CN104711903A - Fruit cultivation bag paper with multilayer compound structure, as well as manufacturing method of fruit cultivation bag paper - Google Patents

Fruit cultivation bag paper with multilayer compound structure, as well as manufacturing method of fruit cultivation bag paper Download PDF

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CN104711903A
CN104711903A CN201510119455.XA CN201510119455A CN104711903A CN 104711903 A CN104711903 A CN 104711903A CN 201510119455 A CN201510119455 A CN 201510119455A CN 104711903 A CN104711903 A CN 104711903A
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pulp
paper
fruit
layer
consumption
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CN104711903B (en
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刘全校
许文才
曹国荣
付亚波
杨永刚
李东立
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Beijing Liyang Shengxing science and Trade Co.,Ltd.
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Beijing Institute of Graphic Communication
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Abstract

The invention belongs to the technical field of fruit cultivation bags, and relates to fruit cultivation bag paper with a multilayer compound structure, as well as a manufacturing method of the fruit cultivation bag paper. The paper achieves the compounding of multilayer structures, which means that the paper achieves the function of compounding multiple types of independent and separate paper in the prior art. The manufacturing method comprises the following steps: each wet paper sheet layer is respectively manufactured; all the wet paper sheet layers are then superposed, so as to form a wet paper sheet with a multilayer structure; the wet paper sheet with the multilayer structure is finally subjected to pressing dewatering and drying dewatering, so as to obtain the fruit cultivation bag paper with the multilayer structure. All the layers in the paper structure have different performance, so that the fruit cultivation bag paper achieves the effect of a double-layer or three-layer fruit cultivation bag manufactured from the multiple types of paper.

Description

Fruit inspecting of a kind of multi-layer compound structure and preparation method thereof
Technical field
The present invention relates to a kind of fruit inspecting, particularly relate to and there is multi-layer compound structure fruit inspecting and preparation method thereof, belong to fruit bagging technology field.
Background technology
Along with the raising of people's living standard, the requirement of people to fruit turns to the green fruit of high-quality and Harmless, and commercially available Pollution-free Fruit price is apparently higher than common fruit, and the production of Pollution-free Fruit depends on whether apply fruit bagging technology.
Fruit bagging technology is in the process of fruit growing, adopt the way of fruit bag, instead of spray traditionally and shine the method for agricultural chemicals, make the fruit in bagging can not be subject to the infringement of birds, the infection of fruit bat bacterium can not be subject to, also can not by branch scratch, and make fruit avoid the direct irradiation of sunlight, more because the gas permeability of bagging itself can produce indivedual greenhouse effects, make humidity, temperature that fruit keeps suitable, improve the sugariness of fruit, improve the gloss of fruit, increase fruited output, and shorten its growth stage.In addition, do not need applying pesticides in the process due to growth, make fruit have high-quality and nuisanceless, meet the demand for development of green non-pollution agricultural.
Fruit bag is divided into single ply bag, double-ply bag and three layers of bag.Usually, double-ply bag, three layers of bag are better than single ply bag to the effect of promoting fruit appearance and quality, but are separate discerptible between each layer bag.
At present, more Study and appliance mainly concentrates on: make and select the internal layer of applicable fruit bag, intermediate layer, outer field paper respectively, namely inner bag paper, middle bag paper, outer bag paper, then carry out combination and make fruit bag, has plenty of double-ply bag, have plenty of three layers of bag, be separate discerptible between each layer bag, and have space.Such as, the mcintosh kind based on Fuji apple, is applicable to selecting double-ply bag black in outer ash.This double-ply bag, outer what select is the paper of grey, the paper of what internal layer was selected is black.Pear varieties based on water-rich areas, the inner bag black mainly selecting light-proofness stronger, the cervine double-ply bag of outer bag.The paper that pears bagging is selected is, what outer bag was selected is lurid paper, the paper of what inner layer bag was selected is black.
The method of the double-deck bagging of this making; adopt two kinds of paper with different performance; a kind of for making inner bag; a kind of for making outer bag; play two kinds of paper performances and effect; reach in protection fruit developmental process, effectively reduce fruit disease and pest, stop the residues of pesticides on fruit face and improve fruit quality.
The shortcoming of above-mentioned fruit bag is that multiple paper is respectively used to outer bag paper, intermediate bag paper, inner layer bag paper, makes fruit bag, and each layer bag is separate separately, has space between each layer bag.The present invention is directed to this shortcoming, make a kind of fruit inspecting, this paper has sandwich construction, every one deck of this paper has different performances, directly can make fruit bag with this paper, object and the effect of fruit Multi-layer bag can be reached, can be used as the paper making fruit bag, in other words be that separable multilayer bag of the prior art is combined into a piece of paper plate, form overall inseparable sandwich construction.
Summary of the invention
The object of the invention is the shortcoming being to overcome prior art, provide a kind of fruit inspecting, this paper a kind ofly has the paper that sandwich construction is combined with each other into, be equivalent to the function and service of the multiple paper of independent separate of the prior art on a piece of paper is opened, every layer in this paper structure has different performances, can reach the effect of the double-deck bagging of the fruit using multiple paper to make, three layers of bagging.
