CN104744079A - Purple-bronze ceramic art glaze - Google Patents

Purple-bronze ceramic art glaze Download PDF

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Publication number
CN104744079A
CN104744079A CN201510148877.XA CN201510148877A CN104744079A CN 104744079 A CN104744079 A CN 104744079A CN 201510148877 A CN201510148877 A CN 201510148877A CN 104744079 A CN104744079 A CN 104744079A
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China
Prior art keywords
parts
glaze
copper
purple
ceramic
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CN201510148877.XA
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Chinese (zh)
Inventor
雍起林
谭长干
刘术军
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Changsha Wangcheng District Copper Government Porcelain Kiln Harmony Plays Woods Pottery Art Garden
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Changsha Wangcheng District Copper Government Porcelain Kiln Harmony Plays Woods Pottery Art Garden
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Application filed by Changsha Wangcheng District Copper Government Porcelain Kiln Harmony Plays Woods Pottery Art Garden filed Critical Changsha Wangcheng District Copper Government Porcelain Kiln Harmony Plays Woods Pottery Art Garden
Priority to CN201510148877.XA priority Critical patent/CN104744079A/en
Publication of CN104744079A publication Critical patent/CN104744079A/en
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Abstract

The invention relates to art ceramics, particularly a purple-bronze ceramic art glaze. The purple-bronze ceramic art glaze is prepared from the following raw materials in parts by weight: 25-35 parts of chrome oxide green, 30-40 parts of white clay and 30-40 parts of red lead. The purple-bronze ceramic art glaze is easy for construction and lower in cost. When being applied to a figure sculpture, the purple-bronze ceramic art glaze has short firing time, thereby greatly enhancing the production efficiency and lowering the production cost and energy consumption. After being fired, the ceramic sounds clear and crisp, and has very close sound as the sculpture prepared from metallic copper. The fired ceramic appears bronze, and completely has the same effect as a copper sculpture; and thus, the purple-bronze ceramic art glaze can be used instead of copper to prepare various sculptures, thereby greatly saving the copper resources and lowering the sculpture cost.

