CN104673461B - A kind of air compressor oil composition of utilization reclaimed oil production - Google Patents
A kind of air compressor oil composition of utilization reclaimed oil production Download PDFInfo
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- CN104673461B CN104673461B CN201510041567.8A CN201510041567A CN104673461B CN 104673461 B CN104673461 B CN 104673461B CN 201510041567 A CN201510041567 A CN 201510041567A CN 104673461 B CN104673461 B CN 104673461B
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Abstract
The invention provides a kind of air compressor oil composition of utilization reclaimed oil production, it is characterised in that：The lubricating oil by following raw materials in parts by weight array into：Reclaimed Base Oil:0.01 99 parts, other base oils：0.01 99.0 parts, viscosity improver：0.01 10.0 parts, detersive：3 10.0 parts, dispersant：1.0 5.0 parts, oxidation and corrosion inhibitor：0.5 3.0 parts, extreme pressure anti-wear additives：0.5 2.0 parts, antirust agent：0.5 4.0 parts, anti emulsifier：0.0001 0.3 parts, defoamer：0.0001 0.01 parts.The air compressor oil composition can meet the performance requirement that (Q/SYRH2033 2001) air compressor oils of GB12691 90 viscosity grade is 32,46,68,100,150.
Description
Technical field
The present invention relates to air compressor oil composition, being particularly suitable for use in has the piston type and oil dripping swinging of oil lubrication empty
Air compressor.
Background technology
The existing air compressor oil formula design of China is oily based on complete new oil, and addition compound additive is
It is main, and the Formula Development and products application research using Reclaimed Base Oil are nearly at blank.The world will consume substantial amounts of every year
Lubricating oil, produces substantial amounts of waste lubricating oil, if waste lubricating oil is discarded into environment, serious dirt will be caused to environment again
Dye, and huge economic benefit can then be brought by regenerating recovery waste lubricating oil.This technology is exactly response national policy, protection ring
Border, the technical scheme rationally actively probed into using resource.The regeneration base produced using Xinjiang Fuke oil Co., Ltd
Plinth oil prepares air compressor oil, and the air compressor oil composition can meet GB12691-90 (Q/SYRH2033-2001)
Air compressor oil viscosity grade is 32,46,68,100,150 performance requirement.
Searching document is disclosed：[1] patent CN103897790 [2] patent CN103740439 [3] patent CN103773575
[4] patent CN103194303 [5] patent CN103131523 [6] patent CN103122268 [7] patent CN103184090
[8] patent CN101538501 [9] patent CN101724489 is the patent for being related to the present invention.
China's air compressor oil is main based on mineral type, the production model supplemented by synthesis type.Although synthesis type performance
Higher but expensive, at present, most of air compressor oil is still oily based on refined mineral oil, and refined mineral oil
Resource gradually atrophy, is environmental protection, economizes on resources, and refuse reclamation turns into the inexorable trend of current development of the situation.China is every
The waste lubricating oil number that year is formed is in terms of ten thousand tons.If waste lubricating oil is discarded into environment, Metal Salts therein contain
The organic compounds such as sulphur, phosphorus, will cause severe contamination to environment.Therefore waste lubricant oil regeneration is reasonable energy utilization, circulation
The inexorable trend of economic development.
The present invention exactly resource gradually with shortage, under the situation of refuse reclamation, Fu Ke oil products limited company utilizes
Reclaimed Base Oil prepares air compressor oil, and the product is mainly used in the piston type for having oil lubrication and oil dripping swinging air pressure
Contracting machine.
The content of the invention
It is an object of the invention to：The air compressor oil for providing a kind of utilization reclaimed lubricating base oil and producing, meets
The air compressor oil performance requirement of each rank.
The object of the present invention is achieved like this：A kind of air compressor oil composition of utilization reclaimed oil production, the profit
Lubricating oil by following raw materials in parts by weight array into：Reclaimed Base Oil:100.0 parts, other base oils：0.01-99.0 parts, viscosity changes
Enter agent：0.01-10.0 parts, detersive：3-10.0 parts, dispersant：1.0-5.0 part, oxidation and corrosion inhibitor：0.5-3.0 parts, extreme pressure resist
Grinding agent：0.5-3.0 parts, antirust agent：0.5-4.0 parts, anti emulsifier：0.0001-0.3 parts, defoamer：0.0001-0.01 parts.
