CN104708878A - High-elastic two-component composite microporous film - Google Patents

High-elastic two-component composite microporous film Download PDF

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Publication number
CN104708878A
CN104708878A CN201510087346.4A CN201510087346A CN104708878A CN 104708878 A CN104708878 A CN 104708878A CN 201510087346 A CN201510087346 A CN 201510087346A CN 104708878 A CN104708878 A CN 104708878A
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Prior art keywords
parts
film
composite microporous
polyurethane
microporous film
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CN201510087346.4A
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CN104708878B (en
Inventor
张子睿
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Kunshan Huayang New Material Ltd Co
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Kunshan Huayang New Material Ltd Co
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Priority to CN201610478036.XA priority Critical patent/CN106113833B/en
Priority to CN201510087346.4A priority patent/CN104708878B/en
Priority to CN201610478035.5A priority patent/CN106113861B/en
Priority to CN201610481554.7A priority patent/CN106142695B/en
Priority to CN201610477974.8A priority patent/CN106079633B/en
Publication of CN104708878A publication Critical patent/CN104708878A/en
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/08—Heat resistant; Fire retardant
    • A41D31/085—Heat resistant; Fire retardant using layered materials
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/10—Impermeable to liquids, e.g. waterproof; Liquid-repellent
    • A41D31/102—Waterproof and breathable
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    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
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    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
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    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
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    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C—CHEMISTRY; METALLURGY
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Abstract

The invention discloses a high-elastic two-component composite microporous film. The high-elastic two-component composite microporous film comprises a microporous polyurethane film and a polytetrafluoroethylene film, wherein the microporous polyurethane film and the polytetrafluoroethylene film are adhered through an adhesive layer; a prefabricated polyurethane sizing agent consists of the following components: 100 parts of polyurethane resin, 20-25 parts of dimethyl formamide, 32-35 parts of methylbenzene, 12-15 parts of butanone, 8-9 parts of thermal expansion microspheres, 1.5-2.5 parts of 1, 4-butanediol, 1.2-1.8 parts of polyacrylamide, 0.3-0.5 part of acrylic ester, and 0.2-0.3 part of organo-siloxane emulsion; the adhesive layer consists of the following components: 100 parts of polyurethane resin, 12-15 parts of dimethyl formamide, 4-6 parts of methylbenzene, 7-9 parts of ethyl acetate, 4-6 parts of thermal expansion microspheres, 0.2-0.4 part of a bridge agent, 0.15-0.25 part of an accelerant and 1.2-2 parts of a silane coupling agent. According to the composite microporous film disclosed by the invention, the elasticity and adaptability are improved, the composite microporous film has high strength high abrasion resistance, and free of water absorption, and the temperature resistance is improved.

