CN104710610B - Alcohol ether phosphate and preparation method thereof and prepare micro cutting liquid with this ester - Google Patents
Alcohol ether phosphate and preparation method thereof and prepare micro cutting liquid with this ester Download PDFInfo
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- CN104710610B CN104710610B CN201510067964.2A CN201510067964A CN104710610B CN 104710610 B CN104710610 B CN 104710610B CN 201510067964 A CN201510067964 A CN 201510067964A CN 104710610 B CN104710610 B CN 104710610B
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Abstract
The invention provides a kind of alcohol ether phosphate, it is characterised in that be prepared from by the material including following components: fatty alcohol, oxirane, expoxy propane, phosphorus pentoxide；Wherein, described fatty alcohol, oxirane, expoxy propane, the mol ratio of phosphorus pentoxide are 1:5 10:1 2:0.3 1.Alcohol ether phosphate prepared by the present invention has the lubricity of excellence, extreme pressure anti-wear, rust-preventing characteristic, preferably water solublity, it is again a kind of excellent surfactant simultaneously, can completely or partially replace traditional extreme pressure anti-wear additives chloride, sulfur, phosphorus to be used in micro cutting liquid, a small amount of micro cutting liquid just can meet the lubrication of intermetallic composite coating, extreme-pressure anti-wear and antirust requirement；Coordinating minimum quantity lubrication device to use, can save the usage amount more than 90% of cutting fluid, energy-saving and emission-reduction, environmental protection effect are notable.
Description
Technical field
The invention belongs to lubrication technical field, relate to a kind of alcohol ether phosphate and preparation method thereof and by this ester system
Standby micro cutting liquid.
Background technology
Traditional metal cutting process uses mineral oil or vegetable oil or cutting fluid to carry out a large amount of shower formula lubrication,
The usage amount of lubricant is big, not only wastes resource, causes the huge pollution of processing site and environment, also simultaneously
The healthy of operator can be had a strong impact on, for solving these problems, in the recent period Minimal Quantity Lubrication Technology is ground
Studying carefully and obtain certain progress, it is big that Minimal Quantity Lubrication Technology solves above lubricant usage amount, seriously polluted etc. asks
Topic, but the research to micro lubricating agent, but there is also certain problem in application aspect, mainly lubrication and
Cooling problem not can solve.
Also have, it is simply that micro lubricating agent generally requires the substantial amounts of sulfur-bearing of interpolation, chloride etc. has bigger pressure to environment
The additive of power increases the extreme pressure anti-wear of product, tool life.Such as Publication No.
A kind of micro quantity lubrication system aluminum alloy cutting fluid and preparation method thereof disclosed in the Chinese patent of CN101376863
And purposes, use: base oil 30%, sulfide isobutene 5-20%, chlorinated paraffin 5-20%, thiophosphate
5-20%, potassium borate 5-20%, surfactant 10%, antirust agent 5%, described base oil use mineral oil or
Vegetable oil.
Summary of the invention
In view of disadvantages described above, it is an object of the invention to overcome the deficiencies in the prior art, it is provided that one has biology
The alcohol ether phosphate of the multiple effect such as degradable, antirust slow release, and it is prepared for a kind of efficient, environmental protection with this ester
Micro cutting liquid.
For achieving the above object, a kind of alcohol ether phosphate that the present invention provides is characterised by, by including following group
The material divided is prepared from: fatty alcohol, oxirane, expoxy propane, phosphorus pentoxide.
Wherein, above-mentioned fatty alcohol, oxirane, expoxy propane, the mol ratio of phosphorus pentoxide are 1:5-10:
1-2:0.3-1.
The above-mentioned fatty alcohol compositions of one or more in the saturated or unsaturated fatty alcohol of C10-C20；
Above-mentioned fatty alcohol preferably be selected from Decanol, lauryl alcohol, different tridecanol, ten four carbon alcohols, hexadecanol, oleyl alcohol,
The compositions of one or more in stearyl alcohol, arachidic alcohol.
It addition, present invention also offers the preparation method of above-mentioned alcohol ether phosphate, it is characterised in that: by fat
After alcohol first carries out additive reaction with oxirane and expoxy propane, add phosphorus pentoxide and carry out Phosphation
Reaction is prepared from.
