CN1046842C - Mothproofing paint - Google Patents
Mothproofing paint Download PDFInfo
- Publication number
- CN1046842C CN1046842C CN95113304A CN95113304A CN1046842C CN 1046842 C CN1046842 C CN 1046842C CN 95113304 A CN95113304 A CN 95113304A CN 95113304 A CN95113304 A CN 95113304A CN 1046842 C CN1046842 C CN 1046842C
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- gulgul
- fabrics
- thickener
- mothproofing
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Abstract
The present invention relates to a mothproof sanitary medicine used for woollen, cotton and silk fabrics, which has the main active component of clorpyrifos or takes the clorpyrifos as a main component, and a few auxiliary biocidal agents are added. The present invention has good function of fumigating and killing moths which damage woollen and cotton fabrics. The present invention has the advantages of convenient use, long residual effect, no influence on the whiteness of fabrics and no toxicity on human bodies and is a novel mosquito preventing medicine.
Description
The present invention relates to a kind of mothproof medicine, specifically a kind of velvet apple silk fabric Mothproof camphor medicine.
In the research and application of modern household mothproofing agent, naphthalene and contraposition benzene dichloride product are generally acknowledged by the world to the murder by poisoning of human body and environment, therefore in the research of the novel mothproofing agent that replaces the naphthalene goods, release effective rapidly, to the person poultry safety, and mothproofing agent free from environmental pollution, property and the health that ensures people is of great importance.
The insecticidal paint Japan Patent is [clear-63-108086, clear-63-185909] existing report, they join organic phosphor and pyrethroid insecticides in some macromolecule resins and make coating, in order to killing sanitary insect pests such as termite, spider, mosquito, fly, louse, flea, when above-mentioned insect be poisoned to death after coating contacts.Be not used for the mothproof usefulness of fumigating, kill moth but relate to.
It is simple to the purpose of this invention is to provide a kind of preparation, nontoxic to human body, and have well mothproof, the gulgul of smoked kill moth effect.
The gulgul that the present invention proposes, based on chlopyrifos, its prescription comprises the 2-20% chlopyrifos, adds 0-10% auxiliary insecticide, 1-5% pigment, 2-30% adhesive, 1-16% thickener, the anticorrosion mildew-resistant profit of 0.01-1%, and 0.1-2% spices and water mix to be formed.Chlopyrifos [0,0-diethyl-0-(3,5, the 6-trichloro-2-pyridyl) thiophosphate], common name: Chlorpyrifos, structural formula is as follows:
Auxiliary insecticide comprises decis, aerosol chrysanthemum ester (Vaporthrin) and 3-borneol etc.Adhesive generally adopts macromolecule resinae adhesives such as polyvinyl acetate, polyacrylate, polyvinyl alcohol.Pigment can be selected versicolor pigment as required for use.Thickener is with thickener commonly used in the textile printing coating, as thickener M type or KG-101 etc.Antisepticize and mildew preventive then adopts methyl p-hydroxybenzoate, ethyl-para-hydroxybenzoate, propylparaben, butyl p-hydroxybenzoate or with the mixture of above-mentioned four kinds of Antisepticize and mildew preventives.Gulgul of the present invention earlier with insecticide emulsification and Antisepticize and mildew preventive mixed dissolution, adds entry, pigment, adhesive, essence and thickener then successively by weight percentage in stirring.Stir more than 30 minutes, form coating.Be coated in equably on the stronger filter paper band of water imbibition with the dosage of every square metre of 50-200 gram and make mothproofing paper.Also can be coated in the surface of other materials such as cloth or plank as required, can be used as linings such as bag, case, cupboard, or make the trade mark of wool textile.They are natural seasoning at room temperature; Or through 100 ℃ of oven dry in 1-3 minute.Insecticide in this moth-proof material slowly volatilizees at normal temperatures and kills moth with fumigation action.Can be in the gulgul that does not add pigment without adhesive.When insecticidal paint in order to when spraying, can not add or add less adhesive and thickener.
Gulgul of the present invention is that a kind of production technology is simple, safe, easy to use, residual effect is long, curtain casemaking clothes moth Tineola bissellilla and other khapra beetles all there are stifling preferably killing action, and the textile whiteness is had no effect: to the true border of mammalian toxicity measurement result non-toxic type.The present invention is a kind of desirable mothproof articles for use, and following test has further confirmed this good effect.
Table 1 mothproofing paper is to the toxic effect of curtain casemaking clothes moth
| Larval mortality (%) visual fabric infringement grading 1 100 surface nondestructives evil 1A 2 100 surface nondestructives evil 1A 3 100 surface nondestructives evil 1A in the sample number into spectrum 100 hours |
Table 2 mothproofing paper is to curtain casemaking clothes moth larva residual effect (lethality %)
| Sample number June in first month March 1 100 100 100 2 100 100 100 3 100 100 80 |
Three kinds of mothproofing papers of table 3 influence the white goods whiteness
| Sample title test result 1. white goods treatment samples 71.40 2. white goods treatment samples 70.42 3. white goods treatment samples 70.71 white goods blank samples 71.50 |
Above-mentioned test is to adopt fumigating system, by FZ/T 20004-91 standard and test with reference to the IWSTM25 standard.They are to adopt the test of ZBD-79 whiteness instrument to hair, cotton goods whiteness.
