CN104705336A - Suspended seed coating with pest killing and sterilizing effects - Google Patents

Suspended seed coating with pest killing and sterilizing effects Download PDF

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Publication number
CN104705336A
CN104705336A CN201510141483.1A CN201510141483A CN104705336A CN 104705336 A CN104705336 A CN 104705336A CN 201510141483 A CN201510141483 A CN 201510141483A CN 104705336 A CN104705336 A CN 104705336A
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seed
peanut
ethiprole
soil
pesticide
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CN201510141483.1A
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CN104705336B (en
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张俊刚
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Shanghai Lvze Bio-Technology Co Ltd
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Shanghai Lvze Bio-Technology Co Ltd
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Abstract

The invention discloses a suspended seed coating with pest killing and sterilizing effects. The suspended seed coating contains difenoconazole, fludioxonil, fipronil, thiamethoxam, a pesticide adjuvant and water. The suspended seed coating with pest killing and sterilizing effects disclosed by the invention can be used for sowing after coating the seeds, so that protective barriers are formed at the peripheries of the seeds, the invasion of plant diseases and insect pests in the soil is effectively avoided, and the healthy growth of the crop seeds can be protected.

Description

A kind of suspension seed-coating agent with pesticide-germicide effect
Technical field
The present invention relates to technical field of pesticide combination, relate in particular to a kind of suspension seed-coating agent with pesticide-germicide effect.
Technical background
Difenoconazole is triazole bactericidal agent, and having protection, treatment and systemic activity, is sterol piptonychia oxidation retarder; the biosynthesis of T suppression cell wall sterol; stop the growth of fungi, broad-spectrum, can improve the yield and quality of crop as leaf surface treatment and seed treatment.
Coughing up bacterium is clearly pyrazoles bactericide, and the mechanism of action is unique, by the transfer suppressing glucose phosphorylated relevant, and the mycelial growth of Antifungi, finally cause germ dead, with existing bactericide without cross resistance.Belong to non-internal-absorting wide-spectrum bactericide.Be mainly used in control kind pass and soil-borne disease bacterium as Alternaria, Ascochyta, aspergillus, Fusariumsp consider to be worth doing, Rhizoctonia and Penicillium etc.
Ethiprole is mainly used as control soil insect, safe and efficient, with existing insecticide without cross resistance.To tag and stomach poison function, have the insect of resistance all effective to organic phosphor, cyclopentadiene, carbamates, pyrethrins insecticide, and the lasting period is long.
Diacloden is the chemical constitution and the biochemical activity of uniqueness that upgrade, alternatively suppresses insect nerve system nicotinic acetylcholine esterase acceptor, and then blocks the normal conduction of insect CNS, causes insect to occur paralysis and dead.Not only there is good stomach toxicity, contact toxicity, strong Uptake and translocation and permeability, and there is the feature such as higher activity, better safety, wider insecticidal spectrum and speed of action is fast, lasting period length, be replace that those are high to mammalian toxicity, have the best kind of the organic phosphor of residual and environmental problem, carbamates, pyrethroid pesticide.
In current farmland, soil insect is more, and soil-borne disease bacterium and disease seriously, jeopardize seed growth safety, cause the disconnected ridge that is short of seedling, crop failure.Prior art is by composite for two kinds, three kinds insecticidal bactericides, and pesticide-germicide spectrum relative narrower, to extermination of disease and insect pest limited efficiency or bad.In addition the insecticide that Long-Time Service is single or bactericide, insect or germ are easy to develop immunity to drugs, and cause consumption to increase greatly, residual, the ill effect such as drug effect variation, and effect field is more single.