Description

A kind of coppery ceramic artistic glaze
Technical field
The present invention relates to a kind of art pottery, be specifically related to a kind of coppery ceramic artistic glaze.
Background technology
Copper is one of metal the earliest of finding of the mankind, has tough and tensile, wear-resistant, that hardness is good and ductility is good advantage.And it is not copper alloy has good corrosion resistance, oxidizable under the environment of drying.The fields such as copper is widely used in electrically, light industry, machinofacture, building industry, national defense industry, are only second to aluminium in the consumption of China's nonferrous materials.At present in artistic portraiture, copper is a kind of important material, and usually use copper to make all kinds of sculpture, the copper consumed in all kinds of sculpture is every year greatly about about 10000 tons.
Current world copper reserves are 6.90 hundred million tons, and global copper ore resource distribution is concentrated, and wherein about 50% is distributed in America.From distribution of countries, world's copper resource mainly concentrates on the states such as Chile, Peru, the U.S., Mexico.Chile is the country that copper resource is the abundantest in the world, 2010, and proven reserve reach 1.9 hundred million tons, accounts for 28% of global reserves; Peru's proven reserve 9,000 ten thousand tons, account for 13% of global reserves, occupy second; The reserves that China is verified are 3,000 ten thousand tons, account for about 4% of global reserves.From Area distribution, global copper is contained the abundantest area and is had five: South America Peru and the domestic Andes Xi Lu of Chile; The Rocky of Western United States and great Ping Canyon; The Congo in Africa and Zambia; The republic of Kazakhstan; Eastern Canada and middle part.
China's internal copper ore resources reserves do not enrich, basic unit price about 3,000 ten thousand tons, are mainly distributed in southwestern three rivers, the middle and lower reach of Yangtze River, southeastern coast, the lucky black east in Qin Qi elder brother metallogenic belt and the Liao Dynasty, Euripides metallogenic belt, western ridge.Wherein, the reserves of Jiangxi, Tibet and Yunnan San Sheng are maximum, account for about 50% of national copper reserves, in addition, what copper reserves were more also has 6 provinces and regions such as Gansu, Anhui, the Inner Mongol, Shanxi, Hubei, Heilungkiang, and the reserves total of these 6 provinces and regions accounts for 32.3% of national copper reserves.The reserves total of above 9 provinces and regions accounts for 80% of national copper mine total reserves.
At present, mineral processing in China and smelting copper mineral raw material mainly contain chalcopyrite, copper glance, purple copper, malachite etc., sample lower, average is about 0.87%, wherein porphyry copper average grade is only about 0.5%, and other types deposit grade is higher, but is also only about 1%.
Therefore, the copper resource of China is very limited, and the copper being used in sculpture aspect is every year a very large resource consumption, if one can be found to substitute, material that copper applies in sculpture will save a large amount of Mineral resources.
Summary of the invention
The present invention is the problem solving copper resource anxiety, provides a kind of at sculpture application aspect coppery ceramic artistic glaze.
Coppery ceramic artistic glaze of the present invention, be made up of the raw material comprising following weight ratio:
Chromoxide green 25 ~ 35 parts, white material soil 30 ~ 40 parts, red lead 30 ~ 40 parts.
One of formula optimization scheme of the present invention is: chromoxide green 28 ~ 32 parts, white material soil 32 ~ 38 parts, red lead 32 ~ 38 parts.
Formula of the present invention more preferably scheme is: chromoxide green 29 ~ 31 parts, white material soil 34 ~ 36 parts, red lead 34 ~ 36 parts.
Formula of the present invention most preferably scheme is: chromoxide green 30 parts, white material soil 35 parts, red lead 35 parts.
Another preferred version of the present invention is made up of the raw material comprising following weight ratio: chromoxide green 33 parts, white material soil 32 parts, red lead 32 parts.
Another preferred version of the present invention is made up of the raw material comprising following weight ratio: chromoxide green 30 parts, white material soil 33 parts, red lead 33 parts.
Another preferred version of the present invention is, also comprises 2 ~ 4 parts, zinc oxide (being more preferably 3 parts).
Another preferred version of the present invention is, also comprises 2 ~ 4 parts, talcum (being more preferably 3 parts).
White material soil, i.e. soft flame-proof clay, English name soft fireclay, soft flame-proof clay is called for short soft clay, and this fireclay has good plasticity-, and mineral composition is kaolinite, halloysite, hydromica etc. mainly.General containing Al2O3 >=22% ~ 30%, SiO2 >=42% ~ 73%, refractoriness 1580 ~ 1670 DEG C.
Making processes is: mixed by the raw material of above-mentioned formula, and by glaze porcelain vase ball milling, being milled to that glaze fineness tails at 10000-hole sieve is 0.5% ~ 1.5%, so adds water to glaze quality concentration 30% ~ 36%.
The present invention also provides the application of described coppery ceramic artistic glaze, and its process is:
(1) mud processed: after being mixed by the embryo mud prepared, grind to form siccative, and then refine into porcelain making embryo mud with vacuum pugmill;
