Summary of the invention
In view of this, the invention provides a kind of analysis measuring apparatus and liquid analysis system, fundamental purpose is the accurate measurement of the liquid solving the inaccurate problem of liquid meter and realize different volumes, improves the measuring accuracy of liquid analysis system.
For achieving the above object, the present invention mainly provides following technical scheme:
On the one hand, embodiments of the invention provide a kind of and analyze measuring apparatus, comprising:
First operation valve, it comprises public port and multiple distribution ports that alternatively can be communicated with described public port, and described multiple distribution port comprises an air port be connected with air;
Reaction analytical equipment, it has first passage mouth and second channel mouth;
Gauge line, its one end is connected with described public port by the second operation valve, the other end is connected with described first passage mouth, the tube wall of described gauge line is provided with the first connection mouth of pipe, described first connects the mouth of pipe connects the first sewer pipe by the 3rd operation valve, wherein, described gauge line is the pipe that internal diameter is less than 4mm.
Fluid driver, is connected with described reaction analytical equipment.
Foregoing, the internal diameter of described gauge line is within the scope of 0.2mm-2mm.
Foregoing, the internal diameter of described reaction analytical equipment is greater than 6 millimeters.
Foregoing, also comprise: detector of liquid, described detector of liquid is arranged on described gauge line.
Foregoing, described detector of liquid is arranged on described gauge line and is specially:
Described detector of liquid is arranged on described first passage mouth and described first and connects in the line segments between the mouth of pipe.
Foregoing, also comprise: connecting pipe;
Described fluid driver is connected with described reaction analytical equipment and is specially:
Described fluid driver is connected with described second channel mouth by described connecting pipe.
Foregoing, described fluid driver is connected with described reaction analytical equipment and is specially:
Described fluid driver is arranged in the line segments of described gauge line, and described second channel mouth is connected with air.
Foregoing, described fluid driver is arranged in the line segments of described gauge line and is specially:
Described fluid driver is arranged in the line segments between described detector of liquid and described first passage mouth; Or,
Described fluid driver is arranged on described detector of liquid and described first and connects in the line segments between the mouth of pipe; Or,
Described fluid driver is arranged in the described first line segments connected between the mouth of pipe and described second operation valve.
Foregoing, also comprise: at least one the 4th operation valve;
The tube wall of described gauge line is also provided with at least one second connection mouth of pipe, and connects on the tube wall between the mouth of pipe and described second operation valve described first;
At least one second connection mouth of pipe described connects the second sewer pipe by least one the 4th operation valve described.
On the one hand, embodiments of the invention provide a kind of liquid analysis system, and it comprises:
First operation valve, it comprises public port and multiple distribution ports that alternatively can be communicated with described public port, and described multiple distribution port comprises an air port be connected with air;
Reaction analytical equipment, it has first passage mouth and second channel mouth;
Gauge line, its one end is connected with described public port by the second operation valve, the other end is connected with described first passage mouth, the tube wall of described gauge line is provided with the first connection mouth of pipe, described first connects the mouth of pipe connects the first sewer pipe by the 3rd operation valve, wherein, described gauge line is the pipe that internal diameter is less than 4mm.
Fluid driver, is connected with described reaction analytical equipment;
Control circuit, for controlling unlatching and the stopping of the work of described first operation valve, described reaction analytical equipment, described second operation valve, described 3rd operation valve and described fluid driver;
Wherein, described first operation valve, described reaction analytical equipment, described second operation valve, described 3rd operation valve and described fluid driver are all connected with described control circuit.
