride 60%, aluminum nitrate 20%, potassium chloride 10%, sodium nitrate 5%, manganese chloride 5% is described
Coverture includes:Aluminum sulfate 40%, barium sulfate 20%, Sodium Chloride 10%;Aluminum fluoric acid sodium 10%;Aluminium oxide 10%, sodium fluoride
10%, the total addition of coverture is the 0.8% of furnace charge amount,
Afterwards process is passivated to upper box and lower box surface, wherein:Passivating solution is consisted of(Weight):Ferrous chloride
9 parts, sodium bisulfate 10-13 parts, fluotitanic acid 10-11 parts, Fluohydric acid. 5-10 parts, zirconium nitrate 2-3 parts, dodecyl sodium sulfate 1-2
Part, water 25-35 parts;
Afterwards zirconium oxide series ceramic material is coated to lower box inner surface;Formed by being coated in lower box inner surface
Zirconium oxide series ceramic material layer, zirconium oxide series ceramic material thickness degree 0.5mm, zirconium oxide series ceramic material layer includes(Weight):
Zirconium oxide 20-30 parts, titanium carbide 10-20 parts, 5 parts of silicon nitride, 5 parts of silicon oxide is heated the lower box after coating, is risen
To 450 DEG C, 50 DEG C/h of heating rate is incubated 3 hours to temperature, after be cooled to 350 DEG C, 100 DEG C/h of rate of temperature fall, insulation 4
Hour, after be cooled to 200 DEG C again, 75 DEG C/h of rate of temperature fall is incubated 6 hours, after be air cooled to room temperature,
Afterwards alumina series ceramic material is coated to upper box inner surface;Formed by being coated in upper box inner surface
Alumina series ceramic material layer, alumina series ceramic material layer thickness 0.5mm, alumina series ceramic material layer includes(Weight):
100 parts of aluminium oxide, titanium nitride 30-40 parts, titanium oxide 10-15 parts are heated the upper box after coating, are warming up to 350
DEG C, 100 DEG C/h of heating rate is incubated 4 hours, after be cooled to 250 DEG C, 50 DEG C/h of rate of temperature fall is incubated 5 hours, after
Be cooled to 150 DEG C again, 25 DEG C/h of rate of temperature fall is incubated 7 hours, after be air cooled to room temperature,
Afterwards heat-resisting paint is coated to upper box and nowel external surface;The coating includes(Weight):Organosilicon
100 parts of resin, 20 parts of sodium silicate, 20 parts of barium sulfate, 10 parts of titanium dioxide, 5 parts of ethylenediamine, 3 parts of Borax, 5 parts of zinc phosphate, methyl is fine
2 parts of dimension element, obtains final casing.
A kind of described transmission case of automobile, aluminum alloy chemically is consisted of(Percentage by weight):Sn:13 ﹪,:The ﹪ of Cu 6,
Mg:2 ﹪, Si:1 ﹪, Ti:0.8 ﹪, Mn 0.6 ﹪, Fe:0.4 ﹪, Ni:0.2 ﹪, Co:0.08 ﹪, Cr:0.06 ﹪, Ag:
0.05 ﹪, Y:0.06 ﹪, Mo:0.08 ﹪, balance of Al and inevitable impurity.
A kind of described transmission case of automobile, aluminum alloy chemically is consisted of(Percentage by weight):Sn:14 ﹪,:The ﹪ of Cu 7,
Mg:3 ﹪, Si:2 ﹪, Ti:0.9 ﹪, Mn 0.7 ﹪, Fe:0.5 ﹪, Ni:0.3 ﹪, Co:0.09 ﹪, Cr:0.07 ﹪,
Ag:0.06 ﹪, Y:0.07 ﹪, Mo:0.09 ﹪, balance of Al and inevitable impurity.
A kind of described transmission case of automobile, aluminum alloy chemically is consisted of(Percentage by weight):Sn:13.5 ﹪,:Cu
6.5 ﹪, Mg:2.5 ﹪, Si:1.5 ﹪, Ti:0.85 ﹪, Mn 0.65 ﹪, Fe:0.45 ﹪, Ni:0.25 ﹪, Co:0.085 ﹪,
Cr:0.065 ﹪, Ag:0.055 ﹪, Y:0.065 ﹪, Mo:0.085 ﹪, balance of Al and inevitable impurity.
A kind of described transmission case of automobile, zirconium oxide series ceramic material layer includes(Weight):20 parts of zirconium oxide, titanium carbide
10 parts, 5 parts of silicon nitride, 5 parts of silicon oxide.
A kind of described transmission case of automobile, zirconium oxide series ceramic material layer includes(Weight):30 parts of zirconium oxide, titanium carbide
20 parts, 5 parts of silicon nitride, 5 parts of silicon oxide.
