CN104674244A - Inorganic acid washing agent - Google Patents

Inorganic acid washing agent Download PDF

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Publication number
CN104674244A
CN104674244A CN201310633635.0A CN201310633635A CN104674244A CN 104674244 A CN104674244 A CN 104674244A CN 201310633635 A CN201310633635 A CN 201310633635A CN 104674244 A CN104674244 A CN 104674244A
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CN
China
Prior art keywords
parts
acid
inorganic acid
washing agent
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310633635.0A
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Chinese (zh)
Inventor
周相勇
张森
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Hao Tai Water Utilities Co Ltd
Original Assignee
Qingdao Hao Tai Water Utilities Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao Hao Tai Water Utilities Co Ltd filed Critical Qingdao Hao Tai Water Utilities Co Ltd
Priority to CN201310633635.0A priority Critical patent/CN104674244A/en
Publication of CN104674244A publication Critical patent/CN104674244A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/04Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

The invention discloses an inorganic acid washing agent. The inorganic acid washing agent comprises the following components in parts by weight: 6 to 12 parts of hydrochloric acid, 0.2 to 0.5 part of corrosion inhibitor, 0.01 to 0.03 part of nonionic surface active agent, 1 to 3 parts of nitric acid, 2 to 4 parts of methenamine, 0.2 to 0.4 part of rodine, 0.1 to 0.3 part of acetic acid, 0.2 to 0.5 part of EDTA and the balance of water. The inorganic acid washing agent has characteristics that the price is cheap, the production cost is low, the corrosion on a stainless steel device and an aluminum alloy device can be avoided, and the inorganic acid washing agent is suitable for washing the special metal devices; and moreover, the washing speed can be increased by virtue of appropriate heating, the rust on the surface of the metal can be effectively eliminated, and various dirt such as tar, seaweeds organisms and the like can be eliminated.