Technology contents
The invention provides a kind of suspension seed-coating agent with pesticide-germicide effect, it contains Difenoconazole, fludioxonil, ethiprole and Diacloden four kinds of active ingredients, and insecticides adjuvant and water;
Wherein the mass percentage content of Difenoconazole, fludioxonil, ethiprole and Diacloden is respectively 0.5-1.5%, 0.5-1.5%, 0.3-1.0% and 6.0-8.0%;
Specifically, the suspension seed-coating agent with pesticide-germicide effect provided by the invention, is made up of following component:
Difenoconazole: 0.5-1.5%
Fludioxonil: 0.5-1.5%
Ethiprole: 0.3-1.0%
Diacloden: 6.0-8.0%
Wetting dispersing agent: 4.0-6.0%
Urea: 2.0-6.0%
Xanthan gum solution: 0.1-0.5%
Aluminium-magnesium silicate: 0.2-0.6%
White carbon: 0.5-2.0%
Permanent bordeaux slurry: 2.0-5.0%
Poly-vinyl alcohol solution: 4.0-8.0%
Silicone oil: 0.2-0.6%
Kathon CG: 0.1-0.5%
Water: surplus
Above-mentioned percentage is all weight percentage.
Wherein wetting dispersing agent is the mixture of polycarboxylate and polyaryl phenolic ether phosphate, and the two mass ratio is 3:1 (Jiangsu Qing Yu chemical company); Urea is as antifreezing agent; 20% xanthan gum solution, aluminium-magnesium silicate and white carbon are used as thickener; 10% poly-vinyl alcohol solution is used as film forming agent; Silicone oil is used as defoamer; Kathon CG is used as bactericide; Permanent bordeaux slurry is used as warning colouration;
Seed coat agent of the present invention can be made into suspension formulation.
Present invention also offers the preparation method of this seed coat agent:
1. the sand milling of solid, sticky material
The water of measured amounts, adds the Difenoconazole, ethiprole, fludioxonil, Diacloden, wetting dispersing agent, aluminium-magnesium silicate, the white carbon that measured respectively, after high-speed shearing machine is sheared, is ground to less than 5 microns, mixes with sand mill;
2. the shearing of liquid material
The water of measured amounts, adds the materials such as xanthan gum solution, poly-vinyl alcohol solution, pigment permanent bordeaux slurry, antifreezing agent urea, defoamer silicone oil, bactericide Kathon CG respectively, shears, mix with high-speed shearing machine;
2. by step 1. in preparation material slowly add step 2. in preparation material in, with high-speed shearing machine shear, mix; .
Seed coat agent of the present invention be by the different mechanism of action and without two kinds of insecticides of interactivity and two kinds of bactericide rational mixture by a certain percentage, in composition, four kinds of active ingredient action compensatings, expand controlling object, improve control efficiency.Can desinsection again can sterilization, and consumption is few, preventive effect is high, residual less, the lasting period is long, is conducive to protection of the environment.Sow after seed pelleting, can form protective barrier around seed, effectively avoid the invasion and attack of damage by disease and insect in soil, reduce seeding quantity, field seedling is even, Miao Quan, Miao Zhuan, for crop high yield is taken a firm foundation.
A kind of seed coat agent composition with pesticide-germicide effect of the present invention is more wider than existing chemical control, can desinsection again can diseases prevention, expand prevention and treatment range, decrease Pesticide use number of times, delay the generation of pest resistance to insecticide, reduce Pesticide use amount, reduce use cost, more environmental.The existing good economic benefit of this pesticide-germicide seed coat agent composition and environmental benefit, have larger application value.
Embodiment
The preparation of xanthan gum solution: dissolved by xanthans with hot water, is made into 20% aqueous solution, for preventing xanthans in put procedure from going bad, can add the bactericide Kathon CG of 0.5%.
The preparation of poly-vinyl alcohol solution: polyvinyl alcohol is put into 50-60 DEG C of hot water and soak 24h, stirring and dissolving, be made into 10% solution.For preventing polyvinyl alcohol in put procedure from going bad, the bactericide Kathon CG of 0.5% can be added.