A kind of described transmission case of automobile, zirconium oxide series ceramic material layer includes(Weight):25 parts of zirconium oxide, titanium carbide
15 parts, 5 parts of silicon nitride, 5 parts of silicon oxide.
A kind of described transmission case of automobile, alumina series ceramic material layer includes(Weight):100 parts of aluminium oxide, nitridation
30 parts of titanium, 10 parts of titanium oxide.
A kind of described transmission case of automobile, alumina series ceramic material layer includes(Weight):100 parts of aluminium oxide, nitridation
40 parts of titanium, 15 parts of titanium oxide.
A kind of described transmission case of automobile, alumina series ceramic material layer includes(Weight):100 parts of aluminium oxide, nitridation
35 parts of titanium, 13 parts of titanium oxide.
A kind of transmission case of automobile and its manufacture method, the change speed gear box includes lower box and upper box, lower box with it is upper
Casing is connected to form change speed gear box cavity, and the upper box inner surface is coated with alumina series ceramic material layer, in the nowel body
Surface-coated has zirconium oxide series ceramic material layer, and upper box and nowel external surface are coated with machine silicon coating,
Upper box and lower box are aluminum alloy material, and aluminum alloy chemically is consisted of(Percentage by weight):Sn:13-14 ﹪,:
Cu 6-7 ﹪, Mg:2-3 ﹪, Si:1-2 ﹪, Ti:0.8-0.9 ﹪, Mn 0.6-0.7 ﹪, Fe:0.4-0.5 ﹪, Ni:0.2-
0.3 ﹪, Co:0.08-0.09 ﹪, Cr:0.06-0.07 ﹪, Ag:0.05-0.06 ﹪, Y:0.06-0.07 ﹪, Mo:0.08-
0.09 ﹪, balance of Al and inevitable impurity;
The preparation method of upper box and lower box:Comprise the following steps:According to above-mentioned aluminum alloy chemical composition dispensing, first will
Aluminium ingot is added in smelting furnace, and at 720 DEG C, after aluminium ingot fusing, temperature of aluminum liquid is raised to 730 DEG C and adds in the middle of stannum aluminum Control for Kiln Temperature
Alloy, after by furnace temperature be increased to 735 DEG C addition copper-aluminium master alloys;Afterwards furnace temperature is increased to into 740 DEG C of addition magnalium intermediate alloys
And pure silicon;Afterwards furnace temperature is increased to into 745 DEG C adds other alloying elements, rear furnace temperature to be increased to 760 DEG C, adds refine cleanser,
Refine cleanser addition is the 0.8% of furnace charge amount, stirs 40 minutes, stands 60 minutes, treats that slag is separated with molten metal, skims,
After add coverture, skim again after standing 30 minutes, upper box and lower box are poured into a mould respectively afterwards;Pouring temperature is
740℃;The upper box for obtaining and lower box carry out heat treatment:Upper box and lower box are heated first, is warming up to 560
DEG C, 50 DEG C/h of heating rate is incubated 2 hours, and Quenching Treatment is carried out afterwards, and hardening media is water, after quenching by upper box and
Lower box is heated to 500 DEG C from room temperature, 100 DEG C/h of heating rate, is incubated 7 hours, after be cooled to 300 DEG C, rate of temperature fall 50
DEG C/h, be incubated 3 hours, after be cooled to 200 DEG C again, 50 DEG C/h of rate of temperature fall is incubated 9 hours, after be air cooled to room temperature;
The refine cleanser includes:Aluminum chloride 60%, aluminum nitrate 20%, potassium chloride 10%, sodium nitrate 5%, manganese chloride 5% is described
Coverture includes:Aluminum sulfate 40%, barium sulfate 20%, Sodium Chloride 10%;Aluminum fluoric acid sodium 10%;Aluminium oxide 10%, sodium fluoride
10%, the total addition of coverture is the 0.8% of furnace charge amount,
Afterwards process is passivated to upper box and lower box surface, wherein:Passivating solution is consisted of(Weight):Ferrous chloride
9 parts, sodium bisulfate 10-13 parts, fluotitanic acid 10-11 parts, Fluohydric acid. 5-10 parts, zirconium nitrate 2-3 parts, dodecyl sodium sulfate 1-2
Part, water 25-35 parts;
Afterwards zirconium oxide series ceramic material is coated to lower box inner surface;Formed by being coated in lower box inner surface
Zirconium oxide series ceramic material layer, zirconium oxide series ceramic material thickness degree 0.5mm, zirconium oxide series ceramic material layer includes(Weight):