From table 1, table 2, table 3 gulgul of the present invention as can be seen the effect of good mothproof, smoked kill moth is arranged not only, color and luster of velvet apple fabric etc. is also had no adverse effects, and the human body skin irritant test is belonged to nonirritant; The human body skin sensitization test (STT) belongs to weak sensibiligen; The Ames gene mutation test is negative, is a kind of desirable mothproof articles for use.
Following embodiment will be further described the technical scheme of gulgul of the present invention.
Embodiment 1 gulgul medicine is by chlopyrifos, aerosol chrysanthemum ester, pigment, and polyacrylate, P-hydroxybenzoic acid third fat, thickener M type, spices and water mix.Its percentage by weight is 7.5: 2.5: 2: 5: 0.1: 7: 0.5: 76.4.The insecticidal paint compound method is earlier with insecticide chlopyrifos (emulsion) and preservative propylparaben, mixed dissolution, stirring, add entry, pigment, adhesive polyacrylate and thickener M type then successively by weight percentage, stir more than half an hour, coating is coated in equably on 100 * 12 centimetres the paper tape, after 100 ℃ of oven dry in 1～3 minute, aerosol chrysanthemum fat and spices in spray or the roller coating again, at last whole piece paper tape pleat is become the paper of 10 * 12 centimetres of sizes to paste, encapsulate with plastic sack.Open plastic sack during use, put 1-2 bar paper tape in the case in per 1 cubic metre of space or the cupboard.
Embodiment 2 gulgul medicines are mixed by insecticide chlopyrifos, pigment, polyacrylate, propylparaben, thickener M type, spices and water.Its percentage by weight is 15: 2: 10: 0.1: 5: 0.5: 67.4.Preparation method such as embodiment 1.
Embodiment 3 gulgul medicines are by chlopyrifos, 3-borneol, pigment, polyvinyl acetate, and propylparaben, thickener M type, spices and water mix.Its percentage by weight is 3.8: 3.8: 2: 5: 0.1: 7: 0.5: 77.8.Preparation method such as embodiment 1.
Embodiment 4 gulgul medicines are mixed by chlopyrifos, decis, pigment, polyvinyl acetate, propylparaben, thickener M type, spices and water.Its percentage by weight is 7.5: 0.1: 2: 5: 0.1: 7: 0.5: 77.8, and preparation method such as embodiment 1.
Use the embodiment of above-mentioned four different formulations, the curtain casemaking clothes moth is all had good killing action, but their residual effect is different.Embodiment 1,3,4 residual effects are six months, the longevity of residure that embodiment 2 tools are above one year.The residual effect of embodiment 1-4 (room temperature 20-26 ℃) in open environment is carried out.In fact all kinds of mothproofing agent major parts are to be placed in the more airtight environment of wardrobe, chest and drawer to use, so the residual effect of practical application is much longer.
Claims (1)
1, a kind of gulgul is characterized in that it contains the adhesive of 2-20% chlopyrifos and 1-5% pigment and 2-30% polyacrylate or high-molecular polyvinyl alcohol resin and 1-15% thickener M and 0.01-1% propylparaben or butyl p-hydroxybenzoate or methyl p-hydroxybenzoate or ethyl-para-hydroxybenzoate or with the combination of Antisepticize and mildew preventive and the 0.1-2% spices and the water of above-mentioned four kinds of preservative blends.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95113304A CN1046842C (en) | 1995-10-19 | 1995-10-19 | Mothproofing paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95113304A CN1046842C (en) | 1995-10-19 | 1995-10-19 | Mothproofing paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1125512A CN1125512A (en) | 1996-07-03 |
| CN1046842C true CN1046842C (en) | 1999-12-01 |
Family
ID=5079921
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95113304A Expired - Fee Related CN1046842C (en) | 1995-10-19 | 1995-10-19 | Mothproofing paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1046842C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103039520A (en) * | 2012-12-25 | 2013-04-17 | 林玉财 | Ointment capable of preventing and curing tree moths |
| CN107459812A (en) * | 2017-08-26 | 2017-12-12 | 安徽智博新材料科技有限公司 | Construction material based on cyclic carbonate |
| CN109749501A (en) * | 2017-11-02 | 2019-05-14 | 丹阳八紫光能有限公司 | A kind of Anti-moth-eating sofa cloth |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2090139A (en) * | 1980-12-29 | 1982-07-07 | Dow Chemical Co | Improvements in Insecticidal Compositions |
| EP0210416A1 (en) * | 1985-07-18 | 1987-02-04 | Shell Internationale Researchmaatschappij B.V. | Insecticidally active agent for combating textile pests |
| US4797381A (en) * | 1987-07-30 | 1989-01-10 | The Standard Oil Company | Preparation of abrasion resistant alumina-supported vanadium-antimony oxidic catalysts |
-
1995
- 1995-10-19 CN CN95113304A patent/CN1046842C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2090139A (en) * | 1980-12-29 | 1982-07-07 | Dow Chemical Co | Improvements in Insecticidal Compositions |
| EP0210416A1 (en) * | 1985-07-18 | 1987-02-04 | Shell Internationale Researchmaatschappij B.V. | Insecticidally active agent for combating textile pests |
| US4797381A (en) * | 1987-07-30 | 1989-01-10 | The Standard Oil Company | Preparation of abrasion resistant alumina-supported vanadium-antimony oxidic catalysts |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1125512A (en) | 1996-07-03 |
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