By technique scheme, the present invention's one analyzes measuring apparatus and liquid analysis system at least has following advantages:
Analysis measuring apparatus of the present invention is by arranging the first operation valve, second operation valve, gauge line, reaction analytical equipment and fluid driver connected in series, and the multiple distribution ports arranging the first operation valve comprise an air port be connected with air, make the present invention when feed liquor or discharge opeing, liquid moves all the time in the same direction, avoid sequential injection formula flow path system must by the defect of liquid storage unit transfer liquid, the length and the tube wall surface that decrease stream flows through conduit during feed liquor amass, thus decrease the probability of liquid residual liquid film or wall built-up on tube wall, improve the precision of feed liquor, especially improve the feed liquor precision when micro-liquid inlet volume (as below 0.1ml), and due to the undersized structural design of gauge line: gauge line is the pipe that internal diameter is less than 4mm, make liquid in tubule, utilize surface tension of liquid and viscosity liquid upwards directly successfully can be flowed in reaction analytical equipment, thus make liquid along tube wall, refluence phenomenon can not occur, on the other hand by arranging gauge line, its one end is connected with public port by the second operation valve, the other end is connected with first passage mouth, the tube wall of gauge line is provided with the first connection mouth of pipe, first connects the mouth of pipe connects the first sewer pipe by the 3rd operation valve, making the present invention when discharging waste liquid, only needing closedown second operation valve and opening the 3rd operation valve just can very easily the waste liquid in gauge line and the waste liquid in reaction analytical equipment be discharged smoothly.
Above-mentioned explanation is only the general introduction of technical solution of the present invention, in order to better understand technological means of the present invention, and can be implemented according to the content of instructions, coordinates accompanying drawing to be described in detail as follows below with preferred embodiment of the present invention.
Embodiment
For further setting forth the present invention for the technological means reaching predetermined goal of the invention and take and effect, below in conjunction with accompanying drawing and preferred embodiment, to according to the embodiment of the present patent application, structure, feature and effect thereof, be described in detail as follows.In the following description, the not necessarily same embodiment that different " embodiment " or " embodiment " refers to.In addition, special characteristic, structure or feature in one or more embodiment can be combined by any suitable form.
As shown in Figure 1, the one that one embodiment of the present of invention propose analyzes measuring apparatus, and it comprises:
First operation valve 1, reaction analytical equipment 2, gauge line 3, second operation valve 4, the 3rd operation valve 5 and fluid driver 6.Wherein,
First operation valve 1, it comprises public port 11 and multiple distribution ports 12 that alternatively can be communicated with described public port 11, and described multiple distribution port 12 comprises an air port be connected with air 121;
Reaction analytical equipment 2, it has first passage mouth 21 and second channel mouth 22;
Gauge line 3, its one end is connected with described public port 11 by the second operation valve 4, the other end is connected with described first passage mouth 21, the tube wall 31 of described gauge line 3 is provided with the first connection mouth of pipe 311, described first connects the mouth of pipe 311 connects the first sewer pipe (not shown) by the 3rd operation valve 5, wherein, described gauge line 3 is less than the pipe of 4mm for internal diameter.
Fluid driver 6, is connected with described reaction analytical equipment 2.
Concrete, first operation valve 1 is for sample introduction and switch different types of liquid, it has public port 11 and multiple distribution port 12, can alternatively be communicated with public port 11, and the control as by control system realizes public port 11 and distributes being communicated with of port 12 with any one.According to test needs, part in multiple distribution port 12 distribute port be used for respectively with the connection such as different types of testing liquid, waste fluid container; Air port 121 is connected with air, when public port 11 be switched to be communicated with air port 121 time, can to suction air in pipeline and reaction analytical equipment 2, to realize the function liquid in gauge line 3 being sent into reaction analytical equipment 2, also can liquid in hybrid reaction analytical equipment 2, or detergent line.The quantity of distributing port 12 can be selected according to actual needs.Certain first operation valve 1 can also for be made up of multiple two-port valve and some connecting pipes; the two ends of each two-port valve connect public port respectively and distribute port; form a multichannel operation valve; the concrete embodiment of the present invention does not limit this, as long as it can have the protection domain that a public port and multiple distribution ports that can alternatively be communicated with described public port all belong to the embodiment of the present invention.
Reaction analytical equipment 2 is for storing the different types of liquid after metering, and different types of liquid reacts in reaction analytical equipment 2, and passes through the correlation properties of liquid in some detection part detection reaction analytical equipments 2.Reaction analytical equipment 2 can be structure as a whole; also can be the Split type structure comprising reaction unit and analytical equipment; the concrete embodiment of the present invention does not limit this, as long as it function of realization response and analysis can all belong to the protection domain of the embodiment of the present invention.