Zirconium oxide 20-30 parts, titanium carbide 10-20 parts, 5 parts of silicon nitride, 5 parts of silicon oxide is heated the lower box after coating, is risen
To 450 DEG C, 50 DEG C/h of heating rate is incubated 3 hours to temperature, after be cooled to 350 DEG C, 100 DEG C/h of rate of temperature fall, insulation 4
Hour, after be cooled to 200 DEG C again, 75 DEG C/h of rate of temperature fall is incubated 6 hours, after be air cooled to room temperature,
Afterwards alumina series ceramic material is coated to upper box inner surface;Formed by being coated in upper box inner surface
Alumina series ceramic material layer, alumina series ceramic material layer thickness 0.5mm, alumina series ceramic material layer includes(Weight):
100 parts of aluminium oxide, titanium nitride 30-40 parts, titanium oxide 10-15 parts are heated the upper box after coating, are warming up to 350
DEG C, 100 DEG C/h of heating rate is incubated 4 hours, after be cooled to 250 DEG C, 50 DEG C/h of rate of temperature fall is incubated 5 hours, after
Be cooled to 150 DEG C again, 25 DEG C/h of rate of temperature fall is incubated 7 hours, after be air cooled to room temperature,
Afterwards heat-resisting paint is coated to upper box and nowel external surface;The coating includes(Weight):Organosilicon
100 parts of resin, 20 parts of sodium silicate, 20 parts of barium sulfate, 10 parts of titanium dioxide, 5 parts of ethylenediamine, 3 parts of Borax, 5 parts of zinc phosphate, methyl is fine
2 parts of dimension element, obtains final casing.
Foregoing invention content is relative to the beneficial effect of prior art:1)The composition of aluminium alloy is simple;2)To this into
The surface treatment procedure that the aluminium alloy for dividing is passivated, it is to avoid the problems such as any surface stain occur, makes acquisition surface clean and tidy;
3)Because lower box inner surface easily contacts gear box oil than upper box inner surface, therefore in lower box inner surface and top box body
Surface carries out differentiation coating, improves corrosion resisting property.4)Organic coating is formed to box outer surface and effectively improves weather-proof pollution resistance
Energy.
Specific embodiment
In order to be more clearly understood to the technical characteristic of the present invention, purpose and effect, now describe the present invention's in detail
Specific embodiment.
Embodiment 1
A kind of transmission case of automobile, the change speed gear box includes lower box and upper box, and lower box is connected to form with upper box
Change speed gear box cavity, the upper box inner surface is coated with alumina series ceramic material layer, and the lower box inner surface coats aerobic
Change zirconium series ceramic material layer, upper box and nowel external surface are coated with machine silicon coating,
Upper box and lower box are aluminum alloy material, and aluminum alloy chemically is consisted of(Percentage by weight):Sn:13 ﹪,:Cu
6 ﹪, Mg:2 ﹪, Si:1 ﹪, Ti:0.8 ﹪, Mn 0.6 ﹪, Fe:0.4 ﹪, Ni:0.2 ﹪, Co:0.08 ﹪, Cr:0.06 ﹪, Ag:
0.05 ﹪, Y:0.06 ﹪, Mo:0.08- ﹪, balance of Al and inevitable impurity;
The preparation method of upper box and lower box:Comprise the following steps:According to above-mentioned aluminum alloy chemical composition dispensing, first will
Aluminium ingot is added in smelting furnace, and at 720 DEG C, after aluminium ingot fusing, temperature of aluminum liquid is raised to 730 DEG C and adds in the middle of stannum aluminum Control for Kiln Temperature
Alloy, after by furnace temperature be increased to 735 DEG C addition copper-aluminium master alloys;Afterwards furnace temperature is increased to into 740 DEG C of addition magnalium intermediate alloys
And pure silicon;Afterwards furnace temperature is increased to into 745 DEG C adds other alloying elements, rear furnace temperature to be increased to 760 DEG C, adds refine cleanser,
Refine cleanser addition is the 0.8% of furnace charge amount, stirs 40 minutes, stands 60 minutes, treats that slag is separated with molten metal, skims,
After add coverture, skim again after standing 30 minutes, upper box and lower box are poured into a mould respectively afterwards;Pouring temperature is
740℃;The upper box for obtaining and lower box carry out heat treatment:Upper box and lower box are heated first, is warming up to 560
