CN104720271A - Antibacterial material and toiletries and health care toothbrush adopting same - Google Patents
Antibacterial material and toiletries and health care toothbrush adopting same Download PDFInfo
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- CN104720271A CN104720271A CN201310714569.XA CN201310714569A CN104720271A CN 104720271 A CN104720271 A CN 104720271A CN 201310714569 A CN201310714569 A CN 201310714569A CN 104720271 A CN104720271 A CN 104720271A
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Abstract
The invention discloses an antibacterial material composed of far infrared ceramic powder and negative ion powder at the volume ratio ranging from 2:1 to 5:1; the far infrared ceramic powder is composed of inorganic mineral, non-metal oxides and metal oxides; the negative ion powder is composed of rare earth powder and tourmaline powder. Correspondingly, the invention further provides toiletries and a health care toothbrush adopting the antibacterial material. When the antibacterial material is applied to daily cleaning and caring products, the partial human body blood circulation can be promoted effectively, and the human body disease prevention ability can be improved; in addition, the toothbrush and instrument adopting the antibacterial material has the self cleaning function.
Description
Technical field
The washing product the present invention relates to anti-biotic material and application thereof, particularly relate to a kind of antibacterial bacteriostatic material, adopting this material to prepare and tooth brush for health protection.
Background technology
Traditional washing product, as: the major parts such as toothpaste, perfumed soap, soap, shampoo (liquid, cream, frost), shower cream, face cream (cream, liquid), washing powder all do not have the effect of antibacterial bacteriostatic.Although with the addition of the Chinese herbal medicines such as such as pseudo-ginseng, peppermint, honeysuckle, the capsule of weeping forsythia in some washing products, the onset time of Chinese herbal medicine is long, can not play good antibacterial and bacteriostasis at short notice.There is no the perfumed soap of antibacterial bacteriostatic effect, soap, shampoo, shower cream, face cream, washing powder etc. within 3 minutes, only have some cleaning actions, but effectively can not suppress the harm of parts of body bacterium.
After brushing teeth, often have many bacterial adhesion on toothbrush, if used and improper storage, toothbrush is very easily contaminated by bacterial.Existingly clean by clear water, clear up toothbrush, thoroughly antibacterial effect cannot be reached at all.The effect of toothbrush self not antiphlogistic antibacterial, it is improper to add long-term cleaning, and when brushing teeth, the bacterium on toothbrush by directly to swallow or the mucous membrane of mouth of breakage and cavity in a tooth invade human body, can cause the diseases such as enteritis, septicemia, ephritis.In current toothbrush manufacture process, not adding can the material of antibacterial bacteriostatic, and therefore, toothbrush does not possess self-cleaning function.Cleaning for toothbrush, needs to use some cleaning fluids, but such complicated operation, and easily the cleaning fluid containing chemical substance is remained on toothbrush, be unfavorable for the maintenance of oral health.
Therefore need to provide a kind of antibacterial bacteriostatic material that may be used in washing product, this material can kill bacterium at short notice, and the growing of anti-bacteria.
Summary of the invention
In order to solve the problem, the invention provides a kind of antibacterial bacteriostatic material, and this materials application arrived in washing product and toothbrush, to realize antibacterial and bacteriostasis, protection human health.
According to an aspect of the present invention, provide a kind of antibacterial bacteriostatic material, be made up of far-infared ceramic powder and negative ion powder in described antibacterial bacteriostatic material; The volume ratio of described far-infared ceramic powder and described negative ion powder is 2: 1 ~ 5: 1;
Described far-infared ceramic powder is made up of inorganic mineral, nonmetal oxide and metal oxide; The percentage that the quality of described nonmetal oxide accounts for the quality of described far-infared ceramic powder is 32% ~ 40%; The percentage that the quality of described metal oxide accounts for the quality of described far-infared ceramic powder is 38% ~ 65%;
Rare earth powder, tourmaline powder is comprised in described negative ion powder; The percentage that the quality of described rare earth powder accounts for the quality of described negative ion powder is 60% ~ 70%; The percentage that the quality of described tourmaline powder accounts for the quality of described negative ion powder is 20% ~ 25%.
According to another aspect of the present invention, provide a kind of washing product, be added with above-mentioned antibacterial bacteriostatic material in described washing product, the volume of described antibacterial bacteriostatic material shared by described washing product is 2% ~ 20%.