The technical principle and beneficial effect of the present invention：The Reclaimed Base Oil produced using Fu Ke oil products limited company is glued
Spend index high, outward appearance is well-illuminated transparent, modest viscosity；There is significant detergent power from detersive；Had from dispersant excellent
Good dispersiveness；There are preferable antioxidant-anticorrosive properties from oxidation and corrosion inhibitor；There is good thickening from viscosity improver
Performance；From anti emulsifier, with splendid emulsion resistance effect；There is defoaming from defoamer, can be in good time according to foaming characteristic
Adjustment.
Air compressor oil produced by the invention, can not only rationally utilize resource, and cost-effective, utilize reclaimed oil
The air compressor oil of preparation, viscosity index (VI) is high, and pour point is low, and flash-point is high, corrosion-resistant to wait excellent properties, complies fully with air compression
Every physical and chemical index of machine oil.
Embodiment
The present invention is described further in conjunction with the embodiments.
Embodiment 1
Prepared with parts by weight, air compressor oil：
Formula 1：
100.0 parts of Reclaimed Base Oil, 15# is refined 22.0 parts, 10.0 parts of PAO2,2.0 parts of ethylene-propylene copolymer, and low alkali value is closed
Into 3.0 parts of sulfoacid calcium, 1.5 parts of polyene-based succimide, double 2.0 parts of the octyl group basic zinc salts of sulphur phosphorus, benzotriazole derivative 1.0
Part, 2.0 parts of sulfide isobutene, 1.0 parts of petroleum sodium sulfonate zinc naphthenate, amine and 0.0004 part of epoxides condensation product, methyl silicon
0.0005 part of oil.
Formula 2：
100.0 parts of Reclaimed Base Oil, 10.5 parts of 2# sulfonation, 10.0 parts of tricarboxymethyl propane oleate, polymethylacrylic acid
3.0 parts of ester, 3.0 parts of low alkali value calcium alkylbenzenesulfonate, 1.0 parts of diene base succimide, 1.0 parts of sulphur phosphorus brothers alcohol radical zinc salt, 2,
1.5 parts of 6- BHTs, 1.5 parts of the positive fourth fat of phosphorous acid two, 1.0 parts of sulfide isobutene, petroleum sodium sulfonate zinc naphthenate
1.5 part, amine and 0.0003 part of epoxides condensation product, 0.0004 part of methyl-silicone oil.
Formula 3：
100.0 parts of Reclaimed Base Oil, 28.0 parts of KG18,13.0 parts of PETO, 4.0 parts of ethylene-propylene copolymer, sulphur
3.0 parts of phosphatization polyisobutene barium salt, 2.5 parts of polyene-based succimide, double 1.0 parts of the octyl group basic zinc salts of sulphur phosphorus, benzotriazole spreads out
0.0003 part of 1.5 parts of biology, 2.5 parts of sulfide isobutene, neutral 1.5 parts of dinonyl naphthalene sulfonate barium, amine and epoxides condensation product,
0.0004 part of methyl-silicone oil.
Formula 4：
100.0 parts of Reclaimed Base Oil, 25.0 parts of 150BS, 15.0 parts of PAO4,5.0 parts of ethylene-propylene copolymer, low alkali value synthesis
3.0 parts of sulfoacid calcium, 2.5 parts of polyene-based succimide, double 1.0 parts of the octyl group basic zinc salts of sulphur phosphorus, 1.0 parts of benzotriazole derivative,
1.5 parts of sulfide isobutene, 1.0 parts of sulphur phosphoric acid nitrogen containing derivative, 1.0 parts of alkenyl succinic acid ester, amine and epoxides condensation product
0.0004 part, 0.0004 part of methyl-silicone oil.