The concrete technology step of above-mentioned alcohol ether phosphate synthesis route is as follows:
Step one, fatty alcohol and catalyst are added in reactor, be filled with protection gas (such as: nitrogen, argon,
The noble gases such as helium) change out air in reactor；
Above-mentioned catalyst is base catalyst；
It is preferably sodium hydroxide or potassium hydroxide；
When using sodium hydroxide or potassium hydroxide, the percentage by weight of its effective ingredient is that above-mentioned reactant is total
The 0.3～0.5% of weight.
Step 2, when in reactor protect gas keep malleation time, by oxirane, the mixture of expoxy propane
Advance reactor (such as: with head tanks such as nitrogen, oxirane, propylene oxide mixture are advanced reactor),
Stirring simultaneously is warming up to 100-120 DEG C, and in the case of keeping reaction temperature less than 120 DEG C, 5-8 is little in reaction
Time, it is Fatty alcohol polyoxyethylene polyoxypropylene ether；
Owing to the reaction of this step is exothermic reaction, in order to prevent the too fast harmful effect of heat release, oxirane
It is necessary to be controlled by with the addition speed of expoxy propane, makes reaction carry out when gentle.
Step 3, etc. after Fatty alcohol polyoxyethylene polyoxypropylene ether has been reacted in aforesaid reaction vessel, add five
Aoxidize two phosphorus, in the case of keeping reaction temperature less than 150 DEG C, stirring reaction 2-4 hour；
Owing to the reaction of this step is exothermic reaction, in order to prevent the overheated carbonization of reaction of local, five oxidations two
The addition speed of phosphorus is necessary to be controlled by.Phosphorus pentoxide powder should be slowly added to control reaction will not
Produce the phenomenon of hot-spot.
Moisture is discharged in step 4, decompression, is alcohol ether phosphate.
It is worthy of note, the alcohol ether phosphate of the present invention is the mixture of a kind of multicomponent phosphate ester herein.
It addition, present invention also offers the using method of above-mentioned alcohol ether phosphate, i.e., it is used for preparing trace and cuts
Cut liquid.
It addition, present invention also offers the manufacture method of above-mentioned micro cutting liquid mother solution, it is characterised in that by
Following components in percentage by weight is prepared from:
Wherein, one or more during above-mentioned fatty-acid monoester refers to ester prepared by monohydric alcohol and unary fatty acid
Compositions, be selected from the straight chain fatty acid that derived by natural oil and straight-chain fatty alcohol or branched fatty alcohol obtain
The ester arrived；
Preferably be selected from methyl oleate, methyl laurate, ethyl laurate, methyl stearate, ethyl stearte,
The compositions of one or more in methyl hexadecanoate, ethyl palmitate, ethyl oleate, butyl oleate；
This fatty-acid monoester should possess the feature being easier to be hydrolyzed to fatty acid and monohydric alcohol in water.
The fatty acid that above-mentioned soap is the saturated of C10-C20 or unsaturated fatty acid and alkali reaction generates
The compositions of one or more in salt, this salt is a kind of good anion surfactant；
It preferably is selected from sodium laurate, potassium laurate, enuatrol, potassium oleate, sodium stearate, potassium stearate
The compositions of one or more.
Above-mentioned hydramine preferably is selected from the one in monoethanolamine, diethanolamine, triethanolamine, isopropanolamine or several
Plant mixture.
Above-mentioned poly-ricinoleate ester preferably is selected from one or more in the poly-ricinoleate ester that the degree of polymerization is 3-6 and mixes
Compound；
It is 4 poly-ricinoleate esters most preferably from the degree of polymerization, marque: L4.
The mother solution of this micro cutting liquid in the preparation, by above-mentioned each component mix and blend at a temperature of 40～60 DEG C
To time transparent.
In use, add water above-mentioned micro cutting liquid mother solution 1-5 times to stir and add to after transparent or semitransparent
Minimum quantity lubrication device uses.