Meanwhile, another object of the present invention there is provided the preparation method of this fruit inspecting, and the application that fruit inspecting is grown up in protection at fruit.
The fruit bag that this fruit inspecting makes, has double-decker and to be combined with each other the effect of fruit bag that fruit bag or three-decker be combined with each other, meet fruit and grow up and protection fruit quality, ensure the greenization of Production of fruit.
Multi-layer compound structure fruit inspecting of the present invention, is characterized in that, fruit inspecting is two-layer or being combined with each other of fitting tightly of three-decker, every one deck be quantitatively 10g/m 2~ 42g/m 2, thickness is 0.036mm ~ 0.081mm, and the total of fruit inspecting is quantitatively 30g/m 2~ 82g/m 2, gross thickness is 0.072mm ~ 0.14mm, and every one deck can select different interpolation pigment as required, is applicable to making fruit bag.
Preferably have double-deck fruit inspecting, the quantitative of every one deck is 20g/m 2~ 42g/m 2, thickness is 0.036mm ~ 0.081mm, and the total of fruit inspecting is quantitatively 40g/m 2~ 82g/m 2, gross thickness is 0.072mm ~ 0.14mm.
Have the fruit inspecting of three-decker, preferably every one deck is quantitatively 10g/m 2~ 42g/m 2, thickness is 0.036mm ~ 0.081mm, and the total of fruit inspecting is quantitatively 40g/m 2~ 82g/m 2, gross thickness is 0.072mm ~ 0.14mm.
The preparation method of sandwich construction fruit inspecting of the present invention, is characterized in that, is to make every one deck l Water Paper page respectively, and as do not made outer l Water Paper page, middle level l Water Paper page, internal layer l Water Paper page, every layer of l Water Paper has different performances.Then, each layer l Water Paper page is superimposed together, forms sandwich construction l Water Paper page.Finally, after press dewatering, drying and dehydrating are carried out to sandwich construction l Water Paper page, sandwich construction fruit inspecting is obtained.
Above-mentioned double-decker fruit inspecting or the preparation method of three-decker fruit inspecting, comprise following steps:
(1), the making of each layer l Water Paper page
Individually prepare each layer l Water Paper page, to wet according to each layer the requirement of page characteristic, select suitable process of plant fiber pulp, be diluted with water to mass concentration 1% ~ 5%, after being uniformly dispersed, add the chemical assistants such as retention agent, sizing agent, reinforcing agent, colouring agent, carry out disperseing and mixing, after mixing, filtering means dehydration, shaping formation each layer l Water Paper page.
Wherein, double-deck fruit inspecting, outer adopts string, is selected from the mixed pulp of one or both or three kinds in waste paper, bleached wood pulp and bleaching straw pulp, one or both the mixed pulp in preferred bleached wood pulp, waste paper.Internal layer adopts string, is selected from one or both the mixed pulp in bleached wood pulp or bleaching straw pulp, preferred bleaching straw pulp.
Outer employing string, be selected from waste paper, the mixed pulp of one or both or three kinds in bleached wood pulp and bleaching straw pulp, reinforcing agent is melamine resin or Polyamide-Polyamsne-Epichlorohydrin resin, quality consumption is 0.5% ~ 7.0% of absolute dried paper pulp amount, sizing agent is reactive sizing agent alkyl ketene dimer emulsion or rosin sizes, quality consumption is 0.5% ~ 5.0% of absolute dried paper pulp amount, retention agent is one or both in cationic starch or cationic polyacrylamide, quality consumption is 0.05% ~ 3.0% of absolute dried paper pulp amount, colouring agent is direct orchil or direct apricot yellow dyestuff.Outer field quantitative more preferably 40g/m 2, thickness is 0.08mm, and degree of sizing is 18s, and machine direction tensile strength is 158kN/m, and cross direction tensile strength is 101kN/m, and tearability is 30N.
Applying glue refers to and makes paper and paper products have the process of resisting Liquid Penetrant performance by introducing sizing agent.When using different sizing agents or adding the different sizing agent measured, the ability that paper and paper products resist Liquid Penetrant performance is different, and namely degree of sizing is different.The method of test degree of sizing is that pattern is converted into little cell type, and pattern half faces up, half reverse side upwards, pour 2% ammonium thiocyanate configured in right amount at culture dish into, capsule is placed on the liquid level of ammonium thiocyanate, be about the FeCl of 1cm place instillation 1% simultaneously with dropper at distance box 3.And start timing, work as FeCl 3in stop timing when just having occurred at red, writing time should be accurate to s, and the time of recording is the degree of sizing of this sample, and during operation, about 45 °, dropper inclination angle, every dropping liquid amount is about 0.06ml.
