CN104733656A - Ceramic sealing battery - Google Patents

Ceramic sealing battery Download PDF

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Publication number
CN104733656A
CN104733656A CN201510104392.0A CN201510104392A CN104733656A CN 104733656 A CN104733656 A CN 104733656A CN 201510104392 A CN201510104392 A CN 201510104392A CN 104733656 A CN104733656 A CN 104733656A
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CN
China
Prior art keywords
cover plate
ceramic
pole
ceramic ring
battery according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510104392.0A
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Chinese (zh)
Inventor
黄志彬
梁伟雄
李昶怡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LITHIUM FORCE HOLDING Co Ltd
Original Assignee
LITHIUM FORCE HOLDING Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LITHIUM FORCE HOLDING Co Ltd filed Critical LITHIUM FORCE HOLDING Co Ltd
Priority to CN201510104392.0A priority Critical patent/CN104733656A/en
Publication of CN104733656A publication Critical patent/CN104733656A/en
Pending legal-status Critical Current

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Connection Of Batteries Or Terminals (AREA)
  • Sealing Battery Cases Or Jackets (AREA)

Abstract

The invention relates to the technical field of battery sealing and more particularly relates to sealing technology and structure of power batteries of hybrid electric vehicles or pure electric vehicles. A ceramic sealing battery comprises a battery shell, wherein a cover plate is arranged on the battery shell; an electrode column is inserted into the cover plate; a ceramic ring is fixed between the electrode column and the cover plate in a welding manner, and is sealed between the electrode column and the cover plate. The ceramic sealing battery provided by the invention has relatively good sealing performance, relatively long service life and relatively good reliability.

