CN104692708A - High-strength synthetic quartz stone plate and manufacturing method thereof - Google Patents
High-strength synthetic quartz stone plate and manufacturing method thereof Download PDFInfo
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- CN104692708A CN104692708A CN201510078321.8A CN201510078321A CN104692708A CN 104692708 A CN104692708 A CN 104692708A CN 201510078321 A CN201510078321 A CN 201510078321A CN 104692708 A CN104692708 A CN 104692708A
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Abstract
The invention discloses a high-strength synthetic quartz stone plate. The high-strength synthetic quartz stone plate is prepared from the following raw materials in percentage by weight (wt%): 32-37% of quartz sand, 28-30% quartz stone powder, 25-36% of the glass sand, 6.5-8% of anticorrosive resin, 0.1-0.18% of a curing agent, 0.04-0.1% of an accelerating agent, 0.38-0.52% of a coupling agent and 0.38-0.52% of micaceous iron oxide, wherein the micaceous iron oxide is modified by coating the surface of the micaceous iron oxide with nano silicon dioxide by adopting a sol-gel method. The quartz stone plate is synthesized artificially from high-purity quartz stone crystals and auxiliaries in vacuum by adopting an isomerization polymerization technology and overcomes the problems that the natural stone is low in density, has cracks and dissolved pores and easily fades. The synthetic quartz stone plate has the hardness of the natural stone, can resist corrosive gas and liquid and can be prepared into different colors according to needs. The synthetic quartz stone plate is friendly to the environment, has high rupture strength and compression strength, is compact and can be colored and patterned differently according to needs of customers.
Description
Technical field
The present invention relates to quartzite slate field, particularly relate to a kind of high-strength anti-corrosion artificial quartz stone plate and preparation method thereof.
Background technology
Current in mordant Working environment, its rot-resistant measure such as ground, metope, irrigation canals and ditches, culvert as chemical plant, smeltery, national defence base installation adopts natural granite, but there is inborn deficiency in grouan, as: crack, interlayer etc., make mordant liquid penetrate into the bottom of grouan, cause the place of grouan or whole laying grouan to corrode.
Summary of the invention
The object of the invention is the geneogenous deficiency solving the stone material existence such as grouan, adopt the mode of artificial synthesis, a kind of making method of high-strength anti-corrosion artificial quartz stone plate is provided, problems such as solving stone material density deficiency, there is crack, solution cavity, fade.
The technical solution used in the present invention is: high-purity quartz stone crystal and auxiliary material are made by isomerization polymerization technology by the mode of artificial synthesis under vacuum, problems such as solving lithotome density deficiency, there is crack, solution cavity, fade.
A kind of high-intensity corrosion artificial quartz stone plate, its material composition wt% is: the quartzy stone sand of 32% ~ 37%, the quartz powder of 28% ~ 30%, 25% ~ 36% glass sand, 6.5% ~ 8% anti-corrosion resin, 0.1% ~ 0.18% solidifying agent, 0.04% ~ 0.1% promotor, the coupling agent of 0.38% ~ 0.52%, the anticorrosion mill base of 0.38% ~ 0.52% and 0.038% ~ 0.052% iron mica powder, described iron mica powder adopts sol-gel method to carry out modification at its Surface coating nanometer grade silica.
A making method for high-intensity corrosion artificial quartz stone plate, comprises the steps:
(1) starting material prepare
A) prepare burden, various starting material are proportionally deployed;
B) stir, deployed anti-corrosion resin, coupling agent, promotor, solidifying agent, anticorrosion mill base, iron mica powder and Rutile type Titanium Dioxide are put into mill base dispersion machine to stir 2 ~ 5 minutes, pure quartz sand, pure silica powder are put into material agitator and stirred 5 ~ 10 minutes, then the material in mill base dispersion machine is added in material agitator and carry out mix and blend 3 ~ 5 minutes;
C) mould base stock is spread, at 200 grams of high-strength kraft paper of ready mold bottom place mat one deck same size;
D) cloth, is layered in template uniformly by the raw material stirred, and what make it try one's best is smooth, and then spreads a kraft paper, then covers one deck rubber;
(2) shaping
A) suppress, the template that cloth is good delivered in press and carry out about 100 ~ 140 seconds vacuumize, and carry out secondary pressurized, the time of secondary pressurized is 20 ~ 30 seconds, then carries out vibrations pressurization 180 ~ 220 seconds;
B) go out mould, the sheet material suppressed is placed in punching block or glass template;
C) thermofixation, is heating and curing the quartzite slate on punching block or glass template, and set time is 40 ~ 120 minutes, and solidification value is 60 ° ~ 110 °;
D) demoulding, by the quartzite slate after solidification by the stripper demoulding;
(3) fixed thick, product thickness is 8 ~ 35mm;
A) first surface is fixed thick;
B) turnover panel;
C) determine thick for second;
(4) on-line automatic cutting is carried out in the both sides of the quartzite slate in production and two ends by cutting on line;
(5) polishing, sends the quartzite slate after cutting on line into polishing in polishing machine;
(6) air-dry, adopt hot blast air-dry;
(7) glazing waxing, pad pasting;
(8) cut.