The analysis measuring apparatus of the embodiment of the present invention is by arranging the first operation valve 1, second operation valve 4, gauge line 3, reaction analytical equipment 2 and fluid driver 6 connected in series, and the multiple distribution ports 12 arranging the first operation valve 1 comprise an air port be connected with air 121, make the present invention when feed liquor or discharge opeing, liquid moves all the time in the same direction, avoid sequential injection formula flow path system must by the defect of liquid storage unit transfer liquid, the length and the tube wall surface that decrease stream flows through conduit during feed liquor amass, thus decrease the probability of liquid residual liquid film or wall built-up on tube wall, improve the precision of feed liquor, especially improve the feed liquor precision when micro-liquid inlet volume (as below 0.1ml), and due to the undersized structural design of gauge line: gauge line is the pipe that internal diameter is less than 4mm, make liquid in tubule, utilize surface tension of liquid and viscosity liquid upwards directly successfully can be flowed in reaction analytical equipment 2, thus make liquid along tube wall, refluence phenomenon can not occur, on the other hand by arranging gauge line 3, its one end is connected with public port 11 by the second operation valve 4, the other end is connected with first passage mouth 21, the tube wall 31 of gauge line 3 is provided with the first connection mouth of pipe 311, first connects the mouth of pipe 311 connects the first sewer pipe by the 3rd operation valve 5, making the present invention when discharging waste liquid, only needing closedown second operation valve 4 and opening the 3rd operation valve 5 just can very easily the waste liquid in the waste liquid in gauge line 3 and reaction analytical equipment 2 be discharged smoothly.
Further, in tubule, utilize surface tension of liquid and viscosity liquid upwards directly successfully all can be sent in reaction analytical equipment 2 to make liquid, the internal diameter of described gauge line 3 is within the scope of 0.2mm-2mm, now, in gauge line 3, utilize surface tension of liquid and viscosity liquid upwards directly successfully all can be sent in reaction analytical equipment 2, thus make liquid along tube wall, refluence phenomenon can not occur.
Further, conveniently various liquid carries out reacting and carry out detection analysis in reaction analytical equipment 2, the internal diameter of described reaction analytical equipment 2 is greater than 6 millimeters, the design of this structure, facilitate various liquid Homogeneous phase mixing in reaction analytical equipment 2, and unnecessary bubble is discharged from reaction analytical equipment 2.
Further, in order to improve feed liquor efficiency, as shown in Figure 1, also comprise: detector of liquid 7; Described detector of liquid 7 is arranged on described gauge line 3.
Concrete; detector of liquid 7 be not with the contactless liquid level sensor of fluid contact; or be not with the photoelectrometer measuring device of fluid contact; certainly can also be other not with the non-contact liquid detecting device of fluid contact; also can be the detector of liquid with liquid comes into contact; whether the concrete embodiment of the present invention does not limit this, have liquid to there is the protection domain all belonging to the embodiment of the present invention as long as it can detect somewhere in gauge line.
Further, described detector of liquid 7 is arranged in the line segments between described first passage mouth 21 and the described first connection mouth of pipe 311.
Further, described analysis measuring apparatus also comprises: connecting pipe 8; As shown in Figure 1, described fluid driver 6 is connected with described second channel mouth 22 by connecting pipe 8.
Further, except described fluid driver 6 to be connected with described second channel mouth 22 by connecting pipe 8, fluid driver 6 can also be arranged in the line segments of described gauge line 3, as shown in Figure 2, described fluid driver 6 is arranged in the line segments of described gauge line 3; Described second channel mouth 22 is connected with air.
Further, described fluid driver 6 can be arranged in the line segments between described detector of liquid 7 and described first passage mouth 21, also can be arranged on described detector of liquid 7 and described first to connect in the line segments between the mouth of pipe 311, can also be arranged in the described first line segments connected between the mouth of pipe 311 and described second operation valve 4.Concrete the present invention executes example and does not limit this, as long as it can drive liquid to flow to through the first operation valve and the second operation valve the protection domain that reaction analytical equipment all belongs to the embodiment of the present invention.