(2) then process sizing, at porcelain embryo moisture, above-mentioned glaze water imposes on idiosome, according to the deep or light thickness deciding glaze layer wanting effect by (more preferably, at porcelain embryo moisture 5% ~ 8% time) 4% ~ 10% time;
(3) fire: within 60min, rise to 1120 ~ 1170 DEG C, 60min ~ 120min at then remaining on 1120 ~ 1170 DEG C from normal temperature heating;
(4) room temperature is cooled to, kiln discharge.
Described step (3) preferably rises to 1140 ~ 1160 DEG C in 60min, 90min at then remaining on 1140 ~ 1160 DEG C.
Coppery ceramic artistic glaze of the present invention imposes on figure sculpture, and the firing time is short, substantially increases production efficiency, reduce production cost and energy consumption, after firing, pottery is clear simultaneously, closely, its appearance presents bronze-colored the sculpture sound made with metallic copper, the light feature of quality of existing pottery, be convenient to carrying, there is again aeneous effect, copper can be substituted to make various statue, there is the effect that copper outward appearance is the same, be used for manufacturing aeneous sculpture, greatly saved copper resource.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described, and to help understanding the present invention better, but protection scope of the present invention is not limited in these embodiments.
Embodiment 1
Coppery ceramic artistic glaze of the present invention, be made up of the raw material of following weight ratio:
Chromoxide green 30 parts, white material soil 35 parts, red lead 35 parts.
Making processes is: mixed by the raw material of above-mentioned formula, by glaze porcelain vase ball milling, is milled to glaze fineness and tails at 10000-hole sieve and be less than 1%, so add water to glaze quality concentration 32%.
Application process is:
(1) mud processed: after being mixed by the embryo mud prepared, grind to form siccative, and then refine into porcelain making embryo mud with vacuum pugmill;
(2) then process sizing, impose on idiosome on by above-mentioned glaze water at porcelain embryo moisture 5% ~ 8% time, the thickness of glaze layer is 0.1mm;
(3) fire: within 60min, rise to 1150 DEG C, 90min at then remaining on 1150 DEG C from normal temperature heating;
(4) room temperature is cooled to, kiln discharge.
Embodiment 2
Coppery ceramic artistic glaze of the present invention, be made up of the raw material of following weight ratio:
Chromoxide green 25, white material soil 30 parts, red lead 30 parts.
Making processes is: mixed by the raw material of above-mentioned formula, by glaze porcelain vase ball milling, is milled to glaze fineness and tails at 10000-hole sieve and be less than 0.5%, so add water to glaze quality concentration 32%.
Application process is:
(1) mud processed: after being mixed by the embryo mud prepared, grind to form siccative, and then refine into porcelain making embryo mud with vacuum pugmill;
(2) then process sizing, impose on idiosome on by above-mentioned glaze water at porcelain embryo moisture 5% ~ 8% time, glaze thickness is 0.05mm;
(3) fire: within 60min, rise to 1150 DEG C, 90min at then remaining on 1150 DEG C from normal temperature heating;
(4) room temperature is cooled to, kiln discharge.
Embodiment 3
Coppery ceramic artistic glaze of the present invention, be made up of the raw material of following weight ratio:
Chromoxide green 28 parts, white 34 parts, material soil, red lead 38 parts, 3 parts, talcum.
Making processes is: mixed by the raw material of above-mentioned formula, by glaze porcelain vase ball milling, is milled to glaze fineness and tails at 10000-hole sieve and be less than 1.2%, so add water to glaze quality concentration 30%.
Be applied to and make ceramic statue, its process is:
(1) mud processed: after being mixed by the embryo mud prepared, grind to form siccative, and then refine into porcelain making embryo mud with vacuum pugmill;
(2) then process sizing, impose on idiosome on by above-mentioned glaze water at porcelain embryo moisture 4% ~ 5% time, the thickness of glaze layer is 0.08mm;
(3) fire: within 60min, rise to 1120 DEG C, 120min at then remaining on 1120 DEG C from normal temperature heating;
(4) room temperature is cooled to, kiln discharge.
Embodiment 4
Coppery ceramic artistic glaze of the present invention, be made up of the raw material comprising following weight ratio:
Chromoxide green 35 parts, white 40 parts, material soil, red lead 30 parts, 3 parts, zinc oxide.
Making processes is: mixed by the raw material of above-mentioned formula, by glaze porcelain vase ball milling, is milled to glaze fineness and tails at 10000-hole sieve and be less than 1.5%, so add water to glaze quality concentration 30%.
Be applied to and make ceramic statue, its process is:
(1) mud processed: after being mixed by the embryo mud prepared, grind to form siccative, and then refine into porcelain making embryo mud with vacuum pugmill;
(2) then process sizing, impose on idiosome on by above-mentioned glaze water at porcelain embryo moisture 4% ~ 5% time, the thickness of glaze layer is 0.08mm;
(3) fire: within 60min, rise to 1120 DEG C, 120min at then remaining on 1120 DEG C from normal temperature heating;
(4) room temperature is cooled to, kiln discharge.
Embodiment 5
Coppery ceramic artistic glaze of the present invention, be made up of the raw material of following weight ratio:
Chromoxide green 33 parts, white material soil 32 parts, red lead 35 parts.