According to a further aspect of the invention, a kind of tooth brush for health protection is provided, evaporation cham comprises the toothbrush handle front end that carries described tooth brush monofilament and is attached thereto the toothbrush handle portion of the handle connect, and adds above-mentioned antibacterial bacteriostatic material in the making material of described tooth brush monofilament, described toothbrush handle front end and/or described toothbrush handle portion of the handle.
According to a specific embodiment of the present invention, the bottom surface of described toothbrush handle front end and/or side are provided with tongue scraper.
According to another detailed description of the invention of the present invention, described tongue scraper adopts and is added with above-mentioned antibacterial bacteriostatic material.
According to another detailed description of the invention of the present invention, described tooth brush monofilament is made up of the silk tuft of two groups of respective array, on the centre that first group of silk tuft is positioned at described toothbrush handle front end or center line; Second group of silk tuft is centered around the both sides and around of described first group of silk tuft, and described silk tuft and described toothbrush handle front end adopt poroid to be embeddedly connected; The diameter of the silk hair of described first group of silk tuft is 0.18mm ~ 0.24mm; The diameter of the silk hair of described second group of silk tuft is 0.14mm ~ 0.16mm.
According to another detailed description of the invention of the present invention, described first group of silk tuft is made up of different the 3rd group of silk tuft of silk nominal diameter and the 4th group of silk tuft; On the centre that described 3rd group of silk tuft is positioned at described toothbrush handle front end or center line; Described 4th group of silk tuft is centered around both sides and the surrounding of described 3rd group of silk tuft; The hardness of described 3rd group of silk tuft is higher than the hardness of described 4th group of silk tuft; Wherein, the diameter forming the silk hair of described 3rd group of silk tuft is 0.21mm ~ 0.24mm; The diameter forming the silk hair of described 4th group of silk tuft is 0.18mm ~ 0.21mm.
According to another detailed description of the invention of the present invention, angledly between described toothbrush handle portion of the handle with described toothbrush handle front end to be connected.
According to another detailed description of the invention of the present invention, between described toothbrush handle portion of the handle with described toothbrush handle front end, Flexible Connector is adopted to be connected.
According to another detailed description of the invention of the present invention, be furnished with some precipitation holes on described tooth brush monofilament surface, described precipitation hole is used for the precipitation of antibacterial bacteriostatic material described in described tooth brush monofilament manufactured materials.
Antibacterial bacteriostatic material provided by the invention is made up of far-infared ceramic powder and negative ion powder, can promote that local blood circulates, bactericidal antiphlogistic.The washing product being added with this antibacterial bacteriostatic material, except having clean effect, also has the effect of health care.Adopt and be added with the toothbrush cleaning teeth of this antibacterial bacteriostatic material, the anti-inflammation and sterilization Repercusion analgesia to tooth and gum can be played while brushing teeth, dispel the effect of oral peculiar smell; And the antibacterial bacteriostatic material of sustained release can make toothbrush self have sterilizing function, the bacterium being attached to toothbrush can be killed automatically, ensure the lasting sanitation and hygiene of toothbrush.In addition; for the tooth stain effectively removing cigarette stain, tea stain and other a variety of causes on tooth; reduce the formation aspect of calculus dentalis and bacterial plaque; this toothbrush that with the addition of evenly trickle antibacterial bacteriostatic material can not damage enamel while the above-mentioned spot of removal, also can carry out available protecting to tooth on the contrary.
Accompanying drawing explanation
By reading the detailed description done non-limiting example done with reference to the following drawings, other features, objects and advantages of the present invention will become more obvious:
Figure 1 shows that the side structure schematic diagram of a kind of detailed description of the invention according to a kind of tooth brush for health protection of the present invention;
Figure 2 shows that the Facad structure schematic diagram of the another kind of detailed description of the invention according to a kind of tooth brush for health protection of the present invention;
Figure 3 shows that another Facad structure schematic diagram of another detailed description of the invention according to a kind of tooth brush for health protection of the present invention;
Figure 4 shows that the side structure schematic diagram of another detailed description of the invention according to a kind of tooth brush for health protection of the present invention;
Figure 5 shows that the side structure schematic diagram of another detailed description of the invention according to a kind of tooth brush for health protection of the present invention;
Figure 6 shows that the structure schematic diagram of another detailed description of the invention according to a kind of tooth brush for health protection of the present invention.