As a further improvement on the present invention, be that described quartzy stone sand comprises (wt%): 4% ~ 5.5% 4 ~ 6 orders quartz stone sands, 12.5% ~ 15% 10 ~ 20 orders quartz stone sands and 14% ~ 16% 40 ~ 70 orders quartz stone sands.
As a further improvement on the present invention, described glass sand comprises (wt%): 4 ~ 8 order glass sands of 5% ~ 7%, 8 ~ 16 order glass sands of 11% ~ 15% and 9% ~ 14% 16 ~ 30 order glass sands.
As a further improvement on the present invention, described anti-corrosion resin is epoxy resin; Described solidifying agent is at least one in BASF-HDI type solidifying agent or BAYER solidifying agent N75; Described promotor is TECH adhesion promoter, TECH silane coupling agent, acid pickling promotor or do in wink speed-raising promotor at least one.
As a further improvement on the present invention, described silicon-dioxide is Rutile type Titanium Dioxide.
Further improve as of the present invention, the thickness of described high-intensity corrosion artificial quartz stone plate is 8 ~ 35mm.
As a further improvement on the present invention, described starting material prepare in the paving mould base stock step of link, and inside four limits of mould, put silica gel strip, the height of silica gel strip exceeds 3 ~ 7mm than mould.
As a further improvement on the present invention, in the thermal cure step of described shaping link, adopt ambient cure.
The beneficial effect that the present invention adopts is: the present invention adopts the mode of artificial synthesis high-purity quartz stone crystal and auxiliary material to be made by isomerization polymerization technology under vacuum, problems such as solving lithotome density deficiency, there is crack, solution cavity, fade, artificial quartz stone plate is made not only to have the hardness of lithotome, and be not afraid of the corrosion of corrosive liquids and gases, in addition, shades of colour can also be modulated into as required.The present invention is environmental protection not only, and improves anti-folding, the ultimate compression strength of stone material, simultaneously stone material do closely knit, and according to the needs of client, various pattern, pattern can be made.
Embodiment
The composition of high-intensity corrosion artificial quartz stone plate of the present invention mainly comprises: pure quartzy stone sand, pure quartz powder, glass sand, glass powder, unsaturated polyester, iron mica, anti-acid color and acid-proof coupling agent, promotor, solidifying agent.
Unsaturated polyester and quartz sand inherently impregnating material, key is after pigment and coupling agent, promotor etc. add, although dispersiveness is all relatively good, can wrap up with quartz sand etc., but guarantee that ready-made quartzite slate has high antiseptic property, here must add natural iron mica, so just more effectively play the erosion of the anticorrosion liquid of isolation and shield.Before converted products, need to carry out acid-proof, alkali, salt detection to all materials, comprise iron mica, pigment and all additives and all must detect.In addition, before doing artificial quartz stone plate, the grating of the proportioning test, particularly quartz sand and silica powder of often kind of material and glass sand, glass powder be made, guarantee that the anticorrosion panel density of working it out reaches and carry out.
