CN104691078B - A kind of preparation method of single plane fluoroscopy PVC milled carbon fiber films - Google Patents

A kind of preparation method of single plane fluoroscopy PVC milled carbon fiber films Download PDF

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Publication number
CN104691078B
CN104691078B CN201310645194.6A CN201310645194A CN104691078B CN 104691078 B CN104691078 B CN 104691078B CN 201310645194 A CN201310645194 A CN 201310645194A CN 104691078 B CN104691078 B CN 104691078B
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carbon fiber
pvc
milled carbon
sensitive adhesive
single plane
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CN104691078A (en
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游爱国
苏达明
厉勇
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Shanghai Naer Industrial Co., Ltd.
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SHANGHAI NAR INDUSTRIAL Co Ltd
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Abstract

A kind of preparation method of single plane fluoroscopy PVC milled carbon fiber films, mainly comprises the following steps:Double pouring paper, PVC milled carbon fiber membrane materials are individually placed to unreel on support;The blade coating black pressure-sensitive adhesive layer on double pouring paper silicone oil faces;By way of hot-air seasoning, remove the partial solvent in black pressure-sensitive adhesive layer;By way of infrared baking, remove the partial solvent remained in black pressure-sensitive adhesive layer;Double pouring paper with black pressure-sensitive adhesive layer are combined with PVC milled carbon fibers film;Winding;Punching;Change base stock;Cutting;Packaging.There is decoration and single plane fluoroscopy through the single plane fluoroscopy PVC milled carbon fiber films that the invention is made.