Internal layer adopts string, be selected from one or both the mixed pulp in bleached wood pulp or bleaching straw pulp, sizing agent is alkyl ketene dimer emulsion or rosin sizes, consumption is 0.5% ~ 2.0%, retention agent is one or both in cationic starch or cationic polyacrylamide, consumption is 0.05% ~ 3.0%, and colouring agent is black pigment carbon black or acetylene black, and consumption is 4% ~ 10%.Internal layer is quantitatively preferably 40g/m 2, thickness is 0.08mm, and degree of sizing is 18s, and machine direction tensile strength is 113kN/m, and cross direction tensile strength is 66kN/m, and tearability is 30N.
The fruit inspecting of three-decker, the outer string adopted is the one in waste paper, bleached wood pulp and bleaching straw pulp, two or three mixed pulp, one or both the mixed pulp in preferred waste paper and bleached wood pulp.The string that middle level adopts is bleached wood pulp or bleaching straw pulp or the mixed pulp of the two, preferred bleaching straw pulp or both mixed pulps.The string that internal layer adopts is bleached wood pulp or bleaching straw pulp, or both mixed pulps, preferred bleaching straw pulp or both mixed pulps.
The chemical assistant that each layer l Water Paper page uses is conventional paper making additive, and consumption is how many, according to the requirement of the physical and mechanical properties of sandwich construction fruit inspecting, determines.
There is the fruit inspecting of three-decker, wherein, the outer string adopted is one, two or three mixed pulp in waste paper, bleached wood pulp and bleaching straw pulp, reinforcing agent is melamine resin or Polyamide-Polyamsne-Epichlorohydrin resin, consumption is 0.5% ~ 3.0%, sizing agent is alkyl ketene dimer emulsion or rosin sizes, consumption is 0.5% ~ 2.0%, retention agent is one or both in cationic starch cationic polyacrylamide, consumption is 0.05% ~ 3.0%, and colouring agent is direct orchil.Further preferred outer field be quantitatively 37g/m 2, thickness is 0.08mm, and degree of sizing is 33s, and machine direction tensile strength is 93.68kN/m, and cross direction tensile strength is 78.64kN/m, and tearability is 30N.
The string that middle level adopts is bleached wood pulp or bleaching straw pulp, or the mixed pulp of the two, and sizing agent is alkyl ketene dimer emulsion, consumption is 0.5% ~ 2.0%, and retention agent is cationic starch, and consumption is 0.05% ~ 3.0%, colouring agent is black pigment carbon black, and consumption is 4% ~ 10%.The quantitative of middle level is 48g/m 2, thickness is 0.08mm, and degree of sizing is 4s, and machine direction tensile strength is 137kN/m, and cross direction tensile strength is 46.06kN/m.
The string that internal layer adopts is bleached wood pulp or bleaching straw pulp, or the mixed pulp of the two, and sizing agent is alkyl ketene dimer emulsion, and consumption is 0.5% ~ 2.0%, and retention agent is cationic starch, and consumption is 0.05% ~ 3.0%.The quantitative of internal layer is 47g/m 2, thickness is 0.03mm, and degree of sizing is 0.1s, and machine direction tensile strength is 26.26kN/m, and cross direction tensile strength is 23.28kN/m.
Retention agent can be cationic starch or cationic polyacrylamide, or both are combined.The consumption of retention agent is 0.05% ~ 3% of absolute dried paper pulp amount.
Sizing agent can be reactive sizing agent alkyl ketene dimer emulsion or rosin sizes.The consumption of sizing agent is 0.5% ~ 5% of absolute dried paper pulp amount.
Reinforcing agent can be melamine resin or Polyamide-Polyamsne-Epichlorohydrin resin.The consumption of reinforcing agent is 0.5% ~ 7%.
The color of every layer given by colouring agent.The direct orchil of outer use or direct apricot yellow dyestuff, or the mixture of the two, consumption is 3% ~ 10%.Intermediate layer uses carbon black or acetylene black, and consumption is 3% ~ 10%.
The retention agent that each layer uses, sizing agent, reinforcing agent, colouring agent and consumption thereof, need the physical and mechanical properties according to each layer and requirement, specifically determine.The consumption of above-mentioned chemical assistant refers to the percentage accounting for absolute dried paper pulp quality.
(2), superimposed, press dewatering, the drying and dehydrating of l Water Paper page
In type each layer l Water Paper page is superimposed together by desired sequence, forms the sandwich construction l Water Paper pages such as superimposed bilayer or three layers, after press dewatering, drying and dehydrating, obtain the sandwich construction fruit inspecting such as bilayer or three layers;
Also can when each layer l Water Paper page be superimposed, each interlayer sprays chemical adhesive oxidized starch or carboxymethyl cellulose, to improve the bond strength of interlayer, avoid this sandwich construction fruit inspecting in the process making fruit bag bag, or in the process used, there is the problem of layering, affect sandwich construction fruit inspecting result of use, thus ensure the quality of sandwich construction fruit inspecting.
The mass content of the moisture of each layer l Water Paper page that above-mentioned steps (1) is formed after filtering is preferably 80% ~ 90%.
The mass content of the moisture after the double-deck or three-decker l Water Paper page squeezing of above-mentioned steps (2) preferably 45% ~ 55%.