The technological process of production: carry out siccative mix and blend, carry out wet feed mix and blend, then, wet feed is joined inside siccative and continue to stir, to be confirmed stir after, being taken out by material is placed on inside mould, inside press mould being pushed conputer controlled, suppresses--vacuumizing (-0.1Mpa)--vibration, according to size or the depth information of sheet material area, setting working parameter.After the anticorrosion quartzite slate suppressed pulls out from mould, need the intermediate temperature setting time of 24 hours, and then put into thicknessing machine and carry out surely thick, polishing, cutting.Solidification can be put into thermofixation stove (electrically heated or burning the heating such as biofuel, Sweet natural gas), or is cured inside the solidification case putting into hot oiling, equally also can adopt the method for ambient cure.
(1), starting material prepare
1, prepare burden: according to the assortment of required production, ready various raw material (pure quartz sand, pure silica powder, anti-corrosion resin, coupling agent, promotor, solidifying agent, special ultra-fine iron mica serial pigment, anticorrosion mill base, rutile titanium white powder etc.) is proportionally allocated.
2, stir: first proportionally deployed anti-corrosion resin, coupling agent, promotor, solidifying agent, anticorrosion mill base are put into special agitation vat and stirred.Meanwhile, the siccatives such as the pure quartz sand weighed up, pure silica powder, rutile titanium white powder are poured into be stirred anti-corrosion resin, coupling agent, promotor, solidifying agent, inside anticorrosion mill base, stir, churning time temperature and humidity environmentally and determining.
3, spread mould base stock: at 200 grams of high-strength kraft paper of ready mold bottom place mat one deck same size, effect easily departs between quartz sand sheet material and mould after preventing raw material solidification.Also will put silica gel strip inside four limits of mould, the height of silica gel strip exceeds 5mm than mould.
4, cloth: adopt automatic distributing or artificial cloth, be layered on uniformly in template by the raw material stirred, what make it try one's best is smooth, and then spreads a kraft paper above, cover one deck rubber again, effect avoids the pressure head of press that the sheet material of densification reality is sucked up.The materials of one block of large plate of quartzite approximately need the raw material of 250Kg.
(2), shaping
1, suppress: template to be delivered in press through automatic transmission belt by template good for cloth and vacuumizes, and carry out secondary pressurized.Then carry out vibrations pressurization, to vacuumize and time of pressurizeing is difference for different sheet material specifications, thickness and different.
2, go out mould: after completing compression moulding, the sheet material suppressed is moved in punching block or glass template by belt conveyor.
3, thermofixation: by the quartzite slate on punching block or glass template, to be sent in thermofixation stove (electrically heated or heating such as burning biofuel, Sweet natural gas etc.) by belt conveyor or to be transported to inside the solidification case of hot oiling and be cured.Set time, generally at 40 ~ 120 minutes etc. this will depending on the character of thickness, solidifying agent after the size of sheet material and capacity.The temperature of usual intermediate temperature setting is at 60 degree ~ about 110 degree.Also ambient cure can be adopted.
4, the demoulding: after completing the set time of setting, be sent to the stripper demoulding through automatic production line, is discharged to dull and stereotyped stack by sheet material from production line with automatic board descending machine, is transported to semifinished product warehouse deposits with fork truck.
(3), fixed thick
The set time of quartzite slate can solidify approximately after 24 hours completely.Then be transported to by thicknessing machine with fork truck, roll on platform with automatic plate loader by sheet material hoisting to the electronic of surely thick production line, large plate then needs to be maneuvered into electronic rolling on platform with driving.
1, first surface is fixed thick: according to the different size of sheet material, set different fixed thick sizes, then by automatic transport belt sheet material is transported to thicknessing machine carries out surely thick.
2, turnover panel: the fixed thick sheet material completed of first surface, to be transported to the turnover panel carrying out 180 degree inside 180 degree of Auto-reversal Machine's by sheet material through automatic transport belt.
3, after completing 180 degree of turnover panels, it is fixed thick that travelling belt automatic conveying obtains carrying out in second thicknessing machine the sheet material of second.
(4), cutting on line both sides and two ends
Complete both sides in the operational process of automatic delivering belt while after cutting, sheet material is transported to online two ends surface trimming by conveying belt.
(5), polishing
The transfer roller of automatic conveying transports sheet material at continuous print and enters in polishing machine, needs according to client the smooth finish setting polishing, adopts the polishing machine of 16 ~ 20, disposablely completes polishing work.The large plate of polishing a slice approximately needs about 15 minutes.