Description

A kind of ceramic seal battery
Technical field
The present invention relates to cell sealing technical field, more specifically, relate to Sealing Technology and the structure of a kind of hybrid vehicle or power battery of pure electric automobile.
Background technology
The sealing means overwhelming majority of existing electrokinetic cell uses organic material sealing ring (as organic materials such as polyethylene, fluorubber, PFA), there is ageing hardening in such sealing ring long-time use under stress and hot conditions, the possibility become fragile, thus lose its sealing, sealing loses and the water in air and oxygen can be caused to enter in battery, battery meeting premature failure, bring hidden danger also can to the security performance of battery.
Summary of the invention
Technical problem to be solved by this invention is, provides that a kind of sealing property is better, the life-span is longer, the battery of the ceramic seal of better reliability.
For solving the problems of the technologies described above, the technical solution used in the present invention is:
A kind of ceramic seal battery, comprise battery container, described battery container is provided with cover plate, described cover plate is fitted with pole, be welded with ceramic ring between described pole and cover plate, described ceramic ring is sealed between described pole and cover plate.
In this programme, sealed by ceramic ring between pole and cover plate, there is good high temperature resistant, high strength, high rigidity, good electrical property, hot property and chemical stability.Adopt the mode of refractory ceramics insulated enclosure to extend the useful life of sealing, also extend the useful life of battery simultaneously.In addition, by welding mode, can allow ceramic ring firmly with pole and cover plate compact siro spinning technology.
Further, the metal level be respectively equipped with between described pole and ceramic ring and between cover plate and ceramic ring, thus can realize welding better.
Further, the material of described metal level is the mixing of a kind of in silver, copper, aluminium, nickel, molybdenum, manganese or at least two kinds.
Further, the thickness of described metal level is 0.1 ~ 100 μm.The advantage of metal layer thickness is metal level and ceramic good bonding strength, and when thickness is greater than 100 μm, metal level and ceramic junction are made a concerted effort can be influenced, becomes the short slab of total part.
Further, pass through Welding between described ceramic ring and pole and cover plate.Soldering can weld dissimilar metal, also can weld foreign material, and to thickness of workpiece difference without strict restriction, is thus applicable to ceramic ring and welding between pole, cover plate.In addition, the thermal endurance of soldering is not high, when battery runs into high-temperature condition, weld is by high temperature, and the sealing now between pole and cover plate will be destroyed, therefore disappointing function can be played, it should be noted that, it is all generally because there is uncontrollable reaction that battery destroys, and produces a large amount of heats and gas in the short time, if can not release heat and gas in good time, battery will be blasted.Therefore this programme can allow battery automatically open function of losing heart when producing high temperature, thus pressure release, avoid battery explosion.
Further, the solder that uses of the soldering mixing that is a kind of in Sn, Ag, Cu, Mg, Al, Si, Ni or at least two kinds.When welding aluminum or aluminum alloy and pottery, welding temperature is 300 ~ 660 DEG C, welds in atmosphere or welds in vacuum, N2, nitrogen and hydrogen mixture; When soldering copper or copper alloy and pottery, welding temperature is 300 ~ 1083 DEG C, in atmosphere welding or weld in vacuum, N2, nitrogen and hydrogen mixture.By experiment, above-mentioned soldering scheme can allow the weld of battery can by high temperature between 250 ~ 400 DEG C, and be more conducive to the explosion prevention function of battery, fail safe is better.
Further, the material of described ceramic ring is the mixing of a kind of in aluminium oxide, zirconia, silica, silicon nitride or aluminium nitride or at least two kinds.
Further, described ceramic ring is that toroidal or the band toroidal of boss or I-shaped are circular.Circular annular form with boss or the circular contact area can guaranteed with pole and cover plate of I-shaped, make sealing more firm and reliable, sealing property is better.
Further, the material of described pole and cover plate is the one in copper, copper alloy, aluminium, aluminium alloy, and the surface of described pole and cover plate is provided with electrodeposited coating, and the material of electrodeposited coating is the compound of a kind of in gold, silver, copper, chromium, tin, nickel or at least two kinds.
Compared with prior art, the invention has the beneficial effects as follows:
Owing to being sealed by ceramic ring between pole and cover plate, thus there is good high temperature resistant, high strength, high rigidity, good electrical property, hot property and chemical stability.Adopt the mode of refractory ceramics insulated enclosure to extend the useful life of sealing, also extend the useful life of battery simultaneously.In addition, by welding mode, can allow ceramic ring firmly with pole and cover plate compact siro spinning technology.In addition, being welded by the mode of soldering, battery can being allowed automatically to open function of losing heart when producing high temperature, thus pressure release, avoid battery explosion.
Accompanying drawing explanation
Fig. 1 is the plan structure schematic diagram of the battery of ceramic seal of the present invention.
Fig. 2 is the enlarged cross sectional views of pole position.
Fig. 3 is pole cross section partial enlarged drawing.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.Wherein, accompanying drawing only for exemplary illustration, expression be only schematic diagram, but not pictorial diagram, can not be interpreted as the restriction to this patent; In order to better embodiments of the invention are described, some parts of accompanying drawing have omission, zoom in or out, and do not represent the size of actual product; For a person skilled in the art, in accompanying drawing, some known features and explanation thereof may be omitted is understandable.
As shown in Figure 1, the present invention discloses a kind of battery of ceramic seal, comprise battery container, the battery roll core be located in housing, the collector plate be located in housing, be located at the cover plate 3 on battery container and be plugged in the positive and negative pole 1,2 on cover plate 3, positive and negative pole 1,2 is connected with collector plate by lug, wherein, pole 1,2 is tightly connected by ceramic ring 4 and cover plate 3.Battery case, comprise pole 1,2, the component external such as ceramic ring 4 can with PP(high polymer polypropylene), PC(Merlon) etc. organic material protect.Ceramic ring 4 is that toroidal or the band toroidal of boss or I-shaped are circular.
Ceramic ring 4 is that pottery is obtained, and it is that raw material is made that pottery is with one or more metal oxides or nitride, has higher melt temperature, highly stable in oxidizing atmosphere, and higher mechanical strength, electrical insulation capability and chemical stability.In the present embodiment, the material of ceramic ring is the mixing of a kind of in aluminium oxide, zirconia, silica, silicon nitride or aluminium nitride or at least two kinds.
Fixed by soldering between described ceramic ring 4 and pole 1,2 and cover plate 3.In order to realize better welding effect, described ceramic ring 4 all forms a metal level 5 through metalized with pole 1,2 and cover plate 3 contact position, is and forms layer of metal layer by various process for treating surface at the nonmetallic surface of ceramic ring and pole and cover plate.Described metal layer material is the mixing of a kind of in silver, copper, aluminium, nickel, molybdenum, manganese or at least two kinds.Metal layer thickness is 0.1 ~ 100 μm.What the solder that soldering uses was a kind of in Sn, Ag, Cu, Mg, Al, Si, Ni or at least two kinds is mixed.
Pole, cover plate materials are copper or copper alloy, and when soldering copper or copper alloy and ceramic ring, welding temperature is 300 ~ 1083 DEG C, in atmosphere welding or weld in vacuum, N2, nitrogen and hydrogen mixture; Because ceramic material surfaces structure is different from metal material surface structure, welding often can not soak ceramic surface, can not act on it and be formed and firmly cohere, thus pottery is a kind of special process with the sealing-in of metal, i.e. metallized method: first firmly stick layer of metal film at ceramic surface, thus realize welding of pottery and metal.
In addition, if described pole, cover plate materials aluminum or aluminum alloy, when welding aluminum or aluminum alloy and ceramic ring, welding temperature is 300 ~ 660 DEG C, welds in atmosphere or welds in vacuum, N2, nitrogen and hydrogen mixture.Or also can plate nickel dam in pole, lid surface, technique and the above-mentioned technique of nickel dam are similar.
In the present embodiment, Positive Poles 1 material is aluminum or aluminum alloy, and negative pole pole 2 material is copper or copper alloy, and cover plate 3 material is the one in aluminium, aluminium alloy or stainless steel, ceramic ring 4 both sides, respectively by the mode of high-temperature process and plating, form the nickel dam of a layer thickness about 30 μm on surface.Fig. 2 is the enlarged cross sectional views of pole position.
Production process: first positive and negative electrode pole, cover plate are put in ceramic annulus respectively, pole is at nexine, ceramic ring is in centre, cover plate is at skin, as shown in Figure 2, evenly coating main material between annulus and pole is the solder of one or more in Ag, Sn, Cu, Mg, Ni, under vacuum atmosphere, high-temperature process under 300 DEG C of conditions, allows ceramic ring and both positive and negative polarity pole, bridge welding be connected together.
The ceramic ring having welded negative pole pole is connected with cover plate, and Positive Poles and another ceramic ring and cover plate is socketed mutually, pole at nexine, ceramic ring in centre, cover plate at skin, as shown in Figure 3 (Fig. 3 is pole cross section partial enlarged drawing).It is the solder of one or more in Ag, Sn, Cu, Mg, Ni that each interlayer spacings coats main material equably.
As shown in 5 in Fig. 3, at N2 protective atmosphere, high-temperature process under 300 DEG C of conditions, allows ceramic ring and Positive Poles, and bridge welding is connected together.
Obviously, the above embodiment of the present invention is only for example of the present invention is clearly described, and is not the restriction to embodiments of the present invention.For those of ordinary skill in the field, can also make other changes in different forms on the basis of the above description, exhaustive without the need to also giving all execution modes here.All any amendments done within the spirit and principles in the present invention, equivalent to replace and improvement etc., within the protection range that all should be included in the claims in the present invention.

