CN104674576B - A kind of method preparing accelerant based on high glass gall - Google Patents
A kind of method preparing accelerant based on high glass gall Download PDFInfo
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- CN104674576B CN104674576B CN201510082676.4A CN201510082676A CN104674576B CN 104674576 B CN104674576 B CN 104674576B CN 201510082676 A CN201510082676 A CN 201510082676A CN 104674576 B CN104674576 B CN 104674576B
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Abstract
The invention belongs to field of inorganic chemical engineering, produce the sodium chloride in produced high glass gall, sodium sulfate particularly to a kind of based on primary brine, as the dyeing and finishing technology comprehensive utilization new technology of accelerant.The invention provides a kind of high glass gall as accelerant when contaminating on dyestuff, both solved height glass gall intractable problem during primary brine processed, solve again conventional dyeing process and add the relatively costly problem that sodium chloride or Matrii Sulfas Exsiccatus bring as accelerant.Meanwhile, it is better than conventional dyeing process product with this type of high glass gall as the effect that accelerant is played, and has saved the consumption of accelerant.
Description
Technical field
The invention belongs to field of inorganic chemical engineering, produce the sodium chloride in produced high glass gall, sodium sulfate particularly to a kind of based on primary brine, as the dyeing and finishing technology comprehensive utilization new technology of accelerant.
Background technology
Printing and dyeing assistant generally comprises printing assistant and dyeing assistant.Wherein dyeing assistant is divided into again: stain, dispersant, levelling agent, color fixing agent, fluorescent whitening agent, softener etc..The present invention is a kind of in stain is for promoting the reagent of dye on dyestuff, also known as accelerant.
Accelerant is that a kind of dyestuff that can improve is to the dye-uptake of fiber, acceleration dyeing rate, dye content in minimizing residual liquid, it is thus achieved that the compound of higher dye level.Its short dye effect is determined by the consumption of accelerant, dyeing temperature and dye bath acid-base value.Owing to accelerant is improving the dyeing rate that also can accelerate dyestuff while tinctorial yield, therefore, to control the opportunity adding accelerant well, it is prevented that dyeing initial stage dye strength time very big excessive addition accelerant and cause uneven dyeing phenomenon.The differences of different with the kind of fiber according to dyestuff from dyeing mechanism, accelerant has many types, but is reduce the zeta potential between fiber and dyestuff nothing more than a class, promote dyestuff and fiber further to；Another kind of is exactly change the electrical of fiber so that it is positive charge different from dye anion on band, produces electrostatic attraction effect and promotes the combination of dyestuff and fiber.Accelerant mainly has following three kinds: 1, Sal or Matrii Sulfas Exsiccatus: be used as the accelerant of direct dyes, reactive dye；2, glacial acetic acid: be used as the accelerant of acid stain dye silk fiber；3, sulphuric acid: be used as the accelerant of acid stain dye wool fibre.Currently for direct dyes contaminates cellulose fibre and the accelerant of one of color additive contaminating cotton fiber on reactive dye, it is typically all and directly buys sodium chloride and anhydrous sodium sulfate, be then added in dye bath and carry out textile dyeing.First, purchase sodium chloride and sodium sulfate price are costly；Second, also need to again be configured to this type of material solution at dyeing phase, expend time in, manpower, increase unnecessary operation.China is printing and dyeing big countries, and the Year's consumption of salt accelerant is considerable, and therefore the present invention has very wide market prospect.