Formula 5：
100.0 parts of Reclaimed Base Oil, 21.0 parts of 150BS, 3.0 parts of polyvinyl n-butyl ether, 3.0 parts of ethylene-propylene copolymer,
3.0 parts of low alkali value calcium alkylbenzenesulfonate, 2.5 parts of diene base succimide, double 1.5 parts of the octyl group basic zinc salts of sulphur phosphorus, 2,6- bis- uncles
1.0 parts of butyl paracresol, 1.0 parts of D2EHDTPA amine salt, 1.5 parts of sulfide isobutene, neutral 1.5 parts of dinonyl naphthalene sulfonate barium, amine
With 0.0004 part of epoxides condensation product, 0.0004 part of methyl-silicone oil.
Above-mentioned preparation 1), 2）, 3) ... select its 1, prepare air compressor oil.
Wherein other base oils include mineral oil 15# refined and/or 150BS and/or MVI400 and/or MVI500 and/or
KG18 and/or MVI300 and/or HVIP8 and/or HVIP5 and/or HVIP6 and/or synthesizing ester base oil trimethylolpropane
Sebacate and/or PETO and/or pentaerythritol adipate and/or trimethylolpropane heptanoate and/or
Neopentyl glycol heptanoate and/or trimethylolpropane ethanedioic acid ester and/or tricarboxymethyl propane oleate and/or poly- α hydro carbons are closed
Into oily PAO2 and/or at least one of PAO4 and/or PAO6.
Wherein the detersive of air compressor oil include low alkali value calcium alkylbenzenesulfonate and/or middle calcium alkylbenzensulfonates and/
Or high base number calcium alkylbenzenesulfonate and/or at least one of sulfur phosphorization polyisobutylene titanate salt and/or magnesium naphthenate.
Wherein the dispersant of air compressor oil be diene base succimide and/or polyene-based succimide and/or
At least one of HMW succimide.
Wherein the oxidation and corrosion inhibitor of air compressor oil is sulphur phosphorus alkyl phenol zinc salt and/or the double octyl group basic zinc salts of sulphur phosphorus
And/or sulphur phosphorus brothers alcohol radical zinc salt and/or sulphur phosphorus secondary alcohol groups zinc salt and/or BHT and/or N- phenyl-α
At least one of naphthylamines and/or benzotriazole derivative.
Wherein the viscosity improver of air compressor oil is polyvinyl n-butyl ether and/or ethylene-propylene copolymer and/or poly-
At least one of methacrylate and/or the different monooctyl ester of polyacrylic acid.
Wherein the extreme pressure anti-wear additives of air compressor oil be the positive fourth fat of phosphorous acid two and/or sulphur phosphoric acid nitrogen containing derivative and/
Or tricresyl phosphate and/or D2EHDTPA amine salt and/or D2EHDTPA phenyl ester and/or sulfide isobutene or the isobutyl of phosphorous acid two
At least one of ester and/or aminothio ester.
Wherein the antirust agent of air compressor oil is barium mahogany sulfonate and/or petroleum sodium sulfonate zinc naphthenate and/or neutrality
At least one of dinonyl naphthalene sulfonate barium and/or alkenyl succinic acid or alkenyl succinic acid ester.
Wherein the anti emulsifier of air compressor oil is amine and epoxides condensation product and/or epoxy second, propane block ether
At least one of and/or PEO-polypropylene oxide.
Every physicochemical property, sees attached list in example.
As can be seen from the table, the air compressor oil prepared using reclaimed lubricating base oil, viscosity index (VI) is high, pour point
Low, demulsification performance is good, disclosure satisfy that the performance requirement that viscosity grade is 32,46,68,100,150.
The standard of product of the present invention is GB12691-90 (Q/SYRH2033-2001).
Reclaimed Base Oil and synthetic ester lubricant are Fu Ke oil products limited company commercially available prod.