Description

The two composite microporous film of component of high resiliency
Technical field
The present invention relates to the two composite microporous film of component of a kind of high resiliency, belong to technical field of textile fabric.
Background technology
Waterproof & Moisture Permeable Film of the prior art is hydrophilic Waterproof & Moisture Permeable Film mainly, utilizes the composite material that this film is made, and its mechanism is contacted with fabric face by sweat vapour, is delivered to the external world by hydrophilic radical.The greatest problem that this fabric exists is exactly: hydrophilic radical adsorbed water molecule, makes fabric become very thick and heavy, clammy, and human body dress has discomfort.Also having a kind of is exactly micro-porous membrane based on nanometer technology principle, wherein main based on the micro-porous membrane of polyurethane and polytetrafluoroethylene film, these two kinds of films have different pluses and minuses, the micro-porous membrane of polyurethane has its excellent spring of good waterproofing and moisture-penetration performances, with the laminating process of fabric in can adapt to different attaching process, prevent fabric wrinkling, the situation that elasticity is not good, in the motion process of simultaneously high strength out of doors, stretching in various degree can be there is in the fabric of joint part, so this thin-film material imparts elasticity and adaptability that clothes become reconciled, also prevent the situation such as Film Tear in violent motion process, make it no matter can both have excellent water resistance in which type of environment.And polytetrafluoroethylene film, because its special microcellular structure (in netted) makes it have wind and water preventing, water vapour permeability that pore type polyurethane film can not have, be better than traditional microporous polyurethane film, but its shortcoming is also obvious, its elasticity of this material is zero substantially, therefore this thin-film material be with the recombination process of fabric in or all well can not adapt to fabric in the strenuous exercise's process in high strength stretches the thin film damage brought, easily cause the decline of the bond properties of water resistance and itself and fabric.
Summary of the invention
The object of the invention is to provide the two composite microporous film of component of a kind of high resiliency, and this composite microporous film improves elasticity and adaptability, has high strength, does not absorb water, anti-wear performance, improves heat resistance simultaneously.
For achieving the above object, the technical solution used in the present invention is: the two composite microporous film of component of a kind of high resiliency, comprise pore type polyurethane film, polytetrafluoroethylene film, bonded by adhesive layer between described pore type polyurethane film, polytetrafluoroethylene film, the number of described polytetrafluoroethylene film hole is per square inch 85 ~ 9,500,000,000, and the average diameter of hole is 0.2um ~ 10um;
Described pore type polyurethane film is also toasted at the baking oven of 80 ~ 150 degree of thermogrades in silicon oil release paper successively by prefabricated polyurethane slurry blade coating, obtains when reaching 150 degree and being cooled to normal temperature after insulation again;
Described prefabricated polyurethane slurry is composed of the following components:
Polyurethane resin 100 parts,
Dimethyl formamide 20 ~ 25 parts,
Toluene 32 ~ 35 parts,
Butanone 12 ~ 15 parts,
Microspheres 8 ~ 9 parts,
Isosorbide-5-Nitrae one butanediol 1.5 ~ 2.5 parts,
Polyacrylamide 1.2 ~ 1.8 parts,
Acrylate 0.3 ~ 0.5 part,
Organosiloxane emulsion 0.2 ~ 0.3 part;
Described adhesive layer is composed of the following components:
Polyurethane resin 100 parts,
Dimethyl formamide 12 ~ 15 parts,
Toluene (TOL) 4 ~ 6 parts,
7 ~ 9 parts, ethyl acetate,
Microspheres 4 ~ 6 parts,
Crane span structure agent 0.2 ~ 0.4 part,
Promoter 0.15 ~ 0.25 part,
Silane coupler 1.2 ~ 2 parts.
The technical scheme improved further in technique scheme is as follows:
As preferably, the volume of described polytetrafluoroethylene film Hole accounts for 80 ~ 90% of polytetrafluoroethylene film volume.
As preferably, the mass ratio between described polytetrafluoroethylene film and pore type polyurethane film is 1:6.5 ~ 7, and Thickness Ratio is 1:0.3 ~ 0.6.
As preferably, the baking oven baking of described 80 ~ 150 degree of thermogrades specifically comprised with the next stage:
The described first stage: under the condition of 80 DEG C, and carry out under the empty vapour atmosphere of low speeds flow;
Second stage: under the condition of 90 DEG C, and carry out under the empty vapour atmosphere of middling speed flowing;
Phase III: under the condition of 110 DEG C, and carry out under the empty vapour atmosphere of strong speed flowing;