Description

A kind of inorganic acid scavenger
Technical field
The invention belongs to chemical field, specifically relate to a kind of inorganic acid scavenger.
Background technology
Acid-alkali clean-out system by means of with dirt generation acid-base reaction, sometimes also with reactions such as oxidation-reductions, make dirt change solubilized into or be scattered in the clean-out system of scavenging solution, being acid or alkaline salt after being mostly mineral acid, alkali and hydrolysis, sometimes also using organic acid.
The auxiliary agent that most of acid-alkali clean-out system all adds necessity by the aqueous solution that is sour, alkali forms.Another kind of under the high temperature conditions with the acid of molten state and dirt digestion or alkali, make originally not dissolve or difficulty is dissolved in dirt in cleaning restraining, be converted into diffluent compound, this kind of acid or alkali are commonly referred to melting agent.When this clean-out system is difficult to for solvent or solution the dirt removed, there is good effect.
The advantage making scavenging solution with sulfuric acid is its low price, does not have corrodibility to stainless steel and aluminium alloy equipment, is applicable to these Special Metal equipment of cleaning.Sulfuric acid is again the not volatile strong acid of one, so can accelerate cleaning speed by suitably heating.Usually nonionogenic tenside is added to improve its rust cleaning ability when general industry utilizing sulfuric acid clean.Adding appropriate nitric acid in sulfuric acid and can remove the multiple dirts such as tar, Jiao Yan, seaweeds biology, a certain amount of inhibition dosage will be added to reduce sulfuric acid to the corrodibility of metal object in clean-out system.
Summary of the invention
The present invention relates to a kind of inorganic acid scavenger, it has low price, the advantage that production cost is low, and corrodibility is not had to stainless steel and aluminium alloy equipment, be applicable to these Special Metal equipment of cleaning, and cleaning speed can be accelerated by suitably heating, effectively can remove the corrosion of metallic surface, moreover, the multiple dirt such as tar, seaweeds biology can also be removed.
Inorganic acid scavenger of the present invention is made up of following formula and the cooperation of quality component forms: hydrochloric acid 6 ~ 12 parts, inhibiter 0.2 ~ 0.5 part, nonionogenic tenside 0.01 ~ 0.03 part, 1 ~ 3 part, nitric acid, urotropine 2 ~ 4 parts, if fourth 0.2 ~ 0.4 part, acetic acid 0.1 ~ 0.3 part, EDTA0.2 ~ 0.5 part, surplus is water.
A kind of manner of formulation of inorganic acid scavenger is: if the sulfuric acid of aforementioned proportion, inhibiter, nonionogenic tenside, nitric acid, urotropine fourth, acetic acid, EDTA are joined in a certain amount of water, stir and can obtain this inorganic acid scavenger.
Embodiment
Embodiment 1:
To prepare inorganic acid scavenger 100g:
Hydrochloric acid 9g, inhibiter 0.2g, nonionogenic tenside 0.01g, nitric acid 1.2g, urotropine 2.1g, if fourth 0.3g, acetic acid 0.2g, EDTA0.2g, surplus is water.
A kind of manner of formulation of inorganic acid scavenger is: if the sulfuric acid of aforementioned proportion, inhibiter, nonionogenic tenside, nitric acid, urotropine fourth, acetic acid, EDTA are joined in a certain amount of water, stir and can obtain this inorganic acid scavenger.
In above-described embodiment, applying rational quality proportioning, make the product obtained not have corrodibility to stainless steel and aluminium alloy equipment, be applicable to these Special Metal equipment of cleaning, is a kind of inorganic acid scavenger efficiently.
Embodiment 2:
To prepare inorganic acid scavenger 100g:
Hydrochloric acid 11g, inhibiter 0.3g, nonionogenic tenside 0.02g, nitric acid 2.1g, urotropine 3.4g, if fourth 0.25g, acetic acid 0.15g, EDTA0.3g, surplus is water.
The manner of formulation of inorganic acid scavenger is identical with embodiment 1.
In above-described embodiment, have changed the mass fraction of each material, the present invention can accelerate cleaning speed by suitably heating, and reaches the effect of the corrosion of effectively removing metallic surface.
Embodiment 3:
To prepare inorganic acid scavenger 100g:
Hydrochloric acid 10g, inhibiter 0.25g, nonionogenic tenside 0.03g, nitric acid 3g, urotropine 1.5g, if fourth 0.2g, acetic acid 0.3g, EDTA0.4g, surplus is water.
In above-described embodiment, by changing the mass fraction of each material, the product obtained not only has the effect that well eliminates rust, and can also remove the multiple dirt such as tar, seaweeds biology.
In sum, the present invention has low price, the advantage that production cost is low, and corrodibility is not had to stainless steel and aluminium alloy equipment, be applicable to these Special Metal equipment of cleaning, and cleaning speed can be accelerated by suitably heating, effectively can remove the corrosion of metallic surface, moreover, the multiple dirt such as tar, seaweeds biology can also be removed.
Although done detailed description, protection domain has been not limited thereto.

Claims (5)

1. an inorganic acid scavenger, it is characterized in that, each component material and mass fraction thereof are: hydrochloric acid 6 ~ 12 parts, inhibiter 0.2 ~ 0.5 part, nonionogenic tenside 0.01 ~ 0.03 part, 1 ~ 3 part, nitric acid, urotropine 2 ~ 4 parts, if fourth 0.2 ~ 0.4 part, acetic acid 0.1 ~ 0.3 part, EDTA0.2 ~ 0.5 part, surplus is water.
2. inorganic acid scavenger according to claim 1, is characterized in that each component materials and mass fraction thereof are: hydrochloric acid 9 parts, inhibiter 0.2 part, nonionogenic tenside 0.01 part, 1.2 parts, nitric acid, urotropine 2.1 parts, if fourth 0.3 part, acetic acid 0.2 part, EDTA0.2 part, surplus is water.
3. inorganic acid scavenger according to claim 1, it is characterized in that each component materials and mass fraction thereof are: hydrochloric acid 11 parts, inhibiter 0.3 part, nonionogenic tenside 0.02 part, 2.1 parts, nitric acid, urotropine 3.4 parts, if fourth 0.25 part, acetic acid 0.15 part, EDTA0.3 part, surplus is water.
4. inorganic acid scavenger according to claim 1, is characterized in that each component materials and mass fraction thereof are: hydrochloric acid 10 parts, inhibiter 0.25 part, nonionogenic tenside 0.03 part, 3 parts, nitric acid, urotropine 1.5 parts, if fourth 0.2 part, acetic acid 0.3 part, EDTA0.4 part, surplus is water.
5. inorganic acid scavenger according to claim 1, it is characterized in that manner of formulation is: if the sulfuric acid of aforementioned proportion, inhibiter, nonionogenic tenside, nitric acid, urotropine fourth, acetic acid, EDTA are joined in a certain amount of water, stir and this inorganic acid scavenger can be obtained.
CN201310633635.0A 2013-12-02 2013-12-02 Inorganic acid washing agent Pending CN104674244A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310633635.0A CN104674244A (en) 2013-12-02 2013-12-02 Inorganic acid washing agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310633635.0A CN104674244A (en) 2013-12-02 2013-12-02 Inorganic acid washing agent