Claims (10)

1. a ceramic seal battery, comprises battery container, it is characterized in that, described battery container is provided with cover plate, described cover plate is fitted with pole, is welded with ceramic ring between described pole and cover plate, described ceramic ring is sealed between described pole and cover plate.
2. ceramic seal battery according to claim 1, is characterized in that, the metal level be respectively equipped with between described pole and ceramic ring and between cover plate and ceramic ring.
3. ceramic seal battery according to claim 2, is characterized in that, the material of described metal level is the mixing of a kind of in silver, copper, aluminium, nickel, molybdenum, manganese or at least two kinds.
4. ceramic seal battery according to claim 3, is characterized in that, the thickness of described metal level is 0.1 ~ 100 μm.
5. ceramic seal battery according to claim 1, is characterized in that, passes through Welding between described ceramic ring and pole and cover plate.
6. ceramic seal battery according to claim 5, is characterized in that, the mixing that the solder that soldering uses is a kind of in Sn, Ag, Cu, Mg, Al, Si, Ni or at least two kinds.
7. ceramic seal battery according to claim 6, is characterized in that, when welding aluminum or aluminum alloy and ceramic ring, welding temperature is 300 ~ 660 DEG C, welds in atmosphere or welds in vacuum, N2, nitrogen and hydrogen mixture; When soldering copper or copper alloy and ceramic ring, welding temperature is 300 ~ 1083 DEG C, in atmosphere welding or weld in vacuum, N2, nitrogen and hydrogen mixture.
8. ceramic seal battery according to claim 1, is characterized in that, the material of described ceramic ring is the mixing of a kind of in aluminium oxide, zirconia, silica, silicon nitride or aluminium nitride or at least two kinds.
9. ceramic seal battery according to claim 1, is characterized in that, described ceramic ring is that toroidal or the band toroidal of boss or I-shaped are circular.
10. ceramic seal battery according to claim 1, it is characterized in that, the material of described pole and cover plate is the one in copper, copper alloy, aluminium, aluminium alloy, the surface of described pole and cover plate is provided with electrodeposited coating, and the material of electrodeposited coating is the compound of a kind of in gold, silver, copper, chromium, tin, nickel or at least two kinds.
CN201510104392.0A 2015-03-10 2015-03-10 Ceramic sealing battery Pending CN104733656A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510104392.0A CN104733656A (en) 2015-03-10 2015-03-10 Ceramic sealing battery

