CN104684533B

CN104684533B - Reagent containing fatty substances and rheology modification of polymers in emulsion system for changing keratin fiber color

Info

Publication number: CN104684533B
Application number: CN201380051923.3A
Authority: CN
Inventors: 马克·本; 莉萨·亚布隆斯基
Original assignee: LOreal SA
Current assignee: LOreal SA
Priority date: 2012-10-02
Filing date: 2013-10-01
Publication date: 2018-01-05
Anticipated expiration: 2033-10-01
Also published as: JP6339084B2; BR112015006280B1; EP2903584A2; WO2014053504A2; JP2015531385A; WO2014053504A3; WO2014053504A4; CN104684533A; BR112015006280A2

Abstract

The present invention describes a kind of reagent and method for being used to change the color of keratin fiber, wherein, the reagent includes：(A) color alkali composition, the color alkali composition contains has greater than about 50mm at 40 DEG C²Fatty substances, rheology modification of polymers, basifier, the short alkyl chain hydroxy compounds and oxidation dye precursors selected from monohydric alcohol and polyalcohol of/s viscosity；And (B) oxidising composition, the oxidising composition contain oxidant.

Description

Contain fatty substances and rheology in emulsion system for changing keratin fiber color Polymer-modified reagent

Technical field

The present invention relates to for changing keratin substances, include the reagent of the color of human keratin fibres such as hair.This The reagent for the color that kind is used to change keratin fiber includes the color alkali (color containing fatty substances and rheology modification of polymers Base) composition and the oxidising composition containing oxidant.

Background technology

It is known that consumer is desirable for color by changing hair and/or by assigning different characteristics to hair Strengthen the cosmetics and personal care composition of the outward appearance of keratin fiber such as hair such as gloss and regulation.Change hair The method of color can include by artificial colors deposit on hair (this provides different tones or color to hair) or The color of (lift) hair is removed, such as from dark-brown tone to burnt umber or light brown tone.

Conventional hair coloring product includes permanent hair dyeing product (also referred to as oxidising dyeing), and these products are in alkalescence Use includes oxidation dye precursors (also referred to as main intermediate or oxidation base) in the case of the overwhelming majority under the conditions of pH Composition and oxygenated products comprising oxidant (such as peroxide and persulfate compound) combination.Generally, this A little oxidation dye precursors, which include, is selected from o- or p-phenylenediamine class, o- or para-aminophenol and heterocycles oxidation Developing alkali.These oxidation bases are colourless or slightly colored compound, can be via oxygen when they are combined with oxygenated products Change method of condensing and produce coloured species.

Often these can be used to change by the way that these oxidation bases are combined with least one colour coupler (coupler) The tone that oxidation base obtains, these colour couplers are selected from, for example, diamines between aromatic series, m-aminophenol, Resorcino, with And some heterocyclic compounds such as benzazolyl compounds.Different molecular as oxidation base and colour coupler can allow to obtain extensively The color of scope.

The oxidant used in permanent color composition can degrade the melanin of hair, according to existing oxidant Property, this may cause distant fiber blast.Therefore, for relatively weak blast, at least one oxidant can To be, for example, hydrogen peroxide.When desirably a greater degree of blast, can use in the presence of hydrogen peroxide Oxide salt (peroxygenated salt), such as persulfate.

Hair coloring composition typically contains ammoniacal liquor as basifier and for activating the oxidant.These basifiers are also Cause dry expansion, so that small oxidation dye molecule permeates cuticula and cortex before the completion of oxidative condensation method.So It is trapped in afterwards by the larger sized coloring complex compound obtained by oxidation reaction in hair fiber, so as to for good and all change hair Color.However, the use of ammonia may influence user, not only due to ammonia makes us undesirable smell, and because it may be used also Bigger intolerance risk can be caused, for example, stimulation and shouting pain to scalp.

By all or at least some ammoniacal liquor replace with least one other standards basifier selection will not often produce and Those equally effective compositions based on ammoniacal liquor, such as because these basifiers may not provide in the presence of oxidant The abundant blast of the fiber of coloring.

Therefore, in the art for improved and/or replacement the dye carried out in the presence of at least one oxidant There are a kind of needs in color method, these colouring methods do not have the shortcomings that at least one existing method.

In order to improve the performance of such hair coloring composition, constantly seek using new and other composition and composition Novel combination；However, the selection of composition may cause difficulty, because they must improve dyeing/lifting energy of said composition Other characteristics such as its application, rheology or viscosity characteristicses of the power without being harmful to said composition, stability and/or cause more Increased infringement of the shortcoming such as to hair makes hair seem more unhealthy.

It is also important that provide the hair coloring composition with different types of denseness (consistency) so that These compositions can be with liquid emulsion, such as liquid-lotion, liquid-gel, liquid-creams, or creams emulsion, such as thick creams Or gel-creams, or the offer of the form of foam or mousse, wherein the liquid emulsion form is with diluter than creams emulsion form Denseness and it is typically packaged in bottle.When the hair of whole head will be colored or when it is desirable that usually using liquid during a kind of only color Precursor emulsion form, because dye composite is easily sprawled, so as to allow bigger coverage, and creams emulsion form can be used for Dye the hair of whole head and for highlighting or only some parts of blast hair.

It is therefore an object of the present invention to obtain the novel composition for oxidising dyeing hair.Another mesh of the present invention Be obtain as hair coloring composition, these hair coloring compositions have denseness or rheology unique, do not drip Property and easily sprawled on hair and meanwhile assign hair other advantages as nursed one's health, the outward appearance of health, gloss and to hair Less infringement.

The content of the invention

In order to realize these and other advantages, the present invention is described as a kind of examination for being used to change the color of keratin fiber Agent, the reagent include：

(A) color alkali composition, the color alkali composition include in the acceptable medium of cosmetics：

(a) gross weight of (A) is based on, by weight at least about 5% at least one fatty substances, the fatty substances are 40 DEG C there is greater than about 50mm²/ s viscosity；And

(b) rheology modification of polymers of the acrylate polymer of at least one crosslinking in water-borne dispersions；

(c) at least one basifier；

(d) at least one short alkyl chain hydroxy compounds selected from monohydric alcohol and polyalcohol；

(e) at least one oxidation dye precursors；And

(B) oxidising composition, the oxidising composition include at least one oxidant in the acceptable medium of cosmetics.

The present invention is also described as a kind of method of keratin fibre staining, and this method includes disclosed above being used for The reagent of color for changing keratin fiber (such as hair) is applied on keratin fiber, wherein by the color alkali and oxidising composition The reagent is mixed to form, it is applied on these fibers afterwards；And the reagent is set to stop one on keratin fiber Section is enough the time for making these fibre stainings.

Embodiment

Except in operational instances, or otherwise indicated, the amount and/or all numerical value of reaction condition of expressing composition should It is interpreted as in all cases by being modified including ± 10% term " about ".

" at least one " refers to one or more and therefore includes single component and mixture/group as used in this Close.

" keratin fiber " can be selected from, for example, the hair of the mankind.

As used in this " from ... formation, " refer to chemically react acquisition, wherein " chemical reaction, " is including spontaneous Chemical reaction and induction chemical reaction.As used herein, phrase " from ... formation ", it is open ending and will The component of composition is limited to those listed, for example, as component (i) and component (ii).In addition, phrase " from ... formation " Do not limit and component is added to order in composition or requires that listed component (for example, component (i) and (ii)) is in office What it is added to before other components in composition.

As used herein, " hydro carbons, " includes alkanes, olefines and alkynes class, wherein these alkane include at least one Individual carbon, and these alkene and alkynes each include at least two carbon；Further wherein these hydrocarbon can be selected from straight chain hydrocarbon, Side chain hydro carbons and cyclic hydrocar-bons；Further wherein these hydrocarbon can be optionally substituted；And further wherein these hydrocarbon The hetero atom at least one insertion hydrocarbon chain can optionally be further comprised.

As used herein, " silicone (silicone) compound " includes, for example, silica, silane, silazane, silica Alkane and organosiloxane；And refer to a kind of compound for including at least one silicon；Wherein the silicone compounds can select From linear chain silicones compound, side chain silicone compounds and cyclic silicone compound；Further wherein the silicone compounds can To be optionally substituted；And further wherein the silicone compounds can optionally further comprise at least one insertion silicon Hetero atom in ketone chain, wherein at least one hetero atom are to be different from least one silicon.

As used herein, " substituted, " refers to containing at least one substituent.The non-limiting examples of substituent include original Son, such as oxygen atom and nitrogen-atoms, and functional group, such as oh group, ether group, alkoxy base, acyloxyalkyl radicals, oxygen Change alkenyl group, polyalkylene oxide groups, hydroxy-acid group, amine groups, amido groups, amide group, Halogen group elements, ester group Group, thiol group, sulfonate ester group, thiosulfuric acid ester group, siloxane group and polysiloxane group.This or more Individual substituent can be further substituted.

As defined herein, " polymer, " include homopolymer and the copolymerization formed by least two different types of monomers Thing.

Term as defined in this refers to the color for being used to change keratin fiber of the present invention " substantially free of ammonia " Composition or reagent be either entirely free of ammonia (including ammonium ion) or the ammonia (including ammonium ion) containing not perceived amount, example Such as, based on these compositions of color or the weight of reagent for changing keratin substrate, no more than by weight 1% or No more than by weight 0.5% or no more than by weight 0.3% or no more than by weight 0.1%.

Unexpectedly and it was unexpectedly found that when secondary colour alkali and oxidising composition, resulting is used for The reagent (also referred to as instant composition) for changing the color of keratin fiber has improved dyeing property.For example, for changing The reagent for becoming the color of keratin fiber provides with good intensity and/or concentration and/or is sending out edge between the tip and root of hair The coloring of good Color uniformity (selectivity also referred to as coloured) and/or the good colourity of fiber.In addition, for changing Becoming the reagent of the color of keratin fiber can be applied on keratin fiber without flowing or dripping without difficulty.

Also unexpectedly and it was unexpectedly found that can be according to present disclosure with lower cost and shorter Production time effectively changes the color of hair, because the color alkali group of lesser amount of dye composition and the present invention can be used Compound can be prepared without using heat or using refrigerating technology.

Fatty substances

The color alkali composition or the color alkali composition of the present invention include at least one fatty substances, and the fatty substances are at 40 DEG C With greater than about 50mm²/ s viscosity.

At least one of the present invention has greater than about 50mm at 40 DEG C²The viscosity of the fatty substances of/s viscosity is basis It is that the methods of ASTM D 445 are measured with kinematic viscosity and can be in greater than about 50mm at 40 DEG C with scope²/ s to about 100mm²/s Between, preferably at 40 DEG C from about 50mm²/ s to about 100mm²/s。

At least one has greater than about 50mm at 40 DEG C²The fatty substances of/s viscosity can be selected from such as mineral oil Oils is (such as at 40 DEG C with mm²/ s is the kinematic viscosity that unit is measured by the methods of ASTM D 445).

Have at 40 DEG C and be more than 50mm²The preferable fatty substances of/s viscosity are that have scope from about 63mm at 40 DEG C²/s To about 70mm²The mineral oil of/s viscosity, from Suo Nuobang companies of the U.S. of supplier (Sonneborn) with trade name Weigh slab oil or from exxonmobil chemical company of supplier (Exxonmobil Chemical) with trade name Primol^TM352 is commercially available.

At least one has greater than about 50mm at 40 DEG C²The fatty substances of/s viscosity can also hereinafter be referred to as " high viscosity mineral oil ".

The color alkali composition of the present invention can be included further with having greater than about 50mm at 40 DEG C²The aliphatic series of/s viscosity The different other fatty substances of material.

" fatty substances " refer in normal temperature (25 DEG C) and a kind of organic compound not soluble in water under atmospheric pressure (750mmHg) Thing (solubility is less than 5% and such as less than 1% and further such as less than 0.1%).Structure of the fatty substances at them In chain with least two siloxane groups or at least one hydrocarbon chain with least six carbon atom.In addition, fatty substances lead to Often dissolved under the conditions of identical temperature and pressure in organic solvent, such as chloroform, ethanol, benzene or decamethylcyclopentasiloxane.

Fatty substances are, for example, being selected from lower paraffin hydrocarbon, fatty alcohol, the ester of aliphatic acid, the ester of fatty alcohol, aliphatic acid, oils Such as the non-silicone oil of mineral oil, vegetable oil, animal oil and synthesis, non-silicone wax and silicone.

In some embodiments, these alcohol and ester have at least one straight or branched containing 6 to 30 carbon atoms , saturation or undersaturated hydrocarbyl group, optionally for example substituted by least one oh group (such as 1 to 4).If it Be it is undersaturated, these compounds can have one to three conjugation or unconjugated carbon-to-carbon double bond.

As for lower paraffin hydrocarbon, in some embodiments, they have from 6 to 16 carbon atoms and are straight or brancheds , optionally ring-type.As example, alkane can be selected from hexane and dodecane, isoparaffin such as isohexadecane and isodecane.

The non-limiting examples of available non-silicone oil include in the composition of present disclosure：The hydrocarbon ils of animal origin is such as complete Hydrosqualene；The hydrocarbon ils of plant origin, such as have from the ester of the liquid glycerin three such as enanthic acid of the aliphatic acid of 6 to 30 carbon atoms or Octanoic acid triglycerides, such as sunflower oil, corn oil, soybean oil, calaba oil, grape-kernel oil, sesame oil, hazelnut oil, Apricot kernel oil, macadimia nut oil, I draw oil, sunflower oil, castor oil, avocado oil, the triglycerides of caprylic/capric such as by Stearineries Dubois companies sell those or by Dai Na meter Te Nobels (Dynamit Nobel) company with title810th, 812 and 818 those sold, SIMMONDSIA CHINENSIS SEED OIL, Butyrospermum fatty oil；With more than 16 carbon atoms The mineral of straight or branched or the hydrocarbon of synthesis source, such as paraffin oil, vaseline, white oil, poly decene, the polyisobutene hydrogenated Such asPartially fluorinated hydrocarbon ils；As fluorinated oil, non-limiting examples include trifluoromethyl-cyclopentane and perfluor -1, 3- dimethyl cyclohexanes, by BNFL fluorine chemicals (Fluorochemicals) company with title "PC1 " and "PC3 " is sold；Perfluor -1,2- dimethylcyclobutanes；Perfluoro alkane class such as R-4112 and ten tetrafluoros oneself Alkane, by 3M companies with titleWithSell, or by chemical (Atochem) company of atropic with name ClaimThe bromine perfluoro capryl of sale；Nonafluoromethoxybutcompositions and nine fluorine ethyoxyl iso-butanes；Perfluor morpholine Derivative, such as by 3M companies with titleThe 4- trifluoromethyl perfluor morpholines of sale.

The fatty alcohol that can be used as fatty substances in the composition of present disclosure includes but is not limited to non-alkoxylate, saturation It is or undersaturated, straight or branched and with from 6 to 30 carbon atoms and more particularly from 8 to 30 carbon atoms；Example Such as, cetanol, stearyl alcohol and their mixture (cetearyl alcohol), octyldodecanol, 2- butyl octanol, the 2- hexyl last of the ten Heavenly stems Alcohol, 2- undecylpentadecanols, oleyl alcohol or linoleyl alcohol (linoleic alcohol).