(6), sheet material rolls off the production line
Complete the sheet material of polishing, through automatic transport belt, sheet material is transported on lower trigger, by automatic board descending machine sheet material unloaded or adopt 90 degree of plate turnovers to be unloaded by sheet material.
(7), classification is checked and accepted
Through the sheet material that polishing completes, after the transport of automation line travelling belt, automatically sheet material is transported to and manually graduately rolls on platform, carry out classification by artificial visually examine.The grade of current product is divided into: A step (excellent plate), B step (existing defects, as: surface with impurity, pore, pinprick, aberration etc., need through cutting or repair after just can normally use), C step (non-serviceable, the plate scrapped).
(8), air-dry
Adopt hot blast drying.
(9), glazing waxing, pad pasting
Civilian quartzite slate, A step all needs to carry out glazing and waxing usually, then sticks plate surface protective film, plays the protective effect in sheet material plate face.Industrial sheet material can suitably reduce by polishing degree as requested, is the highlyest polished to 800 orders, and does not need waxing.
(10), cut
According to the needs of user, infrared rays slab cutting machine can be adopted to carry out the automatic clean cut of dimension board to sheet material.
(11), packaging
1, project plate adopts wooden block to pack usually, and each packaging is generally no more than 3 tons;
2, adopt A font brandreth packaging, be generally large plate that 15mm is thick by putting 60, general dress of all temporarily not packing when stock.
(12), warehouse-in: after each road production process of quartzite slate completes, handle voucher after transferring to warehouse keeper to check range of product, specification, lot number, quantity by polishing departement and join and input company computer system.
Below in conjunction with embodiment, the present invention is described further.
Embodiment one, a kind of high-intensity corrosion artificial quartz stone plate, its material composition wt% is: 4% 4 ~ 6 orders quartz stone sands, 12.5% 10 ~ 20 orders quartz stone sands and 14% 40 ~ 70 orders quartz stone sands; 4 ~ 8 order glass sands of 5%, 8 ~ 16 order glass sands of 11% and 9% 16 ~ 30 order glass sands; The quartz powder of 28%, the epoxy resin of 6.5%, 0.1% BASF-HDI type solidifying agent, 0.04% TECH adhesion promoter, the silane coupling agent of 0.38%, the anticorrosion mill base of 0.38% and 0.038% iron mica powder.
A making method for high-intensity corrosion artificial quartz stone plate, comprises the steps:
(1) starting material prepare
A) prepare burden, various starting material are proportionally deployed;
B) stir, deployed anti-corrosion resin, coupling agent, promotor, solidifying agent, anticorrosion mill base, iron mica powder and Rutile type Titanium Dioxide are put into mill base dispersion machine to stir 2 minutes, pure quartz sand, pure silica powder are put into material agitator and stirred 5 minutes, then the material in mill base dispersion machine is added in material agitator and carry out mix and blend 3 minutes;
C) mould base stock is spread, at 200 grams of high-strength kraft paper of ready mold bottom place mat one deck same size; Inside four limits of mould, put silica gel strip, the height of silica gel strip exceeds 3mm than mould;
D) cloth, is layered in template uniformly by the raw material stirred, and what make it try one's best is smooth, and then spreads a kraft paper, then covers one deck rubber;
(2) shaping
A) suppress, the template that cloth is good delivered in press and carry out about 100 seconds vacuumize, and carry out secondary pressurized, the time of secondary pressurized is 20 seconds, then carries out vibrations pressurization 180 seconds;
B) go out mould, the sheet material suppressed is placed in punching block or glass template;
C) thermofixation, is heating and curing the quartzite slate on punching block or glass template, and set time is 40 minutes, and solidification value is 60 °;
D) demoulding, by the quartzite slate after solidification by the stripper demoulding;
(3) fixed thick, product thickness is 8mm;
A) first surface is fixed thick; B) turnover panel; C) determine thick for second;
(4) on-line automatic cutting is carried out in the both sides of the quartzite slate in production and two ends by cutting on line;
(5) polishing, sends the quartzite slate after cutting on line into polishing in polishing machine;
(6) air-dry, adopt hot blast air-dry;
(7) glazing waxing, pad pasting;
(8) cut.
