CN104726183A - Bio-rolling fluid composition - Google Patents
Bio-rolling fluid composition Download PDFInfo
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- CN104726183A CN104726183A CN201510064271.8A CN201510064271A CN104726183A CN 104726183 A CN104726183 A CN 104726183A CN 201510064271 A CN201510064271 A CN 201510064271A CN 104726183 A CN104726183 A CN 104726183A
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- polyol ester
- rolling fluid
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Abstract
The invention provides an environment-friendly bio-rolling fluid, which is composed of the following raw materials in parts by weight: 0.01-99 parts of oil-fat polyol ester, 0.01-99.0 parts of other base oils, 3.0-20.0 parts of an emulsifier, 2.0-10.0 parts of an extreme pressure agent, 3.0-15.0 parts of an anti-rust agent, 0.1-1.0 part of an oxidation and corrosion inhibitor, 0.2-0.3 part of an antibacterial agent, and 0.5-5.0 parts of a clearing agent. The rolling fluid disclosed by the invention is prepared by taking the oil-fat polyol ester (prepared by taking drainage oil, food pressed oil, cottonseed offal as raw materials) as a raw material, so that renewable resources are reasonably utilized, and green lubricating oil is developed, and therefore, the rolling fluid is of great environment protection significance.
Description
Technical field
The invention belongs to technical field of lubricating oil, relate generally to one and utilize bio-based lubricating base oil to prepare rolling mill compound composition, for the lubrication in plate-strip steel cold-rolling process.
Background technology
Along with widely using and growing interest to environment of lubricating oil, people more and more pay attention to the pollution problem of lubricating oil to environment.Due to traditional with the pollution aggravation of mineral based lubricating oil to environment and the minimizing gradually of petroleum resources, Study and Development novel, biodegradable Green Lubricants has great society and economic implications.
The pure oil type rolling mill compound that cold rolling liquid common at present is mainly divided into base oil or oiliness improver and additive compound to obtain and base oil or oiliness improver and additive, composite emulsification rolling mill compound two class obtained of emulsifying agent.The heat that pure oil type rolling mill compound can not take away high pressure in use in time, high-speed rolling produces, and high temperature can affect the antioxidant property of oil product, thus reduce its work-ing life; Though the rolling mill compound better performances after emulsification, application conditions is comparatively harsh, product cost is higher.Therefore, invention one had both had excellent lubrication, antirust, extreme pressure and antiwear behavior, and the rolling mill compound with good cooling performance is necessary.And along with the shortage of petroleum resources, the use of environment-friendly type rolling mill compound meets national environmental protection development trend.
Summary of the invention
The object of the present invention is to provide and a kind of there is excellent lubrication, antirust, extreme pressure and antiwear behavior, good cooling performance and biodegradable rolling mill compound.
The technical solution used in the present invention is as follows: a kind of bio-based rolling mill compound composition, and this lubricating oil is become by following raw materials in parts by weight array: grease-based polyol ester 0.01-99.0 part, other base oils 0.01-99.0 part, emulsifying agent 3.0-20.0 part, extreme pressure agent 2.0-10.0 part, rust-preventive agent 3.0-15.0 part, oxidation and corrosion inhibitor 0.1-1.0 part, antiseptic-germicide 0.2-0.3 part, purification agent 0.5-5.0 part.
The present invention adopts the grease-based polyol ester prepared for raw material with sewer oil, food oil expression, cottonseed corner material etc. for raw material, reasonably utilizes renewable resources, developing green lubricating oil, has great environment protection significance.
Embodiment
The present invention is described further in conjunction with the embodiments.
embodiment 1
A kind of bio-based rolling mill compound, comprises the component of following parts by weight: fatty acid pentaerythritol ester 50 parts, lipid acid glycerine ester 30 parts, C
8 ~ 10oPE series emulsifying agent 8 parts, positive 4 parts, the fourth fat of phosphorous acid two, barium mahogany sulfonate 10 parts, the two octyl group basic zinc salt 0.8 part of sulphur phosphorus, 0.2 part, phenylformic acid, high base number calcium alkylbenzenesulfonate 1.5 parts, is in harmonious proportion according to the above ratio and get final product.
embodiment 2
A kind of bio-based rolling mill compound, comprises the component of following parts by weight: lipid acid glycerine ester 80 parts, C
8 ~ 10oPE series emulsifying agent 10 parts, the two octyl group basic zinc salt 6 parts of sulphur phosphorus, barium mahogany sulfonate 10 parts, the two octyl group basic zinc salt 0.5 part of sulphur phosphorus, dimethyl fumarate 0.2 part, middle calcium alkylbenzensulfonates 2.5 parts, is in harmonious proportion according to the above ratio and get final product.
embodiment 3
A kind of bio-based rolling mill compound, comprise the component of following parts by weight: lipid acid trihydroxymethylpropanyl ester 90 parts, triethanolamine stearate 12 parts, the two octyl group basic zinc salt 8 parts of sulphur phosphorus, barium mahogany sulfonate 8 parts, sulphur phosphorus brothers alcohol radical zinc salt 0.5 part, dimethyl fumarate 0.2 part, high base number calcium alkylbenzenesulfonate 1.5 parts, is in harmonious proportion according to the above ratio and get final product.
