CN104761194B - A kind of fungi-proofing partition plate - Google Patents
A kind of fungi-proofing partition plate Download PDFInfo
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- CN104761194B CN104761194B CN201410753821.2A CN201410753821A CN104761194B CN 104761194 B CN104761194 B CN 104761194B CN 201410753821 A CN201410753821 A CN 201410753821A CN 104761194 B CN104761194 B CN 104761194B
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- hardwood pulp
- fungi
- oil shale
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- 238000005192 partition Methods 0.000 title claims abstract description 7
- 239000011121 hardwood Substances 0.000 claims abstract description 29
- 239000002699 waste material Substances 0.000 claims abstract description 15
- 239000004058 oil shale Substances 0.000 claims abstract description 14
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000011701 zinc Substances 0.000 claims abstract description 12
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 12
- 239000002893 slag Substances 0.000 claims abstract description 11
- 239000004568 cement Substances 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 235000014347 soups Nutrition 0.000 claims abstract description 5
- 238000001556 precipitation Methods 0.000 claims description 6
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 6
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 3
- 239000013049 sediment Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000002002 slurry Substances 0.000 description 13
- 238000005520 cutting process Methods 0.000 description 12
- 238000007654 immersion Methods 0.000 description 12
- 239000000463 material Substances 0.000 description 10
- 239000002245 particle Substances 0.000 description 10
- 230000000844 anti-bacterial effect Effects 0.000 description 7
- 238000006297 dehydration reaction Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 5
- 241000132536 Cirsium Species 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000018044 dehydration Effects 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 238000007493 shaping process Methods 0.000 description 4
- 230000007704 transition Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 239000011398 Portland cement Substances 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000001467 acupuncture Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000004590 computer program Methods 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 210000000630 fibrocyte Anatomy 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 230000010718 Oxidation Activity Effects 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 238000009966 trimming Methods 0.000 description 1
- 238000002525 ultrasonication Methods 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Paper (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention discloses a kind of fungi-proofing partition plate, it is characterized in that raw material weight proportioning of soup processed is as follows:33 parts~35 parts of oil shale waste, 10 parts~12 parts of carbide slag, 8 parts~10 parts of cement, 15 parts~17 parts of hardwood pulp, nano oxidized 8 parts~10 parts of zinc solution, 20 parts~22 parts of water;It is characterized in that optimal raw material weight proportioning of soup processed is as follows:34 parts of oil shale waste, 11 parts of carbide slag, 9 parts of cement, 16 parts of hardwood pulp, nano oxidized 9 parts of zinc solution, 21 parts of water.The present invention has the characteristics of fungi-proofing ability is strong, intensity is high.
Description
Technical field
The present invention relates to a kind of partition plate, more particularly to a kind of fungi-proofing partition plate.
Background technology
Oil shale waste is oil shale retorting or the remaining material of burning, loose structure, with good activity, thus purposes
Widely.Oil shale waste is silica-rich material, and the main component of oil shale waste is SiO2、Al2O3、Fe2O3, MgO, CaO etc., can use
Make construction material, such as high-grade cement filler, lightweight concrete aggregate haydite and lightweight brick.The comprehensive utilization of oil shale waste
Good resource, environment, economy and social benefit can be obtained, for realizing that the sustainable development of resource is significant.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of fungi-proofing partition plate of good physical performance.
Therefore, the raw material weight proportioning of soup processed for the thistle board that the present invention is provided is:33 parts~35 parts of oil shale waste, 10 parts of carbide slag
~12 parts, 8 parts~10 parts of cement, 15 parts~17 parts of hardwood pulp, nano oxidized 8 parts~10 parts of zinc solution, 20 parts~22 parts of water.
Oil shale waste fineness is that more than 50 mesh, cement uses effective calcium amount in 32.5 grades of Portland cements, carbide slag
More than 70%, carbide slag uses the waste residue that resin processing plant discharges.
Present invention also offers the manufacture method of above-mentioned ceiling board, comprise the following steps that:
(1) preparation of nano burnett's solution
Nano oxidized zinc solution makes in the following manner:Ammoniacal liquor is added drop-wise in zinc nitrate solution, makes solution system pH
Value is more than 9, then obtains precipitation with funnel, and sediment is washed with deionized repeatedly, until the pH value of system is close to 7;Keep
Temperature at 50 DEG C, gradually added into precipitation concentration be 0.95mol/L salpeter solutions stirring, to system pH to 3.5~4.1 it
Between, you can obtain nano oxidized zinc solution.