The exemplary one or more non-silicone waxes that can be used in the composition of present disclosure are selected from Brazil wax, Candelila wax, and Alpha's wax, paraffin, ceresine, vegetable wax such as olive wax, rice wax, the jojoba waxes of hydrogenation or the pure wax of flower The smart wax that the currant that (absolute wax) is such as sold by smooth (Bertin) company (France) of Bel is spent, animal wax such as beeswax, Or modified beeswaxes (cerabellina)；Other waxes or waxy feedstock are according to workable for present disclosure, for example, the raw wax in sea (marine wax) as sold as Suo Feimu (SOPHIM) companies with call number M82, Tissuemat E or in general polyolefin Wax.

Exemplary fatty acid ester is the C of saturated or unsaturated, straight chain or side chain₁-C₂₆Aliphatic monoacid or Polyacid and saturated or unsaturated, straight chain or side chain C₁-C₂₆The ester of aliphatic monobasic alcohol or polyalcohol, these esters The sum of carbon is, for example, more than or equal to 10.

Among monoesters, behenic acid dihydroabietic acid's base ester can be mentioned that with non-limiting；Behenic acid octyldodecyl Ester；The different spermaceti base ester of behenic acid；Lactic acid spermaceti base ester；Lactic acid C₁₂-C₁₅Arrcostab；Lactic acid iso stearyl ester；Lactic acid lauryl Ester；Lactic acid Asia oil base ester；Lactic acid oil base ester；Sad (different) stearyl；The different spermaceti base ester of octanoic acid；Sad octyl group ester；Sad whale Cerul ester；Decyl oleate；The different spermaceti base ester of isostearic acid；The different spermaceti base ester of laurate；Stearic acid spermaceti base ester；Sad isodecyl Base ester；Oleic acid isodecyl base ester；Different n-nonanoic acid isononyl ester；Palmitic acid iso stearyl ester；Castor oil acid methyl vinyl base ester；Stearic acid Nutmeg base ester；Different octyl pelargonate；Different n-nonanoic acid 2- ethylhexyls；Octyl palmitate；Octyl pelargonate；Octyl stearate；Erucic acid is pungent Base dodecyl ester；Erucic acid oil base ester；Ethyl palmitate and isopropyl ester, the own esters of palm acid ethyl -2-, the palmitic acid 2- octyl group last of the ten Heavenly stems Ester, isopropyl ester, butyl ester, cetyl base ester, 2- octyldodecyls, the myristyl of myristic acid Arrcostab such as myristic acid Ester, stearyl, hexyl stearate, butyl stearate, isobutyl stearate；Apple dioctyl phthalate, lauric acid hexyl ester, Yi Jiyue Cinnamic acid 2- hexyl last of the ten Heavenly stems esters.

Other can be C with the non-limiting ester referred to₄-C₂₂Two-or tricarboxylic acids and C₁-C₂₂The ester of alcohol and it is single-, two- or Tricarboxylic acids and C₂-C₂₆Two-, three-, four-or penta hydroxy group alcohol ester.

The even further non-limiting examples of esters include：Diethyl sebacate；Diisopropyl sebacate；Adipic acid Diisopropyl ester；Adipic acid-di-n-propyl ester；Dioctyl adipate；The iso stearyl ester of adipic acid two；Di-2-ethylhexyl maleate；Endecatylene Acid glycerol base ester；Octyldodecyl dodecyl stearoyl base ester；Single castor oil acid pentaerythrite base ester；Four different n-nonanoic acid Ji Wusi Alcohol base ester；Four n-nonanoic acid pentaerythrite base esters；Four isostearic acid pentaerythritol esters；Four sad pentaerythrite base esters；Two octanoic acids the third two Alcohol ester；Didecyl acid propylene glycol ester；Erucic acid tridecane base ester；The isopropyl ester of citric acid three；The iso stearyl ester of citric acid three；Three lactic acid are sweet Oil base ester；Three sad glycerine base esters；Bernel；The oil base ester of citric acid three；Two sad propylene glycol esters；Two Enanthic acid DOPCP；Two different n-nonanoic acid diethylene glycol (DEG) esters；And distearyl acid polyethylene glycol ester.

Among above-mentioned esters, exemplary ester includes ethyl ester, isopropyl ester, nutmeg base ester, the spermaceti of palmitic acid Base ester, stearyl, the own esters of palm acid ethyl -2-, palmitic acid 2- octyl groups last of the ten Heavenly stems ester, myristic acid Arrcostab such as myristic acid it is different Propyl ester, butyl ester, spermaceti base ester, 2- octyldodecyls, hexyl stearate, butyl stearate, isobutyl stearate；Malic acid Dioctyl ester, lauric acid hexyl ester, laurate 2- hexyl last of the ten Heavenly stems esters and different n-nonanoic acid isononyl ester, cetyl octanoate.

Said composition can also include C₆-C₃₀, such as C₁₂-C₂₂The sugared ester and diester of aliphatic acid are as fatty acid ester.Such as exist " sugar " used in present disclosure refers to several alcohol functional groups, is with or without aldehydes or ketones functional group and with least four The oxygen containing hydrocarbon compound of carbon atom.These sugar can be monose, oligosaccharides or polysaccharide.

As suitable sugar, non-limiting examples include sucrose, glucose, galactolipin, ribose, trehalose, maltose, fruit Sugar, mannose, arabinose, xylose, lactose and their derivative, such as alkylation, the derivative such as to methylate is such as Methyl glucoside.

The ester of sugar and aliphatic acid can be with for example, selected from previously described sugared and straight chain or side chain, saturation or insatiable hunger The C of sum₆-C₃₀, such as C₁₂-C₂₂The ester of aliphatic acid or the mixture of ester.If they are undersaturated, these compounds can have There are one to three conjugation or unconjugated carbon-to-carbon double bond.

According to the ester of at least one embodiment be also selected from it is single-, two-, three-and four esters, polyester and theirs is mixed Compound.

These esters can be, such as oleate, laurate, palmitate, myristinate, behenate, coconut oil Ester, stearate, linoleate, linolenate, decylate, arachidonate, or their mixture such as oleate-palm Acid esters, oleate-stearate, the mixed ester of palmitate-stearate.

It is, for example, possible to use monoesters and diester, and the list-or two oleic acid of such as sucrose, glucose or methyl glucoside Ester, stearate, behenate, oleic acid palmitate, linoleate, linolenate, oleic acid stearate.

It can be mentioned that with non-limiting by high (Amerchol) company of liking to be beautiful with titleDO is sold Product, it is the dioleate of methyl glucoside.

The mixture of the sugared exemplary ester or ester of aliphatic acid includes：By Ke Rou De Sita companies (Crodesta) with title The product that F160, F140, F110, F90, F70, SL40 are sold, they are referred to by 73% monoesters and 27% diester and three esters respectively, By 61% monoesters and 39% diester, three esters and four esters, by 52% monoesters and 48% diester, three esters and four esters, by 45% monoesters With 55% diester, three esters and four esters, the palmitate of the sucrose formed by 39% monoesters and 61% diester, three esters and four esters- Stearate, and the monolaurate of sucrose；With title Ryoto sugar esters (such as call number B370) sell and corresponding to by The product of the behenate for the sucrose that 20% monoesters and 80%-three esters of diester-polyester are formed；By Gao Shi meter Te (Goldschmidt) company is with titleSucrose list palmitic acid-dipalmitate-stearate of PSE sale.

Available silicone includes but is not limited to volatility or non-volatile, ring-type, straight in the composition of present disclosure The silicone of chain or side chain, it has from 5 × 10 at 25 DEG C with organic group modification or unmodified^-6To 2.5m²/ s, such as from 1 × 10^-5To 1m²/ s viscosity.

The silicone according to workable for present disclosure can be the form in oil, wax, resin or glue.

In some embodiments, the silicone is selected from polydialkysiloxane, such as dimethyl silicone polymer (PDMS), and tool There is the organically-modified poly- silica of at least one functional group selected from poly- (alkoxylate) group, amine groups and alkoxy base Alkane.

Organopolysiloxane is in more detail in Walter Nore (Walter NOLL) works " silicone chemical and technology " (" Chemistry and Technology of Silicones ") (1968), in academic press (Academic Press) It is defined.They can be volatile or non-volatile.

When they are volatile, silicone is, for example, selected from those with the boiling point between 60 DEG C and 260 DEG C, With for further example, it is selected from：

With from 3 to 7, the ring-type polydialkysiloxane such as from 4 to 5 silicon atoms.It can be, for example, by joining Carbide (Union Carbide) company of conjunction is with title VOLATILE7207 or by Luo Diya (Rhodia) Company is with titleThe octamethylcy-clotetrasiloxane of 70045 V2 sale, by Union Carbide Corporation with title VOLATILE 7158 and by Rhodia with titleTen first of 70045 V5 sale Base cyclopentasiloxane, and their mixture.

Can be with the non-limiting ring for being mentioned that the dimethyl siloxane with following Formula V/methyl alkyl siloxane type Shape copolymer, the silicone such as sold by Union Carbide CorporationFZ 3109：

Further non-limiting it can be mentioned that ring-type polydialkysiloxane and the organic compound derived from silicon Mixture, such as octamethylcy-clotetrasiloxane and the mixture and prestox of four trimethyl silyl pentaerythrites (50/50) Cyclotetrasiloxane and Oxy-1, the mixture of 1 '-(six -2,2,2 ', 2 ', 3,3 '-trimethylsiloxane group) double-neopentane.

Other suitable volatile silicones are included with 2 to 9 silicon atoms and at 25 DEG C with less than or equal to 5 × 10^- ⁶m²The Linear volatile polydialkysiloxane of/s viscosity.One example is by beautiful silicone (TORAY SILICONE) company in east With the title " decamethyl tetrasiloxane that SH 200 " is sold.It is included in the silicone in this one kind also in cosmetics and toilet articles (Cosmetics and Toiletries), volume 91, January 76, the tod Baeyer this (TODD delivered in the 27-32 pages BYERS article " the volatile silicone fluid for being used for cosmetics " (" Volatile Silicone Fluids for) Cosmetics ") in be described.

Even further non-limiting it can be mentioned that non-volatile polydialkysiloxane, polydialkysiloxane Natural gum and resin, the polysiloxane with the modification of foregoing organo-functional group, and their mixture.

These silicone are, for example, polydialkysiloxane is selected from, the poly dimethyl such as with trimethylsilyl end groups Siloxanes.The viscosity of these silicone is measured at 25 DEG C according to the appendix Cs of standard ASTM 445.

In these polydialkysiloxanes, following commercial product can with exhaustive be referred to：Sold by Rhodia 47 and 70047 seriesOil orOil, such as the oil of 70 047 V 500 000；By sieve The sale of Di Ya companiesThe oil of series；The oil of 200 series from DOW CORNING (Dow Corning) company, Such as there is 60000mm²The DC200 of/s viscosity；From General Electric (General Electric) companySF serial (SF 96, SF 18) oily and from General Electric Co. Limited some oil.

There can be dimethyl-silicon with non-limiting be mentioned that so that designation Dimethicone alcohol (CTFA) is known The dimethyl silicone polymer of alkanol end group, the oil of 48 series such as from Rhodia.

In the polydialkysiloxane of this classification, it can be mentioned that with non-limiting by Gao Shi Mitt USA Corporation with title “ABIL The product of 9800 and 9801 " sale, they are poly-diakyl (C₁-C₂₀) siloxanes.

It is for example, polydialkysiloxane, such as to have 200,000 to 1,000 according to the available silicone adhesive of present disclosure, The dimethyl silicone polymer of high number-average molecular weight between 000, individually or it is used in mixed way in a solvent.This solvent can select From volatile silicone, dimethyl silicone polymer (PDMS) oil, polyphenyl methyl siloxane (PPMS) oil, isoparaffin, poly- isobutyl Alkene, dichloromethane, pentane, dodecane, tridecane and their mixture.

It is according to the available product of present disclosure, for example, mixture is such as：By hydroxylated dimethyl silicone polymer on the end of the chain, Or the X 2-1401 of dimethiconol (CTFA) and also referred to as Cyclomethicone (CTFA) is formed Mixture, the product Q21401 such as sold by Dow Corning Corporation；The mixture of dimethyl silicone polymer glue and cyclic silicone, Tathagata From the silicone fluids of product SF 1214 of General Electric Co. Limited；The product is that one kind corresponds to dimethyl silscone, has 500, 000 number-average molecular weight, the glue of SF 30 for being dissolved in the oily silicone fluids of SF 1202 (corresponding to decamethylcyclopentasiloxane)；With not With two kinds of PDMS of viscosity mixture, for example, the mixture of PDMS glue and PDMS oil, such as product from General Electric Co. Limited SF 1236.Product SF 1236 is that defined above have 20m²The glue SE 30 of/s viscosity is with having 5 × 10^-6m²/ s's The oily SF 96 of viscosity mixture.Oily SF 96 of this product for example with 15% glue SE 30 and 85%.

Include but is not limited to contain with the silica of the crosslinking of lower unit according to the available organopolysiloxane resins of present disclosure Alkane system：R₂SiO_2/2、R₃SiO_1/2、RSiO_3/2And SiO_4/2

Wherein R represents the alkyl with 1 to 16 carbon atom.For example, R represents C₁-C₄Low-grade alkyl group such as methyl.

Among these resins, can with it is non-limiting be mentioned that with title " DOW CORNING 593 " sell product or by leading to With electric corporation, with title, " those of silicone fluid SS 4230 and the sale of SS 4267 ", they are with dimethyl/trimethyl The silicone of siloxane structure.

Can be with the non-limiting resin for being mentioned that trimethylsiloxysilicate type, such as by SHIN-ETSU HANTOTAI (SHIN- ETSU) company sold with title X22-4914, X21-5034 and X21-5037 those.

According to the available organically-modified silicone of present disclosure include but is not limited to as previously defined, structure at them In have it is at least one by alkyl fix organo-functional group silicone.

In addition to silicone as described above, these organically-modified silicone can be by above-mentioned organo-functional group official The poly- diaromatic siloxane (such as polydiphenylsiloxane) of energyization and poly- alkyl-aryl-group siloxanes.

Poly- alkaryl siloxanes is, for example, be selected from has scope from 1 × 10 at 25 DEG C^-5To 5 × 10²m²It is/s viscosity, straight Poly dimethyl/methyl phenyl siloxane of chain and/or side chain, poly dimethyl/diphenyl siloxane.

In these poly- alkaryl siloxanes, the product sold with following denotations can be mentioned that with non-limiting：Come from 70641 series of RhodiaOil；From Rhodia70 633 With the oil of 763 series；Healthy and free from worry 556 COSMETIC GRADE FLUID of oil duct (Cosmetic Grade Fluid) from Dow Corning Corporation； The silicone of PK series from Bayer (Bayer) company, such as product PK20；The silicone of PN, PH series from Beyer Co., Ltd, such as Product PN1000 and PH1000；Some oil of SF series from General Electric Co. Limited, such as SF 1023, SF 1154, SF 1250、SF 1265。

Among organically-modified silicone, polysiloxane can be mentioned that with non-limiting, had：Optionally have C₆-C₂₄The polyoxyethylene and/or polyoxypropylene group of alkyl group, are such as sold by Dow Corning Corporation with title DC 1248 Entitled dimethyl silscone polyol (dimethicone copolyol) product or from Union Carbide Corporation OilL 722, L 7500, L 77, L 711 and the alkyl sold by Dow Corning Corporation with title Q25200 (C₁₂)-polymethyl siloxane polyol (methicone copolyol)；Substituted or unsubstituted amine groups, such as by Strong is to like (Genesee) company with the silicone fluids of title GP 4 and GP 7100 product sold or by Dow Corning Corporation with title The product that Q28220 and DOW CORNING 929 or 939 are sold.Substituted amine groups are, for example, C₁-C₄Aminoalkyl groups；Alcoxyl The group of base, such as by SWS silicone (SILICONES) company with title " silicone copolymer F-755 " sale product and by height Apply the ABIL of Mitt USA Corporation's sale2428th, 2434 and 2440.