Making processes is: mixed by the raw material of above-mentioned formula, by glaze porcelain vase ball milling, is milled to glaze fineness and tails at 10000-hole sieve and be less than 0.8%, so add water to glaze quality concentration 36%.
The application of coppery ceramic artistic glaze, its process is:
(1) mud processed: after being mixed by the embryo mud prepared, grind to form siccative, and then refine into porcelain making embryo mud with vacuum pugmill;
(2) then process sizing, impose on idiosome on by above-mentioned glaze water at porcelain embryo moisture 6% ~ 7% time, the thickness of glaze layer is 0.5mm;
(3) fire: within 60min, rise to 1170 DEG C, 60min at then remaining on 1170 DEG C from normal temperature heating;
(4) room temperature is cooled to, kiln discharge.
Embodiment 6
Coppery ceramic artistic glaze of the present invention, be made up of the raw material of following weight ratio:
Chromoxide green 33 parts, white material soil 32 parts, red lead 32 parts.
Making method: mixed by the raw material of above-mentioned formula, by glaze porcelain vase ball milling, is milled to glaze fineness and tails at 10000-hole sieve and be less than 0.5%, so add water to glaze quality concentration 34%.
The application of described coppery ceramic artistic glaze, its process is:
(1) mud processed: after being mixed by the embryo mud prepared, grind to form siccative, and then refine into porcelain making embryo mud with vacuum pugmill;
(2) then process sizing, impose on idiosome on by above-mentioned glaze water at porcelain embryo moisture 7% ~ 8% time, the thickness of glaze layer is 0.1mm;
(3) fire: within 60min, rise to 1160 DEG C, 1000min at then remaining on 1160 DEG C from normal temperature heating;
(4) room temperature is cooled to, kiln discharge.
Embodiment 7
Coppery ceramic artistic glaze of the present invention, be made up of the raw material of following weight ratio:
Chromoxide green 29 parts, white material soil 34 parts, red lead 34 parts.
Making processes is: mixed by the raw material of above-mentioned formula, by glaze porcelain vase ball milling, is milled to glaze fineness and tails at 10000-hole sieve and be less than 0.7%, so add water to glaze quality concentration 31%.
Application:
(1) mud processed: after being mixed by the embryo mud prepared, grind to form siccative, and then refine into porcelain making embryo mud with vacuum pugmill;
(2) then process sizing, impose on idiosome on by above-mentioned glaze water at porcelain embryo moisture 6% ~ 7% time, the thickness of glaze layer is 0.02mm;
(3) fire: within 60min, rise to 1150 DEG C, 100min at then remaining on 1150 DEG C from normal temperature heating;
(4) room temperature is cooled to, kiln discharge.
Embodiment 8
Coppery ceramic artistic glaze of the present invention, be made up of the raw material of following weight ratio:
Chromoxide green 31 parts, white material soil 36 parts, red lead 36 parts.
Making processes is: mixed by the raw material of above-mentioned formula, by glaze porcelain vase ball milling, is milled to glaze fineness and tails at 10000-hole sieve and be less than 1.2%, so add water to glaze quality concentration 33%.
Be applied to potting porcelain sculpture:
(1) mud processed: after being mixed by the embryo mud prepared, grind to form siccative, and then refine into porcelain making embryo mud with vacuum pugmill;
(2) then process sizing, impose on idiosome on by above-mentioned glaze water at porcelain embryo moisture 5% ~ 6% time, the thickness of glaze layer is 1mm;
(3) fire: within 60min, rise to 1160 DEG C, 90min at then remaining on 1160 DEG C from normal temperature heating;
(4) room temperature is cooled to, kiln discharge.
Embodiment 9
Coppery ceramic artistic glaze of the present invention, be made up of the raw material of following weight ratio:
Chromoxide green 34 parts, white material soil 33 parts, red lead 33 parts.
Making processes is: mixed by the raw material of above-mentioned formula, by glaze porcelain vase ball milling, is milled to glaze fineness and tails at 10000-hole sieve and be less than 1.2%, so add water to glaze quality concentration 34%.
Be applied to potting porcelain sculpture:
(1) mud processed: after being mixed by the embryo mud prepared, grind to form siccative, and then refine into porcelain making embryo mud with vacuum pugmill;
(2) then process sizing, impose on idiosome on by above-mentioned glaze water at porcelain embryo moisture 5% ~ 6% time, the thickness of glaze layer is 1mm;
(3) fire: within 60min, rise to 1150 DEG C, 120min at then remaining on 1150 DEG C from normal temperature heating;
(4) room temperature is cooled to, kiln discharge.
Coppery ceramic artistic glaze of the present invention is easily constructed, and cost is lower, imposes on figure sculpture, firing time is short, substantially increases production efficiency, reduces production cost and energy consumption simultaneously, after firing, pottery is clear, and closely, its appearance presents bronze-colored the sculpture sound made with metallic copper, there is effect that copper statue is the same completely, copper can be substituted to make various statue, can saving copper resource greatly, reduce the cost of sculpture.The quality of pottery is light simultaneously, is convenient to carrying.
Above-described embodiment is the present invention's preferably embodiment; but embodiments of the present invention are not restricted to the described embodiments; change, the modification done under other any does not deviate from spirit of the present invention and principle, substitute, combine, simplify; all should be the substitute mode of equivalence, be included within protection scope of the present invention.