DEG C, 50 DEG C/h of heating rate is incubated 2 hours, and Quenching Treatment is carried out afterwards, and hardening media is water, after quenching by upper box and
Lower box is heated to 500 DEG C from room temperature, 100 DEG C/h of heating rate, is incubated 7 hours, after be cooled to 300 DEG C, rate of temperature fall 50
DEG C/h, be incubated 3 hours, after be cooled to 200 DEG C again, 50 DEG C/h of rate of temperature fall is incubated 9 hours, after be air cooled to room temperature;
The refine cleanser includes:Aluminum chloride 60%, aluminum nitrate 20%, potassium chloride 10%, sodium nitrate 5%, manganese chloride 5% is described
Coverture includes:Aluminum sulfate 40%, barium sulfate 20%, Sodium Chloride 10%;Aluminum fluoric acid sodium 10%;Aluminium oxide 10%, sodium fluoride
10%, the total addition of coverture is the 0.8% of furnace charge amount,
Afterwards process is passivated to upper box and lower box surface, wherein:Passivating solution is consisted of(Weight):Ferrous chloride
9 parts, 10 parts of sodium bisulfate, 10 parts of fluotitanic acid, 5 parts of Fluohydric acid., 2 parts of zirconium nitrate, 1 part of dodecyl sodium sulfate, 25 parts of water;
Afterwards zirconium oxide series ceramic material is coated to lower box inner surface;Formed by being coated in lower box inner surface
Zirconium oxide series ceramic material layer, zirconium oxide series ceramic material thickness degree 0.5mm, zirconium oxide series ceramic material layer includes(Weight):
20 parts of zirconium oxide, 10 parts of titanium carbide, 5 parts of silicon nitride, 5 parts of silicon oxide is heated the lower box after coating, is warming up to 450
DEG C, 50 DEG C/h of heating rate is incubated 3 hours, after be cooled to 350 DEG C, 100 DEG C/h of rate of temperature fall is incubated 4 hours, after
Be cooled to 200 DEG C again, 75 DEG C/h of rate of temperature fall is incubated 6 hours, after be air cooled to room temperature,
Afterwards alumina series ceramic material is coated to upper box inner surface;Formed by being coated in upper box inner surface
Alumina series ceramic material layer, alumina series ceramic material layer thickness 0.5mm, alumina series ceramic material layer includes(Weight):
100 parts of aluminium oxide, 30 parts of titanium nitride, 10 parts of titanium oxide is heated the upper box after coating, is warming up to 350 DEG C, is heated up
100 DEG C/h of speed, is incubated 4 hours, after be cooled to 250 DEG C, 50 DEG C/h of rate of temperature fall is incubated 5 hours, after lower the temperature again
To 150 DEG C, 25 DEG C/h of rate of temperature fall is incubated 7 hours, after be air cooled to room temperature,
Afterwards heat-resisting paint is coated to upper box and nowel external surface;The coating includes(Weight):Organosilicon
100 parts of resin, 20 parts of sodium silicate, 20 parts of barium sulfate, 10 parts of titanium dioxide, 5 parts of ethylenediamine, 3 parts of Borax, 5 parts of zinc phosphate, methyl is fine
2 parts of dimension element, obtains final casing.
Embodiment 2
A kind of transmission case of automobile, the change speed gear box includes lower box and upper box, and lower box is connected to form with upper box
Change speed gear box cavity, the upper box inner surface is coated with alumina series ceramic material layer, and the lower box inner surface coats aerobic
Change zirconium series ceramic material layer, upper box and nowel external surface are coated with machine silicon coating,
Upper box and lower box are aluminum alloy material, and aluminum alloy chemically is consisted of(Percentage by weight):Sn:14 ﹪,:Cu
7 ﹪, Mg:3 ﹪, Si:2 ﹪, Ti:0.9 ﹪, Mn 0.7 ﹪, Fe:0.5 ﹪, Ni:0.3 ﹪, Co:0.09 ﹪, Cr:
0.07 ﹪, Ag:0.06 ﹪, Y:0.07 ﹪, Mo:0.09 ﹪, balance of Al and inevitable impurity;
The preparation method of upper box and lower box:Comprise the following steps:According to above-mentioned aluminum alloy chemical composition dispensing, first will
Aluminium ingot is added in smelting furnace, and at 720 DEG C, after aluminium ingot fusing, temperature of aluminum liquid is raised to 730 DEG C and adds in the middle of stannum aluminum Control for Kiln Temperature
Alloy, after by furnace temperature be increased to 735 DEG C addition copper-aluminium master alloys;Afterwards furnace temperature is increased to into 740 DEG C of addition magnalium intermediate alloys