After step (2) drying, the mass content of the moisture of above-mentioned bilayer or three-decker fruit inspecting preferably 8% ~ 12%.
Usually, the fruit inspecting of sandwich construction, the paper pulp that skin, intermediate layer, internal layer use and other components are differentiated, its difference is, after the drying of sandwich construction bagging paper, outer field physical and mechanical properties is higher than intermediate layer and internal layer, simultaneously will to optionally through the sunshine of certain wavelength; Intermediate layer is black, provides the effect preventing heat loss in bagging; Internal layer is white, prevents intermediate layer pigment pollution fruit.
Above-mentioned bilayer or three-decker fruit inspecting, the performance of every layer and the performance of entirety, can be different along with the difference of the kind of the raw-material difference of selection, bag fruit etc.
One of advantage of sandwich construction fruit inspecting of the present invention uses this fruit inspecting, has while facilitating bag, and the cost of investment of bag-making equipment is low.
Another advantage of sandwich construction fruit inspecting of the present invention is; in bag making process and in use procedure; it is good that sandwich construction fruit inspecting has strength character; damaged when not being vulnerable to External Force Acting; than the fruit bag prepared altogether by the paper of several individual separation; more tolerate the effect of external force, thus better to fruit growth protective effect.
Accompanying drawing explanation
Accompanying drawing 1 is double-decker fruit inspecting schematic diagram, and 1 is outer, and 2 is internal layer.
Accompanying drawing 2 is three-decker fruit inspecting schematic diagram, and 1 is outer, and 2 is intermediate layer, and 3 is internal layer.
Detailed description of the invention
By following specific embodiment, the invention will be further described.Following specific descriptions are for the ease of understanding the present invention, are not for limiting the scope of the invention.
Comparative example
In order to the harm preventing pears to be subject to disease and pest in developmental process, make pears surface non agricultural chemical residuum, ensure that the tasty mouthfeel of pears is good to eat, make the bagging of pears of following three kinds of paper.The bagging of pears is made up of outer bag paper, intermediate layer paper, internal layer paper, separate separation between each layer.Below the physical and mechanical properties of each layer paper of actual measurement:
Fruit bag outer bag paper, quantitative 37.568g/m 2, thickness 0.0838mm, degree of sizing 33.44s, the strong 93.68kN/m of longitudinal anti-tensile, cross direction tensile strength 78.64kN/m;
Bag paper in fruit inspecting, quantitative 48.64g/m 2, thickness 0.0886mm, degree of sizing 2.21s, the strong 137.72kN/m of longitudinal anti-tensile, cross direction tensile strength 46.06kN/m;
Fruit inspecting inner bag paper, quantitative 10.454g/m 2, thickness 0.0364mm, degree of sizing 0.10s, the strong 26.22kN/m of longitudinal anti-tensile, cross direction tensile strength 23.28kN/m.
The machine direction tensile strength of the three-ply paper (bagging) of above three kinds of paper composition is 257.62kN/m, and cross direction tensile strength is 147.98kN/m.
Embodiment 1
With bleached softwood wood pulp and bleaching leaf wood paper pulp for outer paper pulp, with bleached softwood wood pulp and bleached wheat straw pulp for intermediate layer paper pulp, with bleached softwood wood pulp and leaf wood paper pulp for internal layer paper pulp, make three-decker fruit inspecting.Concrete making step is as follows:
1, the making of outer l Water Paper page
By the mixed pulp of 30% bleached softwood wood pulp and 70% leaf wood paper pulp, be diluted with water to mass concentration 5%, after being uniformly dispersed, add retention agent cationic starch, sizing agent alkyl ketene dimer emulsion, reinforcing agent melamine resin, the direct apricot dyestuff of colouring agent, carry out disperseing and mixing.After mixing, be diluted to the pulp suspension that mass concentration is 1% further, then carry out filtering and shaping, form outer l Water Paper page, obtain faint yellow outer l Water Paper page.
The consumption of cationic starch is 2% of absolute dried paper pulp amount, and the consumption of alkyl ketene dimer emulsion is 1.5% of absolute dried paper pulp amount, and melamine resin consumption is 0.8%, and the consumption of direct apricot yellow dyestuff is 10% of absolute dried paper pulp amount.
The mass content of the moisture of faint yellow outer l Water Paper page is 85%.
2, l Water Paper page in intermediate layer makes
By the mixed pulp of 20% bleached softwood wood pulp and 80% bleached wheat straw pulp, be diluted with water to mass concentration 5%, after being uniformly dispersed, adding retention agent cationic starch, sizing agent alkyl ketene dimer emulsion, colouring agent black pigment carbon black, carry out disperseing and mixing.After mixing, be diluted to the pulp suspension that mass concentration is 1% further, then carry out filtering and shaping, form intermediate layer l Water Paper page, obtain black intermediate layer l Water Paper page.
The consumption of cationic starch is 2% of absolute dried paper pulp amount, and the consumption of alkyl ketene dimer emulsion is 1.5% of absolute dried paper pulp amount, and the consumption of black pigment carbon black is 15% of absolute dried paper pulp amount.