Embodiment 1:
The formulation that a kind of seed coat agent composition with pesticide-germicide effect can be prepared is suspension seed-coating agent.In preparation, the ratio of quality and the number of copies of each component is:
Difenoconazole: 0.5%
Fludioxonil: 0.5%
Ethiprole: 0.3%
Diacloden: 6.0%
Wetting dispersing agent: 4.0%
Urea: 2.0%
Xanthan gum solution: 15%
Aluminium-magnesium silicate: 0.2%
White carbon: 0.5%
Permanent bordeaux slurry: 2.0%
Poly-vinyl alcohol solution: 4.0%
Silicone oil: 0.2%
Kathon CG: 0.1%
Water: supply 100%
The production stage of this suspension seed-coating agent is:
1. the sand milling of solid, sticky material
Take 40kg water, add difenoconazole technical material 0.5kg, ethiprole former medicine 0.5kg, fludioxonil former medicine 0.3kg, the former medicine 6.0kg of Diacloden, wetting dispersing agent 4kg, aluminium-magnesium silicate 0.2kg, white carbon 0.5kg respectively, after shearing 30 minutes with high-speed shearing machine, granularity less than 5 microns is ground to, about 1-2 hour with sand mill.Mix.
2. the shearing of liquid material
Take 24.7kg water, add xanthan gum solution 15kg, poly-vinyl alcohol solution 4kg, permanent bordeaux slurry 2kg, urea 2kg, silicone oil 0.2kg, Kathon CG 0.1kg respectively, shear with high-speed shearing machine, mix.
3. the material obtained in step 1 is slowly added in the material obtained in step 2, shear with high-speed shearing machine, mix.
4. examine the quality of the production, packaging.I.e. obtained a kind of seed coat agent composition with pesticide-germicide effect of the present invention.
Embodiment 2:
The formulation that a kind of seed coat agent composition with pesticide-germicide effect can be prepared is suspension seed-coating agent.In preparation, the ratio of quality and the number of copies of each component is:
Difenoconazole: 0.7%
Fludioxonil: 0.7%
Ethiprole: 0.5%
Diacloden: 7.6%
Wetting dispersing agent: 4.0%
Urea: 4%
Xanthan gum solution: 15%
Aluminium-magnesium silicate: 0.2%
White carbon: 1%
Permanent bordeaux slurry: 5%
Poly-vinyl alcohol solution: 5%
Silicone oil: 0.5%
Kathon CG: 0.3%
Aqueous solvent: supply 100%
The production stage of this suspension seed-coating agent is:
1. the sand milling of solid, sticky material
Take 40kg water, add difenoconazole technical material 0.7kg, ethiprole former medicine 0.7kg, fludioxonil former medicine 0.5kg, the former medicine 7.6kg of Diacloden, wetting dispersing agent 4kg, aluminium-magnesium silicate 0.2kg, white carbon 1.0kg respectively, after shearing 30 minutes with high-speed shearing machine, granularity less than 5 microns is ground to, about 1-2 hour with sand mill.Mix.
2. the shearing of liquid material
Measure 15.5kg water, add xanthan gum solution 15kg, poly-vinyl alcohol solution 5kg, permanent bordeaux slurry 5kg, urea 4kg, silicone oil 0.5kg, Kathon CG 0.3kg respectively, shear with high-speed shearing machine, mix.
3. the material obtained in step 1 is slowly added in the material obtained in step 2, shear with high-speed shearing machine, mix.
4. examine the quality of the production, packaging.I.e. obtained a kind of seed coat agent composition with pesticide-germicide effect of the present invention.
Embodiment 3:
The formulation that a kind of seed coat agent composition with pesticide-germicide effect can be prepared is suspension seed-coating agent.In preparation, the ratio of quality and the number of copies of each component is:
Difenoconazole: 1.5%
Fludioxonil: 1.5%
Ethiprole: 1.0%
Diacloden: 8.0%
Wetting dispersing agent: 6.0%
Urea: 3.0%
Xanthan gum solution: 15%
Aluminium-magnesium silicate: 0.6%
White carbon: 2.0%
Permanent bordeaux slurry: 3.0%
Poly-vinyl alcohol solution: 4.0%
Silicone oil: 0.6%
Kathon CG: 0.5%
Water: supply 100%
The production stage of this suspension seed-coating agent is:
1. the sand milling of solid, sticky material
Take 40kg water, add difenoconazole technical material 1.5kg, fludioxonil former medicine 1.5kg, ethiprole former medicine 1.0kg, the former medicine 8.0kg of Diacloden, wetting dispersing agent 6kg, aluminium-magnesium silicate 0.6kg, white carbon 2.0kg respectively, after shearing 30 minutes with high-speed shearing machine, granularity less than 5 microns is ground to, about 1-2 hour with sand mill.Mix.