(2) hardwood pulp is handled
Bleached hardwood pulp can remove lignin contained in hardwood pulp completely in bleaching process, to bleach broad-leaved
Fiber is bonding with base material preferably after wood pulp steams for the product pressure of raw material, can improve the rigidity and bending strength of product.Bleaching
Crushed after hardwood pulp and sieve hardwood pulp particle, hardwood pulp grain diameter is 30~40 mesh.
(3) hardwood pulp particle is carried out antibacterial modified
Hardwood pulp is placed in closed pressure immersion can, plus nano burnett's solution, is pressurized to 1MPa, pressure is kept
1 minute, with a small amount of nano oxidized zinc solution of circulation pumped, make to produce vacuum in immersion can, continue after 1 minute by automatic tune
The direction that device changes four way valve is controlled, nano zine oxide is returned to again in immersion can by fluid filling pump, and make in immersion can
Pressure reach 1MPa.Changed the direction of four-way valve again after 1 minute, and by circulation pumped nano zine oxide solution, make
Immersion can formation vacuum.So it is repeated a number of times.Four-way valve is, by cam mechanism, to be adjusted with computer program controlled automatic, is realized
Vacuum, pressurization frequent transitions.Vacuum-pressurization is once a cycle, and process cycle reaches 60 times.
Nano zine oxide has extremely strong oxidation activity, can destroy the bioactivity and metabolism breeding function of bacterium, so that
Reach antibacterial purpose.In addition, nano zine oxide is under ultraviolet irradiation, the electronegative electricity moved freely can be voluntarily decomposited
Son, and the hole of positively charged is left, the oxygen activation in air is active oxygen by this hole, and active oxygen can be most of pathogens
With virus kill.Therefore, using nano granular of zinc oxide as antibacterial material, while being inhaled using the good ion of hardwood pulp fiber
Performance is received, the thistle board of strong antibacterial is obtained.By the ultrasonic wave of the hardwood pulp particle 35kHz after the processing of pressure immersion can
Handled, the processing time of ultrasonic wave is 4~5min, and temperature is 45 DEG C.
Nano zine oxide is introduced after hardwood pulp fibrocyte and gel, can effectively completely cut off hardwood pulp fiber and oxygen
The contact of gas, so as to suppress the progress of burning.Nano zine oxide is introduced in hardwood pulp fibrocyte, gel can effectively delay
The transmission of heat so that cell wall constituent can only be dehydrated carbonization, so that generation flammable volatility product during the thistle board pyrolysis of system
Speed substantially reduce, while the speed of heat transfer to lightweight plate surface slows down, flame retardant effect is obvious.
Ultrasonication can improve the Hydrogenbond between hardwood pulp fiber, so as to greatly improve the intensity of thistle board.
(4) slurry is made
Hardwood pulp particle after will be antibacterial modified is mixed with carbide slag, cement, oil shale waste and water, is stirred 5 minutes and is made
Into required slurry, pulp density is 11%~13%.Pulp density requires that slurry has good mobility but can not cross shunting
It is dynamic, while ensureing that slurry is uniform and stable, it is desirable to which slurry is extruded space not too much in pressure.
(5) stream slurry making sheet
The thickness of the thin bed of material should be controlled in 0.5~0.6mm during head box paving slurry dehydration forming;The rotating speed of agitator should be controlled
In 70~90rpm.
(6) it is dehydrated into base
Slurry is starched on felt through the uniform cloth of head box, is dehydrated through natural-dehydration and multi-stage vacuum, is formed uniform small powder, twine
It is around on forming tube, the shaping number of turns is 15~20, using Pneumatic Pressure, shaping air pressure is 0.25~0.3MPa, reaches that regulation is thick
After degree it is pneumatic go out knife pull base automatically, felt cleaning uses vacuum dehydration.
It is also more crucial factor from the preferable felt of permeability, the performance of felt directly determines the bed of material sometimes
Water separation capability.Felt selects acupuncture combination felt.
(7) pinch-off
The defective work of corner defect is more caused by mechanical trimming, and product appearance qualification rate is low, outward appearance defective work
It could also be sold by changing system into the sheet material of nonstandard specification, production cost remains high.In order to solve this puzzlement production
The problem of product presentation quality, uses high -pressure water cutting in pinch-off process.Base machine rubber conveyer belt will be connect and be changed to the thick nylon of 3mm
Base thin layer type belt of conveyer, to solve the sideslip of conveyer belt, will connect base belt feeder active upper roller and the positioning passive upper roller of belt and centre
Axis parallel degree between transition roller, three rollers is adjusted to be less than 1mm, and positioning belt cutting transporting velocity is 20m/min, connects base skin
Band cutting transporting velocity be 18m/min, make slab from connect base Belt Conveying to positioning belt it is longitudinally cutting during do not produce
Conveying cutting camber line, to ensure slab edge flatness, by the running orbit of vacuum piler transverse cuts shower nozzle with connecing base machine
Central axis degree is adjusted to be less than 1.5%, to ensure the edge-perpendicular degree of slab.Connect automatic by piler after base positioning Water Cutting
Stacking.