The mass content of the moisture of black intermediate layer l Water Paper page is 83%.
3, internal layer l Water Paper page makes
By 20% bleached softwood wood pulp and 80% leaf wood paper pulp, be diluted with water to mass concentration 5%, after being uniformly dispersed, adding retention agent cationic starch, sizing agent alkyl ketene dimer emulsion, carry out disperseing and mixing.After mixing, be diluted to the pulp suspension that mass concentration is 1% further, then carry out filtering and shaping, form internal layer l Water Paper page, obtain white internal layer l Water Paper page.
The consumption of cationic starch is 2% of absolute dried paper pulp amount, and the consumption of alkyl ketene dimer emulsion is 1.5% of absolute dried paper pulp amount.
The mass content of the moisture of white intermediate layer l Water Paper page is 81%.
The paper pulp of l Water Paper page use and the difference of other components of above-mentioned skin, intermediate layer, internal layer are, after the drying of sandwich construction bagging paper, outer field physical and mechanical properties is higher than intermediate layer and internal layer.The outer sunshine to certain wavelength will selectively through, to ensure that sugar degree is higher; Intermediate layer is black, has fabulous light-proofness, provides the light protected environment of fruit growing; Internal layer is white, prevents intermediate layer black pigment from polluting fruit.
4, superimposed, press dewatering, the drying and dehydrating of l Water Paper page
Brown in type skin l Water Paper page, intermediate layer black l Water Paper page, internal layer white l Water Paper page are superimposed together, form superimposed three-decker l Water Paper page.Three-decker l Water Paper page, after press dewatering, drying and dehydrating, obtains the three-decker fruit inspecting of outer faint yellow, intermediate layer black, internal layer white.
The performance of above-mentioned three-decker fruit inspecting is, is quantitatively 75g/m 2, thickness is 0.1725mm, and outside degree of sizing is 33s, and inner side degree of sizing is 11s, and machine direction tensile strength is 295kN/m, and cross direction tensile strength is 206kN/m, and tearability is 60N.Wherein, outer is quantitatively 30g/m 2, thickness is 0.0662mm; The quantitative 30g/m in intermediate layer 2, thickness is 0.0569mm; The quantitative 15g/m of internal layer 2, thickness is 0.0494mm.Outer is 0.675kg/cm with the interfacial bonding strength in intermediate layer, and the interfacial bonding strength of intermediate layer and internal layer is 0.573kg/cm.
This fruit inspecting is applicable to the bagging making pears, prevents pears in developmental process, be subject to the harm of disease and pest, makes pears surface non agricultural chemical residuum, ensures that the tasty mouthfeel of pears is good to eat.
Embodiment 2
Embodiment 2 is with the difference of embodiment 1, and embodiment 2 employs the interlayer adhesive of oxidized starch as the fruit inspecting of three-decker.
The fountain height of oxidized starch is 2g/m 2.
The using method of oxidized starch is: first cationic starch being mixed with mass concentration is 5%, then carries out gelatinization, obtains gelatinization oxidized starch.Oxidized starch good for gelatinization is sprayed be sprayed at inside outer l Water Paper page respectively, the inner side of intermediate layer l Water Paper page, then intermediate layer l Water Paper page is placed on outer l Water Paper page, outer l Water Paper page spray adhesive side and the non-spray adhesive side of intermediate layer l Water Paper page are superimposed together.And then internal layer l Water Paper page is placed on the l Water Paper page of middle level, l Water Paper page spray adhesive side, intermediate layer and internal layer l Water Paper page are superimposed together.
The performance employing the three-decker fruit inspecting of adhesive is, is quantitatively 77g/m 2, thickness is 0.1725mm, and outside degree of sizing is 32s, and inner side degree of sizing is 11s, and machine direction tensile strength is 308kN/m, and tensile strength is 213kN/m, and tearability is 61N.Wherein, outer is quantitatively 30g/m 2, thickness is 0.0662mm; Intermediate layer is 30g/m 2, thickness is 0.0569mm; Internal layer is 15g/m 2, thickness is 0.0494mm.Outer is 1.354kg/cm with the interfacial bonding strength in intermediate layer, and the interfacial bonding strength of intermediate layer and internal layer is 1.095kg/cm.
The skin of the fruit inspecting of this three-decker presents faint yellow, and intermediate layer presents black, and internal layer presents white.
This fruit inspecting is applicable to the bagging making pears, prevents pears in developmental process, be subject to the harm of disease and pest, makes pears surface non agricultural chemical residuum, ensures that the tasty mouthfeel of pears is good to eat.
Owing to employing interlayer adhesive oxidized starch, the interfacial bonding strength of the three-decker fruit inspecting of embodiment 2 is apparently higher than the three-decker fruit inspecting of embodiment 1.