Meanwhile, Ye Shichan salt big country of China, within 2013, salt total output is about 64,000,000 tons, and wherein liquid salt and primary brine yield account for 10%.The current prevailing technology of production of liquid salt is embrane method, the embrane method liquid salt thing followed is exactly the process problem of substantial amounts of high glass gall, specifically: former halogen removes after major part calcium ions and magnesium ions through two alkaline process, after removing brine sludge then through ceramic membrane filter, acid adjustment is to pH5～7, through NF membrane, two strands of liquid of NF membrane output, one be low glass gall and sodium sulphate content very low, this is primary brine；One is then high glass gall, if untreated, directly environment will certainly be caused very big destruction by discharge.Although the high glass gall comprehensive utilization process being no lack of in the last few years comes out, such as frozen saltpeter mention.The problem that but numerous methods all exist process high glass gall difficulty, energy consumption is higher.Before the present invention, the method still not having completely turn waste into wealth, fundamentally solve the harm of high glass gall.High glass gall is as the waste water producing primary brine, and outer row is unfavorable to environmental protection, processes comparatively speaking comparatively difficulty, and processing cost is higher, if it fully being recycled producing or environmental protection all having very great meaning.
Summary of the invention
The present invention is directed to the technical problem that background section above exists, the technical scheme of employing is:
A kind of " waste water " high glass gall that will produce primary brine is provided, turns waste into wealth, the method for preparation accelerant:
First, the pH value of high glass gall is adjusted to 5～8.5, it is then heated to 30～100 DEG C, and it is incubated 1～2 hour, the solid impurity in high glass gall (particularly this kind of impurity of similar calcium carbonate) is made to decompose rapidly, then carry out after gradient cooling (10～20 DEG C/min) is cooled to room temperature (25 DEG C), high glass gall is filtered by the device of similar micro-filtration membrane, remove a small amount of insoluble matter, finally can obtain the high glass gall processed, carry out a certain proportion of mixture with deionized water again, just can serve as accelerant
As preferably: in above-mentioned high glass gall processing procedure, control in high glass gall, the final content of each active component is, sodium sulfate 20g/L～80g/L；Sodium chloride 10g/L～40g/L；Calcium, magnesium ion total amount 0.2g/L～0.5g/L；Iron ion (is mainly 3 valency iron ions) 0.4g/L～0.8g/L；Barium ions 0.06g/L～0.2g/L；Strontium ion 0.11g/L～0.18g/L,
In high glass gall processing procedure, can pass through to add the means of some ion component, the each component in high glass gall is made to be finally reached above-mentioned content range, and when in the high glass gall after processing, each micro ion is in above-mentioned content range, cooperative effect can be played with basic accelerant sodium sulfate, sodium chloride, farthest improve the short dye effect of accelerant, save the consumption of accelerant: general consumption is 5%～10%, and namely the addition of accelerant accounts for by the weight ratio (owf) of dyeing and weaving thing；In the present invention, the consumption of accelerant is 2%～3% (owf), saves accelerant consumption.
Present invention also offers the application in dyeing and printing process of a kind of above-mentioned accelerant, particularly as follows:
Cotton fiber is carried out upper dye; bath raio is 1:30; adopt commercially available K type one chloro-s-triazine reactive dye (active red KE 3B); dye dosage is 6% (owf) of fabric quality; the consumption of the accelerant of addition is 2% (owf) of fabric quality, and the pH regulating dye liquor is 10.
The initial temperature of dyeing is room temperature (25 degrees Celsius), is warming up to 80 degrees Celsius with the heating rate of 4 DEG C/min, dyes 1 hour, after dyeing, it is naturally cooling to room temperature (25 DEG C), dries by the fabric washing in dye liquor and at 70 DEG C, obtain dyed fabric.
The beneficial effects of the present invention is: the present invention is directed to the present situation that current high glass gall is not fully used and in dyeing and finishing technology, accelerant makes consumption considerable, it is proposed that utilize the high glass gall rich in sodium chloride, sodium sulfate to make the process program of printing and dyeing assistant product.Provide a kind of high glass gall as accelerant when contaminating on dyestuff, both solved height glass gall intractable problem during primary brine processed, solve again conventional dyeing process and add the relatively costly problem that sodium chloride or Matrii Sulfas Exsiccatus bring as accelerant.Meanwhile, slightly it is better than conventional dyeing process product with this type of high glass gall as the effect that accelerant is played, and has saved the consumption of accelerant.