For example, the fatty substances are selected from the compound for liquid or pasty state at room temperature and pressure.

For further example, the fatty substances be 25 DEG C temperature and at atmosheric pressure be liquid chemical combination Thing.

The fatty substances are, for example, being selected from lower paraffin hydrocarbon, fatty alcohol, the ester of aliphatic acid, the ester of fatty alcohol, and oils Such as non-silicone mineral oil, vegetable oil and artificial oil, including silicone.

According at least one embodiment, the fatty substances are selected from non-silicone compound such as atoleine, poly decene, fat The liquid ester and their mixture of acid and fatty alcohol.

In some embodiments, fatty substances are selected from alkane, hydro carbons and silicone.

At least one other fatty substances of the present invention can be selected from having greater than about 50mm at 40 DEG C²/ s viscosity The different fatty substances described above of fatty substances.

In some embodiments, at least one other fatty substances have about 50mm at 40 DEG C²/ s or smaller Viscosity.

A kind of preferable other fatty substances are that have about 50mm at 40 DEG C²/ s or smaller is (for example, at 40 DEG C from about 14 To about 30mm²/ s scope) viscosity and from some suppliers such as Suo Nuobang with trade name Blandol, Armedsa with commodity Name Aemoil M-302CG and ExxonMobil Chemical are with 82 commercially available mineral oil of trade name Marcol.

The amount that at least one other fatty substances of the present invention can use is the gross weight relative to color alkali composition By weight at least about 0.5%.For example, the gross weight based on color alkali composition, the amount of at least one other fatty substances can To be by weight from about 1% to about 40%, or such as by weight from about 5% to about 30%.

In other embodiments, the gross weight based on color alkali composition, the amount of at least one other fatty substances can Be by weight from 0% to about 75% or such as by weight from about 5% to about 70% or such as by weight from About 5% to about 60% or such as by weight from about 5% to about 50%.

Based on the gross weight of color alkali composition, there is greater than about 50mm at 40 DEG C²At least one aliphatic thing of/s viscosity The existing amount of matter is by weight at least about 5% or by weight from about 5% to about 80%.

Based on the gross weight of color alkali composition, there is greater than about 50mm at 40 DEG C²At least one aliphatic thing of/s viscosity The amount that matter can use be by weight from about 5% to less than about 50%, preferably by weight from about 10% to less than about 50% Scope.When using at least one other fatty substances, based on the gross weight of color alkali composition, the total amount of fatty substances is high Up to by weight less than about 50%.

In some embodiments, the gross weight based on color alkali composition, (be included in 40 DEG C has greater than about fatty substances 50mm²At least one fatty substances of/s viscosity and optionally at least a kind of other fatty substances) total amount be by weight Meter at least about 5% and can by weight from about 5% to less than about 50%, preferably by weight from about 10% to less than about 50% or such as by weight from about 10% to about 45% or such as by weight from about 10% to about 35% or all In the range of by weight from about 10% to about 30% or such as by weight from about 10% to about 20%.

Therefore, the gross weight based on color alkali composition, the amount of at least one other fatty substances can be by weight From 0% to about 45% or such as by weight from about 5% to about 40% or such as by weight from about 10% to about 30%.

In other embodiments, the gross weight based on color alkali composition, there is greater than about 50mm at 40 DEG C²/ s viscosity The amount that can also use of at least one fatty substances be by weight from about 50% to about 80%, preferably by weight from about 50% to about 70% or by weight about 50% or by weight about 60%.When there is greater than about 50mm at 40 DEG C²/s The amount of at least one fatty substances of viscosity when being by weight less than about 80%, at least one other fatty substances can be with The amount of use is so that the gross weight based on color alkali composition, and the total amount of fatty substances is no more than about 80% by weight.Therefore, Based on the gross weight of color alkali composition, (be included in 40 DEG C has greater than about 50mm to fatty substances²At least one fat of/s viscosity Race's material and optionally at least a kind of other fatty substances) total amount be by weight at least about 50% and can use Amount is by weight from about 50% to about 80%, preferably by weight from about 50% to about 70%, more preferably by weight from about In the range of 50% to about 60%.

In the preferred embodiment of the present invention, color alkali composition be in liquid emulsion or liquid-creams emulsion or The form of creams emulsion.

In the other embodiment of the present invention, the viscosity and/or amount of at least one other fatty substances are so that color Alkali composition is in liquid emulsion or the form of liquid-creams emulsion or creams emulsion.

In the particularly preferred embodiment of the present invention, there is greater than about 50mm at 40 DEG C²The aliphatic thing of/s viscosity After the amount of matter combines with the rheology modification of polymers of the present invention, at least one other fatty substances are introduced into the present invention Color alkali composition in.

The present invention's has greater than about 50mm at 40 DEG C²At least one fatty substances of/s viscosity, it is at least one in addition Fatty substances and their mixture be also present in the present invention oxidising composition in.

Rheology modification of polymers

The acrylate polymer of crosslinking of at least one rheology modification of polymers of the present invention in water-borne dispersions.

In a preferred embodiment, the acrylate polymer of the crosslinking in aqueous liquid dispersion is selected from crosslinking (first Base) acrylic acid/acrylic acid C1-C6 alkyl ester copolymers a kind of polymer and with three construction units either by comprising The monomer mixture polymerization of three kinds of polymerizable monomer components：These three polymerizable monomer components are that one or more have The carboxylic acid monomer and its salt of 3 to 10 carbon atoms, one or more vinyl monomers and one or more lists-or more insatiable hungers The monomer of sum.

Gross weight based on monomer, in one aspect, the amount of carboxylic acid monomer are generally by weight from about 20% to 80%, In another aspect by weight from about 25% to about 70%, and in yet another aspect by weight from about 35% to about 65%.

Gross weight based on monomer, in one aspect, the amount of vinyl monomer be generally by weight from about 80% to 15%th, in another aspect by weight from about 75% to about 25% and in yet another aspect by weight from about 65% to About 35%.

The three-dimensional being partially or substantially crosslinked is produced using third component (one or more lists-or how unsaturated monomer) Polymer network.Refer to that cross-linking monomer contains at least two and contains unsaturated carboxylic acid monomer and second with foregoing by how unsaturated The reactive polymerizable double bond of alkenyl monomer.

As used herein, term " (methyl) acrylic compounds " acid and " (methyl) acrylate " refer to the phase for including acrylic acid The methyl-derivatives and corresponding alkyl acrylate answered.For example, " (methyl) acrylic compounds) " acid refers to acrylic acid and/or first Base acrylic acid and " (methyl) acrylate " refers to alkyl acrylate and/or alkyl methacrylate.

Based on the gross weight of all monomer components, the amount that third component can use in one aspect is by weight from about 0.01% to about 5%, in another aspect by weight from about 0.03% to about 3%, and in yet another aspect by weight From about 0.05% to about 1%.

In a preferred embodiment, the acrylate polymer of crosslinking is micro- crosslinking.

As used herein, term " micro- crosslinking " refers to partial cross-linked Space network of polymer.

In other preferred embodiments, the acrylate polymer of crosslinking is the swellable (alkali- of alkali swellable)。

As used herein, it refers to a kind of gather when term " alkali is swellable " is related to the rheology modification of polymers of the present invention Compound, when the polymer is introduced in solution, assign little or no viscosity, but by pH adjust to faintly acid, neutrality, Or when under weak basic condition, it was observed that measurable increase of viscosity, i.e. be added to alkaline agent or nertralizer swellable containing alkali Polymer solution in cause the development of viscosity.

As used herein, term " alkali is swellable " can also refer to due to the electricity of the anionic carboxylic acid foundation group of polymer Lotus repellent polymer molecules in and when expansion.

The preferable rheology modification of polymers of the present invention be acrylic or methacrylic acid and/or it is one or more they The cross-linked copolymer of C1-C6 Arrcostabs.

The particularly preferred rheology modification of polymers of the present invention is methacrylic acid/ethyl acrylate cross-linked copolymer.

The preferable example of methacrylic acid/ethyl acrylate cross-linked copolymer of the present invention is that micro- crosslinking, alkali are solvable Swollen acrylate polymer, the polymer be as known to INCI title acrylate copolymers and from supply trade route Bo Run Company (Lubrizol) is with trade nameWater of the Aqua SF-1 as the total solid comprising by weight about 30% Property dispersion is commercially available.Aqua SF-1 have carboxyl group functional under its protonated form.This copolymerization Thing belongs to that a kind of alkali for including carboxyl-functional is swellable and the synthesis rheology modifier of the soluble thickener of alkali (AST).This A little thickener polymers are prepared by the radical polymerization individually or with other ethylenically unsaturated monomers combined from acrylic acid. These polymer can be synthesized by solvent/precipitation and emulsion polymerization technology.

Another particularly preferred rheology modification of polymers of the present invention is the anionic acrylate polymer of crosslinking.Institute The anionic acrylate polymer for stating crosslinking may be embodied in the water-borne dispersions containing by weight about 32% total solid In.The example of the anionic acrylate polymer of the crosslinking of the present invention includes but is not limited to, and is handed over by INCI titles acrylate With trade name known to linked polymer -4 and from Lubrizol Corp. of supplierAqua SF-2 are used as comprising by weight The aqueous dispersion commercially available polymer of the total solid of gauge about 32%.Acrylate crosspolymers -4 can also be described as One of acrylic acid, methacrylic acid or its copolymer of simple ester (with trimethylolpropane trimethacrylate crosslinking).

Therefore, in some embodiments, rheology modification of polymers of the invention, which is selected from, is included in containing by weight about Acrylate polymer micro- crosslinking, that alkali is swellable in the water-borne dispersions of 30% total solid.

In other embodiments, rheology modification of polymers of the invention, which is selected from, is included in containing by weight about 32% The anionic acrylate polymer of crosslinking in the water-borne dispersions of total solid.

In other embodiment again, rheology modification of polymers of the invention, which is selected to be included in, contains by weight about 30% Total solid water-borne dispersions in acrylate polymer micro- crosslinking, that alkali is swellable, included in containing by weight The anionic acrylate polymer of crosslinking in the water-borne dispersions of about 32% total solid, and their mixture.

In a preferred embodiment, the polymer is being added to this by least one rheology modification of polymers of the invention In the color alkali composition of invention before in water or in the aqueous solution use nertralizer in and.

In other preferred embodiments, at least one rheology modification of polymers of the invention adds by the polymer Neutralized during into the color alkali composition of the present invention with nertralizer.

Suitable nertralizer is selected from organic amine, organic amine salt and ammonium salt class, in particular selected from ethamine, ethylenediamine, alkanol Amine, cyclammonium and other saturations or it is undersaturated, in ring have one or more nitrogen-atoms cyclic compound.

Nertralizer be to be used with the amount of the rheology modification of polymers of the present invention in being enough in water or in the aqueous solution, so as to So that solution becomes to clarify.

The gross weight of color alkali composition based on the present invention, at least one rheology modification of polymers of the invention can use Amount be by weight from about 0.3% to about 3%, such as by weight from about 0.45% to about 2.75%, further such as by Weight meter is from about 0.5% to about 2%, or such as by weight about 2.55%, or such as by weight about 1.95%.

In a preferred embodiment, there is greater than about 50mm at 40 DEG C²At least one fatty substances of/s viscosity and At least one rheology modification of polymers, which is present in color alkali composition, causes the fatty substances and rheology modification of polymers The scope of weight rate is from about 25:1 to about 3:1, or such as from about 22.5:1 to about 5:1, or such as from about 20:1 to about 10: 1, preferably from about 15:1 to about 10:1, or such as from about 10:1 to about 5:1.

Basifier

The basifier of the present invention can be selected from organic amine, organic amine salt, ammonium salt, inorganic base and hydroxide alkalescenceization Compound.

Organic amine can be selected from 25 DEG C have be less than 12, all such as less than 10 or all such as less than 6 pKb those.Should Pay attention to, this corresponds to the pKb of most overbasic degree of functionality.

Organic amine can be selected from and include one or two primary, secondary or tertiary amine functional group, and at least one straight or branched The C with least one oh group₁-C₈The organic amine of alkyl.

Organic amine is also selected from including one to three same or different C₁-C₄The alkanolamine of hydroxyalkyl group is such as Single-, two- or three alkanolamines, ethamine, ethylenediamine, quinoline, aniline and cyclammonium, such as pyrrolin, pyrroles, pyrrolidines, imidazoles, imidazoles Alkane, imidazoline alkane (imidazolidinine), morpholine, pyridine, piperidines, pyrimidine, piperazine, triazine and their derivative.

In the compound for the alkanol amine type that can be mentioned that include but is not limited to monoethanolamine (also referred to as MEA or MEA), diethanol amine, triethanolamine, monoisopropanolamine, diisopropanolamine (DIPA), N- dimethylaminoethanols amine, 2- amino -2- first Base -1- propyl alcohol, triisopropanolamine, 2- amino-2-methyl-l, ammediol, 3- amido-1,2-propanediols, 3- dimethylaminos - 1,2- propane diols, 2-amino-2-methyl-1-propanol and three (methylol) methane.

Organic amine corresponds to formula (IV)：

Wherein, W is selected from optionally by oh group or C₁-C₆The C of alkyl group substitution₁-C₆Alkylidene residue；Rx、Ry、 Rz and Rt can be same or different, selected from hydrogen atom, C₁-C₆Alkyl group, C₁-C₆Hydroxyalkyl groups and C₁-C₆ Aminoalkyl groups.

It can be mentioned that the example of such amine include but is not limited to：1,3- diaminopropanes, 1,3- diaminourea -2- propyl alcohol, Spermine and spermidine.

In some embodiments, organic amine is selected from amino acid.

As non-limiting examples, the amino acid that can be used can be natural or synthetic source, in L, D or disappear Rotation form, and be selected from including at least one acid functional group, the acid functional group, for example, carboxylic acid, sulfonic acid, phosphonic acids and phosphoric acid official Can group.These amino acid can be in their neutrality or ionic species.

Non-limiting examples are further used as, these amino acid, which can be selected to contain, is optionally comprised in ring or urea groups official The basic amino acid of other amine functional group in rolling into a ball.

Such basic amino acid can be selected from those corresponding to following formula (A)：

Wherein R is to be selected from following group：

Histidine, lysine, arginine, ornithine and citrulling can be selected from corresponding to the compound of formula (A).

The amino acid that can be used in present disclosure includes but is not limited to：Aspartic acid, glutamic acid, alanine, arginine, Ornithine, citrulling, asparagine, carnitine, cysteine, glutamine, glycine, histidine, lysine, isoleucine, Leucine, methionine, N- phenylalanines, proline, serine, taurine, threonine, tryptophan, tyrosine and figured silk fabrics ammonia Acid.

In some embodiments, organic amine is selected from basic amino acid.These amino acid can be selected from, for example, arginine, Lysine and histidine, or their mixture.

In some embodiments, organic amine is selected from the organic amine of heterocyclic type.Except what is referred in amino acid Outside histidine, pyridine, piperidines, imidazoles, 1,2,4- triazoles, tetrazolium and benzimidazole can be mentioned that with non-limiting.