Description

A kind of preparation method of single plane fluoroscopy PVC milled carbon fiber films
Technical field
The present invention relates to a kind of preparation method of ornamental material, furthermore it is related to a kind of single plane fluoroscopy PVC carbon The preparation method of fiber line film.
Background technology
Current single plane fluoroscopy pad pasting is mainly made up of PVC film, pressure sensitive adhesive, three kinds of materials of release liners.Mainly it is pasted onto The outer surface of glass material, the place such as vehicle body glass outer surface, glass curtain wall outer surface, market showcase outer surface. Advertisement picture air brushing peels release liners off on PVC film face when using, back-adhesive surface is attached on glass, reaches single plane fluoroscopy and wide Accuse the effect of publicity.
In order to which advertisement picture can clearly air brushing be on PVC film surface, the PVC film used is substantially PVC white films.And PVC white membrane materials are only on the basis of picture is sprayed, the just effect with decoration, the effect for itself not possessing decoration, limit Application of the single plane fluoroscopy pad pasting in furnishing fields is made.
The content of the invention
The technical problems to be solved by the invention are, overcome existing single plane fluoroscopy membrane material to be used in decoration material field Limitation there is provided a kind of preparation method of the single plane fluoroscopy PVC milled carbon fiber films with decoration functions.
In order to solve the above problems the technical scheme is that such:A kind of single plane fluoroscopy with decoration functions The preparation method of PVC milled carbon fiber films, it is characterised in that comprise the following steps:
1) double pouring paper, PVC milled carbon fiber membrane materials are individually placed to unreel on support;
2) the blade coating black pressure-sensitive adhesive layer on double pouring paper silicone oil faces;
3) by way of hot-air seasoning, the partial solvent in black pressure-sensitive adhesive layer is removed;
4) by way of infrared baking, the partial solvent remained in black pressure-sensitive adhesive layer is removed;
5) double pouring paper with black pressure-sensitive adhesive layer are combined with PVC milled carbon fibers film;
6) wind;
7) punching;
8) base stock is changed;
9) cut, pack.
In step 1) in, the thickness of described PVC milled carbon fiber films is (100 μm~120 μm), is preferably (110 μm);It is double The grammes per square metre for drenching paper is (110g/m2~160g/m2), it is preferably (140g/m2)。
In step 2) in, the solid content of black pressure-sensitive adhesive is (40%~60%), is preferably (45%);Double silicone oil for drenching paper The gluing gap in face is (0.17mm~0.22mm), is preferably (0.20mm);Double dry glue amounts drenched on paper silicone oil face are (110g/ m2~160g/m2), it is preferably (50g/m2)。
In step 3) in, the hot-air seasoning is realized by six section continuous drying baking ovens, its temperature setting difference For:(70 DEG C~80 DEG C), (80 DEG C~90 DEG C), (90 DEG C~100 DEG C), (100 DEG C~110 DEG C), (90 DEG C~100 DEG C), (70 DEG C ~80 DEG C), it is respectively preferably:(75℃)、(85℃)、(95℃)、(105℃)、(90℃)、(80℃).
In step 4) in, the infrared baking is realized by 3 groups of infrared baking pipe groups, its temperature setting difference For:(80 DEG C~90 DEG C), (90 DEG C~110 DEG C), (80 DEG C~90 DEG C), be respectively preferably:(80℃)、(100℃)、(80℃).
In step 5) in, the double pouring paper with black pressure-sensitive adhesive layer come out from infrared baking region are by leading Roller, into composite roll, while PVC milled carbon fiber films unreel and enter composite roll by deflector roll, it is pressure-sensitive with black at composite roll The double pouring paper and PVC milled carbon fiber films of glue-line are combined with each other.Rubber pressure of the composite roll used by chill roll and with cylinder Roller group is into the temperature setting of chill roll is respectively:(10 DEG C~40 DEG C), be preferably:(25℃).
In step 6) in, the machine speed of described winder is (10m/s~30m/s), is preferably:(20m/s);Winding tension For (300N~600N), it is preferably:(450N).
In step 7) in, described small-bore is (1.4mm~2.0mm), is preferably (1.6mm).
In step 8) in, the material of described made aperture is replaced the paper that refoots on rewinding machine, with foraminate double Drench paper to be replaced by release liners, the grammes per square metre of release liners is (93g/m2~138g/m2), it is preferably (118g/m2)。
Compared with existing product, the present invention has following two advantages:
1) without air brushing picture, PVC milled carbon fiber films surface has beautiful PVC milled carbon fiber textures in itself, with dress Decorations are acted on, and have expanded the decoration functions of single-way perspective membrane;
2) while decoration functions are played, the outer surface of glass material is attached to, the function with good single plane fluoroscopy.
Brief description of the drawings
Fig. 1:For single plane fluoroscopy PVC milled carbon fibers film structure schematic diagram of the present invention.
In figure:1-PVC milled carbon fiber film layers;2- black pressure-sensitive adhesives layer;3- off-style paper layers;4- apertures.
Embodiment
In order that technological means, creation characteristic, reached purpose and effect of the present invention are easy to understand, with reference to tool Body is illustrated, and further illustrates the present invention.