Embodiment two, a kind of high-intensity corrosion artificial quartz stone plate, its material composition wt% is: 5% 4 ~ 6 orders quartz stone sands, 15% 10 ~ 20 orders quartz stone sands and 16% 40 ~ 70 orders quartz stone sands; 4 ~ 8 order glass sands of 7%, 8 ~ 16 order glass sands of 15% and 14% 16 ~ 30 order glass sands; The quartz powder of 30%, the epoxy resin of 8%, 08.1% BAYER solidifying agent N75,0.1% acid pickling promotor, 0.52% TECH silane coupling agent, the anticorrosion mill base of 0.52%, the Rutile type Titanium Dioxide of 0.52% and 0.052% iron mica powder.
A making method for high-intensity corrosion artificial quartz stone plate, comprises the steps:
(1) starting material prepare
A) prepare burden, various starting material are proportionally deployed;
B) stir, deployed anti-corrosion resin, coupling agent, promotor, solidifying agent, anticorrosion mill base, iron mica powder and Rutile type Titanium Dioxide are put into mill base dispersion machine to stir 5 minutes, pure quartz sand, pure silica powder are put into material agitator and stirred 10 minutes, then the material in mill base dispersion machine is added in material agitator and carry out mix and blend 5 minutes;
C) mould base stock is spread, at 200 grams of high-strength kraft paper of ready mold bottom place mat one deck same size; Inside four limits of mould, put silica gel strip, the height of silica gel strip exceeds 7mm than mould;
D) cloth, is layered in template uniformly by the raw material stirred, and what make it try one's best is smooth, and then spreads a kraft paper, then covers one deck rubber;
(2) shaping
A) suppress, the template that cloth is good delivered in press and carry out about 140 seconds vacuumize, and carry out secondary pressurized, the time of secondary pressurized is 30 seconds, then carries out vibrations pressurization 220 seconds;
B) go out mould, the sheet material suppressed is placed in punching block or glass template;
C) thermofixation, is heating and curing the quartzite slate on punching block or glass template, and set time is 120 minutes, and solidification value is 110 °;
D) demoulding, by the quartzite slate after solidification by the stripper demoulding;
(3) fixed thick, product thickness is 25mm;
A) first surface is fixed thick; B) turnover panel; C) determine thick for second;
(4) on-line automatic cutting is carried out in the both sides of the quartzite slate in production and two ends by cutting on line;
(5) polishing, sends the quartzite slate after cutting on line into polishing in polishing machine;
(6) air-dry, adopt hot blast air-dry;
(7) glazing waxing, pad pasting;
(8) cut.
Iron mica has sheet structure, effectively can must stop diffusion, the transmission of corrosive medium, be widely used in protective system, but its preservative effect is not satisfactory in relatively harsh environment.Therefore invention adopt sol-gel method iron mica on the surface clad nano silicon-dioxide modification is carried out to it.Infrared spectra (FTIR), power spectrum (EDS) and thermogravimetric analysis (TG) is adopted to determine whether nano silicon is coated on iron mica surface; Scanning electron microscope (SEM) observes the apparent form change of the coated front and back of iron mica; Utilize EIS technical study iron mica through the modified impact on coating corrosion resistance.Result shows: the SiO2 granular size being coated on iron mica surface is consistent, size is about 40nm: make its surface have nano material characteristic after the coated iron mica of nanosized SiO_2, thus improve thermotolerance and the hydrophobicity of iron mica, therefore enhance the corrosion resistance nature of coating greatly.
The test method of high-intensity corrosion erosion artificial quartz stone plate of the present invention:
1, sedimentation test:
With cutting machine, correct for the quartzite slate of thickness 20mm is cut out long 150mm, the anticorrosion quartzite slate sample block of width 150mm, weigh through Libra, record, inside the measuring cup then putting into 500ml, add the dilute sulphuric acid (9.5%-11%) of 500ml, at normal temperatures (20
0c) soak 48h, then, take out sample block, fall to remain in the dilute sulphuric acid on sample block by clean water, put into 50
0toast 60 minutes in C drying baker, after moisture is thoroughly dry, is again put on Libra and weighs, check whether have weightlessness, if weightless 1/1000, then sheet material is not anticorrosion.In addition, check under being put into the microscope of 100 times, the surface of sample block should be do not have vicissitudinous, if sample block surface have the vestige of corrosion to be exactly failed product.In addition, smooth finish instrument is adopted to detect, the antiseptic property detecting sample block that also can be very fast.