The effect of the present invention and effect:
The alcohol ether phosphate using the inventive method to prepare, has the lubricity of excellence, extreme pressure anti-wear, prevents
Rust property, preferable water solublity, it is again a kind of excellent surfactant simultaneously, can completely or partially replace biography
The extreme pressure anti-wear additives chloride, sulfur, phosphorus of system is used in micro cutting liquid, and a small amount of micro cutting liquid is with regard to energy
Meet the lubrication of intermetallic composite coating, extreme-pressure anti-wear and antirust requirement；Minimum quantity lubrication device is coordinated to use, can
Saving the usage amount more than 90% of cutting fluid, energy-saving and emission-reduction, environmental protection effect are notable.
It addition, in the solution of the present invention, be specifically added expoxy propane and carry out copolyreaction, make the present invention's
Product is in addition to possessing above-mentioned characteristic, it is also possible to suppress the generation of foam in product system, simultaneously also can be effective
Increase lubrication oiliness.
When being used for preparing micro cutting liquid, the component being additionally added, such as: fatty-acid monoester provides good profit
Slip, is easier to be hydrolyzed to fatty acid and monohydric alcohol in water simultaneously.
Hydramine can improve the pH value of micro cutting liquid while neutralized alcohol ether phosphate acid number, also has preferably
Rustless property.
Poly-ricinoleate ester then has good lubricity and extreme pressure anti-wear, can partly replace sulfur-bearing, chloride
Extreme pressure anti-wear additives, be easier to prepare water-soluble metalworking liquid.
And soap is outstanding anion surfactant.When this material and other components are together used for making
When making micro cutting liquid, in addition to above-mentioned functions, moreover it is possible to match with the some surface active property of alcohol ether phosphate,
Realize compounding effect, while making product of the present invention possess excellent surface tension force, each component be more uniformly distributed and
Dispersion, can preferably play effect of each component.
Detailed description of the invention
Embodiment one
Step one: the lauryl alcohol and the 5.5kg potassium hydroxide (50%) that weigh 186.38kg (1000mol) are molten
In liquid reactor, it is filled with nitrogen and changes out air in reactor, when nitrogen keeps malleation in polymeric kettle, use
308.35kg (7000mol) oxirane, 58.08kg (1000mol) expoxy propane are mixed by nitrogen feed tank
Compound advances reactor, stirring to be simultaneously warming up to 120 DEG C, keeps reaction temperature to be less than 120 DEG C, during reaction
Between be: 6 hours, be lauryl alcohol polyethylene glycol oxide (7) polyoxypropylene (1) ether.
Step 2, etc. in aforesaid reaction vessel lauryl alcohol polyethylene glycol oxide (7) polyoxypropylene (1) ether reacted
After, it is slowly added to 70.97kg (500mol) the phosphorus pentoxide stirring weighed, keeps reaction temperature to be less than
150 DEG C, then after reacting 3 hours, moisture is discharged in decompression, is lauryl alcohol polyethylene glycol oxide (7) polyoxy third
Alkene (1) ether phosphate.
Above-mentioned a kind of lauryl alcohol polyethylene glycol oxide (7) polyoxypropylene (1) ether phosphate and water are pressed 1:1 mixing
Stirring, is a kind of micro cutting liquid.
Above-mentioned micro cutting liquid GB/T12583 experimental technique is carried out four ball extreme pressure tests, result of the test:
PD>620(kgf)。
Above-mentioned micro cutting liquid is applied to YN3150 gear-hobbing machine processing diameter 120mm, modulus 2.2mm gear,
Hobboing cutter: TiN coating, diameter 75, length 70, originally it was circulated lubrication with 46# machinery oil, existing
Changing KS-2106 minimum quantity lubrication device (3 nozzles, all nozzles are that our company produces energy-conserving spray nozzle) and into
Plant micro cutting liquid, result such as following table:
Embodiment two
Step one: the oleyl alcohol and 12kg sodium hydroxide (30%) solution that weigh 268.49kg (1000mol) are anti-
In answering still, it is filled with nitrogen and changes out air in reactor, when nitrogen keeps malleation in polymeric kettle, use nitrogen
Head tank is by 396.45kg (9000mol) oxirane, the mixing of 116.16kg (2000mol) expoxy propane
Thing advances reactor, stirring to be simultaneously warming up to 120 DEG C, keeps reaction temperature to be less than 120 DEG C, the response time
For: 7 hours, it is oleic alcohol polyoxyethylene (9) polyoxypropylene (2) ether.