In accompanying drawing, same or analogous Reference numeral represents same or analogous parts.
Wherein, in FIG respective drawings mark to refer to content as follows:
1, tooth brush monofilament 11, first group of silk tuft
12, second group of silk tuft 2, toothbrush handle front end
3, toothbrush handle portion of the handle 4, toothbrush handle connecting portion
5, tongue scraper
Detailed description of the invention
Disclosing hereafter provides many different embodiments or example is used for realizing different structure of the present invention.Of the present invention open in order to simplify, hereinafter the parts of specific examples and setting are described.In addition, the present invention can in different example repeat reference numerals and/or letter.This repetition is to simplify and clearly object, itself does not indicate the relation between discussed various embodiment and/or setting.It should be noted that parts illustrated in the accompanying drawings are not necessarily drawn in proportion.Present invention omits the description of known assemblies and treatment technology and process to avoid unnecessarily limiting the present invention.
The invention provides a kind of antibacterial bacteriostatic material, be made up of far-infared ceramic powder and negative ion powder in this antibacterial bacteriostatic material.Wherein, the volume ratio of far-infared ceramic powder and described negative ion powder is 2: 1 ~ 5: 1, such as: 2: Isosorbide-5-Nitrae: 1 or 5: 1.The particle diameter of far-infared ceramic powder can produce 1250 order ~ 80 nanometers, its normal temperature wavelength is 2 μm ~ 18 μm, far infrared transmissivity is 92%, have that peculiar smell is eliminated in sterilization, the function such as to prevent and cure diseases, effectively can improve microcirculation in human body, impel normal microcirculation blood flow to increase by 2 ~ 3 times, improve and organize oxygen supply, improve metabolism, develop immunitypty.
Described far-infared ceramic powder is made up of inorganic mineral, nonmetal oxide and metal oxide.Wherein, the percentage that the quality of described nonmetal oxide accounts for the quality of described far-infared ceramic powder is 32% ~ 40%, such as: 32%, 38% or 40%; The percentage that the quality of described metal oxide accounts for the quality of described far-infared ceramic powder is 38% ~ 65%, such as: 38%, 55% or 65%.
Negative ion powder has excellent antibiotic and sterilizing function, and its negative oxygen ion produced has higher activity, has very strong redox, can destroy the cell membrane of bacterium or the activity of cellular plasm organized enzyme, thus reach the object of antibiotic and sterilizing.Negative ion powder can also play expansion capillary, strengthens blood circulation, enhances metabolism, and strengthens the effect of Lymphatic Circulation; It also can make cell activation, old dead cell is drained or gives power of regeneration, can strengthen cellular energy, the effects such as the function of enhancing cell and vigor.
Rare earth powder, tourmaline powder is comprised in described negative ion powder; The percentage that the quality of described rare earth powder accounts for the quality of described negative ion powder is 60% ~ 70%; The percentage that the quality of described tourmaline powder accounts for the quality of described negative ion powder is 20% ~ 25%.
Far-infared ceramic powder and negative ion powder are combined the antibacterial bacteriostatic material of preparation, the antibacterial bacteriostatic better effects if of the two can be made.
Along with the raising of people's living standard, the concern for the aspect such as body care, oral health is also just increasing.Washing product more and more with health role floods market.In washing product, add anti-inflammation and sterilization material while cleaning-nursing, the propagation of harmful bacteria can be avoided.In toothbrush, add anti-inflammation and sterilization material or some calm Chinese herbal medicines can bring more beneficial effects apart from cleaning in the process of brushing teeth.But the anti-inflammation material added in washing product at present or Chinese herbal medicine, and be not suitable for everyone, the washing product that such as with the addition of the materials such as peppermint is not suitable for using winter; The washing product that with the addition of aloe extract matter is not suitable for pregnant woman and uses; The washing product being added with composition such as such as pseudo-ginseng, honeysuckle etc. in addition is substantially not suitable for children and uses.At present, yet anti-inflammation and sterilization material is not added to the precedent in toothbrush.
Therefore the invention provides a kind of washing product safely, to have no side effect, this washing product is applicable to all groups.Be added with above-mentioned antibacterial bacteriostatic material in described washing product, while washing product can be used like this to carry out cleaning, reach the effect of antibacterial bacteriostatic.Preferably, the volume of antibacterial bacteriostatic material shared by described washing product is 2% ~ 20%, such as: 2%, 15% or 20%.