2, the main test item of quartzite slate
Apparent size: panel length tolerance+2mm, width tolerance 0 ~+2mm; Thickness deviation ± 0.5mm; Diagonal lines deviation≤10mm; 5% of irregularity degree≤thickness; Sheet edge nonstraightness≤1.5mm/m.
Petrographic analysis: surface clean, without obvious stain; Uniform color is consistent; Edges of boards are smooth, without losing fangle; Clear patterns, decorative pattern are obvious; Smooth surface is smooth, non-ripple, uneven, square stock trace, scratch, crackle, bubble, impurity; Scarce, pore is collapsed without damaged, nothing; Splice seamless.
Glossiness: premium grads >=45 °, first grade >=40 °;
Water-intake rate: water-intake rate≤0.1%;
Density: 2.37 ~ 2.5 × 103kg/m3;
Flexural strength: ≮ 16Mpa;
Ultimate compression strength: ≮ 90Mpa;
Heat-shock resistance: rectangular specimen test method (YB4018);
Wear resistance: ≯ 0.007g/cm2;
Anti-skid: USRV value >=35;
Frictional coefficient: between 0.5-0.7 (GB19079.1-2003);
Frost resistance: intensity decrease value is no more than 25%, weight loss is no more than 5% fire line: quartzite surface has the high thermal resistance of having given prominence to, and the fusing point of quartz is up to 1300 DEG C, and quartzite slate can not cause burning because of high temperature;
Shore hardness: >=80HSD;
Acid resistance: 9.5%-11% sulphuric acid soln soaking at room temperature 48h, mass loss rate K≤2% and outward appearance is unchanged.
The invention solves all the time, chemical plant, smeltery, Defence infrastructure construction problem, originally adopted granite building material, owing to there is natural deficiency, work-ing life is short, but also there is radioactive harm.The present invention is environmental protection not only, and the anti-folding of stone material, ultimate compression strength improve a lot, and stone material does closely knit simultaneously, and the thickness of original grouan at least wants 50mm, has now 20mm just enough.
The present invention adopts the mode of artificial synthesis high-purity quartz stone crystal and auxiliary material to be made by isomerization polymerization technology under vacuum, problems such as solving lithotome density deficiency, there is crack, solution cavity, fade, artificial quartz stone plate is made not only to have the hardness of lithotome, and be not afraid of the corrosion of corrosive liquids and gases, in addition, shades of colour can also be modulated into as required.The present invention is environmental protection not only, and improves anti-folding, the ultimate compression strength of stone material, simultaneously stone material do closely knit, and according to the needs of client, various pattern, pattern can be made.
Those skilled in the art should know; protection scheme of the present invention is not limited only to the above embodiments; various permutation and combination and conversion can also be carried out on the basis of above-described embodiment; under the prerequisite without prejudice to spirit of the present invention, the various conversion that the present invention carries out all are dropped in protection scope of the present invention.
Claims (9)
1. a high-intensity corrosion artificial quartz stone plate, its material composition wt% is: the quartzy stone sand of 32% ~ 37%, the quartz powder of 28% ~ 30%, 25% ~ 36% glass sand, 6.5% ~ 8% anti-corrosion resin, 0.1% ~ 0.18% solidifying agent, 0.04% ~ 0.1% promotor, the coupling agent of 0.38% ~ 0.52%, the anticorrosion mill base of 0.38% ~ 0.52% and 0.038% ~ 0.052% iron mica powder, described iron mica powder adopts sol-gel method to carry out modification at its Surface coating nanometer grade silica.
2. a kind of high-intensity corrosion artificial quartz stone plate according to claim 1, is characterized in that described quartzy stone sand comprises (wt%): 4% ~ 5.5% 4 ~ 6 orders quartz stone sands, 12.5% ~ 15% 10 ~ 20 orders quartz stone sands and 14% ~ 16% 40 ~ 70 orders quartz stone sands.