2. the shearing of liquid material
Measure 13.3kg water, add the material such as the good xanthan gum solution 15kg of configured in advance, poly-vinyl alcohol solution 4.0kg, permanent bordeaux slurry 3.0kg, urea 3.0kg, silicone oil 0.6kg, Kathon CG 0.5kg respectively, shear with high-speed shearing machine, mix.
3. the material obtained in step 1 is slowly added in the material obtained in step 2, shear with high-speed shearing machine, mix.
4. examine the quality of the production, packaging.I.e. obtained a kind of seed coat agent composition with pesticide-germicide effect of the present invention.
Embodiment 4:
A kind of suspension seed-coating agent (being called for short BLFS) with pesticide-germicide effect of embodiment 2 prevents and treats soil insect and effect of increasing production is as follows:
1, test objective
BLFS is to the control of peanut soil pest and effect of increasing production in checking, provides foundation for applying.
2, experimental condition
Test site is theatre village of Shi Pogu township of Yanjin County of Henan Province Zhang Zhi Peanut Fields far away, and peanut varieties is " Momordica grosvenori ".Experimental field first crop long-term cropping is wheat.Peanut sowing on May 21.Experimental field apply fertilizer, pour water, the management condition such as insect protected is consistent.
3, experimental scheme and arrangement
3.1 test medicine
Test and contrast medicament four:
1. " BLFS " (embodiment 2);
2. 60% Imidacloprid suspension seed-coating agent, Shanxi Biaozheng Crop Science Co., Ltd;
3. 30% ethiprole Diacloden suspension seed-coating agent, Jiangsu Futian Agrochemical Co., Ltd.;
4. 18% ethiprole chlopyrifos suspension seed-coating agent, Beijing YanHuaYongLe pesticide Co., Ltd produces;
3.2 test process
5 process are established in test altogether:
1. medicament BLFS (embodiment 2) and peanut seed ratio 1:200 dressing (weight ratio);
2. 60% Imidacloprid suspension seed-coating agent and peanut seed ratio 1:330 dressing (weight ratio);
3. 30% ethiprole Diacloden suspension seed-coating agent and peanut seed ratio 1:200 dressing (weight ratio);
4. 18% ethiprole chlorpyrifos microcapsule suspension agent and peanut seed ratio 1:200 dressing (weight ratio);
5. blank (CK).
3.3 plot area and repetition
Experimental plot area 200 ㎡, does not establish repetition.
3.4 spraying times and method
100 ml water dilutions will be added for reagent medicament afternoon May 20, and add peanut seed according to each process ratio, stir, carry out seed dressing and coating, dry.Sowing on the 21st.
4, field investigation
4.1 soil and meteorological data
Experimental field soil types is loam, and soil fertility is medium, pH value 7.0, soil organic matter content 1.2%, and it is good that water waters condition, and soil moisture is suitable for peanut growth.
Sowing weather fine day on the same day, temperature is 19-35 DEG C, gentle breeze weather.The strong weather effects of evil such as vegetative period is calm, disaster caused by hail is harmful.
4.2 effect research
4.2.1 investigation method, time and number of times:
Each process random searching 3 points, often some investigation 0.5 ㎡.In investigation on August 25 once, during results, September 29 was investigated once.Investigation content comprises: peanut growing way, leaf look situation of change and soil insect situation of the harm (wormed fruit number), grub borer population amount alive in soil; Measure peanut yield.
4.2.2 cultivation management situation
Experimental field in sowing on May 21, after planting water, after wheat harvest, impose composite fertilizer once (N 15-P 2o 515-K 2o 15) 35 kilograms, the harvest date is September 29.