With reference to figure 1, Figure 1 shows that the side structure schematic diagram of a kind of detailed description of the invention according to a kind of tooth brush for health protection of the present invention.As shown in Figure 1, described tooth brush for health protection comprises tooth brush monofilament 1, toothbrush handle front end 2, toothbrush handle portion of the handle 3 and toothbrush handle connecting portion 4.Tooth brush monofilament 1 is arranged on toothbrush handle front end 2.Optionally, tooth brush monofilament 1 can adopt the materials such as plastics, nylon yarn and/or silica gel to make, and damages, can carry out round and smooth process to the head of tooth brush monofilament 1 in order to avoid bristle is too sharp-pointed to oral cavity wall or gum.
Toothbrush handle connecting portion 4 is adopted to be connected between toothbrush handle front end 2 with toothbrush handle portion of the handle 3.Above-mentioned antibacterial bacteriostatic material is added with in the making material of described tooth brush monofilament 1, described toothbrush handle front end 2 and/or described toothbrush handle portion of the handle 3.Optionally, also containing antibacterial bacteriostatic material in the making material of toothbrush handle connecting portion 4.
The tooth brush for health protection of the antibacterial bacteriostatic material contained is used to brush teeth, the far-infared ceramic powder contained in toothbrush can send far infrared, promote and improve the blood circulation of oral cavity gum by the fuel factor of far infrared, strengthen metabolism, improve immune function of human body, the anti-inflammatory also had, detumescence, analgesic activity.Negative ion powder can accelerate moisture movement, makes light water become active water, thus makes the penetration of water, extension, dissolving power, metabolism power strengthen, and produce water conservation film.Which kind of like this in the process of brushing teeth, no matter use water, can play a protective role to tooth.The most important thing is, this antibacterial bacteriostatic material not only can kill intraoral bacterium, also can brute force kill for the bacterium that tooth brush for health protection self is grown, and then keeps the cleaning of tooth brush for health protection itself.
With reference to figure 4 ~ Fig. 6, in order to increase the health care of toothbrush, the side of toothbrush handle front end 2 and/or bottom surface are provided with tongue scraper 5.Tongue scraper 5 uses plastics or rubber to make usually, according to special requirement, also has and adopts argent or aluminum to do.Tongue scraper 5 is the multiple kicks in toothbrush handle front end 2, with its tongue that rubs, can remove the tongue fur on tongue, effectively reduces back microorganism (causing smelly bacterium), significantly alleviates halitosis.Preferably, also containing above-mentioned antibacterial bacteriostatic material in the making material of tongue scraper 5.
Preferably, with reference to figure 2, described tooth brush monofilament 1 is made up of the silk tuft of two groups of respective array, on the centre that first group of silk tuft 11 is positioned at described toothbrush handle front end or center line; Second group of silk tuft 12 is centered around both sides and the surrounding of described first group of silk tuft 11.The hardness of described first group of silk tuft 11 is higher than the hardness of described second group of silk tuft 12.The hardness of first group of silk tuft 11 is high, well can clean tooth and teeth space; The lower hardness of second group of silk tuft 12, can protect gum to be damaged.
Preferably, tooth brush monofilament 1 is made up of the brushing cluster of multiple respective array, and described brushing cluster and described toothbrush handle front end 2 adopt poroid to be embeddedly connected.The custom of brushing teeth due to everyone is different, and the wearing and tearing therefore for tooth brush monofilament 1 are also different, and after having portion bristle bunch damage, the toothbrushing effect of whole tooth brush monofilament 1 can weaken greatly, and usually in this case, people can only carry out the replacing of toothbrush.In addition, in order to the maintenance of oral health, the replacement frequency of dentists recommend toothbrush is preferably every three months once, so just substantially increases the use cost of user.Therefore, the tooth brush monofilament 1 that tooth brush for health protection provided by the invention uses is multiple independently brushing clusters, and adopts poroid to be embeddedly connected on toothbrush handle front end 2.When some or multiple brushing cluster goes wrong, the brushing cluster of damage can be removed, then new brushing cluster is placed in embedded hole again, effectively can extend the service life of tooth brush for health protection like this, and effectively reduce use cost.