In the high glass gall that the present invention processed, there is a small amount of dissociated ion, such as calcium ion, magnesium ion, iron ion, strontium ion, barium ions, the positive charge that they are with, easily make dyestuff dispersed in the solution, enable dyestuff uniform and clothing in contact, thus improving dye-uptake and the even dyeing effect of dyestuff.And the ionic radius of calcium, strontium ion is big compared with sodium ion, a small amount of free calcium, strontium, barium ions can effectively stop the Local enrichment of sodium ion such that it is able to better profit from the short dye effect of sodium ion.A small amount of calcium, strontium, barium, ferrum, magnesium ion existence even can also stop the precipitation of Chlorine in Solution sodium crystal when temperature is too low, thus advantageously in the storage of the present invention.
Detailed description of the invention
Experiment 1: the present invention is described further below by instantiation:
In each embodiment, the pH value of high glass gall is adjusted to 5, it is then heated to 80 DEG C, and it is incubated 2 hours, the solid impurity in high glass gall (particularly this kind of impurity of similar calcium carbonate) is made to decompose rapidly, then carry out after gradient cooling (10 DEG C/min) is cooled to room temperature (25 DEG C), high glass gall is filtered by the device of similar micro-filtration membrane, remove a small amount of insoluble matter, finally can obtain the high glass gall processed, carry out a certain proportion of mixture with deionized water again, just can serve as accelerant
And the ratio of each component (in table 1, each unit containing numerical quantity is mass concentration " g/L ") as shown in table 1 in the accelerant obtained in each embodiment:
Table 1
| Sodium sulfate | Sodium chloride | Calcium ion | Magnesium ion | Iron ion /+3 | Barium ions | Strontium ion | |
| Embodiment 1 | 40 | 20 | 0.1 | 0.3 | 0.5 | 0.12 | 0.15 |
| Embodiment 2 | 40 | 20 | 0.2 | 0.3 | 0.4 | 0.10 | 0.12 |
| Embodiment 3 | 40 | 20 | 0.3 | 0.1 | 0.5 | 0.11 | 0.18 |
| Embodiment 4 | 40 | 20 | 0.2 | 0.2 | 0.7 | 0.15 | 0.14 |
| Comparative example 1 | 40 | 20 | 0.3 | 0.3 | 0.4 | 0.06 | 0.06 |
| Comparative example 2 | 40 | 20 | 0.05 | 0.08 | 0.4 | 0.12 | 0.2 |
| Comparative example 3 | 40 | 20 | 0.15 | 0.15 | 0.3 | 0.20 | 0.15 |
| Comparative example 4 | 40 | 20 | 0.2 | 0.3 | 0.86 | 0.15 | 0.08 |
Adopt each embodiment in table 1 or the accelerant in comparative example, cotton fiber is carried out upper dye: bath raio is 1:30, adopt commercially available K type one chloro-s-triazine reactive dye (active red KE 3B), dye dosage is 6% (owf) of fabric quality, the accelerant added consumption is fabric quality 2% that (" 2% " here is particularly limited as: sodium sulfate in accelerant effective ingredient and the gross mass of sodium chloride, for fabric weight 2%), and the pH regulating dye liquor is 10
The initial temperature of dyeing is room temperature (25 degrees Celsius), is warming up to 80 degrees Celsius with the heating rate of 4 DEG C/min, dyes 1 hour, after dyeing, it is naturally cooling to room temperature (25 DEG C), dries by the fabric washing in dye liquor and at 70 DEG C, obtain dyed fabric.