4.2.3 on the impact of peanut growth
Investigation finds, peanut seed, after BLFS process, is emerged, and leaf look dark green is, shinny, growing way is strengthened.
4.2.4 to the other influences of peanut
Produce without poisoning after observing peanut application BLFS seed treatment.
4.2.5 in peanut yield and soil grub a situation arises
Before results, sampling was carried out to each process community September 29 and survey product, take the mean as final result, after natural air drying, weigh peanut 1 meter of duplicate rows pod weight, calculate per mu yield; The borer population amount alive of grub in soil is investigated, calculates Revision insect recluced rate.
5, interpretation of result
Process 1: i.e. medicament BLFS (embodiment 2) and peanut seed ratio 1:200 dressing, peanut pod wormed fruit rate is 2%, grub quantity of living in 1 square metre of soil is 0.75, and blank field peanut pod wormed fruit rate is 8.1%, grub quantity of living in 1 square metre of soil is 9, wormed fruit rate is than contrasting reduction by 6.1 percentage points, Revision insect recluced rate 91.7%.BLFS treatment region per unit area yield 358.17 kilograms, than check plot per unit area yield 312 kilograms volume increase 46.17 kilograms, rate of growth 14.8%.
Process 2: i.e. 60% Imidacloprid suspension seed-coating agent and peanut seed ratio 1:200 dressing; Peanut pod wormed fruit rate is 2.9%, grub quantity of living in 1 square metre of soil is 0.9, and blank field peanut pod wormed fruit rate is that in 8.1%, 1 square metre of soil, grub quantity alive is 9, wormed fruit rate is than contrasting reduction by 5.2 percentage points, Revision insect recluced rate 90%.BLFS treatment region per unit area yield 351.0 kilograms, than check plot per unit area yield 312 kilograms volume increase 39.0 kilograms, rate of growth 12.5%.
Process 3: i.e. 30 ethiprole % Diacloden suspension seed-coating agents and peanut seed ratio 1:200 dressing; Peanut pod wormed fruit rate is 2.5%, grub quantity of living in 1 square metre of soil is 0.83, and blank field peanut pod wormed fruit rate is that in 8.1%, 1 square metre of soil, grub quantity alive is 9, wormed fruit rate is than contrasting reduction by 5.6 percentage points, Revision insect recluced rate 90.8%.BLFS treatment region per unit area yield 354.2 kilograms, than check plot per unit area yield 312 kilograms volume increase 42.2 kilograms, rate of growth 13.5%.
Process 4: i.e. 18% ethiprole chlorpyrifos microcapsule suspension agent and peanut seed ratio 1:200 dressing; Peanut pod wormed fruit rate is 2.7%, grub quantity of living in 1 square metre of soil is 0.88, and blank field peanut pod wormed fruit rate is that in 8.1%, 1 square metre of soil, grub quantity alive is 9, wormed fruit rate is than contrasting reduction by 5.4 percentage points, Revision insect recluced rate 90.2%.BLFS treatment region per unit area yield 356.0 kilograms, than check plot per unit area yield 312 kilograms volume increase 44.0 kilograms, rate of growth 14.1%.
As can be seen from pilot survey result: medicament BLFS (embodiment 2) and peanut seed ratio 1:200 dressing, to soil insect especially grub successful, have certain protection effect to peanut rot disease preventive treatment.Although other chemicals treatment district wormed fruit rate, Revision insect recluced rate and peanut yield also have larger difference than check plot, general effect is not as good as BLFS suspension seed-coating agent.
6, brief summary and discussion
Above-described a kind of suspension seed-coating agent with pesticide-germicide effect, Main Ingredients and Appearance is Difenoconazole, fludioxonil, ethiprole and Diacloden, for seed pelleting before peanut seeding, there is good anti-soil insect, strong sprout and prophylaxis effect, there is stronger advantage compared with similar products, especially to soil insect preventive effect and effect of increasing production all more obvious.