(8) high-temperature vapour is conserved
Piler is sent into still kettle and carries out steam press maintenance.Pressure is 0.9MPa~1MPa, is kept at this pressure
10h。
(9) dry
Sheet material drying machine is dried, and moisture content is less than 10%.
(10) plate face sanding
Plate face is got product after carrying out one side sanding through sander.
The present invention has the characteristics of fungi-proofing ability is strong, intensity is high.
Embodiment
Raw material weight proportioning of soup processed is in the present embodiment:34 parts of oil shale waste, 11 parts of carbide slag, 9 parts of cement, hardwood pulp 16
Part, nano oxidized 9 parts of zinc solution, 21 parts of water.
Oil shale waste fineness is that more than 50 mesh, cement uses effective calcium amount in 32.5 grades of Portland cements, carbide slag
More than 70%, carbide slag uses the waste residue that resin processing plant discharges.
Making step includes:
(1) preparation of nano burnett's solution
Nano oxidized zinc solution makes in the following manner:Ammoniacal liquor is added drop-wise in zinc nitrate solution, makes solution system pH
Value is more than 9, then obtains precipitation with funnel, and sediment is washed with deionized repeatedly, until the pH value of system is close to 7;Keep
Temperature at 50 DEG C, gradually added into precipitation concentration be 0.95mol/L salpeter solutions stirring, to system pH to 3.5~4.1 it
Between, you can obtain nano oxidized zinc solution.
(2) hardwood pulp is handled
Hardwood pulp is bleached, is crushed after bleached hardwood pulp and sieves hardwood pulp particle, hardwood pulp particle
Particle diameter is 30~40 mesh.
(3) hardwood pulp particle is carried out antibacterial modified
Hardwood pulp is placed in closed pressure immersion can, plus nano burnett's solution, is pressurized to 1MPa, pressure is kept
1 minute, with a small amount of nano oxidized zinc solution of circulation pumped, make to produce vacuum in immersion can, continue after 1 minute by automatic tune
The direction that device changes four way valve is controlled, nano zine oxide is returned to again in immersion can by fluid filling pump, and make in immersion can
Pressure reach 1MPa.Changed the direction of four-way valve again after 1 minute, and by circulation pumped nano zine oxide solution, make
Immersion can formation vacuum.So it is repeated a number of times.Four-way valve is, by cam mechanism, to be adjusted with computer program controlled automatic, is realized
Vacuum, pressurization frequent transitions.Vacuum-pressurization is once a cycle, and process cycle reaches 60 times.
Hardwood pulp particle after the processing of pressure immersion can is handled with 35kHz ultrasonic wave, the processing of ultrasonic wave
Time is 4~5min, and temperature is 45 DEG C.
(4) slurry is made
Hardwood pulp particle after will be antibacterial modified is mixed with carbide slag, cement, oil shale waste and water, is stirred 5 minutes and is made
Into required slurry, pulp density is 11%~13%.
(5) stream slurry making sheet
The thickness of the thin bed of material should be controlled in 0.5~0.6mm during head box paving slurry dehydration forming;The rotating speed of agitator should be controlled
In 70~90rpm.
(6) it is dehydrated into base
Slurry is starched on felt through the uniform cloth of head box, is dehydrated through natural-dehydration and multi-stage vacuum, is formed uniform small powder, twine
It is around on forming tube, the shaping number of turns is 15~20, using Pneumatic Pressure, shaping air pressure is 0.25~0.3MPa, reaches that regulation is thick
After degree it is pneumatic go out knife pull base automatically, felt cleaning uses vacuum dehydration.
Felt selects acupuncture combination felt.
(7) pinch-off
High -pressure water cutting is used in pinch-off process.Base machine rubber conveyer belt will be connect, and to be changed to the thick nylon bases of 3mm slim defeated
Band is sent, the axis parallel degree between base belt feeder active upper roller and the positioning passive upper roller of belt and middle transition roller, three rollers will be connect
It is adjusted to be less than 1mm, positioning belt cutting transporting velocity is 20m/min, and it is 18m/min to connect base belt cutting transporting velocity, is made
Slab from connect base Belt Conveying to positioning belt it is longitudinally cutting during do not produce conveying cutting camber line, to ensure slab edge
Glacing flatness, the running orbit of vacuum piler transverse cuts shower nozzle is adjusted to be less than 1.5% with connecing base machine central axis degree, with
Ensure the edge-perpendicular degree of slab.Connect after base positioning Water Cutting by piler automatic piling.