3. a kind of high-intensity corrosion artificial quartz stone plate according to claim 1, is characterized in that described glass sand comprises (wt%): 4 ~ 8 order glass sands of 5% ~ 7%, 8 ~ 16 order glass sands of 11% ~ 15% and 9% ~ 14% 16 ~ 30 order glass sands.
4. a kind of high-intensity corrosion artificial quartz stone plate according to claim 1, is characterized in that described anti-corrosion resin is epoxy resin; Described solidifying agent is at least one in BASF-HDI type solidifying agent or BAYER solidifying agent N75; Described promotor is do at least one in speed-raising promotor in TECH adhesion promoter, acid pickling promotor or wink; Described coupling agent is at least one in TECH silane coupling agent, aluminate coupling agent, titanate coupling agent, silane coupling agent, quartzite coupling agent or hilllock stone coupling agent.
5. a kind of high-intensity corrosion artificial quartz stone plate according to claim 1, is characterized in that described silicon-dioxide is Rutile type Titanium Dioxide.
6. a kind of high-intensity corrosion artificial quartz stone plate as claimed in any of claims 1 to 5, is characterized in that the thickness of described high-intensity corrosion artificial quartz stone plate is 8 ~ 35mm.
7. manufacture a making method for high-intensity corrosion artificial quartz stone plate as claimed in claim 1, it is characterized in that comprising the steps:
(1) starting material prepare
A) prepare burden, various starting material are proportionally deployed;
B) stir, deployed anti-corrosion resin, coupling agent, promotor, solidifying agent, anticorrosion mill base, iron mica powder and Rutile type Titanium Dioxide are put into mill base dispersion machine to stir 2 ~ 5 minutes, pure quartz sand, pure silica powder are put into material agitator and stirred 5 ~ 10 minutes, then the material in mill base dispersion machine is added in material agitator and carry out mix and blend 3 ~ 5 minutes;
C) mould base stock is spread, at 200 grams of high-strength kraft paper of ready mold bottom place mat one deck same size;
D) cloth, is layered in template uniformly by the raw material stirred, and what make it try one's best is smooth, and then spreads a kraft paper, then covers one deck rubber;
(2) shaping
A) suppress, the template that cloth is good delivered in press and carry out about 100 ~ 140 seconds vacuumize, and carry out secondary pressurized, the time of secondary pressurized is 20 ~ 30 seconds, then carries out vibrations pressurization 180 ~ 220 seconds;
B) go out mould, the sheet material suppressed is placed in punching block or glass template;
C) thermofixation, is heating and curing the quartzite slate on punching block or glass template, and set time is 40 ~ 120 minutes, and solidification value is 60 ° ~ 110 °;
D) demoulding, by the quartzite slate after solidification by the stripper demoulding;
(3) fixed thick, product thickness is 8 ~ 35mm;
A) first surface is fixed thick; B) turnover panel; C) determine thick for second;
(4) on-line automatic cutting is carried out in the both sides of the quartzite slate in production and two ends by cutting on line;
(5) polishing, sends the quartzite slate after cutting on line into polishing in polishing machine;
(6) air-dry, adopt hot blast air-dry;
(7) glazing waxing, pad pasting;
(8) cut.
8. the making method of a kind of high-intensity corrosion artificial quartz stone plate according to claim 7, it is characterized in that described starting material prepare in the paving mould base stock step of link, inside four limits of mould, put silica gel strip, the height of silica gel strip exceeds 3 ~ 7mm than mould.
9. the making method of a kind of high-intensity corrosion artificial quartz stone plate according to claim 7, is characterized in that in the thermal cure step of described shaping link, adopts ambient cure.