Optionally, the diameter forming the silk hair of described first group of silk tuft 11 is 0.18mm ~ 0.24mm, such as: 0.18mm, 0.21mm or 0.24mm.
Optionally, the diameter forming the silk hair of described second group of silk tuft 12 is 0.14mm ~ 0.16mm, such as: 0.14mm, 0.15mm or 0.16mm.
Optionally, with reference to figure 3, described first group of silk tuft is made up of the different 3rd group of silk tufts of silk nominal diameter and the 4th group of silk tuft; On the centre that described 3rd group of silk tuft is positioned at described toothbrush handle front end or center line; Described 4th group of silk tuft is centered around both sides and the surrounding of described 3rd group of silk tuft; The hardness of described 3rd group of silk tuft is higher than the hardness of described 4th group of silk tuft.
Wherein, the diameter forming the silk hair of described 3rd group of silk tuft is 0.21mm ~ 0.24mm, such as: 0.21mm, 0.22mm or 0.24mm.The diameter forming the silk hair of described 4th group of silk tuft is 0.18mm ~ 0.21mm, such as, and 0.18mm, 0.19mm or 0.21mm.
In order to dynamics is excessive when alleviating user of toothbrushing, damage is caused to tooth and gum, between toothbrush handle portion of the handle 3 with described toothbrush handle front end 2, preferably adopt Flexible Connector to be connected.Adopt Flexible Connector can effectively alleviate the dynamics that toothbrush handle front end 2 is born, and then reduce the stimulation of tooth brush monofilament 1 for gum.Flexible Connector can adopt the material such as rubber, elastoplast, and for this, the present invention does not limit, as long as the material that can realize this function all can use.
In addition, clinical with practice in finds, if angled connection between toothbrush handle front end 2 and toothbrush handle portion of the handle 3, so will more be of value to depths, oral cavity clean.Therefore, with reference to figure 4, tooth brush for health protection provided by the invention is preferably connected angled between toothbrush handle portion of the handle 3 with toothbrush handle front end 2.Preferably, the connection angle between described toothbrush handle portion of the handle and described toothbrush handle front end is 160 ° ~ 180 °, such as: 160 °, 170 ° or 180 °.
Preferably, tooth brush monofilament 1 surface is furnished with some precipitation holes, and described precipitation hole is used for the precipitation of the antibacterial bacteriostatic material in described tooth brush monofilament 1 manufactured materials.
Antibacterial bacteriostatic material provided by the invention, can promote that local blood circulates, and improves human body diseases prevention ability, and has no side effect.This antibacterial bacteriostatic material is added in washing product or tooth brush for health protection can reach effectively clean, anti-inflammation, antibacterial effect, it is crucial that this tooth brush for health protection also has self-cleaning function.
Although describe in detail about example embodiment and advantage thereof, being to be understood that when not departing from the protection domain of spirit of the present invention and claims restriction, various change, substitutions and modifications can being carried out to these embodiments.For other examples, those of ordinary skill in the art should easy understand maintenance scope in while, the order of processing step can change.
In addition, range of application of the present invention is not limited to the technique of the specific embodiment described in description, mechanism, manufacture, material composition, means, method and step.From disclosure of the present invention, to easily understand as those of ordinary skill in the art, for the technique existed at present or be about to develop, mechanism, manufacture, material composition, means, method or step later, wherein their perform the identical function of the corresponding embodiment cardinal principle that describes with the present invention or obtain the identical result of cardinal principle, can apply according to the present invention to them.Therefore, claims of the present invention are intended to these technique, mechanism, manufacture, material composition, means, method or step to be included in its protection domain.
Claims (10)
1. an antibacterial bacteriostatic material, is made up of far-infared ceramic powder and negative ion powder in described antibacterial bacteriostatic material; The volume ratio of described far-infared ceramic powder and described negative ion powder is 2: 1 ~ 5: 1;
Described far-infared ceramic powder is made up of inorganic mineral, nonmetal oxide and metal oxide; The percentage that the quality of described nonmetal oxide accounts for the quality of described far-infared ceramic powder is 32% ~ 40%; The percentage that the quality of described metal oxide accounts for the quality of described far-infared ceramic powder is 38% ~ 65%;
Rare earth powder, tourmaline powder is comprised in described negative ion powder; The percentage that the quality of described rare earth powder accounts for the quality of described negative ion powder is 60% ~ 70%; The percentage that the quality of described tourmaline powder accounts for the quality of described negative ion powder is 20% ~ 25%.