Claims (2)

1. there is a suspension seed-coating agent for pesticide-germicide effect, it is characterized in that it contains Difenoconazole, fludioxonil, ethiprole and Diacloden, and insecticides adjuvant and water;
Wherein the mass percentage content of Difenoconazole, fludioxonil, ethiprole and Diacloden is respectively 0.5-1.5%, 0.5-1.5%, 0.3-1.0% and 6.0-8.0%.
2. the suspension seed-coating agent with pesticide-germicide effect according to claim 1, is characterized in that it is made up of following component:
Difenoconazole: 0.5-1.5%
Fludioxonil: 0.5-1.5%
Ethiprole: 0.3-1.0%
Diacloden: 6.0-8.0%
Wetting dispersing agent: 4.0-6.0%
Urea: 2.0-6.0%
Xanthan gum solution: 0.1-0.5%
Aluminium-magnesium silicate: 0.2-0.6%
White carbon: 0.5-2.0%
Permanent bordeaux slurry: 2.0-5.0%
Poly-vinyl alcohol solution: 4.0-8.0%
Silicone oil: 0.2-0.6%
Kathon CG: 0.1-0.5%
Water: surplus.
CN201510141483.1A 2015-03-27 2015-03-27 A kind of suspension seed-coating agent with pesticide-germicide effect Active CN104705336B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104926519A (en) * 2015-06-23 2015-09-23 汤海涛 Sesame seed coating agent
CN105272604A (en) * 2015-10-26 2016-01-27 唐睿 Pest-killing and disease-resistant suspended seed coating agent
CN111955463A (en) * 2020-07-01 2020-11-20 浙江天丰生物科学有限公司 Efficient and safe suspended seed coating for wheat
CN112042665A (en) * 2020-08-23 2020-12-08 南通江山农药化工股份有限公司 Seed treatment agent containing imidaclothiz composition and application thereof
CN113068708A (en) * 2021-02-23 2021-07-06 安徽省六安市种子公司安丰种衣剂厂 Seed treatment suspending agent and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN1326319A (en) * 1998-11-16 2001-12-12 辛根塔参与股份公司 Pesticidal composition for seed treatment
WO2007005470A2 (en) * 2005-06-29 2007-01-11 Syngenta Participations Ag Liquid compositions for treating plant propagation materials
CN102326578A (en) * 2011-10-11 2012-01-25 联保作物科技有限公司 Pesticide composition and preparation thereof
CN102334489A (en) * 2011-10-31 2012-02-01 联保作物科技有限公司 Insect-killing and disease-preventing suspension seed coating formulation
CN102599183A (en) * 2012-02-23 2012-07-25 吴元林 Seed treatment compound containing thiamethoxam, and application of seed treatment compound

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1326319A (en) * 1998-11-16 2001-12-12 辛根塔参与股份公司 Pesticidal composition for seed treatment
WO2007005470A2 (en) * 2005-06-29 2007-01-11 Syngenta Participations Ag Liquid compositions for treating plant propagation materials
CN102326578A (en) * 2011-10-11 2012-01-25 联保作物科技有限公司 Pesticide composition and preparation thereof
CN102334489A (en) * 2011-10-31 2012-02-01 联保作物科技有限公司 Insect-killing and disease-preventing suspension seed coating formulation
CN102599183A (en) * 2012-02-23 2012-07-25 吴元林 Seed treatment compound containing thiamethoxam, and application of seed treatment compound

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104926519A (en) * 2015-06-23 2015-09-23 汤海涛 Sesame seed coating agent
CN105272604A (en) * 2015-10-26 2016-01-27 唐睿 Pest-killing and disease-resistant suspended seed coating agent
CN111955463A (en) * 2020-07-01 2020-11-20 浙江天丰生物科学有限公司 Efficient and safe suspended seed coating for wheat
CN112042665A (en) * 2020-08-23 2020-12-08 南通江山农药化工股份有限公司 Seed treatment agent containing imidaclothiz composition and application thereof
CN113068708A (en) * 2021-02-23 2021-07-06 安徽省六安市种子公司安丰种衣剂厂 Seed treatment suspending agent and preparation method thereof

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