The embodiment of the present invention is by being arranged in the line segments of described gauge line 3 by fluid driver 6, making to analyze measuring apparatus 2 can drive liquid to flow to reaction analytical equipment 2 through the first operation valve 1 and the second operation valve 4 by fluid driver 6, and because the second channel mouth 22 arranging reaction analytical equipment 2 is connected with air, the space relative atmospheric on reaction analytical equipment 2 top is made no longer to have malleation or negative pressure, when fluid driver 6 stops driving, liquid can stop flowing immediately, and the liquid level in reaction analytical equipment 2 also can not produce disturbance.Whereby, the volume accuracy analyzing the liquid that measuring apparatus is got can be ensured; In addition, itself just ended the flowing of liquid when fluid driver 6 does not work, be equivalent to the function of stop valve.
Further, in order to discharge unnecessary liquid, and automatic effluent discharge after water analysis completes, do not need additionally to arrange pumping equipment, described fluid driver 6 is the fluid driver of positive and negative bi-directional drive, wherein, fluid driver 6 can be peristaltic pump, when peristaltic pump quits work, itself end the flowing of liquid, be equivalent to the function of stop valve.Certain fluid driver 6 can also be the combination of other types pump and valve, and the concrete embodiment of the present invention does not limit this, as long as it is bi-directional drive and the fluid driver with stop valve function all belongs to the protection domain of the embodiment of the present invention.
Further, in order to realize the accurate measurement of the liquid of more different volumes, described analysis measuring apparatus also comprises: at least one the 4th operation valve 9, as shown in Figure 3,
The tube wall 31 of described gauge line 3 is also provided with at least one second connection mouth of pipe 312, and connects on the tube wall between the mouth of pipe 311 and described second operation valve 4 described first;
At least one second connection mouth of pipe 312 described connects the second sewer pipe (not shown) by least one the 4th operation valve 9 described.
Further, as shown in Figure 4, reaction analytical equipment 2 comprises light source 23 and photodetector 24.
When reaction analytical equipment 2 is structure as a whole, as shown in Figure 4, light source 23 and photodetector 24 are separately positioned on the both sides of reaction analytical equipment 2, and light source 23 and photodetector 24 are in same light path.After liquid in the light transmission reaction analytical equipment 2 that light source 23 is launched, received by photodetector 24, with the principle analysis liquid of luminosity colorimetric.
When reaction analytical equipment 2 is the Split type structure comprising reaction unit 25 and analytical equipment 26, as shown in Figure 5, analytical equipment is connected and the integral tube communicated continuously successively by first paragraph pipe 261, second segment pipe 262 and the 3rd section of pipe 263, wherein the tube wall of second segment pipe 262 both sides arranges plane light-transmission window respectively, and light source 23 and photodetector 24 are separately positioned on the both sides of second segment pipe 262.After liquid in the light transmission second segment pipe 262 that light source 23 is launched, received by photodetector 24, with the principle analysis liquid of luminosity colorimetric.
Further, reaction analytical equipment 2 also comprises electrode pair 27, and as shown in Figure 6, wherein, electrode pair 27 can be one or more pairs of,
When reaction analytical equipment 2 is structure as a whole, electrode pair 27 is arranged in reaction analytical equipment 2, when liquid enters in reaction analytical equipment 2 or after reacting in reaction analytical equipment 2, with potentiometry analytic liquid body.
When reaction analytical equipment 2 is Split type structure, electrode pair 27 is arranged in analytical equipment 26, when liquid enters after in analytical equipment 26, with potentiometry analytic liquid body.
Further, reaction analytical equipment 2 also comprises one or more ion-selective electrode 28, as shown in Figure 7;
When reaction analytical equipment 2 is structure as a whole, one or more ion-selective electrode 28 is arranged in reaction analytical equipment 2, after reaction, liquid is analyzed by selectivity through film and potentiometry when liquid enters in reaction analytical equipment 2 or in reaction analytical equipment 2.