In some embodiments, organic amine is selected from amino acid dipeptide.The amino acid dipeptide that can be used in present disclosure Including but not limited to：Carnosine, anserine and whale carnosine (baleine).

In some embodiments, organic amine is selected from the compound for including guanidine functional group.Except having been carried as amino acid And arginine outside, the such organic amine that can be used in present disclosure includes creatine, kreatinin, 1,1- dimethyl Guanidine, 1,1- diethyl guanidine, glycocyamine, melbine, gamatine, N- guanylalanines, 3- guanidinopropionic acids, 4- guanidine radicals fourths Acid and 2- ([amino (imino group) methyl] amino) ethane -1- sulfonic acid.

As non-limiting examples, organic amine is selected from alkanolamine.For example, organic amine is selected from monoethanolamine, triethanolamine, 2- ammonia Base -2- methyl isophthalic acids-propyl alcohol, or 2-amino-2-methyl-1-propanol and monoethanolamine are preferably selected from, or their mixture.Enter one Step is used as an example, and organic amine is monoethanolamine.

Basifier can be the organic amine in salt form.As used herein, term " organic amine salt " refers to as described above Organic amine organic or inorganic salt.

As a non-limiting examples, organic salt can be selected from the salt of organic acid, such as citrate, lactate, ethanol Hydrochlorate, gluconate, acetate, propionate, fumarate, oxalates and tartrate.

A non-limiting examples are further used as, inorganic salts can be selected from hydrohalide (such as hydrochloride), carbonic acid Salt, bicarbonate, sulfate, hydrophosphate and phosphate.

The ammonium salt that can be used according to present disclosure can be selected from following sour salt：Carbonate, bicarbonate.For example, the salt It is carbonate, such as ammonium carbonate.

The inorganic base that can be used can be selected from alkali metal phosphate and carbonate, for example, such as sodium phosphate, potassium phosphate, carbon Sour sodium, sodium acid carbonate, potassium carbonate, saleratus and their derivative.

Inorganic base can also include alkali metal carboxylate, for example, such as sodium acetate, potassium acetate, sodium citrate and citric acid Potassium, and their derivative.

Hydroxide alkalescence compound can be selected from alkali metal hydroxide, alkaline earth metal hydroxide, transition metal hydrogen Oxide, quaternary ammonium hydroxide, organic hydroxide and their mixture.Suitable example is ammonium hydroxide, hydroxide Sodium, potassium hydroxide, lithium hydroxide, rubidium hydroxide, cesium hydroxide, hydroxide francium, beryllium hydroxide, magnesium hydroxide, calcium hydroxide, hydrogen Strontium oxide strontia, barium hydroxide, molybdenum hydroxide, manganous hydroxide, zinc hydroxide, cobalt hydroxide, cadmium hydroxide, cerium hydroxide, hydroxide Lanthanum, actinium hydroxide, thorium dioxide, aluminium hydroxide, hydroxide guanidine and their mixture.

According at least one embodiment, basifier is selected from alkali carbonate, alkali metal phosphate, organic amine, hydrogen-oxygen Compound alkali compounds and their derivative.

According at least another embodiment, basifier is selected from for example at least one alkanolamine of at least one organic amine.Especially Preferable alkanolamine is monoethanolamine (also referred to as MEA or MEA).

Based on the present invention color alkali composition gross weight, the amount that at least one basifier of the invention can use be by Weight meter is from about 0.01% to about 30%, such as by weight from about 0.1% to about 20%, and further such as by weight From about 0.5% to about 10%, or such as by weight from about 1% to about 10%.

In some embodiments, make in the procedure of manufacture color alkali composition before or after polymer is added With in the basifier of part and at least one rheology modification of polymers.

According at least one embodiment, the composition or reagent of the color of the keratin fiber for changing the present invention contain There is a small amount of ammonia, or substantially free of ammonia.

Short-chain hydroxyl compound

At least one short alkyl chain hydroxy compounds of monohydric alcohol and polyalcohol selected from the present invention includes but is not limited to, second Alcohol (alcohol of denaturation), propyl alcohol, ethylene glycol, propane diols (propylene glycol), butanediol, hexylene glycol, propane diol (propane diol), glycerine and their mixture.

As used herein, term " short alkyl chain " is referred to the alkyl chain from 1 to 10 carbon atom.

Therefore, at least one short alkyl chain hydroxy compounds is selected from low-grade monobasic alcohol, such as contains from about 1 to 5 carbon atom Those, such as ethanol and isopropanol；Polyalcohol, including glycol, as containing from about 2 to 8 carbon atoms, such as the third two Alcohol, ethylene glycol, 1,3 butylene glycol, DPG, butanediol, hexylene glycol, pungent glycol and glycerine.

Other suitable short alkyl chain hydroxy compounds for being selected from monohydric alcohol and polyalcohol can be volatile or non-wave The compound of hair property.

The gross weight of color alkali composition based on the present invention, at least one short alkyl chain hydroxyl selected from monohydric alcohol and polyalcohol Based compound according to the amount that can use of the present invention be scope by weight from about 0.5% to about 15%, such as by weight from About 1% to about 12%, either such as by weight from about 3% to about 10% or such as by weight from about 5% to about 10%.

Oxidation dye precursors

Typically, oxidation dye precursors are selected from o- or p-phenylenediamine, o- or para-aminophenol and heterocyclic compound.This A little oxidation bases are the compounds of colourless or weak coloring, allow to obtain by oxidative condensation process when combining with oxygenated products The species that must be coloured.

Only by way of example, the useful oxidation dye precursors of present disclosure include aromatic diamines, polyhydroxy phenols, amino The derivative of phenols and these compounds, for example, such as the derivative that the N- of amine substitutes, and the ethers of phenols.

By non-limiting examples, oxidation dye precursors can be selected from o- or para-aminophenol, o- or p-phenylenediamine class, Double alkali (double bases), heterocyclic bases and their acid-addition salts.

The exemplary p-phenylenediamine class that can be selected includes compound with logical formula (IV) and their additions with acid Salt：

Wherein, in formula (IV)：

- R8 expression hydrogen atoms, C1-C4 alkyl groups, C1-C4 monohydroxyl alkyl radicals, C2-C4 polyhydroxyalkyl groups, (C1-C4) alkoxy (C1-C4) alkyl group, the C1-C4 alkyl substituted by nitrogen-containing group, phenyl group or 4 '-aminophenyl Group；

- R9 represent hydrogen atom, C1-C4 alkyl groups, C1-C4 monohydroxyl alkyl radicals, C2-C4 polyhydroxyalkyl groups, (C1-C4) alkoxy (C1-C4) alkyl group or the C1-C4 alkyl groups substituted by nitrogen-containing group；

- R8 and R9 can also be formed optionally by one or more alkyl, hydroxyl or urea groups with carrying their nitrogen-atoms 5 yuan or 6 member heterocyclic ring containing nitrogens of group substitution；

- R10 represents hydrogen atom, halogen atom (such as chlorine atom), C1-C4 alkyl groups, sulfo group, carboxylic group, C1- C4 monohydroxyl alkyl radicals, C1-C4 hydroxy alkoxy bases group, C1-C4 acetyl-aminos alkoxy base, C1-C4 mesyls Aminoalkoxy groups or C1-C4 carbamoylamino alkoxy bases；And

- R11 represents hydrogen atom, halogen atom or C1-C4 alkyl groups.

By way of example, in the nitrogen-containing group in above-mentioned formula (IV), amino, single (C1-C4) alkyl amino, two can be selected (C1-C4) alkyl amino, three (C1-C4) alkyl aminos, monohydroxy (C1-C4) alkyl amino, imidazolinyl and ammonium base Group.The exemplary p-phenylenediamine class of above-mentioned formula (XXIII) includes p-phenylenediamine, to toluenediamine, the chloro- p-phenylenediamine of 2-, 2,3- Dimethyl-p-phenylenediamine, 2,6- dimethyl-p-phenylenediamine, 2,6- diethyl-p-phenylenediamines, 2,5- dimethyl-p-phenylenediamine, N, N- dimethyl-p-phenylenediamine, N, N- diethyl-p-phenylenediamines, N, N- dipropyl-p-phenylenediamine, 4- amino-N, N- diethyl Base -3- methylanilines, N, N- couples of (beta-hydroxyethyl)-p-phenylenediamine, 4-N, double (beta-hydroxyethyl) the amino-2-methyl aniline of N-, 4- Double (beta-hydroxyethyl) amino -2- chloroanilines of N, N-, 2- (beta-hydroxyethyl)-p-phenylenediamine, the fluoro- p-phenylenediamine of 2-, 2- isopropyls-right Phenylenediamine, N- (β-hydroxypropyl)-p-phenylenediamine, 2- methylols-p-phenylenediamine, N, N- dimethyl-Beta-methyl-p-phenylenediamine, N- Ethyl-N- (beta-hydroxyethyl)-p-phenylenediamine, N- (β, γ-dihydroxypropyl)-p-phenylenediamine, N- (4 '-aminophenyl)-to benzene Diamines, N- phenyl-pphenylenediamines, 2- (beta-hydroxy ethyoxyl)-p-phenylenediamine, 2- ((β-acetylamino ethyoxyl)-to benzene two Amine, N- ('beta '-methoxy ethyl)-p-phenylenediamine, 2- methyl isophthalic acids-N- (beta-hydroxyethyl)-p-phenylenediamine and they with acid addition Salt.

Exemplary o-phenylenediamine class include N1- (2- ethoxys) -4- nitros-o-phenylenediamine, 4- methyl-o-phenylenediamine and 4- nitros-o-phenylenediamine and their acid-addition salts.

As used herein, term " double alkali " refers to the compound for including at least two aromatic protons, the aromatic proton has amino With it is at least one in hydroxyl.For example, double alkali can be selected from formula (V) compound and they with acid addition salts：

Wherein, in formula (V)：

- Z1 and Z2 can independently selected from can by C1-C4 alkyl groups or linking arm the Y hydroxyl substituted or -- NH2 bases Group；

- linking arm Y is selected from containing the alkylidene chain from the straight or branched of 1 to 14 carbon atom, its can by one or Multiple nitrogen-containing groups and/or one or more hetero atoms such as oxygen, sulphur or nitrogen-atoms interrupt or end-blocking, and optionally by one or Multiple hydroxyl or C1-C6 alkoxy base substitutions；

- R12 and R13 is independently selected from hydrogen or halogen atom, C1-C4 alkyl groups, C1-C4 monohydroxyl alkyl radicals, C2- C4 polyhydroxyalkyl groups, C1-C4 aminoalkyl groups or linking arm Y；

- R14, R15, R16, R17, R18 and R19 are independently selected from hydrogen atom, linking arm Y or C1-C4 alkyl group；

Wherein the compound per molecule of formula (V) only includes single linking arm Y.

In various embodiments, the nitrogen-containing group of above-mentioned formula (V) can be selected from amino, single (C1-C4) alkyl amino, Two (C1-C4) alkyl aminos, three (C1-C4) alkyl aminos, monohydroxy (C1-C4) alkyl amino, imidazolinyl and ammonium Group.

The non-limiting examples of double alkali include N, N '-bis- (beta-hydroxyethyl)-N, N '-bis- (4 '-aminophenyls) -1,3- diaminos Base-propyl alcohol, N, N '-bis- (beta-hydroxyethyl)-N, N '-bis- (4 '-aminophenyls) ethylenediamine, N, N '-bis- (beta-amino phenyl)-four are sub- Methanediamine, N, N '-bis- (4- ethoxys)-N, N '-bis- (4- aminophenyls) tetra-methylenedimine, N, N '-bis- (4- methylaminos Phenyl) tetra-methylenedimine, N, N '-diethyl-N, N '-bis- (4 '-amino -3 '-aminomethyl phenyl) ethylenediamine, the double (2,5- of 1,8- Diaminourea-phenoxy group) -3,5- dioxaoctanes, and their addition salts with acid.

The non-limiting examples for the para-aminophenol that can be used in the context of the present invention can be in particular selected from corresponding In the compound of lower formula (VI) and they with acid addition salts：

Wherein, in formula (VI)：

- R20 is selected from hydrogen atom, halogen atom such as fluorine, C1-C4 alkyl groups, C1-C4 monohydroxyl alkyl radicals, (C1-C4) Alkoxy (C1-C4) alkyl group, C1-C4 aminoalkyl groups or hydroxyl (C1-C4) alkyl amino-(C1-C4) alkyl group, And

- R21 is more selected from hydrogen atom, halogen atom such as fluorine, C1-C4 alkyl groups, C1-C4 monohydroxyl alkyl radicals, C2-C4 Hydroxyalkyl groups, C1-C4 aminoalkyl groups, C1-C4 cyanoalkyl groups or (C1-C4) alkoxy (C1-C4) alkyl base Group.

Only by way of example, para-aminophenol, 4- amino -3- methylphenols, 4- amino -3- fluorophenols, 4- ammonia can be selected Base -3- hydroxymethylphenols, 4- amino-2-methyls phenol, 4- amino -2- hydroxymethylphenols, 4- amino -2- methoxy benzene Phenol, 4- amino -2- amino methyls phenol, 4- amino -2- (beta-hydroxyethyl amino methyl) phenol, N- methyl-para-aminophenol, with And their acid-addition salts.

Exemplary o-aminophenol class can be selected from Ortho-Aminophenol, 2- amino -1- hydroxy-5-methyl bases benzene, 2- amino -1- Hydroxyl -6- methylbenzenes, 5- acetamidos-Ortho-Aminophenol and their acid-addition salts.

Exemplary heterocyclic alkali can be selected from pyridine derivate, pyrimidine derivatives, pyrazole derivatives, pyrazolone derivative, And their acid-addition salts.

The non-limiting examples of pyridine derivate include, for example, (both is by drawing in GB1026978 and GB1153196 Those disclosed in combination herein), such as 2,5- diamino-pyridines, 2- (4- methoxyphenyls) amino -3- aminopyridines, 2,3- Diaminourea -6- methoxypyridines, 2- ('beta '-methoxy ethyl) amino -3- amino -6- methoxypyridines, 3,4- diaminourea-pyridine, And their acid-addition salts.

The non-limiting examples of pyrimidine derivatives include, for example, in DE 2 359 399, JP 88-169571, JP 91- Those described in 10659 and WO 96/15765 (all to be incorporated herein by reference), such as 2,4,5,6- tetra--aminopyrimidines, 4- Hydroxyl -2,5,6- Triaminopyrimidines, 2- hydroxyls -4,5,6- triamidos-pyrimidine, 2,4- dihydroxy -5,6- di-amino-pyrimidines, 2,5, 6- Triaminopyrimidines, and Pyrazolopyrimidine derivative, as referred in french application FR-A-2750048 and Wherein it is mentioned that pyrazolo [1,5-a] pyrimidine -3,7- diamines；2,5- dimethyl pyrazoles [1,5-a] pyrimidine -3,7- two Amine；Pyrazolo [1,5-a] pyrimidine -3,5- diamines；2,7- dimethyl pyrazoles [1,5-a] pyrimidine -3,5- diamines；3- amino-pyrazols And [1,5-a] pyrimidin-7-ol；3- amino-pyrazols simultaneously [1,5-a] pyrimidine -5- alcohol；2- (3- amino-pyrazols simultaneously [1,5-a] pyrimidine -7- Base amino) ethanol；2- (7- amino-pyrazols simultaneously [1,5-a] pyrimidin-3-yl amino) ethanol；[(3- amino-pyrazols are simultaneously [1,5-a] by 2- Pyrimidin-7-yl) (2- hydroxyethyls) amino] ethanol；2- [(7- amino-pyrazols simultaneously [1,5-a] pyrimidin-3-yl) (2- hydroxyethyls) Amino] ethanol；5,6- Dimethyl-pyrazols simultaneously [1,5-a] pyrimidine -3,7- diamines；2,6- dimethyl pyrazoles [1,5-a] pyrimidine- 3,7- diamines；2,5, N7, N7- tetramethyl pyrazolo [1,5-a] pyrimidine -3,7- diamines；3- amino -5- methyl -7- (imidazole radicals third Base amino) pyrazolo [1,5-a] pyrimidine；And their addition salts and their tautomerism when tautomeric equilibrium be present Body form, and their addition salts with acid.