Adopt the accelerant of the various embodiments described above, comparative example, the dyeing ability after textile dyeing is as shown in table 2:
Table 2 (quality standard FZ71004-91)
Experiment 2:
Adopt commercially available pure sodium sulfate, sodium chloride to be made into accelerant, adopt the dyeing as tested in 1 that cotton fiber is dyeed,
The ratio of each component (in table 3, each unit containing numerical quantity is mass concentration " g/L ") as shown in table 3 in the accelerant of preparation in this experiment:
Table 3
| Sodium sulfate | Sodium chloride | Calcium ion | Magnesium ion | Iron ion /+3 | Barium ions | Strontium ion | |
| Embodiment 1 | 40 | 20 | ╲ | ╲ | ╲ | ╲ | ╲ |
Adopt the accelerant in table 3, cotton fiber is carried out upper dye: bath raio is 1:30, adopt commercially available K type one chloro-s-triazine reactive dye (active red KE 3B), dye dosage is 6% (owf) of fabric quality, (" 2% " here is particularly limited as consumption is fabric quality the 2% of the accelerant added: the gross mass of accelerant effective ingredient sodium sulfate and sodium chloride, for fabric weight 2%), and the pH regulating dye liquor is 10
The initial temperature of dyeing is room temperature (25 degrees Celsius), is warming up to 80 degrees Celsius with the heating rate of 4 DEG C/min, dyes 1 hour, after dyeing, it is naturally cooling to room temperature (25 DEG C), dries by the fabric washing in dye liquor and at 70 DEG C, obtain dyed fabric.
Adopt the accelerant of experiment 2, the dyeing ability after textile dyeing is as shown in table 4:
Table 4 (quality standard FZ71004-91)
Experiment 3:
Cotton fiber is dyeed by same (pure) accelerant adopted in experiment 2, (" 8% " here is particularly limited as consumption is fabric quality the 8% of the accelerant that adjustment adds: the gross mass of accelerant effective ingredient sodium sulfate and sodium chloride, for fabric weight 8%), on remaining, dyeing technique is all identical with experiment 2
Adopt the accelerant of experiment 3, the dyeing ability after textile dyeing is as shown in table 5:
Table 5 (quality standard FZ71004-91)
Claims (1)
1. the method preparing accelerant based on high glass gall, it is characterized in that: described method is, first the pH value of high glass gall is adjusted to 5～8.5, it is again heated to 30～100 DEG C, then carries out after gradient cooling is cooled to room temperature, being filtered by high glass gall, the high glass gall processed can be obtained, again with deionized water mixture, obtain accelerant
Wherein, in the processing procedure of above-mentioned high glass gall, the final content of each active component in the described high glass gall processed is made to be by adding some ion component, sodium sulfate 20g/L～80g/L；Sodium chloride 10g/L～40g/L；Calcium, magnesium ion total amount 0.2g/L～0.5g/L；Iron ion 0.4g/L～0.8g/L；Barium ions 0.06g/L～0.2g/L；Strontium ion 0.11g/L～0.18g/L.
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| US20090324574A1 (en) * | 2006-02-02 | 2009-12-31 | Verenium Corporation | Esterases and Related Nucleic Acids and Methods |
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| CN102926234A (en) * | 2012-11-05 | 2013-02-13 | 绍兴文理学院 | Activated dye accelerating agent and dyeing method |
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| CN104695252A (en) * | 2015-02-13 | 2015-06-10 | 中盐金坛盐化有限责任公司 | Method for preparing dyeing accelerant from high liquid glauber salt |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2000096458A (en) * | 1998-09-29 | 2000-04-04 | Ipposha Oil Ind Co Ltd | Exhaustion-accelerating agent and exhaustion dyeing of fiber |
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|---|---|---|---|---|
| US5207800A (en) * | 1991-10-07 | 1993-05-04 | Burlington Chemical Co., Inc. | Low toxicity, biodegradable salt substitute for dyeing textiles: magnesium acetate in direct or reactive dyeing of cotton |
| WO2007068753A1 (en) * | 2005-12-15 | 2007-06-21 | Sicit Chemitech S.P.A. | Process for the production of hydrolyzed-protein based products in composition with zinc |
| US20090324574A1 (en) * | 2006-02-02 | 2009-12-31 | Verenium Corporation | Esterases and Related Nucleic Acids and Methods |
| CN101806002A (en) * | 2010-03-03 | 2010-08-18 | 广东德美精细化工股份有限公司 | Accelerating agent for reactive dyeing, and preparation method and applications thereof |
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