When reaction analytical equipment 2 is Split type structure, one or more ion-selective electrode 28 is arranged in analytical equipment 26, when liquid enters after in analytical equipment 26, analyzes liquid by selectivity through film and potentiometry.
Further, reaction analytical equipment 2 can also comprise other the structure for analyzing liquid, and the concrete embodiment of the present invention does not limit, as long as it can analyze the protection domain that liquid all belongs to the embodiment of the present invention.
A kind of measuring apparatus of analyzing provided for Fig. 3 below illustrates how analysis measuring apparatus realizes the accurate measurement of the liquid of different volumes.
First the internal volume setting public port 11 and the second line segments connected between the mouth of pipe 312 is A, and the second internal volume connecting the mouth of pipe 312 and the first line segments connected between the mouth of pipe 311 is B.
Metering liquid volume is that the course of work of A+B is as follows:
The first step: the distribution port 12 the first operation valve 1 being switched to liquid to be got, public port 11 is connected with the distribution port 12 of liquid to be got, and opens the second operation valve 4; ;
Second step: control the work of fluid driver 6 forward drive, the liquid of distribution port 12 correspondence of liquid to be got is inhaled in gauge line 3 under the driving of fluid driver 6, when detector of liquid 7 detects liquid, fluid driver 6 quits work, or quits work after time delay a period of time;
3rd step: close the second operation valve 4, opens the 3rd operation valve 5;
4th step: fluid driver 6 reverse drive work, is discharged the liquid in the line segments between detector of liquid 7 and the first connection mouth of pipe 311 by the 3rd operation valve 5;
5th step: open the second operation valve 4, close the 3rd operation valve 5, first operation valve 1 and be switched to air port 121, public port 11 is communicated with air port 121;
6th step: fluid driver 6 forward drive work, until all import in reaction analytical equipment 2 by the liquid to be sampled in the line segments between public port 11 and the first connection mouth of pipe 311;
7th step: repeat the above-mentioned first step to the 6th step, can be transported to the liquid amount on demand corresponding to the distribution port 12 of the distribution port 12 of same first operation valve 1 or other the first operation valve 1 in reaction analytical equipment 2.
Metering liquid volume is that the course of work of A is as follows:
The first step: the distribution port 12 the first operation valve 1 being switched to liquid to be got, public port 11 is connected with the distribution port 12 of liquid to be got, and opens the second operation valve 4;
Second step: control the work of fluid driver 6 forward drive, the liquid of distribution port 12 correspondence of liquid to be got is inhaled in gauge line 3 under the driving of fluid driver 6, when detector of liquid 7 detects liquid, fluid driver 6 quits work, or quits work after time delay a period of time;
3rd step: close the second operation valve 4, opens the 4th operation valve 9;
4th step: fluid driver 6 reverse drive work, is discharged the liquid in the line segments between detector of liquid 7 and the second connection mouth of pipe 312 by the 4th operation valve 9;
5th step: open the second operation valve 4, close the 4th operation valve 9, the first operation valve 1 is switched to air port 121, and public port 11 is communicated with air port 121;
6th step: fluid driver 6 forward drive work, until all import in reaction analytical equipment 2 by the liquid to be sampled in the line segments between public port 11 and the second connection mouth of pipe 312;
7th step: repeat the above-mentioned first step to the 6th step, can be transported to the liquid amount on demand corresponding to the distribution port 12 of the distribution port 12 of same first operation valve 1 or other the first operation valve 1 in reaction analytical equipment 2.
By changing the position of not isometric gauge line 3 or rearrange liquids detecting device 7, the liquid volume entered in reaction analytical equipment 2 can be regulated.
More than analyze measuring apparatus and realize the course of work of the accurate measurement of the liquid of different volumes to comprise detector of liquid to illustrate, when analyzing measuring apparatus and not arranging detector of liquid, getting in liquid process, can carry out getting liquid according to the feed liquor time of setting.