Embodiment 3
Embodiment 3 difference from Example 1 is, with bleached softwood wood pulp and bleaching leaf wood paper pulp for outer paper pulp, with bleached softwood wood pulp and bleached wheat straw pulp for internal layer paper pulp, makes double-decker fruit inspecting.Concrete making step is as follows:
1, the making of outer l Water Paper page
By the mixed pulp of 30% bleached softwood wood pulp and 70% leaf wood paper pulp, be diluted with water to mass concentration 5%, after being uniformly dispersed, add retention agent cationic starch, sizing agent alkyl ketene dimer emulsion, reinforcing agent melamine resin, the direct orchil of colouring agent, carry out disperseing and mixing.After mixing, be diluted to the pulp suspension that mass concentration is 1% further, then carry out filtering and shaping, form outer l Water Paper page, obtain faint yellow outer l Water Paper page.
The consumption of cationic starch is 2% of absolute dried paper pulp amount, and the consumption of alkyl ketene dimer emulsion is 1.5% of absolute dried paper pulp amount, and melamine resin consumption is 0.8%, and the consumption of direct orchil is 10% of absolute dried paper pulp amount.
The mass content of the moisture of the outer l Water Paper page of brownish red is 85%.
2, l Water Paper page in intermediate layer makes
By the mixed pulp of 20% bleached softwood wood pulp and 80% bleached wheat straw pulp, be diluted with water to mass concentration 5%, after being uniformly dispersed, adding retention agent cationic starch, sizing agent alkyl ketene dimer emulsion, colouring agent black pigment carbon black, carry out disperseing and mixing.After mixing, be diluted to the pulp suspension that mass concentration is 1% further, then carry out filtering and shaping, form intermediate layer l Water Paper page, obtain black intermediate layer l Water Paper page.
The consumption of cationic starch is 2% of absolute dried paper pulp amount, and the consumption of alkyl ketene dimer emulsion is 1.5% of absolute dried paper pulp amount, and the consumption of black pigment carbon black is 15% of absolute dried paper pulp amount.
The mass content of the moisture of black intermediate layer l Water Paper page is 83%.
3, superimposed, press dewatering, the drying and dehydrating of l Water Paper page
In type outer brownish red l Water Paper page, black inner l Water Paper page are superimposed together, form superimposed double-decker l Water Paper page, double-decker l Water Paper page, after press dewatering, drying and dehydrating, obtains the double-decker fruit inspecting of brownish red skin, black internal layer.
The performance of above-mentioned double-decker fruit inspecting is, is quantitatively 60g/m 2, thickness is 0.1231mm, and outside degree of sizing is 31s, and inner side degree of sizing is 12s, and tensile strength is 186kN/m, and tearability is 49N.Wherein, outer is quantitatively 30g/m 2, thickness is 0.0662mm; Internal layer is 30g/m 2, thickness is 0.0569mm.Outer is 0.487kg/cm with the interfacial bonding strength of internal layer.
The double-decker fruit inspecting of this outside brownish red, inner side black, be applicable to the bagging making mcintosh, apple is made to avoid the direct irradiation of sunlight, and utilize the gas permeability of bagging itself to produce indivedual greenhouse effects, make humidity, temperature that apple keeps suitable, improve the sugariness of apple, improve the gloss of apple, increase fruited output, shorten its growth stage.Not applying pesticides in the growth course of apple, makes apple have high-quality and nuisanceless, meets the demand for development of green non-pollution agricultural.
Embodiment 4
Embodiment 4 difference from Example 3 is, embodiment 4 employs the interlayer adhesive of oxidized starch as double-deck fruit inspecting.
The fountain height of cationic starch is 2g/m 2.
The using method of cationic starch is: first cationic starch being mixed with mass concentration is 5%, then carries out gelatinization, obtains gelatinization cationic starch.Being sprayed by cationic starch good for gelatinization is sprayed at inside outer l Water Paper page respectively, is then placed on outer l Water Paper page by internal layer l Water Paper page, outer l Water Paper page spray adhesive side and internal layer l Water Paper page are superimposed together.
The performance employing the double-decker fruit inspecting of adhesive is, is quantitatively 61.5g/m 2, thickness is 0.1233mm, and outside degree of sizing is 31s, and inner side degree of sizing is 11s, and machine direction tensile strength is 276kN/m, and cross direction tensile strength is 191kN/m, and tearability is 51N.Wherein, outer is quantitatively 30g/m 2, thickness is 0.0662mm; Internal layer is 30g/m 2, thickness is 0.0569mm.Outer is 1.054kg/cm with the interfacial bonding strength of internal layer.
The double-decker fruit inspecting that this skin is brownish red, internal layer is black is applicable to the bagging making mcintosh, and this fruit inspecting is applicable to the bagging making mcintosh, and make apple sugariness high, good luster, output is high, and the growth stage is shorter, green non-pollution.
The interfacial bonding strength that embodiment 4 employs the double-decker fruit inspecting of interlayer adhesive does not use the double-decker fruit inspecting of interlayer adhesive apparently higher than embodiment 3.
Embodiment 5
Embodiment 5 difference from Example 1 is, the mixed pulp of leaf wood paper pulp and 70% bleached wheat straw pulp is bleached for outer paper pulp with 30%, take bleached wheat straw pulp as intermediate layer paper pulp, with 30% bleaching leaf wood paper pulp and 70% bleached wheat straw pulp for internal layer paper pulp, make three-decker fruit inspecting.Other are identical with embodiment 1.