2. a washing product, is characterized in that, is added with antibacterial bacteriostatic material as claimed in claim 1 in described washing product, and the volume of described antibacterial bacteriostatic material shared by described washing product is 2% ~ 20%.
3. a tooth brush for health protection, evaporation cham comprises the toothbrush handle front end that carries described tooth brush monofilament and is attached thereto the toothbrush handle portion of the handle connect,
It is characterized in that:
Antibacterial bacteriostatic material as claimed in claim 1 is added in the making material of described tooth brush monofilament, described toothbrush handle front end and/or described toothbrush handle portion of the handle.
4. tooth brush for health protection according to claim 3, is characterized in that, the bottom surface of described toothbrush handle front end and/or side are provided with tongue scraper.
5. tooth brush for health protection according to claim 4, is characterized in that, described tongue scraper adopts and is added with antibacterial bacteriostatic material as claimed in claim 1.
6. according to the tooth brush for health protection in claim 3 ~ 5 described in any one, described tooth brush monofilament is made up of the silk tuft of two groups of respective array, it is characterized in that, on the centre that first group of silk tuft is positioned at described toothbrush handle front end or center line; Second group of silk tuft is centered around the both sides and around of described first group of silk tuft, and described silk tuft and described toothbrush handle front end adopt poroid to be embeddedly connected; The diameter of the silk hair of described first group of silk tuft is 0.18mm ~ 0.24mm; The diameter of the silk hair of described second group of silk tuft is 0.14mm ~ 0.16mm.
7. tooth brush for health protection according to claim 6, is characterized in that, described first group of silk tuft is made up of the different 3rd group of silk tufts of silk nominal diameter and the 4th group of silk tuft;
On the centre that described 3rd group of silk tuft is positioned at described toothbrush handle front end or center line; Described 4th group of silk tuft is centered around both sides and the surrounding of described 3rd group of silk tuft;
The hardness of described 3rd group of silk tuft is higher than the hardness of described 4th group of silk tuft;
Wherein, the diameter forming the silk hair of described 3rd group of silk tuft is 0.21mm ~ 0.24mm; The diameter forming the silk hair of described 4th group of silk tuft is 0.18mm ~ 0.21mm.
8. the tooth brush for health protection according to claim 3 ~ 7 any one, is characterized in that, angledly between described toothbrush handle portion of the handle with described toothbrush handle front end is connected.
9. according to the tooth brush for health protection in claim 3 ~ 8 described in any one, it is characterized in that, between described toothbrush handle portion of the handle with described toothbrush handle front end, adopt Flexible Connector to be connected.
10. tooth brush for health protection according to claim 9, is characterized in that, is furnished with some precipitation holes on described tooth brush monofilament surface, and described precipitation hole is used for the precipitation of antibacterial bacteriostatic material described in described tooth brush monofilament manufactured materials.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310714569.XA CN104720271A (en) | 2013-12-23 | 2013-12-23 | Antibacterial material and toiletries and health care toothbrush adopting same |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310714569.XA CN104720271A (en) | 2013-12-23 | 2013-12-23 | Antibacterial material and toiletries and health care toothbrush adopting same |
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| CN104720271A true CN104720271A (en) | 2015-06-24 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310714569.XA Pending CN104720271A (en) | 2013-12-23 | 2013-12-23 | Antibacterial material and toiletries and health care toothbrush adopting same |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109008175A (en) * | 2018-07-24 | 2018-12-18 | 安徽玉达工具有限公司 | A kind of full wood brush |
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| KR100496241B1 (en) * | 2004-03-06 | 2005-06-17 | 김성협 | A compound or manufacturing method of ceramic coating |
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| CN1392115A (en) * | 2002-08-13 | 2003-01-22 | 河北工业大学 | Multifunctinoal health ceramic material and its preparing method and use |
| KR100496241B1 (en) * | 2004-03-06 | 2005-06-17 | 김성협 | A compound or manufacturing method of ceramic coating |
| CN200950901Y (en) * | 2006-07-28 | 2007-09-26 | 张忠浩 | Health care toothbrush |
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Application publication date: 20150624 |