The typical physical and chemical index of the development oil of embodiment is in table 1.
This oil product is by lubricating oil Comprehensive Assessment, and every physical and chemical index all reaches service requirements.Adopt grease-based polyol ester or grease-based polyol ester and PAO or grease-based polyol ester and ester class base oil, can be in harmonious proportion out qualified rolling mill compound.
Grease-based polyol ester base oil of the present invention is Focke & Co. (GmbH & Co.) commercially available prod.
Emulsifying agent: polyoxyethylene sorbitol acid anhydride trioleate, C
8 ~ 10oPE series emulsifying agent, triethanolamine stearate, alkylphenol polyoxyethylene are all purchased from Jiangsu Hai'an Petrochemical Plant;
Oxidation and corrosion inhibitor: the two octyl group basic zinc salt of sulphur phosphorus, sulphur phosphorus brothers alcohol radical zinc salt, sulphur phosphorus secondary alcohol groups zinc salt are all purchased from the emerging petroleum additive limited liability company in Jinzhou;
Extreme pressure anti-wear additives: phosphorous acid two positive fourth fat, sulphur phosphoric acid nitrogen containing derivative, tritolyl phosphate or thiophosphoric acid amine salt, thiophosphoric acid phenyl ester, sulfide isobutene, phosphorous acid diisobutyl ester are all purchased from Shandong Zibo Hui Hua Chemical Co., Ltd.;
Rust-preventive agent: barium mahogany sulfonate, petroleum sodium sulfonate zinc naphthenate, neutral dinonyl naphthalene sulfonate barium, alkenyl succinic acid, alkenyl succinic acid ester are all purchased from the emerging petroleum additive limited liability company in Jinzhou;
Antiseptic-germicide: FF-02, three red oil, dimethyl fumarate, phenylformic acid are all purchased from Shanghai Jie Yikang Chemical Industry Science Co., Ltd;
Purification agent: high base number calcium alkylbenzenesulfonate, middle calcium alkylbenzensulfonates are all purchased from Shandong Zibo Hui Hua company limited.
Claims (2)
1. a bio-based rolling mill compound, it is characterized in that, this lubricating oil is become by following raw materials in parts by weight array: grease-based polyol ester 0.01-99.0 part, other base oils 0.01-99.0 part, emulsifying agent 3.0-20.0 part, extreme pressure agent 2.0-10.0 part, rust-preventive agent 3.0-15.0 part, oxidation and corrosion inhibitor 0.1-1.0 part, antiseptic-germicide 0.2-0.3 part, purification agent 0.5-5.0 part.
2. rolling mill compound according to claim 1, is characterized in that: grease-based polyol ester base oil 40 DEG C of kinematic viscosity are 5.0-400.0mm
2﹒ s
-1, viscosity index>=80, acid number≤2, flash-point>=180 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510064271.8A CN104726183B (en) | 2015-02-09 | 2015-02-09 | A kind of bio-based rolling mill compound composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510064271.8A CN104726183B (en) | 2015-02-09 | 2015-02-09 | A kind of bio-based rolling mill compound composition |
Publications (2)
| Publication Number | Publication Date |
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| CN104726183A true CN104726183A (en) | 2015-06-24 |
| CN104726183B CN104726183B (en) | 2017-07-04 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510064271.8A Active CN104726183B (en) | 2015-02-09 | 2015-02-09 | A kind of bio-based rolling mill compound composition |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105112125A (en) * | 2015-09-07 | 2015-12-02 | 龚灿锋 | Antimicrobial rust-inhibiting additive for lubricating oil |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6303547B1 (en) * | 2000-09-19 | 2001-10-16 | Ethyl Corporation | Friction modified lubricants |
| CN101434886A (en) * | 2008-12-17 | 2009-05-20 | 武汉同盛精细化工技术开发有限责任公司 | Rolling oil composition for 12-roller reversing mill |
| CN103275812A (en) * | 2013-04-26 | 2013-09-04 | 青岛中科润美润滑材料技术有限公司 | Method for preparing base oil of lubricating oil from waste animal and vegetable oil |
| CN103409206A (en) * | 2013-08-26 | 2013-11-27 | 广西大学 | Hot rolling lubricant for titanium and titanium alloy strips |
-
2015
- 2015-02-09 CN CN201510064271.8A patent/CN104726183B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6303547B1 (en) * | 2000-09-19 | 2001-10-16 | Ethyl Corporation | Friction modified lubricants |
| CN101434886A (en) * | 2008-12-17 | 2009-05-20 | 武汉同盛精细化工技术开发有限责任公司 | Rolling oil composition for 12-roller reversing mill |
| CN103275812A (en) * | 2013-04-26 | 2013-09-04 | 青岛中科润美润滑材料技术有限公司 | Method for preparing base oil of lubricating oil from waste animal and vegetable oil |
| CN103409206A (en) * | 2013-08-26 | 2013-11-27 | 广西大学 | Hot rolling lubricant for titanium and titanium alloy strips |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105112125A (en) * | 2015-09-07 | 2015-12-02 | 龚灿锋 | Antimicrobial rust-inhibiting additive for lubricating oil |
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| Publication number | Publication date |
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| CN104726183B (en) | 2017-07-04 |
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