CN1046842C - Mothproofing paint - Google Patents

Mothproofing paint Download PDF

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Publication number
CN1046842C
CN1046842C CN95113304A CN95113304A CN1046842C CN 1046842 C CN1046842 C CN 1046842C CN 95113304 A CN95113304 A CN 95113304A CN 95113304 A CN95113304 A CN 95113304A CN 1046842 C CN1046842 C CN 1046842C
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CN
China
Prior art keywords
present
gulgul
fabrics
thickener
mothproofing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CN95113304A
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Chinese (zh)
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CN1125512A (en
Inventor
潘家复
朱竑侃
孙仲康
林国芳
陈巧云
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SHANGHAI INST OF ENTOMOLOGY CH
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SHANGHAI INST OF ENTOMOLOGY CH
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Priority to CN95113304A priority Critical patent/CN1046842C/en
Publication of CN1125512A publication Critical patent/CN1125512A/en
Application granted granted Critical
Publication of CN1046842C publication Critical patent/CN1046842C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

The present invention relates to a mothproof sanitary medicine used for woollen, cotton and silk fabrics, which has the main active component of clorpyrifos or takes the clorpyrifos as a main component, and a few auxiliary biocidal agents are added. The present invention has good function of fumigating and killing moths which damage woollen and cotton fabrics. The present invention has the advantages of convenient use, long residual effect, no influence on the whiteness of fabrics and no toxicity on human bodies and is a novel mosquito preventing medicine.

Description

Gulgul
The present invention relates to a kind of mothproof medicine, specifically a kind of velvet apple silk fabric Mothproof camphor medicine.
In the research and application of modern household mothproofing agent, naphthalene and contraposition benzene dichloride product are generally acknowledged by the world to the murder by poisoning of human body and environment, therefore in the research of the novel mothproofing agent that replaces the naphthalene goods, release effective rapidly, to the person poultry safety, and mothproofing agent free from environmental pollution, property and the health that ensures people is of great importance.
The insecticidal paint Japan Patent is [clear-63-108086, clear-63-185909] existing report, they join organic phosphor and pyrethroid insecticides in some macromolecule resins and make coating, in order to killing sanitary insect pests such as termite, spider, mosquito, fly, louse, flea, when above-mentioned insect be poisoned to death after coating contacts.Be not used for the mothproof usefulness of fumigating, kill moth but relate to.
It is simple to the purpose of this invention is to provide a kind of preparation, nontoxic to human body, and have well mothproof, the gulgul of smoked kill moth effect.
The gulgul that the present invention proposes, based on chlopyrifos, its prescription comprises the 2-20% chlopyrifos, adds 0-10% auxiliary insecticide, 1-5% pigment, 2-30% adhesive, 1-16% thickener, the anticorrosion mildew-resistant profit of 0.01-1%, and 0.1-2% spices and water mix to be formed.Chlopyrifos [0,0-diethyl-0-(3,5, the 6-trichloro-2-pyridyl) thiophosphate], common name: Chlorpyrifos, structural formula is as follows: Auxiliary insecticide comprises decis, aerosol chrysanthemum ester (Vaporthrin) and 3-borneol etc.Adhesive generally adopts macromolecule resinae adhesives such as polyvinyl acetate, polyacrylate, polyvinyl alcohol.Pigment can be selected versicolor pigment as required for use.Thickener is with thickener commonly used in the textile printing coating, as thickener M type or KG-101 etc.Antisepticize and mildew preventive then adopts methyl p-hydroxybenzoate, ethyl-para-hydroxybenzoate, propylparaben, butyl p-hydroxybenzoate or with the mixture of above-mentioned four kinds of Antisepticize and mildew preventives.Gulgul of the present invention earlier with insecticide emulsification and Antisepticize and mildew preventive mixed dissolution, adds entry, pigment, adhesive, essence and thickener then successively by weight percentage in stirring.Stir more than 30 minutes, form coating.Be coated in equably on the stronger filter paper band of water imbibition with the dosage of every square metre of 50-200 gram and make mothproofing paper.Also can be coated in the surface of other materials such as cloth or plank as required, can be used as linings such as bag, case, cupboard, or make the trade mark of wool textile.They are natural seasoning at room temperature; Or through 100 ℃ of oven dry in 1-3 minute.Insecticide in this moth-proof material slowly volatilizees at normal temperatures and kills moth with fumigation action.Can be in the gulgul that does not add pigment without adhesive.When insecticidal paint in order to when spraying, can not add or add less adhesive and thickener.
Gulgul of the present invention is that a kind of production technology is simple, safe, easy to use, residual effect is long, curtain casemaking clothes moth Tineola bissellilla and other khapra beetles all there are stifling preferably killing action, and the textile whiteness is had no effect: to the true border of mammalian toxicity measurement result non-toxic type.The present invention is a kind of desirable mothproof articles for use, and following test has further confirmed this good effect.
Table 1 mothproofing paper is to the toxic effect of curtain casemaking clothes moth
Larval mortality (%) visual fabric infringement grading 1 100 surface nondestructives evil 1A 2 100 surface nondestructives evil 1A 3 100 surface nondestructives evil 1A in the sample number into spectrum 100 hours
Table 2 mothproofing paper is to curtain casemaking clothes moth larva residual effect (lethality %)
Sample number June in first month March 1 100 100 100 2 100 100 100 3 100 100 80
Three kinds of mothproofing papers of table 3 influence the white goods whiteness
Sample title test result 1. white goods treatment samples 71.40 2. white goods treatment samples 70.42 3. white goods treatment samples 70.71 white goods blank samples 71.50
Above-mentioned test is to adopt fumigating system, by FZ/T 20004-91 standard and test with reference to the IWSTM25 standard.They are to adopt the test of ZBD-79 whiteness instrument to hair, cotton goods whiteness.
From table 1, table 2, table 3 gulgul of the present invention as can be seen the effect of good mothproof, smoked kill moth is arranged not only, color and luster of velvet apple fabric etc. is also had no adverse effects, and the human body skin irritant test is belonged to nonirritant; The human body skin sensitization test (STT) belongs to weak sensibiligen; The Ames gene mutation test is negative, is a kind of desirable mothproof articles for use.
Following embodiment will be further described the technical scheme of gulgul of the present invention.
Embodiment 1 gulgul medicine is by chlopyrifos, aerosol chrysanthemum ester, pigment, and polyacrylate, P-hydroxybenzoic acid third fat, thickener M type, spices and water mix.Its percentage by weight is 7.5: 2.5: 2: 5: 0.1: 7: 0.5: 76.4.The insecticidal paint compound method is earlier with insecticide chlopyrifos (emulsion) and preservative propylparaben, mixed dissolution, stirring, add entry, pigment, adhesive polyacrylate and thickener M type then successively by weight percentage, stir more than half an hour, coating is coated in equably on 100 * 12 centimetres the paper tape, after 100 ℃ of oven dry in 1~3 minute, aerosol chrysanthemum fat and spices in spray or the roller coating again, at last whole piece paper tape pleat is become the paper of 10 * 12 centimetres of sizes to paste, encapsulate with plastic sack.Open plastic sack during use, put 1-2 bar paper tape in the case in per 1 cubic metre of space or the cupboard.
Embodiment 2 gulgul medicines are mixed by insecticide chlopyrifos, pigment, polyacrylate, propylparaben, thickener M type, spices and water.Its percentage by weight is 15: 2: 10: 0.1: 5: 0.5: 67.4.Preparation method such as embodiment 1.
Embodiment 3 gulgul medicines are by chlopyrifos, 3-borneol, pigment, polyvinyl acetate, and propylparaben, thickener M type, spices and water mix.Its percentage by weight is 3.8: 3.8: 2: 5: 0.1: 7: 0.5: 77.8.Preparation method such as embodiment 1.
Embodiment 4 gulgul medicines are mixed by chlopyrifos, decis, pigment, polyvinyl acetate, propylparaben, thickener M type, spices and water.Its percentage by weight is 7.5: 0.1: 2: 5: 0.1: 7: 0.5: 77.8, and preparation method such as embodiment 1.
Use the embodiment of above-mentioned four different formulations, the curtain casemaking clothes moth is all had good killing action, but their residual effect is different.Embodiment 1,3,4 residual effects are six months, the longevity of residure that embodiment 2 tools are above one year.The residual effect of embodiment 1-4 (room temperature 20-26 ℃) in open environment is carried out.In fact all kinds of mothproofing agent major parts are to be placed in the more airtight environment of wardrobe, chest and drawer to use, so the residual effect of practical application is much longer.