And pure silicon;Afterwards furnace temperature is increased to into 745 DEG C adds other alloying elements, rear furnace temperature to be increased to 760 DEG C, adds refine cleanser,
Refine cleanser addition is the 0.8% of furnace charge amount, stirs 40 minutes, stands 60 minutes, treats that slag is separated with molten metal, skims,
After add coverture, skim again after standing 30 minutes, upper box and lower box are poured into a mould respectively afterwards;Pouring temperature is
740℃;The upper box for obtaining and lower box carry out heat treatment:Upper box and lower box are heated first, is warming up to 560
DEG C, 50 DEG C/h of heating rate is incubated 2 hours, and Quenching Treatment is carried out afterwards, and hardening media is water, after quenching by upper box and
Lower box is heated to 500 DEG C from room temperature, 100 DEG C/h of heating rate, is incubated 7 hours, after be cooled to 300 DEG C, rate of temperature fall 50
DEG C/h, be incubated 3 hours, after be cooled to 200 DEG C again, 50 DEG C/h of rate of temperature fall is incubated 9 hours, after be air cooled to room temperature;
The refine cleanser includes:Aluminum chloride 60%, aluminum nitrate 20%, potassium chloride 10%, sodium nitrate 5%, manganese chloride 5% is described
Coverture includes:Aluminum sulfate 40%, barium sulfate 20%, Sodium Chloride 10%;Aluminum fluoric acid sodium 10%;Aluminium oxide 10%, sodium fluoride
10%, the total addition of coverture is the 0.8% of furnace charge amount,
Afterwards process is passivated to upper box and lower box surface, wherein:Passivating solution is consisted of(Weight):Ferrous chloride
9 parts, 13 parts of sodium bisulfate, 11 parts of fluotitanic acid, 10 parts of Fluohydric acid., 3 parts of zirconium nitrate, 2 parts of dodecyl sodium sulfate, 35 parts of water;
Afterwards zirconium oxide series ceramic material is coated to lower box inner surface;Formed by being coated in lower box inner surface
Zirconium oxide series ceramic material layer, zirconium oxide series ceramic material thickness degree 0.5mm, zirconium oxide series ceramic material layer includes(Weight):
30 parts of zirconium oxide, 20 parts of titanium carbide, 5 parts of silicon nitride, 5 parts of silicon oxide is heated the lower box after coating, is warming up to 450
DEG C, 50 DEG C/h of heating rate is incubated 3 hours, after be cooled to 350 DEG C, 100 DEG C/h of rate of temperature fall is incubated 4 hours, after
Be cooled to 200 DEG C again, 75 DEG C/h of rate of temperature fall is incubated 6 hours, after be air cooled to room temperature,
Afterwards alumina series ceramic material is coated to upper box inner surface;Formed by being coated in upper box inner surface
Alumina series ceramic material layer, alumina series ceramic material layer thickness 0.5mm, alumina series ceramic material layer includes(Weight):
100 parts of aluminium oxide, 40 parts of titanium nitride, 15 parts of titanium oxide is heated the upper box after coating, is warming up to 350 DEG C, is heated up
100 DEG C/h of speed, is incubated 4 hours, after be cooled to 250 DEG C, 50 DEG C/h of rate of temperature fall is incubated 5 hours, after lower the temperature again
To 150 DEG C, 25 DEG C/h of rate of temperature fall is incubated 7 hours, after be air cooled to room temperature,
Afterwards heat-resisting paint is coated to upper box and nowel external surface;The coating includes(Weight):Organosilicon
100 parts of resin, 20 parts of sodium silicate, 20 parts of barium sulfate, 10 parts of titanium dioxide, 5 parts of ethylenediamine, 3 parts of Borax, 5 parts of zinc phosphate, methyl is fine
2 parts of dimension element, obtains final casing.
Embodiment 3
A kind of transmission case of automobile, the change speed gear box includes lower box and upper box, and lower box is connected to form with upper box
Change speed gear box cavity, the upper box inner surface is coated with alumina series ceramic material layer, and the lower box inner surface coats aerobic
Change zirconium series ceramic material layer, upper box and nowel external surface are coated with machine silicon coating,
Upper box and lower box are aluminum alloy material, and aluminum alloy chemically is consisted of(Percentage by weight):Sn:13.5 ﹪,:Cu
6.5 ﹪, Mg:2.5 ﹪, Si:1.5 ﹪, Ti:0.85 ﹪, Mn 0.65 ﹪, Fe:0.45 ﹪, Ni:0.25 ﹪, Co:0.085 ﹪,