The analysis measuring apparatus of the embodiment of the present invention is by arranging the first operation valve, second operation valve, gauge line, reaction analytical equipment and fluid driver connected in series, and the multiple distribution ports arranging the first operation valve comprise an air port be connected with air, make the present invention when feed liquor or discharge opeing, liquid moves all the time in the same direction, avoid sequential injection formula flow path system must by the defect of liquid storage unit transfer liquid, the length and the tube wall surface that decrease stream flows through conduit during feed liquor amass, thus decrease the probability of liquid residual liquid film or wall built-up on tube wall, improve the precision of feed liquor, especially improve the feed liquor precision when micro-liquid inlet volume (as below 0.1ml), and due to the undersized structural design of gauge line: gauge line is the pipe that internal diameter is less than 4mm, make liquid in tubule, utilize surface tension of liquid and viscosity liquid upwards directly successfully can be flowed in reaction analytical equipment, thus make liquid along tube wall, refluence phenomenon can not occur, on the other hand by arranging gauge line, its one end is connected with public port by the second operation valve, the other end is connected with first passage mouth, the tube wall of gauge line is provided with the first connection mouth of pipe, first connects the mouth of pipe connects the first sewer pipe by the 3rd operation valve, making the present invention when discharging waste liquid, only needing closedown second operation valve and opening the 3rd operation valve just can very easily the waste liquid in gauge line and the waste liquid in reaction analytical equipment be discharged smoothly.
The present invention also provides a kind of liquid analysis system, and it comprises:
First operation valve, it comprises public port and multiple distribution ports that alternatively can be communicated with described public port, and described multiple distribution port comprises an air port be connected with air;
Reaction analytical equipment, it has first passage mouth and second channel mouth;
Gauge line, its one end is connected with described public port by the second operation valve, the other end is connected with described first passage mouth, the tube wall of described gauge line is provided with the first connection mouth of pipe, described first connects the mouth of pipe connects the first sewer pipe by the 3rd operation valve, wherein, described gauge line is the pipe that internal diameter is less than 4mm;
Fluid driver, is connected with described reaction analytical equipment;
Control circuit, for controlling unlatching and the stopping of the work of described first operation valve, described reaction analytical equipment, described second operation valve, described 3rd operation valve and described fluid driver;
Wherein, described first operation valve, described reaction analytical equipment, described second operation valve, described 3rd operation valve and described fluid driver are all connected with described control circuit.
The liquid analysis system of the embodiment of the present invention is by arranging the first operation valve, second operation valve, gauge line, reaction analytical equipment and fluid driver connected in series, and the multiple distribution ports arranging the first operation valve comprise an air port be connected with air, make the present invention when feed liquor or discharge opeing, liquid moves all the time in the same direction, avoid sequential injection formula flow path system must by the defect of liquid storage unit transfer liquid, the length and the tube wall surface that decrease stream flows through conduit during feed liquor amass, thus decrease the probability of liquid residual liquid film or wall built-up on tube wall, improve the precision of feed liquor, especially improve the feed liquor precision when micro-liquid inlet volume (as below 0.1ml), and due to the undersized structural design of gauge line: gauge line is the pipe that internal diameter is less than 4mm, make liquid in tubule, utilize surface tension of liquid and viscosity liquid upwards directly successfully can be flowed in reaction analytical equipment, thus make liquid along tube wall, refluence phenomenon can not occur, on the other hand by arranging gauge line, its one end is connected with public port by the second operation valve, the other end is connected with first passage mouth, the tube wall of gauge line is provided with the first connection mouth of pipe, first connects the mouth of pipe connects the first sewer pipe by the 3rd operation valve, making the present invention when discharging waste liquid, only needing closedown second operation valve and opening the 3rd operation valve just can very easily the waste liquid in gauge line and the waste liquid in reaction analytical equipment be discharged smoothly.
The above, it is only preferred embodiment of the present invention, not do any pro forma restriction to the present invention, any simple modification done above embodiment according to technical spirit of the present invention, equivalent variations and modification, all still belong in the scope of technical solution of the present invention.