The non-limiting examples of pyrazoles and pyrazolone derivative are included in DE 3,843,892, DE 4,133,957, WO 94/08969th, WO 94/08970, FR-A-2,733,749 and DE 195 43 988 are (all these to be hereby incorporated by reference This) described in compound, such as 4,5- diaminostilbenes-methyl pyrazole, 3,4- diamino-pyrazoles, 4,5- diaminostilbenes-(4 '-chlorine Benzyl) pyrazoles, 4,5- diaminostilbenes, 3- dimethyl pyrazoles, 4,5- diaminourea -3- methyl isophthalic acids-Phenylpyrazole, 4,5- diaminourea - 1- methyl -3- Phenylpyrazoles, 4- amino -1,3- dimethyl -5- callosity bases pyrazoles, 1- benzyl -4,5- diaminourea -3- methylpyrazoles, 4,5- diaminourea -3- the tert-butyl group -1- methylpyrazoles, the 4,5- diaminostilbenes-tert-butyl group -3- methylpyrazoles, 4,5- diaminostilbenes - (beta-hydroxyethyl) -3- methylpyrazoles, 4,5- diaminostilbenes-(beta-hydroxyethyl) pyrazoles, 4,5- diaminostilbenes-ethyl -3- methyl pyrroles Azoles, 4,5- diaminostilbenes-ethyl -3- (4 '-methoxyphenyl) pyrazoles, 4,5- diaminostilbenes-ethyl -3- methylols pyrazoles, 4, 5- diaminourea -3- methylol -1- methylpyrazoles, 4,5- diaminourea -3- methylol -1- isopropylpyrazols, 4,5- diaminourea -3- first Base -1- isopropylpyrazols, 4- amino -5- (2 '-amino-ethyl) amino -1,3- Dimethyl-pyrazols, 3,4,5- triamidos pyrazoles, 1- methyl -3,4,5- triamidos pyrazoles, 3,5- diaminostilbenes-methyl -4- methylaminos pyrazoles, 3,5- diaminourea -4- are (to hydroxyl second Base) amino -1- methylpyrazoles, 2- (4,5- diaminostilbene H- pyrazol-1-yls), H2SO4,2,3- diaminourea -6,7- dihydro -1H, 5H- pyrazolos [1,2-z] pyrazoles -1- ketone, 1- methyl -3- phenyl -2- pyrazolones and their acid-addition salts.

Based on the gross weight of the color alkali composition, at least one oxidation dye precursors can in the color alkali composition of present disclosure It is for example to be by weight in scope from about 0.0001% to about 12% with existing amount, such as from about 0.0001% to about 8.0%, Or from about 0.005% to about 5%.

In addition, one or more oxidation dye precursors of present disclosure can use with one or more color former combinations.

By the way that oxidation dye precursors and one or more color former combinations are often changed into the color obtained with them very much Adjust, colour coupler is in particular selected from diamines, m-aminophenol, Resorcino and some heterocyclic compounds such as indoles chemical combination between aromatic series Thing.

Different kinds of molecules for oxidation base and colour coupler allows to obtain abundant color.

The colour coupler that can be used in present disclosure, which is included in the method for oxidation of keratin fibre staining, routinely to be used Those, for example, m-aminophenyl phenols, m-phenylene diamine (MPD) class and a diphenols, aphthols, list-or polyhydroxylated naphthalene derivatives, With heterocyclic coupler agent, for example, such as indole derivatives, indolin derivatives, sesamol and its derivative, pyridine derivate, pyrrole Azoles and triazole derivative, pyrazoline ketone, indazole class, benzimidazole, benzothiazoles, Benzooxazole kind, 1,3- benzos two Luxuriant class (1,3-benzodioxoles), quinolines, Benzomorpholine derivatives, pyrazoloazole coupler (pyrazoloazole) derivative, Pyrrolo- Zole derivatives, imidazo Zole derivatives, Pyrazolopyrimidine derivative, pyrazoline -3,5- derovatives, pyrrolo- [3,2-d] oxazole derivatives, pyrazolo [3,4-d] thiazole, thiazole and azoles S- oxide derivatives, thiazole and azoles S, S- Dioxide derivative, and their acid-addition salts.

Suitable colour coupler includes, for example, those with formula (D)：

Wherein, R₁It is unsubstituted hydroxyl or amino or by one or more C_1-6Hydroxyalkyl groups substitution hydroxyl or Amino, R₃And R₅It is each independently hydrogen, hydroxyl, amino or by C_1-6Alkyl, C_1-6Alkoxy or C_1-6Hydroxyalkyl groups take The amino in generation；And R₂、R₄And R₆It is each independently hydrogen, C_1-6Alkoxy, C_1-6Hydroxy alkyl or C_1-6Alkyl, or R₃ And R₄Methylene-dioxy or ethylen-dioxy groups can be formed together.The example of such compound includes meta-derivative, such as Phenols, meta-aminophenol class, m-phenylene diamine (MPD) class etc., it can be unsubstituted, or with alkyl, hydroxyl on amino group or phenyl ring Base alkyl, alkyl amino etc. are substituted.Suitable colour coupler includes m-aminophenol, 2,4 di amino toluene, 4- amino, 2- hydroxyls Base toluene, Phenyl Methyl Pyrazolone 98Min, 3,4- methylenedioxyphenols, 3,4- methylene-dioxies -1- [(beta-hydroxyethyl) amino] Benzene, 1- methoxyl group -2- amino -4- [(beta-hydroxyethyl) amino] benzene, 1- hydroxyls -3- (dimethylamino) benzene, 6- methyl isophthalic acids-hydroxyl Base -3 [(beta-hydroxyethyl) amino] benzene, the chloro- 1- hydroxyls -3- aminobenzenes of 2,4- bis-, 1- hydroxyls -3- (diethylamino) benzene, 1- hydroxyls Base -2- methyl -3- aminobenzenes, the chloro- 6- methyl isophthalic acids of 2--hydroxyl -3- aminobenzenes, 1,3- diaminobenzenes, 6- methoxyl group -1,3- diaminos Base benzene, 6- hydroxyl-oxethyl -1,3- diaminobenzenes, 6- methoxyl group -5- ethyl -1,3- diaminobenzenes, 6- ethyoxyl -1,3- diaminos Double (beta-hydroxyethyl) amino -3- aminobenzenes of base benzene, 1-, 2- methyl isophthalic acids, 3- diaminobenzenes, 6- methoxyl group -1- amino -3- [(β-hydroxyl Ethyl) amino]-benzene, 6- (beta-amino ethyoxyl) -1,3- diaminobenzenes, 6- (beta-hydroxy ethyoxyl) -1- amino -3- (methyl ammonia Base) benzene, 6- Carboxvmethoxv -1,3- diaminobenzenes, double (beta-hydroxyethyl) amino -3- aminobenzenes of 6- ethyoxyls -1-, 6- hydroxyl second Base -1,3- diaminobenzenes, 1- hydroxyl -2- isopropyl -5- methylbenzenes, 1,3- dihydroxy benzenes, the chloro- 1,3- dihydroxy benzenes of 2-, 2- first The chloro- 1,3- dihydroxy benzenes of base -1,3- dihydroxy benzenes, 4-, the chloro- 2- methyl isophthalic acids of 5,6- bis-, 3- dihydroxy benzenes, 1- hydroxyl -3- amino - Benzene, 1- hydroxyls -3- (carbamo, lmethyl amino) benzene, 6- hydroxy benzos morpholine, 4- methyl -2,6- dihydroxy-pyridines, 2,6- Dihydroxy-pyridine, 2,6- diamino-pyridines, 6- amino benzos morpholine, 1-phenyl-3-methyl-5-pyrazolones ketone, 1- hydroxyl naphthalenes, 1, 7- dihydroxy naphthlenes, 1,5- dihydroxy naphthlenes, 5- amino-2-methyls phenol, 4- oxyindoles, 4- hydroxyls indoline, 6- hydroxyls Yin Diindyl, 6- hydroxyls indoline, 2,4- diaminourea (amion) phenoxetol, and their mixture.

Other colour couplers can be selected from, for example, 2,4- diaminostilbenes-(beta-hydroxy ethyoxyl) benzene, 2- methyl -5- aminobenzenes Phenol, 5-N- (beta-hydroxyethyl) amino-2-methyls phenol, 3- amino-phenols, 1,3- dihydroxy benzenes, 1,3- dihydroxy -2- methylbenzenes, The chloro- 1,3- dihydroxy benzenes of 4-, 2,4- diaminourea 1- (beta-hydroxy ethyoxyl) benzene, 2- amino -4- (beta-hydroxy ethylamino) -1- first Epoxide benzene, 1,3- diaminobenzenes, 1,3- double (2,4- diamino phenoxies) propane, sesamol, 1- amino -2- methoxyl groups -4,5- Methylenedioxybenzenes, alpha-Naphthol, 6- oxyindoles, 4- oxyindoles, 4- hydroxy-N-methvls indoles, 6- hydroxyls indoline, 2, 6- dihydroxy -4- picolines, 1H-3- methylpyrazole -5- ketone, 1- phenyl -3- methylpyrazole -5- ketone, 2- amino -3- hydroxyl pyrroles Pyridine, 3,6- dimethyl pyrazoles [3,2-c] -1,2,4- triazoles, 2,6- dimethyl pyrazoles [l, 5-b]-l, 2,4- triazole, 6- first Base pyrazolo [l, 5-a]-benzimidazole, and their acid-addition salts.

In one embodiment, colour coupler includes resorcinol, 1- naphthols, 2- methylresorcinols, 4- amino -2- hydroxyls Base toluene, m-aminophenol, 2,4- diamino phenoxies ethanol, Phenyl Methyl Pyrazolone 98Min, hydroxy benzo morpholine, 2- methyl- 5- hydroxyethyls (etyyl) amino-phenol, 6- oxyindoles, 2- amino -3- pyridones, the chloro- orthoresols of 5- amino -6-, 4- Chloro resorcinol, their salt and their mixture.

When exist these colour couplers when, based on the gross weight of color alkali composition, the amount scope that they may have be by Weight meter is from about 0.0001% to about 12%；Or by weight from about 0.1% to about 8%；Or from about 1% to about 5%.

Generally, the acid-addition salts of alkali oxide and colour coupler can be selected from hydrochloride, hydrobromate, sulfate, tartrate, Lactate and acetate.

The color alkali composition of the present invention can further include at least one direct dyes, the direct dyes can include but It is not limited to, nitro dye, azo direct dye, methane direct dyes and their addition salts of benzene-series.These directly contaminate Material can have the feature of nonionic, anion or cation.

Oxidant

Reagent requirement for the color for the keratin fiber for changing the present invention includes the oxidation group of at least one oxidant Compound, the oxidant can be selected from, for example, peroxide, persulfate, perborate, percarbonate, alkali metal bromate, The iron cyanide or their mixture.The oxidant that can also be used includes at least one oxidoreducing enzyme such as laccase (laccase), peroxidase and 2- electron redox enzyme (such as uricase), when appropriate in their own donor or In the presence of co-factor.The oxygen in air can also be used as oxidant.

In one embodiment, oxidant is selected from hydrogen peroxide, urea peroxide, alkali metal bromate, the iron cyanide, mistake Saline oxide, perborate, percarbonate, laccase, peroxidase, oxidoreducing enzyme and their mixture.

In one embodiment, oxidant is the hydrogen peroxide being present in the aqueous solution, and its titer can be with scope From 1 to 40 volume, such as from 5 to 40 volumes or such as from 5 to 20 volumes.

In another embodiment, oxidant is persulfate and/or single persulfate, for example, such as potassium peroxydisulfate, mistake Sodium sulphate, ammonium persulfate and their mixture.In one embodiment, the oxidant in present disclosure is selected from peroxide Change hydrogen, potassium peroxydisulfate, sodium peroxydisulfate and their mixture.

Generally, the gross weight based on oxidising composition, oxidant there will be amount be by weight from about 0.05% to About 50%, such as by weight from about 0.1% to about 30% or such as by weight from about 0.1% to about 20% or all As by weight from about 1% to about 12%.

The acceptable medium of cosmetics

The composition of the present invention may include other compounds for forming the acceptable medium of the cosmetics.This cosmetics can The medium of receiving includes the mixture of water or water and the acceptable organic solvent of at least one cosmetics.

As the example of organic solvent, can with it is non-limiting be mentioned that alcohols such as ethanol, isopropanol, benzylalcohol and Benzyl carbinol, or glycols or glycol ethers (such as the monomethyl of ethylene glycol, propane diols, single ethyl and monobutyl ethers) or Alkyl ether (the example of its ethers (such as monomethyl ether of propane diols, butanediol, hexylene glycol, DPG) and diethylene glycol Such as the single ethylether or single-butyl ether of diethylene glycol).

pH

The pH of color alkali composition be greater than 7 and can be with scope from more than 7 to about 12, or from more than 7 to about 11, it is or all Such as from about 7.5 to about 12, or such as from about 7.5 to about 11, or such as from about 7.5 to about 10 or such as from about 7.5 to about 9, or Such as about 9 to about 11, and it can use well-known acidulant or basifier in the colouring art of keratin fiber Adjust desired value.

The reagent of color for changing keratin fiber (that is, is blended in one from by color alkali composition and oxidising composition Act obtained composition) pH can be with scope from about 2 to about 14, such as from about 2 to about 12, or such as about 4 to about 12, or all Such as from about 4 to about 11.

In some embodiments, the pH for the reagent for the color for changing keratin fiber can be less than 7, such as from about 2 to 6.8, or such as from about 2 to about 6.5, or such as from about 4 to about 6.0.In other embodiments, for changing keratin The pH of the reagent of the color of fiber can be higher than 7, such as from about 7.1 to about 12, or such as from about 7.5 to about 11, or such as from About 7.5 to about 10, or such as from about 9 to about 11, or such as from about 10 to about 11.

The color alkali composition of present disclosure is preferably at the form of emulsion, for example, oil-in-water emulsion and water-in-oil emulsion.

In particularly preferred embodiments, the color alkali composition of present disclosure is preferably at the shape of oil-in-water emulsion Formula.

The color alkali and oxidising composition of the present invention can further include at least one auxiliary agent.Auxiliary agent can include, but unlimited In thickener and with those described above (such as withAqua SF-1 and Aqua SF-2 It is commercially available those) different rheology modification of polymers, cationic polymer, film forming polymer, pigment, dyestuff, wetting agent and NMF, emulsifying agent (from fall into above-mentioned fatty substances those are different), structural agent, propellant, surfactant, gloss Agent and conditioner.