Cr:0.065 ﹪, Ag:0.055 ﹪, Y:0.065 ﹪, Mo:0.085 ﹪, balance of Al and inevitable impurity;
The preparation method of upper box and lower box:Comprise the following steps:According to above-mentioned aluminum alloy chemical composition dispensing, first will
Aluminium ingot is added in smelting furnace, and at 720 DEG C, after aluminium ingot fusing, temperature of aluminum liquid is raised to 730 DEG C and adds in the middle of stannum aluminum Control for Kiln Temperature
Alloy, after by furnace temperature be increased to 735 DEG C addition copper-aluminium master alloys;Afterwards furnace temperature is increased to into 740 DEG C of addition magnalium intermediate alloys
And pure silicon;Afterwards furnace temperature is increased to into 745 DEG C adds other alloying elements, rear furnace temperature to be increased to 760 DEG C, adds refine cleanser,
Refine cleanser addition is the 0.8% of furnace charge amount, stirs 40 minutes, stands 60 minutes, treats that slag is separated with molten metal, skims,
After add coverture, skim again after standing 30 minutes, upper box and lower box are poured into a mould respectively afterwards;Pouring temperature is
740℃;The upper box for obtaining and lower box carry out heat treatment:Upper box and lower box are heated first, is warming up to 560
DEG C, 50 DEG C/h of heating rate is incubated 2 hours, and Quenching Treatment is carried out afterwards, and hardening media is water, after quenching by upper box and
Lower box is heated to 500 DEG C from room temperature, 100 DEG C/h of heating rate, is incubated 7 hours, after be cooled to 300 DEG C, rate of temperature fall 50
DEG C/h, be incubated 3 hours, after be cooled to 200 DEG C again, 50 DEG C/h of rate of temperature fall is incubated 9 hours, after be air cooled to room temperature;
The refine cleanser includes:Aluminum chloride 60%, aluminum nitrate 20%, potassium chloride 10%, sodium nitrate 5%, manganese chloride 5% is described
Coverture includes:Aluminum sulfate 40%, barium sulfate 20%, Sodium Chloride 10%;Aluminum fluoric acid sodium 10%;Aluminium oxide 10%, sodium fluoride
10%, the total addition of coverture is the 0.8% of furnace charge amount,
Afterwards process is passivated to upper box and lower box surface, wherein:Passivating solution is consisted of(Weight):Ferrous chloride
9 parts, 12 parts of sodium bisulfate, 10.5 parts of fluotitanic acid, 7 parts of Fluohydric acid., 2.5 parts of zirconium nitrate, 1.5 parts of dodecyl sodium sulfate, water 30
Part;
Afterwards zirconium oxide series ceramic material is coated to lower box inner surface;Formed by being coated in lower box inner surface
Zirconium oxide series ceramic material layer, zirconium oxide series ceramic material thickness degree 0.5mm, zirconium oxide series ceramic material layer includes(Weight):
25 parts of zirconium oxide, 15 parts of titanium carbide, 5 parts of silicon nitride, 5 parts of silicon oxide is heated the lower box after coating, is warming up to 450
DEG C, 50 DEG C/h of heating rate is incubated 3 hours, after be cooled to 350 DEG C, 100 DEG C/h of rate of temperature fall is incubated 4 hours, after
Be cooled to 200 DEG C again, 75 DEG C/h of rate of temperature fall is incubated 6 hours, after be air cooled to room temperature,
Afterwards alumina series ceramic material is coated to upper box inner surface;Formed by being coated in upper box inner surface
Alumina series ceramic material layer, alumina series ceramic material layer thickness 0.5mm, alumina series ceramic material layer includes(Weight):
100 parts of aluminium oxide, 35 parts of titanium nitride, 13 parts of titanium oxide is heated the upper box after coating, is warming up to 350 DEG C, is heated up
100 DEG C/h of speed, is incubated 4 hours, after be cooled to 250 DEG C, 50 DEG C/h of rate of temperature fall is incubated 5 hours, after lower the temperature again
To 150 DEG C, 25 DEG C/h of rate of temperature fall is incubated 7 hours, after be air cooled to room temperature,
Afterwards heat-resisting paint is coated to upper box and nowel external surface;The coating includes(Weight):Organosilicon
100 parts of resin, 20 parts of sodium silicate, 20 parts of barium sulfate, 10 parts of titanium dioxide, 5 parts of ethylenediamine, 3 parts of Borax, 5 parts of zinc phosphate, methyl is fine
2 parts of dimension element, obtains final casing.