Fourth stage: under the condition of 140 DEG C, and carry out under the empty vapour atmosphere of low speeds flow.
As preferably, described microspheres is akzonobel company microspheres, and it has in flexible shell containing low-boiling point materials such as iso-butane, propane, pentanes.
Because technique scheme is used, the present invention compared with prior art has following advantages and effect:
1. the two composite microporous film of component of high resiliency of the present invention, avoiding adsorbing the materials such as the dust in empty vapour, the salt in sweat, grease cosmetics and washing agent due to pore type polytetrafluoroethylene film layer, achieve and keep stable waterproof and perspire vapour performance for a long time; Secondly, combine and there is layer of polyurethane and polytetrafluoroethylene film layer, while improving external prevention rainwater performance, have the performance enhancing and internally discharge human body sweat vapour, make fabric have better comfort property and more wide range of application; Again, because this pair of component thin-film material has a large amount of uniform hole, and there is the hydrophilic microvoid polyurethane resin bed refusing the type of oil, thus the discharge be more conducive to from human body water vapour, greatly reduce the moisture on residual thin polyurethane rete surface, thus improve the wearability of coating fabric and wear dry and comfortable, most importantly substantially increase the elasticity of PTFE film material, make clothes clothes also have good mechanical property under high sharp movement and extreme condition.
2. the two composite microporous film of component of high resiliency of the present invention, for the particular combination with polytetrafluoroethylene film, optimizes the formula of pore type polyurethane film, thus improves elasticity and adaptability, have high strength simultaneously, do not absorb water, anti-wear performance; Secondly, the present invention adopts the fill a prescription selection of above-mentioned solvent and silane coupler of special adhesive can make to have better bond properties between adhesive and polytetrafluoroethylene film, improve heat resistance simultaneously, resist cold and can reach less than-150 DEG C, heat-resistingly reach+150 DEG C, (ISO 2136 standard) resistance to tortuous 9000 nothings are split.
Accompanying drawing explanation
Accompanying drawing 1 is the two composite microporous membrane structure schematic diagram of component of high resiliency of the present invention.
In above accompanying drawing: 1, pore type polyurethane film; 2, polytetrafluoroethylene film; 3, adhesive layer; 4, hole.
Detailed description of the invention
Below in conjunction with drawings and Examples, the invention will be further described:
Embodiment 1: the two composite microporous film of component of a kind of high resiliency, comprise pore type polyurethane film 1, polytetrafluoroethylene film 2, bonded by adhesive layer 3 between described pore type polyurethane film 1, polytetrafluoroethylene film 2, the number of described polytetrafluoroethylene film 2 hole 4 is per square inch 85 ~ 9,500,000,000, and the average diameter of hole 4 is 0.2um ~ 10um;
Described pore type polyurethane film 1 is also toasted at the baking oven of 80 ~ 150 degree of thermogrades in silicon oil release paper successively by prefabricated polyurethane slurry blade coating, obtains when reaching 150 degree and being cooled to normal temperature after insulation again;
Described prefabricated polyurethane slurry is composed of the following components:
Polyurethane resin 100 parts,
Dimethyl formamide 22 parts,
Toluene 32 parts,
Butanone 13 parts,
Microspheres 8.5 parts,
Isosorbide-5-Nitrae one butanediol 1.8 parts;
Polyacrylamide 1.5 parts;
Acrylate 0.35 part,
Organosiloxane emulsion 0.25 part.
Described adhesive layer 3 is composed of the following components:
Polyurethane resin 100 parts,
Dimethyl formamide 12 parts,
Toluene (TOL) 5 parts,
8 parts, ethyl acetate,
Microspheres 5 parts,
Crane span structure agent 0.3 part,
Promoter 0.2 part,
Silane coupler 1.5 parts.
The volume of above-mentioned polytetrafluoroethylene film Hole accounts for 80 ~ 82% of polytetrafluoroethylene film volume.
Mass ratio between above-mentioned polytetrafluoroethylene film 2 and pore type polyurethane film 1 is 1:6.5 ~ 7, and Thickness Ratio is 1:0.3 ~ 0.6.
The baking oven baking of above-mentioned 80 ~ 150 degree of thermogrades specifically comprised with the next stage:
The described first stage: under the condition of 80 DEG C, and carry out under the empty vapour atmosphere of low speeds flow;
Second stage: under the condition of 90 DEG C, and carry out under the empty vapour atmosphere of middling speed flowing;
Phase III: under the condition of 110 DEG C, and carry out under the empty vapour atmosphere of strong speed flowing;