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Application Number Priority Date Filing Date Title
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105161640A (en) * 2015-08-26 2015-12-16 惠州亿纬锂能股份有限公司 Cover plate assembly and battery comprising same
CN105679989A (en) * 2016-03-16 2016-06-15 惠州亿纬科技有限公司 Manufacturing method of battery electrode terminal
CN106450068A (en) * 2016-10-26 2017-02-22 东莞市盖瓷新能源科技有限公司 Power battery polar column ceramic sealing device and sealing achieving method
CN106784450A (en) * 2017-01-19 2017-05-31 佛山市康荣精细陶瓷有限公司 A kind of sealed cover plate structure of lithium battery and preparation method thereof
CN108198966A (en) * 2017-12-01 2018-06-22 力神动力电池系统有限公司 A kind of battery cover board with novel pole sealing structure
CN115347288A (en) * 2021-05-13 2022-11-15 荣盛盟固利新能源科技有限公司 Battery cover plate and power battery
CN115360463A (en) * 2022-08-05 2022-11-18 新化柏盛陶瓷科技有限公司 Ceramic sealer for lithium battery and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013000416A1 (en) * 2011-06-28 2013-01-03 Shenzhen Byd Auto R & D Company Limited Cover assembly and lithium ion battery comprising the same
CN103441224A (en) * 2013-09-02 2013-12-11 广州力柏电动科技有限公司 Ceramic sealed battery
CN203386821U (en) * 2013-09-02 2014-01-08 广州力柏电动科技有限公司 Porcelain-sealed battery
CN204632818U (en) * 2015-03-10 2015-09-09 广州力柏电动科技有限公司 A kind of ceramic seal battery

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013000416A1 (en) * 2011-06-28 2013-01-03 Shenzhen Byd Auto R & D Company Limited Cover assembly and lithium ion battery comprising the same
CN103441224A (en) * 2013-09-02 2013-12-11 广州力柏电动科技有限公司 Ceramic sealed battery
CN203386821U (en) * 2013-09-02 2014-01-08 广州力柏电动科技有限公司 Porcelain-sealed battery
CN204632818U (en) * 2015-03-10 2015-09-09 广州力柏电动科技有限公司 A kind of ceramic seal battery

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105161640A (en) * 2015-08-26 2015-12-16 惠州亿纬锂能股份有限公司 Cover plate assembly and battery comprising same
CN105679989A (en) * 2016-03-16 2016-06-15 惠州亿纬科技有限公司 Manufacturing method of battery electrode terminal
CN106450068A (en) * 2016-10-26 2017-02-22 东莞市盖瓷新能源科技有限公司 Power battery polar column ceramic sealing device and sealing achieving method
CN106450068B (en) * 2016-10-26 2023-01-24 东莞市盖瓷新能源科技有限公司 Power battery pole ceramic sealing device and sealing implementation method
CN106784450A (en) * 2017-01-19 2017-05-31 佛山市康荣精细陶瓷有限公司 A kind of sealed cover plate structure of lithium battery and preparation method thereof
CN108198966A (en) * 2017-12-01 2018-06-22 力神动力电池系统有限公司 A kind of battery cover board with novel pole sealing structure
CN115347288A (en) * 2021-05-13 2022-11-15 荣盛盟固利新能源科技有限公司 Battery cover plate and power battery
CN115360463A (en) * 2022-08-05 2022-11-18 新化柏盛陶瓷科技有限公司 Ceramic sealer for lithium battery and preparation method thereof
CN115360463B (en) * 2022-08-05 2024-04-16 新化柏盛陶瓷科技有限公司 Ceramic sealer for lithium battery and preparation method thereof

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Application publication date: 20150624