Embodiment 4
A kind of transmission case of automobile, the change speed gear box includes lower box and upper box, and lower box is connected to form with upper box
Change speed gear box cavity, the upper box inner surface is coated with alumina series ceramic material layer, and the lower box inner surface coats aerobic
Change zirconium series ceramic material layer, upper box and nowel external surface are coated with machine silicon coating,
Upper box and lower box are aluminum alloy material, and aluminum alloy chemically is consisted of(Percentage by weight):Sn:13.3 ﹪,:Cu
6.2 ﹪, Mg:2.3 ﹪, Si:1.4 ﹪, Ti:0.83 ﹪, Mn 0.62 ﹪, Fe:0.41 ﹪, Ni:0.22 ﹪, Co:0.083 ﹪,
Cr:0.064 ﹪, Ag:0.053 ﹪, Y:0.062 ﹪, Mo:0.084 ﹪, balance of Al and inevitable impurity;
The preparation method of upper box and lower box:Comprise the following steps:According to above-mentioned aluminum alloy chemical composition dispensing, first will
Aluminium ingot is added in smelting furnace, and at 720 DEG C, after aluminium ingot fusing, temperature of aluminum liquid is raised to 730 DEG C and adds in the middle of stannum aluminum Control for Kiln Temperature
Alloy, after by furnace temperature be increased to 735 DEG C addition copper-aluminium master alloys;Afterwards furnace temperature is increased to into 740 DEG C of addition magnalium intermediate alloys
And pure silicon;Afterwards furnace temperature is increased to into 745 DEG C adds other alloying elements, rear furnace temperature to be increased to 760 DEG C, adds refine cleanser,
Refine cleanser addition is the 0.8% of furnace charge amount, stirs 40 minutes, stands 60 minutes, treats that slag is separated with molten metal, skims,
After add coverture, skim again after standing 30 minutes, upper box and lower box are poured into a mould respectively afterwards;Pouring temperature is
740℃;The upper box for obtaining and lower box carry out heat treatment:Upper box and lower box are heated first, is warming up to 560
DEG C, 50 DEG C/h of heating rate is incubated 2 hours, and Quenching Treatment is carried out afterwards, and hardening media is water, after quenching by upper box and
Lower box is heated to 500 DEG C from room temperature, 100 DEG C/h of heating rate, is incubated 7 hours, after be cooled to 300 DEG C, rate of temperature fall 50
DEG C/h, be incubated 3 hours, after be cooled to 200 DEG C again, 50 DEG C/h of rate of temperature fall is incubated 9 hours, after be air cooled to room temperature;
The refine cleanser includes:Aluminum chloride 60%, aluminum nitrate 20%, potassium chloride 10%, sodium nitrate 5%, manganese chloride 5% is described
Coverture includes:Aluminum sulfate 40%, barium sulfate 20%, Sodium Chloride 10%;Aluminum fluoric acid sodium 10%;Aluminium oxide 10%, sodium fluoride
10%, the total addition of coverture is the 0.8% of furnace charge amount,
Afterwards process is passivated to upper box and lower box surface, wherein:Passivating solution is consisted of(Weight):Ferrous chloride
9 parts, 11 parts of sodium bisulfate, 10.2 parts of fluotitanic acid, 6 parts of Fluohydric acid., 2.2 parts of zirconium nitrate, 1.2 parts of dodecyl sodium sulfate, water 25-
35 parts;
Afterwards zirconium oxide series ceramic material is coated to lower box inner surface;Formed by being coated in lower box inner surface
Zirconium oxide series ceramic material layer, zirconium oxide series ceramic material thickness degree 0.5mm, zirconium oxide series ceramic material layer includes(Weight):
21 parts of zirconium oxide, 12 parts of titanium carbide, 5 parts of silicon nitride, 5 parts of silicon oxide is heated the lower box after coating, is warming up to 450
DEG C, 50 DEG C/h of heating rate is incubated 3 hours, after be cooled to 350 DEG C, 100 DEG C/h of rate of temperature fall is incubated 4 hours, after
Be cooled to 200 DEG C again, 75 DEG C/h of rate of temperature fall is incubated 6 hours, after be air cooled to room temperature,
Afterwards alumina series ceramic material is coated to upper box inner surface;Formed by being coated in upper box inner surface
Alumina series ceramic material layer, alumina series ceramic material layer thickness 0.5mm, alumina series ceramic material layer includes(Weight):
100 parts of aluminium oxide, 34 parts of titanium nitride, 11 parts of titanium oxide is heated the upper box after coating, is warming up to 350 DEG C, is heated up
100 DEG C/h of speed, is incubated 4 hours, after be cooled to 250 DEG C, 50 DEG C/h of rate of temperature fall is incubated 5 hours, after lower the temperature again
To 150 DEG C, 25 DEG C/h of rate of temperature fall is incubated 7 hours, after be air cooled to room temperature,
Afterwards heat-resisting paint is coated to upper box and nowel external surface;The coating includes(Weight):Organosilicon
100 parts of resin, 20 parts of sodium silicate, 20 parts of barium sulfate, 10 parts of titanium dioxide, 5 parts of ethylenediamine, 3 parts of Borax, 5 parts of zinc phosphate, methyl is fine
2 parts of dimension element, obtains final casing.