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| CN106116265A (en) * | 2016-06-24 | 2016-11-16 | 安徽弗仕通实业有限公司 | A kind of high temperature resistant artificial stone and preparation method thereof |
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| CN108527662A (en) * | 2018-04-27 | 2018-09-14 | 佛山市南海区卓迪机械有限公司 | A kind of stone countertops automatic production line |
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| CN109333206A (en) * | 2018-09-30 | 2019-02-15 | 清远戈兰迪高分子材料有限公司 | A kind of processing method of quartz pitted skin plate |
| CN111231353A (en) * | 2020-03-05 | 2020-06-05 | 福建磐珉新材有限公司 | Preparation method of artificial quartz synthetic stone plate with texture |
| CN112299876A (en) * | 2020-07-20 | 2021-02-02 | 广东欧文莱陶瓷有限公司 | Process for preparing leather surface of artificial quartz stone plate |
| CN112297207A (en) * | 2020-10-27 | 2021-02-02 | 潘浪锋 | Quartz stone plate forming equipment of gradual skinning |
| CN113459533A (en) * | 2021-07-16 | 2021-10-01 | 湖北联弘新材料科技股份有限公司 | Production method of environment-friendly quartz stone plate |
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| CN106810115A (en) * | 2015-12-01 | 2017-06-09 | 衡阳双雁运输机械有限公司 | Fire resisting quartzite slate and its manufacture method |
| CN106833002A (en) * | 2015-12-07 | 2017-06-13 | 徐文寿 | The manufacture method of the antibiotic colored quartz basin of resin base complex abrasion-proof |
| CN105801013A (en) * | 2016-02-19 | 2016-07-27 | 山东源根化学技术研发有限公司 | Self-cleaning anti-haze outdoor artificial quartz stone plate and preparation method thereof |
| CN106116265A (en) * | 2016-06-24 | 2016-11-16 | 安徽弗仕通实业有限公司 | A kind of high temperature resistant artificial stone and preparation method thereof |
| CN106113884A (en) * | 2016-06-28 | 2016-11-16 | 成都汇玉科技产业有限公司 | A kind of production method of artificial quartz in lump composite plate |
| CN106242359A (en) * | 2016-07-29 | 2016-12-21 | 山东康洁利人造石有限公司 | A kind of artificial quartz stone checkered plate and production technology thereof |
| CN106242360A (en) * | 2016-07-29 | 2016-12-21 | 山东康洁利人造石有限公司 | A kind of antibacterial artificial quartz and production technology thereof |
| CN106975588B (en) * | 2017-02-17 | 2020-06-16 | 哈尔滨工程大学 | Super-hydrophobic material and preparation method thereof |
| CN106975588A (en) * | 2017-02-17 | 2017-07-25 | 哈尔滨工程大学 | A kind of super hydrophobic material and preparation method thereof |
| CN107226637A (en) * | 2017-05-17 | 2017-10-03 | 铜陵四通防腐防水有限责任公司 | A kind of novel artificial quartzite plate and preparation method thereof |
| CN107571377A (en) * | 2017-08-29 | 2018-01-12 | 北京禾木之家科技发展有限公司 | A kind of preparation method of light composite board |
| CN107698211A (en) * | 2017-08-29 | 2018-02-16 | 北京禾木之家科技发展有限公司 | The preparation method of light composite board |
| CN108911780A (en) * | 2017-08-29 | 2018-11-30 | 北京禾木之家科技发展有限公司 | A kind of preparation method of light composite board |
| CN108527662A (en) * | 2018-04-27 | 2018-09-14 | 佛山市南海区卓迪机械有限公司 | A kind of stone countertops automatic production line |
| CN109333206B (en) * | 2018-09-30 | 2022-05-27 | 清远戈兰迪高分子材料有限公司 | Processing method of quartz stone pitted surface plate |
| CN109333206A (en) * | 2018-09-30 | 2019-02-15 | 清远戈兰迪高分子材料有限公司 | A kind of processing method of quartz pitted skin plate |
| CN111231353A (en) * | 2020-03-05 | 2020-06-05 | 福建磐珉新材有限公司 | Preparation method of artificial quartz synthetic stone plate with texture |
| CN112299876B (en) * | 2020-07-20 | 2022-03-11 | 广东欧文莱陶瓷有限公司 | Process for preparing leather surface of artificial quartz stone plate |
| CN112299876A (en) * | 2020-07-20 | 2021-02-02 | 广东欧文莱陶瓷有限公司 | Process for preparing leather surface of artificial quartz stone plate |
| CN112297207A (en) * | 2020-10-27 | 2021-02-02 | 潘浪锋 | Quartz stone plate forming equipment of gradual skinning |
| CN113459533A (en) * | 2021-07-16 | 2021-10-01 | 湖北联弘新材料科技股份有限公司 | Production method of environment-friendly quartz stone plate |
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