Fourth stage: under the condition of 140 DEG C, and carry out under the empty vapour atmosphere of low speeds flow.
Above-mentioned microspheres is akzonobel company microspheres, and it has in flexible shell containing low-boiling point materials such as iso-butane, propane, pentanes.
Embodiment 2: the two composite microporous film of component of a kind of high resiliency, comprise pore type polyurethane film 1, polytetrafluoroethylene film 2, bonded by adhesive layer 3 between described pore type polyurethane film 1, polytetrafluoroethylene film 2, the number of described polytetrafluoroethylene film 2 hole 4 is per square inch 85 ~ 9,500,000,000, and the average diameter of hole 4 is 0.2um ~ 10um;
Described pore type polyurethane film 1 is also toasted at the baking oven of 80 ~ 150 degree of thermogrades in silicon oil release paper successively by prefabricated polyurethane slurry blade coating, obtains when reaching 150 degree and being cooled to normal temperature after insulation again;
Described prefabricated polyurethane slurry is composed of the following components:
Polyurethane resin 100 parts,
Dimethyl formamide 25 parts,
Toluene 35 parts,
Butanone 15 parts,
Microspheres 9 parts,
Isosorbide-5-Nitrae one butanediol 2.2 parts;
Polyacrylamide 1.8 parts;
Acrylate 0.4 part,
Organosiloxane emulsion 0.3 part.
Described adhesive layer 3 is composed of the following components:
Polyurethane resin 100 parts,
Dimethyl formamide 15 parts,
Toluene 6 parts,
9 parts, ethyl acetate,
Microspheres 4.5 parts,
Crane span structure agent 0.25 part,
Promoter 0.25 part,
Silane coupler 1.8 parts.
The volume of above-mentioned polytetrafluoroethylene film Hole accounts for 87 ~ 89% of polytetrafluoroethylene film volume.
Mass ratio between above-mentioned polytetrafluoroethylene film 2 and pore type polyurethane film 1 is 1:6.5 ~ 7, and Thickness Ratio is 1:0.3 ~ 0.6.
Above-mentioned microspheres is akzonobel company microspheres, and it has in flexible shell containing low-boiling point materials such as iso-butane, propane, pentanes.
Specific targets numerical value of the present invention is as follows:
A. hydrostatic pressing value washes front >12000mmH2O, >8000mmH2O(washing methods ISO 6330, method of testing ISO 811 after five washings),
B. vapor transfer rate: 10000g/m224h(JIS 1099 A1),
C. anti-flammability is B level by (GB8965.2-2009) criterion,
D. peel strength (GB11042-89): 4N,
E. cold-resistantly can reach less than-150 DEG C, heat-resistingly reach+150 DEG C, (ISO 2136 standard) resistance to tortuous 9000 nothings are split,
F. film stretching rate 25%,
G. film response rate 96%,
H. wind-proof performance: completely windproof (>10 level),
I. thermal impedance (GB/T 11048-2008 A method): 0.1097m2K/W.
When adopting the composite microporous film of the two component of above-mentioned high resiliency, avoiding adsorbing the materials such as the dust in empty vapour, the salt in sweat, grease cosmetics and washing agent due to pore type polytetrafluoroethylene film layer, achieve and keep stable waterproof and perspire vapour performance for a long time; Secondly, combine and there is hydrophilic layer of polyurethane and the polytetrafluoroethylene film layer of refusing oil, while improving external prevention rainwater performance, there is the performance enhancing and internally discharge human body sweat vapour, make fabric have better comfort property and more wide range of application; Again, because this pair of component thin-film material has a large amount of uniform hole, and there is the hydrophilic microvoid polyurethane resin bed refusing the type of oil, thus the discharge be more conducive to from human body water vapour, greatly reduce the moisture on residual thin polyurethane rete surface, thus improve the wearability of coating fabric and wear dry and comfortable, most importantly substantially increase the elasticity of PTFE film material, make clothes clothes also have good mechanical property under high sharp movement and extreme condition; Secondly, the present invention adopts the fill a prescription selection of above-mentioned solvent and silane coupler of special adhesive can make to have better bond properties between adhesive and polytetrafluoroethylene film, improve cold tolerance simultaneously, resist cold and can reach less than-150 DEG C, heat-resistingly reach+150 DEG C, (ISO 2136 standard) resistance to tortuous 9000 nothings are split.
Above-described embodiment, only for technical conceive of the present invention and feature are described, its object is to person skilled in the art can be understood content of the present invention and implement according to this, can not limit the scope of the invention with this.All equivalences done according to Spirit Essence of the present invention change or modify, and all should be encompassed within protection scope of the present invention.