Referring to Fig. 1, a kind of single plane fluoroscopy PVC milled carbon fiber films with decoration functions, are a kind of three laminates, point Wei not PVC milled carbon fibers film layer 1, black pressure-sensitive adhesive layer 2, off-style paper layer 3;In PVC milled carbon fibers film layer 1 and black pressure-sensitive adhesive layer There is the aperture 4 communicated on 2.
The connected mode of three-decker is:Centre is black pressure-sensitive adhesive layer, bond respectively PVC milled carbon fiber films the back side and The silicone oil face of release liners;
Specific preparation method is as follows
1) double pouring paper, PVC milled carbon fiber membrane materials are individually placed to unreel on support:
PVC milled carbon fiber films, which are placed on, to be unreeled on support, and the thickness of PVC milled carbon fibers film 1 (Fig. 1-1) is (100 μm~120 μ M), it is preferably (110 μm);Double pouring paper, which are placed on, to be unreeled on support, and double grammes per square metres for drenching paper are (110g/m2~160g/m2), it is preferably (110g/m2);
2) the blade coating black pressure-sensitive adhesive layer on the silicone oil face of double pouring paper:
PVC milled carbon fiber films are unreeled, and are drawn to by deflector roll up to gluing head, and comma scraper there will be in glue groove herein Black pressure-sensitive adhesive blade coating forms the pressure-sensitive adhesive layer (Fig. 1-2) of black in the silicone oil face of double pouring paper.The solid content of black pressure-sensitive adhesive is (40%~60%), be preferably (45%);The gluing gap in double silicone oil faces for drenching paper is (0.17mm~0.22mm), is preferably (0.20mm);Double dry glue amounts drenched on paper silicone oil face are (110g/m2~160g/m2), it is preferably (50g/m2);
3) by way of hot-air seasoning, the partial solvent in black pressure-sensitive adhesive layer is removed:
Scrape and coat black pressure-sensitive adhesive layer into the 1st section of baking zone, the 1st section of baking zone saves continuous drying baking ovens by six, Organic solvent in black pressure-sensitive adhesive volatilizees herein, into solvent recovering system.The temperature of six section continuous drying baking ovens is set It is fixed to be respectively:(70 DEG C~80 DEG C), (80 DEG C~90 DEG C), (90 DEG C~100 DEG C), (100 DEG C~110 DEG C), (90 DEG C~100 DEG C), (70 DEG C~80 DEG C), be respectively preferably:(75℃)、(85℃)、(95℃)、(105℃)、(90℃)、(80℃);
4) mode of outside line drying, removes the partial solvent remained in black pressure-sensitive adhesive layer:
The double pouring paper for scribbling black pressure-sensitive adhesive layer come out from the 1st section of baking zone by deflector roll into the 2nd section of drying area, 2nd section of drying area is made up of 3 groups of infrared baking pipes, and the organic solvent of the residual in black pressure-sensitive adhesive volatilizees herein, Into solvent recovering system.The temperature of 3 groups of infrared baking pipe groups is set:(80 DEG C~90 DEG C), (90 DEG C~110 DEG C), (80 DEG C~90 DEG C), be respectively preferably:(80℃)、(100℃)、(80℃);
5) double pouring paper of black pressure-sensitive adhesive layer are combined with PVC milled carbon fibers film:
The double pouring paper with black pressure-sensitive adhesive layer come out from the 2nd section of drying area pass through deflector roll, into composite roll, simultaneously PVC milled carbon fiber films are unreeled enters composite roll by deflector roll, at composite roll, double pouring paper and PVC with black pressure-sensitive adhesive layer Milled carbon fiber film is combined with each other.The composite roll used is made up of chill roll with the rubber roller with cylinder.The temperature of chill roll Spending setting is respectively:(10 DEG C~40 DEG C), be preferably:(25℃);
6) wind:
The material being combined passes through deflector roll, is wound on winder.The machine speed of winder is (10m/s~30m/s), preferably For:(20m/s);Winding tension is (300N~600N), is preferably:(450N);
7) punching:
The material being combined is punched out on punching machine, and aperture (Fig. 1-4) footpath is (1.4mm~2.0mm), preferably For (1.6mm);
8) base stock is changed:
The material of made aperture, the paper that refoots is replaced in rewinding machine thereon, with foraminate double paper that drench by release liners (figure 1-3) replace, the grammes per square metre of release liners is (93g/m2~138g/m2), it is preferably (118g/m2);
9) cut, pack.
Compared with existing product, the present invention has following two advantages:
1) without air brushing picture, PVC milled carbon fiber films surface has beautiful PVC milled carbon fiber textures in itself, with dress Decorations are acted on, and have expanded the decoration functions of single-way perspective membrane;
2) while decoration functions are played, the outer surface of glass material is attached to, the function with good single plane fluoroscopy.
The foregoing describe the basic principles, principal features and advantages of the present invention.It should be understood by those skilled in the art that, this Invention is not restricted to the described embodiments, the principle of the simply present invention described in embodiment and specification, is not departing from this hair Various changes and modifications of the present invention are possible on the premise of bright spirit and scope, and these changes and improvements will fall into claimed The scope of the present invention in.The claimed scope of the invention is by described claims and its waits thing and defines.