The different monooctyl ester of viscosity improver polyvinyl n-butyl ether, ethylene-propylene copolymer, polymethacrylates, polyacrylic acid is equal
It is purchased from Jinzhou Petrochemical Co.；
Detersive low alkali value calcium alkylbenzenesulfonate, middle calcium alkylbenzensulfonates, high base number calcium alkylbenzenesulfonate are purchased from Shandong Zibo
Hui Hua Co., Ltds, sulfur phosphorization polyisobutylene titanate salt, magnesium naphthenate are purchased from Shandong Zibo Hui Hua Co., Ltds；
Dispersant diene base succimide, polyene-based succimide, HMW succimide are purchased from Shandong
Zibo Hui Hua Chemical Co., Ltd.s；
Oxidation and corrosion inhibitor is that sulphur phosphorus alkyl phenol zinc salt, the double octyl group basic zinc salts of sulphur phosphorus, sulphur phosphorus brothers alcohol radical zinc salt, sulphur phosphorus are secondary
Alcohol radical zinc salt, BHT, N- phenyl-alpha-naphthylamines, benzotriazole derivative are purchased from the emerging petroleum additive in Jinzhou
Co., Ltd；
It is the positive fourth fat of extreme pressure agent phosphorous acid two, sulphur phosphoric acid nitrogen containing derivative, tricresyl phosphate or D2EHDTPA amine salt, thio
Phenyl phosphate, sulfide isobutene, aminothio ester, phosphorous acid diisobutyl ester are purchased from Shandong Zibo Hui Hua Chemical Co., Ltd.s；
Antirust agent barium mahogany sulfonate, petroleum sodium sulfonate zinc naphthenate, neutral dinonyl naphthalene sulfonate barium, alkenyl succinic acid, alkene
Base succinate is purchased from the emerging petroleum additive Co., Ltd in Jinzhou；
Anti emulsifier amine and epoxides condensation product, epoxy second, propane block ether, PEO-polypropylene oxide are equal
It is purchased from Nanjing Ning Jiang chemical plant；
Defoamer is purchased from Shandong Zibo Hui Hua Chemical Co., Ltd.s；
Polyalphaolefin class artificial oil is purchased in Mobil lubricating oil Co., Ltd.
Claims (1)
1. a kind of air compressor oil composition of utilization reclaimed oil production, it is characterised in that：Said composition is pressed by following raw materials
Parts by weight are constituted：100.0 parts of Reclaimed Base Oil, 21.0 parts of 150BS, 3.0 parts of polyvinyl n-butyl ether, ethylene-propylene copolymer
3.0 parts, 3.0 parts of low alkali value calcium alkylbenzenesulfonate, 2.5 parts of diene base succimide, double 1.5 parts of the octyl group basic zinc salts of sulphur phosphorus, 2,
1.0 parts of 6- BHTs, 1.0 parts of D2EHDTPA amine salt, 1.5 parts of sulfide isobutene, neutral dinonyl naphthalene sulfonate barium 1.5
Part, amine and 0.0004 part of epoxides condensation product, 0.0004 part of methyl-silicone oil.
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| CN201510041567.8A CN104673461B (en) | 2015-01-28 | 2015-01-28 | A kind of air compressor oil composition of utilization reclaimed oil production |
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| CN104673461B true CN104673461B (en) | 2017-09-12 |
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| CN105482870A (en) * | 2015-12-18 | 2016-04-13 | 常熟市制冷压缩机铸件厂 | Lubricating oil for freezer compressor |
| CN107164035A (en) * | 2017-05-12 | 2017-09-15 | 广西大学 | A kind of composition of environment-friendly fully synthetic supercharging pump oil |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101033433A (en) * | 2007-04-14 | 2007-09-12 | 中国石油化工集团公司 | Regeneration method for waste lubricating oil |
| CN104263481A (en) * | 2014-10-22 | 2015-01-07 | 中国石油化工股份有限公司 | Air compressor oil and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RO118446B1 (en) * | 2001-04-26 | 2003-05-30 | Rafinăria "Astra Română" S.A. | Lubricant composition for air compressors |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101033433A (en) * | 2007-04-14 | 2007-09-12 | 中国石油化工集团公司 | Regeneration method for waste lubricating oil |
| CN104263481A (en) * | 2014-10-22 | 2015-01-07 | 中国石油化工股份有限公司 | Air compressor oil and preparation method thereof |
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