Step 2, etc. after oleic alcohol polyoxyethylene (9) polyoxypropylene (2) ether has reacted in aforesaid reaction vessel,
It is slowly added to 113.55kg (800mol) the phosphorus pentoxide stirring weighed, keeps reaction temperature to be less than
150 DEG C, then after reacting 4 hours, moisture is discharged in decompression, is oleic alcohol polyoxyethylene (9) polyoxypropylene
(2) ether phosphate.
Take oleic alcohol polyoxyethylene (9) polyoxypropylene (2) the ether phosphate 50kg of above-mentioned preparation, methyl oleate
25kg, triethanolamine 15kg, enuatrol 5kg, 5kg poly-ricinoleate ester L4 stir at a temperature of about 50 DEG C
Mix and be a kind of micro cutting liquid to solution in about 30 minutes.
By above-mentioned micro cutting liquid: water mixes to transparent being used in by 1:3 and is applied to linear velocity and is
The aluminium alloy bars of 800m/min hyper tape saw cut Φ 320mm, was circulated lubrication with emulsion originally,
Change now KS-2106 minimum quantity lubrication device (U-shaped nozzle, 2 go out liquid/gas hole) and a kind of micro cutting into
Liquid, result such as following table:
| Project | Before transformation | After transformation |
| Cut a cutter required time | 150 seconds | 150 seconds |
| Saw blade average life | 3/month | 2/month |
| Lubricant consumes | 25kg/ days | 0.8kg/ days |
| Working site | Cutting fluid flows everywhere, on-the-spot dirty and messy | The cleanest |
Embodiment three
Step one: weigh arachidic alcohol and 7kg potassium hydroxide (50%) solution of 298.55kg (1000mol)
In reactor, it is filled with nitrogen and changes out air in reactor, when nitrogen keeps malleation in polymeric kettle, use nitrogen
440.5kg (10000mol) oxirane, 116.16kg (2000mol) expoxy propane are mixed by gas head tank
Compound advances reactor, stirring to be simultaneously warming up to 120 DEG C, keeps reaction temperature to be less than 120 DEG C, during reaction
Between be: 6.5 hours, be arachidic alcohol polyoxyethylene (10) polyoxypropylene (2) ether.
Step 2, etc. in aforesaid reaction vessel arachidic alcohol polyoxyethylene (10) polyoxypropylene (2) ether reacted
After, it is slowly added to 141.94kg (1000mol) the phosphorus pentoxide stirring weighed, keeps reaction temperature to be less than
150 DEG C, then after reacting 3.5 hours, moisture is discharged in decompression, is arachidic alcohol polyoxyethylene (10) polyoxy
Propylene (2) ether phosphate.
Take arachidic alcohol polyoxyethylene (10) polyoxypropylene (2) the ether phosphate 40kg of above-mentioned preparation, oleic acid fourth
Ester 30kg, monoethanolamine 10kg, sodium stearate 10kg, 10kg trimerization ricinoleate ester are about 40 DEG C temperature
Lower stirring about 30 minutes to the solution of degree is a kind of micro cutting liquid.
Embodiment four
Step one: weigh stearyl alcohol and 6kg sodium hydroxide (40%) solution of 270.56kg (1000mol)
In reactor, it is filled with nitrogen and changes out air in reactor, when nitrogen keeps malleation in polymeric kettle, use nitrogen
396.45kg (9000mol) oxirane, 116.16kg (2000mol) expoxy propane are mixed by gas head tank
Compound advances reactor, stirring to be simultaneously warming up to 120 DEG C, keeps reaction temperature to be less than 120 DEG C, during reaction
Between be: 5 hours, be stearyl alcohol polyoxyethylene (9) polyoxypropylene (2) ether.
Step 2, etc. in aforesaid reaction vessel stearyl alcohol polyoxyethylene (9) polyoxypropylene (2) ether reacted
After, it is slowly added to 85.16kg (600mol) the phosphorus pentoxide stirring weighed, keeps reaction temperature to be less than
150 DEG C, then after reacting 2.5 hours, moisture is discharged in decompression, is stearyl alcohol polyoxyethylene (9) polyoxy
Propylene (2) ether phosphate.