Claims (10)

1. a coppery ceramic artistic glaze, is characterized in that, is made up of the raw material comprising following weight ratio: chromoxide green 25 ~ 35 parts, white material soil 30 ~ 40 parts, red lead 30 ~ 40 parts.
2. coppery ceramic artistic glaze according to claim 1, is characterized in that, be made up of the raw material comprising following weight ratio: chromoxide green 28 ~ 32 parts, white material soil 32 ~ 38 parts, red lead 32 ~ 38 parts.
3. coppery ceramic artistic glaze according to claim 2, is characterized in that, be made up of the raw material comprising following weight ratio: chromoxide green 29 ~ 31 parts, white material soil 34 ~ 36 parts, red lead 34 ~ 36 parts.
4. coppery ceramic artistic glaze according to claim 3, is characterized in that, be made up of the raw material comprising following weight ratio: chromoxide green 30 parts, white material soil 35 parts, red lead 35 parts.
5. coppery ceramic artistic glaze according to claim 1, is characterized in that, be made up of the raw material comprising following weight ratio: chromoxide green 33 parts, white material soil 32 parts, red lead 32 parts.
6. coppery ceramic artistic glaze according to claim 1, is characterized in that, be made up of the raw material comprising following weight ratio: chromoxide green 30 parts, white material soil 33 parts, red lead 33 parts.
7. coppery ceramic artistic glaze according to Claims 1 to 4 any one claim, is characterized in that, also comprise the raw material of following weight: 2 ~ 4 parts, zinc oxide.
8. coppery ceramic artistic glaze according to Claims 1 to 4 any one claim, is characterized in that, also comprise the raw material of following weight: 3 parts, zinc oxide.
9. coppery ceramic artistic glaze according to Claims 1 to 4 any one claim, is characterized in that, also comprise the raw material of following weight: 2 ~ 4 parts, talcum.
10. coppery ceramic artistic glaze according to Claims 1 to 4 any one claim, is characterized in that, also comprise the raw material of following weight: 3 parts, talcum.
CN201510148877.XA 2015-03-31 2015-03-31 Purple-bronze ceramic art glaze Pending CN104744079A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105906381A (en) * 2016-03-28 2016-08-31 河南科技学院 Making method for purple bronze ceramic artwork
CN114605072A (en) * 2022-03-15 2022-06-10 福建省德化县零度创意有限公司 Full-glaze vermilion porcelain and preparation process thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102515852A (en) * 2011-12-30 2012-06-27 江苏拜富科技有限公司 High-temperature preparation method of chrome-tin purple pigment
CN102795890A (en) * 2012-07-06 2012-11-28 佛山市南海万兴材料科技有限公司 Chrome-carried tin oxide violet ceramic pigment and preparation method thereof
CN104230379A (en) * 2013-06-24 2014-12-24 魏红霞 Preparation method of relief glaze

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102515852A (en) * 2011-12-30 2012-06-27 江苏拜富科技有限公司 High-temperature preparation method of chrome-tin purple pigment
CN102795890A (en) * 2012-07-06 2012-11-28 佛山市南海万兴材料科技有限公司 Chrome-carried tin oxide violet ceramic pigment and preparation method thereof
CN104230379A (en) * 2013-06-24 2014-12-24 魏红霞 Preparation method of relief glaze

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105906381A (en) * 2016-03-28 2016-08-31 河南科技学院 Making method for purple bronze ceramic artwork
CN105906381B (en) * 2016-03-28 2018-08-14 河南科技学院 A kind of production method of coppery ceramics
CN114605072A (en) * 2022-03-15 2022-06-10 福建省德化县零度创意有限公司 Full-glaze vermilion porcelain and preparation process thereof
CN114605072B (en) * 2022-03-15 2023-05-23 福建省德化县零度创意有限公司 Full-glaze cinnabar-red porcelain and preparation process thereof

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