Claims (5)

1. the two composite microporous film of component of high resiliency, it is characterized in that: comprise pore type polyurethane film (1), polytetrafluoroethylene film (2), by adhesive layer (3) bonding between described pore type polyurethane film (1), polytetrafluoroethylene film (2), the number of described polytetrafluoroethylene film (2) hole (4) is per square inch 85 ~ 9,500,000,000, and the average diameter of described hole (4) is 0.2um ~ 10um;
Described pore type polyurethane film (1) is also toasted at the baking oven of 80 ~ 150 degree of thermogrades in silicon oil release paper successively by prefabricated polyurethane slurry blade coating, obtains when reaching 150 degree and being cooled to normal temperature after insulation again;
Described prefabricated polyurethane slurry is composed of the following components:
Polyurethane resin 100 parts,
Dimethyl formamide 20 ~ 25 parts,
Toluene 32 ~ 35 parts,
Butanone 12 ~ 15 parts,
Microspheres 8 ~ 9 parts,
Isosorbide-5-Nitrae one butanediol 1.5 ~ 2.5 parts,
Polyacrylamide 1.2 ~ 1.8 parts,
Acrylate 0.3 ~ 0.5 part,
Organosiloxane emulsion 0.2 ~ 0.3 part;
Described adhesive layer (3) is composed of the following components:
Polyurethane resin 100 parts,
Dimethyl formamide 12 ~ 15 parts,
Toluene (TOL) 4 ~ 6 parts,
7 ~ 9 parts, ethyl acetate,
Microspheres 4 ~ 6 parts,
Crane span structure agent 0.2 ~ 0.4 part,
Promoter 0.15 ~ 0.25 part,
Silane coupler 1.2 ~ 2 parts.
2. the two composite microporous film of component of high resiliency according to claim 1, is characterized in that: the volume of described polytetrafluoroethylene film Hole accounts for 80 ~ 90% of polytetrafluoroethylene film volume.
3. the two composite microporous film of component of high resiliency according to claim 1, it is characterized in that: the mass ratio between described polytetrafluoroethylene film (2) and pore type polyurethane film (1) is 1:6.5 ~ 7, Thickness Ratio is 1:0.3 ~ 0.6.
4. the two composite microporous film of component of high resiliency according to claim 1, is characterized in that: the baking oven baking of described 80 ~ 150 degree of thermogrades specifically comprised with the next stage:
The described first stage: under the condition of 80 DEG C, and carry out under the empty vapour atmosphere of low speeds flow;
Second stage: under the condition of 90 DEG C, and carry out under the empty vapour atmosphere of middling speed flowing;
Phase III: under the condition of 110 DEG C, and carry out under the empty vapour atmosphere of strong speed flowing;
Fourth stage: under the condition of 140 DEG C, and carry out under the empty vapour atmosphere of low speeds flow.
5. the two composite microporous film of component of high resiliency according to claim 1, is characterized in that: described microspheres is akzonobel company microspheres, and it has in flexible shell containing low-boiling point materials such as iso-butane, propane, pentanes.
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CN201610478035.5A CN106113861B (en) 2015-02-25 2015-02-25 Breathable films for sportswear fabric
CN201610481554.7A CN106142695B (en) 2015-02-25 2015-02-25 Waterproof composite film for composite material
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105083748A (en) * 2015-07-16 2015-11-25 海宁市海豚物资有限公司 High temperature sterilization easy-to-tear food packing film
CN105105387A (en) * 2015-09-15 2015-12-02 天守(福建)超纤科技股份有限公司 Moisture absorption ultra-fine fiber leather and manufacturing method thereof
CN111016308A (en) * 2019-11-25 2020-04-17 江苏惟妙纺织科技有限公司 High molecular microporous film composite lace