Take stearyl alcohol polyoxyethylene (9) polyoxypropylene (2) the ether phosphate 60kg of above-mentioned preparation, oleic acid second
Ester 20kg, diethanolamine 10kg, sodium laurate 5kg, 5kg poly-ricinoleate ester L4 are about 60 DEG C temperature
Lower stirring about 30 minutes to solution is a kind of micro cutting liquid.
Embodiment five
Step one: weigh hexadecanol and 10kg sodium hydroxide (30%) solution of 242.5kg (1000mol)
In reactor, it is filled with nitrogen and changes out air in reactor, when nitrogen keeps malleation in polymeric kettle, use nitrogen
Gas head tank is by 396.45kg (6000mol) oxirane, the mixing of 58.08kg (1000mol) expoxy propane
Thing advances reactor, stirring to be simultaneously warming up to 120 DEG C, keeps reaction temperature to be less than 120 DEG C, the response time
For: 8 hours, it is hexadecanol polyoxyethylene (6) polyoxypropylene (1) ether.
Step 2, etc. in aforesaid reaction vessel hexadecanol polyoxyethylene (6) polyoxypropylene (1) ether reacted
After, it is slowly added to 42.58kg (300mol) the phosphorus pentoxide stirring weighed, keeps reaction temperature to be less than
150 DEG C, then after reacting 3 hours, moisture is discharged in decompression, is hexadecanol polyoxyethylene (6) polyoxy third
Alkene (1) ether phosphate.
Take hexadecanol polyoxyethylene (6) polyoxypropylene (1) the ether phosphate 45kg of above-mentioned preparation, Palmic acid
Methyl ester 25kg, isopropanolamine 13kg, potassium laurate 9kg, 8kg poly-ricinoleate ester L4 are about 50 DEG C temperature
Lower stirring about 30 minutes to the solution of degree is a kind of micro cutting liquid.
Embodiment six
Step one: weigh Decanol and 6kg sodium hydroxide (40%) solution of 158.28kg (1000mol)
In reactor, it is filled with nitrogen and changes out air in reactor, when nitrogen keeps malleation in polymeric kettle, use nitrogen
Gas head tank is by 220.25kg (5000mol) oxirane, the mixing of 58.08kg (1000mol) expoxy propane
Thing advances reactor, stirring to be simultaneously warming up to 120 DEG C, keeps reaction temperature to be less than 120 DEG C, the response time
For: 5.5 hours, it is Decanol polyoxyethylene (5) polyoxypropylene (1).
Step 2, etc. after Decanol polyoxyethylene (5) polyoxypropylene (1) has reacted in aforesaid reaction vessel,
It is slowly added to 56.77kg (400mol) the phosphorus pentoxide stirring weighed, keeps reaction temperature to be less than 150 DEG C,
After reacting 2.5 hours again, moisture is discharged in decompression, is Decanol polyoxyethylene (5) polyoxypropylene (1)
Ether phosphate.
Take Decanol polyoxyethylene (5) polyoxypropylene (1) the phosphate ester 55kg of above-mentioned preparation, lauric acid first
Ester 22kg, triethanolamine 12kg, the poly-ricinoleate ester of potassium oleate 8kg, 7kg six are at a temperature of about 50 DEG C
Stir and be a kind of micro cutting liquid to solution in about 30 minutes.
Embodiment seven
Step one: ten four carbon alcohols and the 9kg sodium hydroxide (30%) that weigh 214.39kg (1000mol) are molten
In liquid reactor, it is filled with nitrogen and changes out air in reactor, when nitrogen keeps malleation in polymeric kettle, use
264.3kg (6000mol) oxirane, 87.12kg (1500mol) expoxy propane are mixed by nitrogen feed tank
Compound advances reactor, stirring to be simultaneously warming up to 120 DEG C, keeps reaction temperature to be less than 120 DEG C, during reaction
Between be: 6 hours, be tetradecyl alchohol polyoxyethylene poly-oxygen propylene aether.