Publications (1)

Publication Number Publication Date
CN104674244A true CN104674244A (en) 2015-06-03

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310633635.0A Pending CN104674244A (en) 2013-12-02 2013-12-02 Inorganic acid washing agent

Country Status (1)

Country Link
CN (1) CN104674244A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106191877A (en) * 2016-08-11 2016-12-07 黄平县力星清洗剂生产有限公司 A kind of abluent for cleaning dyeing apparatus surface smut
CN106191947A (en) * 2015-12-01 2016-12-07 江苏九天光电科技有限公司 Before being suitable for steel band plating, quickly defat activates two-in-one inorganic agent collocation method
CN106222712A (en) * 2015-12-01 2016-12-14 江苏九天光电科技有限公司 Before being suitable for steel band plating, quickly defat activates two-in-one inorganic agent
CN106222713A (en) * 2015-12-01 2016-12-14 江苏九天光电科技有限公司 Before being suitable for steel band plating, quickly defat activates two-in-one inorganic agent, collocation method and application
CN106544613A (en) * 2016-11-30 2017-03-29 佛山市高明区诚睿基科技有限公司 A kind of preparation method of use for laboratory rustless steel stirring rod
CN112708893A (en) * 2019-10-24 2021-04-27 中国石油天然气股份有限公司 Cleaning agent, preparation method thereof, cleaning device and cleaning method of plate heat exchanger
CN112779544A (en) * 2019-11-06 2021-05-11 晟通科技集团有限公司 Rust removal cleaning agent and use method thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106191947A (en) * 2015-12-01 2016-12-07 江苏九天光电科技有限公司 Before being suitable for steel band plating, quickly defat activates two-in-one inorganic agent collocation method
CN106222712A (en) * 2015-12-01 2016-12-14 江苏九天光电科技有限公司 Before being suitable for steel band plating, quickly defat activates two-in-one inorganic agent
CN106222713A (en) * 2015-12-01 2016-12-14 江苏九天光电科技有限公司 Before being suitable for steel band plating, quickly defat activates two-in-one inorganic agent, collocation method and application
CN106191877A (en) * 2016-08-11 2016-12-07 黄平县力星清洗剂生产有限公司 A kind of abluent for cleaning dyeing apparatus surface smut
CN106544613A (en) * 2016-11-30 2017-03-29 佛山市高明区诚睿基科技有限公司 A kind of preparation method of use for laboratory rustless steel stirring rod
CN106544613B (en) * 2016-11-30 2019-01-22 佛山市高明区诚睿基科技有限公司 A kind of preparation method of use for laboratory stainless steel stirring rod
CN112708893A (en) * 2019-10-24 2021-04-27 中国石油天然气股份有限公司 Cleaning agent, preparation method thereof, cleaning device and cleaning method of plate heat exchanger
CN112779544A (en) * 2019-11-06 2021-05-11 晟通科技集团有限公司 Rust removal cleaning agent and use method thereof

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Application publication date: 20150603