Thickener and with above-mentioned rheology modification of polymers (such as withAqua SF-1 and Aqua SF-2 it is commercially available those) different rheology modification of polymers can be further comprising the present invention composition and can , as described in US2010154140A, to be tied selected from polymeric viscosifier and non-polymeric thickener with its full text by quoting Close herein.

The thickener of the present invention can be selected from polymeric viscosifier and non-polymeric thickener.At least one polymeric viscosifier can be with Selected from ionic or nonionic, associativity or non-associative polymer.Exemplary polymeric viscosifier includes different primary glue. Representational non-polymeric thickener includes mineral salt such as sodium chloride；The ethyoxyl of the molecule of oxyethylation and especially polyalcohol The alkyl or acyl derivative of change.These polymer can be physically or chemically modified.

The gross weight of first or oxidising composition based on the present invention, what at least one thickener of the invention preferably used Amount be by weight from more than 0% to about 15%, preferably by weight from about 0.1% to about 10%, and more preferably by weight Count from about 1% to about 5%.

At least one cationic polymer can also be included according to the color alkali of the present invention and oxidising composition.

In at least one embodiment, it is included at least one of composition of present disclosure cationic polymer and does not select From cationic associative polymer.In other words, these cationic polymers do not include in their structure and contained from 10 To the side of 30 carbon atoms or end hydrophobic chain, such as alkyl or alkenyl type.

It can be selected from according at least one cationic polymer of the composition of present disclosure, such as：

(1) homopolymerization species and copolymer analog, their derived from propylene acid or methacrylate or acid amides and comprising extremely Few one is selected from the unit with formula (VI), (VII), (VIII) and (IX)：

Wherein：

R₃, can be same or different, represent hydrogen atom or CH₃Group；

It A, can be same or different, represent the C of straight or branched₁-C₆And for example, C₂-C₃Alkyl group or C₁-C₄Hydroxyalkyl group；

R₄、R₅And R₆, can be same or different, represent a C₁-C₁₈Alkyl group or benzyl group, such as C₁- C₆Alkyl group；

R₁And R₂, can be same or different, represent hydrogen or C₁-C₆Alkyl group, such as methyl or ethyl；

X^-Expression is derived from inorganic or organic acid anion, such as methyl-sulfuric acid root anion or halogen ion such as chlorion or bromine Ion.

The polymer of this family can also include at least one unit derived from least one comonomer, comonomer The family of the following can be selected from：Acrylamide, Methacrylamide, diacetone acrylamide, on nitrogen by rudimentary (C₁- C₄) AAM and Methacrylamide, acrylic or methacrylic acid or its ester, vinyl lactam such as second Vinyl pyrrolidone or caprolactam, and vinyl esters.

Therefore, among the polymer of this family, can be mentioned that with exemplary：

With dimethyl suflfate or with dimethyl halide quaternized acrylamide copolymer and acrylate Methacrylate copolymers, the product such as sold by Hercules (Hercules) company with title HERCOFLOC,

The copolymer of acrylamide and MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, for example, described in EP 80 976 And sold with title BINA QUAT P 100 by vapour Ba-Jia Ji (Ciba Geigy) companies,

The copolymer of acrylamide and methylacryoyloxyethyl front three ammonium methyl sulphate, by Hercules company with name Claim what RETEN was sold,

Quaternized or on-quaternised vinyl pyrrolidone/propenoic acid dialkyl aminoalkyl ester or acrylate are total to Polymers, the product such as sold by American International Specialty Products Company (ISP) with title GAFQUAT, such as GAFQUAT 734 or GAFQUAT 755, or the product of copolymer 845,958 and 937 is alternatively referred to as,

Acrylate/caprolactam/vinyl pyrrolidone trimer, it is such as international by the U.S. The product that Te Pin companies are sold with title GAFFIX VC 713,

Vinyl pyrrolidone/methacryiamidopropyl dimethylamine copolymer, for example, by American International Specialty Products Company Sold with title STYLEZE CC 10,

Quaternized vinyl pyrrolidone/dimethylaminopropyl methacrylamide copolymer, it is such as international by the U.S. The product that Te Pin companies are sold with title GAFQUAT HS 100, and methacryloxy (C₁-C₄) three (C of alkyl₁-C₄) The cross-linked polymer of alkylammonium salt, the polymer such as obtained in the following manner：With the quaternized acrylic acid dimethyl of chloromethanes The homopolymerization of amino ethyl ester, or acrylamide and anti-with the copolymerization of the quaternized acrylate of chloromethanes Should, it is and a kind of compound (such as methylene bisacrylamide containing ethylenic degree of unsaturation after the homopolymerization or copolyreaction Acid amides) crosslinking.In at least one embodiment, a kind of acrylamide/methacryloxyethyl of crosslinking can be used Trimethyl ammonium chloride copolymer (by weight 20/80), its form are containing by weight 50% copolymerization in mineral oil A kind of dispersion of thing.This dispersion is with title by vapour bar (Ciba) companyWhat SC 92 was sold. In some embodiments, a kind of methacryloxyethyl trimethyl ammonia chloride ammonium homopolymer of crosslinking, the homopolymer can be used By weight about 50% homopolymer is included in mineral oil or liquid ester.These dispersions are with title by CibaThe Hes of SC 95SC 96 is sold.

Other examples are the cellulose ether derivatives for including quaternary ammonium group, such as by Union Carbide Corporation (Union Carbide Corporation) gathered with what title JR (JR 400, JR 125, JR 30M) or LR (LR 400, LR 30M) was sold Compound.

(2) copolymer of cellulose or the cellulose derivative of water soluble quaternary ammonium monomer is grafted with, is such as grafted with such as first The hydroxyl first of base acryloyl ethyl trimethyl ammonium, methacryiamidopropyl trimethyl ammonium or dimethyldiallylammonium salt Base, ethoxy or hydroxypropyl cellulose.These are with title CELQUAT L by National Starch (National Starch) company 200 and CELQUAT H 100 are sold.

(3) non-cellulosic cationic polysaccharide, such as guar gum containing trialkylammonium cation group.Such product is for example Sold by Meyhall companies with trade name JAGUAR C13S, JAGUAR C15, JAGUAR C17 and JAGUAR C162.

(4) there is piperazinyl units and the polymer of divalent alkyl or hydroxyl alkylidene group.

(5) for example, the water-soluble polyaminoamide prepared by the polycondensation of a kind of acid compound and a kind of polyamine；These Polyaminoamide can be crosslinked with the following：Epihalohydrins, diepoxide, dianhydride, undersaturated dianhydride, double unsaturations Derivative, double halohydrins, double azetidines (bis-azetidinium), double halogenacyl diamines, double alkyl halides or replacement Ground and a kind of oligomer are crosslinked, the oligomer be by with double halohydrins, double azetidines, double halogenacyl diamines, double alkyl halides, What the reaction of epihalohydrins, diepoxide or a kind of reactive difunctional compound of diunsaturated derivative obtained；Crosslinking The amount that agent uses be each polyaminoamide amine groups from 0.025 to 0.35mol in the range of；These polyaminoamides It can be partially alkylated or alkylated, or if they contain at least one tertiary amine function, they can be quaternized.It can be referred to exemplary It is the adipic acid/dimethylamino hydroxypropyl sold by Shandeshi (Sandoz) company with title CARTARETINE F, F4 or F8 Base/diethylenetriamines polymer.

(6) at least one polyalkylene polyamine containing two primary amine groups and at least one secondary amine group and one kind are passed through The polymer that the reaction of dicarboxylic acids obtains, the dicarboxylic acids are selected from diglycolic acid and the C of saturation₃-C₈Aliphatic dicarboxylic acid.Poly- alkylene Mol ratio between base polyamine and dicarboxylic acids is from 0.8:1 to 1.4:In the range of 1；By resulting polyaminoamide with Epichlorohydrin is by epichlorohydrin relative to the secondary amine group of polyaminoamide from 0.5:1 to 1.8:Mol ratio in the range of 1 carries out anti- Should.Such polymer is with title HERCOSETT 57, PD 170 or DELSETTE for example by Hercules company 101 sell.

(7) cyclopolymer of cyclopolymers of alkyldiallylamine and dialkyl diallyl ammonium, such as contain corresponding at least one Homopolymer or copolymer of formula (X) or (XI) unit as the key component of chain：

Wherein, k and t is equal to 0 in formula or l, k+t sum are equal to 1；R₉Represent hydrogen atom or methyl group；R₇And R₈It is only each other On the spot represent C₁-C₈Alkyl group, wherein alkyl group are C₁-C₅Hydroxyalkyl group, wherein alkyl be C₁-C₄Amidoalkyl group Group；Or R₇And R₈It is in connection to represent heterocyclic group such as piperidyl or morpholinyl together to nitrogen-atoms thereon；At least R in one embodiment₇And R₈C is represented independently of one another₁-C₄Alkyl group；Y^-Organic or inorganic anion, as bromide ion, Chlorion, acetate, borate, citrate, tartrate anion, bisulfate ion, bisulfite, sulfate radical or phosphate radical.

In polymer defined above, it can be mentioned that with exemplary by nail (unit of length) section (Nalco) company with title100 HesThe 280 dimethyl diallyl ammonium chloride homopolymers sold (and its is low The homologue of weight average molecular weight) and with title550 diallyldimethylammonium chlorides and third sold The copolymer of acrylamide.

(8) ammonium polymer of season two of the repeat unit containing formula (XII)：

Wherein：

R₁₀、R₁₁、R₁₂And R₁₃, can be same or different, represent C₁-C₆Aliphatic, alicyclic or aryl fat (wherein alkyl group is C for fat race group or Hydroxyalkyl Fatty race group₁-C₄), or alternately R₁₀、R₁₁、R₁₂And R₁₃Together Or it is individually in connection to nitrogen-atoms composition heterocycle thereon, these heterocycles are optionally containing the second miscellaneous original outside denitrogenating Son, or alternately R₁₀、R₁₁、R₁₂And R₁₃Represent the C of straight or branched substituted with nitrile, ester, acyl group or amide group₁-C₆ Alkyl group or group -- CO--O--R₁₄- D or -- CO--NH--R₁₄- D (wherein R₁₄It is alkylidene and D is quaternary ammonium group)；

A₁And B₁Represent C₂-C₆Polymethylene groups, these groups be it is straight chain or side chain, saturated or unsaturated, And optionally comprising at least one aromatic ring or at least one former selected from oxygen and sulphur for being connected on main chain or being inserted The atom of son at least one is selected from sulfoxide, sulfone, disulphide, amino, alkylamino, hydroxyl, quaternary ammonium, urea groups, acid amides and ester The group of group, and

X^-Expression is derived from inorganic or organic acid anion；

A₁、R₁₀And R₁₂With in connection piperazine ring can be formed to two nitrogen-atoms thereon；

And wherein, if A₁Straight or branched, saturation or undersaturated alkylidene or hydroxyalkylene group are represented, Then B₁It also may indicate that group -- (CH₂)_n--CO-D-OC--(CH₂)_n-- wherein n be scope from 1 to 6 number, and D is selected from：

A) there is the diol residue of following formula：-- O--Z--O--, wherein Z represent the group or right based on straight or branched hydrocarbon Ying Yu is with the group of one of following formula：--(CH₂—CH₂--O)_x--CH₂--CH₂--；Or -- [CH₂--CH(CH₃)--O]_y--CH₂-- CH(CH₃) --, wherein x and y represent integer of the scope from 1 to 4, represent definition and unique degree of polymerization or any scope from 1 to 4 numeral (expression average degree of polymerization)；

B) double-secondary diamine residue, such as bridged piperazine derivatives；

C) have with double primary diamines residues of following formula：-- NH--Y--NH--, wherein Y are represented based on straight or branched hydrocarbon Group, or alternately group -- CH₂--CH₂--S--S--CH₂--CH₂--；And

D) have with the urylene group of following formula：--NH--CO--NH--.

In at least one embodiment, X^-It is anion such as chlorion or bromide ion.

For example, these polymer have in number-average molecular weight of the scope from 1000 to 100,000.

In some embodiments, using the polymer by being formed corresponding to the repeat unit of formula (XIII)：

Wherein, R₁₀、R₁₁、R₁₂And R₁₃Can be same or different, it represents C₁-C₄Alkyl or hydroxyalkyl group, n With p be scope from 2 to 6 integer, and X^-It is derived from the anion of inorganic acid or organic acid.

In at least one embodiment, correspond to this family at least one cationic polymer include with formula (W) and (U) repeat unit：

Such as pass through gel permeation chromatography determine its molecular weight ranges be from 9,500 to 9,900 those；

For example, its molecular weight determined by gel permeation chromatography is those of 1200.

(9) polyquaternary polymers being made up of the repeat unit with formula (XIV)：

Wherein, p represents integer of the scope from 1 to 6, and D can be zero or can represent group -- (CH₂)_r-- CO--, its Middle r represents numerical value of the scope from 1 to 6, and X^-It is anion.

Such polymer can be retouched according in U.S. Patent number 4,157,388,4,702,906 and 4,719,282 It is prepared by the method stated.They are for example to be described in patent application EP 122324.

In these polymer, it can be mentioned that example include by Milano (Miranol) company sell product MIRAPOL A 15, MIRAPOL AD1, MIRAPOL AZ1 and MIRAPOL 175.

(10) quadripolymer of vinyl pyrrolidone and vinyl imidazole, such as by BASF (BASF) company with name The product for claiming LUVIQUAT FC 905, FC 550 and FC 370 to sell.

(11) vinylamide homopolymer or copolymer, such as example poly- (vinyl of the vinylamide homopolymer of partial hydrolysis Amine/vinylamide) class.

(12) polyurethane/cationic ester derivant, for example, by the following the flexible property that is formed of reaction those：

(a1) from least one reactive functional groups that active hydrogen (labile hydrogen) is included with least two At least one cation unit that tertiary amine or quaternary ammonium obtain,

(a2) at least two different nonionic units of at least two reactive functional groups comprising active hydrogen are carried At least one mixture, these functional groups are selected from such as oh group, primary or secondary amine groups, and thiol group, and

(b) at least one compound of at least two isocyanate functional groups is included.

(13) other cationic polymers that can be used under the background of present disclosure include, for example, cationic protein or Cationic protein hydrolysate, polyalkyleneimine (polyalkyleneimine) (such as polyethyleneimine), contain vinylpyridine Or the polymer and chitin derivative of vinylpyridine unit.

The cationic polymer being particularly useful in the present invention includes but is not limited to, polyquaternium 4, polyquaternium 6, poly- season Ammonium salt 7, polyquaternium 10, polyquaternium 11, polyquaternium 16, polyquaternium 22, polyquaternium 28, polyquaternium 32, poly- season Ammonium salt -46, polyquaternium -51, polyquaternium -52, polyquaternium -53, polyquaternium -54, polyquaternium -55, polyquaternium - 56th, polyquaternium -57, polyquaternium -58, polyquaternium -59, polyquaternium -60, polyquaternium -63, polyquaternium -64, poly- Quaternary ammonium salt -65, polyquaternium -66, Polyquaternium-67, polyquaternium -70, polyquaternium -73, polyquaternium -74, polyquaternary amine Salt -75, polyquaternium -76, polyquaternium -77, polyquaternium -78, polyquaternium -79, polyquaternium -80, polyquaternium - 81st, polyquaternium -82, polyquaternium -84, polyquaternium -85, polyquaternium -86, polyquaternium -87, polyquaternium -90, poly- Quaternary ammonium salt -91, polyquaternium -92, polyquaternium -94 and guar hydroxypropyltrimonium chloride (guar hydroxypropyltrimonium chloride)。

The particularly preferred cation polymer of the present invention is included from the obtainable polymerization of high (Amerchol) company of liking to be beautiful Thing JR-125, polymer JR-400, polymer JR-30M HEC polymers (polyquaternium 10)；From Rhodia Obtainable AGUAR13-S, guar hydroxypropyltrimonium chloride；And from obtained by nail (unit of length) section (Nalco) company100 and 280, dimethyldialkylammonium ammonium chloride (polyquaternium 6).