Step 2, etc. after tetradecyl alchohol polyoxyethylene poly-oxygen propylene aether has reacted in aforesaid reaction vessel, slowly add
Enter the 60kg phosphorus pentoxide stirring weighed, keep reaction temperature less than 150 DEG C, then react 3 hours with
After, moisture is discharged in decompression, is tetradecyl alchohol polyoxyethylene poly-oxygen propylene aether phosphate ester.
By above-mentioned tetradecyl alchohol polyoxyethylene poly-oxygen propylene aether phosphate ester and water nearly percentage by weight 1:3 mix and blend
It is a kind of micro cutting liquid to transparent.
Embodiment eight
Step one: the different tridecanol and the 8kg sodium hydroxide (30%) that weigh 200.36kg (1000mol) are molten
In liquid reactor, it is filled with nitrogen and changes out air in reactor, when nitrogen keeps malleation in polymeric kettle, use
286.33kg (6500mol) oxirane, 87.12kg (1500mol) expoxy propane are mixed by nitrogen feed tank
Compound advances reactor, stirring to be simultaneously warming up to 120 DEG C, keeps reaction temperature to be less than 120 DEG C, during reaction
Between be: 6.5 hours, be different tridecanol polyoxyethylene polyethenoxy ether.
Step 2, etc. after different tridecanol polyoxyethylene polyethenoxy ether has reacted in aforesaid reaction vessel, slowly
Add the 50kg phosphorus pentoxide stirring weighed, keep reaction temperature to be less than 150 DEG C, then it is little to react 3.5
Shi Yihou, decompression is discharged moisture, is different tridecanol polyoxyethylene polyoxypropylene ether phosphate.
Above-mentioned different tridecanol polyoxyethylene polyoxypropylene ether phosphate and water nearly percentage by weight 1:2 are mixed and stirs
Mix and be a kind of micro cutting liquid to transparent.
The micro cutting liquid that above-described embodiment three to eight manufactures can obtain such as effect suitable in embodiment one and two
Really.
Claims (8)
1. the mother solution of a micro cutting liquid, it is characterised in that be prepared from by following components in percentage by weight:
Described alcohol ether phosphate, is prepared from by the material including following components: fatty alcohol, oxirane, expoxy propane, phosphorus pentoxide；
Wherein, described fatty alcohol, oxirane, expoxy propane, the mol ratio of phosphorus pentoxide are 1:5-10:1-2:0.3-1；
The described fatty-acid monoester mixture of one or more in methyl oleate, methyl laurate, ethyl laurate, methyl stearate, ethyl stearte, methyl hexadecanoate, ethyl palmitate, ethyl oleate, butyl oleate；
The described soap mixture of one or more in sodium laurate, potassium laurate, enuatrol, potassium oleate, sodium stearate, potassium stearate；
Described hydramine one or more mixture in monoethanolamine, diethanolamine, triethanolamine, isopropanolamine；
Described poly-ricinoleate ester is one or more mixture in the poly-ricinoleate ester of 3-6 selected from the degree of polymerization.
The mother solution of a kind of micro cutting liquid the most as claimed in claim 1, it is characterised in that:
The described fatty alcohol compositions of one or more in the saturated or unsaturated fatty alcohol of C10-C20.
The mother solution of a kind of micro cutting liquid the most as claimed in claim 1, it is characterised in that:
The described fatty alcohol compositions of one or more in Decanol, lauryl alcohol, different tridecanol, ten four carbon alcohols, hexadecanol, oleyl alcohol, stearyl alcohol, arachidic alcohol.
The mother solution of a kind of micro cutting liquid the most as claimed in claim 1, it is characterised in that: the manufacture method of described alcohol ether phosphate,
After first being carried out additive reaction by fatty alcohol with oxirane and expoxy propane, add phosphorus pentoxide and carry out what phosphating reaction was prepared from.