Claims (1)

1, a kind of gulgul is characterized in that it contains the adhesive of 2-20% chlopyrifos and 1-5% pigment and 2-30% polyacrylate or high-molecular polyvinyl alcohol resin and 1-15% thickener M and 0.01-1% propylparaben or butyl p-hydroxybenzoate or methyl p-hydroxybenzoate or ethyl-para-hydroxybenzoate or with the combination of Antisepticize and mildew preventive and the 0.1-2% spices and the water of above-mentioned four kinds of preservative blends.
CN95113304A 1995-10-19 1995-10-19 Mothproofing paint Expired - Fee Related CN1046842C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN95113304A CN1046842C (en) 1995-10-19 1995-10-19 Mothproofing paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN95113304A CN1046842C (en) 1995-10-19 1995-10-19 Mothproofing paint

Publications (2)

Publication Number Publication Date
CN1125512A CN1125512A (en) 1996-07-03
CN1046842C true CN1046842C (en) 1999-12-01

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Family Applications (1)

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CN95113304A Expired - Fee Related CN1046842C (en) 1995-10-19 1995-10-19 Mothproofing paint

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CN (1) CN1046842C (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103039520A (en) * 2012-12-25 2013-04-17 林玉财 Ointment capable of preventing and curing tree moths
CN107459812A (en) * 2017-08-26 2017-12-12 安徽智博新材料科技有限公司 Construction material based on cyclic carbonate
CN109749501A (en) * 2017-11-02 2019-05-14 丹阳八紫光能有限公司 A kind of Anti-moth-eating sofa cloth

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2090139A (en) * 1980-12-29 1982-07-07 Dow Chemical Co Improvements in Insecticidal Compositions
EP0210416A1 (en) * 1985-07-18 1987-02-04 Shell Internationale Researchmaatschappij B.V. Insecticidally active agent for combating textile pests
US4797381A (en) * 1987-07-30 1989-01-10 The Standard Oil Company Preparation of abrasion resistant alumina-supported vanadium-antimony oxidic catalysts

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2090139A (en) * 1980-12-29 1982-07-07 Dow Chemical Co Improvements in Insecticidal Compositions
EP0210416A1 (en) * 1985-07-18 1987-02-04 Shell Internationale Researchmaatschappij B.V. Insecticidally active agent for combating textile pests
US4797381A (en) * 1987-07-30 1989-01-10 The Standard Oil Company Preparation of abrasion resistant alumina-supported vanadium-antimony oxidic catalysts

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