Claims (7)

1. a kind of preparation method of the single plane fluoroscopy PVC milled carbon fiber films with decoration functions, it is characterised in that including following step Suddenly:
1) double pouring paper, PVC milled carbon fiber membrane materials are individually placed to unreel on support;
2) the blade coating black pressure-sensitive adhesive layer on double pouring paper silicone oil faces;
3) by way of hot-air seasoning, the partial solvent in black pressure-sensitive adhesive layer is removed;
4) by way of infrared baking, the partial solvent remained in black pressure-sensitive adhesive layer is removed;
5) double pouring paper with black pressure-sensitive adhesive layer are combined with PVC milled carbon fibers film;
6) wind:
7) punching;
8) base stock is changed;
9) cut, pack;
The thickness of the PVC milled carbon fibers film is 100 μm~120 μm;
The step 2) in the solid content of black pressure-sensitive adhesive be 40%~60%, the gluing gap in double silicone oil faces for drenching paper is 0.17mm~0.22mm, double dry glue amounts drenched on paper silicone oil face are 110g/m2~160g/m2, the step 7) in aperture A diameter of 1.4mm~2.0mm.
2. a kind of preparation method of single plane fluoroscopy PVC milled carbon fiber films with decoration functions according to claim 1, its It is characterised by, in step 1) in, double grammes per square metres for drenching paper are 110g/m2~160g/m2
3. a kind of preparation method of single plane fluoroscopy PVC milled carbon fiber films with decoration functions according to claim 1, its It is characterised by, in step 3) in, the hot-air seasoning is realized by six section continuous drying baking ovens, its temperature setting difference For:70 DEG C~80 DEG C, 80 DEG C~90 DEG C, 90 DEG C~100 DEG C, 100 DEG C~110 DEG C, 90 DEG C~100 DEG C, 70 DEG C~80 DEG C.
4. a kind of preparation method of single plane fluoroscopy PVC milled carbon fiber films with decoration functions according to claim 1, its It is characterised by, in step 4) in, the infrared baking is realized by 3 groups of infrared baking pipe groups, the setting point of its temperature It is not:80 DEG C~90 DEG C, 90 DEG C~110 DEG C, 80 DEG C~90 DEG C.
5. a kind of preparation method of single plane fluoroscopy PVC milled carbon fiber films with decoration functions according to claim 1, its It is characterised by, in step 5) in, double pouring paper with black pressure-sensitive adhesive layer pass through deflector roll, into composite roll, while PVC carbon Fiber line film is unreeled enters composite roll by deflector roll, at composite roll, double pouring paper and PVC carbon fibers with black pressure-sensitive adhesive layer Line film is combined with each other;The composite roll used is made up of chill roll with the rubber roller with cylinder;The temperature setting of chill roll For 10 DEG C~40 DEG C.
6. a kind of preparation method of single plane fluoroscopy PVC milled carbon fiber films with decoration functions according to claim 1, its It is characterised by, in step 6) in, the machine speed of the winding is 10m/s~30m/s, and the tension force of winding is 300N~600N.
7. a kind of preparation method of single plane fluoroscopy PVC milled carbon fiber films with decoration functions according to claim 1, its It is characterised by, step 8) it is the progress replacing base stock on rewinding machine, replaced with foraminate double paper that drench by release liners, release liners Grammes per square metre is 93g/m2~138g/m2
CN201310645194.6A 2013-12-05 2013-12-05 A kind of preparation method of single plane fluoroscopy PVC milled carbon fiber films Active CN104691078B (en)

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CN109435397A (en) * 2018-11-18 2019-03-08 张雅慧 A kind of new-energy automobile radiation protection new material

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Publication number Priority date Publication date Assignee Title
CN2858266Y (en) * 2005-04-29 2007-01-17 上海富顺单向透视材料有限公司 Unidirectional perspective film with black coat
CN201122415Y (en) * 2007-09-24 2008-09-24 上海纳尔实业有限公司 Stereo one-way perspective film
CN201769403U (en) * 2010-04-21 2011-03-23 上海纳尔数码喷印材料股份有限公司 Black pressure-sensitive adhesive PVC car stick
CN102862409A (en) * 2011-07-08 2013-01-09 上海纳尔数码喷印材料股份有限公司 One-way perspective digital printed material with bottom coated with BOPP membrane and process method
CN103419524A (en) * 2012-05-17 2013-12-04 上海纳尔数码喷印材料股份有限公司 Three-layer unidirectional perspective film printing material and manufacturing method thereof

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DE502004008524D1 (en) * 2004-02-18 2009-01-08 Johns Manville Europe Gmbh Dimensionally stable insert suitable for roofing membranes or waterproofing membranes

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2858266Y (en) * 2005-04-29 2007-01-17 上海富顺单向透视材料有限公司 Unidirectional perspective film with black coat
CN201122415Y (en) * 2007-09-24 2008-09-24 上海纳尔实业有限公司 Stereo one-way perspective film
CN201769403U (en) * 2010-04-21 2011-03-23 上海纳尔数码喷印材料股份有限公司 Black pressure-sensitive adhesive PVC car stick
CN102862409A (en) * 2011-07-08 2013-01-09 上海纳尔数码喷印材料股份有限公司 One-way perspective digital printed material with bottom coated with BOPP membrane and process method
CN103419524A (en) * 2012-05-17 2013-12-04 上海纳尔数码喷印材料股份有限公司 Three-layer unidirectional perspective film printing material and manufacturing method thereof

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Address after: No. 26 Xinhan Road, Xinchang Industrial Park, Pudong New Area, Shanghai, 20114

Patentee after: Shanghai Naer Industrial Co., Ltd.

Address before: No. 26 Xinhan Road, Xinchang Industrial Park, Pudong New Area, Shanghai, 20114

Patentee before: Shanghai NAR Industrial Co., Ltd.