The mother solution of a kind of micro cutting liquid the most as claimed in claim 4, it is characterised in that the manufacture method of described alcohol ether phosphate, concrete technology step is as follows:
Step one, fatty alcohol and catalyst are added in reactor, be filled with protection gas shift and go out air in reactor；
Step 2, when reactor being protected gas keep malleation, the mixture of oxirane, expoxy propane advances reactor, stirring simultaneously are warming up to 100-120 DEG C, in the case of keeping reaction temperature less than 120 DEG C, reacts 5-8 hour；
Step 3, addition phosphorus pentoxide, in the case of keeping reaction temperature less than 150 DEG C, stirring reaction 2-4 hour；
Moisture is discharged in step 4, decompression, is alcohol ether phosphate；
Wherein, described catalyst is base catalyst.
The mother solution of a kind of micro cutting liquid the most as claimed in claim 5, it is characterised in that:
Described catalyst is sodium hydroxide or potassium hydroxide；
The effective ingredient of described sodium hydroxide or potassium hydroxide is the 0.3-0.5% of reactant gross weight.
7. the mother solution of a kind of micro cutting liquid as described in claim 1-6 is arbitrary, it is characterised in that:
Its manufacture method is: when mixing to transparent by each component at a temperature of 40-60 DEG C.
8. the mother solution of a kind of micro cutting liquid as described in claim 1-6 is arbitrary, it is characterised in that:
Its using method is: the water stirring that the mother solution of described micro cutting liquid adds 1-5 times adds use in minimum quantity lubrication device after transparent or semitransparent.
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| CN105038919A (en) * | 2015-06-19 | 2015-11-11 | 重庆电子工程职业学院 | Cutting fluid for machine tool |
| CN105131275B (en) * | 2015-09-18 | 2017-05-17 | 佛山市贝特尔化工有限公司 | Preparation method of environment friendly phosphate ester copolymer |
| FR3045066B1 (en) * | 2015-12-14 | 2017-12-08 | Rhodia Operations | ALCOXYLATED PHOSPHATE ESTERS FOR LUBRICATING COMPOSITIONS |
| CN105695042B (en) * | 2016-03-04 | 2018-06-08 | 上海金兆节能科技有限公司 | Lubricant compositions and preparation method thereof and prepare micro cutting liquid with the composition |
| CN107760417A (en) * | 2016-08-15 | 2018-03-06 | 惠州市米特仑科技有限公司 | A kind of novel environment friendly transparent cutting liquid |
| CN106632456B (en) * | 2016-12-20 | 2018-08-14 | 上海金兆节能科技有限公司 | Sweet dew polyol fatty acid phosphate and preparation method thereof and prepare environmentally friendly micro lubricating oil with ester |
| CN107057801A (en) * | 2017-04-18 | 2017-08-18 | 上海金兆节能科技有限公司 | A kind of environmentally friendly micro cutting liquid and preparation method thereof |
| CN106914584B (en) * | 2017-04-18 | 2018-10-19 | 上海金兆节能科技有限公司 | A kind of aluminium alloy casting crystallizer mould oil and preparation method thereof |
| CN107118841A (en) * | 2017-06-15 | 2017-09-01 | 上海金兆节能科技有限公司 | Environment-friendly type micro cutting liquid and preparation method thereof |
| IT201800010416A1 (en) * | 2018-11-19 | 2020-05-19 | Lamberti Spa | LUBRICANT ADDITIVES FOR METAL WORKING |
| CN111018677A (en) * | 2019-12-18 | 2020-04-17 | 浙江绿科安化学有限公司 | Synthetic method for preparing isomeric lauryl polyoxyethylene ether from n-hexanol |
| CN110981906B (en) * | 2019-12-18 | 2022-08-09 | 浙江皇马科技股份有限公司 | Synthetic method of isomeric dodecyl alcohol polyoxyethylene ether phosphate ester |
| CN115368960A (en) * | 2022-08-26 | 2022-11-22 | 江苏钟山新材料有限公司 | Metal cutting fluid and application thereof |
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| CN101941987B (en) * | 2010-08-24 | 2012-10-24 | 浙江皇马科技股份有限公司 | Method for preparing isooctanol polyoxyethylene polyoxypropylene ether phosphate ester |
| CN104031732B (en) * | 2014-06-13 | 2015-10-21 | 上海金兆节能科技有限公司 | Special micro lubricating agent of oil-water-gas three-phase lubricating system with trace amount and preparation method thereof |
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