The performance of above-mentioned three-decker fruit inspecting is, is quantitatively 75g/m 2, thickness is 0.1631mm, and outside degree of sizing is 30s, and inner side degree of sizing is 13s, and machine direction tensile strength is 256kN/m, and cross direction tensile strength is 176kN/m, and tearability is 49N.Wherein, outer is quantitatively 30g/m 2, thickness is 0.0626mm; The quantitative 30g/m in intermediate layer 2, thickness is 0.0513mm; The quantitative 15g/m of internal layer 2, thickness is 0.0492mm.Outer is 0.512kg/cm with the interfacial bonding strength in intermediate layer, and the interfacial bonding strength of intermediate layer and internal layer is 0.487kg/cm.
The three-decker fruit inspecting of the outer brownish red of embodiment 5, intermediate layer black, internal layer white, its interfacial bonding strength is than three-decker fruit inspecting much little of embodiment 1.Therefore, when using the fruit inspecting of embodiment 5 making and use this fruit inspecting to make fruit bag, note causing the problems such as interlaminar separation because interfacial bonding strength is smaller.
The three-decker fruit inspecting of embodiment 5 is also applicable to the bagging making pears, and growing up healthy and sound and ensureing the quality of pears and green fruit industry protection pears is significant.
Embodiment 6
Embodiment 6 difference from Example 1 is, skin and the intermediate layer of embodiment 6 all use composite paper-plastic material to be separated the paper pulp obtained, and with bleached softwood wood pulp and leaf wood paper pulp for internal layer paper pulp, makes three-decker fruit inspecting.Other are all identical with embodiment 1.
The three-decker fruit inspecting performance of embodiment 6 is be quantitatively 75g/m 2, thickness is 0.1783mm, and outside degree of sizing is 29s, and inner side degree of sizing is 13s, and machine direction tensile strength is 273kN/m, and cross direction tensile strength is 187kN/m.Wherein, outer is quantitatively 30g/m 2, thickness is 0.06295mm; Intermediate layer is 30g/m 2, thickness is 0.06295mm; Internal layer is 15g/m 2, thickness is 0.0524mm.Outer is 0.634kg/cm with the interfacial bonding strength in intermediate layer, and the interfacial bonding strength of intermediate layer and internal layer is 0.668kg/cm.
The three-decker fruit inspecting of embodiment 6, skin presents faint yellow, and intermediate layer presents black, and internal layer presents white.
Embodiment 7
Embodiment 7 difference from Example 3 is, the outer composite paper-plastic material that uses is separated the paper pulp obtained, with bleached softwood wood pulp and bleached wheat straw pulp for internal layer paper pulp, and making double-decker fruit inspecting.Other are identical with embodiment 3.
The performance of the double-decker fruit inspecting of embodiment 7 is, is quantitatively 60g/m 2, thickness is 0.1198mm, and outer degree of sizing is 33s, and internal layer degree of sizing is 13s, machine direction tensile strength 247kN/m, and cross direction tensile strength is 162kN/m, and tearability is 40N.Wherein, outer is quantitatively 30g/m 2, thickness is 0.629mm; Internal layer is quantitatively 30g/m 2, thickness is 0.0569mm.Interfacial bonding strength is 0.675kg/cm.This fruit inspecting, skin presents brownish red, and internal layer presents black.
The double-decker fruit inspecting obtained as mentioned above, three-decker fruit inspecting, its skin has higher WATER RESISTANCE, and intermediate layer or internal layer present black, has light-proofness and heat insulating ability, is conducive to improving fruit quality, better can realize the object of this fermentation.

Claims (8)

1. multi-layer compound structure fruit inspecting, is characterized in that, fruit inspecting is two-layer or being combined with each other of fitting tightly of three-decker, every one deck be quantitatively 10g/m 2~ 42g/m 2, thickness is 0.036mm ~ 0.081mm, and the total of fruit inspecting is quantitatively 30g/m 2~ 82g/m 2, gross thickness is 0.072mm ~ 0.14mm.
2. according to the multi-layer compound structure fruit inspecting of claim 1, it is characterized in that, every one deck can select different interpolation pigment as required.
3. according to the multi-layer compound structure fruit inspecting of claim 1, it is characterized in that, have double-deck fruit inspecting, the quantitative of every one deck is 20g/m 2~ 42g/m 2, thickness is 0.036mm ~ 0.081mm, and the total of fruit inspecting is quantitatively 40g/m 2~ 82g/m 2, gross thickness is 0.072mm ~ 0.14mm;
Have the fruit inspecting of three-decker, the quantitative of every one deck is 10g/m 2~ 42g/m 2, thickness is 0.036mm ~ 0.081mm, and the total of fruit inspecting is quantitatively 40g/m 2~ 82g/m 2, gross thickness is 0.072mm ~ 0.14mm.