Gross weight based on first or oxidising composition, the generally existing amount of cationic polymer be by weight from more than 0% to about 15%, preferably by weight from about 0.5% to about 10%, and more preferably by weight from about 1% to about 5%.

It can also be routinely used for being administered to comprising at least one according to the color alkali of the present disclosure present invention and oxidising composition The additive in composition on hair.

" additive " refer to addition, different from the material for the compound being already mentioned above.

As the example of workable additive, it can be mentioned that antioxidant or reducing agent class with non-limiting, ooze Saturating agent class, chelating agent class, perfumery, buffer class, dispersant class, ceramide type, sun-screening agent class, antiseptic kind, opacifier Class and antistatic additive class.

Oxidising composition comprising at least one oxidant further can be selected from above-mentioned aliphatic thing comprising at least one The fatty substances of matter, including at least one have greater than about 50mm at 40 DEG C²The fatty substances of/s viscosity.Therefore, at some In embodiment, the gross weight based on oxidising composition, the total amount of fatty substances can be by weight with scope in oxidising composition Meter from about 1% to about 20% or such as by weight from about 5% to about 20% or such as by weight from about 10% to About 20%.

According to the preferred embodiment of the present invention, when color alkali composition mixes with oxidising composition, based on from the present invention Color alkali and oxidising composition combination formed be used for change keratin fiber color reagent gross weight, fatty substances Total amount be by weight at least about 1.25% and could range up and be less than about 50% by weight, or up to by weight About 40%, or up to by weight about 30%, or up to by weight about 20%, or up to by weight about 10%.

Different forms may be at according to the color alkali of the present disclosure present invention and oxidising composition, such as in liquid, liquid Body-gel, liquid-creams, the form of creams or lotion.

In a preferred embodiment, the method for color alkali composition is manufactured, color alkali composition is related to when mixing each composition Do not require the use of heat and do not require the use of emulsifier blade (emulsifier blade) cool colour alkali composition.

In other preferred embodiments, color alkali composition not seek survival in fatty alcohol to form emulsion.When color alkali group When compound does not contain fatty alcohol, color alkali composition can be prepared in the presence of no heat using following mixing velocity, should The shear rate of mixing velocity is less than the hair color for being used to prepare conventional/business that typically provides in the form of an emulsion Shear rate.

According to this disclosure, the method for manufacture color alkali composition is related to following general step：

Using blender by acrylate copolymer (for example,Aqua SF-1 or Aqua SF-2) mixed with water,

A certain amount of nertralizer (such as monoethanolamine) is added in mixture, so as to neutralize acrylate polymer (by Indicated by the formation of settled solution),

Add highly viscous fatty substances (has greater than about 50mm at 40 DEG C²The mineral oil of/s viscosity) at the same with modulation Disk blade (chopper blade) mixes, wherein can increase mixing velocity to ensure appropriate mixing.

Optionally, if it is desired that emulsion, adds more high viscosity fatty substances,

Short alkyl chain hydroxy compounds (such as ethanol) is added,

And if necessary, pH adjusting agent is added to obtain desired pH.

Acrylate copolymer can also the preneutralization before they are combined with other compositions according to the above method.

Above reduce the amount of the time required for the hair color alkali composition for preparing conventional/business.

It is used for the method for keratin fibre staining according to the present invention, including：

(1) reagent of the color as described above for being used to change keratin fiber is applied to keratin fiber, wherein (A) and (B) is mixed before being applied on fiber to form the reagent for the color for being used to change keratin fiber；And

(2) reagent is stayed on keratin fiber and continues one section of change for being enough to realize the color of desired fiber Time.

The method of present disclosure is to include the reagent of the color for changing keratin fiber according to present disclosure being applied to Method on keratin fiber.Reagent for changing fiber color is by the color alkali of present disclosure is combined into shape with oxidising composition Into, wherein color be develop at basic ph and oxidising composition can add when in use or it can be with color alkali Composition uses simultaneously or order uses.

When being applied on keratin fiber and after one section of quiescent time, for example, scope is from about 1 to 60 minute, such as From about 5 to 45 minutes, these keratin fibers are rinsed, is optionally cleaned with shampoo and rinsed again, then dried.

The reagent for the color for being used to change keratin fiber according to present disclosure can be by least by the color alkali and oxygen of the present invention Agent composition (including the oxidising composition for including at least one oxidant as defined above) is mixed to get.

In a specific embodiment, oxidising composition is form aqueous or in emulsion.

In another embodiment, oxidising composition is substantially anhydrous.

Term " substantially anhydrous " refers to that oxidising composition is either entirely free of water or the water containing not perceived amount, example Such as, the weight based on oxidising composition, by weight no more than 5%, or it is no more than 2% by weight, or does not surpass by weight Cross 1%.It should be noted that this refers to for example with reference to water, the crystallization water of such as salt or by the composition according to present disclosure The water for the trace that the raw material used in preparation absorbs.

Oxidising composition can contain at least one solvent, selected from water, organic solvent and their mixture.

When oxidising composition is substantially anhydrous, oxidising composition can include at least one molten selected from organic solvent Agent.

Include ethanol, isopropanol, benzylalcohol, benzyl carbinol for the suitable organic solvent that is used in oxidising composition, two Alcohol and glycol ethers (such as propane diols, hexylene glycol, glycol monoethyl ether, single ether or monobutyl ether), propane diols and its ethers are (such as Propylene glycol monomethyl ether), butanediol, DPG, diethylene glycol alkyl ether (such as diethylene glycol monoethyl ether and monobutyl ether), hydro carbons Such as straight chain hydrocarbon, mineral oil, polybutene, the polyisobutene of hydrogenation, the poly decene of hydrogenation, poly decene, saualane, vaseline, Isoparaffin, and their mixture.

Relative to the gross weight of oxidising composition, amount scope that at least one solvent may have for example be by weight from About 0.5% to about 70%, such as by weight from about 2% to about 60%, preferably by weight from about 5% to about 50%.

Oxidising composition may be at the form of powder, gel, liquid, foam, lotion, creams, mousse and emulsion.

The pH of oxidising composition can be from about 2 to about 12 with scope, and such as from about 6 to about 11, and it can use this Well-known acidulant/basifier is adjusted to desired value in field.

According to an embodiment of the invention, included for changing the reagent of color of keratin fiber：

(a) gross weight based on the reagent, by weight at least about 5%, preferably by weight from about 5% to less than about 50% or it is included in 40 DEG C from least one of about 50% to about 80% by weight there is greater than about 50mm²The ore deposit of/s viscosity The fatty substances of thing oil；

(b) gross weight based on the reagent, it is selected from by weight from least one of about 0.3% to about 3% at water-based point The rheology modification of polymers of the acrylate polymer of crosslinking in granular media；

(c) at least one basifier；

(d) gross weight based on the reagent, by weight from least one of about 0.5% to about 15% be selected from monohydric alcohol and The short-chain hydroxyl compound of polyalcohol；

(e) it is at least one to be selected from alkali oxide and the oxidation dye precursors of colour coupler and their mixture；

(f) optionally, at least one direct dyes；And

According to another implementation of the invention, the reagent of the color for changing keratin fiber is a kind of combination Thing, said composition have greater than about 50mm comprising at least one in the acceptable medium of cosmetics at 40 DEG C²/ s viscosity Fatty substances, the rheology modification of polymers of the acrylate polymer of at least one crosslinking selected from water-borne dispersions, extremely A kind of few basifier, at least one short-chain hydroxyl compound selected from monohydric alcohol and polyalcohol；At least one oxidation dye precursors； At least one oxidant.

According to another implementation of the invention, the reagent for changing keratin fiber is a kind of composition, the group Compound is included in a kind of at least one of acceptable medium of cosmetics has greater than about 50mm at 40 DEG C²The aliphatic series of/s viscosity Material, at least one acrylic ester polymerization for including by weight about 30% total solids content selected from water-borne dispersions The rheology modification of polymers of thing and acrylate crosspolymers -4, at least one basifier, at least one selected from monohydric alcohol and The short-chain hydroxyl compound of polyalcohol；At least one oxidation dye precursors；At least one oxidant.

According to another implementation of the invention, the reagent of the color for changing keratin fiber can include two kinds Composition, a kind of color alkali composition in water-in-oil emulsion form, color alkali composition contain in the acceptable medium of cosmetics There is at least one that there is greater than about 50mm at 40 DEG C²The fatty substances of/s viscosity, at least one rheology as defined above change Property polymer, at least one basifier；With at least one short-chain hydroxyl compound selected from monohydric alcohol and polyalcohol；And oxidation Composition, the oxidising composition contain at least one of the acceptable medium of cosmetics oxidant.

, can be by mixing for changing the reagent of color of keratin fiber according to another embodiment again of the present invention Two kinds of units obtain, and include the first module of color alkali composition, and color alkali composition contains in the acceptable medium of cosmetics, extremely Few one kind has greater than about 50mm at 40 DEG C²The fatty substances of/s viscosity, at least one as defined above rheology modified poly- Compound, at least one basifier；With at least one short-chain hydroxyl compound selected from monohydric alcohol and polyalcohol；And oxide compound The second unit of thing, the oxidising composition contain at least one oxidant in the acceptable medium of cosmetics.

PH for the reagent for the color for changing keratin fiber is between from about 2 to about 14.In some embodiments, PH for the reagent for the color for changing keratin fiber is between from about 2 to about 14.In some embodiments, for changing The pH of the reagent of the color of keratin fiber is above 7.In other embodiments, for changing the color of keratin fiber The pH scopes of reagent are from about 1 to about 7.

Have been surprisingly found that has greater than about 50mm at 40 DEG C²The fatty substances of/s viscosity, it is and such as foregoing fixed The liquid emulsion composition that the combination of the rheology modification of polymers of justice is stablized, when being combined with oxidising composition, it is produced Final mixture, the final mixture are thick with not dripping for being still susceptible to sprawl on keratin fiber (such as hair) Degree.

It also have been discovered that the reagent of the color for changing keratin fiber is administered on fiber obtained it is satisfactory Fiber coloring simultaneously make use of with routine oxidation dyeing composition compared with lower amount of oxidant.

According to another implementation of the invention, there is provided, should for the kit (kit) of keratin fibre staining Kit includes the first module containing above-mentioned color alkali composition and the second unit containing above-mentioned color alkali composition.

The coloring obtained using the composition and method of present disclosure can also be lasting or wash resistant/colour fading.

Although the number range and parameter that illustrate the wide scope of present disclosure are approximations, unless otherwise indicated in instantiation Middle illustrated numerical value is reported as accurately as possible.However, any numerical value, which inherently includes, comes from their corresponding examinations Necessary some errors of the standard deviation of test amount.

Following instance is used for the embodiment for illustrating present disclosure, but substantially without restricted.

Embodiment

1-formulation Example of embodiment

It is prepared for the following composition of present disclosure：

The liquid emulsion color alkali composition of table 1

^aAt 40 DEG C from about 63 to about 70mm²/ s viscosity；From supplier U.S. Suo Nuobang with trade nameWeight white Mineral oil or from ExxonMobil Chemical of supplier with trade name Primol^TM352 is commercially available

The liquid emulsion color alkali composition of table 2

^aFrom about 63 to about 70mm at 40 DEG C²/ s viscosity；From supplier U.S. Suo Nuobang with trade nameWeight is white Color mineral oil or from ExxonMobil Chemical of supplier with trade name Primol^TM352 is commercially available

Each formula in upper table 1 and 2 is (the amounting to 1000 grams) prepared as follows：

By acrylate copolymer (withAqua SF-1 are commercially available) it is added to the water and with equipped with tune Solution obtained by the VMI Rayneri blenders mixing of disk blade processed.10g monoethanolamines are added to neutralize acrylic ester copolymer Thing.Solution completely in and when become clarification thick gel.Mixing velocity is increased to 600 revs/min.Solution become it is thicker and Become white paste.Mineral oil is added in solution.Mixing velocity is increased between 700-1000RPM.Add denaturation Alcohol (ethanol) to reduce the viscosity of solution.Continue mixing about 10 minutes under about 1200 revs/min.By antioxidant, burnt sulfurous Sour sodium and arabo-ascorbic acid are added in emulsion.Reduce mixing velocity.For the composition in table 1, by the remainder of monoethanolamine Divide and be added in emulsion.If necessary, acidulant and/or basifier are added to adjust pH.

It was found that even if when high-caliber mineral oil is merged in above formula, the formula remains in that stabilization and is in liquid The form of emulsion.

The creams emulsion color alkali composition of table 3

The creams emulsion color alkali composition of table 4

Each formula in upper table 3 and 4 is (the amounting to 1000 grams) prepared as follows：

By acrylate copolymer (withAqua SF-1 are commercially available) it is added to the water and with equipped with tune Solution obtained by the VMI Rayneri blenders mixing of disk blade processed.10g monoethanolamines are added to neutralize acrylic ester copolymer Thing.Solution completely in and when become clarification thick gel.Mixing velocity is increased at least about 600 revs/min.The solution becomes It is thicker and become white paste.80g mineral oil is added in the solution to produce a kind of emulsion and increase mixing velocity To at least about 1000 revs/min.Then the half (420 grams of remainders) of the oily remainder is added in the emulsion simultaneously Continue mixing about 10 minutes.Mixing velocity is increased at least about 1200RPM to ensure appropriate mixing.By required denaturation The half of total concentration of alcohol (ethanol) add to adjust or reduce the viscosity of emulsion.Then the remainder of mineral oil is added simultaneously Continue mixed for several minutes.If having used other fatty substances, it can also be added in this stage, together with what be may want to Other additives.It is also added into the remainder of the alcohol of denaturation.Antioxidant, sodium pyrosulfite and arabo-ascorbic acid are added to In emulsion.Reduce mixing velocity.For the composition in table 3, the remainder of monoethanolamine is added in emulsion.If necessary If, acidulant and/or basifier are added to adjust pH.

It was found that even if when high-caliber mineral oil is merged in above-mentioned formula, the formula keeps stable and is in creams emulsion Form.

The oxidising composition of table 5

* in 40 DEG C of viscosity in about 30mm2/s

Above oxidising composition prepares as follows：

Cetostearyl alcohol, stereth -20, mineral oil, PEG-4 vegetable seed oleamide and tocopherol are added into main burning In cup and it is heated to 80 DEG C (A phases).Heat the water to 80 DEG C and be added in A phases to form solution.By the solution 2500 turns/ Homogenization 10 minutes under point.Then glycerine, the sodium of Pentetic Acid five, polyquaternium -6, the U.S. oronain in sea are added in the solution and mixed Close 10 minutes.Then phase A is cooled to 25 DEG C.Hydrogen peroxide is added in the solution and homogenized 5 minutes.Remove homogenizer Blade simultaneously replaces with reticle blade.Phosphoric acid is added so that pH is adjusted to 2.0-2.40.