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107189300A (en) * 2017-07-07 2017-09-22 昆山金有利新材料科技有限公司 A kind of air-permeable elastic film and preparation method
CN111705516A (en) * 2020-06-10 2020-09-25 昆山恒泰复合材料科技有限公司 Waterproof flame-retardant composite fabric for outdoor protective cover and preparation process thereof
CN112724847B (en) * 2020-12-14 2023-03-31 苏州市雄林新材料科技有限公司 High-low temperature composite film and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3223568A (en) * 1961-01-30 1965-12-14 Sterling W Alderfer Production of foamed plastic materials
US3330713A (en) * 1962-01-30 1967-07-11 Dunlop Rubber Co Method of coating textile fabrics
CN102555380A (en) * 2012-01-21 2012-07-11 昆山华阳复合材料科技有限公司 Moisture-permeable waterproof film used for fabric and fabrication process thereof
CN202507633U (en) * 2012-01-04 2012-10-31 昆山华阳复合材料科技有限公司 Dry microporous moisture-permeable composite textile
CN202528513U (en) * 2012-04-03 2012-11-14 昆山华阳复合材料科技有限公司 Air-permeable and moisture-permeable waterproof functional double-component composite fabric

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100340397C (en) * 2003-01-22 2007-10-03 中国人民解放军总后勤部军需装备研究所士兵系统研究中心 Method for preparing laminated textile with waterproof and transmission of humidity made from bi-directiona elastic Teflon
KR20050037057A (en) * 2003-10-17 2005-04-21 강수행 Decoration seet manufacturing process
EP2131406A1 (en) * 2008-06-02 2009-12-09 Nederlandse Organisatie voor toegepast- natuurwetenschappelijk onderzoek TNO A method for manufacturing a thermoelectric generator, a wearable thermoelectric generator and a garment comprising the same
CN201541785U (en) * 2009-10-30 2010-08-11 江苏三川染整有限公司 Multifunctional fabric
NL2005845C2 (en) * 2010-12-09 2012-06-12 Kooiker Bedrijfswagenspuiterij En Carrosserie B V Structural material and method of manufacturing thereof.
CN102825847A (en) * 2011-06-16 2012-12-19 谢培金 Porous membrane hollow-out fabric
CN202664346U (en) * 2012-03-01 2013-01-16 蔡志猛 Outdoor sports wear fabric
CN202635647U (en) * 2012-06-21 2013-01-02 德尔惠股份有限公司 Novel cool and comfortable sport suit
US9988746B2 (en) * 2012-10-01 2018-06-05 The Board Of Trustees Of The University Of Illinois Partially degradable fibers and microvascular materials formed from the fibers
CN103213334A (en) * 2013-04-17 2013-07-24 常州市华健药用包装材料有限公司 Medical bacterium filtering and resisting composite material
CN103932436A (en) * 2014-04-02 2014-07-23 湖州森诺氟材料科技有限公司 Ultrathin leisure fabric with windproof and breathable functions and manufacturing method thereof
CN104249532A (en) * 2014-09-05 2014-12-31 江阴市繁荣色织有限公司 Warm-keeping deodorizing reflective fabric

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3223568A (en) * 1961-01-30 1965-12-14 Sterling W Alderfer Production of foamed plastic materials
US3330713A (en) * 1962-01-30 1967-07-11 Dunlop Rubber Co Method of coating textile fabrics
CN202507633U (en) * 2012-01-04 2012-10-31 昆山华阳复合材料科技有限公司 Dry microporous moisture-permeable composite textile
CN102555380A (en) * 2012-01-21 2012-07-11 昆山华阳复合材料科技有限公司 Moisture-permeable waterproof film used for fabric and fabrication process thereof
CN202528513U (en) * 2012-04-03 2012-11-14 昆山华阳复合材料科技有限公司 Air-permeable and moisture-permeable waterproof functional double-component composite fabric

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105083748A (en) * 2015-07-16 2015-11-25 海宁市海豚物资有限公司 High temperature sterilization easy-to-tear food packing film
CN105105387A (en) * 2015-09-15 2015-12-02 天守(福建)超纤科技股份有限公司 Moisture absorption ultra-fine fiber leather and manufacturing method thereof
CN111016308A (en) * 2019-11-25 2020-04-17 江苏惟妙纺织科技有限公司 High molecular microporous film composite lace

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