4. according to the multi-layer compound structure fruit inspecting of claim 1, it is characterized in that, there is double-deck fruit inspecting, outer field quantitative more preferably 40g/m 2, thickness is 0.08mm, and degree of sizing is 18s, and machine direction tensile strength is 158kN/m, and cross direction tensile strength is 101kN/m, and tearability is 30N; Internal layer is quantitatively 40g/m 2, thickness is 0.08mm, and degree of sizing is 18s, and machine direction tensile strength is 113kN/m, and cross direction tensile strength is 66kN/m, and tearability is 30N;
The fruit inspecting of three-decker, outer field is quantitatively 37g/m 2, thickness is 0.08mm, and degree of sizing is 33s, and machine direction tensile strength is 93.68kN/m, and cross direction tensile strength is 78.64kN/m, and tearability is 30N; The quantitative of middle level is 48g/m 2, thickness is 0.08mm, and degree of sizing is 4s, and machine direction tensile strength is 137kN/m, and cross direction tensile strength is 46.06kN/m; The quantitative of internal layer is 47g/m 2, thickness is 0.03mm, and degree of sizing is 0.1s, and machine direction tensile strength is 26.26kN/m, and cross direction tensile strength is 23.28kN/m.
5. prepare the method for the multi-layer compound structure fruit inspecting of claim 1, it is characterized in that, comprise the following steps:
(1), the making of each layer l Water Paper page
Individually prepare each layer l Water Paper page, to wet according to each layer the requirement of page characteristic, select suitable process of plant fiber pulp, be diluted with water to mass concentration 1% ~ 5%, after being uniformly dispersed, add retention agent, sizing agent, reinforcing agent, colouring agent chemical assistant, carry out disperseing and mixing, after mixing, filtering means dehydration, shaping formation each layer l Water Paper page;
(2) in type each layer l Water Paper page is superimposed together by desired sequence, forms superimposed sandwich construction l Water Paper page, after press dewatering, drying and dehydrating, obtain sandwich construction fruit inspecting;
Or when each layer l Water Paper page is superimposed, each interlayer sprays chemical adhesive oxidized starch or carboxymethyl cellulose.
6. according to the method for claim 5, it is characterized in that, wherein, double-deck fruit inspecting, outer adopts string, and be selected from the mixed pulp of one or both or three kinds in waste paper, bleached wood pulp and bleaching straw pulp, internal layer adopts string;
The fruit inspecting of three-decker, the outer string adopted is the one in waste paper, bleached wood pulp and bleaching straw pulp, two or three mixed pulp; The string that middle level adopts is bleached wood pulp or bleaching straw pulp or the mixed pulp of the two, and the string that internal layer adopts is bleached wood pulp or bleaching straw pulp, or both mixed pulps.
7. according to the method for claim 5, it is characterized in that, double-deck fruit inspecting, skin is selected from waste paper, the mixed pulp of one or both or three kinds in bleached wood pulp and bleaching straw pulp, reinforcing agent is melamine resin or Polyamide-Polyamsne-Epichlorohydrin resin, quality consumption is 0.5% ~ 7.0% of absolute dried paper pulp amount, sizing agent is reactive sizing agent alkyl ketene dimer emulsion or rosin sizes, quality consumption is 0.5% ~ 5.0% of absolute dried paper pulp amount, retention agent is one or both in cationic starch or cationic polyacrylamide, quality consumption is 0.05% ~ 3.0% of absolute dried paper pulp amount, colouring agent is direct orchil or direct apricot yellow dyestuff, internal layer is selected from one or both the mixed pulp in bleached wood pulp or bleaching straw pulp, sizing agent is alkyl ketene dimer emulsion or rosin sizes, consumption is 0.5% ~ 2.0%, retention agent is one or both in cationic starch or cationic polyacrylamide, consumption is 0.05% ~ 3.0%, colouring agent is black pigment carbon black or acetylene black, and consumption is 4% ~ 10%.
8. according to the method for claim 5, it is characterized in that, there is the fruit inspecting of three-decker, wherein, the outer string adopted is waste paper, one in bleached wood pulp and bleaching straw pulp, two or three mixed pulp, reinforcing agent is melamine resin or Polyamide-Polyamsne-Epichlorohydrin resin, consumption is 0.5% ~ 3.0%, sizing agent is alkyl ketene dimer emulsion or rosin sizes, consumption is 0.5% ~ 2.0%, retention agent is one or both in cationic starch cationic polyacrylamide, consumption is 0.05% ~ 3.0%, colouring agent is direct orchil,
The string that middle level adopts is bleached wood pulp or bleaching straw pulp, or the mixed pulp of the two, and sizing agent is alkyl ketene dimer emulsion, consumption is 0.5% ~ 2.0%, and retention agent is cationic starch, and consumption is 0.05% ~ 3.0%, colouring agent is black pigment carbon black, and consumption is 4% ~ 10%;
The string that internal layer adopts is bleached wood pulp or bleaching straw pulp, or the mixed pulp of the two, and sizing agent is alkyl ketene dimer emulsion, and consumption is 0.5% ~ 2.0%, and retention agent is cationic starch, and consumption is 0.05% ~ 3.0%.
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