Embodiment 2- hair colorings are studied；Colour measurement

The reagent of color for changing hair is prepared and is used for by secondary colour alkali composition and oxidising composition It is hair coloring in the following manner when in use：

- mix 10g color alkali composition A with 10g oxidising compositions B；

- resulting mixture is applied on hair swatch；

- and then hair swatch shampoo washed, rinsed and then dried.

If desired, color alkali composition can be with oxidising composition with 1:1 ratio or 1:2 ratio or with 1:3 Ratio mixing.

Depending on the pH of color alkali composition, resulting mixture has the pH more than or less than 7.

By each formula and oxidising composition in following table, B (for example, composition in table 5) mixes according to above-mentioned steps Close to form the reagent for being used for changing hair (sample) color.After hair-dyeing, used in CIEL*a*b* systems Minolta CM2600d spectrocolorimeters (including reflection part, 10 degree of angle, light source D65) measure the color of sample. In this system, L* represents the intensity of color, and a* represents green/beauty's colour axis and b* represents indigo plant/yellow color axle.

According to this system, L value is bigger, then color is lighter or intensity is smaller.On the contrary, L value is lower, then color it is deeper or Intensity is bigger.

Δ E represent control hair swatch (undyed/untreated) and treated (or dyeing) hair sample it Between color change, and determined by the change of L* values, a* values and b* values.

The comparative dye formula of table 6 and liquid emulsion color alkali composition

Table 6A colourity results

^aFormula plus oxidising composition

^bTone 5.6 is red tone

L* represents brightness or the intensity of color；L values are higher, and the color of hair is brighter.

* Δs-E (DE) represents the difference between two kinds of colors.If DE is less than 1.0, there's almost no human eye can discover Any aberration.If DE is more than 1.0, exist with the noticeable aberration of eyes.

The above results show than the hair handled with Comparative composition to be shown with the hair that the colouring compositions of the present invention are handled Write deeper, it means that compared with comparative dye composition, composition of the invention deposits stronger red.It is in addition, of the invention Formula BB and CC its compared with comparative dye composition have in the total amount of dye composition at least 50% reduction still Generate than to the color deposition (smaller L value) bigger than dye composite, showing the amount of dyestuff in composition of the invention In remain able to further to reduce so as to allow bigger cost to reduce and less stability/suspension using dye composition Liquid problem.Identical result is observed for both hairs not scalding and scalding.

The comparative dye formula of table 7 and liquid emulsion color alkali composition

Table 7A colourity results

^aFormula plus oxidising composition

^bTone 4.15 is kermesinus brown tone

* * Δs-E (DE) represent the difference between two kinds of colors.If DE is less than 1.0, there's almost no human eye can examine Any aberration felt.If DE is more than 1.0, exist with the noticeable aberration of eyes.

The above results show than the hair handled with Comparative composition to be shown with the hair that the colouring compositions of the present invention are handled Write deeper, it means that compared with comparative dye composition, composition of the invention deposits stronger brown.In addition, the 3rd Being formulated (FF), there is at least about 30% reduction in the amount of dye composition still to produce compared with comparative dye composition for it Than to the color deposition (smaller L value) bigger than dye composite, showing the amount of dyestuff in the present compositions still It so can further reduce and be asked so as to allow bigger cost to reduce with less using stability/suspension of dye composition Topic.Identical result is observed for both hairs not scalding and scalding.

The comparative dye formula of table 8 and liquid emulsion color alkali composition

Table 8A colourity results

^aFormula plus oxidising composition

^bTone 06N is a kind of medium golden brown tone

The above results show more notable than the hair handled with comparative formula with the hair of the colouring compositions processing of the present invention It is deeper, it means that compared with comparative dye composition, composition of the invention deposits stronger brown.In addition, the 3rd matches somebody with somebody Side, II, its with comparative dye composition and formula HH compare with the amount of dye composition at least 37% reduction still Generate than to the color deposition (smaller L value) bigger than dye composite, showing the amount of dyestuff in composition of the invention In remain able to further to reduce so as to allow bigger cost to reduce and less stability/suspension using dye composition Liquid problem.Identical result is observed for both hairs not scalding and scalding.

Table 9：The creams emulsion color alkali composition of the invention of dyestuff with different total amounts

Table 9A colourity results

^aFormula plus oxidising composition

^bTone 6.54 is purple tone

Mixture with alkaline pH is generated according to the mixture of the color alkali composition of the present invention and oxidising composition.According to Composition of the invention more than observation deposited strong reddish violet on hair swatch.In addition, such as by using with least The journey for the color deposition that the L* and DE values of the hair of the composition LL processing of the reduction of the amount of 50% dye composition are confirmed L* the and DE values of the hair of degree and color change with being handled with composition KK are still comparable.These results show in this hair The amount of dyestuff remains able to further reduce in bright composition uses dyestuff so as to allow bigger cost to reduce with less The stability of compound/suspension problem.Identical result is observed for both hairs not scalding and scalding.

Table 10：The creams emulsion color alkali composition of the invention of dyestuff with different total amounts

^bThe about 50mm at 40 DEG C²/ s or smaller viscosity

Table 10A colourity results

Hair dye type^a	Tone^b	Formula number：	90% grizzled hair type	L*	CIE76 DE
						The color alkali of the present invention	6.54	It is formulated OO	Do not scalded	23.12	4.12
The color alkali of the present invention	6.54	It is formulated PP	Do not scalded	22.75	3.52
						The color alkali of the present invention	6.54	It is formulated OO	Scalded	22.12	3.56
The color alkali of the present invention	6.54	It is formulated PP	Scalded	24.32	2.95

^aFormula plus oxidising composition

^bTone 6.54 is purple tone

Mixture with acid pH is generated according to the mixture of the color alkali composition of the present invention and oxidising composition.According to Composition of the invention more than observation deposited strong reddish violet on hair swatch.In addition, such as by using with least The journey for the color deposition that the L* and DE values of the hair of the composition NN processing of the reduction of the amount of 50% dye composition are confirmed L* the and DE values of the hair of degree and color change with being handled with composition MM are still comparable.These results show in this hair The amount of dyestuff remains able to further reduce in bright composition uses dyestuff so as to allow bigger cost to reduce with less The stability of compound/suspension problem.Identical result is observed for both hairs not scalding and scalding.

Embodiment 3- suspension/stability study

The sample of the color alkali composition of the present invention is placed on and is set to scope from room temperature to 45 DEG C of different temperature Temperature controlled compartment in.Separation or the precipitation of emulsion are not observed within the time of 2 months.

Also using yield stress measurement (Elastic Function, G ' (Pa)) (temperature in the increased temperature from 20 DEG C to 60 DEG C Scan it is per minute for 1 DEG C, with 0.1% deformation) for the following color alkali formula of the invention of stability test.Dye composite Stability also do not become with increased temperature or over time unstable energy with composition suspension dye molecule Power is relevant.

Table 11- color alkali formulation examples

^*From about 63 to about 70mm at 40 DEG C²/ s viscosity；From supplier U.S. Suo Nuobang with trade nameWeight is white Color mineral oil or from ExxonMobil Chemical of supplier with trade name Primol^TM352 is commercially available

Table 11A- yield stress measured values

Formula	At 25 DEG C of yield stresses (Pa)	At 45 DEG C of yield stresses (Pa)
			It is formulated QQ	2.5	2.5
It is formulated RR	3.0	3.0
			It is formulated SS	2.5	3.0

Yield stress measured value shows the stability of composition not as composition is exposed at higher temperatures And change or only slightly change.In addition, the stability characteristic of the composition containing dye composition is not with containing dyestuff The composition of compound has no difference.

The viscosity researchs of embodiment 4- over time

Viscosity time experiment has been carried out to study the viscous of the composition for oil (fatty substances) present invention for using various concentrations The change of degree (color alkali composition adds oxidising composition without oxidation dye precursors).Test contrast product simultaneously.Instrument and Parameter is described as：

Viscosimeter-plum Teller RM 180Rheomat

Sequence number：3113402413

Main shaft #2 continues 30 seconds

Viscosity measurement-uD (deflection unit)-Pa-S

Measurement is to carry out at room temperature

Tested and comparative formula using the basic components (not having high viscosity mineral oil) in following preparation example IV Viscosity compared to the high viscosity mineral oil comprising varying level color alkali composition of the invention viscosity over time.

Table 12- does not have dyestuff and the basic components of high viscosity mineral oil

Table 12A viscosity datas-basic components+high viscosity mineral oil^a

* comparative formulas do not contain high viscosity mineral oil and acrylate copolymer ( Aqua SF-1)

The above results show comparative formula relative to the present invention color alkali composition those in terms of viscosity number exist compared with Big change.It has also been found that the color alkali composition of the present invention has denseness that is excellent, not dripping.Even in the color alkali group of the present invention Compound after being mixed with oxidising composition this denseness remain in that.

Embodiment 5- uses the formulation types of the high viscosity mineral oil of varying level

The above results show that color alkali composition remains in that stabilization under the heavy oil of high concentration.

For those of ordinary skill in the art it will be appreciated that in the situation without departing substantially from the spirit or scope of the present invention Different modifications and variations can be made to delivery system, composition and the method for the present invention down.Therefore, it is intended to the present invention Cover the modifications and variations of the present invention, condition is that they are fallen into the range of appended claims and its equivalent.

Claims

1. a kind of reagent for being used to change the color of keratin fiber, comprising：

(A) color alkali composition, included in the acceptable medium of cosmetics：

(a) be based on (A) gross weight, by weight from 10% to 50% at least one mineral oil, the mineral oil is at 40 DEG C With according to the methods of ASTM D 445 with the scope that kinematic viscosity measures from 63mm²/ s to 70mm²/ s viscosity；

(b) be based on (A) gross weight, by weight from 0.3% to 3% at least one rheology modification of polymers, selected from propylene The cross-linked copolymer of acid or methacrylic acid and/or they one or more C1-C6 Arrcostabs；

(c) at least one basifier；

(d) gross weight of (A) is based on, at least one from 0.5% to 15% by weight is selected from ethanol, propyl alcohol, ethylene glycol, third Glycol, butanediol, hexylene glycol, propane diol, the short alkyl chain hydroxy compounds of glycerine and their mixture；

(e) it is at least one to be selected from oxidation base and the oxidation dye precursors of colour coupler and their mixture；And

(B) oxidising composition, at least one oxidant is included in the acceptable medium of cosmetics,

Wherein, the scope of (a) and the weight rate of (b) is from 20 in (A):1 to 3:1,

Wherein, the reagent of the color for changing keratin fiber is entirely free of ammonia or the weight based on the reagent contains not Ammonia more than by weight 1%, the ammonia include ammonium ion.

2. reagent according to claim 1, further include different from (A) (a) and be selected from C₆-C₁₆Lower paraffin hydrocarbon, mineral, The non-silicone oils of plant, animal and synthesis source, fatty alcohol, fatty acid ester, aliphatic alcohol ester, aliphatic acid, non-silicone wax and At least one other fatty substances of silicone.

3. reagent according to claim 2, wherein, at least one other fatty substances different from (A) (a) are There is the 50mm measured according to the methods of ASTM D 445 with kinematic viscosity at 40 DEG C²/ s or smaller viscosity mineral oil.

4. reagent according to claim 2, wherein, based on the gross weight of (A), at least one mineral oil and it is described extremely A kind of few total amount of other fatty substances is by weight from 5% to less than 50%.

5. reagent according to claim 2, wherein, based on the gross weight of (A), at least one mineral oil and it is described extremely A kind of few total amount of other fatty substances is by weight from 50% to 80%.

6. reagent according to claim 1, wherein, (A) (b) is selected from methacrylic acid/ethyl acrylate copolymers of crosslinking Thing.

7. reagent according to claim 1, wherein, (A) (b) is selected from water-based point containing by weight 30% total solid Acrylate copolymer in granular media.

8. reagent according to claim 1, wherein, (A) (b) is selected from the anionic acrylate polymer of crosslinking.

9. reagent according to claim 1, wherein, (A) (b) is selected from acrylate crosspolymers -4.

10. reagent according to claim 1, wherein, based on the gross weight of (A), (A) (b) is with by weight from 0.45% Amount to 2.75% is present.

11. reagent according to claim 1, wherein, in (A), (a) and (b) weight rate scope are from 15:1 to 10:1。

12. reagent according to claim 1, wherein, (A) (c) is selected from alkali carbonate, alkali metal phosphate, organic Amine, hydroxide alkalescence compound and their derivative, and the gross weight based on (A), with by weight from 0.01% Amount to 30% is present.

13. reagent according to claim 12, wherein, (A) (c) be selected from monoethanolamine, triethanolamine, 2- amino-2-methyls- 1- propyl alcohol and their mixture.

14. reagent according to claim 1, wherein, (A) (e) is selected from adjacent and p-phenylenediamine alkali oxide, double alkali, described double Alkali is the compound for including at least two aromatic protons, and the aromatic proton has at least one, adjacent in amino and hydroxyl and to ammonia The addition salts and m-aminophenol, m-phenylene diamine (MPD), a diphenol, naphthols of base phenol, heterocyclic bases and these compounds and acid Colour coupler, heterocyclic coupler agent and their hydrochlorate.

15. reagent according to claim 1, wherein, (A) further includes at least one direct dyes.

16. reagent according to claim 1, wherein, the pH scopes of (A) are from 7.5 to 12.

17. reagent according to claim 1, wherein, at least one oxidant be selected from hydrogen peroxide, urea peroxide, Alkali metal bromate, the iron cyanide, peroxide salt, perborate, percarbonate, laccase, peroxidase, oxidoreducing enzyme, And they mixture and based on (B) gross weight, with by weight from 0.05% to 50% amount exist.

18. reagent according to claim 1, wherein, the pH scopes of the reagent are from 7.1 to 12 or from 2 to 6.8.

19. reagent according to claim 1, wherein, (A) further includes at least one nertralizer, at least one Nertralizer is selected from ethamine, ethylenediamine, alkanolamine, cyclammonium and the saturation or unsaturation in ring with one or more nitrogen-atoms Other cyclic compounds.

20. reagent according to claim 1, wherein, (A) and/or (B) further includes at least one auxiliary agent, described to help Agent be selected from thickener and the rheology modification of polymers different from (A) (b), cationic polymer, film forming polymer, pigment, dyestuff, Wetting agent and NMF, the emulsifying agent different from (A) (a), structural agent, propellant, surfactant, polishing material and conditioning Agent.

21. reagent according to claim 1, wherein, (B) further includes at least one fatty substances, and described at least one Kind fatty substances are selected to have at 40 DEG C is more than 50mm according to the methods of ASTM D 445 with what kinematic viscosity measured²/ s viscosity Fatty substances, with having at 40 DEG C 50mm is more than with what kinematic viscosity measured according to the methods of ASTM D 445²The institute of/s viscosity State fatty substances different other fatty substances and their mixture.

22. reagent according to claim 1, wherein, the reagent is instant hair coloring composition.

23. a kind of method for keratin fibre staining, including：

(1) reagent of the color according to claim 1 for changing keratin fiber is applied to keratin fiber, (A) and (B) is mixed wherein before being applied on the fiber to form the examination for the color for being used to change keratin fiber Agent；And

(2) reagent is stayed on the keratin fiber when continuing one section and being enough to realize that desired fiber color changes Between.

24. a kind of multi-compartment kit, including：

(A) first module of the color alkali composition limited containing claim 1,

Wherein, the pH scopes of the color alkali composition are from 9 to 11；And

(B) second unit containing oxidizing compositions, the oxidising composition is in the acceptable medium of cosmetics comprising at least A kind of oxidant.