(8) high-temperature vapour is conserved
Piler is sent into still kettle and carries out steam press maintenance.Pressure is 0.9MPa~1MPa, is kept at this pressure
10h。
(9) dry
Sheet material drying machine is dried, and moisture content is less than 10%.
(10) plate face sanding
Plate face is got product after carrying out one side sanding through sander.
Claims (1)
1. a kind of fungi-proofing partition plate, it is characterized in that raw material weight proportioning of soup processed is as follows:33 parts~35 parts of oil shale waste, 10 parts of carbide slag~
12 parts, 8 parts~10 parts of cement, 15 parts~17 parts of hardwood pulp, nano oxidized 8 parts~10 parts of zinc solution, 20 parts~22 parts of water;
Nano oxidized zinc solution makes in the following manner:Ammoniacal liquor is added drop-wise in zinc nitrate solution, makes solution system pH value big
Precipitation is obtained in 9, then with funnel, and sediment is washed with deionized repeatedly, until the pH value of system is close to 7;Keeping temperature
At 50 DEG C, gradually added into precipitation concentration be 0.95mol/L salpeter solutions stirring, to system pH to 3.5~4.1 between,
It can obtain nano zine oxide solution.
Priority Applications (1)
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CN201410753821.2A CN104761194B (en) | 2013-03-21 | 2013-03-21 | A kind of fungi-proofing partition plate |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310124186.7A CN103172318B (en) | 2013-03-21 | 2013-03-21 | Antibacterial partition board |
CN201410753821.2A CN104761194B (en) | 2013-03-21 | 2013-03-21 | A kind of fungi-proofing partition plate |
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CN201310124186.7A Division CN103172318B (en) | 2013-03-21 | 2013-03-21 | Antibacterial partition board |
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CN104761194A CN104761194A (en) | 2015-07-08 |
CN104761194B true CN104761194B (en) | 2017-08-04 |
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CN201410753824.6A Active CN104763096B (en) | 2013-03-21 | 2013-03-21 | Preparation method for partition plate |
CN201310124186.7A Expired - Fee Related CN103172318B (en) | 2013-03-21 | 2013-03-21 | Antibacterial partition board |
CN201410753821.2A Expired - Fee Related CN104761194B (en) | 2013-03-21 | 2013-03-21 | A kind of fungi-proofing partition plate |
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CN201410753824.6A Active CN104763096B (en) | 2013-03-21 | 2013-03-21 | Preparation method for partition plate |
CN201310124186.7A Expired - Fee Related CN103172318B (en) | 2013-03-21 | 2013-03-21 | Antibacterial partition board |
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CN103964803B (en) * | 2014-04-22 | 2016-01-27 | 叶长青 | A kind of fungi-proofing plasterboard |
CN104058653B (en) * | 2014-05-30 | 2016-04-13 | 蚌埠华东石膏有限公司 | A kind of hardwood pulp concrete and preparation method thereof |
CN106676938B (en) * | 2016-07-01 | 2019-05-10 | 广东松本绿色新材股份有限公司 | Technique for manufacturing decorative boards, combo and stream copy device based on composite material |
CN109942313A (en) * | 2019-03-11 | 2019-06-28 | 江苏华友装饰工程有限公司 | Light wall material and preparation method thereof |
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- 2013-03-21 CN CN201310124186.7A patent/CN103172318B/en not_active Expired - Fee Related
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CN1104613A (en) * | 1993-11-18 | 1995-07-05 | 中国建筑材料科学研究院房建材料与混凝土研究所 | Manufacture of lightweight fibre-cement slab |
CN101913832A (en) * | 2010-08-04 | 2010-12-15 | 李彦峰 | Antibacterial mildew-proof high-strength whitewash mortar |
CN102093004A (en) * | 2010-12-13 | 2011-06-15 | 郭东京 | Composite tailing non-fired and non-steamed building block brick and preparation method thereof |
CN102515675A (en) * | 2011-11-16 | 2012-06-27 | 宁波易和绿色板业有限公司 | Novel thermal insulation fireproof wall calcium silicate board and preparation method thereof |
Also Published As
Publication number | Publication date |
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CN104763096A (en) | 2015-07-08 |
CN104763096B (en) | 2017-02-01 |
CN103172318A (en) | 2013-06-26 |
CN103172318B (en) | 2015-03-18 |
CN104761194A (en) | 2015-07-08 |
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