Embodiment 5
A kind of transmission case of automobile, the change speed gear box includes lower box and upper box, and lower box is connected to form with upper box
Change speed gear box cavity, the upper box inner surface is coated with alumina series ceramic material layer, and the lower box inner surface coats aerobic
Change zirconium series ceramic material layer, upper box and nowel external surface are coated with machine silicon coating,
Upper box and lower box are aluminum alloy material, and aluminum alloy chemically is consisted of(Percentage by weight):Sn:13.7 ﹪,:Cu
6.8 ﹪, Mg:2.9 ﹪, Si:1.6 ﹪, Ti:0.87 ﹪, Mn 0.68 ﹪, Fe:0.48 ﹪, Ni:0.29 ﹪, Co:0.087 ﹪,
Cr:0.066 ﹪, Ag:0.057 ﹪, Y:0.068 ﹪, Mo:0.087 ﹪, balance of Al and inevitable impurity;
The preparation method of upper box and lower box:Comprise the following steps:According to above-mentioned aluminum alloy chemical composition dispensing, first will
Aluminium ingot is added in smelting furnace, and at 720 DEG C, after aluminium ingot fusing, temperature of aluminum liquid is raised to 730 DEG C and adds in the middle of stannum aluminum Control for Kiln Temperature
Alloy, after by furnace temperature be increased to 735 DEG C addition copper-aluminium master alloys;Afterwards furnace temperature is increased to into 740 DEG C of addition magnalium intermediate alloys
And pure silicon;Afterwards furnace temperature is increased to into 745 DEG C adds other alloying elements, rear furnace temperature to be increased to 760 DEG C, adds refine cleanser,
Refine cleanser addition is the 0.8% of furnace charge amount, stirs 40 minutes, stands 60 minutes, treats that slag is separated with molten metal, skims,
After add coverture, skim again after standing 30 minutes, upper box and lower box are poured into a mould respectively afterwards;Pouring temperature is
740℃;The upper box for obtaining and lower box carry out heat treatment:Upper box and lower box are heated first, is warming up to 560
DEG C, 50 DEG C/h of heating rate is incubated 2 hours, and Quenching Treatment is carried out afterwards, and hardening media is water, after quenching by upper box and
Lower box is heated to 500 DEG C from room temperature, 100 DEG C/h of heating rate, is incubated 7 hours, after be cooled to 300 DEG C, rate of temperature fall 50
DEG C/h, be incubated 3 hours, after be cooled to 200 DEG C again, 50 DEG C/h of rate of temperature fall is incubated 9 hours, after be air cooled to room temperature;
The refine cleanser includes:Aluminum chloride 60%, aluminum nitrate 20%, potassium chloride 10%, sodium nitrate 5%, manganese chloride 5% is described
Coverture includes:Aluminum sulfate 40%, barium sulfate 20%, Sodium Chloride 10%;Aluminum fluoric acid sodium 10%;Aluminium oxide 10%, sodium fluoride
10%, the total addition of coverture is the 0.8% of furnace charge amount,
Afterwards process is passivated to upper box and lower box surface, wherein:Passivating solution is consisted of(Weight):Ferrous chloride
9 parts, 12 parts of sodium bisulfate, 10.8 parts of fluotitanic acid, 9 parts of Fluohydric acid., 2.7 parts of zirconium nitrate, 1.7 parts of dodecyl sodium sulfate, water 32
Part;
Afterwards zirconium oxide series ceramic material is coated to lower box inner surface;Formed by being coated in lower box inner surface
Zirconium oxide series ceramic material layer, zirconium oxide series ceramic material thickness degree 0.5mm, zirconium oxide series ceramic material layer includes(Weight):
28 parts of zirconium oxide, 17 parts of titanium carbide, 5 parts of silicon nitride, 5 parts of silicon oxide is heated the lower box after coating, is warming up to 450
DEG C, 50 DEG C/h of heating rate is incubated 3 hours, after be cooled to 350 DEG C, 100 DEG C/h of rate of temperature fall is incubated 4 hours, after
Be cooled to 200 DEG C again, 75 DEG C/h of rate of temperature fall is incubated 6 hours, after be air cooled to room temperature,
Afterwards alumina series ceramic material is coated to upper box inner surface;Formed by being coated in upper box inner surface
Alumina series ceramic material layer, alumina series ceramic material layer thickness 0.5mm, alumina series ceramic material layer includes(Weight):
100 parts of aluminium oxide, 38 parts of titanium nitride, 14 parts of titanium oxide is heated the upper box after coating, is warming up to 350 DEG C, is heated up
100 DEG C/h of speed, is incubated 4 hours, after be cooled to 250 DEG C, 50 DEG C/h of rate of temperature fall is incubated 5 hours, after lower the temperature again
To 150 DEG C, 25 DEG C/h of rate of temperature fall is incubated 7 hours, after be air cooled to room temperature,
Afterwards heat-resisting paint is coated to upper box and nowel external surface;The coating includes(Weight):Organosilicon
100 parts of resin, 20 parts of sodium silicate, 20 parts of barium sulfate, 10 parts of titanium dioxide, 5 parts of ethylenediamine, 3 parts of Borax, 5 parts of zinc phosphate, methyl is fine
2 parts of dimension element, obtains final casing.